vol. 3, no.2, pp 870-891, april-june 2011 solubility...
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International Journal of ChemTech Research CODEN( USA): IJCRGG ISSN : 0974-4290
Vol. 3, No.2, pp 870-891, April-June 2011
Solubility-Temperature Correlation Constantsfor Binary Systems
Byron Smith R J1* and PL Sabarathinam2
Department of Technology, Annamalai University,Tamil Nadu – 608 002, India
Corres. Author: [email protected] ,[email protected]
Phone: +91 416 2202537,Fax: +91 416 2243092
Abstract: The solubility data is widely used in the separation and formulation process industry whereby the relativesolubility can aid in the separation of the compounds. With the product based approach in pharmaceutical sectorinvolving solubilities, a ready reference to calculate the solubility would be of much help. Hence this paper reports thetemperature dependency of solubility of common compounds in water, ethanol and methanol using the characteristicconstants of two equations.Key words: binary systems, solubility data, correlation constants.
1. IntroductionThe solubility data are a pre requisite in operationsinvolving a solute and a solvent which is normallyencountered in many separation operations and in theformulation industry (Drugs and pharmaceuticals andcosmetics). Collection of this data for the compoundsinvolved forms the basic step in design of thesesystems. Even though experimental data are the mostpreferred data for use, estimated values often forms thepreliminary set of data used. The extensive solubilitydata compilation by [1] can be used to find thesolubility at different temperatures. Some of the othersources of this information are IUPAC-NISTSolubility Data Series, [2] and [3]. But to get thevalues at interpolated temperatures, having an equationwill be of much help. Hence in this work, theexperimental binary salt solubility data are subjected todata fitting to identify the equations that better fit theexperimental data with least deviation and thecorresponding correlation constants are reported forcommonly used binary systems.
2. CorrelationThe experimental solubility data reported in Stephenand Stephen (1963) at different temperatures werestored in separate data files. A computer program was
developed for 10 different forms of correlations andthe data files were run through these 10 correlationsand the correlation that gave the least deviation wasselected for each liquid. It was found that a largenumber of systems fitted well with the following twocorrelations,S = A - B/(C+T) - (1)S = A + B*T + C* T2 - (2)
The characteristic correlation constants A, B and C foreach system were calculated by the least squaremethod using a C programme developed for thisapplication. The correlation constants for the binarysystems are presented in Table1. The averagepercentage deviation (APD) was calculated using theformula…APD = 1/n ∑│(Nexpt. – Ncorrel.) / Nexpt.│* 100 --- (3)
The average percentage deviations for the correlatedvalues from those of the calculated values are alsoprovided in Table 1. The water solubility of PotassiumIodide offered the least deviation (0.052 %) and themaximum deviation (6.889 %) is obtained for CalciumTartrate. Figure 1 is plot of experimental vs correlatedvalues of Solubility at various temperatures forPotassium Iodide – Water system. Examples are,
Byron Smith R J et al /Int.J. ChemTech Res.2011,3(2) 871
Example 1System: Potassium Iodide - WaterTemperature: 250CCharacteristic constants from Table 1: A = 89.558; B= 6649.039; C=198.628: Equation 1Solubility Calculated = 59.826 mass%Solubility Experimental (Stephen and Stephen, 1963) = 59.800 mass%Percentage deviation = 0.043%
Example 2System: Barium Sulfide – WaterTemperature: 400CCharacteristic constants from Table 1: A =3.548; B=0.172; C=0.0005: Equation 2Solubility Calculated = 11.246 mass%Solubility Experimental (Stephen and Stephen, 1963) = 10.5 mass%Percentage deviation = 7.111%
0
10
20
30
40
50
60
70
80
0 20 40 60 80 100 120
Temperature (0C)
Solu
bilit
y (m
ass%
)
S calS exptl
Figure 1 Temperature solubility plot for Potassium Iodide – Water system
0
5
10
15
20
25
30
0 20 40 60 80 100
Temperature (0C)
Solu
bilit
y (m
ass%
)
S calS exptl
Figure 2 Temperature Solubility plot for Barium Sulfide – Water system
Byron Smith R J et al /Int.J. ChemTech Res.2011,3(2) Table 1: Pages 872 to 890
Table 1: Solubility - Temperature Correlation Constants
Eqn 1: Solubility S = A – B/(C + T), Eqn 2: S = A + BT + CT2
where T is the Temperature in 0C. The units of Solubility are in mass %. The units if provided in g/l or mol % are expressed along with thecompound name.
Correlation ConstantsCompound Name
Eqn. Molar
Mass(g/mol) T
Min
0 C
TM
ax0 C
A B CAPD
