Water & its treatment

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<p>Research Review Meeting</p> <p>UNIT-IIIwater and its treatment</p> <p>Water &amp; Its treatment</p> <p>1). Like air, water is one of the few basic materials which is of prime importance for the preservation of life on this earth.</p> <p>2). All are aware of the uses of water for drinking, cooking, cooking, bathing &amp; for farming etc.</p> <p>3). But few know the importance of water as an engineering matrial.</p> <p>4). As an engineering material water is used for producing steam, in boilers to generate hydro-electric power, furnishing steam for engines, for construction of concrete structures for manufacturing purposes &amp; as a solvent in chemical process.</p> <p>1UNIT: III WATER &amp; Its TreatmentSources of Water: The Main Sources Of Water Are:1). Rain water2). River water3). Spring or well water4). Sea water1). Rain water: Rain water is the purest form of natural water. However, it dissolves considerable amount of gases (CO2 SO2 - NO NO2 etc) and suspended solid particles from atmosphere, during its journey through it and becomes polluted.</p> <p>2UNIT: III WATER &amp; Its Treatment2). River water: River are formed by rain and spring waters. During its flow over the surfacee of land, it dissolves minerals of the soil such as chlorides, sulfates, bicarbonates of sodium, calcium, magnesium ions etc..</p> <p>3). Spring or well water or Lake water: it contains cosnstant chemical composition. The minerals present in the lake water in the form dissolved form and high quantity of organic matter.</p> <p>4). Sea water: It is the most impure form of natural water. It contains larger percentage of the dissolved salts (above 3.5%) out of which about 2.6% is NaCl. The NaCl which is present in the dissolved form in sea water will come out as NaCl crystals due to evaporation of sea water.The other salts present in the sea water are sulphates of sodium, bicarbonates of potassium, magnesium, calcium, bromides of potassium, magnesium etc.</p> <p>3UNIT: III WATER &amp; Its TreatmentUnderground water: Spring &amp; well waters are the underground water sources. They are in general clearer in appearance due to the filtering action of the soil.They contain more of the dissolved salts generally, underground water is of high organic purity.</p> <p>Types of impurities in water:</p> <p>The impurities present in water are classified as:</p> <p>1). Dissolved impurities: dissolved impurities may organic or inorganic. Inorganic impurities: the carbonates, bicarbonates, sulphates, chlorides of calcium, magnesium, iron potassium and aluminium.Organic impurities: Organic water products, amino acids, proteins, etc.Gases: O2 , CO2 , Oxides of nitrogen and sulphur, H2S etc. </p> <p>4UNIT: III WATER &amp; Its Treatment2). Suspended impurities: It is of two types:</p> <p>Inorganic - sand &amp; clay;Organic vegetable and animal matter.</p> <p>3) Biological Impurities: Micro-Organisms like Pathogenic bacteria, fungi, algae etc</p> <p>5UNIT: III WATER &amp; Its TreatmentDISADVANTAGES OF HARDWATER / CAUSES OF HARDNESS:</p> <p>The following are the disadvantages when hard water is used for various purpose:</p> <p>DOMESTIC USE:</p> <p>Washing and Bathing : Hard water does not form lather easily with soap is wasted</p> <p>Drinking : Hard water causes bad effects on our digestive system. Sometimes, stone formation takes place in kidneys</p> <p>Cooking : The boiling point of water is increased due to the presence of salts. Hence, more fuel and time are required for cooking.6UNIT: III WATER &amp; Its Treatment(ii) INDUSTRIAL USE:</p> <p>Textile Industry : Hard water causes wastage of soap. Precipitates of calcium and magnesium soap adhere to the fabrics and cause problem</p> <p>Paper Industry : Calcium and Magnesium salts in water may effect the quality of paper.