~ SUMiTOMO CHEMiCAL MATERIAL SAFET DATA SHEET Prepared using guideJines hlln EC-olrecuve 2001middot5SEC

VAZARY 10FW Dot no C[ 20J3 middot02middotcH1l5

[I IUENTfFICATfON OF THE SCBSTANCpoundlPRETARlno AND OF THE COiiPANY Ul)IIRTAK[NG

Supplier

Regional sales oftlcc SUMrTOilO CHEIllCAL SIG APORpound PTE LTD 150 Beach Ro~d 19-0507 Gatewn West Singapore 189720 TeL +656291 9636

Emergency telephone +60 66793711 (Fax no +60 6 679 (98) OR cGS (lt91 96~( (Fnx II () +6562 3779) (not ~4hrs) lntended usc Ins-cti ( ioc (t enni lie-idc- )

2 COMPOSITIONIN FORMnol ON INGREDIENTS ----~~--~---------------

I hi~ product i to be con Sldcred 3$ 3 prepar(ltiofl in con formance 10 EC l~itct ~L5

Inio rl11t ion on hazardl)us in~rediens Chemitili dcc ription Fenmiddotakral ~ lO~o tlow crnulsi ofi cil 11 a rc r

Composition informlt-ltion on ingredien15 Number wIn- C S-number Chemical name

iO 51630-58 middot 1 alphamiddotClt110-3-phcno)bcn)12-4 eil loropl1cnyl )iso vak rlt1le

10 ( ) solVent Number EC-numIJetmiddot Annex-l ntlmber S)mbnl(s) Rilk-phrse(s) 1 T R1325 Rl3 R50middot5 3 2 (1 Xll R22

Other information () = All components are rcgi~ lcred in EGEeSGLINCS

[3 HAZARDS IDENTIfICATION ---I Harmful if swallowed To xic to aqu atic organir1ls l11~y cau~c long-term aders erfeclS in lhe ltiql11t ic l~ ironment

[-4 FIRST AID MEASURES -------------------------------------_-----~___J Symptoms nd effects I-fay cause a trans ent itching andio r burning sensltJ lion on epOScd human skill Ham jld if

swallowed first aid

General [n case of acc ident or if you feel l ~middotell seek i~ d l cal acivl c0 il11l11~dgt I) (shoI the lbel where possible)

lnhalation Ilove to trcsh air Ifs) l11p toms [J SI seck llledi c~1 advice Skin Ren10middote conraminoted cloIhing t ( immediately ~ i (h soap nd v ater pound )e Rinse thoroughly with pier) iii wa er Eyciids shou ld r c hdd oWily from the c)middotcba ll to Cl~ )t i

Ihorough rin sing Sed medical advice if irritation de ve lops Tngestion RinSe mouth gimiddotc waTe lO drinK Nc C induce middotolniting in uncopsc ious or ct)nfused gt ~ ) lS

Seek medical adv ice Adyice to physician Symptomacic trcat mr~nt is fldmiddotiseo

[5 FIRE FIGHTIiG i[EASlfRES

Extinguishing media Dr) chemical powdcr Unsuitable extinguishing media Water with full I aer Jel Special exposure hazards ~ n ne knovn Hazardous decomposi tion Icombustion products Protective e1uipmen~ protec-ion Other information Vater US8G to ei I ~Ujsh 3 fire should no be a lomiddotc to e1te r the drainag e yste m ur

middotvalCfCOlifSCS

Product ~Od f TDSI-F002 D~te of 12S1 is l illW03

SUMITOMO CHEMICAL VfATERIAL SAFETY DATA SHEET

Prepmed u illg gujd~ li nes from EC-dircclie 200Ii58EC

WAZARY 10FW

6 ACCIDENTAL RELEASE MEASURES Persona l precautions For peroJl al protection Se~ Section 8 Emironme ntai prccnutions Do nor allow to escape info sewage sYStcn1 or wci t rcolS(S

Iethods for clean ing up In case of spill (liquid) soaK it up immed i at~ l y with sui tflble absorbc nl u ch as S(lldllS~ (1shy

grl))U lflf abso rbtnt clay Sw~cp up and pU T it into a cont2~ncr for disposal (SCi Segt1i l 1 i 3 j

