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WATER QUALITY AND HYDROLOGIC DATA FOR THE WEST BRANCH SWIFT RIVER AND EAST BRANCH FEVER BROOK, QUABBIN RESERVOIR DRAINAGE BASIN, MASSACHUSETTS By Rochelle L. Rittmaster and Gerald G. Girouard U.S. GEOLOGICAL SURVEY Open-File Report 90-182 Prepared in cooperation with the METROPOLITAN DISTRICT COMMISSION and the MASSACHUSETTS DEPARTMENT OF ENVIRONMENTAL PROTECTION, DIVISION OF WATER POLLUTION CONTROL Marlborough, Massachusetts 1992

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  • WATER QUALITY AND HYDROLOGIC DATA FOR THE WEST BRANCH SWIFT RIVER AND EAST BRANCH FEVER BROOK, QUABBIN RESERVOIR DRAINAGE

    BASIN, MASSACHUSETTS

    By Rochelle L. Rittmaster and Gerald G. Girouard

    U.S. GEOLOGICAL SURVEY Open-File Report 90-182

    Prepared in cooperation with the

    METROPOLITAN DISTRICT COMMISSION and theMASSACHUSETTS DEPARTMENT OF ENVIRONMENTAL PROTECTION,DIVISION OF WATER POLLUTION CONTROL

    Marlborough, Massachusetts 1992

  • U.S. DEPARTMENT OF THE INFERIOR

    MANUEL LUJAN, JR., Secretary

    U.S. GEOLOGICAL SURVEY

    Dallas L, Peck, Director \

    For additional information, write to:

    District ChiefMassachusetts Rhode Island OfficeU.S. Geological SurveyWater Resources Division28 Lord Rd., Suite 280Marlborough, MA 01752

    Copies of this report can be purchased from:

    Books and Open-File Reports Section U.S. Geological Survey Box 25425, Federal Center Denver, CO 80225

  • CONTENTSPage

    Abstract ........................................................................................................................................ 1Introduction................................................................................................................................. 1Sample-site numbering system ............................................................................................... 2Collection and computation of data ...................................................................................... 2Sampling procedures and handling ....................................................................................... 3Laboratory analyses ................................................................................................................... 7References ................................................................................................................................... 7

    ILLUSTRATIONSPage

    Figure 1-3. Maps showing:1. Locations of the West Branch Swift River and East Branch Fever Brook

    drainage basins, Massachusetts ................................................................................... 22. Locations of sampling sites, West Branch Swift River basin, Massachusetts ........... 53. Locations of sampling sites, East Branch Fever Brook basin, Massachusetts ......... 6

    TABLESPage

    Table 1. Wet deposition chemistry at station number 423027072204501, precipitation collectorat New Salem, Massachusetts ................................................................................................ 8

    2. Daily mean discharge at station number 01174565, West Branch Swift River nearShutesbury, Massachusetts ..................................................................................................... 16

    3. Physical characteristics and concentrations of chemical constituents of streamflow at station number 01174565, West Branch Swift River near Shutesbury, Massachusetts ..............................^............................................................................................ 18

    4. Physical characteristics and concentrations of chemical constituents of streamflow at station number 01174555, West Branch Swift River near Cooleyville, Massachusetts ............................................................................................................................ 30

    5. Physical characteristics and concentrations of chemical constituents of streamflow at station number 01174560, West Branch Swift River at Cooleyville, Massachusetts ............................................................................................................................ 32

    6. Physical characteristics and concentrations of chemical constituents of streamflow at station number 01174563, West Branch Swift River tributary at Cooleyville, Massachusetts ............................................................................................................................ 34

    111

  • TABLES (continued)Page

    7. Physical characteristics and concentrations of chemical constituents of streamflow at station number 01174564, West Branch Swift River tributary 2 at Cooleyville, Massachusetts ............................................................................................................................ 36

    8. Physical characteristics and concentrations of chemical constituents of ground water at station number 422800072232901, Swift River till well near Cooleyville, Massachusetts ............................................................................................................................ 38

    9. Physical characteristics and concentrations of chemical constituents of ground water at station number 422803072231801, Swift River sand and gravel well near Cooleyville, Massachusetts .................................................................................................... 39

    10. Daily mean discharge at station number 01174050, East Branch Fever Brook nearPetersham, Massachusetts ......................................^............................................................... 42

    11. Physical characteristics and concentrations of chemical constituents of streamflow at station number 01174050, East Branch Fever Brook near Petersham, Massachusetts ............................................................................................................................ 44

    12. Physical characteristics and concentrations of chemical constituents of streamflow at station number 01174035, Brooks Pond tributary near Petersham, Massachusetts ........................................................................................................................... 56

    13. Physical characteristics and concentrations of chemical constituents of streamflow at station number 01174040, East Branch Fevei[ Brook below Brooks Pond near Petersham, Massachusetts ............................................................................................ 58

    14. Physical characteristics and concentrations of chemical constituents of streamflow at station number 01174045, East Branch Fever Brook at West Road near Petersham, Massachusetts ......................................|............................................................... 60

    15. Physical characteristics and concentrations of chemical constituents of ground water at station number 422906072124301, Fever Brook till well near Petersham, Massachusetts ............................................................................................................................ 62

    16. Physical characteristics and concentrations of chemical constituents of ground water at station number 422910072120501, Knault's well near Petersham, Massachusetts ............................................................................................................................ 64

    17. Physical characteristics and concentrations of chemical constituents of ground water at station number 422906072130201, Fever Brook sand and gravel well near Petersham, Massachusetts ...................................................................................................... 65

    18. Description of soil-collection sites and samplings ....>............................................................... 6719. Results of chemical analysis of leachate extractions of soil samples collected in the

    Swift River and Fever Brook watersheds ........................................................................... 6820. Results of mineralogic analysis of clay-size (less thaii 2 micrometers) fraction of

    soil samples ............................................................................................................................... 6921. Physical characteristics and concentrations of chem: cal constituents of soil waters

    from the West Branch Swift River and East Branch Fever Brook basins .................. 70

    IV

  • CONVERSION FACTORS AND ABBREVIATIONS

    For the convenience of readers who may prefer to use metric (International System) units rather than the inch-pound units used in this report, values can be converted by using the following factors.

    Multiply inch-pound unit

    inch (in.)

    foot (ft)

    mile (mi)

    square mile (mi2)

    cubic foot (ft3)

    cubic foot per second (ftVs)

    cubic foot per second

    By

    Length

    2.54

    0.3048

    1.609

    Area

    2.590

    259.0

    Volume

    0.02832

    Flow

    0.02832

    0.01093

    To obtain metric unit

    centimeter (cm)

    meter (m)

    kilometer (km)

    square kilometer (km2)

    hectare (ha)

    cubic meter (m3)

    cubic meter per second (m3/i

    cubic meter per secondper square mile per square kilometer

    [(m3/s)/km2]

    Temperature

    Temperature in degrees Celsius (°C) can be converted to degrees Fahrenheit (°F) as follows: °F = (1.8 x °C) + 32

  • Water Quality and Hydrologic Data for the WestBranch Swift River and East Branch Fever Brook,

    Quabbin Reservoir Drainage Basin, Massachusetts

    By Rochelle L. Rittmaster and Gerald G. Girouard

    ABSTRACT

    Water quality and hydrologic data were collected as part of a study of the effects of acid precipitation on stream water quality in two watersheds in central Mas- sachusetts, conducted by the U.S. Geological Survey from November 1983 through September 1985. The two watersheds, West Branch Swift River (12.7 square miles) and East Branch Fever Brook (4.85 square miles), located north of Quabbin Reservoir, differ in surficial geology and hydrologic characteristics. Data are reported on precipitation quality and quantity and streamflow quality and quantity at the outlet of each watershed and at several tributaries. Also reported are the quality of soil water and ground water, chemistry of soil leachates, and mineralogical analyses of the clay-sized fraction of watershed soils.

    INTRODUCTION

    This report presents data collected by the U.S. Geological Survey from November 1983 through September 1985 during a study of effects of acid precipitation on stream-water quality. A paired watershed approach was used to assess the influence of geology and surface hydrologic characteristics on ameliorating the effects of acid deposition. The study was conducted in cooperation with the Water Pollution Control Division of the Massachusetts Department of Environmental Protection (MDEP) and the Metropolitan District Commission (MDC).

    The MDC operates Quabbin Reservoir, the primary source of public water supply for the Boston metropolitan area in eastern Massachusetts.

    The West Branch Swift River and East Branch Fever Brook are located in central Massachusetts to the northwest and northeast, respectively, of Quab- bin Reservoir (fig. 1). The West Branch Swift River (Swift River) drains a basin of 12.7 mi2 (square miles) that is characterized by steep till-covered bedrock ridges in the headwater areas and gently sloped stratified drift near the basin outlet. The East Branch Fever Brook (Fever Brook), which drains 4.85 mi2, has gentle slopes with till and stratified drift mixed throughout the basin.

    The data presented include chemical and hydrologic information for the determination of water yields and chemical quality of water used for supply and recreational purposes. They include chemical analyses of precipitation and stream samples collected approximately weekly, and daily mean discharge at gaging stations on Swift River and Fever Brook (figs. 2, 3). Wells drilled in each of the drainage basins were sampled approximately month- ly for chemical analysis of ground water. Soil samples were analyzed for physical, chemical, and mineralogical properties, and soil-water samples were collected for chemical analysis.

    Most of the data in this report are presented separately for each watershed and shown in tables at the end of this report. Hydrologic and chemical data collected from the Swift River basin are listed in tables 2 through 9. Similar data for the Fever Brook basin are presented in tables 10 through 17. Data on the soils and soil-water samples collected in both basins are combined in tables 18 through 21.

  • 27 MASSACHUSETTS A Worcester

    Figure 1. Locations of the West Branch Swift kiver and East Branch Fever Brook drainage basins, Massachusetts.

    The authors are grateful to State officials and local residents who provided time and information for this study. Special thanks are extended to Mr. David Ashenden and Mr. Bruce Spencer of the MDC for their on-site assistance and observations, and to Gail Batch elder at the University of Mas- sachusetts at Amherst, Massachusetts, for her laboratory analyses of soil samples.

    SAMPLE-SITE NUMBERING SYSTEM

    Gaps left in the series of numbers reserves station numbers for assignment in proper sequence should intermediate stations be established in the future.

    Ground-water and soil-water sampling sites were assigned 15-digit identification numbers. The first 13 digits provide the geographic coordinates of the site in degrees, minutes, and seconds of latitude and longitude. The last 2 digits are sequential iden- tification numbers for sites within the 1-second by 1-second quadrangle identified by the 13-digit latitude-longitude.

    A sample site numbering system for surface water and ground water was used to identify, record, organize, and track sample analyses. Eight-digit sta- tion numbers were assigned to each surface-water gaging station and surface-water sampling site. These numbers were assigned in downstream order.

    CO LECTION AND COMPUTATION OF DATA

    Wet deposition was collected weekly, using an Aerochem-Metrics1 Model 301 wet/dry deposition sampler. The sampler was operated on private

    Use of brand names in this report is for identification purposes only and does not constitute endorsement by the U.S. Geological Survey.