</p> <p>Sugar Industry : Water containing sulphates, carbonates, nitrates affects the crystallisation of sugar.</p> <p>Pharmaceutical Industry : Hard water may form some undesirable products while preparation of pharmaceutical products.7UNIT: III WATER &amp; Its Treatment(iii) STEAM GENERATION IN BOILERS: For steam generation, boilers are employed. If hard water is used in boilers, It may lead to the following troubles</p> <p>Boiler Corrosion</p> <p>Scale and Sludge formation.</p> <p>Priming and Foaming</p> <p>Caustic embrittlement Pharmaceutical industry8UNIT: III WATER &amp; Its TreatmentHARDNESS OF WATER (OR) HARDWATER AND SOFT WATER:</p> <p>Hard Water : Those water which does not produce lather (or) very little lather with soap is called Hard Water</p> <p>Soft Water : Soft water readily produce a lot of lather when mixed with little soap.</p> <p>The Hardness of water is caused by the presence of dissolved salts such as Bicarbonates, Sulphates, Chlorides and Nitrates of bivalent metal ions like Ca+2 &amp; Mg+2 9UNIT: III WATER &amp; Its TreatmentSoap is sodium/potassium salt of higher fatty acids like stearic, oleic and palmetic acids.</p> <p>When soap is mixed with soft water lather is produced due to stearic acid and sodium stearate </p> <p> Na Stearate + H2O NaOH + Stearic Acid [C17H35COOH]</p> <p> Stearic Acid + Na-Stearate Formatioin of lather. 10UNIT: III WATER &amp; Its TreatmentWhen soap comes in contact with HARD WATER,Sodium stearate will react with dissolved calcium and magnesium salts and produce calcium stearate or magnesium stearate which is white precipitate</p> <p> 2Na Stearate + Ca+2 Ca Stearate + 2Na+</p> <p>[2C17H35COONa] + Ca+2 [(C17H35COO)2 Ca] + 2Na+ (Soap) (Soluble) (Insoluble) (Soluble) </p> <p> [2C17H35COONa] + Mg+2 [(C17H35COO)2 Mg] + 2Na+ (Soluble) (Soluble) (Insoluble) (Soluble) 11UNIT: III WATER &amp; Its TreatmentHardness</p> <p>Name Of Water0-70 mg/litreSoft Water</p> <p>70-150 mg/litreModerate Hard Water150-300 mg/litreHard Water</p> <p>&gt; 300 mg/litreVery Hard WaterDifferent Type Of Water have different degree of hardness. The different types of water are commercially classified on the basis of degree of hardness as follows:</p> <p>12UNIT: III WATER &amp; Its Treatment13UNIT: III WATER &amp; Its TreatmentTYPES OF HARDNESS </p> <p>The hardness of water is of two types</p> <p>Temporary hardness (or) Carbonate hardnessPermanent hardness (or) Non-Carbonate hardness</p> <p>Temporary Hardness: Temporary hardness is caused by two dissolved bicarbonate salts Ca(HCO3) and Mg(HCO3). The hardness is called Temporary Hardness</p> <p>Because it can be removed easily by means of boiling.</p> <p>Ca(HCO3)2 Heating CaCo3 + H2O + CO2 Mg(HCO3)2 Heating Mg(OH)2 + 2CO2 </p> <p>14UNIT: III WATER &amp; Its Treatment(2) PERMANENT HARDNESS: Permanent hardness of water is due to the dissolved chlorides, sulphates and nitrates of calcium and magnesium.</p> <p>These salts are CaCl2, CaSo4, Ca(NO3)2, MgCl2, MgSo4, Mg(No3)2</p> <p>These Hardness cannot be removed easily by boiling. Hence it is called Permanent Hardness. Only chemical treatment can remove this hardness.Total Hardness Of Water = Temporary Hardness + Permanent Hardness15UNIT: III WATER &amp; Its TreatmentDEGREE OF HARDNESS:</p> <p>The Concentration of hardness as well as non-hardness constituting ions are, usually expressed in the term of Equivalent amount of CaCo3</p> <p>Since this mode permits the multiplication and division concentration, when required. The choice of CaCo3 in particular is due to its molecular weight (m.wt) is 100 (Equivalent wt = 50), and moreover, It is unsoluble salt that can be precipitated in water treatment.16UNIT: III WATER &amp; Its TreatmentTherefore 100 parts by weight of CaCo3 