vipu exam r1
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Written Exam for Dr. Vipu
Norman S. Hoffman, PE 3651 Foremast. Dr. Galveston, TX 77554
Phone: (409)‐621‐6740 Email: [email protected]
April 1, 2010
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April 1, 2010 Written Exam for Dr. Vipu Norman S. Hoffman, PE 3651 Foremast. Dr. Galveston, TX 77554 Phone: (409)‐621‐6740, Email: [email protected]
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Table of contents
Plain Concrete Constitutive Laws 3
Smeared Concrete Constitutive Laws 6
Nano‐particle Concrete 21
Figures and Tables
Figure 1, Smeared Constitutive Model for Concrete 7
Figure 2, Stress Strain relationship for Panels TEF‐3, ‐4, and ‐5 9
Table 1, Constitutive Equation Comparison for Plain Concrete and Fiber Concrete 11
Table 2, Softened Membrane Model (SMM) Smeared Constitutive Equation
Comparison for Concrete and Steel Fiber Concrete 17
References 26
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April 1, 2010 Written Exam for Dr. Vipu Norman S. Hoffman, PE 3651 Foremast. Dr. Galveston, TX 77554 Phone: (409)‐621‐6740, Email: [email protected]
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Summarize in complete and concise form the state of knowledge on the constitutive models
for concrete (stress‐strain and failure).
A survey of literature reveals that constitutive material models for plain concrete can be
categorized into three very broad groups based on loading situation, namely:
1) Unixial models
2) Biaxial models
3) Triaxial models
The basic uniaxial stress strain model for plain concrete consists of an ascending branch and a
descending branch. The peak of the curve occurs at a location called concrete compressive
strength while the corresponding strain is the peak compressive strain. There have been
numerous studies and approximations for modeling the stress strain curve of plain concrete
(Popovics, 1970). Important and straight forward approximations of the curve include those
ranging from the Hognestad, 1952 parabola (to which Hognestad attributes to Stussi, 1932), to
those of Desayi & Krishnan 1964 and Wang & Shah, 1978. (See Table 1). The basic approach
for researchers modeling the curve is to base the shape on key parameters that can be
obtained easily from physical tests of specimens, namely the failure criteria, fc’ and e0.
Interestingly, for all the research done on the stress strain curve for plain concrete, the basic
Stussi, 1932 model is still used today in flexural design.
Tension models of plain concrete depend on the testing procedure used (Belarbi, 1994) A
linear behavior is obtained up to the tensile capacity which then ends abruptly with a brittle
failure, thus providing no descending branch. Gopal & Shah, 1985 developed a testing
technique and corresponding analytic model for determining the descending branch of the
tensile curve.
Biaxial models for plain concrete include those developed Zaman 1993, and Gerstle, 1981.
Please refer to Table 1 for a summary and short description of these models.
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How will the constitutive models of concrete be affected if fibers are added?
The addition of fiber to the constitutive models for concrete will by necessity have the same
effect as on the physical or experimental test results. The addition of fibers to plain concrete
has an improving effect on the key material properties listed below, and thus affects the
constitutive model for fiber concrete (Rao 2009, Thomas 2007, Vandewalle 2002, Li 1992,
Traina 1991).
Unixial Compressive Strength, fc’
Uniaxial Peak strain at compressive strength, e0
Modulus of Elasticity, Ec
Uniaxial Tensile Strength, ft
Modulus of Rupture Ductility
Poisson’s Ratio,
The addition of fiber, particularly steel fiber, affects most significantly the tensile strength and
ductility of concrete. Thomas 2007 achieved 38.2% increase in tensile split cylinder strength
using just 1.5% fiber content by volume. Tests by Rao 2009 on standard Modulus of Rupture
test prisms (6” x 6” x 24”) show a marked post peak improvement in load carrying capacity of
fiber concrete as compared to plain concrete. Whereas the plain concrete specimens failed
completely and suddenly upon reaching peak load, the fiber concrete specimens sustained
significant load post‐peak (steel fiber content ranged from 0.5% to 1.5% by volume). Rao
attributes this to the bridging effect of the fibers across the tensile crack. Other researchers (Li
1992, Thomas 2007) show similar tensile results.