  • property, in an open field, on undisturbed pas- tureland, and was set on a platform to diminish potential for vegetation and dust contamination of the samples. Because of a change in land ownership of the original site, the collector was moved in April 1985 to a site 0.5 mi (miles) away that was owned by the MDC. The samples were collected as 7-day com- posites of wet deposition. Chemical analyses of those samples are identified in table 1 by the begin- ning date of the 7-day period. Samples were generally collected on Tuesday to coincide with the day designated for weekly precipitation collection for the National Atmospheric Deposition Program (NADP) (Bigelow, 1982). Samples were analyzed for major cations and anions, nutrients, and some trace metals. Some weeks have only partial chemical data listed because of insufficient quantity of precipitation or malfunction or vandalism of the equipment.

    Daily mean discharges for stations on the Swift River (01174565) and Fever Brook (01174050) were computed from continuous records of stage and in- termittent measurements of stream discharge and stage (tables 2 and 10). These data have also been published by the U.S. Geological Survey (1987). Stage was recorded at 15-minute intervals on a punch-tape water-stage recorder. Instantaneous discharge was measured with a Price current meter, using general guidelines of the U.S. Geological Sur- vey (Rantz and others, 1982). The relation between stage and discharge was developed using discharge measurements made over a range of stages. Obser- vations of factors affecting stage, such as ice, vegeta- tion, and beaver impoundments were used to adjust stage records in determining the daily flows reported in tables 2 and 10.

    Heavy rains in May 1984 resulted in stream levels above maximum stage-recording levels of the gaging stations. Peak discharge for this event was estimated using the slope-area method (Dalrymple and Benson, 1967), based on high water marks estab- lished during peak flow at the gaging stations.

    Stream samples were collected at the gaging sites approximately weekly and more frequently during snowmelt and following some rainstorms (tables 3 and 11). This sampling scheme permitted evaluation of water quality on the basis of seasonality and hydrologic conditions. Water samples also were collected at tributaries to Swift River and Fever Brook during late-winter and spring snowmelt, summer low flow, and autumn-winter baseflow conditions (tables 4-7, and 11-14). Except for the gaging site on Swift River, grab samples were collected at all stream sampling locations because

    waters were well-mixed, as identified by measure- ments of uniform specific conductance, pH, and temperature across the channels. The Swift River gaging site was located downstream of the con- fluence of a tributary to the main channel, and lateral profiles of pH and specific conductance indi- cated incomplete mixing of the tributary and main channel waters. At this site, samples were collected across the stream channel and composited in a churn splitter.

    Monitoring wells were drilled in till and stratified drift in each drainage basin. Water levels were measured approximately monthly, and water samples were collected monthly to bimonthly (tables 8-9 and 15-17). At least three well volumes were evacuated from the wells in stratified drift prior to each sampling. Because the wells in till recovered slowly upon evacuation of standing waterj sometimes only two well volumes were removed before each sampling.

    Water from the unsaturated zone in both basins was sampled periodically, when near-saturated con- ditions existed (table 21). Two types of collectors were used: (1) zero-tension lysimeters, consisting of polyvinyl chloride (PVC) pipe cut lengthwise to form a trough, and driven into the soil, and (2) a negative-tension TIMCO lysimeter with porous Teflon cups installed at depths ranging from 4 to 18 in. (inches) below ground surface. Because water drained quickly through these soils, water was recovered only from the deep lysimeter in the Swift River basin and from the deep and medium depth lysimeters in the Fever Brook basin. Soil-water samples yielded variable amounts of water, some sufficient only for pH and specific conductance and some sufficient for full chemical analysis (pH, specific conductance, major cations and anions).

    Soil samples were collected from the O, A, and B horizons at several sites in the study basins (table 18). The sites were selected to provide an areal distribution and variation in surficial geology and underlying bedrock type.

    SAMPLING PROCEDURES AND HANDLING

    Temperature, specific conductance, and pH were measured in the field. An Extech digital con- ductivity meter and an Extech model 609 digital pH meter with an Orion glass combination pH electrode were used. Two reference solutions (Barnes, 1964) of low ionic strength were used to calibrate the pH meter prior to sample measurement.

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    CONTOUR INTERVAL 10 FEETSOIL-WATER-SAMPLING SITE

    AND SOIL-SAMPLE SITENATIONAL GEODETIC VERTICAL

    DATUM OF 1929 DRAINAGE BASIN BOUNDARY

    Figure 3.--Locations of sampling sites, East Branch Fever Brook basins, Massachusetts.

  • Samples were filtered, preserved, and chilled in the field in accordance with methods recommended by the U.S. Geological Survey (Skougstad and others, 1979). Samples were shipped on ice to the U.S. Geological Survey Central Laboratory in Doraville, Georgia, for chemical analysis. Part of each sample was retained for measurement of alkalinity in a laboratory in the Massachusetts office.

    Initially, dissolved aluminum was analyzed from samples that passed through a 0.4-^m (micrometer) filter. However, investigators (Jones and others, 1974) have observed that particulate and colloidal aluminum can pass through that filter pore size, causing overestimation of monomeric, "free" aluminum concentrations, the form of aluminum considered most toxic to fish (Driscoll and others, 1980). Therefore, during the first year of sample collection, two aliquots were periodically submitted for dissolved aluminum analysis -- one having passed through a 0.4-^m filter, and one having passed through a 0.1-^m filter. Dissolved aluminum con- centrations reported for water samples collected at the two basin outlets after December 1,1984, are only for those samples that passed through the 0.1-^wm filter.

    LABORATORY ANALYSES

    Concentrations of chemical constituents in the water samples were determined by methods outlined by Skougstad and others (1979). Many of the methods were developed especially for the analysis of low ionic-strength waters. Alkalinity was measured by incremental titration (M.C. Yurewicz, U.S. Geological Survey, written communication, 1985) using 0.01639-molar sulfuric acid as the titrant. This method is sensitive to the detection of the actual buffering threshold of water, the point at which the pH drops very quickly with small additions of acid. In contrast, a fixed-endpoint titration requires acid titration of the sample to pH 4.3 or 4.5. Because total carbonic-acid concentrations are low in these waters, the true endpoint generally is at a pH sig- nificantly higher (pH 5.0 to 5.3) than that of a fixed- endpoint titration. Therefore, the alkalinity measured by incremental titration is more conserva- tive and accurate than the alkalinity measured by fixed-endpoint titration in the determination of the buffering capacities of the waters.

    Chemical analysis of soil-water leachates in- cluded exchangeable base cations (calcium, mag- nesium, sodium, and potassium) and exchangeable acidity (aluminum and hydrogen) (table 19) (Thomas, 1982). Mineralogical analysis of the clay-

    size fraction (less than 2^m) of watershed soils was performed at the Department of Geology and Geog- raphy, University of Massachusetts, using X-ray dif- fraction.

    REFERENCES

    Barnes, I., 1964, Field measurement of alkalinity and pH: U.S. Geological Survey Water-Supply Paper 1535-H, 17 p.

    Bigelow, D.S., 1982, National Atmospheric Deposi- tion Program instruction manual, site opera- tion: Program Coordinator's Office, National Atmospheric Deposition Program, Colorado State University, Fort Collins, CO, 30 p.

    Dalrymple, T., and Benson, M.A., 1967, Measure- ment of peak discharge by the slope-area method: Techniques of Water-Resources In- vestigations of the U.S. Geological Survey, Book 3, Chapter A2, 12 p.

    Driscoll, C.J., Jr., Baker, J.P., Bisogni, J.J., Jr., and Schofield, C.L., 1980, Effect of aluminum speciation on fish in dilute acidified waters: Nature, v. 284, p. 161-164.

    Jones, B.F., Kennedy, V.C., and Zellweger, G.W., 1974, Comparison of observed and calculated concentrations of dissolved aluminum and iron in stream water: Water Resources Research, v. 10, p. 791-793.

    Rantz, S.E., and others, 1982, Measurement and computation of streamflow: v. 1, measurement of stage and discharge: U.S. Geological Survey Water-Supply Paper 2175, 284 p.

    Skougstad, M.W., Fishman, M.J., Friedman, L.C., Erdmann, D.E., and Duncan, S.S., eds., 1979, Methods for determination of inorganic sub- stances in water and fluvial sediments: U.S. Geological Survey Techniques of Water- Resources Investigations, Book 5, Chapter Al, 626 p.

    Thomas, G.W., 1982, Exchangeable cations in Page, A.L., Muller, R.H., and Keeney, D.R. (eds.), Methods of Soil Analysis, Part 2, Chemical and Biological Properties: Agronomy Monograph 9, Madison, WI., p. 159-164.

    U.S. Geological Survey, 1987, Water Resources Data, Massachusetts and Rhode Island, Water Year 1985, U.S. Geological Survey Water-Data Report MA-RI-85-1.

  • Tabl

    e I.

    Wet

    dep

    ositi

    on c

    hem

    istr

    y at

    stat

    ion

    num

    ber 4

    2302

    7072

    2045

    01, p

    reci

    pita

    tion

    colle

    ctor

    at N

    ew S

    alem

    , Mas

    sach

    uset

    ts

    [p.S

    /cm

    , mic

    rosi

    emen

    s pe

    r cen

    timet

    er a

    t 25

    degr

    ees

    Cel

    sius

    ; mg/

    L, m

    illig

    ram

    s pe

    r lite

    r, |ig

    /L, m

    icro

    gram

    s pe

    r lite

    r;in

    ., in

    ches

    ; <, l

    ess

    than

    ; das

    hes

    indi

    cate

    not

    ana

    lyze

    d]

    oo

    Date

    1983

    Nov. 22-29

    Nov. 29-Dec. 06

    Dec.

    07-13

    Dec.

    13-20

    Dec.

    20-27

    Dec.

    28,

    1983-

    Jan. 03

    , 1984

    1984

    Jan.

    03-10

    Jan.

    11-17

    Jan.

    17

    -24

    Jan.

    24-31

    Jan.

    31-Feb. 07

    Feb. 07-14

    Feb. 14-21

    Feb. 21-28

    Feb. 28-Mar. 06

    Mar. 06-13

    Mar. 13-20

    Mar. 20-27

    Mar. 27-Apr. 03

    Apr. 03-10

    Apr. 10-17

    Rain-

    fall

    (i

    n.)

    2.85

    1.92

    2.12

    1.54

    1.26 .99

    .51

    .90

    .32

    1.10

    1.24 .58^

    3.68

    1.04

    1.43

    1.81

    3.09

    3.09 .00

    1.21

    2.37

    Spe-

    cific

    con-

    duct-

    ance

    (JlS

    /cm)

    12 15 147

    13 45 13 42 24 21 44 12 14 13 19

    716 15 21

    PH

    (sta

    nd-

    ard

    unit

    s)

    4.8

    4.5

    4.8

    4.8

    4.7

    4.0

    4.5

    4.0

    4.3

    4.4

    3.9

    4.7

    4.6

    4.5

    4.3

    4.7

    4.5

    4.4

    4.4

    Calcium,

    dis-

    solved

    (mg/

    L as Ca

    )

    0.10

    .08

    .05

    .06

    .03

    .12

    .13

    .03

    .39

    .10

    .09

    .20

    .06

    .11

    .04

    .14

    .07

    .05

    .07

    .13

    Magne-

    sium

    , dis-

    solved

    (mg/L

    as Mg)

    0.02 .09

    .08

    .07

    .02

    .07

    .08

    <.01

    <-01

    .03

    .05

    .0*

    .10

    .03

  • Tabl

    e \.-

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    dep

    ositi

    on c

    hem

    istr

    y at s

    tatio

    n nu

    mbe

    r 423

    0270

    7220

    4501

    , pre

    cipi

    tatio

    n co

    llect

    or a

    t New

    Sal

    em, M

    assa

    chus

    etts

    -Con

    tinue

    d

    Date

    1984 Cont.

    Apr.

