your shield against airborne viruses and bacteria · 2020. 7. 10. · 11138-49-1 sodium aluminate...

YOUR SHIELD AGAINSTAIRBORNE VIRUSES AND BACTERIA

INDEX

OVERVIEW.

US STANDARD SAFETY DATAINFORMATION REPORT

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SGS-CSTC STANDARDS TECHNICAL SERVICES REPORT

OVERVIEW

WHAT IS MYAIRSHIELD™ ?MyAirShield™ is a patented, portable chlorine dioxide microbe blocking device that, when opened, creates a protective atmospheric shield. This protective shield provides the ultimate protection against airborne viruses, bacteria, fungus and spores.

HOW DOES MYAIRSHIELD™ WORK?Considered one of the most powerful antimicrobial agents, chlorine dioxide creates an atmospheric shield protecting you against germs, airborne viruses, bacteria’s, pollens, and odors. Once opened your MyAirShield™ begins to release ClO2 gas continuously and slowly for up to 90 days. Also, since it’s an oxidizing agent, MyAirShield™ provides the ultimate protection against airborne contaminants and allergens. MyAirShield™ improved technology provides safe and effective protection against contagious diseases like influenza, the common cold, coughs, bronchitis, tuberculosis, and other respiratory illnesses.

OVERVIEW

HOW TO USE MYAIRSHIELD™ ?When you receive your MyAirShield™, unpack the box and peel of the sticker on the badge. Attach the clip to MyAirShield™ badge and hang it round your neck or clip it on your shirt or Blazer infront of you the holes of the Shield facing outwards. Once you opened, MyAirShield™ will last for up to 90 days.

Your MyAirShield™ produces a cloud round your head and body. It is effective in closed rooms or areas, where is no wind or fast air circulation. Perfect to use in planes, trains, cars, offices, hospitals, home, cinemas and other closed areas.

TESTED & RESEARCHED IN ORGANIZATIONS SUCH AS: Hygiene & Microbiology Research Center. Department For Environment and Human Health and Japan Food Research Laboratories. Accredited laboratory that is recognized by international health organizations HSA and SAC.


REPORT NO. GSL20200512009

APPLICANT: HEBEI LICHE ZHUOGE NEW MATERIALS CO., LTD

ADDRESS: NO. 1, NAN LICHE, WUQIANG, HENGSHUI, HEBEI, CHINA

PRODUCT NAME: CHLORINE DIOXIDE GRANULES

COMPOSITION/INGREDIENT: SEE SECTION 3 ON THE SDS

SUMMARY: AS PER REQUEST, THE CONTENTS AND FORMATS OF THE SDS ARE PREPARED IN ACCORDING WITH US REGULATIONS RELATING TO LABOR 29 CFR 1910.1200(G), AND IS PROVIDED PER ATTACHED.

MY AIR SHIELD - 2020 - US STANDARD SAFETY DATA INFORMATION REPORT PAGE 1

1 IDENTIFICATION

• Product identifier• Trade name: Chlorine Dioxide Granules• Product code: Chlorine card, My Air Shield.• Recommended use of the chemical and restrictions on use• Application of the substance/ mixture: Disinfection and sterilization.• Emergency telephone number US Poison Center: Tel: + 1 800 222 1222 (Available 24 hours a day) In China: Jianyong Huang: Tel: +86-311-86250322 (Available 24 hours a day)

2 HAZARD(S) IDENTIFICATION

• Classification of the substance or mixture:

Corrosive to metals Category 1 May be corrosive to metalsAcute toxicity-oral Category 4 Harmful if swallowedAcute toxicity-dermal Category 4 Harmful in contact with skinSkin corrosion/irritation Category 1B Causes severe skin burns and eye damageSerious eye damage/eye irritation Category 1 Causes serious eye damageSpecific target organ toxicity Category 2 May cause damage to organs through -repeated exposure repeated exposure

• Classification system: The classification is according to the latest edition of OSHA Hazard Communication Standard (29 CFR 1910.1200) and extended by company and literature data.• Label elements• Labeling according to OSHA Hazard Communication Standard (29 CFR 1910.1200)• Hazard pictograms:

• Signal word: Danger• Hazard-determining components of the labeling: Sodium aluminate, Sodium chlorite• Hazard statements: - May be corrosive to metals - Harmful if swallowed and in contact with skin - Causes severe skin burns and eye damage - May cause damage to organs through prolonged or repeated exposure• Precautionary statement: - If medical advice is needed, have product container or label at hand. - Keep out of reach of children. - Read label before use. - Keep only in original packaging. - Absorb spillage to prevent material damage. - Do not breathe dust. - Wash hands and face thoroughly after handling. - Do not eat, drink or smoke when using this product.