hardness must be equivalent to1</p> <p>162 parts by weight of Ca(HCo3)2 hardness2146 parts by weight of Mg(HCo3)2 hardness3136 parts by weight of CaSo4 hardness4111 parts by weight of CaCl2 hardness5164 parts by weight of Ca(No3)2 hardness6120 parts by weight of MgSo4 hardness7146 parts by weight of MgCl2 hardness8136 parts by weight of Mg(No3)2 hardness17UNIT: III WATER &amp; Its TreatmentThe method of calculating degree of hardness will be clear from the following formula</p> <p>Hardness causing in salt in terms of CaCo3 Amount of the hardness causing salt x 100 Molecular weight of hardness causing salt</p> <p>UNITS OF HARDNESS:</p> <p>These are 4 different units in which the hardness of water is expressed as given below</p> <p>Parts per million (PPM): PPM is the number of parts of CaCo3 equivalent hardness per 106 parts of water.</p> <p> i.e., 1 PPM = 1 part of CaCo3 equivalent hardness in 106 parts of water.18UNIT: III WATER &amp; Its Treatment(2) Milli grams Per Litre (mg/litre): mg/L is the number of milligrams of CaCo3 equivalent hardness present per litre of water.</p> <p> i.e., 1 mg/L = 1 mg of CaCo3 equivalent hardness of 1 L of water.</p> <p>But 1 L water weights = 1 kg of water 1 kg = 1000 gms = 1000 x 1000 mg = 106 mg</p> <p> 1 mg/L = 1 mg of CaCo3 equivalent per 106 mg of water = 1 part of CaCo3 equivalent per 106 parts of water 1 mg/L = 1 ppm19UNIT: III WATER &amp; Its TreatmentDegree Of Clark (ocl) :</p> <p>ocl is number of grains (1/7000 lb) of CaCo3 equivalent hardness per gallon (10 lb) of water.</p> <p>(or)</p> <p>It is defined as the number of parts of CaCo3 equivalent hardness per 70,000 parts of water.</p> <p> 1ocl = 1 grain of CaCo3 eq. hardness per gallon of water.</p> <p>(or)</p> <p>1ocl = 1 part of CaCo3 eq. hardness per 70,000 parts of water 1 ppm = 0.07ocl20UNIT: III WATER &amp; Its TreatmentDegree Of French (oFr) :</p> <p>oFr is the number of parts of CaCo3 equivalent hardness per 105 parts of water.</p> <p>1oFr = 1 part of CaCo3 equivalent hardness per 105 parts of water</p> <p>Note: The hardness of water can be converted into all the four units by making use of the following interconversion formula</p> <p>1 ppm = 1mg/L = 0.07ocl = 0.1oFr 1ocl = 1.43oFr = 14.3 ppm = 14.3 mg/L 0.1o Fr = 1 ppm21UNIT: III WATER &amp; Its TreatmentPROBLEM:</p> <p>A sample of water gives an analysis 13.6 mg/L of CaSO4. 7.3 mg/L of Mg(HCO3)2. Calculate the total hardness and permanent hardness.</p> <p>Sol: </p> <p>The Total hardness of H2O = Temporary hardness + Permanent Hardness = 5 + 10 = 15 mg/L</p> <p>Permanent hardness = 10 ppm (or) 10 mg/LSaltQuantity Present (mg/L)M.WtEq. of CaCo3CaSO413.613613.6x100 = 10 136Mg(HCo3)27.31467.3 x 100 = 5 14622UNIT: III WATER &amp; Its TreatmentPROBLEM</p> <p>(2) Calculate the total hardness of 1000 litre of a sample of water containing the following impurities 16.2 mg/L of Ca(HCO3), 11.1 mg/L of CaCl2, 60 mg/L of MgSo4 and Ca(HCO3)2, 11.1 mg/L of CaCl2, 60 mg/L of MgSo4 and 19 mg/L if MgCl2.</p> <p>Sol: </p> <p>Total hardness of H2O = Temporary hardness + Permanent Hardness = 10 + 10 + 50 + 20 = 90 mg/L</p> <p>Total hardness for 1000 litres = 90 x 1000 = 90,000 mg/LSaltQuantity Present (mg/L)M.WtEq. of CaCo3Ca(HCO3)216.216216.2x100 = 10 162CaCl211.111111.1x100 = 10 111MgSO46012060x100 = 50 120MgCl2199519x100 = 20 9523UNIT: III WATER &amp; Its TreatmentPROBLEM</p> <p>(3) A Sample of hard water contains the following dissolved salts per litre.CaCl2 = 111 mgs, CaSO4 = 1.36 mgs, Ca(HCO3)2 = 16.2 mgs, Mg(HCO3)2 = 14.6 mgs, Silica = 40 gms, Turbidity = 10 mgs.Calculate the temporary, permanent and total hardness of water in ppm, Ocl &amp; OFr</p> <p>Sol:</p> <p>Note: Si &amp; Turbidity must not be considered because they do not cause hardness to water.SaltQuantity Present (mg/L)M.WtEq. of CaCo3CaCl2111 