친환경 저가 pdp용 소재개발에 관한 산업분석 · 1.1.3 pdp산업의 발전 ... 2.4...
TRANSCRIPT
-
PDP
()
2005. 4.
-
" PDP "( 2005.
1. 15 2005. 4. 15)
2005. 4. .
: PDP
:
: LG
: SDI
:
: PDE
:
:
:
:
:
:
:
:
:
:
-
I.
PDP
PDP
, ,
PDP 1 PDP
.
PDP
II.
, , , PDP display
,
PDP 1 43% PDP
,
,
. PDP
,
-
PDP 43% 25%
- , ,
4.8%, 1.76%, 7.2%
(borosilicate glass)
(soda-lime silica glass)
,
- 65 process
, , seal
- Pb , , seal, frit filler
Pb-free
4
-
- PDP
-
-
(1)
matching
, ,
matching
-
System
filler ,
profile
1000
Sheet
PDP
(2)
PDP sustain
- , ,
PDP
- : < 85
- PET ,
- : >99%
-
- , ,
PDP sustain
- : < 5% (d=20cm)
-
PDP
- Roll to Roll (proto type)
(3)
Doping Dopant
Grain
Splash
(Vf , Vs)
Doped MgO
Dopant Doping
sputtering
Green Sheet
(Vf , Vs)
(4) PDP
metal base-Ag
- 0.1 2 base metal
- Ag(10 50%), metal base Ag
Ag ink
-
- Nano size Ag particle
- Ink
-
profile
metal base-Ag
- , sheet,
- Metal base Ag
- metal base Ag material
-
Ag ink
- nano size Ag particle
- Ink
-
- Ink
PDP
-
III.
PDP 1
60% PDP
.
PDP , display
,
PDP .
, ,
. , PDP
Pb , , seal, ,
Pb-free .
, PDP , ,
, ,
.
-
1.1 1
1.1.1 PDP () 1
1.1.2 PDP 1
1.1.3 PDP 3
1.1.4 PDP 3
1.1.5 PDP 4
1.2 PDP 8
1.2.1 PDP 8
1.2.2 PDP 12
1.2.3 PDP 21
1.2.4 PDP 22
1.2.5 PDP 25
1.3 29
1.4 31
1.4.1 31
1.4.2 32
1.6 34
1.7 35
2. PDP 36
2.1 PDP 36
2.2 PDP 40
2.2.1 (PDP, PDP) 40
2.2.2 (PDP, PDP ) 45
2.2.3 PDP 48
2.2.4 PDP 49
2.3 PDP 53
2.3.1 53
2.3.2 55
2.3.3 (, ) 58
2.3.4 62
-
2.4 66
3. 67
3.1 PDP 67
3.1.1 67
3.2 PDP 67
3.2.1 67
3.2.2 PDP 74
3.2.3 PDP 79
3.3 83
3.4 84
3.4.1 84
3.4.2 84
3.4.3 84
3.4.4 PDP / 85
3.4.5 PDP / 92
3.4.6 98
3.5 99
3.6 101
4. 101
4.1 101
4.2 102
4.3 102
4.3.1 102
4.3.2 103
4.4 103
5. 104
5.1 104
5.2 104
5.3 105
6. 106
-
6.1 106
6.2 108
6.2.1 108
6.2.2 113
6.2.3 119
7. 120
121
-
- 1 -
1.
1. 1
1. 1. 1 PDP ()
Plasma Display Panel(PDP) 1
(),
147 ,
flat panel display
device.
1. 1. 2 PDP
(a) panel
.
(b) sustain(X)
, (ITO)
(Ag Cr/Cu/Cr-Y) .
, . sustain
(X) Scan(Y) adress
.
(c) (adress)
. 130
(b)(c) PDP
seal align. //
PDP . (Ne, Ar He+Xe) 300400torr
.
-
- 2 -
Upper glass
Bus electrode
Sustain Electrode
MgO Layer
Dielectric
Upper glass
Bus electrode
Sustain Electrode
MgO Layer
Dielectric
Cu
Front Glass Plate
w 260, t 2(Data )
Phosphors
w80, h130, 550-570 C(, )
Back Glass plate
Metal Address Electrodesw 100, t 2
Visible light
White Dielectric
Black Stripes
2.8
: Tg 380-4005, t14 : Tg 460-47050, t14 ITO:100
7000,
Xe+He/Ne/Ar
60 ()
2.8mm 12 Adress/Adress 260
Dielectric ITO Electrode
MgO
Bus Electrode
550-570 C()
t15(R.G.B)
Glass
Cu
Front Glass Plate
w 260, t 2(Data )
Phosphors
w80, h130, 550-570 C(, )
Back Glass plate
Metal Address Electrodesw 100, t 2
Visible light
White Dielectric
Black Stripes
2.8
: Tg 380-4005, t14 : Tg 460-47050, t14 ITO:100
7000,
Xe+He/Ne/Ar
60 ()
2.8mm 12 Adress/Adress 260
Dielectric ITO Electrode
MgO
Bus Electrode
550-570 C()
t15(R.G.B)
Glass
(a)
(b)
Lower glass
Address E lectrode Dielectric
Phosphor Barrier Rib
(c)
PDP PDP (a) PDP , (b) ,
(c)
-
- 3 -
1. 1. 3 PDP
1927 PDP .
1954 DC PDP
1964 Slottow Bitzer AC PDP
1980 PDP (Lap-top) .
1990 AC color PDP
1995
1. 1. 4 PDP
, , : PDP 100 CRT
1/10 , 1/6 .
: PDP
RGB CRT .
:PDP
. AC PDP
,
.
: PDP ,
160
.
, , : PDP -4090
CRT LCD PDP
.
: 30,000 .
: LCD (LCD-65, PPD-27)
.
Contrast .
.(12 lm/W)
-
- 4 -
.
.
1. 1. 5 PDP
PDP
()
ITO SnO2
pattering
Cr/Al/Cr
glass paste
seal 5 sealing (glass paste)
()
.
, 1
adress(Cr/Cu/Cr Cr/Al/Cr )
Adress .
.
R,G,B
PDP
()
sealing
MgO
Xe/Ne/He (670 hpa)
Aging.
-
- 5 -
() ()
Bus
seal
Bus
seal
Etching Printing, ,
Printing, ,
Printing, SandblastingPressing, Etching
Printing, Green sheet
Printing
E-beamSputteringIon plating
Align
//
Aging
PDP
-
- 6 -
ITO
Glass
/
Glass
, Frit, vehicle
Photo Mask
Screen Mask
MgO
ITO Coated Glass
ITO Patterning
BUS
Black Stripe
paste
Laminating
/
/
Dispensing
ITO
DFR
Photo Mask, ,Frit, vehicle
, Frit, vehicle
Photo Mask
Frit, vehicle
Frit, filler, vehicle Seal Line
PDP
-
- 7 -
Glass
/
/
/
Sand Blasting
Laminating
Glass
,frit,vehicle, screen
Photo Mask
(wet chemical)
, vehicle,Screen Mask)
,Screen Mask
Photo Mask
CaCO3
DFR
Frit, vehicle,Screen Mask
Address
paste ( )
paste
PDP
-
- 8 -
1. 2. PDP
1. 2. 1 PDP
PDP , , , Seal,
, , , , filter, , DFR,
PDP panel SiO2-B2O3
(strain )
strain
65
70%
PDP
Strain() 575 510
(10-7
/) 825 875
(kgf/) 7.8 x 105 7.3 x 105
(log) 12 8.5
(SiO2) (%) 49 72
(%) 0 14
(/)
AC PDP
.
