water pollution (nres 102)

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    Water Pollution

    point source

    non-point source

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    Point versus non-point point source pollution

    discharge from factories, sewage treatmentplants, mines, power plants

    easy to identify, monitor, regulate we have done a good job controlling, and hasresulted in much improved water quality

    (National Pollution Discharge EliminationSystem, NPDES)

    non-point source agricultural runoff, storm-water, atmosphericdeposition

    broadly scattered, difficult to regulate andcontrol

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    Water Pollutants

    organic wastes pathogens chemical pollutants (metals,

    mercury)/ oil sediments nutrients hormone disruptors and drugs

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    Organic Wastes

    known as oxygen demanding wastes most are biodegradable, but dissolved

    O2 used up measure as BOD, biochemical oxygen

    demand (typically 5 day) raw sewage, paper mill discharge,

    food waste, dead animals

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    Dissolved oxygen versustemperature

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    Biochemical Oxygen Demand

    amount of oxygen required forbiochemical decomposition process microbial decomposition

    depletes stream O 2 concentrations three zones

    pollution zone active decomposition zone recovery zone

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    Organic Waste Added to Stream

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    Pathogens

    outbreaks of waterborne diseases Milwaukee, WI

    Cryptosporidium in 1993, (400,000 people) Fecal Coliform bacteria ( E. coli )

    standard measure, indicates fecal material ispresent

    these bacteria usually harmless Walkerton, ON example of where cow

    manure got into drinking water (5 died, manymore sick)

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    Sediments still a major problem despite 75 years of

    programs

    important water quality problem in Illinois bare soil and intense rainfall leads toerosion, and sediments entering streams smothers organisms

    adds oxygen demand leads to poor aquatic habitats turbidity

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    Embarras River - Camargo

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    Nutrients

    eutrophication enrichment of aquatic system nutrients

    leading to growth of plant andphytoplankton (algal blooms, periphyton,blue-green algae)

    cultural eutrophication when eutrophication is accelerated by

    human processes that add nutrients to abody of water

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    Lake

    Eutrophication

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    US EPA TMDLs EPA want states to address non-point

    source pollution

    total maximum daily loads - largest amountof a nutrient a stream can receive withoutcausing degradation

    focused on nitrogen and phosphorus

    P usually limiting nutrient to algal growth infreshwaters most degradation in US now thought to be

    nutrients from agriculture

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    Nutrient Standards

    all states being required to develop, includingIllinois

    must show that nutrients cause problems foraquatic life in Illinois concentration high nearly everywhere habitat problems (sediments) how to demonstrate?

    sewage treatment plants versus agriculture

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    Big Ditch Outlet

    Copper Slough

    North Fork Salt Creek North Fork Vermilion

    Jordan CreekSangamon River Fisher

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    Common Substrate Study

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    Phosphorus in detergents

    used to be present in all detergents

    many states banned in 1970s to 1980s in hand dish detergent, laundry detergents still no nationwide ban, but not in any. Why?

    was still present in ADDs until July 2010

    automatic dishwasher detergents 16 states banned phosphate recently in ADDs were 3 to 8% P, now < 0.5%

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    Hormone Disruptors and Drugs

    estrogens phthalates (plasticizers)

    Endocrine disruptors? caffeine to ibuprofen typically from sewage effluent

    now at low concentrations in mostlarge rivers long-term exposure effects?

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    From Kolpin et al.(2002)EnvironmentalScience &Technology36:1202-1211

    Cited >3100 timesalready

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    Groundwater Pollution

    often long-term problem chemicals/pollutants can

    accumulate/move over many years,difficult to remove

    bioremediation one approach utilizes microorganisms in the ground to

    consume or break down pollutants

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    Water Pollution Today

    much better than before Clean WaterAct of 1972

    still problems with nutrients and manynew chemicals easy problems fixed (point sources),

    non-point more difficult sewage treatment has helped

    next class