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11/23/13 Waterproof breathable fabrics: Technologies and practices www.textiletoday.com.bd/magazine/print/746 1/5 Technical Review Issue: October , 2013 Waterproof breathable fabrics: Technologies and practices Laga S.K. Vignesh Dhanabalan and Joshi Rashmi M. D.K.T.E.S Textile & Engineering Institute, Ichalkaranji-416115(M.H), India Email: [email protected], [email protected], [email protected] This article is published in two parts, this is the second part. Please continue reading from the previous issue. 6. Method employed for application of coating The lamination process has to be chosen carefully to ensure that the breathability of the laminate is maintained at a high level. There are four main methods of incorporating membranes into textile Laminate of membrane and outer fabric Liner or insert processing Laminate of membrane and lining fabric Laminate of outer fabric, membrane and lining 6.1 Laminating Laminating waterproof breathable fabrics are made by application of membranes onto textile product. They are thin membrane made from polymeric materials that offer high resistance to water penetration but allow water vapor at the same time. The maximum pore size of the membrane is around 10 micron. They are of two types: 1) Micro porous membranes 2) Hydrophilic membranes Micro porous membranes have tiny holes on their surface smaller than a rain drops but larger than water vapor molecule. Some of the membranes are made from Polytetrafluroethylene (PTFE) polymer, Polyvinylidene fluoride (PVDF) etc,. The hydrophilic membranes are thin films of chemically modified polyester or polyurethane. The poly (ethylene oxide) constitutes hydrophilic part of the membrane by forming amorphous region in the main polymer system. This amorphous region acts as intermolecular pores allowing water vapor molecules to pass through but, preventing the penetration of liquid water due to the solid nature of the membrane. Fig 4: Laminated waterproof breathable fabrics 7. Breathable, Permanent Water-Repellent Treatment of Cotton Rudolph d. Deanin made etherification on cotton to determine Breathable permanent Water-Repellent Treatment and stated that cotton fiber or fabric treated commercially with long chain aliphatic acid chlorides in hot organic amine baths by a rapid economical process. To cause low degrees of etherification and produce good water repellency and dry-cleaning resistance, with no loss of vapor permeability was observed [8]. 8. Nano web on water proof and breathability Hae Wook Ahn et al studied and compared the waterproof and breathable properties of clothing made from an electrospun nanoweb and conventional coating of PTFE, and have stated results that, the Nano web laminate had a higher water vapor transmission rate but lower water resistance than the polytetrafluroethylene laminate. The water penetration tests carried suggested that water resistances are sufficient enough to prevent wetting by rain. The wearing test revealed that Nano web laminated clothing provided more comfortable clothing-microclimate than polytetrafluroethylene laminated clothing in normal warm environment. In the

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Page 1: Waterproof breathable fabrics  technologies and practices 2

11/23/13 Waterproof breathable fabrics: Technologies and practices

www.textiletoday.com.bd/magazine/print/746 1/5

TechnicalReview Issue: October ,

2013

Waterproof breathable fabrics: Technologies and practices

Laga S.K. Vignesh Dhanabalan and Joshi Rashmi M.

D.K.T.E.S Textile & Engineering Institute, Ichalkaranji-416115(M.H), India

Email: [email protected], [email protected], [email protected]

This article is published in two parts, this is the second part. Please continue reading from the previous issue.

6. Method employed for application of coating

The lamination process has to be chosen carefully to ensure that the breathability of the laminate is maintained at a high level.

There are four main methods of incorporating membranes into textile

Laminate of membrane and outer fabricLiner or insert processing

Laminate of membrane and lining fabricLaminate of outer fabric, membrane and lining

6.1 Laminating

Laminating waterproof breathable fabrics are made by application of membranes onto textile product. They are thin membrane

made from polymeric materials that offer high resistance to water penetration but allow water vapor at the same time. Themaximum pore size of the membrane is around 10 micron. They are of two types:

1) Micro porous membranes 2) Hydrophilic membranes

Micro porous membranes have tiny holes on their surface smaller than a rain drops but larger than water vapor molecule. Some of

the membranes are made from Polytetrafluroethylene (PTFE) polymer, Polyvinylidene fluoride (PVDF) etc,. The hydrophilicmembranes are thin films of chemically modified polyester or polyurethane. The poly (ethylene oxide) constitutes hydrophilic part of

the membrane by forming amorphous region in the main polymer system. This amorphous region acts as intermolecular pores

allowing water vapor molecules to pass through but, preventing the penetration of liquid water due to the solid nature of themembrane.