7 HANDLING AND STORAGE

Handling Th ~ usual precautions or hOlld ling chem ical shouid be obcn-cd For pe rsonn protectio n see middot$ccr ion S

Fire and explosio n prevc ntio n No spiciti c recommendati ons Storage r~qllirem ents Store in a cool place Ao id direct sunih Keep conti1er tightly closd Other infor mtioll Do nor mix with ware r lexcept for norm~ 1 r r ~p a3Ii on middotl Ao id elevated temperaturcs

8 EXPOSURE CONTROLPERSONAL PROTECTION ~ ~------~----~~~--~~--------------------------~ Eng in eeri ng contr ols Provide adequate middotmiltiol1

Exposure limits 10 tXI)Os1 re limits have kr cS iished (or -hi n~ ~ ~ril

Personal protection Res piratory The usua l precaulions [or hnnd ling Chemi c) sh oul d e ohelmiddotmiddotd H 1 ld Wea r protective glo ves o[ rllbba pI3tic Eye Wear safer) goggl es or face shie ld Skin a nd body Wear sui table p iOt~cliw clothing

App ea rance Viscous liq uid

Colour Whitf til pak elloviish brOll11 00 clU5 OIl

Od ou r Sligld y characteristic

Boil ing pointr~nge Not determ ined

~1eting pointrange NOi appl icab le

Flash point ~ 150C (estimal-dmiddot

Fl nmmabiiity 0 (in)flammabk

A uto ignition tern pe r atu re ~ot deerm il1~d

Explosive properties -Oi alai lh

Explosiorlimi ts lOt 3Y3ii hle

Oxidis in g pr operti es 0101 applica ble

Vapour press ure (Oi ck~~rm ined (Co r fenakr - (ill iC (l [ maerial ) 037 rnP a ltI t 25 C I

Density I 00 I 02 gilD I at 20(

Bulk density -lot applicable

Solubility in water

So lub il ity in oth er so lvenrs -lot deiermine-i

pH a lu e 6middot S

Relative vapo ur d~n$ i t)middot (a ir=l )

Viscositl - DOD mPas (25(1

[ToSTABILITY AlD REACTIVITY ]

Stability S l~i j l ~ under recolnmendgtd sto rage ail u I~ ci~ i l ) g conditions (sec S~ci)r 7)

Conditions to avoid ont kl0lYfl

Material s to aoi d -v1c - 01 11

Hazudotls decomposition products 1- I(gtmiddoti c and corrosive nm 1middotS middotmder nre condilions (ce dS(l S ccti ~n 5i

Produ ct cude TDS imiddot P002 Drrte of lost isgtl e 31 middotol middot2n~

+ SUMiTOMO CHEMICAL jVfATEFJAL SAFETY DATA SHEET

Prepnrcd tsing guidciine~ from ECmiddotdi rec [ln 200J~ ~E(

WAZARY iO rW

11 TOXICOLOGICAL I~FORMAnON

Name

Acute toxicity Oral LD male rat 2300 mgkg

remale ratmiddot 2600 n ikg cal gt 000 mg k g (mas J(~ I middot ~d I r t~~~ t)

[rr itation Skin Slighr irrHant (rabbit) E)e Slighl irritant (reb)- ) Sensitisation 10 ~en~Ii~ing Other toxicological inform at ion

12 ECOLOGICAL IlFORMATION

Tile follow in g data are ap[1licab ie 0 til ingredien t(s) liskd bdow ame Fltnaie rafc_ techn ical graJ ~

Fcotoxicitv fish ACllt~ 10--ICi ) 9611-LC ( R ~i1bo trollt) middot nUOJ6pg ~ f fJov~th r l ~ i

ITiiaria i 200pgiL (Oow-hrough algae ACll te tox icitS 9 6-r C ~ ( - 1( lOlgl

Fate degradat io n biotic Not readily biodegradabl( bioaccumlilation bioconccntcHion factors rarg frem l2(1 to 4700 fo r ariou5 (rga nisl1I s As matcia l t2lKC1 1J P b ~

aquati c organisms is rapidh lost on transfer lO clean middotlIe r in plactic~ the cnmp0V1d can he regarded as hav ing no tendency lO bioaccummulate Fenvakrate techniC-il gr1oe