Solubility in WaterAcetanilide 1 135.1652 0 70 -5.280000E-01 8.344599E+01 -9.565900E+01 2.041Acetic Acid 1 60.0524 20 100 -6.100000E-02 8.333558E+00 -1.091710E+02 3.227Aluminium Chloride 2 133.3405 -55 100 3.027100E+01 6.548400E-02 -4.160000E-04 0.490Aluminium Nitrate 2 212.9962 10 80 3.455600E+01 1.675140E-01 1.124000E-03 0.375Ammonium AluminiumSulfate 1 474.2700 0 95 -2.594200E+01 4.252736E+03 -1.494430E+02 4.092Ammonium Bromide 1 97.9423 -17 170 1.299260E+02 2.979911E+04 3.224720E+02 0.298Ammonium BromideCadmium Bromide 2 370.1503 1 110 5.414300E+01 2.284340E-01 -2.730000E-04 0.4984(Ammonium Bromide)Cadmium Bromide 2 663.9772 1 160 7.213200E+01 7.539300E-02 1.050000E-04 0.510Ammonium Chloride 1 53.4913 -15 115 3.569130E+02 5.036145E+05 1.507260E+03 0.257Ammonium ChlorideCadmium Chloride 1 236.7973 3 105 1.874110E+02 9.910113E+04 6.270720E+02 0.2104(Ammonium Chloride)Cadmium Chloride 2 397.2712 4 113 3.017700E+01 3.395910E-01 -6.790000E-04 0.798
Ammonium Chromate 1 152.0702 0 75 -1.693000E+02 1.372394E+05 -7.249190E+02 0.162Ammonium Cobalt (II)Sulfate 1 287.1250 0 80 -9.853700E+01 4.043373E+04 -3.875330E+02 0.825Ammonium Di Chromate 2 252.0644 0 100 1.527600E+01 5.860220E-01 -1.287000E-03 0.888Ammonium DiHydrogenOrtho Arsenate 2 158.9733 0 90 2.571600E+01 3.317930E-01 -6.900000E-05 0.598Ammonium DiHydrogenOrtho Phosphate 1 115.0254 0 110 -1.339530E+03 4.239871E+06 -3.122080E+03 0.121Ammonium Dithionate 1 196.1930 0 30 7.567500E+01 9.160816E+02 4.911610E+01 0.033Ammonium Formate 2 63.056 -20 80 5.041700E+01 4.342900E-01 -1.770000E-04 0.325Ammonium FormateHydrogen Formate 1 109.0816 -6 39 1.196230E+02 1.890986E+03 5.486490E+01 0.382Ammonium Hexa BromoStannate (II) 2 670.2672 2 91 3.671300E+01 4.684260E-01 -3.500000E-05 0.663Ammonium Hexa ChloroIridate 1 441.0146 15 69 -3.230000E-01 8.405994E+01 -9.656150E+01 1.126Ammonium Hexa ChloroPlatinate 1 443.8846 0 100 -1.375000E+00 2.532666E+02 -1.538370E+02 4.555Ammonium Hexa chloroStannate (II) 1 403.5612 1 81 -1.164300E+01 5.885537E+03 -1.590350E+02 1.989Ammonium HydrogenCarbonate 1 79.0554 -4 108 3.149600E+01 -5.162810E-01 2.475000E-03 3.448Ammonium HydrogenOtho Phosphate 1 132.0558 0 70 6.196900E+01 1.260945E+03 3.946220E+01 1.690Ammonium HydrogenTartarate 2 167.1182 0 25 1.044000E+00 7.685000E-02 2.480000E-04 1.828Ammonium HydroxySuccinate 1 151.1188 -4 25 -2.981600E+01 5.338689E+03 -1.214710E+02 0.327Ammonium Iodide 1 144.9428 -28 140 1.062560E+02 1.436383E+04 3.137400E+02 0.271Ammonium Iron (II)Sulfate 1 284.0388 0 70 1.633680E+02 5.951673E+04 3.905600E+02 0.773
Ammonium Lead Sulfate 2 435.3918 20 100 1.060800E+01 8.962100E-02 3.370000E-04 1.686Ammonium Meta Vanadate 1 116.9779 15 96 -2.885300E+01 4.234191E+03 -1.398650E+02 6.348Ammonium Nickel (II)Sulfate 1 286.8918 0 70 7.177500E+01 1.755198E+04 2.475420E+02 3.169Ammonium Nitrate 2 80.0432 0 100 5.492800E+01 5.993280E-01 -2.597000E-03 1.110Ammonium Penta Borate 1 400.1670 0 60 -1.255900E+01 2.138343E+03 -1.295390E+02 1.053Ammonium Perchlorate 2 117.4889 -3 84 1.082700E+01 3.572980E-01 2.490000E-04 0.680Ammonium Tartarate 2 184.1486 -7 60 3.163900E+01 3.971120E-01 -2.532000E-03 0.540Ammonium Tetra BromoStannate (II) 2 474.3826 0 80 2.628400E+01 8.734190E-01 -2.785000E-03 3.279Ammonium Tetra ChloroStannate (II) 2 296.5786 2 97 2.749700E+01 5.845310E-01 -3.200000E-05 1.132Ammonium Thio Cynate 1 76.1160 13 71 3.064910E+02 1.470786E+05 5.826900E+02 0.051Ammonium TriBromoStannate (II) 1 376.4403 0 74 -2.181900E+01 5.622837E+03 -1.272350E+02 4.773Ammonium TrichloroStannate (II) 1 243.0873 2 81 1.808870E+02 3.259665E+04 2.615350E+02 0.209Ammonium Zinc Sulfate 2 293.5718 0 80 6.587000E+00 2.129260E-01 9.520000E-04 0.971Arsenic TriOxide 1 197.8414 0 98 -6.117000E+00 1.502061E+03 -2.075360E+02 2.442Barium Azide 1 221.3802 0 17 1.696900E+01 6.505588E+01 1.096780E+01 0.761Barium Bromate 1 393.1444 0 99 -3.210000E+00 5.715989E+02 -1.657500E+02 5.420Barium Bromide 2 297.148 0 100 4.953800E+01 7.432300E-02 3.010000E-04 0.173Barium Cacodylate 2 411.3196 0 99 4.313300E+01 5.607580E-01 -1.801000E-03 2.698barium Chlorate 1 304.2424 0 105 1.456090E+02 6.524653E+04 2.734580E+02 0.281Barium Chloride 1 208.2460 0 60 1.144860E+02 5.649979E+04 6.212060E+02 0.147Barium ChlorideCadmium Chloride 2 391.552 23 109 3.854500E+01 1.702870E-01 6.960000E-04 0.741Barium Chlorite 1 272.2436 0 100 2.565100E+01 6.158975E+02 -1.296800E+02 1.731Barium diHydro diSulfide 1 203.4758 -15 100 2.781600E+01 6.460227E+02 -1.393140E+02 0.707