The affect of fiber on uniaxial cylinder compressive strength was modest, as compared to its
affect on the tensile strength. Thomas 2007 found an 8.3% increase in compressive capacity
using 1.5% fiber content by volume. He found that there is an increasing linear relation
between fiber content and compressive strength, up to 1.5% fiber, which was the limit of his
investigation.
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Although there is only a modest increase in compressive strength, there is a substantial
increase in compressive strain, e0. Thomas attributes the gain in strain to the confinement
effect of the fibers within the concrete matrix. Again, the relation is linear with increasing fiber
content and the improvement over plain concrete is up to 29% for 1.5% fiber by volume.
Thomas 2007 also found only a slight gain in Ec (8%) with increasing fiber content, up to 1.5%
by volume. There was a lesser gain in poisons ratio.
Key investigation into the biaxial behavior of fiber reinforced concrete was performed by
Kupfer 1969, Traina 1991 and Yin & Hsu 1989. These researchers established the basic failure
envelope for fiber concrete, with respect to plain concrete. Both show that there are
differences between the two types of concrete. The primary difference under biaxial loading is
the increase in compressive strength over plain concrete, for all stress ratios. Furthermore,
when compared to the uniaxial strength, the biaxial strength increases by as much as 85% with
1.5% fiber volume over plain concrete (Traina 1991).
Important Constitutive models for fiber concrete include biaxial models developed by Tan 1993
and Hu 2003. The Tan 1994 model considers only compression‐compression while Hu 2003
considers both compression and tension. Hu presents a single smooth biaxial failure curve.
These models utilize the Traina and Yin experimental data.
To what problems can you apply these constitutive models.
Fiber concrete has been used for many years to reduce cracking of floor slabs. It is anticipated
though that fiber concrete can be used in beams and girders to reduce or minimize shear
stirrups. The analytic models can be used in computer simulation models (finite element) to
predict behavior of plain and steel fiber concrete structures without the necessity of
performing actual testing. (Although it is good practice to perform some physical testing to
calibrate the finite element model).
Use Tables to Summarize equations. (See Table 1)
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Summarize in complete and concise form the state of knowledge on the Smeared constitutive
models for concrete.
The most current and complete model for prestressed and reinforced concrete is the Softened
Membrane Model or SMM (Hsu, 2009). This is a 2‐D model which applies to membrane
elements and broadly encompasses all shear members such as walls, girder webs, particularly
deep beams.
The individual SMM constitutive equations are summarized in Table2 and illustrated in Fig. 1 for
concrete. The equations cover the following:
Concrete in Tension (pre‐cracking and post cracking branches)
Concrete in Compression (ascending and descending branches)
Equilibrium Equations
Compatibility Equations
Post‐Cracking Hsu/Zhu (Poisson) Ratios
Uniaxial – Biaxial Transformation Equations
Embedded Mild Steel
Embedded Prestressing Tendon
Constitutive Models for Concrete, Discussion:
Constitutive models for concrete are being investigated by two general groups of concrete
researchers. There are those models that have been developed by materials researchers and
there are those models developed by researchers attempting to predict the behavior of whole
structural assemblies, including reinforcing. The latter group of models is generally referred to
as smeared models. The models overlap and indeed the materials models form the basis of the
structures models. It must be clearly understood that the distinctive difference between the
two sets of research is the presence of reinforcing steel such as deformed mild steel rebar or
stressing tendon. Concrete with reinforcing steel behaves differently than concrete without
reinforcing steel.
The research at the University of Houston with respect to concrete Dr. Hsu’s constitutive
models (such as the SMM) has focused on structural assemblies of concrete and reinforcing
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steel. These assemblies are tested to determine the constitutive properties on what is called a
smeared or average basis. Smeared model properties by definition span multiple cracks in the
concrete. The smeared constitutive model is a macro or full scale model which is used to model
whole structural behavior, particularly shear behavior of reinforced concrete continuums such
as walls beam webs, and other membrane structures. Smeared constitutive models are
designed and calibrated to full‐scale structures.
The materials research models for concrete focus on the mirco level of concrete. They
generally consider concrete on the single crack level, and may even model the cracks
themselves.
The overlap of model groups occurs at the concrete‐rebar interface. Constitutive bond
researchers model the bond between concrete and reinforcing. These models form a bridge
between the materials models and the smeared model research.