.
GUSWO Pb glass frit filler .
- PbO-ZnO frit
PbO frit filler
-
- 9 -
PDP
PDP
.
PbO-B2O3-SiO2 frit, Al2O3, TiO2 filler vehicle
paste
Seal
.
.
Seal PDP
- Pb frit, filler, vechile dispensing
paste
2
PDP .
90% ITO . ITO
In .
In
.
Bus/Adress
.
() (bus/adress ) .
- bus
Bus adress Ag paste Cr/Cu/Cr
Cr/Cu/Cr
Ag paste
-
- 10 -
Xe (147nm :VUV-vacuum ultra
violet) .
,
photolithography
PbO
.
-
.
-
.
AC PDP
.
- PDP MgO
Filter
PDP 800900
. PDP .
filter
Ne + Xe , He + Xe
, He + Ne + Xe
.
-
- 11 -
DFR( ) DFR(Dry film resist)
(Photo-resist PR) PET (Poly ehylene terephthalate)
PE(Polyethylene)
.
ITO
(PE)
(PR)
(PET)
(PE)
(PR)
(PET)
(PE)
(PR)
(PET)
DFR
-
- 12 -
PDP DFR
.
DFR
.
DFR
1. 2. 2 PDP
ITO coating
.
, ,
500600 10 40100m/
.
120200 .
, , ,
.
, ,
, , Seal, , , , , filter,
,
-
- 13 -
PDP
1 2 3 1 2
ITO
MgO
-
ITO target
()
MgO target
filler
Borosilicate
ITO
Ag
Pb
MgO
ATO
Cr/Cu/Cr
Pb free
paste
paste
paste
paste
paste
-
filler
Pb
Pb
Pb
Ag, Cr/Cu
-
Pb free
Pb free
Pb free
PDP PDP
.
.
boro-silicate
3
.
.
.
PDP
.
PDP , .
- 3
.
PDP ,
ITO ITO
set
-
- 14 -
(soda-lime) (PD 200)
(/)
paste paste (frit), filler
vehicle
- , ,
, PbO, B2O3, SiO2
.
(wt, %)
()PbO SiO2 B2O3 Al2O3 ZnO
6570 25 35 05 550600
5560 2025 46 35 570590
530580,
80% 6585(10-7/),
470490 ,
Ag MgO matching .
paste
-
- 15 -
2040 screen printing
.
paste
2040 um
green sheet
.
PDP
.
- stripe, well waffle
stripe stripe.
PDP
waffle, meander honeycomb
Stripe Type Well Type Waffle Type
-
- 16 -
paste , vehicle, filler,
pigment .
- , filler, pigment
PbO-SiO2-B2O3 , filler Al2O3, TiO2, ZnO
.
- , ,
. 300450
calcination , 570590 30
.
30120 120150
,
Seal
Seal matching( )
, , , ,
.
Seal filler
.
PbO-ZnO-B2O3 () 430
450, 8589(10-7/),
7178(10-7/)
Seal sealing
sealing crack
source
-
- 17 -
Sealing
(sustain)
ITO , ITO
target sputter .
ITO , ,
- ITO In2O3 SnO2 ITO
ZnO, Sb doped SnO2 CdSnO .
- SnO2 , spray CVD
. SnO2 ,
.
Bus/Adress
Bus adress glass powder panel
, panel
,
.
Bus adress PbO PbO-B2O3-
SiO2 Ag vehicle
polymer .
Ag paste .
Ag, frit 70%
vehicle 30%
- bus adress Cr/Cu/Cr, Cr/Al/Cr
-
- 18 -
Address , photolithography
, lift-off,
Ag address 7080.
paste
Dupont Taiyo ink
Ag, frit,
71(Ag ) 68.6(Ag )
Vehicle
11 12.4
(,
)18 19.0
photolithography
CRT .
- , ,
.
BaMgAl10O17:Eu,
Zn2SiO4:Mn, BaAl12O19:MnYBO3:Tb,
Y0.65Gd0.35BO3:Eu, Y2O3:Eu, Gd2O3:Eu .
-
CaWO4:Pb (), CaWO4:W (), Sr3(PO4)2:Eu+2,
Ba3(PO4)2:Eu+2, Y2SiO5:Ce
+3 (), YP0.85V0.15O4 (,
), SrMg(SiO4)2:Eu+2 (, ), BaMg2Al14O24:Eu
+2 (),
Sr5Cl(PO4)3:Eu+2 BaMgAl10O17:Eu
+2
-
Zn2SiO4:Mn, YBO3:Tb, BaMgAl10O17:Mn, Y3(Al,Ga)5O12:Ce, BaMg2-
Al14O24:Eu,Mn (), CeMgAl11O19:Tb (), Mg(Ga,Al)2O4:Mn
-
YVO4:Eu+3, Y2O3:Eu
+3 (), YP0.65V0.35O4:Eu+3, Y,GdBO3:Eu
+3 (
)
- 2003 BaMgAl10O17:Eu2+
-
- 19 -
LG
.
- 2004 CMS:Eu2+ VUV
BAM:Eu2+
.
-
.
, MgO
.
- MgO . MgO
PDP ,
DISPLAY
DISPLAY
PDP .
-
- 20 -
Filter
(8001000nm), ,
, (constast)
, ,
-
,
DFR DFR PE
, UV
.
DFR PET
.
.
AC DC Xe Kr .
He, Ne, Ar
( : Penning effect)
rare gas
Ne He
Xe .
- 2 He + Xe, Ne + Xe , 3
Ne + Xe + Kr, He + Ne + Xe
, VUV .
-
- 21 -
gas 300380
.
1 2 hole
400450
sealing( ).
sealing ,
soda-lime (glass tube) ,
sealing seal PbO-B2O3
Sealing glass
Sealing
A A
Sealing glass
Sealing
A A
Sealing glass
Sealing
HoleNe+XeNe+Xe
Sealing glass
Sealing
HoleNe+XeNe+Xe
PDP sealing
1. 2. 3 PDP
AGC PDP()
- 1991 PDP
1995 AGC Float 1996
42" 3
- PDP
-
- 22 -
ITO .
- 1954 Rupprecht InO 10cm
- 1968 Philips Van Boort E Kauer spray
ITO 210cm .
- 1990
full-color ,
Xe 147
.
- CRT VUV
, MgO
H2O CO2 MgO ,
,
- 1976 T. Urade, S. Andoh MgO
.
1979 T. Shinoda MgO, CaO, SrO, BaO
, MgO
.