Barium Fluoride (g/l) 1 175.3368 10 30 1.635000E+00 1.112097E+00 1.994160E+01 0.363Barium Formate 1 227.3754 0 100 -1.915300E+01 1.623271E+04 -4.054500E+02 0.330Barium Hydroxide 1 171.3560 0 80 -7.308000E+00 8.174122E+02 -9.361130E+01 3.726Barium Iodate 1 487.1454 0 100 -8.800000E-02 1.463308E+01 -1.517800E+02 2.806Barium Malonate 1 239.3864 0 80 4.150000E-01 1.161942E+01 4.098890E+01 3.499Barium Methyl Phosphate 2 247.3461 10 100 2.777000E+00 -4.651800E-02 2.270000E-04 6.107Barium Nitrate 1 261.3498 0 100 -1.008500E+02 6.215763E+04 -5.892980E+02 1.284Barium PerChlorate 1 336.2412 0 140 8.900800E+01 8.621742E+03 3.263830E+02 0.342Barium Sulfide 2 169.4 0 100 3.549000E+00 1.729800E-01 4.870000E-04 6.565Boracic Acid 1 361.8319 0 120 -1.380800E+01 2.619987E+03 -1.599160E+02 1.793Bromine 1 159.8080 0 30 2.294000E+00 -1.743776E+01 1.302300E+01 1.3413-Bromo-6-AminoBenzene Sulfonic Acid 1 252.0823 0 85 -8.410000E-01 1.414335E+02 -1.341760E+02 1.791Cadmium BenzeneSulfonate (g/l) 2 418.6642 18 80 2.108020E+02 3.570538E+00 2.887700E-02 2.366Cadmium Napthalene 2Sulfonate 1 526.8470 17 82 -8.950000E-01 1.397470E+02 -1.020480E+02 5.967Cadmium Sulfate 2 208.4576 119 187 9.145900E+01 -5.567310E-01 4.920000E-04 2.495Calcium 2 EthylButanoate 2 270.3834 0 70 2.324200E+01 -1.617200E-01 8.480000E-04 0.150Calcium 2 PropylPentanoate 1 326.4906 0 80 -3.293800E+01 -1.616575E+04 3.878050E+02 0.205Calcium 4- OxoPentanoate 1 270.2970 0 55 1.887000E+00 3.307008E+03 -1.283570E+02 0.553Calcium Bromide 2 199.888 -22 105 5.568400E+01 2.966590E-01 -8.610000E-04 2.489Calcium Carbonate (g/l) 2 100.0892 0 50 7.700000E-02 -6.930000E-04 -3.000000E-06 3.572Calcium Cinnamate 1 334.3862 2 100 -3.580000E-04 2.227932E+01 -1.195330E+02 0.665Calcium Formate 2 130.1154 0 100 1.401200E+01 1.265800E-02 2.700000E-05 0.269Calcium Gluconate 1 430.3774 20 96 -6.612000E+00 9.867030E+02 -1.192470E+02 4.703
Calcium Glutamate 2 201.194 0 100 1.295000E+00 3.652400E-02 7.900000E-05 3.303Calcium Hexa CyanoFerrate (II) 2 292.1132 -10 64 3.228100E+01 1.883690E-01 8.700000E-05 0.759Calcium Hydroxide 2 74.0946 0 70 1.910000E-01 -9.670000E-04 -4.000000E-06 1.719Calcium Iodide 2 293.889 0 100 6.475000E+01 1.359200E-01 2.980000E-04 0.227Calcium Malonate 1 142.1264 0 80 5.810000E-01 1.297153E+01 4.334120E+01 1.569Calcium Methyl Malonate 2 156.1532 10 80 5.640000E-01 -1.924000E-03 -1.800000E-05 2.857Calcium Nitrate 1 164.0898 -28 50 2.683500E+01 1.860443E+03 -8.849390E+01 1.250Calcium Succinate 2 156.1532 10 80 1.346000E+00 -4.670000E-03 -4.800000E-05 3.387Calcium Sulfate 1 136.1376 20 100 -2.170000E-01 -5.014369E+01 7.631500E+01 1.706Calcium Tartrate (g/l) 1 188.1520 0 85 -6.410000E-01 1.283502E+02 -1.300320E+02 6.889Carbon di Oxide 1 44.0098 0 60 -7.100000E-02 -1.135626E+01 2.772100E+01 0.596Carbon di Sulfide 1 76.1310 0 49 2.550000E-01 -3.208268E+00 -6.224900E+01 0.892Cerium (III) AmmoniumNitrate 2 486.2211 9 65 6.804000E+01 2.286020E-01 1.432000E-03 0.354Cerium (IV) AmmoniumNitrate 1 548.2260 25 112 5.171600E+01 9.897198E+02 -1.377410E+02 2.331Cerium Butanoate 1 401.4143 11 76 -2.400000E-02 -2.972230E+02 7.200260E+01 0.263Cesium Chloride 1 168.3584 0 119 9.273900E+01 5.455719E+03 1.765570E+02 0.102Cesium Hexa ChloroPlatinate 1 673.6188 0 100 -1.139000E+00 4.986581E+02 -4.292350E+02 0.719Cesium Hexa FluoGermanate (IV) 1 452.3912 0 30 2.940000E-01 2.132188E+01 -4.018740E+01 4.759Cesium Nitrate 2 194.9103 0 106 7.033000E+00 6.728630E-01 -7.490000E-04 4.080Cesium Oxalate HydrogenOrtho Tellurate 1 583.4742 0 50 -1.250900E+01 2.085216E+03 -1.110640E+02 2.513Cesium Sulfate 1 361.8684 0 108 8.900800E+01 8.621742E+03 3.263830E+02 0.023Chlorine 1 70.9060 0 100 -2.010000E-01 -4.366836E+01 2.752570E+01 5.597Chromium PerChlorate 2 350.3478 0 25 5.112400E+01 -5.139000E-03 -5.139000E-03 0.502
Chromium Tri Oxide 2 99.9942 0 100 6.179400E+01 3.253900E-01 1.400000E-04 0.302Cineole 2 154.2516 2 50 6.660000E-01 1.270000E-04 1.270000E-04 5.135Cobalt Benzene Sulfonate(g/l) 1 373.2606 17 80 -1.295970E+02 2.654448E+04 -1.470690E+02 1.417Cobalt Bromide 2 218.7412 0 100 4.650100E+01 -2.464000E-03 -2.464000E-03 2.238Cobalt Chloride 2 129.8392 0 100 2.844600E+01 -1.918000E-03 -1.918000E-03 2.990Cobalt Iodide 2 312.7422 -10 110 5.829600E+01 -2.343000E-03 -2.343000E-03 1.905Cobalt Napthalene 2Sulfonate 1 473.3802 20 82 -5.615000E+00 7.359135E+02 -1.161210E+02 2.064Cobalt Nitrate 2 182.943 50 30 4.487500E+01 4.118000E-03 4.118000E-03 0.214Cobalt Nitrite 1 150.9442 0 40 -1.913000E+00 2.898867E+02 -1.453070E+02 2.385Cobalt Rubidium Sulfate 1 421.9840 0 100 -6.757900E+01 2.156121E+04 -2.983980E+02 1.328Copper (II) AmmoniumSulfate 1 291.7378 0 100 -8.645000E+01 3.191660E+04 -3.305720E+02 0.461Copper (II) BenzeneSulfonate 2 377.8734 18 80 2.354420E+02 4.623417E+00 8.199000E-03 1.286Copper (II) Bromide 1 223.3540 0 50 5.897700E+01 1.499193E+02 2.147290E+01 0.590Copper (II) Chloride 2 134.452 25 112 4.121800E+01 9.021100E-02 4.280000E-04 0.149Copper (II) Napthalene 2Sulfonate (g/l) 1 477.9930 20 84 -2.130000E+01 2.685025E+03 -1.051110E+02 2.549Copper (II) Sulfate 2 159.6036 -1 110 1.197500E+01 2.379070E-01 7.130000E-04 1.891Creatinine Picrate 1 342.2244 8 92 -4.840000E-01 7.053438E+01 -1.257860E+02 3.854d-Glutamic Acid HydroChloride (g/l) 1 183.5913 0 100 -7.870350E+02 3.520651E+05 -3.203190E+02 0.543Ethyl Acetate 2 88.106 15 50 9.413000E+00 7.540000E-04 7.540000E-04 0.187Ethyl Malonic Acid (g/l) 1 132.1150 0 30 4.206050E+02 4.495394E+03 -3.915200E+01 2.528Ethylene diNitrate (g/l) 1 152.0634 15 50 1.342400E+01 3.552632E+02 3.396900E+01 0.900Gadolinium Sulfate 2 602.6728 0 34 3.843000E+00 -8.979500E-02 1.216000E-03 1.9224-Heptanoate 1 14.1870 0 75 1.880000E-01 -9.288346E+00 1.735900E+01 0.770