Ecotoxi city fish 28 day exposure (Sh~epshc~d minn l)wl Concemratioli (~OfT) = (LS 6gttgiL dap hnia L l re C1C ie l eSl S ( [Japhnia O I Iil frJ 1i1 ktOtCi2 i COlCCnlral ion (IOFC) = middotmiddotil n05flgiL

13 DiSPOSAL CONSIDERATIONS J Product Acco rd ing to local regulations For rurlth~r adicc contact n13l U1cturer Contamina ted packaging According to local regulations

r)4 TRltNSPORT I)FORlIIAnON =J Land 1IL1Jspor (AD RJ RlDi

ADR class ADRmm it~m No lie I Ie

RID cI~ss ADRfRID packin~ group II I

-lazard identificati on 0 90 Substance idcntiiicat ionlQ JOS2

TREM-Card (EriC TSC R) - 9000 U) nu mbcl 308~

Pro pCI Sbipping Nanleuro

Sea Iru iSjHJr (JDGmiddotcode ~~() IiJO I llllO G code Class 9

Packing ~rOlip fll page 9020 U numl1c r 3082

EMS none JrAG

ltmiddotine polluta nt yes

Proper Shipping ii ame En ironmentally htzardol15 ubstance Iquid n t ~ Co l1uins J ono FtnmiddotaJ rar~ I

middot111 middotonsporl ]CAO-T -1r --DCR

ICAO -TI I [ATA-DGR U numbe r 30S2

Class 9 P~cing group Ifl

Cargo 91J un l ill~itedl Passengers 9 I ltI (unlimied

Proper Shipping al1 c ~ n ironmenla1 ) hazardou s 5ubs ~Jce lijuio 11 0 $ (Contain s I O~ C F~ 1 valerate)

Prod uct code TDS~ -r00 2 Dafe OfJ1ST iss ue 3 10 1(1((

SUMITOMO CHEMiCAL fllATERrAL SAFETV DATA SHEET

Prepared using guidelines from EC-directive 20U I 58EC

WAZARY 10FW

15 REGl1JATOliY IFORMATlO J Chemical de~cription Fen laleratc 10 fl o emulsion oil in wJier

Labeling according to EC direclil~s EC-number Sa s2cti on 2

Symbol(s)

R(isk) phrasc(s)

S(afet)) phrase(s)

DIG EROlS FOR THE ENVIROtlENT iNI

R22 Harmful if SWQllo~d

RS153 Toic to aquatic orn)$I1)s ~11y CJ use long-[erm 8Cher5e ff~(s in (1 ( (lql1nic envi ronment S2 Kc~p out of reach of chi ldren S13 Keep away tiom fo od drink and animal fceding5 tll lfs S202 ] When using do not enl drink or 1ll0K lt23 Do not breath fumes S24125 Avoid contaci with s~in and eyes S3 637 IVear suilable protecti ve clothil~~ and gloes S46 lfswalowed seek medico l Jdvice immedi ate ly and show this contai n ur labe S49 Keep only in the original c)lltaincr S6 1 Avoid rel ease 10 the cl1ronment Refer to special instructions i Safet y dlt11 3 sh gt

16 OTHER I)FORMATlON ] Thi s information onl co ncerns rbe above mentioned proQlIct and does nOI r c ~d l(l be val id if us~d with othel product(s) or in any process The irform3tion is to our best present kno wl cdge correct and com plete and is gen in good failh hUI withollt warrant) 11 rCIIl8ins the uscr s on responsibility to make sure doni the information is apr ro pcc and complete for his spec iai use of this r rndltt

R-pllrase information Chemica name alpha -Cyano-3 -~henoybcn~ I 2middot( 4-ch lorophenv)is(wa lcratc

Solvenl

Hi story

fltisk-phrase(s) R23i25 R43 RO~3 ()l~ by lDhlat~()n and if swalJowed lay CaU51 sen slt is 1 ttof1 l~ )l d1

COlltC- ry tOXIC 10 aq ualic organisms Illa~ caUI e long-te rm iHI lr~ e

effecs in lht aqua(i enyjr0nmenl

1lt22

Date of prlntingword file geneatiGf 31-01middot~O ~i3

Revision one

Composed by AJ1 Suton (ba sd on data supp ~d fro8 Sumitomo UK)