Fig. 1 Smeared Constitutive Model for Concrete (Hoffman, 2009)
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To what problems can we apply these constitutive models for Concrete with Fibers?
Fiber Concrete has been used for many years to reduce cracking of floor slabs. It is anticipated
though that concrete containing steel fibers (SFC) can be used in beams and girders to reduce
or minimize shear stirrups. Phase 2 of this research is underway at U of H (Rao, 2009) to test
full scale prestressed SFC bridge girders without shear steel. The models can also be used to
predict post peak behavior of any shear dominant structure, such as low‐rise shear walls, deep
beams, etc.
The distinctive feature of the SMM is that it can predict post peak shear behavior (descending
branch behavior) because Poisson effects (Hsu‐Zhu ratios) are included in the elasticity function
that bridges between stress and strain. Post‐peak behavior of concrete structures is important
in seismic design and research where prediction of deflection and strength of damaged
structures is critical.
The solution to the constitutive, equilibrium, and compatibility equations requires an iterative
algorithm in order to generate the complete monotonic shear stress‐strain curve. The
constitutive models are ultimately be used in finite element software, such as Open Sees, to
model structural behavior concrete structures.
By testing individual macro‐elements of prestressed SFC in the Universal Element Testing
machine, one can likewise determine the constitutive laws within the SMM framework that
govern prestress SFC behavior. These laws can then be put into Open Sees to model the
behavior of complete prestressed SFC structures.
The effect of steel fibers on the Constitutive Models:
Please refer to Table 2 for a comparison and remarks regarding the effect of steel fiber on the
SMM.
The softened membrane model consists of the constitutive equations listed in the summary
table below. These equations are bound together and satisfy the necessary conditions of
compatibility and equilibrium.
The smeared constitutive laws for concrete comprise those for concrete, for mild steel, and for
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steel prestressing strand. The laws are depicted graphically in the figures below. The effects of
fiber are given with respect to the Fiber Factor which is fiber volume times fiber aspect ratio:
FF=Vf*(lf/Df)
The two constitutive laws that will be influenced the most are the post cracking Tensile Stress
curve and the embedded mild steel and embedded tendon curves. The most significant though
is the steel fiber conctete in tension curve. Regular concrete undergoes a simple smooth decay
of strength post‐cracking. Steel fiber concrete on the other hand exhibits initially higher
tension stiffening characteristics just past cracking due to the fibers “bridging” the crack with a
tensile force. However, as cracking increases, the steel fibers begin to pullout or otherwise fail.
The point where this begins to happen is roughly at the yield strain of the steel. As the fibers
fail the bridging force decreases until finally a dominant crack opens where most of the bridging
fibers failed. The bridging force is transferred to the tendon.
The influence of steel fiber on the tensile behavior of concrete is illustrated in the figure above.
The results of prestresed steel fiber concrete panels (dashed lines) are plotted concurrently
Fig. 5.2 11 relationships of panels TEF-3, 4, and 5
Cracking of the panels
Tensile Strain, 1
Tens
ile S
tres
s σ
1 , M
Pa
(ks
i)
Fig. 2
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with the results for prestressed regular concrete (solid lines). The steel fibers increase the
stiffness post‐cracking and greatly improve toughness.
How the effects of fiber are being determined:
The purpose of the current testing is to determine the effect of fiber content, specifically Fiber
Factor, on the constitutive laws of prestressed SFC. To determine this, five prestressed SFC
panels were tested under the sequential loading. The data in the two loading stages were
recorded separately. In the first stage of tensile loading, all five panels were used to obtain the
tensile constitutive laws of SFC and prestressing tendons. In the second stage compressive
loading, the softening coefficients of prestressed SFC were determined as related to the
perpendicular tensile strains, and fiber factor. In the first series of panels TEF‐1, 2, and 3, the
prestress level and fiber aspect ratio was held constant while the fiber percentage was
increased. The tensile strain targets ranged from 0.005 to 0.016. Wang (2006) showed that the
softening coefficient, , decreases with increased tensile strain, 1 , in prestressed concrete.
The SFC results were normalized with respect to tensile strain level to show the effect of
softening with respect to fiber factor.