Hydrazonium Nitrate 1 95.0578 10 60 1.510950E+02 7.662868E+03 7.767850E+01 0.177Hydrazonium Sulfate 2 162.1634 25 60 5.457100E+01 4.886910E-01 6.050000E-04 1.145Hydrogen Bromide 2 80.9119 -15 100 6.937000E+01 -2.700000E-05 -2.700000E-05 0.793Iron (II) Nitrite 1 179.8568 -27 60 9.101000E+00 4.596220E+03 -1.459010E+02 1.068Lanthanum Bromate 2 522.6121 0 35 4.965500E+01 4.346390E-01 4.019000E-03 0.284Lanthanum Sulfate 2 565.9838 0 100 2.927000E+00 -3.683500E-02 1.430000E-04 2.348Lead Acetate 1 325.2890 0 50 -5.877200E+01 9.110432E+03 -1.214730E+02 0.946Lead Bromide (g/l) 1 367.0080 0 100 -4.318500E+01 1.010715E+04 -2.136750E+02 3.230Lead Chloride 1 278.1060 15 100 -6.322000E+00 2.562364E+03 -3.709310E+02 1.889Lead Chloro Fluoride 1 261.6514 0 100 -1.570000E-01 5.434134E+01 -3.049560E+02 0.254Lead Hexa Fluo Silicate 2 349.2764 0 100 6.495400E+01 2.795250E-01 -9.820000E-04 1.411Lead Iodide 1 461.0090 0 100 -2.402000E+00 4.758585E+02 -1.710320E+02 5.388Lead Nitrate 1 331.2098 0 100 1.227340E+02 2.103681E+04 2.204940E+02 0.163Lithium Bromate 2 134.8432 5 100 6.008000E+01 2.563120E-01 -7.530000E-04 0.627Lithium Bromide 2 86.8450 -72 100 5.886900E+01 2.151090E-01 -7.250000E-04 1.816Lithium carbonate 2 73.8912 0 100 1.496000E+00 -8.815000E-03 9.000000E-06 0.564Lithium Chloride 2 42.3940 0 160 4.139800E+01 1.729730E-01 -3.600000E-04 1.076Lithium d- Tartrate 2 161.9540 0 30 2.954300E+01 -6.651790E-01 1.279000E-02 0.367Lithium Formate 2 51.9587 -20 120 2.431700E+01 2.782280E-01 3.060000E-04 4.860Lithium HydrogenPhosphite 1 93.8618 0 98 -4.210000E+00 -2.305147E+03 1.732460E+02 0.841Lithium Hydroxide 1 23.9483 0 100 7.278000E+00 5.180568E+02 -1.572530E+02 0.720Lithium Iodide 2 133.8455 0 120 5.849600E+01 1.473480E-01 7.460000E-04 2.647Lithium Meta Phosphate 1 85.9129 0 40 3.100000E-02 -9.313750E-01 1.301700E+01 2.131Lithium Molybdate 2 166.8786 0 98 4.522900E+01 -3.410500E-02 6.300000E-05 0.308Lithium Nitrate 2 68.9459 0 70 2.980800E+01 9.787950E-01 -6.619000E-03 5.673Lithium Sel;enite 2 140.8402 0 100 1.996000E+01 -1.287330E-01 1.940000E-04 0.824Lithium Sulfate 2 109.9396 -16 103 2.660500E+01 -4.171200E-02 1.250000E-04 0.217
Lithium Tetra ChloroAurate (III) 1 345.7195 10 80 6.309140E+02 6.768827E+05 1.161020E+03 0.161Lithium Thio Cynate 2 65.0187 20 40 4.876900E+01 1.533960E-01 3.546000E-03 0.354Magnesium BenzeneSulfate (g/l) 1 338.6324 17 82 -2.047050E+02 4.352194E+04 -1.735380E+02 1.808Magnesium Cerium Nitrate 1 1259.579 11 111 2.972200E+01 6.094913E+03 -1.979930E+02 0.503Magnesium Chlorate 2 191.2074 -18 93 5.443300E+01 2.187080E-01 3.000000E-06 1.699Magnesium Chloride 2(Cadmium Chloride) 1 461.8130 3 121 1.117890E+02 1.838589E+04 2.742670E+02 0.599Magnesium Cinnamate 1 318.6112 15 100 2.729000E+00 1.152492E+02 4.575920E+01 1.533Magnesium DiThionate 2 184.4214 0 30 3.200200E+01 9.058800E-02 5.420000E-04 0.260Magnesium Formate 1 114.3404 0 100 7.339000E+00 7.761656E+02 -1.617720E+02 1.266Magnesium Iodide 1 278.1140 0 215 6.891000E+01 3.903999E+02 2.404970E+01 1.532Magnesium LanthanumNitrate 1 1094.7850 19 113 2.746500E+01 6.254286E+03 -1.994440E+02 0.486Magnesium Napthalene 2Sulfonate (g/l) 1 438.7520 17 82 -5.537000E+00 7.341335E+02 -1.136220E+02 3.091magnesium NeodymiumNitrate 1 1537.8186 0 109 2.792600E+01 6.769136E+03 -2.033760E+02 0.939Magnesium Selenate 1 167.2626 -7 60 4.764200E+01 1.154983E+03 3.727660E+01 2.184Malonic Acid 1 104.0622 0 30 5.275850E+02 3.482398E+03 -3.857400E+01 2.131Manganese Bromide 2 214.746 -20 100 5.609600E+01 -4.640000E-04 -4.640000E-04 0.559Melamine 1 126.1206 20 99 -2.026000E+00 2.738602E+02 -1.381570E+02 3.779Mercury (II) Cyanide 1 252.6254 108 209 1.467980E+02 2.212433E+04 8.951790E+01 1.064Methyl d- Glocoside 2 194.184 18 78 4.607700E+01 1.739000E-03 1.739000E-03 0.293Methyl Malonic Acid (g/l) 1 118.0890 0 30 2.940930E+02 6.381254E+03 -4.022200E+01 3.523Methyl Propanoate (mol%) 1 88.1060 -2 42 1.106000E+00 -1.376699E+01 1.833500E+01 0.494N4-Acetyl Sulfa Pyridine 1 291.3240 20 99 -4.300000E-02 4.723341E+00 -1.184350E+02 1.9731-Napthylamine-2-Sulfonic Acid 1 223.2460 0 100 -7.500000E-01 1.314689E+02 -1.334310E+02 2.122