mg/L111111x100 =100 111CaSO41.36 mg/L1361.36x100 = 1 136Ca(HCO3)216.2 mg/L16216.2x100 = 10 162Mg(HCO3)214.6 mg/L14614.6x100 = 10 14624UNIT: III WATER &amp; Its TreatmentTotal hardness of H2O = Hardness of Ca(HCO3)2+ Mg(HCO3)2 interms of CaCO3 equivalents</p> <p> = 10 + 10 = 20 mg/L</p> <p>Permanent hardness = Hardness of CaCl2+ CaSO4 interms of CaCO3 equivalents</p> <p> = 100 + 1 = 101 mg/L</p> <p>Conversion of hardness:</p> <p>1 ppm = 1mg/L = 0.07ocl = 0.1o FrTotal hardness of the sample of water = 121 ppm = 121 mg/L = 121 x 0.07 = 8.47ocl and = 121 x 0.1 = 12.1o F</p> <p>Permanent hardness = 101 mg/L, 101 ppm, 7.07ocl, 10.1o FrTotal hardness = 20 mg/L, 20 ppm, 1.4ocl and 2o Fr25UNIT: III WATER &amp; Its TreatmentPROBLEM</p> <p>(04) 1 litre of water from an underground reservoir in Tirupati town in A.P showed the following analysis for contents:Mg(HCO3)2 = 42 mg; Ca(HCO3)2 = 146 mg; CaCl2 = 71 mg;NaOH = 40 mg; MgSO4 = 48 mg; Organic impurities = 100 mg;</p> <p>Calculate temporary and permanent and total hardness of the sample of 10,000 lit. of water</p> <p>Note: NaOH &amp; Organic impurities donot causes any hardness. The Bicarbonate salt cause temp hardness,</p> <p>While other are responsible for Permanent hardness.</p> <p>Mg(HCO3)2 = 42 mg in 10,000 (or) 42/10,000 ppm Its CaCO3 eqs are = [42/10000] x [100/146]</p> <p>Similarly for Ca(HCO3)2 it is [146/10000] x [100/162]For CaCl2 it is [71/10000] x [100/111]For MgSO4 it is [48/10000] x [100/120]26UNIT: III WATER &amp; Its TreatmentTemporary Hardness = [42/10000] x [100/146] + [146/10000] x [100x162]Permanent Hardness = [71/10000] x [100/111] + [48/10000] x [100x120]</p> <p>Total Hardness = Temporary Hardness + Permanent Hardness = ............ + = ... ppm27UNIT: III WATER &amp; Its TreatmentPROBLEM</p> <p>(5) Calculate the temporary &amp; permanent hardness of water in ocl, containing the following dissolved salts. CaCO3=50 mg/L, MgCl2=9.5 Mg/L, CaCl2=2.2 mg/L and MgSO4=12 mg/L </p> <p>Note: CaCO3 is an insoluble salt. It does not cause hardness. If CaCO3 is given as H.C.S, It must be considered as Ca(HCO3)2 whose hardness is expressed in the term of CaCO3 equivalent</p> <p>Sol:SaltQuantity Present (mg/L)M.WtEq. of CaCo3CaCO350 mg/L10050 mg/LMgCl29.5 mg/L959.5x100 = 10 95MgSO412 mg/L12012x100 = 10 12CaCl222.2 mg/L11122.2x100 = 20 11128UNIT: III WATER &amp; Its TreatmentTemporary Hardness Of Water = [Hardness Of CaCO3] = 50 ppm/50 mg/L = 50 x 0.7 = 3.5 ocl</p> <p>Permanent Hardness Of Water = Hardness of MgCl2 + MgSO4 + CaCl2 = 10 + 10 + 20 = 40 mg/L = 40 x 0.7 = 2.8o cl29UNIT: III WATER &amp; Its TreatmentDETERMINATION OF HARDNESS OF WATER BY EDTA METHOD:-</p> <p>This is a Complexometric method where Ethlene Diamine Tetra Acetic Acid (EDTA) is the reagent</p> <p>EDTA forms complexes with different metal ions at different pH.</p> <p>Calcium &amp; Magnesium ions form complexes with EDTA at pH 9-10. To maintain the pH 9-10 NH4Cl, NH4OH buffer solution is used.</p> <p>An Alcoholic solution of Eriochrome Black-T (EBT) is used as an indicator</p> <p>The disodium salt of EDTA under the trade name Triplex-III is used for complexation 30UNIT: III WATER &amp; Its Treatment EDTA</p> <p> Disodium Salt Of EDTA</p> <p> M-DETA COMPLEX</p> <p>31UNIT: III WATER &amp; Its TreatmentBASIC PRINCIPLE:</p> <p>When hardwater comes in contact with EDTA, at pH 9-10, the Ca+2 &amp; Mg+2 forms stable, colourless complex with EDTA.</p> <p>Ca+2 + + EBT pH 9-10 Ca-EBT Mg+2 Mg-EBT (Complex)</p> <p>(from hard water) (unstable, wine red colour)</p> <p>To the hard water sample the blue coloured indicator EBT is added along with the NH4Cl, NH4OH buffer solution. EBT forms an unstable, winered complex with Ca+2 &amp; Mg+2</p> <p> Ca+2 + + EDTA pH 9-10 Ca-EDTA Mg+2...</p>

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