wastewater nutrient recovery using anaerobic membrane

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HYDROPONIC FERTIGATION WITH ANAEROBIC MEMBRANE BIOREACTOR (ANMBR) PERMEATE -A TOOL FOR WASTEWATER NUTRIENT RECOVERY Jorge Calabria, George Dick, Robert Bair, Onur Ozcan Daniel Yeh, Ph.D.

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Page 1: Wastewater Nutrient Recovery Using Anaerobic Membrane

HYDROPONIC FERTIGATION WITH ANAEROBIC MEMBRANE BIOREACTOR (ANMBR) PERMEATE - A TOOL FOR WASTEWATER NUTRIENT RECOVERY

Jorge Calabria, George Dick, Robert Bair, Onur Ozcan

Daniel Yeh, Ph.D.

Page 2: Wastewater Nutrient Recovery Using Anaerobic Membrane

BACKGROUND

DECENTRALIZED TREATMENTUrbanization Site specific re-use opportunities

Reclaimed water for irrigation

NUTRIENT MANAGEMENTNitrogen cycle managementPhosphorus productionUrban Agriculture

Presenter
Presentation Notes
ammonia synthesis enabled the widespread fertilization of croplands for decades hence. As a direct result, the world's population skyrocketed from 1.6 billion to six billion during the 20th century. But Haber's nourishing discovery has a dark side he probably never imagined. The boom of fertilizer, long injudiciously applied, has come at a high price for the environment.
Page 3: Wastewater Nutrient Recovery Using Anaerobic Membrane

FOODHow will we feed 7 billion+ people?

Presenter
Presentation Notes
Phosphorous mining http://phys.org/news/2013-04-phosphorus-essential-lifeare.html
Page 4: Wastewater Nutrient Recovery Using Anaerobic Membrane

WASTEWATER AS A RESOURCE

“WASTEWATER is a RENEWABLERECOVERABLE SOURCE of POTABLE WATER, ENERGY,

and RESOURCES. “ ~ George Tchobanoglaus

Page 5: Wastewater Nutrient Recovery Using Anaerobic Membrane

ANAEROBIC MEMBRANE BIOREACTOR (ANMBR)

Anaerobic DigestionMembrane

Ultrafiltration (0.03 micron)

Outputs: Biogas

Permeate containing: Water

Nutrients0.0

100.0

200.0

300.0

400.0

500.0

600.0

700.0

800.0

0 50 100 150 200 250 300 350

Con

cent

rati

on (

mg/

l)

Day

Pilot AnMBR Permeate Nutrient Concentrations

TP

Total Nitrogen

Ammonia

Page 6: Wastewater Nutrient Recovery Using Anaerobic Membrane

HYDROPONICS GROWTH: LABORATORY TRIAL

Hydroponic grow bed:• 1 Liter of nutrient solution• (3) 3” diameter net cups with hydroton media• 6” aeration stone• Additional nutrient solution: pH adjusted

permeate (nitric acid added: pH=6.5)

Page 7: Wastewater Nutrient Recovery Using Anaerobic Membrane

Nutrient solutions: AnMBR permeate (P1)

50% Dilution of Permeate (P0.5)

pH Adjusted Permeate (P1*)

Compared to performance achieved by commercial fertilizer (C1)

Six growth performance parameters: Plant Height (PH)

Root-to-Shoot Weight Ratio (RS)

Leaf Count (LC)

Final Dry Weight (DW)

Bloom Count (BC)

0%

20%

40%

60%

80%

100%

120%RS

LC

DWBC

PH

P1 C1

HYDROPONICS GROWTH: LAB TRIAL RESULTS

Page 8: Wastewater Nutrient Recovery Using Anaerobic Membrane

Nutrient solutions: AnMBR permeate (P1)

50% Dilution of Permeate (P0.5)

pH Adjusted Permeate (P1*)

Compared to performance achieved by commercial fertilizer (C1)

Six growth performance parameters: Plant Height (PH)