19801990 AC-PDP MgO
- 1996 T. Sasaki K. Yoshida MgO/MgF2
( )
- 1999 S. J. Rho MgO Cs
1. 2. 4 PDP
--
,
,
-
- 23 -
, ,
.
- aus
cycle
-
.
PDP
3040%
PDP ,
item
item .
- 60%
GlassFrit
, , ,
In2O3, SnO2,Sb2O3, ZnO
PbO, ZnO, B2O3, SiO2, Al2O3
(Y,Gd)BO3:Eu3+ BaMgAl10O17:Eu3+
MgO
,
Target(ITO, AZO)
,
Seal
Fe, Cr, Co, Ag, Sn
, ,
Paste or Sheet
Paste
(Driver IC)
PDP Set
GlassFrit
, , ,
In2O3, SnO2,Sb2O3, ZnO
PbO, ZnO, B2O3, SiO2, Al2O3
(Y,Gd)BO3:Eu3+ BaMgAl10O17:Eu3+
MgO
,
Target(ITO, AZO)
,
Seal
Fe, Cr, Co, Ag, Sn
, ,
Paste or Sheet
Paste
(Driver IC)
PDP Set
PbTiO3, Al2O3
PDP --
-
- 24 -
5
080%
-
test
- PDP paste 10
, , 3D ,
PDP , ,
Know-how (:
)
-
glass frit , seal
, PDP
PDP , , seal, ,
Pb ,
.
- Pb
- Pb-free PDP line
Pb
-
- 25 -
BATCH FLOAT BATH CUTTING
MOLTEN METAL
FLOAT
SHEET GLASS
FLOAT
SHEET GLASSCUTTING
1. 2. 5 PDP
PDP
Floating .
Floating
PbO-B2O3-SiO2
(glass frit)
vehicle ,
.
PbO-B2O3-SiO2
. filler
vehicle ,
.
Seal
PbO-B2O3-SiO2
, PbO TiO2 PbTiO3
filler .
seal , filler pigment vehicle
seal paste
-
- 26 -
PbO, B2O3, SiO2 PbO, B2O3, SiO2
Filler Vehicle
Paste
,
< >
< Frit >
< >
< Filler >
Filler
Vehicle : Binder, Solvent, Dispensor
PbO, Al2O3, TiO2
PbO, B2O3, SiO2 PbO, B2O3, SiO2 PbO, B2O3, SiO2 PbO, B2O3, SiO2
Filler Vehicle
Paste
,
< >
< Frit >
< >
< Filler >
Filler
Vehicle : Binder, Solvent, Dispensor
PbO, Al2O3, TiO2
, seal paste
-
- 27 -
ITO In2O3 SnO2 , sputtering
.
- , ITO
In2O3 SnO2 slurry , spray dry
, .
ITO .
- ITO sputter . sputtering
B/P(Backing Plate) metal .
- ITO target sputtering
. ITO In2O3
kg $700 ,
.
Bus/Address
Ag paste .
- Paste Ag , Pb glass frit,
vehicle .
- Ag Ag , , pH,
, .
- Glass frit .
- Vehicle , , 20cps .
- Vehicle 1 ,
#400 paste .
.
-
- 28 -
Vehicle
1
2
Paste
#400
,
, ,
Vehicle
1
2
Paste
#400
,
, ,
Ag
. ,
,
.
.
PDP ,
.
.
.
frit ,
paste , .
-
- 29 -
Raw MaterialRaw Material
ExtractionExtraction
ReactionReaction
CleaningCleaning
FiltrationFiltration
Doping
Slurry
CakeCake
CalcinationCalcination
Wet millingWet milling
Spray dryingSpray drying
PressingPressing
SinteringSintering
MgO pelletMgO pellet
SolventAdditive
1. 3
PDP 2001 97% 2005
55% , 1
.
- SDI (29.9%), LGE (25.1%), (23.3%)
3 , 2005 2004 60%
.
2005 $650, 2004 5 2
50%
.
- HD , PC , ,
-
- 30 -
.
PDP 2004 1 $1,311 2005 1
$840 . , 2005 PDP 42
400, 50 650
.
PDP 60% ,
, ,
.
,
. Pb RGB color
.
PDP 2008 PDP
CRT
1 PDP .
PDP PDP
.
-
- 31 -
PDP
PDP
PDP
(/)
seal
Bus
Adress
DRF
1. 4
1. 4. 1
PDP 1
60%
PDP , , ,
,
PDP PDP
,
Pb- PDP Pb-
,
, ,
PDP
-
- 32 -
road map. PDP
PDP
,
PDP
1. 4. 2
PDP
PDP PDP,
PDP ,
PDP
PDP ,
-
-
PDP
(
)
PDP ,
,
PDP
PDP
PDP
-
-
PDP
-
-
PDP
PDP
PDP
-
- 33 -
PDP
: ()
:
()
(LG)
(SDI)
()
(PDE)
()
(
)
(
)
()
()
()
()
()
()
()
1. 5
PDP
4, , 7,
2
2,
2 17
.
-
- 34 -
1. 6
PDP
- PDP
- :
PDP
- PDP
- PDP
PDP RFP
- PDP ,
, PDP PDP
7 RFP .
RFP .
- RFP 4
.
- RFP
PDP ,
, RFP .
- 4 ,
RFP , .
- PDP
, ,
, ,
, .
-
- 35 -
1. 7
2005.1 2005.4
1.15 1.30 2.15 2.28 3.15 3/31 4.15
1. 1
(PDP
)
2. PDP
3. PDP
4. PDP
5. RFP (/
)
6.
7.
8.
-
- 36 -
2. PDP
2. 1 PDP
,
, PDP (
43%- ) PDP
- / 8.8%.
- 80% ,
PDP /
, , ,
- Ag address, bus , ,
Dupont
.
- 7.2% , Ag
. Ag
.
- 50% .
(/)
- , frit PDP
3.4%
- , PDE,
, , ,
,
- C&Chem MgO
.
.
.
-
- 37 -
- MgO pellet E- Beam
PDP
green sheet
.
DFR
- DFR
, .
- 80
.
- SKC
.
- LG , ,
.
- LG, SDI
, , , ,
.
- CRT
,
.
- PDP #1, #2 Line frit(frit
ring) clip
, 2 line frit ring
,
.
- LGE soda glass
- Frit .
frit Pb
Pb free .
seal
- seal Pb ,
-
- 38 -
vehicle paste
.
filter
- filter
LG , ,
filter .
-
- 39 -
PDP,
(%)
()
8.8 ITO-
(AGC) ITO Coated Glass()
Ag
7.2
R&D(, ,
, ,
IMD, LG DRM)
(Dupont) Frit Glass &
Formulation
Black Stripe
Frit Glass
1.0
R&D(, LG DRM,
, IMD,
)
(Taiyo Ink) Black
Formulation
Frit Glass.
2.56
R&D
(,
PDE,
)
(AGC) Formulation
Frit Glass.
0.8
,
,
PDE,
,
, LG DRM
(AGC) Filler & pigment
Formulation
Frit Glass.