    17

    -24

    Apr.

    24-May 01

    May

    01-0

    8Ma

    y 08

    -15

    May

    15-2

    2

    May

    22-29

    May

    29-June

    051

    June

    05

    -12

    June 12-19

    June 19

    -26

    June

    2 6-

    July

    03Ju

    ne 26-July

    102

    July 03

    -10

    July 10

    -17

    July 10

    -242

    July

    17-24

    July 24

    -31

    July 31

    -Aug

    . 07

    Aug.

    07-14

    Aug.

    14-21

    Aug.

    21-28

    Aug. 28-Sept. 04

    Sept

    . 04

    -11

    Sept

    . 11-18

    Sept

    . 18-25

    Rain-

    fall

    (in.

    )

    0.81 .00

    2.25

    1.66 .21

    1.78

    9.14 .00

    .58

    .62

    '

    .53

    3.

    501.89

    1.39 .56

    .00

    .76

    .88

    .08

    .83

    .00

    .48

    .00

    Spe-

    cifi

    cco

    n-du

    ct-

    ance

    (US/cm)

    .37

    -- 16 34 25 15 ~ 60 35 45 ~ 23 35 23 23 ~ 37 24 86 42 ~ 38

    PH(stand-

    ard

    units)

    4.1

    --

    4.5

    4.3

    4.3

    4.5

    3.9

    4.1

    4.3

    ~4.

    34.

    1

    4.3

    4.3

    4.2

    4.4

    3.7

    4.0

    --

    4.1

    Calc

    ium,

    dis-

    solved

    (mg/

    Las

    Ca

    )

    0.16

    .1

    2.1

    0.0

    9

    .06

    .13

    .11

    __ --.06

    .09

    .03

    .17

    -- --.03

    __ -- ~

    .11

    Magne-

    sium,

    dis-

    solved

    (mg/L

    as Mg

    )

    0.04

    .0

    1.03

    .05

    .06

    ~ .0

    2.1

    1

    __ .09

  • Tabl

    e 1.

    Wet

    dep

    ositi

    on c

    hem

    istr

    y at

    stat

    ion

    num

    ber 4

    2302

    7072

    2045

    01, p

    reci

    pita

    tion

    colle

    ctor

    at N

    ew S

    alem

    , Mas

    sach

    uset

    ts--

    Con

    tinue

    d

    Date

    1984

    Con

    t.

    Sept

    . 25-Oct. 02

    Oct. 02-09

    Oct. 09-16

    Oct. 17

    -23

    Oct. 23-30

    Oct. 30-Nov. 06

    Nov. 06-13

    Nov. 13-20

    Nov. 20-27

    Nov. 27-Dec. 05

    Dec. 05-11

    Dec. 11-19

    Dec. 19-26

    Dec.

    26

    , 1984-

    Jan. 02,

    1985

    1985

    Jan.

    02

    -08

    Jan. 08-15

    Jan.

    15

    -22

    Jan. 22-29

    Jan. 29-Feb. 05

    Feb. 05-13

    Feb. 13-19

    Feb. 19-25

    Feb. 25-Mar. 05

    Mar. 05-12

    Rain-

    fall

    (in.)

    0.00 .00

    .00

    1.06 .63

    1.82

    1.76

    .10

    .00

    .26

    .75

    .06

    1.97 .45

    .47

    .00

    .39

    .00

    .52

    1.25 .00

    .41

    1.14

    1.27

    Spe-

    cific

    con-

    duct-

    ance

    ((IS/cm)

    28 48 6 11 42 19 73 68 30 36 55 38 44 11 71 27 20

    PH

    (sta

    nd-

    ard

    units)

    4.2

    4.0

    4.9

    4.6

    4.1

    4.4

    3.8

    3.8

    4.1

    4.1

    4.0

    4.1

    4.0

    4.8

    3.8

    4.2

    4.3

    Calcium,

    dis-

    solved

    (mg/L

    as Ca

    )

    0.04 .08

    <.02

    .02

    .03

    .09

    .06

    __

    .31

    .23

    .07

    Nitro-

    Magne-

    Potas-

    Nitro-

    gen,

    sium

    , So

    dium

    , sium,

    gen,

    ammonia,

    dis-

    dis-

    dis-

    ammonia

    dis-

    solved

    solved

    solved

    total

    solved

    (mg/

    L (mg/L

    (mg/L

    (mg/

    L (mg/L

    as Mg

    ) as

    Na)

    as K)

    as N)

    as N)

    __ <0.01

    <0.2

    0.04

    0.248

    .03

  • Tabl

    e 1 .

    -Wet

    dep

    ositi

    on c

    hem

    istry

    at s

    tatio

    n nu

    mbe

    r 423

    02 70

    7220

    4501

    , pre

    cipi

    tatio

    n co

    llect

    or a

    t New

    Sal

    em, M

    assa

    chus

    etts

    -Con

    tinue

    d

    Date

    Rain-

    fall

    (in.)

    Spe-

    cific

    con-

    duct-

    ance

    (US/

    cm)

    PH

    (sta

    nd-

    ard

    unit

    s)

    Magne-

    Potas-

    Nitro-

    Calcium,

    sium,

    Sodi

    um,

    sium,

    gen,

    dis-

    dis-

    dis-

    dis-

    ammonia

    solved

    solved

    solved

    solved

    total

    (mg/

    L (mg/L

    (mg/

    L (mg/L

    (mg/L

    as Ca

    ) as

    Mg)

    as Na

    ) as

    K)

    as N)

    Nitro-

    gen,

    ammonia,

    dis-

    solved

    (mg/L

    as N)

    Sulfate,

    dis-

    solved

    (mg/

    L as SO

    )

    Nitro-

    gen,

    nitrate,

    dis-

    solved

    (mg/

    L as N)

    Phos-

    phor

    us,

    orth

    o,

    dis-

    solved

    (mg/L

    as P)

    1985 Cont.

    Mar.

    Mar.

    Mar.

    Apr.

    Apr.

    Apr.

    Apr.

    Apr.

    May

    May

    May

    May

    June

    June

    June

    June

    July

    July

    July

    July

    Aug.

    Aug.

    Aug.

    Aug.

    Aug.

    Sep.

    12-19

    19-26

    2 6-

    Apr.

    0202-09

    09-16

    16-23

    23-30

    30-May 07

    07-14

    14-2

    1

    21-29

    2 9- June 04

    04-11

    11-18

    18-2

    51

    25-July 02

    02-16

    16-23

    23-31

    31-Aug. 07

    07-08

    09-13

    13-2

    021-27

    27-Sept. 04

    04-11

    1.38 .00

    1.00 .76

    .10

    .25

    .24

    1.25 .00

    1.23

    1.06 .85

    .00

    1.06 .78

    .76

    1.95 .32

    1.18 .76

    .16

    .28

    2.84

    1.98

    1.51

    1.03

    50 21 49 140

    121 10 27 21 40 60 44 24 67 44 36 44 30

    115 66 25 67 28

    4

    4 4 3 3 4 4

    4 4 3

    4--

    4 3 4 4 4 4 3 3 4 3 4

    .0 .4 .1 .6 .7 .7 .2 .3 .0 .9 .0 .2 .8 .0 .1 .0 .1 .6 .8 .5 .8 .2

    _

    __

    __

    __

    _

    0.23

    0.05

    <0.2

    0.03

    .70

    .17

    .5

    .14

    --

    --

    .05

    .07

  • Tabl

    e 1.

    - Wet

    dep

    ositi

    on c

    hem

    istr

    y at

    stat

    ion

    num

    ber 4

    2302

    7072

    2045

    01, p

    reci

    pita

    tion

    colle

    ctor

    at N

    ew S

    alem

    , Mas

    sach

    uset

    ts-C

    ontin

    ued

    Date

    1983

    Nov. 22-29

    Nov. 29-Dec. 06

    Dec. 07-13

    Dec. 13-20

    Dec.

    20-27

    Dec.

    28,

    1983-

    Jan.

    03,

    1984

    1984

    Jan. 03-10

    Jan.

    11-17

    ^

    Jan. 17-24

    10

    Jan.

    24-31

    Jan.

    31-Feb. 07

    Feb. 07-14

    Feb. 14-21

    Feb. 21-28

    Feb. 28-Mar. 06

    Mar. 06-13

    Mar. 13-20

    Mar. 20-27

    Apr. 03-10

    Apr. 10-17

    Apr. 17-24

    May 01-08

    May 08-15

    May 15

    -22

    May 22-29

    May 2 9-

    June 05

    1

    Chlo-

    Fluo-

    ride,

    ride,

    dis-

    dis-

    solved

    solved

    (mg/L

    (mg/

    L as

    Cl

    ) as

    F)

    <0.20

    <0.01

    .44

  • Tabl

    e 1.

    Wet

    dep

    ositi

    on c

    hem

    istry

    at s

    tatio

    n nu

    mbe

    r 423

    0270

    7220

    4501

    , pre

    cipi

    tatio

    n co

    llect

    or a

    t New

    Sal

    em, M

    assa

    chus

    etts

    Con

    tinue

    d

    CO

    Chlo-

    Fluo-

    ride,

    ride.

    Copper,

    Date

    dis-

    dis-

    dis-

    solved

    solved

    solved

    (mg/L

    (mg/L

    (^lg

    /L

    as Cl)

    as F)

    as Cu)

    1984 Cont.

    June 12-19

    <0.2

    0.03

    June 19-26

    1.2

    .06

    June 2 6- July 03

    June 26-July 10

    2July 03-10

    .2

  • Tabl

    e 1.

    -Wet

    dep

    ositi

    on c

    hem

    istr

    y at

    sta

    tion

    num

    ber 4

    2302

    7072

    2045

    01, p

    reci

    pita

    tion

    colle

    ctor

    at N

    ew S

    alem

    , Mas

    sach

    uset

    ts C

    ontin

    ued

    Chlo-

    Fluo-

    ride,

    ride

    , Date

    dis-

    dis-

    solved

    solved

    (mg/

    L (mg/L

    as Cl

    ) as F)

    1984 Con

    t.

    Nov.

    20-27

    Nov. 27-Dec. 05

    0.5

    <0.01

    Dec.

    05-11

    Dec.

    11-19

    Dec.

    19-26

    .06

    .03

    Dec.

    26,

    1984-

    Jan.

    02,

    1985

    .2

    .04

    1985

    Jan.

    02-08

    Jan.

    08-15

    Jan.

    15-22

    Jan.

    22-29

    Jan.

    29-Feb. 05

    Feb.

    05-13

    .68

    .03

    Feb.

    13-19

    Feb.

    19-25

    Feb. 25-Mar. 05

    .19

    .02

    Mar.

    05-12

    .65

    <.01

    Mar. 12-19

    Mar.

    19-26

    Mar.

    26-Apr. 02

    .17

    <.01

    Apr.

    02-09

    .92

    .05

    Apr.

    09-16

    Apr. 16-23

    Apr. 23-30

    Apr. 30-May 07

    May

    07-1

    4May

    14-21

    .15

    .02

    Manga-

    Sele-

    Vana-

    Copp

    er,

    Iron

    , Lead,

    nese

    , Mercury,

    nium

    , dium,

    Carb

    on,

    dis-

    dis-

    dis-

    dis-

    dis-

    dis-

    dis-

    organic

    solved

    solved

    solved

    solved

    solved

    solved

    solved

    total

    (Hg/L

    (Hg/L

    (Hg/L

    (y.g

    /L

    (^g/L

    (Hg/

    L (H

    g/L

    (mg/

    L as Cu)

    as Fe

    ) as Pb)

    as Mn)

    as Hg)

    as Se)

    as V)

    as C)

    2.0

    6 3.