- Wear protective gloves/protective clothing/eye protection/face protection. - IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. - Take off contaminated clothing and wash it before reuse. - Specific treatments see the first aid measures on this label. - Store in corrosive resistant container with a resistant inner liner. - Store locked up. - Dispose of contents/container in accordance with local/regional/national/international regulation.· Hazards not otherwise classified (HNOC): Contact with acids liberates very toxic gas; Corrosive to the respiratory tract.

3 COMPOSITION/INFORMATION ON INGREDIENTS

· Chemical characterization: Mixture· Description: Mixture of the substances listed below with nonhazardous additions.

Components: CAS No. Composition Name w/w, % 11138-49-1 Sodium aluminate ≤75 7758-19-2 Sodium chlorite ≥20 7647-14-5 Sodium chloride ≥1 497-19-8 Sodium carbonate ≥0.5

4 FIRST AID MEASURES

· Description of first aid measures After inhalation: Remove person to fresh air and keep comfortable for breathing. Get medical attention if you feel unwell. After skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Immediately call a POISON CENTER or doctor/ physician. After eye contact: Rinse cautiously with water for several minutes. Remove contact lens es, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. After swallowing: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician.

· Information for doctor· Most important symptoms and effects, both acute and delayed: Causes severe skin burns and eye damage, Harmful if swallowed and in contact with skin, May cause damage to organs through prolonged or repeated exposure; Corrosive to the respiratory tract.· Indication of any immediate medical attention and special treatment needed: Treated according to symptoms, there is not known specific medicine.


5 FIRE-FIGHTING MEASURES

· Suitable extinguishing agents: Use water spray or alcohol resistant foam to extinguish. DO NOT USE CO2, chemical dry powder, water with full jet.· Special hazards arising from the substance or mixture: May forms corrosive vapour contact with acid solution.· Special protective equipment and precaution for firefighters Protective equipment: Wear an approved positive pressure self-contained breathing apparatus (Comply with OSHA)

6 ACCIDENTAL RELEASE MEASURES

· Personal precautions, protective equipment and emergency procedures: Cut off leakage source and collect spillage timely if safe do it; Ensure adequate ventilation; Do not eat, drink or smoke when using this product; Do not breathe dust; Wear protective equipment; Avoid contact with skin and eyes.· Environmental precautions: Do not allow the product to enter sewers/surface or ground water. Inform respective authorities in case of seepage into water course or sewages system.· Methods and material for containment and cleaning up: Sweep up and shovel into suitable containers for disposal; Ensure good ventilation; Dispose contaminated material as waste according to item 13.

7 HANDLING AND STORAGE

· Precautions for safe handling : Read label before use; Keep only in original packaging; Ensure good ventilation at work place; Do not eat, drink or smoke when using this product; Wear protective gloves/ protective clothing/eye protection/face protection; Do not breathe dust; Avoid contact with skin and eyes.· Information about fire and explosion protection: Normal measures for preventive fire protection.· Conditions for safe storage, including any incompatibilities· Requirements to be met by storerooms and receptacles: Store in a cool and well-ventilated place.· Information about storage in one common storage facility: Keep out of reach of children. Keep away from caid.· Further information about storage conditions: Store locked up; Keep only in original packaging.


8 EXPOSURE CONTROLS/PERSONAL PROTECTION

· Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace· Additional information: The lists that were valid during the creation were used as basis.· Based on the composition shown in section 3, the following measures are suggested for occupational safety measure:· Appropriate engineering controls: Handle in accordance with good industrial hygiene and safety practice; Wash hands and face after handling; See section 7 for information about design of technical facilities.· Breathing equipment: Suitable respiratory protective device must be used.· Protection of hands: Protective gloves Gloves made from butyl rubber Neoprene™ rubber, nitrile rubber (thickness> 0.3mm; breakthrough times up to 480 minutes).

Eye protection: Protective goggles with side-shields.

Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.


9 PHYSICAL AND CHEMICAL PROPERTIES

· Information on basic physical and chemical properties

· Appearance: Form Granules, 1-6mm Color White Odor Weak odor Odor threshold Not determined.· pH -value Not determined.· Change in condition Melting point/melting range Not determined. Boiling point and boiling range Not determined.· Freezing point Not determined.· Flash point Not applicable· Flammability (solid, gas) Not flammable solid· Decomposition temperature Not determined.· Self-ignition Not determined· Danger of explosion Product does not present explosive hazard· Explosion limits Lower: Not explosive Upper: Not explosive· Oxidizing properties Not explosive· Vapor pressure Not determined.· Density Not determined.· Relative density Not determined.· Vapor density Not determined.· Evaporation rate Not determined.· Solubility in/Miscibility with Water Soluble in water.· Partition coefficient (n-octanol/water) Not determined.· Viscosity Dynamic Not determined. Kinematic Not determined.· Other information Not determined.