4.0
,
PDE,
,
(OKUNO) Filler & pigment
Formulation
3.0 LG, SDI
(KASEI) Formulation
filter
Filter 12.0R&D
(LG, SKC) (AGC)
Seal
Frit Glass.
0.4
R&D
(, ,
)
(AGC) Filler
Formulation
. Penning Gas 0.08
(PRAXAIR)
. MgO Single Crystal 1.76,
C&Chem
(Mitsubishu)
Preformed
Glass
Frit Glass.0.08
R&D
()
(ATG) Filler
Frit Glass.
0.08 , tube
DFR ITO
1.2
R&D
(, SKC,
)
(TOK) .
-
- 40 -
2. 2 PDP
2. 2. 1 (PDP, PDP)
PDP '04 $387(350)
'05 $650(647) 90% (80%)
, '08 1,575 (1,310)
.
PDP 02 40
- 02 40 50% LCD TV
50 40
- '06 50" TV '08
76% .
PDP ( : $)
2000 2001 2002 2003 2004 2005 2006 2007 2008
(%)
4,365 8,900 16,120 22,770 38,780 64,730 98,040 133,270 157,545 64.5
: PDP , , 2003
'04 PDP
1 PDP
.
- 2002 FHP 34.3%, NEC
20% SDI LG 11% .
- 2004 SDI, LGE 44.3%, 4 55.7%
, 2002
.
-
- 41 -
PDP (:, $)
Class2003 2004 2005 2006 2007 2008
(%)
30" 271 418 505 632 665 656 19
40" 1,207 2,506 4,545 6,227 7,430 8,390 47
50" 231 522 1,136 1,986 2,662 3,671 74
60" 22 35 126 181 333 393 78
1,731
(22,770)
3,481
(38,780)
6,312
(64,730)
9,025
(98,040)
11,090
(133,270)
13,110
(157,545)50
: 2004, ( )
PDP (:)
2003 2004 2005 2006 2007 2008
(%)
SDI 336 850 1,700 2,500 3,100 3,400 58.9
LGE 288 780 1,600 2,300 2,800 3,200 61.9
Orion 9 40 40 40 100 100 61.9
FHP 408 630 1,000 1,200 1,800 2,200 40.1
Matsushita 329 780 1,400 2,200 2,500 3,000 55.6
Pioneer 143 270 300 500 800 1,200 53.0
NEC 188 220 200 300 400 480 20.6
Formosa 10 60 60 120 160 200 82.1
CPT 20 50 50 120 160 200 58.5
1,731 3,680 6,350 9,280 11,820 13,980 51.9
: 2004
-
- 42 -
PDP 20041,389 2006
3,241 50% TV
.
1 PDP 2 2004 70
ITO
250 .
2004 205, 2006 479 50%
PDP , .
(/)
2002 40 2004
96 .
PDP ( : )
2002 2003 2004 2005 2006
10,511 16,445 25,096 38,954 58.546
8,600 13,445 20,533 31,872 47,902
Black Stripe 1,194 1,869 2,852 4,427 6,653
3,085 4,784 7,301 11,332 17,032
956 1,495 2,281 3,541 5,322
4,778 7,475 11,407 17,706 26,612
3,583 5,606 8,555 13,280 19,959
Filter 14,333 22,426 34,222 53,119 79,836
Seal 4,778 7,475 11,407 17,706 26,612
956 1,495 2,281 3,541 5,322
2,102 3,289 5,019 7,791 11,709
Preformed Glass 956 1,495 2,281 3,541 5,322
956 1,495 2,281 3,541 5,322
DFR 1,433 2,243 3,422 5,312 7,984
60,193 93,051 138,940 215,664 324,133
: PDP , , 2003
-
- 43 -
2004 114, 2006 266
PDP . PDP
frit
.
ITO display
2000 112 2004 156 2005
162
2001 500m
80% (400m) .
Display
ITO
.
Display ITO
1998 1999 2000 2001 2002 2003 2004 2005
(t) 110 120 150 170 190 215 230 250
(%) - 109.1 125.0 113.3 111.8 113.2 107.0 108.7
() 9,350 10,200 11,250 11,900 13,300 14,600 15,600 16,250
(%) - 109.1 110.3 105.8 111.8 109.8 106.8 104.2
: ITO ( )
ITO
PDP
LG,
SDI .
-
- 44 -
PDP
.
DFR
2004 DFR 34, 2006 803
.
DFR 5 50%
DFR PDP LDI DFR DFR DFR
20% .
40%
10% .
LCD, PDP 50%
.
- DFR ,
DFR
.
DFR (x 104 m2)
2004 2005 2006 2007 2008
PDP
ITO 190 350 500 610 720
Rib ()
190 350 500 610 720
LDI DFRPDP, PCB,
250 270 280 300 310
: 2004 Display bank
LDI DFR DFR (PCB, PDP) 1.0% ,
.
2004 $22.8 2006 $53.2 PDP
-
- 45 -
0.08 % 0.15 %
PRAXAIR
2. 2. 2 (PDP, PDP )
2003 42 2,330
206 224 4,567
,
,
- 70% , 42"
HD
.
PDP
2003 2004 2005 2006 2007 2008 2010 2012
(%)
() 42 90.7 149.4 224 340 573.6 1,638.2 4,679 67
() 2,330 3,477 3,947 4,567 6,052 7,686 12,396 19,995 27
: PDP ,2004. 6,
2003 7,525
2004 11,888 2006 33,710 68.5%
.
- 2003 4,111, ITO 1,600,
540, 448
.
DFR 2003 30
-
- 46 -
(93 m2 21%
DFR (PDP)
79%
21%
350 100
93 30
DFR
- PDP , IT
.
2004 PDP 60% , 2006
PDP 50% .
- LG JSR, SDI
LG PDE, SDI
. PDP
,
.
- 2003 PDP
.
-
PDP PDP
.
-
-
- 47 -
-
- 48 -
PDP (:)
2003 2004 2005 2006
2,480 2,861 3,920 6,322
ITO 1,600 1,840 2,337 2,968
(540) (810) (1,350) (1,822)
Black Stripe 187 280 420 630
(93) ( - ) (298) (535)
(30) ( - ) (120) (130)
(114) ( - ) (340) (587)
(48) ( - ) (123) (197)
Filter 448 672 1,008 1,512
Seal (54) (84) (135) (209)
30 45 67.5 101.3
157 157 267 371
Preformed Glass 30 45 67.5 101.3
53 80 120 180
DFR 30 45 67.5 101
5,894 6,919 10,640.5 60,193
():PDP , 2003,
( ) , 2004, , , , , Seal
.
1$=1,150, 1=10
: PDP Cap
(2004 70%, 2005 80%, 2006 90%)
-
- 49 -
2. 2. 3 PDP
< PDP >
PDP 2004 4 4
(3,841) 2005 8 9(7,000), 2012 26
1(21,180) .
- , , LCD,
DLP 40
PDP
PDP
2004 2006 2008 2010 2012
(%)
()3,481
(05-7,000)
9,025
(10,500)
13,110
(07-13,500)17,036 21,180 28
() 44,597 112,746 181,176 217,411 260,89320
(08)
: 2004 ; 1$=1,150
PDP
, ,
. TV
.