    1

  • Tabl

    e 1 .

    Wet

    dep

    ositi

    on c

    hem

    istr

    y at

    stat

    ion

    num

    ber 4

    2302

    7072

    2045

    01, p

    reci

    pita

    tion

    colle

    ctor

    at N

    ew S

    alem

    , Mas

    sach

    uset

    ts C

    ontin

    ued

    Date

    Chlo-

    ride

    , dis-

    solved

    (mg/

    L as Cl)

    Fluo-

    Manga-

    ride,

    Copper,

    Iron

    , Lead,

    nese

    , Mercury,

    dis-

    dis-

    dis-

    dis-

    dis-

    dis-

    solved

    solved

    solved

    solved

    solved

    solved

    as F)

    as Cu

    ) as Fe)

    as Pb)

    as Mn)

    as Hg

    )

    Sele-

    Vana-

    nium

    , dium,

    Carb

    on,

    dis-

    dis-

    organic

    solved

    solved

    tota

    l (|ig/L

    (|Ag/L

    (mg/L

    as Se)

    as V)

    as

    C)

    1985

    Cont.

    May

    May

    June

    June

    June

    June

    July

    July

    July

    July

    Aug.

    Aug.

    Aug.

    Aug.

    Aug.

    Sept

    21-29

    2 9-

    June 04

    04-11

    11-18

    18-25

    1

    25-July 02

    02-16

    16-23

    23-31

    31-Aug. 07

    07-0

    809-13

    13-20

    21-27

    27-Sept. 04

    . 04-11

    0.34

    .21

    .08

    .18

    .21

    .04

    .17

    .38

    .20

    .11

    __

    0.26

    19

    11

    7.0

    3

    .02

    3.0

    8 4.

    0 2

    <.01

    -

    16

    -

  • Table 2.-Daily mean discharge at station number 01174.565, West Branch Swift River nearShutesbury, Massachusetts

    [Period of record begins November 8,1983; (ft^/sj/mi2, cubjic feet per second per square mile;dashes indicate not applicable]

    Discharge, in cubic feet per second, water year October 1983 to September 1984

    Day Oct Nov Dec Jan Feb Mar Apr May June July Aug Sept

    12345

    6789

    10

    1112131415

    1617181920

    2122232425

    262728293031

    Total Mean Maximum Minimum (ffVsJ/ Inches

    __ __ 3.63.84.2

    2319129.48.5

    6855261915

    40372625

    144

    13073546249

    --

    3529252424

    26118593934

    3129

    175299126

    8363524638

    3537403530

    272534624537

    1,76256.8

    299244.485.16

    3429272624

    2424222120

    2120201918

    1715141413

    1414141746

    362420191717

    660 2,21.346131.681.93

    1515193944

    3828222120

    2025272981

    405143184121112

    8564548786

    83615763

    04870.6

    405155.566.00

    5143373532 2

    36 235 ]30 ]2927

    4048576538

    5372219277

    25 6523212124

    24 ]29 ]29

    65636892

    311073

    31 7036 65

    42 6269 5170 4554 5147 50

    44 434341424438

    1,152 2,<37.270 :212.933.37

    36322927

    91 2,83.053276.547.30

    262424

    10060

    4035457045

    3540609060

    4337322926

    2522243626

    222019

    173612521

    421 1,78.1

    612196.157.09

    2051591147861

    5044383227

    2320181817

    1514151714

    1311111012

    119.27.77.66.8

    078.335.9

    2056.82.833.16

    7.47.67.26.55.6

    18164672920

    1514118.26.9

    1218252414

    109.27.46.75.9

    4.55.58.86.86.34.9

    556.417.9

    1644.51.411.63

    4.33.93.83.53.2

    2.83.65.63.63.3

    2.92.32.22.22.2

    1.71.61.61.5

    10

    4.03.22.42.42.1

    1.71.41.41.41.41.8

    89.02.87

    101.4.23.26

    2.11.71.92.62.8

    1.91.41.41.41.3

    1.21.01.01.01.2

    1.41.41.41.11.0

    1.0.90.90.90.90

    .90

    .90

    .90

    .90

    .90

    39.301.312.8.90.10.12

    16

  • Table l.-Daily mean discharge at station number 01174565, West Branch Swift River near Shutesbury, Massachusetts-Continued

    Discharge, in cubic feet per second, water year October 1984 to September 1985

    Day

    12345

    6789

    10

    1112131415

    1617181920

    2122232425

    262728293031

    TotalMeanMaximumMinimum(ft j /s) /mi-Inches

    Oct

    0.947.64.63.12.7

    1.91.91.61.61.6

    1.51.51.51.41.4

    1.41.31.41.41.4

    1.41.66.03.93.3

    4.24.23.63.63.33.0

    79.842.587.6

    94- .20

    .23

    Calendar year 1984Water year 1985

    Nov

    2.52.32.12.0

    32

    27127.75.86.3

    9.941251612

    129.78.16.66.0

    5.75.65.75.55.1

    5.14.84.78.7

    11

    307.910.3412.0.81.90

    Total 11,Total 4,

    Dec

    7.97.26.88.87.5

    40178.46.75.9

    6.27.48.8

    1212

    1111151622

    1726282020

    191715152522

    461.614.9405.91.171.35

    384.21112.51

    Jan

    2031272117

    1513121111

    109.89.49.08.8

    8.68.48.28.08.0

    8.07.87.67.47.2

    7.17.06.86.76.56.4

    344.711.1316.4.88

    1.01

    Mean 31Mean 11

    Feb

    6.36.26.16.06.0

    6.06.06.06.06.0

    6.06.2

    232521

    171513109.6

    9.39.4

    132240

    322721

    380.113.6406.01.071.11

    . 1 Maximum

    . 3 Maximum

    Mar

    1817141317

    1413141717

    181621065945

    3738333029

    2926232221

    191919201919

    94730.5

    162132.412.77

    612162

    Apr

    2222222326

    2622242320

    1817161414

    1413131211

    11109.68.68.9

    8.27.77.97.77.4

    459.015.3267.41.201.34

    MinimumMinimum

    May

    6.96.6

    131511

    1212109.38.8

    8.27.57.26.55.8

    5.95.4

    182115

    1621139.87.6

    6.86.29.9

    139.27.4

    June

    9.98.16.96.06.0

    7.15.85.76.65.1

    4.16.26.15.45.1

    5.58.98.57.25.7

    4.74.44.65.65.7

    5.04.86.49.79.4

    325.0 190.210.5215.4.83.95

    .90 (ft

    .94 (ft

    6.349.94.1.50.56

    3/s)/mi3 /s)/mi

    July

    6.94.43.32.92.6

    2.83.42.92.82.4

    2.42.44.32.72.6

    3.14.02.51.61.3

    1.21.31.11.11.4

    3.56.63.52.82.54.2

    90.52.926.91.1.23.27

    2 2.452 .89

    Aug

    22127.95.53.8

    2.92.56.04.23.0

    2.92.81.51.32.7

    28126.45.45.4

    4.13.32.92.4

    12

    21149.06.47.8

    18

    239.17.71

    281.3.61.70

    InchesInches

    Sept

    139.27.35.95.1

    7.620141122

    17128.98.25.6

    5.14.74.23.73.4

    3.12.92.83.55.0

    4.12133159.3

    287.69.59

    332.8.75.84

    33.312.0

    17

  • Table ^. Physical characteristics and concentrations of Chemical constituents of stream/low atstation number 01174565, West Branch Swift River i tear Shutesbury, Massachusetts

    [ft3/s, cubic feet per second; uS/cm, microsiemens per centimeter at 25 degrees Celsius; °C, degrees Celsius; mg/L, milligrams per liter; |ig/L, micrograms per liter,

  • Table ^.-Physical characteristics and concentrations of chemical constituents ofstreamflow at station number 01174565, West Branch Swift River near Shutesbury, Massachusetts-Continued

    Date

    11-01-8311-08-8311-15-8311-22-8311-29-83

    12-06-8312-13-8312-20-8312-27-8301-03-84

    01-10-8401-17-8401-24-8401-27-8401-31-84

    02-05-8402-05-8402-07-8402-14-8402-15-84

    02-16-8402-16-8402-17-8402-21-8402-28-84

    03-06-8403-13-8403-20-8403-27-8403-27-84

    04-03-8404-03-8404-05-8404-05-8404-06-84

    04-06-8404-10-8404-16-8404-16-8404-17-84

    04-17-8404-24-8405-01-8405-08-8405-16-84

    Potas- sium, dis- solved (mg/L as K)

    0.56.54.50.41.37

    .36

    .33

    .35

    .37

    .34

    .37

    .38

    .41

    .31

    .38

    .36

    .33

    .35

    .37

    .35

    .36

    .34

    .34

    .38

    .41

    .37

    .33

    .34

    .34

    .49.28

    .28

    .32.38.37.31

    Nitro- Nitro- gen, gen; ammonia,

    ammonia dis- total solved (mg/L (mg/L as N) as N)

    0.02.12.01.03

  • Table 3. Physical characteristics and concentrations of chemical constituents ofstreamflow at station number 01174565, West Branch Swift River near Shutesbury, Massachusetts-Continued

    Solids, sum of consti- tuents,

    dis- Date solved

    (mg/L)

    11-01-8311-08-8311-15-8311-22-8311-29-83

    12-06-8312-13-8312-20-8312-27-8301-03-84

    01-10-8401-17-8401-24-8401-27-8401-31-84

    02-05-84 02-05-8402-07-8402-14-8402-15-84

    02-16-84 02-16-8402-17-8402-21-84 02-28-84

    03-06-8403-13-8403-20-8403-27-84 03-27-84

    04-03-84 04-03-8404-05-84 04-05-8404-06-84

    04-06-8404-10-8404-16-84 04-16-8404-17-84

    04-17-8404-24-8405-01-8405-08-8405-16-84

    __

    __

    __ 24

    21

    24

    28282623

    22

    16

    __2219

    19

    _

    22252421

    Alum- inum, Alum- total inum, recov- dis- erable solved

    as Al) as Al)

    --

  • Table 3.--Physical characteristics and concentrations of chemical constituents ofstreamflow at station number 01174565, West Branch Swift River near Shutesbury, Massachusetts-Continued

    Date

    11-01-8311-08-8311-15-8311-22-8311-29-83

    12-06-8312-13-8312-20-8312-27-8301-03-84

    01-10-8401-17-8401-24-8401-27-8401-31-84

    02-05-84 02-05-8402-07-8402-14-8402-15-84

    02-16-84 02-16-8402-17-8402-21-8402-28-84

    03-06-8403-13-8403-20-8403-27-84 03-27-84

    04-03-8404-03-8404-05-84 04-05-8404-06-84

    04-06-8404-10-8404-16-8404-16-8404-17-84

    04-17-8404-24-8405-01-8405-08-8405-16-84

    Manga- nese, Manga-

    Lead, total nese, dis- recov- dis- solved erable solved (jlg/L (jig/L (M-g/L as Pb) as Mn) as Mn)