1-Napthylamine-4-Sulfonic Acid 1 223.2460 0 100 -3.200000E-02 6.900676E+00 -1.249750E+02 5.8652-Napthol 1 144.1726 7 75 -1.550000E-01 1.724228E+01 -9.866600E+01 4.228Neodymium Bromate 1 527.9466 0 45 1.842020E+02 3.398945E+04 2.211210E+02 0.282Neodymium Chloride 2 250.599 10 55 4.891800E+01 2.577800E-02 2.600000E-04 0.064Nickel Benzene Sulfonate(g/l) 1 373.0274 18 82 -3.224230E+02 8.830439E+04 -2.150730E+02 0.359Nickel Bromide 2 218.508 -20 140 5.287200E+01 -9.380000E-04 -9.380000E-04 0.959Nickel Chlorate 2 225.6024 -18 79 5.345000E+01 8.000000E-06 8.000000E-06 1.449Nickel Iodide 2 312.509 -20 90 5.621200E+01 -1.229000E-03 -1.229000E-03 0.700Nickel Napthalene 2Sulfonate 1 473.1470 17 83 -7.671000E+00 1.022697E+03 -1.132210E+02 2.231Nitro Amino Guanidine 1 119.0828 10 50 -5.800000E-01 5.276843E+01 -8.207700E+01 1.449Nitro Glycerine 1 227.0872 15 80 -1.250000E-01 1.485203E+02 -1.207180E+02 1.672Nitro Guanidine 1 104.0682 30 100 -2.802000E+00 3.184884E+02 -1.301120E+02 4.949Ortho Phosphoric Acid 2 97.995 -81 42 8.134100E+01 3.861130E-01 1.945000E-03 2.755Oxalic Acid 2 90.0354 15 25 4.034000E+00 4.460000E-03 4.460000E-03 1.197Potassium Acetate 2 98.1425 0 96 6.817600E+01 2.362130E-01 -1.174000E-03 0.508Potassium Azide 1 81.1181 -12 354 5.287390E+02 1.071145E+06 2.144310E+03 0.200Potassium Benzoate 2 160.2133 18 50 3.951600E+01 8.543400E-02 1.173000E-03 0.430Potassium Bromate 1 167.0020 5 50 -2.051200E+01 3.434285E+03 -1.472890E+02 0.449Potassium Bromide 1 119.0020 -12 100 7.723100E+01 6.800658E+03 1.608770E+02 0.189Potassium BromideCadmium Bromide 1 391.2100 -9 100 1.117660E+02 8.997561E+03 1.550820E+02 0.206Potassium Carbonate 2 138.2052 -11 70 5.123700E+01 8.706300E-02 1.300000E-04 0.329Potassium Chloride 1 74.5510 -10 454 1.477840E+02 1.061556E+05 8.441040E+02 2.314Potassium ChlorideCadmium Chloride 1 257.8570 -4 100 1.441930E+02 3.955685E+04 3.209650E+02 0.4374(Potassium Chloride) 2 481.51 19 54 2.566200E+01 1.767580E-01 2.204000E-03 1.059
Cadmium ChloridePotassium Chromate 2 194.1896 0 100 3.798500E+01 5.797200E-02 1.350000E-04 0.306Potassium Citrate 2 306.3953 15 30 5.943300E+01 1.159640E-01 3.440000E-03 0.097Potassium Cobalt (II)Sulfate 2 329.2444 0 80 8.256000E+00 2.262080E-01 8.610000E-04 1.896Potassium Copper (II)Sulfate 1 333.8572 0 40 -1.679000E+01 2.625489E+03 -1.214830E+02 0.418Potassium Dithionate 1 238.3124 0 30 -8.286000E+00 8.960062E+02 -8.279430E+01 2.108Potassium Formate 1 84.1157 -20 157 2.919000E+01 2.012395E+04 -4.407100E+02 0.096Potassium FormateHydrogen Formate 2 130.1413 0 80 6.057600E+01 3.592980E-01 2.230000E-04 0.154Potassium Hexa ChloroPlatinate (II) 1 486.0040 0 100 -3.558000E+00 8.308113E+02 -1.965010E+02 2.514Potassium Hexa CyanoFerrate (II) 1 329.2472 0 99 2.435120E+02 5.458868E+04 2.561620E+02 0.748Potassium Hexa CyanoFerrate (III) 1 368.3452 15 25 3.869700E+01 6.816615E+02 2.059520E+01 0.880Potassium Hexa FluoGermanate (g/l) 1 264.7764 0 40 -4.213000E+00 5.368142E+02 -7.903440E+01 2.321Potassium Hexa FluoSilicate (g/l) 2 220.2724 0 88 8.470000E-01 3.659700E-02 1.360000E-04 4.946Potassium HydrogenCarbonate 1 100.1151 0 70 -1.868560E+02 1.314462E+05 -6.403330E+02 0.314Potassium HydrogenSulfate 2 136.1635 0 100 2.749800E+01 2.408330E-01 3.450000E-04 0.764Potassium Hydroxide 2 56.1053 0 100 4.920300E+01 2.332230E-01 -8.030000E-04 1.289Potassium Iodate 2 214.0007 0 100 4.402000E+00 1.497300E-01 5.230000E-04 0.827Potassium Iodide 1 166.0025 0 100 8.955800E+01 6.649039E+03 1.986280E+02 0.052Potassium Iron (II) Sulfate 2 326.1582 0 70 1.653900E+01 4.256420E-01 -1.584000E-03 1.877Potassium MagnesiumSulfate 2 294.6162 0 75 1.250200E+01 3.880750E-01 -7.090000E-04 0.717
Potassium Nickel (II)Sulfate 2 437.1024 0 70 5.866000E+00 2.816070E-01 9.010000E-04 2.131Potassium Nitrate 2 101.1029 0 114 1.061500E+01 7.527590E-01 -1.426000E-03 2.580Potassium Nitrite 2 85.1035 0 98 7.405900E+01 6.193000E-02 1.800000E-05 0.270Potassium OrthoPhosphate 2 212.2653 8 45 4.182100E+01 2.705080E-01 2.344000E-03 1.094Potassium OxalateHydrogen Ortho Tellurate 1 395.8594 0 50 -7.945000E+00 1.205829E+03 -1.137500E+02 1.566Potassium Penta Borate 1 442.2864 0 102 -1.161500E+01 2.081559E+03 -1.606800E+02 5.394Potassium Permanganate 1 158.0336 0 65 -2.030200E+01 3.406071E+03 -1.486710E+02 1.838Potassium Selenate 2 221.1536 -20 100 5.208600E+01 3.416200E-02 2.300000E-05 0.303Potassium Sulfate 1 174.2536 0 170 4.833600E+01 9.496510E+03 2.280340E+02 0.615Potassium Tetra ChloroAurate (II) 2 377.8765 10 60 1.783100E+01 1.006974E+00 6.150000E-04 0.353Potassium Tetra CyanoPlatinate (II) 2 377.3568 0 95 6.060000E+00 1.150153E+00 -5.245000E-03 5.386Potassium Thio Sulfate 1 190.3142 0 90 9.092700E+01 2.304733E+03 5.555320E+01 0.816Potassium TriChloroStannate (II) 2 264.147 4 71 2.372200E+01 7.827780E-01 6.150000E-04 0.345Potassium Zinc Sulfate 2 443.7824 0 17 1.156900E+01 4.408320E-01 9.620000E-04 0.748Praseodymium Borate 2 524.6143 0 45 3.630600E+01 5.741940E+03 -9.300000E-05 0.334PreseodymiumManganese Nitrate 1 1623.0530 15 111 3.194800E+01 5.507968E+03 -1.919350E+02 0.382Preseodymium Nitrate 1 326.9224 16 56 5.496000E+01 2.374397E+02 -6.735390E+02 0.587Propyl Formate (mol%) 1 88.1060 -1 45 4.640000E-01 -4.484473E+00 1.575500E+01 0.512Propylene 1 42.0804 0 20 2.600000E-02 -3.874840E-01 6.065000E+00 3.8123- Pyridine Carboxylic Acid 1 123.1110 0 100 -4.368000E+00 8.174481E+02 -1.576300E+02 2.169Pyro Phosphoric Acid 2 177.9749 -75 61 8.256600E+01 2.837710E-01 -3.170000E-04 1.416Rubidium Bromate 2 213.37 25 40 1.185000E+00 4.389100E-02 1.122000E-03 2.282Rubidium Bromide 1 165.3718 1 113 9.081200E+01 5.839163E+03 1.336700E+02 0.613