The tensile target strains for the sequential load panels (TEF) were not designed to examine
ultimate tensile properties of the SFC. Fortunately, panel TEF‐5 was tested (inadvertently) until
tensile failure of the strand, so there is data available for this range of tensile strain for SFC.
For proportional loading, it is anticipated that the simultaneous application of compressive
force in conjunction with tensile forces will increase the pull‐out capacity of the steel fibers,
thus enhancing their performance. Yin (1989) has shown that this is the case for biaxial
compression‐compression loading and Hu (2003) prepared an analytic model for compression‐
tension loading. This factor will show up in f1(x) as a function of the compressive force or
strain.
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Table1 Constitutive Equation Comparison for Plain Concrete and Fiber Concrete
Constitutive Property
Equation for Plain Concrete Equation for Fiber Concrete Remarks
Plain Concrete, or Fiber in Uniaxial Tension
Ascending Branch, Gopal and Shah, 1985
Descending Branch, Gopal and Shah, 1985
1.01
See Table 2, Eq. 17 & 18 for constitutive equation for Fiber Concrete in tension
Eq. 1
Eq. 2
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Constitutive Property
Equation for Plain Concrete Equation for Fiber Concrete Remarks
Plain Concrete or fiber Concrete in Uniaxial Compression
Hogenstad, 1952 and Stussi, 1932
k1 ranges from 0.7 to 0.9 k2 ranges from 0.35 to 0.45 k3 ranges from 0.85 to 1.0 eu ranges from 0.003 to 0.005
See Table 2, Eq. 21, 22 for constitutive equation for Fiber Concrete in Compression.
The Hognestad/Stussi Curve is what is used today for concrete design. The curve is defined by key parameters k1, k2, and k3. It is more a method for applying an assumed stress strain distribution or gradient to a concrete bending member, as opposed to being a true model relating stress to strain.
Plain Concrete or fiber Concrete in Uniaxial Compression
Desayi, 1964 (equation for the full curve)
Desayi equation is for the full ascending and descending stress strain curve. The descending branch inflection point is not well captured. Eq. 3
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Constitutive Property
Equation for Plain Concrete Equation for Fiber Concrete Remarks
Plain Concrete or fiber Concrete in Uniaxial Compression
Wang 1978 (equation for the full curve)
The Wang equation is for the full ascending and descending stress strain curve. This equation does a better job at capturing the descending branch inflection point than the Desayi equation.
Plain Concrete or fiber Concrete in Biaxial Compression
Gerstle, 1981
Hu 2003
where,
And kappa values are material constants determined from a experimental test curve for any specific fiber concrete …
Hu utilizes a single smooth biaxial failure curve. Requires test data points. Model is solved iterativly.
Eq. 4
Eq. 5
Eq. 6
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Constitutive Property
Equation for Plain Concrete Equation for Fiber Concrete Remarks
Plain Concrete or fiber Concrete in Biaxial Compression
Chen, 1994
Tan, 1994 Biaxial stress‐strain curve is given by
where,
,
,
, and
, finally,
where nu1, nu0, l, r’ , Vf and tau are
properties of the fibers with the concrete matrix.
Tan equations do not require test points, unlike Hu.
Eq. 7 Eq. 8
Eq. 9
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Constitutive Property
Equation for Plain Concrete Equation for Fiber Concrete Remarks
Tan 1994 further defines the failure envelope by:
where,
and,
Eq. 10
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Constitutive Property
Equation for Plain Concrete Equation for Fiber Concrete Remarks
Plain Concrete or fiber Concrete in Triaxial Compression
Warkne 1975
where:
Eq. 11
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Table 2 Softened Membrane Model (SMM) Smeared Constitutive Equation Comparison for Concrete and Steel Fiber Concrete
Constitutive Property
SMM Equation for Reinforced Concrete (RC), including prestressed Proposed SMM Equation for Steel Fiber Concrete (SFC), including prestressed Remarks
Concrete, or SFC in Tension
For SFC, there is a tension stiffening effect that occurs during Stage T2. After the reinforcing steel yields, there begins a softening region when the fibers bridging the cracks begin to pull out. This effect was not modeled by Mansour (2005) for sequential loading. Korb (2006) attempted to model this behavior from the results of his proportional load panel tests, but the cause was not realized and the equation used is awkward. Thus stage T2 is modified and Stage T3 is added to account for fiber failure across the crack bridge. Stage T3 will tend to zero as strain increases. Equations proposed by Mansour (2005) account for increases ductility and stiffness of the SFC, but do not tend to zero with increasing strain. Functions f1(F) and F2(F) are functions of the Fiber Factor, F = (Lf/Df)Vf Proper understanding of SFC in tension is crucial to being able to properly model it and predict experimental curves with analytic functions.