    0.85.8.3.9.1 60

    .5

    .9 50

    .73.9.4

    1.5.3

    9.05.81.6

    1.4 50

    4.2.3.8

    1.5

    1.6 100.8.7

    .8

    .81.1.7

    .6

    .4 90

    1.0 80

    1.4.7 40

    .4

    _ _.6

    1.4

    2515256855

    3545404335

    2826223830

    49 2 21

    454153

    120 2 96

    996539

    32263438

    2 27

    342 34

    2 21 2 50

    762 47

    2734

    233

    37

    2 37

    31262833

    Mercury, Sele- Vana- Carbon, total Mercury, Sele- nium, dium, Carbon, organic, recov- dis- nium, dis- dis- organic dis- erable solved total solved solved total solved (jig/L (jig/L (jig/L (jig/L (fig/L (mg/L (mg/L as Hg) as Hg) as Se) as Se) as V) as C) as C)

    0.2

  • Table 3.-Physical characteristics and concentrations ofchtmical station number 01174565, West Branch Swift River near Shutesbury

    constituents of stream/low at , Massachusetts Continued

    Date

    05-22-84 105-29-8405-30-8405-30-84 205-31-84

    06-05-8406-12-8406-19-8406-26-8407-03-84

    07-10-8407-17-8407-24-8407-31-8408-07-84

    08-14-8408-21-8408-28-84 109-04-8409-11-84

    09-18-8409-25-84 110-02-8410-09-8410-16-84 1

    10-23-8410-30-8411-06-8411-13-8411-20-84

    11-27-84 112-05-8412-11-84 112-18-8412-26-84

    01-02-8501-08-8501-16-8501-22-8501-29-85 1

    02-05-8502-13-8502-19-8502-25-8503-05-85

    Time

    1416101009

    1515141113

    1209131310

    1413151413

    1314140913

    1512101414

    0909091312

    1013111312

    1315140909

    :00:45:30:40:30

    :30:00:30:00:45

    :30:45:30:00:00

    :15:45:00:15:15

    :45:00:45:30:00

    :00:30: 15: 15:15

    :30:30:45:00:45

    :30:30:00:00:45

    :00-.30

    :00:30:30

    Stream- flow,

    instan- taneous (ft3 /s)

    22193753

    630

    602017106.

    21196.4.2.

    2.3.1.2.1.

    1.

    151.1.

    3.3.

    27236.

    4.6.5.

    1619

    31127.4.1.

    2.369.

    4016

    8

    898

    34693

    39

    73

    33

    6

    468

    419

    5

    9

    Spe- cific con- duct- ance (flS/cm)

    352223

    22

    2937404244

    3130363845

    46364541

    4749374347

    4037323337

    4439393435

    34 423835

    3939353036

    pH (stand- Temper- ard ature

    units) (°C) C

    655

    5

    66666

    66666

    66666

    66666

    66556

    66655

    56666

    66656

    .4 14.5

    .6 11.5

    .1 10.5

    .1 10.5

    .1 14.5

    .5 17.5

    .7 17.0

    .8 14.0

    .6 17.0

    .0 17.0

    .1 16.5

    .6 20.0

    .5 17.5

    .6 18.0

    .5 20.0

    .6

    .8 17.0

    .7 13.0

    .8

    .8 10.0

    .8 15.0

    .4 9.0

    .6 9.0

    .7 9.0

    .5 12.5

    .4 10.0

    .6 7.5

    .8 7.0

    .0 1.0

    .1 1.0

    .4 .5

    .2 1.0

    .9 2.5

    .9 .5

    .8 2.5

    .3 .5

    .1 .5

    .1 .5

    .3 .5

    .3 .5

    .1 .5

    .1 1.0

    .6 1.0

    .2 .0

    ^ard- Calcium, less dis- (mg/L solved as (mg/L aC03 ) as Ca)

    7 2.25 1.65 1.4

    4 1.3

    6 1.98 2.38 2.49 2.79 2.6

    7 1.97 2.18 2.4

    __ 10 3.1

    11 3.212 3.58 2.59 2.8

    10 3.0

    8 2.5 7 2.18 2.3

    9 2.68 2.48 2.38 2.27 2.2

    7 2.18 2.49 2.68 2.58 2.4

    9 2.68 2.58 2.37 2.08 2.3

    Magne- sium, dis- solved (mg/L

    as Mg)

    0.48.36.33

    .29

    .35

    .45

    .50

    .59

    .55

    .43

    .41

    .47

    .58

    .61

    .69

    .49

    .56

    .67

    .51

    .45

    .50

    .54

    .55

    .51

    .57

    .48

    .45

    .45

    .54

    .52

    .52

    .57

    .52

    .45

    .43

    .53

    Sodium, dis- solved (mg/L

    as Na)

    311

    1

    23334

    223

    --4

    45334

    3 22

    33322

    22223

    33323

    .0

    .8

    .5

    .5

    .3

    .2

    .4

    .9

    .0

    .6

    .6

    .5

    .6

    .6

    .4

    .0

    .9

    .2

    .3

    .5

    .9

    .3

    .3

    .0

    .9

    .8

    .6

    .7

    .9

    .9

    .0

    .1

    .4

    .0

    .6

    .0

    See footnotes at end of table.

    22

  • Table 3. Physical characteristics and concentrations of chemical constituents ofstreamflow at station number 01174565, West Branch Swift River near Shutesbury, Massachusetts-Continued

    Date

    05-22-8405-29-8405-30-8405-30-8405-31-84

    06-05-8406-12-8406-19-8406-26-8407-03-84

    07-10-8407-17-8407-24-8407-31-8408-07-84

    08-14-8408-21-8408-28-8409-04-8409-11-84

    09-18-8409-25-84 10-02-8410-09-8410-16-84

    10-23-8410-30-8411-06-8411-13-8411-20-84

    11-27-8412-05-8412-11-8412-18-8412-26-84

    01-02-85 01-08-8501-16-8501-22-8501-29-85

    02-05-8502-13-8502-19-8502-25-8503-05-85

    Potas- sium, dis-solved (mg/L as K)

    0.37.29.33

    .28

    .29

    .38

    .41

    .44

    .48

    .28

    .33

    .36

    _

    .67

    .623 l"l 6

    .76

    .773 1.5

    .56

    .47

    .54

    .49

    .44

    .38

    .40

    .35

    .45

    .42

    .44

    .44

    .43

    .57

    .43

    .39

    .39

    Nitro- Nitro- gen, gen, ammonia,

    ammonia dis-total solved (mg/L (mg/L as N) as N)

    Alka- linity field(mg/L as

    CaC03 )

    1.4.6.2

    .32.74.1 4.3

    .52.12.81.86.4

    5.73.55.75.56.1

    5.76.3 2.63.95.5

    3.12.7.4.6

    1.3

    2.02.01.91.01.0

    .61.42.12.32.1

    2.51.01.4.6

    1.2

    Sulfate, dis-solved (mg/L as S04 )

    7.15.95.1 5.6

    7.26.76.86.96.8

    6.26.26.0

    _ 6.8

    7.07.1 7.56.76.9

    7.1 7.27.3

    8.38.37.27.37.8

    4 3l' 9

    8.27.57.5

    4 1.5

    8.47.66.67.8

    Nitro- gen,

    nitrate, dis-solved (mg/L as N)

    __

  • -Physical characteristics and concentrations of chemical constituents ofstr*Table 3.--.station number 01174565, West Branch Swift River near Shutc.sbury

    earn/low at , Massachusetts Continued

    Solids, sum of consti- tuents,

    dis- Date solved

    (mg/L)

    05-22-8405-29-8405-30-8405-30-8405-31-84

    06-05-8406-12-8406-19-8406-26-8407-03-84

    07-10-8407-17-8407-24-8407-31-8408-07-84

    08-14-8408-21-8408-28-8409-04-8409-11-84

    09-18-8409-25-8410-02-8410-09-8410-16-84

    10-23-8410-30-8411-06-8411-13-8411-20-84

    11-27-8412-05-8412-11-8412-18-8412-26-84

    01-02-8501-08-8501-16-8501-22-8501-29-85

    02-05-8502-13-8502-19-8502-25-8503-05-85

    __

    1815

    222729

    30

    222427

    33

    3437

    2932

    29

    2426

    2929272626

    2453292928

    2029262232

    Alum- inum, Alum- Copper, total inum, Arsenic, total recov- dis- dis- Arsenic, recov- erable solved solved total erable (jig/L (jig/L (jig/L (jig/L (jig/L as Al) as Al) as As) as As) as Cu)

    60

  • Table ^.-Physical characteristics and concentrations of chemical constituents of stream/low at station number 01174565, West Branch Swift River near Shutesbury, Massachusetts-Continued

    Date

    05-22-8405-29-8405-30-8405-30-8405-31-84

    06-05-8406-12-8406-19-8406-26-8407-03-84

    07-10-8407-17-8407-24-8407-31-8408-07-84

    08-14-8408-21-8408-28-8409-04-8409-11-84

    09-18-8409-25-8410-02-8410-09-8410-16-84

    10-23-8410-30-8411-06-8411-13-8411-20-84

    11-27-8412-05-8412-11-8412-18-8412-26-84

    01-02-8501-08-8501-16-8501-22-8501-29-85

    02-05-8502-13-8502-19-8502-25-8503-05-85

    Lead, dis- solved(mr/Las Pb)

    0.3

    .6

    .4

    .7

    .8

    .4

    .71.71.2

    .8

    .61.51.4.6

    .4

    .8

    .6

    .6

    .1

    .1

    .6

    .3

    .1

    .22.6.1.7

    .4

    .91.0.8.1

    .1

    .5

    .2

    .1

    .1

    Manga- nese, total recov- erable(|ig/L as Mn)

    __

    120

  • Table ^.--Physical characteristics and concentrations ofcht'micai station number 01174565, West Branch Swift River near Shlttesbury

    constituents ofstreamflow at , Massachusetts-ContiToiod

    Date Time

    Stream- flow,

    instan- taneous(ft j /s)

    03-12-8503-19-8503-26-8504-02-8504-09-85

    04-16-8504-23-8504-30-8505-07-8505-14-85

    05-21-8505-28-8506-04-85J-06-11-85 106-18-85

    06-25-8507-02-8507-10-85 107-16-8507-23-85

    07-30-85 107-30-85 108-07-8508-13-8508-20-85

    08-26-8509-04-8509-10-85

    09:4510:3016:0013:3013:00

    11:3014:3013:1512:3013:15

    12:3013:1513:3014:0013:00

    14:3013:3013:0013:3014:00

    12:1513:1510:4512:3016:00

    15:4511:4514:45

    10034202326

    14108

    147

    11854

    15

    54221

    2 215

    206

    .6

    .4

    .6

    .6

    .1

    .5

    .5

    .6

    .5

    .1

    .6

    .6

    .7

    .2

    .2

    Spe- cific con- duct- ance(}iS/cm)

    2733343335

    3738 3743

    3441414541

    4639474556

    50 485139

    323632

    PH (stand- ard

    units)

    5.46.26.46.36.2

    6.46.56.66.56.6

    6.46.46.66.16.6

    6.66.56.66.86.8

    6.7 6.66.86.3

    6.06.26.1

    Temper- ature(°C)

    2.0.5

    4.04.06.0

    Hard- ness (mg/L as

    CaC03 )

    67 77

    9.5 812.0 812.0 910.0 517.0 9

    14.0 814.515.5

    9

    16.015.5 i 9

    14.59

    20.010

    17.0

    17.0 119

    15.515.0 1019.0

    16.5 716.015.0

    Calcium, dis- solved (mg/L

    as Ca)

    12 22

    22212

    2__2

    2

    2

    3

    32 3

    2

    .7

    .2

    .1

    .2

    .4

    .4

    .7

    .5

    .6

    .4

    .7

    .6

    .7

    .0

    .5

    .7

    .2

    .1

    Magne- sium, dis- solved (mg/L

    as Mg)

    0.37.44

    __.42.44

    .51

    .53

    .46

    .31

    .52

    .52__

    .53

    .54

    .53

    .59

    .60

    .46

    .59

    .40

    Sodium, dis- solved (mg/L

    as Na)

    1.92.6 2.73.0

    3.23.53.82:i3.8

    3.1__3.8 3.7

    3.5 4.0

    5.13.8 4.6

    2.3

    See footnotes at end of table.