Produci ltode TDSlA-F002 Date of la s iu J Iill20fl3 Page of 4

+ SUMiTOMO CHEMICAL jVfATEFJAL SAFETY DATA SHEET

Prepnrcd tsing guidciine~ from ECmiddotdi rec [ln 200J~ ~E(

WAZARY iO rW

11 TOXICOLOGICAL I~FORMAnON

Name

Acute toxicity Oral LD male rat 2300 mgkg

remale ratmiddot 2600 n ikg cal gt 000 mg k g (mas J(~ I middot ~d I r t~~~ t)

[rr itation Skin Slighr irrHant (rabbit) E)e Slighl irritant (reb)- ) Sensitisation 10 ~en~Ii~ing Other toxicological inform at ion

12 ECOLOGICAL IlFORMATION

Tile follow in g data are ap[1licab ie 0 til ingredien t(s) liskd bdow ame Fltnaie rafc_ techn ical graJ ~

Fcotoxicitv fish ACllt~ 10--ICi ) 9611-LC ( R ~i1bo trollt) middot nUOJ6pg ~ f fJov~th r l ~ i

ITiiaria i 200pgiL (Oow-hrough algae ACll te tox icitS 9 6-r C ~ ( - 1( lOlgl

Fate degradat io n biotic Not readily biodegradabl( bioaccumlilation bioconccntcHion factors rarg frem l2(1 to 4700 fo r ariou5 (rga nisl1I s As matcia l t2lKC1 1J P b ~

aquati c organisms is rapidh lost on transfer lO clean middotlIe r in plactic~ the cnmp0V1d can he regarded as hav ing no tendency lO bioaccummulate Fenvakrate techniC-il gr1oe

Ecotoxi city fish 28 day exposure (Sh~epshc~d minn l)wl Concemratioli (~OfT) = (LS 6gttgiL dap hnia L l re C1C ie l eSl S ( [Japhnia O I Iil frJ 1i1 ktOtCi2 i COlCCnlral ion (IOFC) = middotmiddotil n05flgiL

13 DiSPOSAL CONSIDERATIONS J Product Acco rd ing to local regulations For rurlth~r adicc contact n13l U1cturer Contamina ted packaging According to local regulations

r)4 TRltNSPORT I)FORlIIAnON =J Land 1IL1Jspor (AD RJ RlDi

ADR class ADRmm it~m No lie I Ie

RID cI~ss ADRfRID packin~ group II I

-lazard identificati on 0 90 Substance idcntiiicat ionlQ JOS2

TREM-Card (EriC TSC R) - 9000 U) nu mbcl 308~

Pro pCI Sbipping Nanleuro

Sea Iru iSjHJr (JDGmiddotcode ~~() IiJO I llllO G code Class 9

Packing ~rOlip fll page 9020 U numl1c r 3082

EMS none JrAG

ltmiddotine polluta nt yes

Proper Shipping ii ame En ironmentally htzardol15 ubstance Iquid n t ~ Co l1uins J ono FtnmiddotaJ rar~ I

middot111 middotonsporl ]CAO-T -1r --DCR

ICAO -TI I [ATA-DGR U numbe r 30S2

Class 9 P~cing group Ifl

Cargo 91J un l ill~itedl Passengers 9 I ltI (unlimied

Proper Shipping al1 c ~ n ironmenla1 ) hazardou s 5ubs ~Jce lijuio 11 0 $ (Contain s I O~ C F~ 1 valerate)

Prod uct code TDS~ -r00 2 Dafe OfJ1ST iss ue 3 10 1(1((

SUMITOMO CHEMiCAL fllATERrAL SAFETV DATA SHEET

Prepared using guidelines from EC-directive 20U I 58EC

WAZARY 10FW

15 REGl1JATOliY IFORMATlO J Chemical de~cription Fen laleratc 10 fl o emulsion oil in wJier

Labeling according to EC direclil~s EC-number Sa s2cti on 2

Symbol(s)

R(isk) phrasc(s)

S(afet)) phrase(s)