Fig 4: Laminated waterproof breathable fabrics

7. Breathable, Permanent Water-Repellent Treatment of Cotton

Rudolph d. Deanin made etherification on cotton to determine Breathable permanent Water-Repellent Treatment and stated that

cotton fiber or fabric treated commercially with long chain aliphatic acid chlorides in hot organic amine baths by a rapid economical

process. To cause low degrees of etherification and produce good water repellency and dry-cleaning resistance, with no loss ofvapor permeability was observed [8].

8. Nano web on water proof and breathability

Hae Wook Ahn et al studied and compared the waterproof and breathable properties of clothing made from an electrospun

nanoweb and conventional coating of PTFE, and have stated results that, the Nano web laminate had a higher water vaportransmission rate but lower water resistance than the polytetrafluroethylene laminate. The water penetration tests carried suggested

that water resistances are sufficient enough to prevent wetting by rain. The wearing test revealed that Nano web laminated clothing

provided more comfortable clothing-microclimate than polytetrafluroethylene laminated clothing in normal warm environment. In the

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provided more comfortable clothing-microclimate than polytetrafluroethylene laminated clothing in normal warm environment. In the

rainy test conditions, no difference was observed between the polytetrafluroethylene and the Nano web laminated clothing in any of

the measured variables [9].

Roohollah Bagherzadeh studied Transport properties of multi-layer fabric based on electro spun nanofibers mats as a breathable

barrier textile material and found that Multi-layered electro spun nanofibers mats equipped fabric (MENMEF) showed better

performance in windproof property better than Gortex fabric. Also, the water vapor permeability of MENMEF was in a range of

normal woven sport and work clothing. Comparisons of barrier properties of MENMEF and conventionally PTFE coated

materials showed that, the properties obtained by conventional PTFE could be achieved by layered fabric systems with electrospun Nano fiber mats [10].

9. Water Vapor Transport through Protective Textiles at Low Temperatures

Volkmar T. Bartels et al studied on water vapor transport at low temperatures and have stated that the moisture accumulation in

clothing are much better in breathable than in non breathable garments (These differences are highly significant on a level of at leastp > 0.995). The ability to transport water vapor and the physiological function of breathable foul weather protective clothing

existed at subzero ambient temperatures down to -20°C [11].

10.1 Testing of waterproof breathable fabrics

The many methods employed to test the water vapor permeability of the fabric they are

S.noMethodology Standard Purpose

1Sweating Guarded Hot

Plate Tests

(ISO 11092, ISO1999, and ASTM

F 1868)

Measurement of thermal and water-vapor resistance

under steady-state conditions

2 Upright Cup Method ASTM E96Water Vapor Transmission of Materials , permeability,

plastics (general), plastic sheet and film, sheet material

3 Inverted Cup Method ASTM E96

4Desiccant Inverted Cup

Test MethodE96 M-05

5Dynamic Moisture

Permeation Cell TestASTM F 2298

Standard Test Methods for Water Vapor DiffusionResistance and Air Flow Resistance of Clothing

Materials Using the Dynamic Moisture Permeation

6 Moisture vapor transmition

cell

Moisture vapor transmition behavior of fabric

7 Dynamic moisture

permeable cell

Moisture transmition capability of cell

8 Holographic bench

technique

Calculating mass flow

10.2 Waterproof Rating

Waterproof Rating

(mm)

Resistance provided Withstand capabilities

0-5,000 mm No resistance to some resistance to moisture Light rain, dry snow, no pressure

6,000-10,000 mmRainproof and waterproof under light

pressureLight rain, average snow, light pressure

11,000-15,000 mmRainproof and waterproof except under high

pressure Moderate rain, average snow, light pressure

16,000-20,000 mmRainproof and waterproof under high

pressureHeavy rain, wet snow, some pressure

20,000 mm+Rainproof and waterproof under very high

pressureHeavy rain, wet snow, high pressure

10.3 Calculation of permeability index

The permeability index was developed by woodcock

Im = Rt/(LR x Ret)

Where Rt - the total thermal resistance of the clothing plus surface air layer (m2 ºC/W).