10 STABILITY AND REACTIVITY

· Reactivity: React slowly.

· Chemical stability: Stable under recommended storage conditions.

· Possibility of hazardous reactions: No known hazardous reaction.

· Conditions to avoid: High temperatures, direct sunlight and high humidity.

· Incompatible materials: Acids, ammonium salts.

· Hazardous decomposition products: Chlorine dioxide.


11 TOXICOLOGICAL INFORMATION

· Acute toxicity : Harmful if swallowed; Harmful in contact with skin; ATE (oral)=500-2000 mg/kg; ATE (dermal)= 1500-2000 mg/kg.

· LD/LC50 values that are relevant for classification: No animal test been done for this product.

7758-19-2 Sodium chlorite Rat LD50-oral 165mg/kg Rabbit LD50-skin 134 mg/kg

7647-14-5 Sodium chloride Mouse LD50-oral 4000mg/kg Rabbit LD50-skin >10000mg/kg Rat LD50-oral 3000mg/kg LC50-inhalation > 42000mg/m3/1H

497-19-8 Sodium carbonate Mouse LD50-oral 6600mg/kg Rat LD50-oral 4090 mg/kg

Remark: All the above data are from literature.

· Primary irritant effect· Skin corrosion/irritation: Corrosive to skin.· Serious eyes damage/ irritation: Corrosive to eyes.· Sensitization: Not sensitive to skin or respiratory.

Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Corrosive; Toxic; Harmful.

· Carcinogenic categories· IARC (International Agency for Research on Cancer): 7758-19-2 Sodium chlorite 3· NTP (National Toxicology Program): None of the ingredients is listed


12 ECOLOGICAL INFORMATION

· Toxicity· Aquatic toxicity: Not hazardous to the aquatic environment.

11138-49-1 Sodium aluminate Long–term toxicity to fish NOEC (28 days) 4.7 - 23.1 mg/L Short–term toxicity to aquatic invertebrates EC50 (24 h) 85.92 mg/L LC50 (4 days) 9.19 - 55.5 mg/L Long–term toxicity to aquatic invertebrates NOEC (8 days) 4.9 mg/L LOEC (28 days) 4.26 mg/L Toxicity to aquatic algae and cyanobacteria EL50 (72 h) 100 mg/L Toxicity to microorganisms EC50 (3 h) 100 mg/L NOEC (3 h) 100 mg/L7647-14-5 Sodium chloride Short–term toxicity to fish LC50 (4 days) 5.84 g/L Long–term toxicity to fish NOEC (33 days) 252 - 533 mg/L LOEC (33 days) 352 - 734 mg/L Short–term toxicity to aquatic invertebrates LC50 (48 h) 4.136 g/L Long–term toxicity to aquatic invertebrates NOEC (21 days) 314 mg/L LOEC (21 days) 441 mg/L Toxicity to aquatic algae and cyanobacteria EC50 (5 days) 2.43 g/L

497-19-8 Sodium carbonate Short–term toxicity to fish LC50 (4 days) 300 mg/L Short–term toxicity to aquatic invertebrates EC50 (48 h) 200 - 227 mg/L

· Persistence and degradability: Inorganic substance.· Bio-accumulative potential: Low bio-accumulation.· Mobility in soil: Low mobility in soil.· Additional ecological information· Other adverse effects: No known other adverse effects.

13 DISPOSAL CONSIDERATION

· Waste treatment methods Recommendation: Must not be disposed together with household garbage.· Un-cleaned packaging Recommendation: Dispose of contents/container in according to the local regulation.


14 TRANSPORT INFORMATION

· UN-Number DOT, IMDG, IATA UN1759· UN proper shipping name DOT, IMDG, IATA CORROSIVE SOLID, N.O.S.· Transport hazard class (es) DOT, IMDG, IATA Class 8 Corrosive substances Label 8· Packing group 8 DOT, IMDG, IATAV II· Environmental hazardous Marine pollution No· Special precautions for user Warning: Corrosive substances Danger code (Kemler) 80· EMS number F-A,S-B· Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Void· UN “Model Regulation” UN1759, CORROSIVE SOLID, N.O.S., 8, II

15 REGULATORY INFORMATION

· Safety, health and environmental regulations/legislation specific for the substance or mixture· Sara· Section 355 (extremely hazardous substances): None of the ingredients is listed.· Section 313 (Specific toxic chemical listings): None of the ingredients is listed.· TSCA (Toxic Substances Control Act): 7758-19-2 Sodium chlorite 7647-14-5 Sodium chloride 497-19-8 Sodium carbonate· Proposition 65