‐1
‐0.8
‐0.6
‐0.4
‐0.2
0
0.2
0.4
‐0.005 0 0.005 0.01 0.015 0.02
Concrete Stress (MPa)
Concrete Strain (mm/mm)
TEF‐3, Concrete Stress vs Strain (ksi)
Experimental Results, 1.5% Steel Fibers
Existing Theory (No Fibers)
Stage UC
Stage T1
StageT2 Stage T3
Eq. 12
Eq. 13
Eq. 14
Eq. 16
Eq. 17
Eq. 18
Eq. 15
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Constitutive Property
SMM Equation for Reinforced Concrete (RC), including prestressed Proposed SMM Equation for Steel Fiber Concrete (SFC), including prestressed Remarks
Concrete or SFC in Compression
Softening for RC:
.
Softening for presteressed SFC:
9.01 pc WffffFf , where
FFf 2.01
SFC will effect the descending branch of the SFC in compression curve, stage C2. Function f2(F) will be used to adjust the shape of the parabolic curve to fit the experimental data. Additionally, the experimental data shows that increasing the fiber factor, increases the softening coefficient (increases the peak compressive concrete stress). The softening factor will thus influence the shape of both Stage C1 and C2 of the SFC in compression curve.
Eq. 20
Eq. 19
Eq. 22
Eq. 21
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Constitutive Property
SMM Equation for Reinforced Concrete (RC), including prestressed Proposed SMM Equation for Steel Fiber Concrete (SFC), including prestressed Remarks
Mild Steel
))(293.0( 5 FfByn
Steel Fibers have two effects on embedded steel. First it lowers the apparent yield stress and second, it stiffens the post yield behavior, which for the bare bar is typically perfectly plastic. The factors F5(F) and F6(F) are used to adjust the apparent yield of steel and post‐yield slope. These factors are obtained from the experimental results.
Embedded Prestressing Strand
The prestressing tendon embedded in SFC displays stiffer post yield modulus than concrete without steel fiber. As such, function f4(F) will be used to adjust the post yield stiffness and will be fitted from the experimental results of the sequential load tests. Because of the shape of the knee of the tendon stress strain curve, the yield stress is not a well defined point as it is with mild steel. As such the apparent yield stress for tendon embedded in SFC should not require modification to the 0.7fpu apparent yield value currently being used for tendon embedded in regular concrete.
Equilibrium
Same as RC
Eq. 23
Eq. 25
Eq. 24
Eq. 27
Eq. 28
Eq. 26
Eq. 30
Eq. 29
Eq. 31
Eq. 32
Eq. 35
Eq. 34
Eq. 33
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Constitutive Property
SMM Equation for Reinforced Concrete (RC), including prestressed Proposed SMM Equation for Steel Fiber Concrete (SFC), including prestressed Remarks
Compatibility
Same as RC
Poisson (Hsu‐Zhu)
The Hsu‐Zhu ratios are presumed to be the same as RC, however, literature review for tests on un‐reinforced SFC (“plain” SFC) indicates that SFC tends to be increase confinement and this could influence (reduce) the Poisson ratio of plain SFC. However, panel cracking (reinforced concrete and reinforced SFC) is usually so extensive at the target tensile strains (usually 1% or more) that that the effect may not be significant.
For SFC, this could have effect on peak and post‐peak shear behavior. If experimental peak shear strains are difficult to correlate with the analytic model, then the Hsu‐Zhu relation may need refinement.
Uniaxial‐biaxial transformation 2
2112
121
21121 11
1
,
22112
12112
212 1
1
1
,
2221
22
122
2 cossin22
sincos
,
2221
22
122
2 cossin22
cossin
t .
