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866 Handbook of Paint Raw Materials

DUPONT CO.: TI-PURE Titanium Dioxide:

DUPONT white pigments for Coatings

Rutile Titanium Dioxide:

Grade:

R-100: Sp. Gr.: 4.2 % Min. Ti02: 97 Meets ASTM D-476 Spec: Type I1 Principal Applications: Interior gloss finishes--trade sales

and industrial

R-900: Sp. Gr.: 4.0 8 Min. Ti02: 94 Meets ASTM D-476 Spec: Type I1 Principal Applications: General purpose--especially high gloss

finishes

R-901: Sp. Gr.: 3.8 % Min. Ti02: 85 Meets ASTM D-47b Spec: Type 111 Principal Applications: General purpose trade sales--especial-

ly emulsion flats

R-902: Sp. Gr.: 4.0 % Min. Ti02: 91 Meets ASTM D-476 Spec: Type IV Principal Applications: General purpose for interior and

exterior finishes

R-931: Sp. Gr.: 3.6 8 Min. Ti02: 80 Meets ASTM D-476 Spec: Type I11 Principal Applications: High PVC interior and exterior flat

emulsion and alkyd paints

R-960: Sp. Gr.: 3.9 % Min. Ti02: 89 Meets ASTM D-476 Spec: Type IV Principal Applications: Exterior finishes requiring outstand-

ing gloss, tint retention and chalk resistance.

Titanium Dioxides 867

DUPONT CO.: TI-PURE Titanium Dioxide(Continued):

DuPont white pigments for Coatings(Continued)

Rutile-Slurries:

Grade:

R-940: Slurry Density: Lb/Gal: 19.5 % Solids: 76.5 Brookfield Viscosity cp: <lo00 Principal Applications: Aqueous

gloss. Slurry counterpart of R-900 coatings--gloss and semi-

R-941: Slurry Density: L b / G a l : 15.8 % Solids: 64.5 Brookfield Viscosity cp: <SO0 Principal Applications: Aqueous coatings--high PVC flats.

Slurry counterpart of R-931

R-942: Slurry Density: Lb/Gal: 19.4 % Solids: 76.5 Brookfield Viscosity cp: <lo00 Principal Applications: Exterior aqueous coatings. Slurry

counterpart of R-902.


DUPONT CO.: TI-PURE Titanium Dioxide(Continued):

Product Description:

TI-PURE R-100 is a very low binder demand, easy dispersing pigment of interest for interior industrial and trade sales applications.

TI-PURE R-900 (R-940 Slurry) offers particular advantage in high gloss and semi-gloss finishes because of its high hiding power at low pigment volume concentrations plus excellent brightness, ease of dispersion, gloss and cleanness of tint. Its chalk resistance is satisfactory for many exterior trade sales paints. Accordingly, it can be considered as general purpose pigment.

TI-PURE H-901 has outstanding hiding efficiency in all types of flat paints and finds wide acceptance in emulsion paints.

TI-PURE R-902 (R-942 Slurry) has an excellent balance of chalk resistance and optical values in a broad range of exterior finishes. It is recommended for its high quality performance in automotive refinish and exterior trade sales paint. High level of chalk resistance in addition to its optical properties make it a multipurpose pigment for both interior and exterior coatings.

TI-PURE R-931 (R-941 Slurry) provide a good balance between hiding power and film integrity in high PVC flat pigments. They are most efficient in paints containing 2.0 lb. or more Ti02 per gallon with the PVC ranging between 45% and 608.

TI-PURE R-960 provides outstanding chalk resistance, tint retention and gloss retention along with excellent low-shear dispersion, color acceptance (resists flocculation) and hiding power. Because of its excellent exterior durability, it is the pigment of choice for automotive OEM topcoats and coil coatings for residential and industrial siding.

TI-PURE Rutile Slurries retain the performance properties of their respective dry TI-PURE counterparts. However, they offer significant advantages in ease of handling, reduced waste, lower raw materials and dispersion costs.


KERR-MCGEE CHEMICAL CORP.: TRONOX Titanium Dioxides:

TRONOX Chloride Process Titanium Dioxide CR-800:

TRONOX CR-800 is a low oil absorption treated rutile pigment produced by the chloride process. It has high gloss producing properties for interior trade sales paints and industrial coatings. It may be used in exterior applications where the maximum chalk resistance of CR-822 is not required. It exhibits high brightness and excellent tint strength in gloss and semi-gloss enamels.

pigment for letter press, gravure, polyamid, and other inks. CR-800 is also recommended as high gloss, low abrasivity

Typical Properties: Ti02 content, minimum Density

Specific gravity As pounds per gallon One pound bulks-gallons

Oil absorption Water demand PH Specific resistance Average particle diameter Chalk resistance Specification