• Chemicals known to cause cancer: None of the ingredients is listed.• Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed.• Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed.• Chemicals known to cause developmental toxicity: None of the ingredients is listed.• Washington, WAC 173-334-130 (CHCC): None of the ingredients is listed.• Chemicals of Concern, published by Maine DEP on July, 2015: None of the ingredients is listed.• Chemicals of High Concern to Children, published by Department of Health, Vermont, Rev Date Nov 24, 2014: None of the ingredients is listed.• High Priority Chemicals of Concern for children's Health, Oregon, update on May 18, 2016: None of the ingredients is listed.• Carcinogenicity categories• EPA (Environmental Protection Agency): None of the ingredients is listed.• TLV (Threshold Limit Value established by ACGIH): None of the ingredients is listed.• NIOSH-Ca (National Institute for Occupational Safety and Health): None of the ingredients is listed.• OSHA-Ca (Occupational Safety & Health Administration): None of the ingredients is listed.


16 OTHER INFORMATION

The contents and format of this SDS are in accordance with 29 CFR 1910.1200(g).

DISCLAIMER OF LIABILITY:

The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable.

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Abbreviations and acronyms:

DOT: Department of TransportationIMDG: International Maritime Code for Dangerous Goods.IATA: International Air Transport AssociationLD50: Lethal dose, 50 percentLC50: Lethal concentration, 50 percentEC50: Concentration of maximal effect, 50 percentEL50: Effective loading rate, 50 percent NOEC: No observed effect concentration LOEC: Lowest Observed Effect Concentration


SGS-CSTC STANDARDS TECHNICALSERVICES REPORT

SGS-CSTC STANDARDS TECHNICALSERVICES REPORT

Test ReportReport No: ASH20-008579-02Date: 29 Apr 2020

Client name: Hebei Liche Zhuoge New Materials Co., LtdClient address: No. 1, Liche Industrial Area, Wuqiang, Hengshui, Hebei, ChinaSample name: Chlorine CardSample Batch No.: /Product Date: /Manufacturer: /

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Above information and sample(s) was/were submitted and certified by the client, SGSquoted the information with no responsibility as to the accuracy, adequacy and/orcompleteness.

SGS reference No.: MCHTJ2000182-01./TJF20-001325Date of sample received: 12 Mar 2020Testing period: 12 Mar 2020 – 26 Apr 2020Test Requested: Selected test(s) as requested by applicantTest Method: Please refer to the next page(s)Test Result(s): Please refer to the next page(s)

Chinese shall prevail in this report.Unless otherwise stated the results shown in this test report refer only to the items tested,and for clients internal use only, not to the society has the proof function. This documentcannot be used for publicity, without prior written approval of the SGS.

MY AIR SHIELD - 2020 - SGS-CSTC STANDARDS TECHNICAL SERVICES REPORT PAGE 1

SAMPLE DESCRIPTION

Specimen No.: 1 SGS Sample ID: ASH20-008579.001 Description: White particle TEST METHOD(S):

* Acute inhalation toxicity test:Test environment: Barrier system animal room. Certificate No. SYXK(Zhe)2018-0003, room temperature 22.4°C ~ 24.1°C, relative humidity 45.6%~50.7%.Test animal: ICR mice, obtained from Laboratory Animal Center for Zhejiang Academy of Medical Sciences. Certificate No. SCXK(Zhe)2019-0002.No. of animals/sex: 10 males, 10 femalesSample preparation: Grinding the sample.Test method: The sample was administered as supplied at a limit dose. Using a single concentration oral and nasal exposure system, the parameters were set before the exposure (concentration 5mg/L, average aerosol flow 20.052L/min, average dilution flow 0.015L/min, average pumping flow 17.052L/min). The results of the operation (concentration 5.2mg/L) were obtained directly after the end of the exposure, and the cumulative injection was 102.4g. Inhalation were conducted for 4 hours at a time. The animals were observed for signs of toxicity or behavioral changes frequently per day thereafter. Individual weights were recorded weekly. Gross autopsies were performed on all animals that died during the observation period and on all survival animals after 14 days.

TEST RESULT(S):

Neither abnormal clinical symptoms nor poisoning deaths occurred in all experimental animalsduring 14 days observation. Body weights of animals were no significantly changes during thestudy. Gross anatomy no remarkable pathological findings on all survivor animals after 14 daysobservation. LC50>5.2mg/L.

Attached table Results of acute inhalation toxicity test

CONCLUSION:

Inhalation LC50 of the sample on ICR mice is more than 5.0mg/L.Remark: * Test was carried out by external laboratory assessed as competent.

MY AIR SHIELD - 2020 - SGS-CSTC STANDARDS TECHNICAL SERVICES REPORT PAGE 2

your shield against airborne viruses and bacteria · 2020. 7. 10. · 11138-49-1 sodium aluminate...

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