DIG EROlS FOR THE ENVIROtlENT iNI

R22 Harmful if SWQllo~d

RS153 Toic to aquatic orn)$I1)s ~11y CJ use long-[erm 8Cher5e ff~(s in (1 ( (lql1nic envi ronment S2 Kc~p out of reach of chi ldren S13 Keep away tiom fo od drink and animal fceding5 tll lfs S202 ] When using do not enl drink or 1ll0K lt23 Do not breath fumes S24125 Avoid contaci with s~in and eyes S3 637 IVear suilable protecti ve clothil~~ and gloes S46 lfswalowed seek medico l Jdvice immedi ate ly and show this contai n ur labe S49 Keep only in the original c)lltaincr S6 1 Avoid rel ease 10 the cl1ronment Refer to special instructions i Safet y dlt11 3 sh gt

16 OTHER I)FORMATlON ] Thi s information onl co ncerns rbe above mentioned proQlIct and does nOI r c ~d l(l be val id if us~d with othel product(s) or in any process The irform3tion is to our best present kno wl cdge correct and com plete and is gen in good failh hUI withollt warrant) 11 rCIIl8ins the uscr s on responsibility to make sure doni the information is apr ro pcc and complete for his spec iai use of this r rndltt

R-pllrase information Chemica name alpha -Cyano-3 -~henoybcn~ I 2middot( 4-ch lorophenv)is(wa lcratc

Solvenl

Hi story

fltisk-phrase(s) R23i25 R43 RO~3 ()l~ by lDhlat~()n and if swalJowed lay CaU51 sen slt is 1 ttof1 l~ )l d1

COlltC- ry tOXIC 10 aq ualic organisms Illa~ caUI e long-te rm iHI lr~ e

effecs in lht aqua(i enyjr0nmenl

1lt22

Date of prlntingword file geneatiGf 31-01middot~O ~i3

Revision one

Composed by AJ1 Suton (ba sd on data supp ~d fro8 Sumitomo UK)

Produci ltode TDSlA-F002 Date of la s iu J Iill20fl3 Page of 4

SUMITOMO CHEMiCAL fllATERrAL SAFETV DATA SHEET

Prepared using guidelines from EC-directive 20U I 58EC

WAZARY 10FW

15 REGl1JATOliY IFORMATlO J Chemical de~cription Fen laleratc 10 fl o emulsion oil in wJier

Labeling according to EC direclil~s EC-number Sa s2cti on 2

Symbol(s)

R(isk) phrasc(s)

S(afet)) phrase(s)

DIG EROlS FOR THE ENVIROtlENT iNI

R22 Harmful if SWQllo~d

RS153 Toic to aquatic orn)$I1)s ~11y CJ use long-[erm 8Cher5e ff~(s in (1 ( (lql1nic envi ronment S2 Kc~p out of reach of chi ldren S13 Keep away tiom fo od drink and animal fceding5 tll lfs S202 ] When using do not enl drink or 1ll0K lt23 Do not breath fumes S24125 Avoid contaci with s~in and eyes S3 637 IVear suilable protecti ve clothil~~ and gloes S46 lfswalowed seek medico l Jdvice immedi ate ly and show this contai n ur labe S49 Keep only in the original c)lltaincr S6 1 Avoid rel ease 10 the cl1ronment Refer to special instructions i Safet y dlt11 3 sh gt

16 OTHER I)FORMATlON ] Thi s information onl co ncerns rbe above mentioned proQlIct and does nOI r c ~d l(l be val id if us~d with othel product(s) or in any process The irform3tion is to our best present kno wl cdge correct and com plete and is gen in good failh hUI withollt warrant) 11 rCIIl8ins the uscr s on responsibility to make sure doni the information is apr ro pcc and complete for his spec iai use of this r rndltt

R-pllrase information Chemica name alpha -Cyano-3 -~henoybcn~ I 2middot( 4-ch lorophenv)is(wa lcratc

Solvenl

Hi story

fltisk-phrase(s) R23i25 R43 RO~3 ()l~ by lDhlat~()n and if swalJowed lay CaU51 sen slt is 1 ttof1 l~ )l d1

COlltC- ry tOXIC 10 aq ualic organisms Illa~ caUI e long-te rm iHI lr~ e

effecs in lht aqua(i enyjr0nmenl

1lt22

Date of prlntingword file geneatiGf 31-01middot~O ~i3

Revision one

Composed by AJ1 Suton (ba sd on data supp ~d fro8 Sumitomo UK)

Produci ltode TDSlA-F002 Date of la s iu J Iill20fl3 Page of 4