1 st meeting on priority substances inventory guidance copenhagen, 16.09.2010 frank...
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1ST MEETING ON PRIORITY SUBSTANCES INVENTORY GUIDANCECopenhagen, 16.09.2010
Frank Marscheider-WeidemannFraunhofer Institute for Systems and Innovation Research ISI , Karlsruhe
Substance Flow Analyses
The Fraunhofer Gesellschaft
The Fraunhofer-Gesellschaft is the leading organization for applied research in Europe.
80 research institutions, 57 of them institutes at 40 locations throughout Germany
Branches in Europe, USA, Asia and in the Near East
15,000 employees
Budget € 1.4 billion (>2/3 from research contracts).
The Fraunhofer-Gesellschaft in Germany
Itzehoe
BerlinGolm
Magdeburg
Hannover
Braunschweig
Bremen
OberhausenDortmund
DuisburgAachenEuskirchen
SchmallenbergSt. Augustin
IlmenauJena
Dresden
Chemnitz
Würzburg
Erlangen
Pfinztal
DarmstadtKaiserslauternSt. Ingbert
SaarbrückenKarlsruhe
Stuttgart
Freiburg
Freising
Rostock
TeltowCottbus
HalleSchkopau
Paderborn
Nürnberg
Efringen-Kirchen
MünchenHolzkirchen
Leipzig
Branches of Institutes, Research Institutions, Working Groups, Branch Labs and Application Centers
Institutes
57 institutesat 40 locations
Facts and Figures of the Fraunhofer ISI
Broadly based know-how
Clients
Budget 2008: approx. € 16 million
280 research and consultancyprojects per year
Number of staff: 170(120 scientists)
21% Social scientists
33% Economists
13% Industrial engineers
15% Engineers
18% Natural/life scientists
2,0% Research promotion
51,2% Public sector national
19,9% European Union
16,4% Industry
10,5% other R&D
Emission inventories for surface waters in Germany
• 1995: First methodological approaches to creating a German inventory, visiting federal states and examining how data are processed in regional databases. The use of electronic systems varies strongly between the single states (UDIS).
• 1995: Point source inventory including major industries and municipal waste water plants, using information from federal states, International Commission for the Protection of the Rhine etc.
Emission inventories for surface waters in Germany
• 2000: Inventory for N/P, heavy metals and AOX, subdivided into branches/sectors and main water bodies using the MONERIS/MORE model for information about diffuse sources. Compiling lists of the 10 major polluters for these substances, some are historical mines (from the Middle ages).
Firmenname Ort Anhang nach § 7a
Flussgebiet Fracht [kg/a] Bemerkung
BASF AG Ludwigshafen 22 Rhein 8.000 IKSR, 1998Bayer AG Leverkusen 22 Rhein 5.610 IKSR, 1998Entwässerung. Altstandort Kupferschieferbergbau
Mansfeld 39 Elbe 3.764 Direkteinleiter Sachsen-Anhalt 1997
Solvay Rheinberg 30 Rhein 1.210 UmwelterklärungWacker –Chemie Burghausen 22 Donau 1.200 Umweltbericht 1997/98Bayer AG Brunsbüttel 22 Elbe 1.110 Direkteinleiter Schleswig-Holstein 1997Norddeutsche Affinerie Hamburg 39 Elbe 523 Direkteinleiter Hamburg;
22 Elbe 506 N.N.Fa. Intraserv GmbH und Co. Höchst KG
Frankfurt 22 Rhein 460 Umweltbericht
Ciba Grenzach 22 Rhein 435 Umweltbericht
Top 10 polluter of copper
2000
gewerblichhäuslich
BurgfeyerStollen
NickelZink
0
10
20
30
Source: Erft Verband
Heavy metals from historical mines: Pollutant sources of the Erft
industraldomestic
t/a
Burgfeyer StollenZinc
Nickel
Results for copper (2000)
Material flow of copper: production, utilization and emissions to water and soil in Germany (2000)
NPEO-production54,500 t
Emulsion polymerization
4,000 t
1,400 t
Leather / Textile Auxiliaries
3,000 t
Construction chemistry2,000 t
Industrial cleaners1,000 t
Lubricating/Drilling Oils 800 t
Agricultural chemistry700 t
Flocculants 200 t
900 t (or 300 t)
2,000 (or 3,000 t
APEO)
1,000 t
Paints/Coatings 200 t
Others 300 t
600 t
300 t
200 t
100 t
300 t
ca. 660 t APEO
ca. 50 t + ?