    26

  • Table 3.--Physical characteristics and concentrations of chemical constituents ofstreamflow at station number 01174565, West Branch Swift River near Shutesbury, Massachusetts-Continued

    Date

    03-12-8503-19-8503-26-8504-02-8504-09-85

    04-16-8504-23-8504-30-8505-07-8505-14-85

    05-21-8505-28-8506-04-8506-11-8506-18-85

    06-25-85 07-02-8507-10-8507-16-8507-23-85

    07-30-8507-30-8508-07-8508-13-8508-20-85

    08-26-8509-04-8509-10-85

    Nitro-Potas- Nitro- gen, sium, gen, ammonia, dis- ammonia dis-solved total solved (mg/L (mg/L (mg/L as K) as N) as N)

    0.59 0.13.40

  • Table 3. Physical characteristics and concentrations of chemical constituents of stream/low at station number 01174565, West Branch Swift River near Shi^tesbury, Massachusetts-Continued

    Date

    03-12-85 03-19-85 03-26-85 04-02-85 04-09-85

    04-16-85 04-23-8504-30-85 05-07-85 05-14-85

    05-21-8505-28-85 06-04-8506-11-85 06-18-85

    06-25-85 07-02-8507-10-85 07-16-8507-23-85

    07-30-8507-30-8508-07-85 08-13-8508-20-85

    08-26-8509-04-8509-10-85

    Solids, Alum-sum of inum, consti- total tuents, recov-

    dis- erablesolved ((Ag/L (mg/L) as Al)

    21 23

    14 25

    24 2526 15 26

    23

    27

    27

    41

    30

    33

    30

    21

    Alum- Copper, inum, Arsenic, total dis- dis- Arsenic, recov-solved solved total erable(flg/L (Jlg/L (flg/L (^g/L as Al) as As) as As) as Cu)

    2 260 2

  • Table 3. Physical characteristics and concentrations of chemical constituents ofstreamflow at station number 01174565, West Branch Swift River near Shutesbury, Massachusetts-Continued

    Date

    03-12-8503-19-8503-26-8504-02-8504-09-85

    04-16-8504-23-8504-30-8505-07-8505-14-85

    05-21-8505-28-8506-04-8506-11-8506-18-85

    06-25-8507-02-8507-10-8507-16-8507-23-85

    07-30-8507-30-8508-07-8508-13-8508-20-85

    08-26-8509-04-8509-10-85

    Manga- nese,

    Lead, total dis- recov- solved erable(flg/L (flg/L as Pb) as Mn)

    0.8.5

  • Table ^.--Physical characteristics and concentrations ofche^nical constituents ofstreamflow at station number 01174555, West Branch Swift River near Cooleyville, Massachusetts

    [ft /s, cubic feet per second; |iS/cm, microsiemens per centimeter, °C, degrees Celsius: mg/L, milligrams per liter, Jig/L, micrograms per liter,

  • Table 4.-Physical characteristics and concentrations of chemical constituents of stream/low at station number 01174555, West Branch Swift River near Cooleyville, Massachusetts Continued

    Date

    04-05-84 04-05-8405-30-84 05-30-8408-28-84

    09-11-8410-02-8410-17-8412-18-8404-30-85

    05-07-8505-28-8506-25-8507-23-8508-07-8508-26-85

    Solids,sum of constit- uents, dis-

    solved (mg/L)

    ~

    14

    __

    _

    Alum-inum, total recov- erable

    as Al)

    90

    200

    _

    Alum- Copper, inum, Arsenic, total dis- dis- Arsenic, recov- solved solved total erable

    as Al) as As) as As) as Cu)

    1 150

    1290

    80

  • Table 5.--Physical characteristics and concentrations of chewed constituents ofstreamflow atstation number 01174560, West Branch Swift River al Cooleyville, Massachusetts

    [ft /s, cubic feet per second; (iS/cm, microsiemens per centimeter at 25 degrees Celsius; °C, degrees Celsius; mg/L, milligrams per liter, (ig/L, micrograms per

    liter,

  • Table 5.-Physical characteristics and concentrations of chemical constituents of stream/low at station number 01174560, West Branch Swift River at Cooleyville, Massachusetts Continued

    Date

    04-05-84 04-05-8404-06-8405-30-84 05-30-84

    08-28-8409-11-8410-02-8410-17-8412-19-84

    04-30-8505-28-8506-25-8507-23-8508-07-8508-26-85

    Solids, sum of constit- uents, dis-solved (mg/L)

    16

    __

    _ 20

    Alum- inum, total recov- erable

    as Al)

    240

    _20

    160

    _

    Alum- inum, dis- solved

    as Al)

    180 1 140

    1280

    __10

    160

    __

    190

    Copper, Arsenic, total Copper,

    dis- Arsenic, recov- dis- solved total erable solved

    as As) as As) as Cu) as Cu)

    11 1 2.0

    :: :: :: ::__ _ __ __

  • Table 6.--Physical characteristics and concentrations of chemical constituents of stream/low at station number 01174563, West Branch Swift River tributary a! Cooleyville, Massachusetts

    [ft3/s, cubic feet per second; \iSlcm, microsiemens per centimeter at 25 decrees Celsius; °C, degrees Celsius; mg/L,

    milligrams per liter; Jig/L, micrograms per liter,

  • Table 6. Physical characteristics and concentrations of chemical constituents ofstreamflow at station number 01174563, West Branch Swift River tributary at Cooleyville, Massachusetts Continued

    Solids,sum of consti- tuents,

    dis-Date solved

    (mg/L)

    04-05-84 16 04-05-8404-06-84 1405-30-84 05-30-84

    08-28-8409-11-8410-02-8410-17-8412-19-84

    04-30-8505-28-8506-25-8507-23-8508-07-8508-26-85 18

    Alum-inum, Alum- Copper, Iron, total inum, Arsenic, total Copper, total recov- dis- dis- Arsenic, recov- dis- recov- erable solved solved total erable solved erable(H-g/L (M-g/L (M-g/L (p.g/L ((ig/L (p.g/L (p.g/L as Al) as Al) as As) as As) as Cu) as Cu) as Fe)

    320 150

  • -Physical characteristics and concentrations of chemical constituents ofstr

  • Table 7. Physical characteristics and concentrations of chemical constituents of stream/low at station number 01174564, West Branch Swift River tributary 2 at Cooleyville, Massachusetts Continued

    Solids,sum of consti- tuents,

    dis-Date solved

    (mg/L)

    04-05-84 4104-05-8404-06-84 3805-30-84 05-30-84

    08-28-8409-11-8410-02-8410-17-8412-18-84 66

    04-30-8505-28-8506-25-8507-23-8508-07-8508-26-85 56

    Alum-inum, total recov-erable

    as Al)

    600

    __20

  • Table ^.--Physical characteristics and concentrations ofchenical constituents of ground water at station number 422800072232901, Swift River till well mar Cooleyville, Massachusetts

    [|iS/cm, microsiemens per centimeter at 25 degrees Celsius; °C, degrees Celsius; mg/L, milligrams per liter, |ig/L, micrograms per liter,

  • Table 9.--Physical characteristics and concentrations of chemical constituents of ground water at station number 422803072231801 , Swift River sand and gravel well near Cooleyville, Massachusetts

    [flS/cm, microsiemens per centimeter at 25 degrees Celsius; °C, degrees Celsius; mg/L, milligrams per liter; |ig/L, micrograms per liter,

  • Table 9. Physical characteristics and concentrations Oj number 422803072231801, Swift River sand and gravel well near

    if chemical constituents of ground water at station Cooleyville, Massachusetts-Continued

    Copper, Arsenic, dis- total solved

    Date (flg/L as As)

    12-20-8301-30-8402-28-8403-28-8404-25-84

    04-25-8406-06-8407-17-8409-12-84 110-24-84

    11-20-8412-20-8401-29-8502-19-8503-19-85

    04-10-8506-11-8508-20-85

    (flg/L as Cu)

    0.11.02.43.22.8

    1.6.2.2

    1.41.01.6

    .1 1.0

    Iron, dis- solved

    as Fe)

    10

  • Table 10. Daily mean discharge at station number 01174050, East Branch Fever Brooknear Petersham, Massachusetts

    [Period of record begins November 29,1983; (ft3/s)Ani2, cubic feet per second per square mile; dashes indicate not applicable]

    Discharge, in cubic feet per second, water year October 1983 to September 1984

    Day Oct

    12345

    6789

    10

    1112131415

    1617181920

    2122232425

    262728293031

    TotalMeanMaximumMinimum (ft 3 /s)mi 2 Inches

    Nov

    __

    __

    __ --

    __

    __ 3025

    __

    Dec

    1612119.19.9

    1126171413

    7.56.6

    214939

    221310108.3

    6.09.3

    12119.0

    9.07.79.2

    20149.7

    442.314.3496.02.572.96

    Jan

    8.38.27.87.37.1

    7.27.37.26.56.9

    7.16.85.06.45.1

    5.04.13.65.43.3

    3.33.73.35.0

    12

    119.77.55.26.16.1

    198.56.40

    123.31.151.33

    Feb

    4.03.74.0

    1417

    181211,118.2

    1013141325

    9760463938

    2921171921

    15141620

    629.921.7973.73.914.21

    Mar

    129.07.97.36.5

    11117.76.86.1

    5.33.93.26.85.7

    5.85.95.19.3

    14

    1626282016

    161416181715

    352.311.4283.22.042.36

    Apr

    1317191943

    10262362825

    2317151317

    2935221617

    1715141414

    1412108.69.0

    695.623.2

    1028.64.174.65

    May

    7.06.26.2

    1723

    1815132116

    1412172219

    1414141312

    129.18.79.28.5

    7.77.85.1

    45200185

    791.525.5

    2005.14.595.30

    June

    13093614228

    2122171210

    8.75.15.14.02.0

    2.72.72.73.42.2

    1.61.31.1.87

    1.4

    1.91.61.51.31.2

    488.3716.3

    130.87

    2.933.27

    July

    1.41.21.11.11.1

    1.111178.38.7

    7.64.92.21.81.6

    3.04.5

    233014

    128.96.85.82.0

    1.82.22.11.62.12.5

    192.46.21

    301.11.121.29

    Aug

    2.11.91.81.21.1

    1.1.97.77.68.61

    .60

    .48

    .45

    .54

    .70

    .28

    .32

    .55

    .421.1

    .82

    .,941.1.41.31

    .23

    .21

    .17

    .20

    .25

    .33

    22.64.73

    2.1.17.13.15

    Sept

    0.44.19.27.29.19

    .21

    .19

    .18

    .21

    .24

    .22

    .12

    .21

    .36

    .33

    .35

    .39

    .44

    .44

    .47

    .22

    .31

    .26

    .22

    .21

    .27

    .23

    .28

    .43

    .47

    8.64.29.47.12.05.06

    42

  • Table IQ. Daily mean discharge at station number 01174050, East Branch Fever Brook near Petersham, Massachusetts-Continued