Ret - total evaporation resistance of the clothing plus the air layer (m2 kPa/W).

Rt/Ret – the ratio represents effective heat transmition.

LR (lewis relation) - the ratio of evaporative mass transfer coefficient.

10.4 Acceptance standard level worldwide for water repellent breathable fabrics

BS 7209 is a standard widely acceptable throughout the world for the water vapor permeable index (WVPI). The good breathable

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BS 7209 is a standard widely acceptable throughout the world for the water vapor permeable index (WVPI). The good breathable

fabric should have a minimum of 80% and lower grade should have at least 50% WVPI.

10.5 The relative water vapor permeability (%) is govern by

Heat loss when the fabric is placed on the measuring head X 100

Heat loss from bare measuring head

The main requirements for WVPI are based on

Water vapor permeability index percentage.

Resistance to water penetration.

Cold cracking temperature.Surface wetting (spray rating) after cleaning.

Similarly, for a typical breathable fabric the acceptable parameters should have

Water-vapor permeability (min 5000gm-2 for 24 hrs)

Water proofness min 130 cm (hydrostatic pressure)

Wind proofness less than 1.5 ml/cm2/second @ 1M bar

11. Labeling of a water proof fabric and the breathable characteristics

Manufacturers describe the waterproof breathability of fabrics using two numbers. The first is in millimeters (mm) and is a measure

of how waterproof a fabric is. In the case of a 10k or 10,000 mm fabric, if a square tube with inner dimensions of 1” x 1” over a

piece of said fabric is set, it will be filled with water to a height of 10,000 mm (32.8 feet) before water would begin to leak through.

The higher the number, the more waterproof the fabric. The second number is to measure how breathable the fabric is, and it is

normally expressed in terms of how many grams (g) of water vapor can pass through a square meter (m2) of the fabric from the

inside to the outside in a 24 hour period. In the case of a 20k (20,000 g) fabric, this would be 20,000 grams. Larger the number,

higher the breathability of the fabric.

12. Application of breathable fabrics in end products

12.1 Mechanical Counter Pressure (MCP) Suit.A skin-tight suit for high tech cloth exerts pressure over the rocketer's body to provide pressure. Open pores in the suit actually

allow the body to be cooled by perspiration. Tears will cause bruising to the skin, but are not as lethal as they are on a conventional

suit. These materials provide 20% energy expenditure compared with NASA suit [13].

12.2 Air Permeable Outerwear

Gore tech, Polartec Neoshell and Mountain Hardwear Dry.Q allow a nominal amount of airflow, helping to more quickly and

effectively carry moisture away from your body. Meanwhile, they remain totally water and windproof. You get breathability

comparable to a soft shell and waterproofing on par with a hard shell. You stay 100 percent dry from the inside and out.

12.3 Neoprene sports wear

Stomatex “breathable neoprene” is made from closed-cell foam neoprene. These fabrics can be applied as laminates or loose

linings according to users’ requirements. The product is suitable for use wherever thermal insulation or body protection is required

and comfort would normally be compromised by sweating. It has already been used in wide-ranging application including

orthomedical supports, sports supports, back supports, equestrian underwear, surface water sports, wetsuits, survival suits, surfing

wetsuits, warm-up suits, dive suits, liners and footwear [15].

12.4 Mountain wear

Mountain Hardwear's Dry.Q water-proof breathable fabric is among a new breed of sporting apparel [14]

Fig 5: Breathable snow protect mountain wear

12.5 Medical Fabric Waterproof and Breathable

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Eastex Medical Fabrics include 100% polyester and polyester-nylon blends offered in several stretch and non-stretch constructionswith different coatings to match specific product requirements. Fluid-proof, breathable, antimicrobial, flame-retardant, and air-tight

for manufacturing inflatable products, these healthcare fabrics can be sewn and sonic- or RF welded. A full line of fabrics forOEMs and contract manufacturers of healthcare products such as wheelchair cushions, mattresses, and orthopedic braces [18].