The uniaxial‐biaxial strain relationships are the same as for RC Note that the stress and strains in the compatibility and equilibrium equations are biaxial. The key to a relatively simple solution algorithm is this straight‐forward transformation between uniaxial and biaxial strain.
Eq. 37
Eq. 38
Eq. 36
Eq. 41
Eq. 40
Eq. 39
Eq. 45
Eq. 44
Eq. 43
Eq. 42
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Concrete Mixtures with Nanoparticles
What are the types of nanoparticles used in concrete?
Although there are many types of nanoparticles that can be added to concrete, research has
generally focuses on three types of particles (Chung, 2004, Hui 2007, Gao 2009):
a) Nanosilica (SiO2)
b) Nanotitaniates (TiO2)
c) Nanocarbon fibers
Nanosilicates are spherical particles of SiO2 with a diameter on the order of 10‐9 m. Nanosilcates
are popular because they are readily available as they are a byproduct of the extraction of
metallic silica and alumina from electric arc furnaces.
Nano carbon fibers are extremely short length of carbon fiber with diameters on the order of
10‐9 m and aspect ratios ranging from (L/d) of 50 – 200.
Properties of nanoparticle concrete that are being studied include:
a) Increased Compressive strength
b) Improved Tensile toughness, strength, and fatigue behavior
c) Reduced Creep
d) Electrical resistivity, particularly for nanaocarbon fibers.
What factors must be considered in designing concrete mixtures with nanoparticles?
Factors to be considered in designing mixes include:
a) Dispersion due to high specific surface electrical charge
b) Effect of dispersants on the concrete mix
c) Influence of flocking or aggregation of nanoparticles and formation of inclusions or
weak pockets
d) Increase in density affects strength and creep for nanosilcate.
e) Increase in water demand vs. strength and workability (see discussion item 3)
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Dispersion:
To minimize aggregation of nanoparticles in the cement matrix where inclusions or weakness
could form, nanoparticle concrete additives must be thoroughly dispersed thoroughly and
uniformly dispersed throughout the cement paste during mixing.
Dispersants and special multi‐step mixing techniques and sequences are required for mixing
nanoparticles and fibers in concrete due to their high specific surface energy. High speed pre‐
mixing of small batches of nanoparticles or fibers in special “blenders” helps with dispersion, as
does the use of chemical surfactants, such as liquid soap and superplasticizers. Sonication is
another method to disperse nanoparticles. Soncation is the use of sound or ultrasound energy
to agitate and mix the nanoparticles by breaking the inter‐particle attraction. The un‐clumped
particles are then free to disperse within the water and ultimately the concrete paste.
Jo (2007), for example, used a 5 step procedure for mixing a 50 cubic inch batch of nanosilicate
concrete:
1) Mix nanoparticles with water at high speed for 1 minute (120 rpm)
2) Cement was added and mixed at medium speed (80 rpm) for 30 seconds
3) Sand was then added, gradually, at medium speed
4) Superplasticizer was added and stirred at high speed for 30 seconds
5) The mixture was allowed to rest for 90 seconds, then mixed for an additional minute at
high speed.
Creep:
A more creep resistant concrete (long term) is desirable; however, current concrete design
codes would need to be extended for applications where creep resistant concrete is used. Long
term creep influences residual steel forces in prestressed and post tensioned concrete
structures significantly. Serviceability considerations would be improved. Particular attention,
for example, would need to be paid to ACI sect. 18.4. For example, section 18.4.2 limits on
stress for structures with relatively high sustained service loadings could be increased for
structures using low creep concrete.
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What are the mechanisms that will explain the modified behavior of nanoparticle concrete?
Mechanisms that explain nanoparticle behavior, particularly silicates, revolve around the
increased homogeneity of Ca(OH)2 crystal growth during hydration. Hydrate products
crystallize around a nanoparticle “kernel” during hydration. If the appropriate content of
nanoparticles with respect to hydrate products is incorporated in the mix, the hydrate crystal
growth will tend to be controlled and the resulting product will be more homogeneous. This
homogeneity makes the cement matrix more compact and thus improves density and reduces
porosity. This denser, more uniform matrix helps explain the improved flexural and fatigue
properties found by researchers (Li 2002).