ca. 1,000 t
?
ca. 270 t
ca. 200 t
? (low)
?
exports:42,500 t
imports:500 t
- 50%
- 70%
- 30%
+/- 0%
- 25%
- 60%
+/- 0%
- 50%
+/- 0%
in Germany processed amount
imports/exports
in Germanyused amount
relevant quantityfor waters
tendency
Sum: 12,200 t 6,800 t
Decline!
significant decline(< 100 t)
significant decline
substituted by 2001!
NP pro-duction36,300 t
Processingdomestic4,400 t
for NPEO-production19,600 t
Phenolic Resins3,700 t
Epoxide resins100 t
Manuf. NPEO-derivates 300t
< 1 t
? (low)Emissions during productionand processing
imports:2,800 t
exports:15,100 t
?
Processing in Germany
12,200 t
Trisnonylphenyl-phosphite 6,600t
Fluxes for the NP / NPEO-use and resulting emissions for D (1999/2000)
E xporte in Deutschlandverarbeitete M enge
in Deutschlandverwendete
MengeE m iss ionen in d ie
G ew ässer
NachnutzungsphaseProduktion Nutzung
75 g A nth racen
A nth racen-P roduktion
ca . 550 t
In D vera rbe ite teM enge: ca. 0 ,2 t ?
Im port vonK reosot:6 .000 t
?Im prägn ieren
von H olz30 t A n th racen
V erbrennungs-prozesseca. 9 ,3 t
99 ,9%
E xport30 .000 t
Teer
ölpr
oduk
tion
ca.7 t b le ibeninnerha lb der
E U
?
K reoso t30.000 t
(davon 30 tA nthracen)
E m iss ionenbe i V era rbe itung
E m issionen be iP roduktion
E inträge überN iederschläge
K lä ran lagen
E m issionen ausbehandeltem
H olz
?
Substance flow of anthracene in Germany
Emission inventories and SFA for surface waters
• Increased importance of emissions from end-user products, e.g. lead emissions from fishing or diving. Use of substance flow analysis is needed to find the best emission reduction measure (SOCOPSE, COHIBA).
• Timeline of uses: substances are banned, but found in water.
• SFA are a good tool to get data particularly for products, but they are normally static (e. g. difficulties with PAH emissions: domestic heating in winter)
Conclusions• Constructing emission balances are a prerequisite for an
efficient combination of measures to reduce pollution in river basin management
SFA CadmiumEU 27 (kg/y)
Consumption of foodWaste
Compost
WWTP
Air
Water
Land
SedimentHuman body
Fertilizers for agriculture and gardening Contaminatedsoil
Production of fertilizers
Car washing
Washing and cleaning,detergents
Tap water
Artist paintContaminated
sediments
Production ofNiCd batteries
Recycling plants forNiCd batteries
Land filling of municipal waste
Iron and steel production
Non-ferrous metal production
Combustion of fossil fuelsheat production
15.6
Low
?
Long rangetransport0.1
1.8
5160
5
8200
2600
4400
540
Stormwatertreatment
Pollutant in Zink,corrosion of materials
11
2200
Source: COHIBA, City of Stockholm
Development of domestic incineration in Germany
Development of particulate emissions from plants of the 1st BImSchV: increasing importance of emissions from wood fuels
BMU, 2007
WoodCoalOilNatural gasTotal
Starting to use MORE for other priority substances: PAH
erosion6.4%
surface runoff18.3%
tile drainage0.5%
urban systems29.8%
WWTP6.5%
atmospheric deposition
21.4%
groundwater6.5%
industry2.3%
inland navigation/leisure
boat8.2%
PAH emissions to water in Germany 2005