    Discharge, in cubic feet per second, water year October 1984 to September 1985

    Day

    12345

    6789

    10

    1112131415

    1617181920

    2122232425

    262728293031

    TotalMeanMaximumMinimum(ft 3 /s)/mi2Inches

    Oct Nov

    .34 .57

    .73 .541.1 .671.1 .13.42 1.1

    .50 1.6

    .37 .54

    .38 1.3

    .38 1.7

    .16 1.8

    .23 2.6

    .21 11

    .11 8.7

    .38 7.2

    .08 4.9

    .16 6.9

    .11 5.6

    .18 2.4

    .23 2.1

    .22 2.4

    .30 2.5

    .50 2.1

    .63 2.3

    .44 1.7

    .47 1.4

    .59 1.2

    .62 1.31.8 1.8.59 1.8.61 1.3.62

    Dec

    1.91.4.88

    1.11.7

    4.04.12.92.72.3

    2.63.24.44.53.9

    3.76.16.15.56.3

    4.59.39.46.88.3

    7.25.96.76.24.85.0

    14.56 81.15 143.38.47 2.70

    1.8 11.08 .13.08 .49.10 .54

    Calendar year 1984 TotalWater year 1985 Total

    4.639.4.88.83.96

    3,6181,573

    Jan

    6.39.37.96.37.6

    5.15.04.72.23.3

    4.65.33.22.53.0

    2.83.33.83.41.8

    2.43.03.63.63.6

    2.41.82.01.61.31.4

    118.13.819.31.3.69.79

    .89

    .48

    Feb

    2.12.51.81.51.4

    1.92.31.82.02.1

    1.72.18.8

    117.6

    7.27.76.35.74.1

    3.04.34.98.0

    11

    7.78.67.5

    136.64.88

    111.4-.88.91

    Mean 9.89Mean 4.31

    Mar

    6.74.64.63.57.3

    6.35.25.97.46.0

    6.030492914

    12127.97.59.9

    6.58.48.28.35.7

    7.47.57.65.73.14.0

    307.29.91

    493.11.782.06

    MaximumMaximum

    Apr

    5.07.37.39.7

    11

    117.88.1

    1012

    118.77.57.07.9

    7.76.25.77.96.6

    5.35.54.02.94.1

    4.73.04.34.02.3

    --

    205.56.85

    122.31.231.37

    20049

    May

    2.12.02.05.36.0

    4.86.04.34.44.6

    3.61.93.01.91.7

    1.32.01.81.53.0

    1628119.27.7

    5.55.54.68.16.96.8

    172.55.56

    281.31.001.15

    MinimumMinimum

    June

    2717127.24.0

    6.06.24.65.9^5.9

    2.62.01.71.11.5

    1.84.85.83.31.5

    1.01.41.41.91.1

    .96

    .901.64.33.6

    140.064.67

    27.90.84.94

    .08 (ft 3

    July

    3.42.31.5.85.70

    .801.01.0.73.84

    .90

    .841.31.21.2

    .95

    .891.11.31.6

    1.11.51.0.86

    1.1

    2.42.41.31.41.4.91

    39.771.283.4.70.23.27

    /s)/mi2.08 (ft 3 /s)/mi2

    Aug

    4.13.83.52^.82.3

    2.52.13.93.12.7

    3.42.01.92.52.5

    13118.06.76.2

    3.82.11.41.12.0

    5.77.85.53.52.84.2

    Sept

    4.44.04.26.44.7

    4.33.34.43.22.2

    2.63.82.82.42.2

    2.01.71.51.51.3

    1.0.47.36.93.56

    .663.65.65.94.8-

    127.9 86.784.13

    131.1.74.86

    1.78 Inches.78 Inches

    2.896.4.36.52.58

    24.210.5

    43

  • Table \\.--Physical characteristics and concentrations of chemical constituents of stream/low at station number 01174050, East Branch Fever Brook n^ar Petersham, Massachusetts

    [ft3/s, cubic feet per second; fiS/cm, microsiemens per centimeter at 25 degrees Celsius; °C, degrees Celsius;

    mg/L^nilligrams per liter ; |ig/L, micrograms per liter;

  • Table 1 1.-Physical characteristics and concentrations of chemical constituents ofstreamflow at station number 01174050, East Branch Fever Brook near Petersham, Massachusetts Continued

    Date

    11-01-8311-08-8311-15-8311-22-8311-29-83

    12-06-8312-13-8312-20-8312-27-8301-03-84

    01-10-8401-17-8401-24-8401-27-8401-31-84

    02-05-8402-07-8402-14-8402-15-8402-16-84

    02-16-8402-17-8402-21-8402-28-8403-06-84

    03-13-8403-20-8403-27-8403-27-8404-03-84

    04-05-8404-06-8404-06-8404-10-8404-10-84

    04-17-8404-17-8404-24-8405-01-8405-08-84

    Nitro- Nitro- Phos- Potas- Nitro- gen, Alka- gen, phorus, Phos- Chlo- Fluo- Silica, sium, gen, ammonia, linity Sulfate, nitrate, ortho, phorus, ride, ride, dis- dis- ammonia dis- field dis- dis- dis- dis- dis- dis- solved solved total solved (mg/L solved solved solved solved solved solved (mg/L (mg/L (mg/L (mg/L as (mg/L (mg/L (mg/L (mg/L (mg/L (mg/L as as K) as N) as N) CaC03 ) as SOJ as N) as P) as P) as Cl) as F) Si02 )

    1.21.11.2.96.72

    .69

    .62

    .56

    .73

    .67

    .69

    .68

    .73

    .74

    .7

    .66

    .65

    .62

    .62

    .62

    .61.52.54.58

    .64

    .63

    .54

    .54

    .53

    .52

    .33

    .53

    .53

    .56

    .55

    0.03.06.14.06

  • Table \\.--Physical characteristics and concentrations of chemical constituents ofstreamflow at station number 01174050, East Branch Fever Brook near Petersham, Massachusetts--Continued

    Solids, sum of consti- tuents,

    dis- Date solved

    (mg/L)

    11-01-83 11-08-83 11-15-83 11-22-83 11-29-83

    12-06-83 12-13-83 12-20-83 12-27-83 01-03-84

    01-10-84 01-17-84 01-24-84 01-27-8401-31-84

    02-05-8402-07-8402-14-8402-15-8402-16-84

    02-16-8402-17-8402-21-8402-28-8403-06-84

    03-13-8403-20-8403-27-8403-27-8404-03-84

    04-05-8404-06-8404-06-8404-10-8404-10-84

    04-17-8404-17-8404-24-8405-01-8405-08-84

    __ _

    __ 33

    353627

    28

    __25 24

    25

    282628

    Alum- inum, Alum- total inum, recov- dis- erable solved (Jig/L (|J.g/L as Al) as Al)

    90 70 70

    110 130 110

    130 130 130

    100 10 90

    100 140 120 100110

    150 140805070

    160 80

    2 70

    110 801008070

    607080

    2 20

    90

    120 90100 100

    2 80- 1 1 n

    2 <

    70 60220

    20

    60

    Copper, Arsenic, total Copper,

    dis- Arsenic, recc^v- dis- solved total erable solved (|j.g/L (|J.g/L (fig/L (fig/L as As) as As) as Gu) as Cu)

    1 1

    1

    1

    0.2 2.0 5.2 3.1 .6

    .5

    .7

    .3 i- 1.2

    2.9

    1.2 5.4 1.7 5.2- -|

  • Table 11.-Physical characteristics and concentrations of chemical constituents of stream/low at station number 01174050, East Branch Fever Brook near Petersham, Massachusetts-Continued

    Date

    11-01-8311-08-8311-15-8311-22-8311-29-83

    12-06-8312-13-8312-20-8312-27-8301-03-84

    01-10-8401-17-8401-24-8401-27-8401-31-84

    02-05-8402-07-8402-14-8402-15-8402-16-84

    02-16-8402-17-8402-21-8402-28-8403-06-84

    03-13-8403-20-8403-27-8403-27-8404-03-84

    04-05-8404-06-8404-06-8404-10-8404-10-84

    04-17-8404-17-8404-24-8405-01-8405-08-84

    Manga- nese,

    Lead, total dis- recov- solved erable (jlg/L (jlg/L as Pb) as Mn)

    0.5.3.4

    1.1.4 50

    .7

    .8 501.0.3

    4.3

    4.413.02.96.51.9

    1.1 50.4

    1.31.01.0 60

    __1.2 90.6

    1.01.0

    1.2.9.7

    1.0

    1.1 20.9 40

    .3

    .6 30 1.1 1.2

    Manga- nese, dis- solved

    as Mn)

    3335375145

    5045474355

    5250537553

    5753414168

    2 8

    91583431

    3337

    o 25225

    21

    25o 342 34

    226

    26226

    313832

    Mercury, Sele- Vana- Carbon, total Mercury, Sele- nium, dium, Carbon, organic, recov- dis- nium, dis- dis- organic dis- erable solved total solved solved total solved (jig/L (jig/L (jig/L (jig/L (jig/L (mg/L (mg/L as Hg) as Hg) as Se) as Se) as V) as C) as C)

  • Table 1 1. Physical characteristics and concentrations of chemical constituents of stream/low at station number 01174050, East Branch Fever Brook near Petersham, Massachusetts-Continued

    Date

    05-16-84 105-22-8405-29-8405-30-8405-30-84 2

    05-31-8406-05-8406-12-8406-19-84 106-26-84 1

    07-03-84 107-10-8407-17-8407-24-8407-31-84

    08-07-84 108-14-8408-21-8408-28-84 109-04-84

    09-11-84 109-18-8409-25-8410-02-8410-09-84 1

    10-16-8410-23-8410-30-84 111-06-8411-13-84

    11-20-8411-27-8412-05-8412-11-8412-19-84

    12-26-8401-02-8501-08-8501-16-8501-22-85

    Time

    13:0009:0014:0016:1516:20

    16:0009:0010:0009:0014:30

    09:0010:0012:1511:0010:00

    12:1511:0010:3010:0010:00

    08:4508:3008:1509:0013:45

    14:3009:0008:0011:0010:00

    11:0013:0012:0013:0016:15

    09:3014:3009:3009:0009:30

    Stream-flow,

    instan-taneous(ft 3/s)

    147.1

    35177

    380253.63.02.2

    1.48.44.16.61.9

    .9

    .47

    .47

    .32

    .3

    .23

    .23

    .16

    .85

    .34

    .26

    .63

    .08

    .98.9

    2.11.61.72.64.8

    5.79.65.12.72.4

    Spe- cificcon-duct-ance(US/cm)

    49494339

    3434424441

    4343444140

    3934333536

    3738434544

    4848435258

    6777696862

    5948707265

    PH(stand-ard

    units)

    6.26.06.05.5

    5.45.55.65.65.7

    5.55.85.55.75.7

    5.75.55.85.75.9

    6.06.06.06.16.1

    6.36.26.26.26.1

    5.95.96.16.15.8

    5.85.95.95.95.9

    Temper-

    Hard-ness(mg/L

    ature as

  • Table II. Physical characteristics and concentrations of chemical constituents of stream/low at station number 01174050, East Branch Fever Brook near Petersham, Massachusetts-Continued