95%

4.1 34.4 lb/gal 0.0291 gal/lb 17 lb oi1/100 lb pigment 18 lb water/100 lb pigment 7.0 11,000 ohms 0.23 um medium ASTM D 476-73, type 11, 111

TRONOX Chloride Process Titanium Dioxide CR-800PG:

TRONOX CR-800PG is of great advantage when used in those plastics applications requiring a blue white, excellent dispersing Ti02. In addition to its high tinting strength it also exhibits comparatively low abrasivity.

ethylene film and vinyl sheet goods. It is also used in most other common plastics applications. It meets the Plastic Pipe Institute's guide-lines for formulation substitution and is authorized by the National Sanitation Foundation for general interchangeability in NSF-listed formulations.

CR-800PG has found wide acceptance in powder coatings, poly-

Typical Properties: Ti02, content, minimum Solid density Bulk density Oil absorption Average particle size PH Specific resistance Grit on 325 mesh, maximum

95% 4.1 g/ml 40-55 lb/cu ft 17 lb o i l / l O O lb pigment 0.19 um 6 .O-8.0 7600 ohms 0.004%


KERR-MCGEE CHEMICAL CORP.: TRONOX Titanium Dioxides(C0ntinued):

TRONOX Chloride Process Titanium Dioxide CR-800s:

TRONOX C R - 8 0 0 s is the slurry counterpart of TRONOX CR-800. The high gloss producing and strength properties of CR-800 have been preserved in its slurry form.

TRONOX CR-800s is recommended for interior gloss and semi- gloss water-borne coatings, as well as exterior water-borne coatings where the maximum durability of CR-822 is not required

supplemented with functional extenders to obtain the required dry hiding properties.

Specifications:

TRONOX CR-800s may also be used in flat coatings when it is

Solids 76.5+-1% Volatile water Density 19.3-19.9 lb/gal Viscosity @ 100 RPM 300-500 CP PH 8.5-9.5

Typical Viscosity Profile: RPM Viscosity, cp 100 400 50 650 20 1300 10 2300


TRONOX CR-801 is a medium oil absorption treated rutile pigment produced by the chloride process and is designed as a general purpose trade sales pigment. It is characterized by high brightness and high strength at all pigments volume concentrations such as in gloss enamels, semi-gloss enamels, satin and flat latex paints, and flat solvent thinned paints. It may be used in exterior coatings where the chalk resistance of CR-821 or CR-822 is not required.

Typical Properties: Ti02 content, minimum 93% Density

Specific gravity 4.0 Scattering coefficient per pound Ti02

In enamels 4.2 In flat latex 3.7

Oil absorption 26 lb oi1/100 lb pigment Water demand 30 lb water/100 lb pigment

Specific resistance 6000 ohms Average particle diameter 0.24 um Chalk resistance medium Specification ASTM D476-73 Type 11, 111

PH 7.5


KERR-MCGEE CHEMICAL CORP.: TRONOX Titanium Dioxides(Continued):


TRONOX CR-813 is a high oil absorption treated rutile pigment which has been designed specifically for interior flat architectural paints, both latex and solvent based, where it exhibits outstanding brightness, highest strength and an exceptionally clean tint tone. A change to CR-813 from lower dry hiding pigments in such finishes permits formulators to achieve equal opacity at lower cost, with no loss of film integrity.

ment for low gloss water based flexographic inks. TRONOX CR-813 is also recommended as the highest hiding pig-


Specific Gravity Scattering coefficient per

In enamels In flat latex


87%

3.85

3.9 4.4 36.5 lb oi1/100 lb pigment 44 Ib water/100 lb pigment 7.5 6000 ohms 0.25 um medium ASTM 476-73 Type I11

pound Ti02


TRONOX CR-813s is the slurry counterpart of TRONOX CR-813. The excellent high dry hiding properties of CR-813 have been preserved in its slurry form.

coatings, such as flat latex wall paints and ceiling tile and paper coatings.

Specifications:

TRONOX CR-813s is recommended for interior flat water-borne

Solids 64.5+-1% Vola ti le water Density 15.6-16.2 lb/gal Viscosity k? 100 RPM 125-250 CP PH 8.5-9.5

Typical Viscosity Profile RPM Viscosity, cp 100 170 50 270 20 490 10 800




TRONOX CR-821 is a treated rutile pigment produced by the chloride process. It has been designed to be a universal high gloss pigment for both interior and exterior film application. It has a high initial gloss, ease of dispersion, opacifying power and good exterior weathering properties.

CR-821 is recommended for all classes of coatings: architectural, industrial and maintenance; solvent thinned or water thinned; interior or exterior.