- TV , TV,
,
.
- 40 PDP .
- PC TV
PDP TV
- 2004 2006
2008
2000 2002 40% 2002
2005 42
400
-
- 50 -
marking
PDP TV
.
PDP 2000 2002 17 ,
2003 64
- 2004 3,477(90.7) 50%
2012 19,995(4,679) 22%
.
- PDP SDI LGE
.
- ,
..
42 HD
.
2. 2. 4 PDP
PDP 1
, SDI LGE
.
- 43% .
PDP
.
-
- 51 -
-
PDP 5080%
, 5
.
.
- PDP PDP
.
- AGC PD-200
- PDP
/
PDP 50% PDP 60%
, PDP
.
Seal
Seal 2005 30%, 2006
50% .
.
, marketing
.
, , ITO
( 500m) 90% .
In ITO
.
-
- 52 -
- ITO 1500ton In
.
- 2006 ITO
ITZ () , 10
. .
In 2003
419ton 494, 2004 496ton
500ton .
2006 900ton .
, In 2004 10 , $840890/kg,
2004 2 ( 100 )
- 1kg $600
ITO ()
2003 2004 2005 2006 2007 2008 2009 2010 2011 2012
() 1,600 1,840 2,020 2,200 2,400 2,800 3,200 3,700 4,200 4,800
* : 15% , PDP LCD display .
Bus / Adress
PDP
10%
.
Ag Ag
Ag
green sheet
green sheet
.
-
- 53 -
PDP .
.
- 2004 400 2008 6,400, 2012 10,307
.
-
PDP
,
.
70% 30%
SDI, LG .
( : )
2000 2002 2004 2005 2006 2007 2008 2010 2012
5 92 400 1,600 3,200 6,400 7,040 8,518 10,307
: Display Bank 2003 CMRI-2003 2004 2007 200%
, 2008 2012 10%
DFR
PDP DFR
40% . DFR
LDI DFR 50%
.
PDP PDP ITO
Rib () DFR
. ITO PDP
DFR ITO
,
DFR
-
- 54 -
.
2. 3 PDP
2. 3. 1
PDP .
KCC PDP
PDP
- , AGC
PD200 .
- Central, NEG, (NSG) PDP
.
.
PDE Pb ,
PDE .
, PDE Pb
Pb free
seal
Pb , LGE ,
seal paste .
- 2001 8
-
- 55 -
ITO ( 1.5 )
.
Glass Coating
, , IGC, , ITO Coating
50% .
- Energy, Dowa, Tosoh ITO
(Indium
) .
ITO
,
AZO, IZO
.
Bus/Address
Ag .
- LG DRM, IMD, , ,
, .
- Glass , PDE .
LG SDI .
PDP
PDP
.
MgO MgO Pellet
, Panel 7ton
.
DFR
DFR LG, , ,
-
- 56 -
.
Performed glass
frit ring performed glass
PDP
Soda glass LGE, Pb
SDI .
2. 3. 2
PDP
. PDP , Contrast,
.
- Sodalime KCC
.
(/)
Pb
/ Pb-free
, .
()
SDI
.
sheet ,
, .
-
- 57 -
PDE,
. Paste
, LGDRM, IMD, .
, , , .
Seal
PDP seal frit PDP
seal , paste
.
* PRTR(
) (WEEE, RoHS)
, 2002
.
- () , () , () seal
.
,
.
- SnO-P2O5, ZnO-P2O5, V2O5-P2O5,
B2O3-SiO2, Bi2O3 , ,
.
ITO
. ITO (nodule)
SnO2
. .
- 1991 6.7g/cm3 , 1994
7.0g/cm3 , 1998 7.067.1cm3 .
1990 70% 85%, 95%, 98%
99% .
-
- 58 -
ITO
.
paste , .
PDP
Ag paste
.
- Dupont .
Ag paste
.
,
.
- LG, SDI .
- , KIST, KAIST, , ,
.
MgO
.
. C&Chem MgO
.
.
PDP TV
.
.
MgO Pellet Doped MgO , green
sheet .
-
- 59 -
.
.
DFR
DFR , DFR
.
,
LDI (Laser Direct Imaging)
.
.
Xe
PDP ,
.
, Pb free PDP
.
2. 3. 3 (, )
PDP , ,
.
Ashahi 79.4%
PDP .
CPT, 1PDC .
-
- 60 -
2.8mm 1.8mm
,
.
.
- / ,
PDP .
(NEG), Noridake, Yamamura, Okuno
PDP ()
.
PDP
- , , , , ,
.
, ,
SDI, LGE, CPT ,
PDP .
Pb-free
.
seal
Seal Pb ,
Pb-free paste .
ITO Japan
Energy, DOWA, Tosoh , 80%
.
-
- 61 -
(2001)
(t) (%)
Japan Energy
51
50
46
23
30.0
29.4
27.1
13.5
170 100.0
: ( )
ITO
.
- Japan Energy, , 3 85%
. , Japan
Energy .
KASEI optonics 67.5% Nichia
chem() OSRAM sylvania() 22%
KASEI optonics .
, , RGB
.
, ,
, , .
-
- 62 -
/ (%) , ()
(79.4),
,
-LG, , CPT
-CPT, IPDC ,
()
65" -6500
50" -6000
42" -3000
- (2.81.8)
-Glass
(39.3), JSR,
Target (37.6)
-LG, , CPT
-CPT, FPDC
Cr/Cr 130,000/kg,
Cu 80,000/kg
Al 67,000/kg,
Ag paste55,00065,000/kg
Ag 30,000/
-Tape,
JSR(53.4), (25.7),
, , ,
,
-LG,SDI,CPT
- CPT, FPDC
Pb paste 7000
9000/kg
Pb 550
06500/kg
-Pb-free paste
B2O3 ()
-Zn
(26),
(24), (21.6),
(19.2),
(9.2
-
-, 500,000800,000/
-
-
(68.6),
(31.4)
-
-LG, SDI, CPT
-CPT , IPDC
High-end 10001500/
Low-end 5001000
-(
)
-Pb-free paste
(B2O3, ZnO)
(53), (18.5),
(13.5),
(15)
-SDI, LG, CPT
-CPT, FPDC
Pb
paste 55006500/kg,
paste paste 850
09500/kg
Paste
KASEI(67.5), NiChIA
(11.9), (10.0),
OSRAM Sylvania(1), LG
(3.1)
-LG
-LG, SDI, CPT
-CPT, FPDC
paste (3) 62000
67000/kg
-
Blue , ,
Green (
), Red
IC
NEC(63.2), (20.1),
IT(16.6)
-LG, SDI, CPT
-CPT,FPDC
(33.9), (32.9),
(19.4), ,
-, ,
-, ,
set ,
50" Ag 23,000/
50" Cu 28,000/
50" 25,000/
Asahi glass - LGE
EMI (41.9), DNP(26.8),
(24), ,
- 2, ,
-, , ,
50" 50006000/
50" 4000/
50" 20003000/
TATEHO( 504.),
MITSUBISHI Mat.(MgO ),
Konoshima, Deudsea Periclase
(), Paultec
- LGE THP,
NEC, Pioneer, Matsushita
: Fuji chimera , 2003 (2003)
-
- 63 -
2. 3. 4
(1) : .