    Date

    05-16-8405-22-8405-29-8405-30-8405-30-84

    05-31-8406-05-8406-12-8406-19-8406-26-84

    07-03-8407-10-8407-17-8407-24-8407-31-84

    08-07-8408-14-8408-21-8408-28-8409-04-84

    09-11-8409-18-8409-25-8410-02-8410-09-84

    10-16-8410-23-8410-30-8411-06-8411-13-84

    11-20-8411-27-8412-05-8412-11-8412-19-84

    12-26-8401-02-8501-08-8501-16-8501-22-85

    Potas- sium, dis- solved (mg/L as K)

    0.54.45.56.53

    .48

    .35

    .47

    .52

    .46

    .48

    .58

    .45

    .37

    __

    .52

    .50

    .641.0.71

    .891.4 1.11.5

    1.21.21.01.0.85

    .85

    .77

    .85

    .921.0

    Nitro- Nitro- gen, gen, ammonia,

    ammonia dis- total solved (mg/L (mg/L as N) as N)

    0.252

  • Table 1 1. Physical characteristics and concentrations of chemical constituents of stream/low at station number 01174050, East Branch Fever Brook near Petersham, Massachusetts-Continued

    Solids, sum of consti- tuents,

    dis- Date solved

    (mg/L)

    05-16-8405-22-8405-29-8405-30-84 05-30-84

    05-31-8406-05-8406-12-8406-19-8406-26-84

    07-03-8407-10-8407-17-8407-24-8407-31-84

    08-07-8408-14-8408-21-8408-28-8409-04-84

    09-11-8409-18-8409-25-8410-02-8410-09-84

    10-16-8410-23-8410-30-8411-06-8411-13-84

    11-20-8411-27-8412-05-8412-11-8412-19-84

    12-26-84 01-02-85 01-08-85 01-16-85 01-22-85

    26262522

    2122242524

    24262323

    __

    _28303231

    3334 34

    3640353538

    34 32 38 44 57

    Alum- inum, Alum- Coppe: total inum, Arsenic, tota! recov- dis- dis- Arsenic, recoi erable solved solved total crab! (jig/L ((ig/L (Jig/L (fig/L (jig/1 as Al) as Al) as As) as As) as Ci

    _ __ _ __ _70

  • Table 1 l.-Physical characteristics and concentrations of chemical constituents ofstreamflow at station number 01174050, East Branch Fever Brook near Petersham, Massachusetts Continued

    Lead, dis- solved

    Date (^lg/L as Pb)

    05-16-8405-22-8405-29-8405-30-8405-30-84

    05-31-8406-05-8406-12-8406-19-8406-26-84

    07-03-8407-10-8407-17-8407-24-8407-31-84

    08-07-8408-14-8408-21-8408-28-8409-04-84

    09-11-8409-18-8409-25-8410-02-8410-09-84

    10-16-8410-23-8410-30-8411-06-8411-13-84

    11-20-8411-27-8412-05-8412-11-8412-19-84

    12-26-8401-02-8501-08-8501-16-8501-22-85

    __ 1

  • Table 1 \.~Physical characteristics and concentrations of chemical constituents of streamflow at station number 01174050, East Branch Fever Brook near Petersham, Massachusetts-Continued

    Date

    01-29-85 102-05-8502-13-8502-19-85 102-25-85

    03-05-8503-12-8503-19-8503-26-8504-02-85

    04-09-8504-16-8504-23-85 104-30-8505-07-85

    05-14-85 105-21-8505-28-8506-04-8506-11-85

    06-18-8506-25-85 107-02-8507-10-8507-16-85

    07-23-85 107-30-85 108-08-8508-13-8508-20-85

    08-27-8509-04-8509-10-85

    Time

    09:3009:3016:4509:3015:45

    13:3011:3014:3009:0009:45

    10:0009:3010:1509:3009:15

    09:3008:3008:0009:0009:15

    09:3016:3009:0014:1509:30

    10:1009:1509:0009:1519:30

    09:0009:0009:30

    Stream-flow,

    instan-taneous(ft 3 /s)

    0.961.3

    113.9

    13

    7.129116.06.7

    115.71.92.24.6

    1.31.82.96.62.4

    5.1.9

    2.4.8.95

    .48

    .531.4.62

    4.2

    7.05.54.0

    Spe- cificcon-duct-ance(US /cm)

    7069616953

    57 545052

    5557595957

    6058505658

    5458576558

    5654566364

    656857

    pH(stand-ard

    units)

    6.06.16.06.15.8

    6.05.95.76.06.0

    6.05.96.06.26.1

    6.16.05.75.75.6

    5.85.55.75.75.7

    5.85.95.65.75.6

    5.75.65.7

    Temper-ature

  • Table 11. -Physical characteristics and concentrations of chemical constituents of stream/low at station number 01174050, East Branch Fever Brook near Petersham, Massachusetts-Continued

    Nitro- Potas- Nitro- gen, sium, gen, ammonia, dis- ammonia dis- solved total solved

    Date (mg/L (mg/L (mg/L as K) as N) as N)

    01-29-8502-05-8502-13-8502-19-8502-25-85

    03-05-8503-12-8503-19-8503-26-8504-02-85

    04-09-8504-16-8504-23-8504-30-8505-07-85

    05-14-8505-21-8505-28-8506-04-8506-11-85

    06-18-8506-25-8507-02-8507-10-8507-16-85

    07-23-8507-30-8508-08-8508-13-8508-20-85

    08-27-8509-04-8509-10-85

    1.0.91.95.90.77

    .70

    .66

    .64_

    .65

    .68

    .68

    .73

    .76

    .25

    .72

    .61

    .51

    .48__

    .61

    .46

    __.39

    .49

    .56

    0.16.16.14.08.09

  • Table \\.--Physical characteristics and concentrations of chemical constituents of stream/low at station number 01174050, East Branch Fever Brook near Petersham, Massachusetts Continued

    Date

    01-29-8502-05-8502-13-8502-19-8502-25-85

    03-05-8503-12-8503-19-8503-26-8504-02-85

    04-09-8504-16-8504-23-8504-30-8505-07-85

    05-14-8505-21-8505-28-8506-04-8506-11-85

    06-18-8506-25-8507-02-8507-10-8507-16-85

    07-23-8507-30-8508-08-8508-13-8508-20-85

    08-27-8509-04-8509-10-85

    Solids, sum of consti- tuents,

    dis-solved(mg/L)

    4539

    24

    312630__14

    3029302917

    3030__32

    30__22__31

    __31 32

    31

    Alum- inum, Alum- Copper total inum, Arsenic, total recov- dis- dis- Arsenic, recoverable solved solved total erabl(H-g/L (H-g/L (H-g/L (\ig/L (^g/Las Al) as Al) as As) as As) as Cu

    f

    Copper, dis-

    3 solved(Hg/Las Cu)

    2 220 0.62 220

    ___ 2-yg __ __ ___

    2 802 100

    2 80__ 2-yg __ __ __

    2 300

    -- 80 -- --

    5.02.11.61.4

    1.71.11.3.5

    2 80 .6

    2 70 1.72 60 .82 70 - - -- .12 90

  • Table 11.-Physical characteristics and concentrations of chemical constituents ofstreamflow at station number 01174050, East Branch Fever Brook near Petersham, Massachusetts Continued

    Date

    01-29-8502-05-8502-13-8502-19-8502-25-85

    03-05-8503-12-8503-19-8503-26-8504-02-85

    04-09-8504-16-8504-23-8504-30-8505-07-85

    05-14-8505-21-8505-28-8506-04-8506-11-85

    06-18-8506-25-8507-02-8507-10-8507-16-85

    07-23-8507-30-8508-08-8508-13-8508-20-85

    08-27-8509-04-8509-10-85

    Manga- nese,

    Lead, total dis- recov- solved erable (Hg/L (jig/L as Pb) as Mn)

    0.1.1.7.3.1

    1.0.8.6.7

    1.0

    1.4.4.3

    1.0

    1.0

  • Table l2.-Physical characteristics and concentrations of chemical constituents of stream/low at station number 01174035, Brooks Pond tributary near Petersham, Massachusetts

    [ft3/s, cubic feet per second; (iS/cm, microsiemens per centimeter at 25 degrees Celsius; °C, degrees Celsius; mg/L, milligrams per liter, mg/L, micrograms per liter,

  • Table ll. Physical characteristics and concentrations of chemical constituents ofstreamflow at station number 01174035, Brooks Pond tributary near Petersham, Massachusetts Continued

    Date

    02-16-8404-06-8405-30-84 05-30-8408-28-84

    09-11-8410-02-8410-17-8412-19-8404-30-85

    05-28-8506-25-8507-23-8508-08-8508-27-85

    Solids,sum of consti- tuents,

    dis-solved (mg/L)

    __20

    :: __ _ 22

    Alum-inum, total recov-erable

    as Al)

    220

    90

    See footnote at end of table.

    Lead, dis- solved

    Date

    Manga-nese,totalrecov-erable

    Manga- nese, dis- solved

    Mercury, total recov- erable

    Mercury,dis- solved

    Sele- nium, total

    Sele- nium, dis- solved

    as Pb) as Mn) as Mn) as Hg) as Hg) as Se) as Se)

    Vana- Carbon,dium, Carbon, organic,dis- organic dis- solved total solved (flg/L (mg/L (mg/L as V) as C) as C)

    02-16-8404-06-8405-30-84 05-30-84 08-28-84

    1.1 140 1406450

    0.2 1.1

    5.0

    09-11-8410-02-84 10-17-84 12-19-84 04-30-85

    .4

    .2

    150

    30

    96

    30

    6.4

    3.5

    05-28-8506-25-8507-23-8508-08-85 08-27-85 33 7.2

    Sample filtered through 0.1 micrometer pore filter,

    57

  • Table 13.-Physical characteristics and concentrations of chemical constituents ofstreamflow at station number 01174040, East Branch Fever Brook, below Brooks Pond near Petersham, Massachusetts

    [ft3/s, cubic feet per second; (oS/cm, microsiemens per centimeter at 25 degrees Celsius; °C, degrees Celsius; mg/L, milligrams per liter; |ig/L, micrograms per liter,

  • Table l3.--Physical characteristics and concentrations of chemical constituents of stream/low at station number 01174040, East Branch Fever Brook below Brooks Pond near Petersham, Massachusetts-Continued

    Solids,sum ofconsti-tuents,

    dis-Date solved

    (mg/L)

    02-16-84 2803-27-8404-06-8404-06-8404-10-84

    04-17-8405-30-8405-30-8408-28-8409-11-84

    10-02-8412-19-84 3204-30-8505-28-8506-25-85

    07-23-8508-08-8508-27-85 34

    See footnote

    Lead,dis-solved

    Date (|ig/Las Pb)

    02-16-84 1.003-27-8404-06-8404-06-8404-10-84

    04-17-8405-30-8405-30-8408-28-8409-11-84 1.0

    10-02-8412-19-84 .404-30-8505-28-8506-25-85

    07-23-8508-08-8508-27-85

    Alum-inum,totalrecov-erable(|lg/Las Al)

    170

    70

    130

    at end of

    Manga- nese,totalrecov-erable(Hg/Las Mn)

    110

    30

    20

    Alum- Copper,inum, Arsenic, totaldis- dis- Arsenic, recov-solved solved total erable(jig/L (|ig/L (|ig/L (fig/Las Al) as As) as As) as Cu)

    100

  • Table 14. Physical characteristics and concentrations of chemical constituents ofstreamflow at station number 01174045, East Branch Fever Brook at West Road near Petersham, Massachusetts

    [ft3/s, cubic feet per second; fiS/cm, microsiemens per centimeter at 25 degrees Celsius; °C, degrees Celsius; mg/L, milligrams per liter; |lg/L, micrograms per liter;