The hardness of the hydrated Ca(OH)2 crystals has been studied by Ulm (2009) in order to
determine how creep behavior is influenced. The controlled growth crystals are denser and
thus exhibit better creep performance. Because of the more uniform crystal growth around the
nano‐kernel, pores typically filled with water are now filled with these nanocrystals. The more
densely packed crystals inhibit C‐S‐H movement over time, thus reducing the movement
associated with creep.
Nanosilcia increased the water demand of the cement past. When the mix is designed with the
appropriate amount of water and super plasticizer, this increased hydration or pozzolanic
reaction of the nanosilica extender is the mechanism that improves the compressive strength.
Designing a mix using nanosilcia requires careful attention to water content. Due to the specific
surface area of the SiO2 nanoparticles the pozolanic reaction is more effective and efficient
than with larger particles of the same material. Higher nano SiO2 content must be
accompanied by adjustments to the water content and super plasticizer (Jo 2007). The higher
hydration of the nanoparticles required additional water to avoid desiccation, however too
much water reduced strength. The right balance of water and superplasticizer is required when
designing nanosilcia mixes.
The mechanism by which carbon nanofibers operate to improve the flexural toughness and
tensile characteristics of concrete (Chen 1992) are very much different from the chemical
interaction behavior of nanosilicate particles. The individual fibers act to hold the mortar
matrix together longer by bridging microcracks. Nanocarbon fibers bond to some extent to the
cement, but improved chemical bonding can be achieved by treating the fibers with ozone gas.
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This increases the surface oxygen concentration on the nanocarbon fibers and increases
wetability and thus the degree of fiber dispersion (Chung, 2003).
What are the important factors that have to be considered for the constitutive models for
nanoconcrete materials?
Factors to consider when developing constitutive models of nanoconcrete include the
modification of the compressive stress strain curve. Tests at U of H on carbon fiber
nanoconcrete specimens (Gao, 2009), for example, indicate increased ductility in compression
when compared to regular high strength concretes. These tests were performed with carbon
nanofiber contents ranging from 1% to 2.5% by volume.
The smeared tensile stress strain curve also needs to be developed for nanoconcretes due to its
increased toughness over normal concrete (Zhou, 2010).
The modification to the existing set of constitutive equations for normal concrete (eg., the
Softened Membrane Model framework) would likely be straightforward. It would require
materials test to determine the constitutive laws, but the general structure of each constitutive
equation and solution method would generally be the same.
How will you develop a constitutive model for these concrete materials?
To develop constitutive models, uniaxial compression tests must be performed to determine
the nanoconcrete’s stress strain curve (Gao, 2009). Specifically, strength, peak and maximum
strains, ductility and in particular the shape of the descending branch of the stress strain curve
need to be determined. This would be the un‐softened characteristic stress strain curve of the
nanoconcrete. To determine how tensile strain influences the peak compressive performance,
the softening factors would need to be determined from tests in the Universal Element Testing
Machine in the TC Hsu Structural Lab (Zhou, 2010).
Since nanoparticles improve fatigue and flexural strength, additional testing needs to be done
to develop the tensile properties of the material. The post‐cracking smeared stress strain curve
needs to be determined. Since tensile ductility is enhanced, the shape and area under of the
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smeared tensile strain curve will differ from that of regular concrete (larger area under the
curve). In order to determine this smeared curve, one will need to test specimens reinforced
with rebar and loaded in uniaxial tension. Tensile load would be applied to rebar embedded in
and projecting from the ends of prismatic nanoconcrete specimens. Foil strain gages should be
applied at intervals along the length of the rebar to better determine the constitutive curve for
the embedded rebar.
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Constitutive Model References:
Belarbi, A. and Hsu, T. T. C. (1994), “Constitutive Laws of Concrete in Tension and Reinforcing Bars Stiffened by
Concrete,” Structural Journal of the American Concrete Institute, Vol. 91, No. 4, pp. 465‐474.
Belarbi, A. and Hsu, T. T. C. (1995), “Constitutive Laws of Softened Concrete in Biaxial Tension‐Compression,”
Structural Journal of the American Concrete Institute, Vol. 92, No. 5, pp. 562‐573.
Chen, W.F. Constitutive Equations for Engineering Materials, Vol. 1: Elasticity and Modelling, Elsevier Publications, 1994.