Rubidium BromideCadmium Bromide 1 437.5798 1 107 1.299870E+02 1.310743E+04 1.342550E+02 0.0044(Rubidium Bromide)Cadmium Bromide 1 933.6952 1 114 9.979700E+01 3.933292E+03 7.511680E+01 0.233Rubidium ChlorideCadmium Chloride 1 304.2268 1 103 -2.965500E+02 3.226519E+05 -1.043670E+03 0.5634(Rubidium Chloride)Cadmium Chloride 2 666.9892 1 108 2.137200E+01 3.846970E-01 -3.630000E-04 0.877Rubidium Nitrate 2 147.4727 0 118 1.569400E+01 1.094944E+00 -4.266000E-03 1.794Rubidium Oxalate.Hydrogen Ortho Tellurate 1 488.5990 0 50 -1.056900E+01 1.664286E+03 -1.163970E+02 0.796Rubidium Sulfate 1 266.9932 0 102 6.649100E+01 4.707389E+03 1.192410E+02 0.257Rubidium Tetra ChloroAurate (III) 2 424.2463 10 100 1.007000E+00 4.035570E-01 3.110000E-04 1.725Silver 2 Ethyl Butanoate 2 223.0197 0 30 4.120000E-01 1.021000E-03 9.000000E-06 2.103Silver 2,2 DimethylPropanoate 2 208.9929 0 80 1.095000E+00 6.075000E-03 2.600000E-05 1.686Silver Acetate (g/l) 1 166.9125 0 80 -2.177800E+01 6.078629E+03 -2.093890E+02 0.305Silver Bromate 1 235.7702 25 90 -5.870000E-01 8.811105E+01 -1.373620E+02 2.050Silver Butanoate 1 194.9661 0 80 -2.880000E-01 9.922047E+01 -1.504840E+02 4.185Silver Chlorite 1 175.3198 0 100 -2.120000E+00 5.077720E+02 -2.196820E+02 4.863Silver Chlorite AllylThioUrea (g/l) 1 252.4463 15 50 -3.700000E-02 3.858480E+00 -5.778860E+01 1.001Silver Nitrate 1 169.8729 0 35 1.132580E+02 3.661110E+03 6.161520E+01 0.195Silver Nitrite (g/l) 1 153.8735 0 60 -6.889000E+00 8.270607E+02 -9.977230E+01 3.379Silver Perchlorate 2 207.3186 0 35 8.200200E+01 9.191100E-02 8.140000E-04 0.089Silver Propanoate 1 180.9393 0 80 -2.894700E+01 9.151874E+03 -2.658470E+02 1.849Silver Sulfate 2 311.7936 0 100 7.060000E-01 5.804000E-03 1.400000E-05 4.790Sodium 3-PyridineCarboxylate 1 145.0928 0 100 7.174300E+01 3.765321E+03 6.066380E+01 3.375
Sodium AluminiumSulfate 2 484.173 10 30 2.561200E+01 1.119080E-01 2.715000E-03 0.133Sodium BenzeneSulfonate 1 180.1534 3 120 9.847900E+01 1.097970E+04 1.334020E+02 0.775Sodium Bromate 1 150.8919 5 100 1.263590E+02 3.005675E+04 2.814220E+02 0.145Sodium Chlorate 2 106.4409 -15 122 4.508300E+01 2.686860E-01 -2.470000E-04 0.852Sodium Chloride 1 58.4427 0 180 2.343900E+01 7.483884E+02 -2.684430E+02 0.521Sodium Chromate 1 161.9731 0 100 6.179700E+01 6.359076E+02 1.453040E+01 3.821Sodium Dichromate 2 261.9673 0 98 6.131900E+01 1.754410E-01 4.210000E-04 0.967Sodium Dihydrogen HypoPhosphate 1 205.9392 25 50 -2.949000E+00 2.907516E+02 -8.388880E+01 0.935Sodium DihydrogenOrtho Phosphate 2 119.9769 0 83 3.556900E+01 6.420160E-01 -2.758000E-03 1.566Sodium Dithionate 2 206.0995 1 100 6.108000E+00 3.505260E-01 -1.730000E-04 2.380Sodium Fluoride 1 41.9881 0 100 6.726000E+00 4.615485E+02 1.435280E+02 0.201Sodium Formate 2 68.0074 -20 123 3.508800E+01 5.189610E-01 -2.348000E-03 5.252Sodium Hexa ChloroIridate (IV) 2 450.9175 15 85 1.878000E+00 1.454393E+00 -6.844000E-03 3.734Sodium Hexa CyanoFerrate (II) 1 303.9123 1 79 -9.361100E+01 3.869708E+04 -3.730540E+02 1.003Sodium Hexa FluoGermanate (IV) (g/l) 2 264.7764 0 80 1.444700E+01 3.555090E-01 -1.410000E-03 4.941Sodium Hexa FluoSilicate (g/l) 2 188.0559 0 100 4.368000E+00 1.327140E-01 6.430000E-04 3.441Sodium Hexa HydroxoStannate (g/l) 1 266.7133 0 120 -9.454500E+01 -1.093275E+05 1.775950E+02 0.877Sodium HydrogenCarbonate 1 84.0068 0 60 -2.897500E+01 1.232045E+04 -3.467090E+02 0.941Sodium Hydrogen HypoPhosphate 1 227.9211 25 50 -5.169000E+00 5.070089E+02 -7.763070E+01 0.930Sodium Hydrogen 2 125.9595 0 43 7.841800E+01 1.722950E-01 3.404000E-03 2.265