(2)
2001 PDP PDP
.
G-7, 21C ,
, , PDP
PDP
.
- 1995 2001 : G-7
.
- 2002 2008 : 70 HDTV PDP .
- 2003 2005 : PDP, , TCP
.
- 2004 2007 : PDP
.
- 2004 2009 : PDP
.
- 2004 2008 : PDP
.
, , ,
.
PDP PDP
PDP
.
PDP
.
-
- 64 -
- PDP 42 KCC 04
07 .
70 HDTV PDP (, 02. 10-05. 0 3)
.
Seal
() PDP
410 sealing frit
.
PDP, , TCP (
: ) .
SDI PDP
Red/Green/Blue powder
.
MgO , (MgO)
target .
DFR
" PDP "
405nm LDI DFR 2004
.
filter
PDP PDP
.
-
- 65 -
()
()
()
PDP ,
,
TCP
(
())
SDI
03.0705.06
(3)
42.37
(21.18)
-:PDP Paste
-Paste , Panel
-(,,vehicle)
- paste ,test panel ,
-
:PDP
TCP: PDPmoduleTCP driver package
PDP
(
())
LG
04.1007.09
(1)
04.1009.09
()
122.4
( 61.2)
100 FHD PDP
Public/home theater PDP
50 HD PDP 4, 42 HD PDP 8
-size100 1200cd/, 3000, >19201080,
60,000hr, 990W, >90%
-LDI(laser Direct Imaging) DFR,
- reset
- PDP sealing frit
-
- PDP
- : up
PDP
-90 , 42 4 ,
2
Dead zone free Multi-PDP
-150multi PDP,509(33)40982304seam 3
70 HDTV
PDP
(
()
SDI,
LG,
PDP,
,
02.1005.03
(1)
133.13
(61.85)
60 HDTV PDP
- PDP
- cell /
-PDP micro plasma (,)
-HDTV PDP
, dispensing
,
Bus ,
ink-jet
-
- 66 -
70 HDTV
PDP
(
()
(LG,
SDI, UPD,
PDP,
,
)
05.04
(2)
70 HDTV PDP
- PDP (LG)
- PDP (SDI)
- PDP (UPD)
- PDP (PDP)
-PDP micro plasma ()
-HDTV PDP ()
PDP
(
)
LG
PDP
(04.10
07.09)
145.67
(89.54)
PDP glass(42)
-, PDP ITO glass
- PDP glass
- 85%, 15/
-42 6 , ITO coated glass
PDP IC
-PDP data driver IC
- PDP IC package
-channel 256, 70mm wide TCP
PDP
- PDP
-EMI class B, 95% , flim filter
-
green sheet
-(PbO-free) green sheet
- 85%, 1215
-
Green sheet
-PDP , sheet slurry
- 2.6
-
PDP
(
())
RIST
(04.1108.10
(4, 1)
04.1107.10
(3))
36.75
(27.25)
PDP (,,) RF plasma
- paste
(,RIST)
Paste (screen ink jet)
-(MgO) target
(, RIST)
MgO
MgO
MgO paste
-
(, RIST)
Pb-free
paste (screen dry film)
- (RIST)
-
- 67 -
2. 4
2005 SDI, LGE, PDP PDP
53% 1
CRT 2 display .
- , PDP FHP, NEC,
Pioneer, Matsushita, AU optronics(), CPT, Formosa()
.
PDP 1
.
-
.
PDP 1 PDP
PDP
,
PDP
.
-
- 68 -
3.
3. 1 PDP
3. 1. 1
PDP .
3. 1. 2
PDP .
PDP
PDP, , (
, tack time , IC, IC )
Glass , , , , , , Frit seal, Filter
Pb-free, , EMI , , ,
( , Contrast , , counter
noise ) ,
(fine pitched ), MgO
, frit pitched
3. 2 PDP
3. 2. 1
Asahi, NEG, Noritake Pb
Pb-free
.
-
- 69 -
Pb-free
, .
KCC
PDP .
(/)
Pb glass frit, Zn Glass frit, Pb-free
glass frit , Pb free
.
PbO
.
Bi2O3
Bi2O3 PbO 8
.
1015
Ag .
R2O(Na2O, K2O )
10%
.
/
screen printing
sheet
dry film .
-
- 70 -
: PbO, ZnO ,
: PbO, Al2O3,
TiO2
(80%), /
,
, ( 530~580)
, (6585)
, filler, pigment ,
, ( 550)
Seal : PbO , Pb-free
,
ITO , NESA , , ,
, /
(Bus/Adress) Cr, Ag
, , , ,
,
, .
,
.
Glass
(float )
: MgO
,
sputter, 2
.
,
BaO-MgO-Al2O3 : Eu
Zn2SiO4 : Mn(Y,Gd)++
, , , ,
, sputter
, ,
VUV
: Soda-lime glass,
glass
Press frit
Fliter (), scratch,
(100),
PDP
-
- 71 -
(/ )
()
Glass Frit
(PbOZnO
)
(>70%)
(>3.0kV)
Tg=460
53
58
=80510-7/K
,
,
,
,
()
Glass Frit
(PbOAl2O3,
TiO2 )
(>70%)
(>1.0kV),
()
PbO() Bi2O3 BaO-ZnO P2O5
PbO-SiO2-
B2O3-Al2O3
Bi2O3-SiO2-B2O3
-Al2O3
(Bi2O3: 2050%)
BaO-ZnO- SiO2
-B2 O3(BaO:520%,
ZnO:1020%)
P2O5-ZnO-SiO2-
B2O3
,
Pb
-Pb
( )
-
Bi2O3
,
,
-
()
-Pb
PDE
,
.
PDP
straining point 600 .
-
- 72 -
,
, 912 .
.
paste doctor blade
tape green sheet
sheet .
PDP PDP
200300 150
(barrier rib) . PDP
, .
seal
Pb
50-60%
.
2000
.
, ,
.
ITO
, (In) ( 9095%)
ZnO ITO 200
ITO . ITO
ITO
,
.
SnO ITO, ZnO , ,
-
- 73 -
, ,
.
- SnO
Sb, Cl, F, P +5 ,
Sb, Sb SnO
ATO(Antimony Tin Oxide)
- ATO SnO
SnO2 10
- SnO
(lift-off)
ITO
,
size .
SDI PDP ITO Coating
LG 76 PDP ITO Coated Glass
, Glass Coating .
PDP , LG ITO coating
, SDI PDP ITO coating
.
( )
SDI, LGE PDP
green sheet
.
Ag Vehicle
.
.
PDP
-
- 74 -
.
, LG, SDI
.
- know-how
.
- , ,
, .
PDP , , , Single
Scanning MgO
.
PDP () ()
,
, .
-
.
- Jitter,
.
() ()
,
, PDP ,
, HD .