12.6 Neo-G MEDICAL GRADE OPEN PATELLA KNEE SUPPORT 'breathable design

Used For - strains, sprains and instability, injured, weak or arthritic knees, patellar tracking, rehabilitation, sporting andoccupational injuries

Fig 6: Neo-G knee support

12.7 3M™ Conformable Breathable Incise Tape 9948The Conformable Incise Tape is a single coated medical tape consisting of a 1 mil moisture vapor permeable plastic film coated

with a hypoallergenic, pressure sensitive adhesive. They are translucent material with very Good MVTR, high breathability andComfortness.

Fig 7: 3M incise tape 9948

13. Conclusion

Thermal comfort remains a major comfort factor in deciding of the fabric. Thermal comfort can be attained once when thedifference in outer temperature is in parallel to the microclimate created within the fabric. Various ventilation factors for the requiredend application have to be predetermined clearly without fail because wrong usage leads to lag in comfortness.

Extensive research is required to understand the relationship between segmental ventilation and local comfort of the fabricsubjected to active usage of the person.

14. Bibliography

Arunangshu Mukhopadhyay and Vinay Kumar Midha, “A Review on Designing the Waterproof Breathable Fabrics Part I,

Fundamental Principles and Designing Aspects of Breathable Fabrics” , Journalof Industrial Textiles 37: 225, (2008).Apurba das and R.Alagiruswamy, “Science in clothing comfort”, Woodhead publications, ISBN 13:978-81-908001-5-0,

(2010).Shishoo.R, “Textiles for Sport”, Woodhead publications, ISBN 978-1-85573-922-2, 2005.

Williams.J.T, “Textiles for cold weather apparel”, Woodhead publications, ISBN 978-1-84569-411-1, (2009).Horrocks.A.R, Anandh.S.C, “Handbook of technical textiles”, Woodhead Publishing Limited, ISBN 1 85573 385 4,

(2000).Shirley Institute, Toray Industries Inc., Naka, Y. and Kawakami, K. (1985).Moisture-Permeable Waterproof Coated

Fabric, USP 4560611, December: 8602376Manjeet Jassal, Amit Khungar, Pushpa Bajaj and T. J. M. Sinha, “Waterproof Breathable Polymeric Coatings Based onPolyurethanes”, Journal of Industrial Textiles 33: 269, (2004).

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Polyurethanes”, Journal of Industrial Textiles 33: 269, (2004).

Rudolph D. Deanin AND Dhirajlal C. Patel, Breathable, Permanent Water-Repellent Treatment of C1ot, Textile ResearchJournal; 40; 970, (1970).

Volkmar T. Bartels and Karl Heinz Umbach, “Water Vapor Transport through Protective Textiles at Low Temperatures”,Textile Research Journal 72: 899, (2002)

Holme, I., “Porous Polymers and Fusible Films”, J. Coated Fabrics15, 198–204 (1985).Hae Wook Ahn, Chung Hee Park and Seung Eun Chung, “Waterproofand breathable properties of nanoweb applied

clothing”, Textile Research Journal 81(14) 1438–1447. (2011).Roohollah Bagherzadeh, Masoud Latifi, Saeed Shaikhzadeh Najar1, Mohammad Amani Tehran, Mohsen Gorji and Lingxue

Kong, “Transport properties of multi-layer fabric based on electrospun nanofiber mats as a breathable barrier textilematerial”, Textile Research Journal 82(1) 70–76. September 14, (2011).

Sanjay S. Chaudhari, Rupali S. Chitnis and Dr. Rekha Ramkrishnan, ”Waterproof Breathable Active Sports Wear Fabrics”,(2010).Apurba das and R.Alagiruswamy, “Science in clothing comfort”, Woodhead publications, ISBN 13:978-81-908001-5-0,

(2010).

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