PhosphiteSodium Hydrogen SeleniteDihydrogen Selenite 2 279.9298 -7 83 4.124500E+01 5.309710E-01 -3.230000E-04 0.938Sodium HydrogenSuccinate 2 140.0708 0 75 1.734000E+01 6.375360E-01 -3.394000E-03 6.277Sodium Hypo Phosphate 1 249.9030 25 50 -6.050000E-01 1.177479E+02 -8.168280E+01 0.680Sodium Iodate 2 197.8924 0 100 2.484000E+00 2.402950E-01 -1.340000E-04 0.856Sodium Iodide 2 149.8942 0 100 6.065200E+01 2.217510E-01 -6.520000E-04 1.456Sodium Meta Vanadate 2 121.9294 25 75 1.441300E+01 1.142340E-01 9.210000E-04 1.369Sodium Molybdate 1 205.9171 0 100 4.708900E+01 2.571901E+02 1.532060E+01 2.543Sodium Napthalene 1Sulfonate 1 230.2132 2 90 -6.500000E-02 1.305860E+01 -1.209870E+02 1.476Sodium Nitrate 2 84.9946 0 313 4.235700E+01 2.249180E-01 -1.200000E-04 1.189Sodium Ortho Phosphate 2 163.9406 0 75 4.034000E+00 2.989100E-01 1.590000E-04 3.052Sodium Oxalate 2 133.9991 0 100 2.779000E+00 2.625800E-02 7.800000E-05 1.714Sodium Oxide Chromate 1 223.9521 0 37 2.695500E+01 4.268074E+02 -6.006110E+01 0.555Sodium p- HydroxyBenzene Sulfonate 1 196.1518 0 60 -5.859000E+01 1.674469E+04 -2.480540E+02 0.512Sodium p- NitroPhenoxide 2 161.0923 50 224 2.284000E+00 1.011060E-01 2.145000E-03 1.663Sodium p- TolueneSulfonate 1 194.1802 0 60 5.177600E+01 5.570254E+02 1.646580E+01 0.523Sodium p-Amino BenzeneSulfonate 1 195.1680 0 60 -1.573070E+02 8.195476E+04 -4.839960E+02 0.285Sodium p-Chloro BenzeneSulfonate 1 214.5986 0 60 -1.972600E+01 4.595830E+03 -1.568020E+02 0.240Sodium Perchlorate 2 122.4403 0 143 6.308500E+01 2.229090E-01 -1.340000E-04 3.163Sodium Pyro Selenite 2 204.9365 -9 109 4.044300E+01 7.579040E-01 -4.035000E-03 3.361Sodium Pyro Sulfite 1 190.0965 -9 97 5.396600E+01 7.896289E+02 3.429300E+01 2.689Sodium Succinate 2 162.0527 0 72 1.722000E+01 3.226410E-01 1.401000E-03 2.178
Sodium Sulfathiazole 1 385.3820 0 37 -3.092800E+01 3.192339E+03 -7.945100E+01 4.566Sodium Sulfide 2 78.0395 -10 90 1.112700E+01 2.521690E-01 3.550000E-04 3.268Sodium Sulfite 2 126.0377 33 67 3.008300E+01 -9.923300E-02 -6.100000E-05 0.189Sodium Tetra ChloroAurate (III) 1 361.7682 10 60 4.129500E+01 1.265544E+03 -8.558170E+01 0.532Sodium Tetra DecaneSulfonate 1 316.4304 25 33 -2.392000E+00 2.902735E+01 -3.578150E+01 4.260Sodium Tetra FluoBeryllate (II) 2 130.9853 0 100 1.331000E+00 1.209900E-02 3.100000E-05 3.244Sodium Tetrachromate 2 461.9557 0 22 7.277300E+01 8.992400E-02 1.657000E-03 0.474Sodium Thio Cyanate 1 81.0674 11 101 7.270100E+01 5.047111E+02 1.389720E+01 1.254Sodium Trichromate 2 361.9615 0 99 7.984500E+01 4.696700E-02 1.260000E-04 0.155Sodium Tungstate 2 293.8271 -3 100 4.134400E+01 6.191100E-02 1.780000E-04 0.814Sparteine (g/l) 1 228.3364 11 50 1.095000E+00 -3.632848E+01 -3.081000E+00 6.319Strontium Benzoate 2 329.8506 16 409 5.208000E+00 6.955000E-03 1.440000E-04 0.708Strontium Bromide 2 247.428 0 100 4.619600E+01 2.197160E-01 1.010000E-04 0.214Strontium Cacodylate 2 361.5996 0 99 4.334500E+01 6.405320E-01 -3.483000E-03 2.003Strontium Chloride 1 158.5260 20 200 8.201200E+01 6.577694E+03 1.162660E+02 1.231Strontium Dithionate 1 247.7364 0 30 -2.762900E+01 3.945611E+03 -1.227370E+02 0.130Strontium Formate 2 177.6554 0 100 7.680000E+00 2.155640E-01 -2.270000E-04 4.586Strontium Iodide 2 314.429 0 175 6.095500E+01 1.786050E-01 -1.760000E-04 2.035Strontium Malate 2 219.6926 20 70 -4.051000E+00 3.152220E-01 3.469000E-03 6.151Strontium Malonate (g/l) 2 189.6664 0 50 5.552000E+00 -1.345000E-02 -1.950000E-04 1.262Strontium Nitrate 1 211.6298 1 88 5.210600E+01 2.263357E+02 7.402010E+00 3.021Strontium Tartrate (g/l) 1 289.7376 0 85 -7.275000E+00 1.612959E+03 -1.935140E+02 1.772Strontium ThioSulfate 2 199.7382 0 40 8.735000E+00 3.968460E-01 1.457000E-03 1.009Sulfur di Oxide 1 64.0588 8 50 -3.222000E+00 -5.545450E+02 2.354200E+01 0.464Thallium AluminiumSulfate 1 846.9334 0 16 -8.133000E+00 9.737233E+02 -8.784620E+01 2.660
Tin (II) Iodide 1 372.4990 20 100 -2.793000E+00 6.560329E+02 -1.952520E+02 1.635TriChloro Ethylene 1 131.3889 -38 22 -1.500000E-02 1.495592E+00 -5.749000E+01 1.785Yttrium Bromide 2 328.6179 0 95 3.943900E+01 1.650040E-01 1.660000E-04 1.073Yttrium Chloride 2 195.2649 0 50 4.362600E+01 2.020100E-02 1.630000E-04 0.051Yttrium Nitrate 1 274.9206 0 66 9.760500E+01 4.990981E+03 1.010390E+02 0.094Yttrium Sulfate 2 465.9846 4 95 7.715000E+00 -4.568000E-02 -1.660000E-04 3.496Zinc Benzene Sulfonate (g/l) 1 379.7074 10 82 -9.440900E+01 3.282275E+04 -1.462490E+02 1.990Zinc Chlorate 2 232.2824 -18 55 5.963500E+01 2.674990E-01 1.650000E-04 1.570Zinc Formate 1 155.4154 0 100 -5.722000E+00 1.230539E+03 -1.352750E+02 3.279Zinc Iodide 2 319.189 -10 100 8.085800E+01 2.429600E-02 3.100000E-05 0.132Zinc Napthalene 2Sulfonate 1 479.8270 20 82 -6.457000E+00 9.543356E+02 -1.068700E+02 4.298Solubility in Ethanol3-Pyridine Carboxylic Acid 1 123.111 0 78 -2.730000E+00 3.785745E+02 -1.164070E+02 4.150Ammonia 2 17.0304 0 30 2.158300E+01 -6.930760E-01 9.417000E-03 3.933Ammonium Thio Cyanate 1 76.116 19 64 -5.300000E-02 2.651384E+03 -1.564770E+02 0.271Barium Bromide 2 297.148 0 70 5.675000E+00 -9.891600E-02 4.840000E-04 3.756Barium Iodide 2 391.149 0 70 4.370300E+01 -9.877000E-03 -2.700000E-05 0.024Calcium Bromide 2 199.888 0 85 3.047500E+01 1.728400E-01 9.690000E-04 2.194Calcium Chloride 2 110.986 0 97 1.581200E+01 2.400450E-01 5.170000E-04 1.370Calcium Nitrate 2 164.0898 10 80 2.878500E+01 2.688550E-01 -2.110000E-04 1.504Cobalt (II) Bromide 2 218.7412 10 80 3.826600E+01 2.946840E-01 -7.030000E-04 0.933Copper (II) Chloride 2 134.452 0 60 2.988900E+01 1.479150E-01 7.270000E-04 0.287Iron (III) Chloride 2 162.206 0 50 5.725800E+01 7.320600E-02 8.890000E-04 0.619Magnesium Sulfate 1 120.3626 15 55 7.000000E-03 -6.071070E-01 1.779430E+01 3.022Mercury (II) Bromide 1 360.398 0 70 1.612200E+01 5.471754E+02 -1.024630E+02 1.601Mercury (II) Chloride 2 271.496 -30 20 2.621700E+01 2.776430E-01 3.500000E-05 5.758Mercury (II) Cyanide 2 252.6254 0 40 8.371000E+00 3.983600E-02 2.240000E-04 0.303