.
Jitter
,
-
- 75 -
.
DFR
LDI
,
DFR
.
,
, .
Glass frit PDP ,
, .
3. 2. 2 PDP
AGC NEG 5%
NSG, Saint Gobain,
Central Glass
.
PDP , ,
glass .
.
2
, 4 , 6
.
, , ITO coating
.
-
- 76 -
(/)
AGC, Noritake
. PDP
.
contrast
, , IC chip driver
, .
PDP
,
.
,
.
paste
paste .
Bi, B2O3-ZnO , vehicle
Seal
, NEG, , PbO
, .
Bi P2O5 Pb free
- P2O5, ZnO-B2O3, Bi2O3
, PbO .
- PbO
, ,
2002
SDI, LGE
.
-
- 77 -
size PDP ITO coated glass
.
- ITO coated glass
Asahi NEG .
ITO .
- ZnO
.
- 2004 1 TCO
1m .
YbFeO
Homologous (00l)
.
- InGaZnO, InO(ZnO)n, GaZnO (ZnAl)O
.
.
- GdGeO, CdPbO, AgSbO ,
ITO
.
paste Dupont, , ,
, DOWA, .
- Glass Asahi, NEG, Noritake
.
NEC PIONEER JSR(Japan Synthetic
Rubber)
, green sheet
. JSR sheet
-
- 78 -
.
.
.
.
.
PDP ,
, MgO
(MMC) .
Doping MgO pellet .
- PDP Pellet
PDP MgO
PDP Panel Maker Pellet
PDP
.
DFR
PDP DFR
.
-
.
Asahi
glass frit FHP, NEC .
Glass Frit
PDP .
-
- 79 -
, .
PDP
1995 2002 2004 2006 2008 2010
(%)
70 %
(Pb)
(Pb-free)
(Pb)
(Pb)
(Pb-free)
(Pb)
(Pb)
(Pb-free)
(ITO)
(Pb)
(Pb)
(Pb)
(Pb)
(Pb-free)
/
Filter
Seal
* : -, -
-
- 80 -
3. 2. 3 PDP
data .
ITO coated glass data .
ITO coated glass
(%)
15/
70
4-point Probe
85% UV-VIS Spectrophotometer
m
250sec Stop Watch
(/)
PDP .
.
()
.
PDP Pb
Pb-free
PDP
.
PDP ,
-
- 81 -
.
- matrix, filler , ,
,
( filler
0.6Mpam) 2
.
- sandblasting
- leadborosilicate PbO 5075wt%
lead-free glass
.
(53), (18.5),
(13.5) PDE .
45%
.
Seal
Seal() , ()
.
() , () , ()
,
.
ITO Target
, 80% .
Green sheet 0%
.
-
-
- 82 -
20~30% .
/
ITO
Sn
Grain size
80%
90%
ITO Glass Target Sputtering
70%
Sensitivity 400mJ/cm2
20 %
Resistivity(10 )3.7 10
-6,# Conductor: 2.6 10-6
,# Black: 10-3 10-4(ohmcm)
Pattern Profile edge curl 4 & no under cut
Line Resolution 40
Firing Temperature 580
Uniformity at Sheet 1.0
30 %
Uniformity after firing 0.5
Matching with Glass & Dielectric No coloring & bubble
Sheet Stability 6month
LG SDI PDP PDP
.
.
CMS
-
- 83 -
MgO
dopant
.
MgO
.
DFR
DFR
,
, LDI DFR
.
LDI
.
PDP
PDP
2005
.
PDP ,
, PDP
, ,
.
.
-
- 84 -
3. 3
-
- 85 -
2003 2004 2005 2006 2007 2008 2009 2010 2011 2012
Ag 1 3 0.1 2 0.1 1
80, 40 50, 50 30, 20
Laninator
(80%)
(70%)
Green Sheet ,
(80%),
(90%)
(80%)
Glass paste
, ,
Aspect ratio
Film
Dry Film Resist
Resist ,
ITO : , ,
MgO MgO MgO
2%5%, 95% 5%9% 98% 9%15% 98%
MgO
Filter 1,000
: 96%
: 80%
: 10-4
: 98%
: 85%
: 10-3
: 99%
: 90%
: 10-3
3. 4
3. 4. 1
, ,
40 HDTV
.
. PDP
,
PDP Pb
Pb free ,
-
- 86 -
.
PDP
.
3. 4. 2
6 (, , , , , )
, '83 '04 () ,
, .
3. 4. 3
PDP 1989. 1. 1 2003. 12. 31 , ,
, PDP 26
,
.
-
- 87 -
3. 4. 4 PDP /
(Pb )
sheet
paste
,
ITO
ITO
ITO
(Pb )
sheet
paste
,
MgO
MgO
MgO
(Pellet,
Paste, Film, Sheet,
)
, MgO
Glass frit(Pb )
Glass frit(Pb free)
,
Ag
Ag
paste
PDP ,
3
- SDI .
-
- 88 -
.
0
50
100
150
200
PDP
,
.
0.71 ,
.
0.58 ,
.
-
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0
0.2
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0.6
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1
1.2
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97
, , .
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.
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.
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.
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.
-
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1
1
2
2
2
3
4
7
8
8
9
9
9
10
13
13
15
17
17
19
20
20
22
27
0 5 10 15 20 25 30
EB
M gO DB
M gO DA
Ag FB
Shee t AC
DE
BC
AE
Ag FA
C E
ITO BA
Pas te AD
EA
FE
C B
Pas te FC
AB
ITO BB
M gO DC
DD
Shee t C C
AA
Pas te C D
C A
PDP
PDP
MgO MgO
17 .
93 03 1
.
(90)
13 .
-
- 91 -
0
2
4
6
8
2 2 2 4 4 1
3 3 2 2 5 2
1 3 4 1 1 3
5 2 7 1 2 0
1 3 3 1 1 1
1997 1998 1999 2000 2001 2002
PDP
PDP
PDP ,
.
- ,
.
,
.
-
- 92 -
('98~'02)
-120%
-100%
-80%
-60%
-40%
-20%
0%
20%
40%
0 0.5 1 1.5 2 2.5
.
PDP ,
.
.
-
- 93 -
('98~'02)
-150%
-100%
-50%
0%
50%
0 0.2 0.4 0.6 0.8 1 1.2 1.4
-6.89%
PDP
PDP
,
.
9902
.
-
- 94 -
0
10
20
30
40
50
60
70
80
0 30 60 90 120 150 180 210 240
1: 1983~1990
2: 1991~1994
3: 1995~1998
4: 1999~2002
4
3
1 2
PDP
3. 4. 5 PDP /
PDP , Paste,
, , Sheet
.
ITO , ,
.
-
- 95 -
1
2
2
2
3
3
6
6
9
9
10
10
10
11
11
13
13
17
17
18
19
21
22
22
27
28
0 5 10 15 20 25 30
EC
M gO DA
EB
FD
Ag FB
M gO DB
BC
Sheet AC
AE
Ag FA
DE
Pas te AD
EA
ITO BA
FE
CB
CE
M gO DC
AB
ITO BB
Pas te FC
Sheet CC
DD
AA
Pas te CD
CA
PDP
PDP
Paste , , Paste,
.