Root-to-Shoot Weight Ratio (RS)

Leaf Count (LC)

Final Dry Weight (DW)

Bloom Count (BC)

0%

20%

40%

60%

80%

100%RS

LC

DWBC

PH

P0.5 C1

HYDROPONICS GROWTH: LAB TRIAL RESULTS

Page 9: Wastewater Nutrient Recovery Using Anaerobic Membrane

Nutrient solutions: AnMBR permeate (P1)

50% Dilution of Permeate (P0.5)

pH Adjusted Permeate (P1*)

Tap Water (Blank)

Compared to performance achieved by commercial fertilizer (C1)

Six growth performance parameters: Plant Height (PH)

Root-to-Shoot Weight Ratio (RS)

Leaf Count (LC)

Final Dry Weight (DW)

Bloom Count (BC)

0%

20%

40%

60%

80%

100%

120%RS

LC

DWBC

PH

C1 P1*

HYDROPONICS GROWTH: LAB TRIAL RESULTS

Page 10: Wastewater Nutrient Recovery Using Anaerobic Membrane

Nutrient solutions: AnMBR permeate (P1)

50% Dilution of Permeate (P0.5)

pH Adjusted Permeate (P1*)

Tap Water (Blank)

Compared to performance achieved by commercial fertilizer (C1)

Six growth performance parameters: Plant Height (PH)

Root-to-Shoot Weight Ratio (RS)

Leaf Count (LC)

Final Dry Weight (DW)

Bloom Count (BC)

HYDROPONICS GROWTH: LAB TRIAL RESULTS

0%

20%

40%

60%

80%

100%

120%RS

LC

DWBC

PH

C1 Blank

Page 11: Wastewater Nutrient Recovery Using Anaerobic Membrane

Normalized Composite Growth Score

HYDROPONICS GROWTH: LAB TRIAL RESULTS

0%10%20%30%40%50%60%70%80%90%

100%

C1 P1* P1 C0.5 P0.5 Blank

Page 12: Wastewater Nutrient Recovery Using Anaerobic Membrane

Deficiency Symptoms Plants grown in pure

permeate solution (NG) experienced scorching of older leaves

Potentially attributable to ammonia-induced deficiency of another nutritive cation

HYDROPONICS GROWTH: LAB TRIAL RESULTS

Page 13: Wastewater Nutrient Recovery Using Anaerobic Membrane

INTEGRATING WASTEWATER TREATMENT AND AGRICULTURE: THE B.B.R.A.T.S. MODEL

Biorecycling and Bioenergy Research and Training Station (BBRATS) at Learning Gate Community School in Lutz, FL.

Page 14: Wastewater Nutrient Recovery Using Anaerobic Membrane

CONTINUED GREENHOUSE OPERATION

November 2013

Page 15: Wastewater Nutrient Recovery Using Anaerobic Membrane

CONTINUED GREENHOUSE OPERATION

Page 16: Wastewater Nutrient Recovery Using Anaerobic Membrane

CONTINUED GREENHOUSE OPERATION

April 2014

Page 17: Wastewater Nutrient Recovery Using Anaerobic Membrane

CONCLUSIONS AnMBR permeate supported supports

hydroponic cultivation but with less than optimal performance resulting from: Lower concentrations of phosphorus

High NH4+:NO3

- Ratio

Inhibits uptake of other cations causing deficiencies of K+, Ca2+, and Mg2+

Additional permeate polishing processes could improve growth performance Promote nitrification

Increase micronutrient concentrations

Ensure safety

AnMBR Permeate Nutrient Concentrations (mg/L)

NH4 TP TN

average 173 51 189

SD 118 28 152

Page 18: Wastewater Nutrient Recovery Using Anaerobic Membrane

ACKNOWLEDGEMENTS

This material is based upon work supported by the National Science Foundation under Grant No. 1243510. Any opinions, findings, and conclusions or recommendations expressed in this material are those of the author(s) and do not necessarily reflect the views of the National Science Foundation.