Collins, M. P., Vecchio, F. J., and Mehlhorn, G. (1985), “An International Competition to Predict the Response of
Reinforced Concrete Panels,” Canadian Journal of Civil Engineering, Ottawa, Vol. 12, No. 3, pp. 626‐644.
Desayi, P. and Krishnan, S., Equation for the stress‐strain curve of concrete, ACI J., Vol. 61(1964)345‐350. Dhonde, H.B., Mo, Y.L., and Hsu, T.C. (2006), “Fiber Reinforcement in Prestressed Concrete Beams”, Texas
Department of Transportation Report 0‐4819, March 2006.
Gerstle, K.H. Simple formulation of biaxial concrete behaviour, ACI Journal, 78(1981)62‐68.
Gopalaratnam, Shah, Softening Response of Plain Concrete in Direct Tension, ACI Journal, May‐June 1985.
Hoffman (2009), Constitutive Properties of Steel Fiber Concrete, Proceedings of the October 2009 ASCE Texas
Section Fall Meeting, Houston, TX.
Hognestad, Fundamental Concepts in Ultimate Load Design, Journal of the American concrete Institute, V 23, June
1952.
Hsu, T. T. C. (1993), Unified Theory of Reinforced Concrete, CRC Press, Inc., Boca Raton, FL, 336 pp.
Hsu, T.T.C. (2009), Unified Theory of Reinforced Concrete, 2nd. edition, CRC Press, Inc. Boca Raton, FL.
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Hsu, T. T. C. and Zhang, L. X. (1996), “Tension Stiffening in Reinforced Concrete Membrane Elements,” Structural
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Fibers.” Research Report, Department of Civil and Environmental Engineering, University of Houston,
Houston, TX.
Pang, X. B. and Hsu, T. T. C. (1995), “Behavior of Reinforced Concrete Membrane Elements in Shear,” Structural
Journal of the American Concrete Institute, Vol. 92, No. 6, pp. 665‐679.
Rao (2009), Shear Properties of Steel Fiber Concrete Girders, Proceedings of the October 2009 ASCE Texas Section
Fall Meeting, Houston, TX.
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and Composites, Vol. 16, 1994
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Thomas, Ramaswamy, Mechanical Properties of Steel Fibre Reinforced Concrete, ASCE Journal of Materials in Civil
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Triana, Mansour, Biaxial Strength and Deformational Behavior of Plain and Steel Fiber Concrete, ACI Material
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Wang, J., Laskar, A., Mo, Y.L., Hsu, TC (2006), “Rational Shear Provisions for AASHTO LRFD Specifications”, Texas
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Zhu, R. R. H., and Hsu, T. T. C. (2002), “Poisson Effect of Reinforced Concrete Membrane Elements,” Structural
Journal of the American Concrete Institute, Vol. 99, No. 5, pp. 631‐640.
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Nanoparticle References
Chung, D.D.L., Cement‐Matrix Structural Nanocomposites, Metals and Materials International, Vol. 10, No. 1, 2004 Gao, Di, Electrical Resistance of Carbon‐nanofiber concrete, Smart Structures and Materials, Vol 18, 2009 Hui‐gang, Xiao , Mechanical and sensing properties of structural materials with nanophase materials, Pacific
Science Review, vol. 5, 2003 Jo, Byung‐Wan, Characteristics of cement mortar with nano‐SiO2 particles, Construction and Building Materials 21,
2007 Li, Gengying, Properties of high‐volume fly ash concrete incorporating nano‐SiO2, Cement and Concrete Research
34, 2004 Li, Hui, Abrasion resistance of concrete containing nano‐particles for pavement, Wear 260, 2006 Li, Hui, Flexural fatigue performance of concrete containing nano‐particles for pavement, International Journal of
Fatigue 29, 2007 Shebl, S.S., Mechanical behavior of activated nano silicate filled cement binders, Journal of Material Science, Vol.
44, 2009
Ulm, Franz‐Josef, Proceedings of the National Academy of Sciences, June 15, 2009
Zhou, Junming, Seismic Performance of framed Shear Walls with Carbon Nano fiber Concrete, Preceedings of the American Society of Civil Engineers Earth and Space Conference, Honolulu, HA, 2010