, , MgO
.
MgO 8902 1
, MITSUBISHI 11
-
- 96 -
.
4
5
5
6
6
10
10
11
13
14
15
15
16
16
20
20
22
22
31
37
56
61
64
84
0 10 20 30 40 50 60 70 80 90
Sheet CC
MgO DA
BC
EB
ITO BA
Ag FB
ITO BB
MgO DB
DE
FE
MgO DC
CB
AE
AB
Paste AD
Sheet AC
Ag FA
EA
CE
DD
Paste FC
AA
CA
Paste CD
PDP
PDP
. ( )
(9702) 5
-
- 97 -
0
1
2
3
0 1 2 2 0 0
0 3 0 0 0 0
1 0 0 1 0 0
0 0 1 2 0 0
0 0 0 1 0 0
0 1 1 0 2 1
1997 1998 1999 2000 2001 2002
PDP
(9702)
.
02 ,
.
0
2
4
6
8
0 0 4 2 0 2
3 2 0 1 1 0
0 0 4 2 4 4
0 0 1 3 6 8
0 4 1 0 0 0
4 3 4 1 1 8
1997 1998 1999 2000 2001 2002
PDP
-
- 98 -
PDP
, PDP
. ()
,
.
- , ,
.
0.00
1.00
2.00
3.00
4.00
5.00
6.00
7.00
8.00
9.00
0.00 1.00 2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00
Backword
Fodward
PioneerInitiator
Wea
kness
Str
eng
th
0.00
0.05
0.10
0.15
0.00 0.05 0.10 0.15
PDP
PDP .
,
. ( )
,
.
-
- 99 -
0%
10%
20%
30%
40%
50%
60%
70%
80%
90%
0% 10% 20% 30% 40% 50% 60% 70% 80% 90%
0%
2%
4%
6%
8%
10%
0% 2% 4% 6% 8% 10%
PDP
( )
Asahi glass
, Mitsubishi, Hitachi
.
Mitsubishi MgO
.
Asahi glass
.
Hitachi
.
-
- 100 -
ASAHI GLASS 3 0 2 0 4 1 10
MITSUBISHI 0 2 1 6 0 0 9
HITACHI 0 0 5 0 0 4 9
MATSUSHITA 0 0 0 3 0 4 6
NEG 2 0 2 0 1 1 6
( : 8902)
3. 4. 6
(1)
, ,
,
PDP
,
Pb
/ Pb-free
,
sheet
PDP
,
,
-
- 101 -
,
(2)
6 (, , , , ,
)
6 PDP
,
,
.
PDP Pb
Pb-free PDP
.
, sealing frit filler
,
.
3.5
,
65 paste ,
paste .
-
- 102 -
Seal PbO sealing
50 60 seal
.
ITO (1/8) ITO
.
Ag
Ag
.
MgO
70% .
PDP
- 500
- 500
- 410 seal
PDP
-ZnO Roll to Roll
-ZnO
-
- doping
PDP
- metal base-Ag
- Ag ink
1
2
3
4
-
- 103 -
3. 6
PDP 1
PDP
.
- PDP
.
- Pb Pb-tree
.
- sodalime PDP
.
4.
4. 1
(1, 2), ,
- 1 , 2
1 2
1
PDP
2
-
- 104 -
4. 2
1 2
05 06 07 08 09
1
RFP-1
2PDP
RFP-2
3 RFP-3
4 PDP RFP-4
4. 3
4. 3. 1
(:)
2005 5,400 3,000 2,400
2006 9,000 5,000 4,000
2007 9,000 5,000 4,000
2008 9,000 5,000 4,000
2009 9,000 5,000 4,000
41,400 23,000 18,400
-
- 105 -
4. 3. 2
(:)
1 2 2005 2006 2007 2008 2009
7,000 5,000 12,000
PDP 7,000 7,000 14,000
4,500 3,200 7,700
PDP 4,500 3,200 7,700
4. 4
)
(: )
1 2 PDP 80 20 40 90 20 30 280
80 20 40 90 20 30
)
(: )
1 2 05 06 07 08 09PDP 40 50 50 70 70 280
40 50 50 70 70 280
-
- 106 -
5.
5. 1
PDP
PDP
PDP Panel ,
know-how
PDP display
FED(Field Emmision Display), EL
display
PDP
SDI, LGE PDP
PDP
PDP glass Frit FED LCD
PDP
5. 2
PDP size,
display
display 1 display
.
PDP
.
PDP
-
- 107 -
display
.
- PDP ()
/
Seal
PDP
.
PDP ,
.
- 2005 11,350
PDP
.
.
- 50 60
.
5. 3
PDP ,
display ,
, 1
PDP
,
.
PDP ,
, ,
,
PDP ,
-
- 108 -
6.
6. 1
PDP 1 PDP
PDP
- PDP 60%
PDP
soda-lime ,
65
PDP Pb Pb-free
PDP 45
infra Pb-free
Pb
PDP , PDP
,
PDP P-200
, PDP , P-200
, , , seal glass frit PDP
. ,
, sealing glass frit Pb-free
concept
bench-marking copy
.
R&D
-
- 109 -
,
, 43%
25%
(
) , ,
65
. sealing
seal 5060
seal
.
, , , seal, 50%
Pb 506
0 Pb-free .
PDP
item
PDP
PDP
-
- 110 -
6. 2
RFP
6. 2. 3
1 2 2005 2006 2007 2008 2009
PDP
PDP
-
- 111 -
7.
: PDP
-
- 112 -
/ ()(E-mail)1
018-276-3211
2 LG 02-526-4772, 019-336-3675
3 SDI 031-288-4611, 011-306-4446
4 032-814-1710, 011-787-5771
5 PDE
054-467-6630, 011-808-9808
6 02-2298-4545
7 02-2049-6010, 017-409-2751
8 02-320-1616, 017-261-0644
9 02-940-5236, 019-240-5236
10 032-860-7545, 011-9088-3730
11 KIST 02-958-5553, 011-358-5600
12 011-204-5873
13 042-481-5754, 010-3131-8679
14 02-3452-8144(805), 011-9952-2195
15 02-563-7963, 016-226-5425
8.
1. , " /", 1999
-
- 113 -
2. , "(IT) DT(Display Technology)
, 2001
3. ,
, 2001
4. , Display Sealing glass , 1998
5. , frit , 1995
6. , Ag-Pd , 1997
7. , glass frit , 1992
8. , MLCC Cu paste , 1999
9. , PDP Sealing glass powder , 2001
10. , Ag ITO ,
2004
11. , " 5 , ",
2003
12. , "",
2003
13. , "4(730920)HDTV OLED
, 2004
14. , "PDP
", 2004
15. Fuji Chimera Research Institute, Inc., "2004 ", 2004
16. , "4 In-line type OLED ", 2004
17. -- , "", 2004
18. , "21 1
", 2 ", 2005
19. , workshop
, 2005
20. , PDP , 2004