Typical Properties: Ti02 content, minimum 928 Density

Specific gravity 4.0 Scattering coefficient per pound Ti02

In enamels 4.1 In flat latex

Oil absorption Water demand

PH Specific resistance Average particle diameter Chalk resistance Spec if icat ion

3.0 18.6 lb oil/LOO lb pigment 21.0 lb water/100 lb

pigment 7.8 6,500 ohms 0.22 um high ASTM D 476-84 Type II1,IV

TRONOX CR-821s

TRONOX CR-821s titanium dioxide pigment slurry is a water dispersion of TRONOX CR-821. It is recommended for all classes of interior or exterior water thinned coatings, inks, and adhesives.

latex paints. Its high gloss and strength properties make it especially suitable for gloss and semigloss finishes. With selected functional extenders it gives high hiding in eggshell and flat finishes also. Because of its good weather resistance properties it is recommended for exterior house paints of all types as well.

Typical Properties:

TRONOX CR-821's major application will be in architectural

Solids, 5 76.5+-1

Density, lbs./gals. 19.2-19.9

PH 8.5-9.5

Volatile water

Viscosity @ 60 RPM, cp 200-300




TRONOX CR-822 is a treated rutile pigment produced by the chloride process. It has been designed to have the highest degree of gloss and tint retention properties in exterior film applications. It is characterized by an optimum balance of high initial gloss, ease of dispersion, opacifying power and exterior weathering properties.

CR-822 is recommended for all interior and exterior enamels and lacquers in architectural, industrial and maintenance finishes. It is also recommended for exterior plastics applications, particularly tinted vinyl siding.


Specific Gravity Scattering coefficient per

In enamels In flat latex


9 0 %

4 . 0 1

4.1 3.1 19 lb oi1/100 lb pigment 21 lb water/100 lb pigment 7.7 7,500 ohms 0.22 um highest ASTM D476-73 Type II1,IV

pound Ti02


TRONOX CR-822s is the slurry counterpart of TRONOX CR-822. The excellent durability, strength, and gloss producing properties of CR-822 have been preserved in its slurry form.

TRONOX CR-822s is recommended primarily for maximum durability in gloss and semi-gloss exterior water-borne coatings. However, it may also be used in interior coatings advantageously and may even be used in flat coatings when it is supplemented with functional extenders to obtain the required dry hiding properties.

Specifications: Sol ids Vo 1 ati le Density Viscosity @ 100 RPM

Typical Viscosity Profile: PH RPM 100 50 20 10

76.5+-1% water 19.1-19.7 lb/gal 175-300 CP 8 . 5 - 9 . 5

Viscosity, cp 225 350 650

1 1 0 0




TRONOX CR-834 is specifically designed for plastics and plastisol applications. While used with most all resins it is widely accepted in rigid vinyl pipe and siding formulations, ABS and polystyrene.

It meets the Plastic Pipe Institute guidelines for formulation substitution and is authorized by the National Sanitation Foundation for general interchangeability in NSF listed formulations.

It is characterized by: * good dispersibility * high tinting strength and opacity * blue tint tone * excellent color retention after processing wi.th problem resins such as polyvinyl chloride and ABS

Typical Values Ti02 content, minimum Density, solid Oil absorption Average particle size Lightfastness Rutile content of contained pH Specific resistance Resistance to anti-oxidant

d i sc o 1 or at i on Bulk density

9 7 9 4.2 g/ml 15 lb oi1/100 lb pigment 0.19 um excel lent

6 to 7 7,600 ohms

excel lent

Ti02 100%

40-55 lbs/ft 3


NL CHEMICALS, INC.: TITANOX Titanium Dioxide Pigment:

Anatase pigmentary:

Physical Properties:

1000 Paper: Specific Gravity: 3.9 Percent Ti02, Min.: 98.5 Oil Absorption: 25.0 Percent Retained on 325 Mesh: 0.05 Chalk Resistance: None

A.S.T.M. D476-73 Type: I General Product Applications: Paint, Exterior, Flat/Paint,

pH: 7-9

Traffic. Paper: Filler, Coating. White Sidewall Tires.

1070 General Purpose: Specific Gravity: 3.8 Percent Ti02, Min.: 95.0 Remainder: A1 Oil Absorption: 20.5 Percent Retained on 325 Mesh: 0.01 Chalk Resistance: None

A.S.T.M. D476-73 Type: I General Product Applications: Paint: Exterior, Flat/Paint:

pH: 7-8

Traffic. Paper: Coating. Ceramic Mill Add. Synthetic Fibers.