Sodium Terafluo Borate 1 109.7933 0 60 -4.450000E-01 8.650890E+01 -1.193950E+02 0.914Sodium Thio Cyanate 1 81.0674 16 52 1.366900E+01 1.363519E+02 -9.206600E+01 0.251Strontium Bromide 2 247.428 10 80 3.719000E+01 1.351860E-01 -7.020000E-04 1.617Sulfur Nitride (g/l) 2 184.2668 0 40 6.970000E-01 1.628000E-02 6.300000E-04 3.111Urea Phosphate 1 158.0504 10 46 -8.051000E+00 1.071702E+03 -7.560500E+01 0.541Solubility in MethanolAmmonia 2 17.0304 0 30 2.918700E+01 -5.018080E-01 -1.440000E-04 0.322Ammonium Thio Cyanate 2 76.116 25 64 3.066600E+01 2.016500E-01 2.567000E-03 0.230Barium Bromide 2 297.148 0 60 3.067800E+01 -6.040200E-02 2.320000E-04 0.119Barium Nitrate 2 261.3498 0 60 6.700000E-02 -4.360000E-04 -1.000000E-06 3.060Cadmium Chloride 1 208.246 20 50 -1.082000E+00 2.372931E+02 -9.434400E+01 0.536Cadmium Iodide 2 366.209 0 50 6.712400E+01 8.005800E-02 5.190000E-04 0.103Cadmium Sulfate 1 208.476 15 55 6.000000E-03 -9.030980E-01 1.143300E+01 2.580Calcium Bromide 1 199.888 0 65 1.886100E+01 1.635034E+03 -1.135710E+02 1.204Calcium Chloride 2 110.986 0 215 2.108400E+01 1.472490E-01 1.070000E-04 5.706Calcium Iodide 2 293.889 0 60 5.391800E+01 7.546500E-02 3.910000E-04 0.306Calcium Lactate 2 218.2214 15 69 5.750000E-01 6.874550E-01 -1.574000E-03 1.277Cobalt (II) Bromide 2 218.7412 20 80 -7.900000E-02 1.710667E+00 -1.126900E-02 4.054Copper (II) Chloride 2 134.452 0 60 3.597700E+01 4.647200E-02 3.090000E-04 0.287Copper (II) Sulfate 1 159.6036 15 45 -1.156200E+01 2.486701E+03 -2.167400E+02 0.764d-Mannitol (mol%) 1 182.173 47 80 -9.100000E-02 8.871065E+00 -9.935680E+01 1.905Magnesium Sulfate 1 120.3626 15 55 -3.100000E-02 -1.277978E+01 2.579700E+01 2.027Mercury (II) Bromide 1 360.398 10 60 5.122800E+01 4.108570E+02 1.541400E+01 0.836Mercury (II) Chloride 2 271.496 -10 150 2.198000E+01 8.155770E-01 -3.038000E-03 6.549Mercury (II) Cyanide 2 252.6254 1 44 2.619400E+01 2.617310E-01 -1.910000E-03 0.694Nickel Bromide 2 218.508 10 70 2.316900E+01 1.340600E-01 1.010000E-03 0.849Nickel Sulfate 1 154.7576 15 55 -7.100000E-02 9.527590E+00 -8.732400E+01 1.019Potassium Bromide 2 119.002 0 60 1.827000E+00 1.019100E-02 5.800000E-05 0.993
APD Average Percentage Deviation, For correlation constants A, B and C, the term E±00 is taken as 10±00. For example9.543356E+02 has to be read as 9.543356*1002. The Compounds are given in alphabetical order.
Potassium Chloride (mol%) 2 74.551 20 50 1.004000E+00 -5.567000E-03 -1.130000E-04 3.581Potassium Fluoride 2 58.0964 20 55 2.240000E-01 -1.248000E-03 -1.800000E-05 4.194Sodium Chloride 2 58.4428 20 50 7.950000E-01 -1.031000E-03 -1.600000E-05 0.264Sodium Fluoride 1 41.9881 20 55 5.580000E-01 7.805213E+00 3.963300E+01 1.603Sodium Sulfate 2 142.0371 20 50 5.000000E-03 -2.000000E-06 0.000000E+00 1.928Sodium Thio Cyanate 1 81.0674 16 52 5.788700E+01 3.064412E+03 7.991700E+01 0.251Strontium Bromide 2 247.428 10 70 5.306500E+01 5.138300E-02 4.390000E-04 0.360Thallium Picrate 1 432.4677 0 65 -9.340000E-01 1.618204E+02 -1.231920E+02 1.614Trinitro TrimethyleneTriamine 1 222.117 0 64 -2.720000E-01 3.481689E+01 -8.652400E+01 4.477Urea Phosphate 2 158.0504 10 46 2.084200E+01 4.171250E-01 6.148000E-03 0.506
Byron Smith R J et al /Int.J. ChemTech Res.2011,3(2) 891
3. ConclusionWithin the given temperature range, Table 1 providesthe correlation constants for easy calculation ofsolubility of common substances in water, ethanol andmethanol systems. The average percentage deviationsare also provided for each system. The results of thiswork can save considerable time in calculating thesolubility of binary systems in the formulation andseparation industry.
References1) Stephen H and Stephen T, Solubility of
Inorganic and Organic Compounds – BinarySystems 1 (Part 1 and 2); (Pergamon Press,1963)
2) Robert H. Perry and Don W. Green editors,Perry’s Chemical Engineers Handbook,Eighth Edition, (Mc Graw Hill BookCompany, 2008)
3) Seidell A, Solubilities of Inorganic andOrganic Compounds; A Compilation ofQuantitative Solubility Data From thePeriodical Literature, (Nabu Press, 2010).
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NomenclatureA,B,C - characteristic correlation constantsAPD - Average Percentage Deviationn -Number of data pointsNExpt -Prandtl numberNcorrel. -Correlated Prandtl numbert - Temperature, 0C