1072 Fibers: Specific Gravity: 3.9 Percent Ti02: 98.5 Oil Absorption: 19.0 Percent Retained on 325 Mesh: 0.01 Chalk Resistance: None pH: 7-8 A.S.T.M. D476-73 Type: I General Product Applications: Synthetic Fibers

Rutile Pigmentary:

2020 General Purpose: Specific Gravity: 4.1 Percent Ti02, Min.: 94.0 Remainder: A1 Oil Absorption: 18.5 Percent Retained on 325 Mesh: 0.01 Chalk Resistance: Mod.

A.S.T.M. D476 Type: 11, 111 General Product Applications: Paint, Interior: Gloss, Serni-

pH: 7-8

Gloss, Flat/Exterior: Gloss, Semi-Gloss, Flat/Other: Masonry, Product Finishes. Plastics & Rubber: Polyvinyl Chloride, Plastisol. Printing Inks: Flexographic, Metal Decorating.


NL CHEMICALS, INC.: TITANOX Titanium Dioxide Pigment(C0ntinued):

Rutile Pigrnentary(C0ntinued):

2071 Plastics: Specific Gravity: 4.1 Percent Ti02, idin.: 96.5 Remainder: A1 Oil Assorption: 16.5 Percent Retained on 325 Mesh: 0.01 Chalk Resistance: None pH: 6-8 A.S.T.X. D476-73 Type: I1 General Product Applications: Plastics & Rubber: Polyvinyl

Chloride, Polyethylene, Polystyrene

2073 Plastics: Specific Gravity: 4.2 Percent TiO2, Min.: 97.5 Remainder: AI 011 Absorption: 17.0 Percent Retained on 325 Mesn: 0.01 Chalk Resistance: None #I: 7-8 H.S.T.M. D476-73 Type: I1 tieneral Product AppllCdtlOnS: Plastics & Rubber: Polyvinyl

Chloride, Polyethylene, Polystyrene

2081 Laminates: Specific Gravity: 4.0 Percent Ti02, Min.: 91.0 Remainder: A l , Si O i l Absorption: 28.0 Chalk Resistance: tiigh p ~ : 7-8 A . S . T . M . D476-73 Type: 111, IV General Product Applications: Melamine Laminate

2030 Printing Inks: Specific Gravity: 4.1 Percent Ti02, Min.: 94.0 Remainder: A1 Oil Absorption: 19.5 Percent Retained on 325 Mesh: 0.01. Chalk Resistance: Mod.

A.S.T.M. D476-73 Type: SI, I11 General Product Applications: Printing Inks: Plexographic,

pH: 7-8

Gravure, Metal Decorating.


NL CHEMICALS: TITANOX Titanium Dioxide Pigment(C0ntinued):

Rutile, Pigrnentary(Continued):

2101 Multi-Purpose: Specific Gravity: 4.0 Percent Ti02, Min.: 92.0 Remainder: Al, Si Oil Absorption: 21.0 Percent Retained on 325 Mesh: 0.01 Chalk Resistance: High PH: 7-a A.S.T.M. D476-73 Type: 11, 111, IV General Product Applications: Paint: Interior, Gloss, Semi-

Gloss, Flat/Paint: Exterior, Gloss, Semi-Gloss, Flat/Traffic, Masonry, Product Finishes, Automotive 2131 Multi-Purpose:

Specific Gravity: 3.7 Percent TiO2, Min.: 80.0 Remainder: Al, Si Oil Absorption: 44.0 Percent Retained on 325 Mesh: 0.01 Chalk Resistance: Mod.

A.S.T.M. D476-73 Type: I11 General Product Applications: Paint: Interior, Semi-Gloss,

Flat/Exterior: Flat/Traffic, Masonry, Product Finishes/Paper: Filler, Coating 2160 Chalk Resistance:

p H : 7-9

Specific Gravity: 4.0 Percent Ti02, Min.: 90.0 Remainder: Al, Si Oil Absorption: 18.0 Percent Hetained on 325 Mesh: 0.01 Chalk Resistance: V. High pH: 7-8 A.S.T.M. D476-73 Type: 111, IV General Product Applications: Paint: Interior, Gloss,

Semi-Gloss, Flat/Exterior, Gloss, Semi-Gloss, Flat, Masonry, Product Finishes, Automotive/Plastics & Rubber: Polyvinyl Cnloride, Plastisol.

Non-Pigmentary: 3020:

Percent Ti02, Min.: 99.5 Percent Retained on 325 Mesh: 80.0 General Product Applications: Glass

Pre-Dispersed Anatase: Slurry Properties: 1050 Slurry:

Solids: 73.0 Viscosity: 600 cps p H : 9-10 TiOZ#/g: 13.3 Counterpart: 1000 General Product Applications: Paper: Filler, Coating

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