annexures · 2018-07-19 · metropolitan eximchem private limited proposed speciality chemical...

METROPOLITAN EXIMCHEM PRIVATE

LIMITED

PROPOSED SPECIALITY CHEMICAL

MANUFACTURING PLANT AT JHAGADIA

GIDC, DISTRICT BHARUCH FORM I

KADAM ENVIRONMENTAL CONSULTANTS | JULY 2018 24

3 ANNEXURES

Annexure 1: Production Details

Table 3-1: List of Products with Capacity

S.

No. Name of Products

Production

capacity,

MT/Annum

Category

1 4-Amino-3-Methoxy Azobenzene-3-Sulphuric Acid 140 5(f) B

2 5-Nito 2-Amino Phenol 150 5(f) B

3 5 Amino 6 Methyl Benzimidazolone 150 5(f) B

4 5 Chloro 8 Hdroxy quinolene 200 5(f) B

5 2,5 Dichloro p-Phenylene diamine 120 5(f) B

6 4-(2 Chloro-Ethyl Sulfonyl) Butric Acid 50 5(f) B

7 2-Chloro 4-(2 Chloro Ethyl sulfonyl) Butric Acid 100 5(f) B

8 2,4,6-Tri[ ( 2,4-Dihydroxy3-Methyl) Phenyl] 1,3,5- Trizine 100 5(f) B

9 2-(4,6-Di Phenyl-1,3,5-Triazine-2-yl)-5(2-Hydroxyethoxy) Phenol 50 5(f) B

10 2,3-Dibromo propanyl chloride 50 5(f) B

11 2-Amino 4[(2,3,-Di Bromo 1-oxypropyl)amine],Benzene Sulfonic Acid 30 5(f) B

12 3-Amino-4-[(4-Amino 2 sulfophenyl)-Diazynyl]5 hydroxynapthalene,2,7

Disulfonic acid 20 5(f) B

13 4,4'-Diamino Diphenyl Amine Sulphate 20 5(f) B

14 Anilino methane sulfonic acid 25 5(f) B

15 Cuprate{2-[1-amino-4-hydroxyl 3-(2 hydroxyl-5-sulfophenyl)azo-4,5-

dimethoxy phenyl]}azo-2-Naphthalene sulfonic acid 20 5(f) B

16 3-(4-Chloro-2-Fluro-5-mercaptophenyl)-1-Methyl-6- trifluromethyl,H-

pyrinidine-2-,4-dione 300 5(f) B

17 3(2-Chloro ropionyl aniline)propionic acid methyl ester 200 5(f) B

18 Diamino Benzoic Acid 10 5(f) B

19 3,3 Dinitro di Phenyl Sulfone 20 5(f) B

20 2,2-Bis(4-hydroxy-3-nitrophenol,hexafluro) propane 20 5(f) B

21 3-(Dibromo Propionyl)Amido-Benzoyl K Acid 10 5(f) B

22 3,7-Diamino-2-,8-Dimethyl dibenzothiophenne 5,5 dioxide hyrochloride 10 5(f) B

23 3-(2,4-Dichlorophenyl)-6-Fluroquinazoline-2,4 (1H,3H-Dione 10 5(f) B

24 Di Phenyl Sulfone 150 5(f) B

25 2-Amino di methyl terephthalate 150 5(f) B

26 Zinc tetraisopropyl bis(dithiophosphate) 150 5(f) B

27 Zink O,O- Dibutyl DiThiophosphate 100 5(f) B

28 Dipropyleneglycol methyl-n-propylether 30 5(f) B

29 2,3 Dichloro 6-quinoaline carbonyl chloride 30 5(f) B

30 Direct yeoolw F6GZ 100 5(f) B

31 Diethyl sulfate 200 5(f) B

32 4,4`Thio diphenol 150 5(f) B

33 1,3,benzene diol 4 ( 4,6,bis 2 dimethyl phenyl) 1,3,5 triazine 2-yl 100 5(f) B

34 2-(2-hydroxy,4- methoxy phenyl) 4,6 diphenyl 1,3,5 triazine 100 5(f) B


LIMITED





S.

No. Name of Products

Production

capacity,

MT/Annum

Category

35 BTCA(1,2,3,4-Butanetetracarboxylic acid) 100 5(f) B

36 2 anilino 6 dibutyl amino, 3 methyl fluoran 500 5(f) B

37 IPFENCARBAZONE 150 5(b) A

38 m-cresol pure 10 5(f) B

39 Oligomer of Phenyl phthalimide para bis phenol 100 5(f) B

Total 3925

Table 3-2: List of By-product

S. No. Name of By-products Production capacity, MT/Annum

1 Ortho toludine Diamine 225


LIMITED





Annexure 2: Copy of Plot Holding Letter

METROPOLITAN EXIMCHEM PRIVATE LIMITED PROPOSED SPECIALITY CHEMICAL MANUFACTURING PLANT AT

JHAGADIA GIDC, DISTRICT BHARUCH FORM I


Annexure 3: Site Location Map

METROPOLITAN EXIMCHEM PRIVATE LIMITED PROPOSED SPECIALITY CHEMICAL MANUFACTURING PLANT AT JHAGADIA GIDC, DISTRICT BHARUCH FORM I


Annexure 4: Site Layout Map


LIMITED





Table 3-3: Area Break up at Site

S. No. Title Area, m2 % of total Area

1 Processing Area 3300 4.7

2 Storage Area 1400 2.0

a Hazardous Chemicals 1536 2.2

b Other Non-hazardous chemicals 400 0.6

c Hazardous Waste 100 0.1

d Water Storage 300 0.4

e Fuel Storage 144 0.2

3 Effluent Treatment Plant 1100 1.6

4 Boiler 1400 2.0

5 DG Sets 100 0.1

6 Roads 5155.5 7.3

7 Administrative Building 450 0.6

8 Open Space 14384 20.5

9 Greenbelt Area 23291.67 33.2

10 Area for proposed Expansion 17000.94 24.2

11 Parking area 180 0.3

Total 70242.11 100.0


LIMITED





Annexure 5: List of Key Equipment

Table 3-4: Major Equipment List

S. No Name of Equipment Nos. of Equipment 1 Reactors - SS/MSGL/ MSRLTL/PP/HDPE 40, (+/-) 5

2 Solvent Storage Tanks (For Solvent - Toluene, Methanol, DMF, Hexane, Benzene, EDC 8 to 10

3 Solvent Recovery Tanks (For Solvent - Toluene, Methanol, DMF, Hexane, Benzene, EDC)

4 Storage Tanks (Other Than Solvents) 10 to 12

5 Metering Tanks 20 to 25

6 Filter Presses (Various Sizes &Types) 12

7 Centrifuges 8

8 Dryers

RVD 1 to 2

FBD 3 to 5

Tray Dryer (Normal & Vacuum) 2 to 3

9 Boiler - IBR, Coal Fired (10.54 kg/cm2, Dry Saturated Steam) 1

10 Air Compressors (7 Kg/cm2, Dry Air) 4

11 Brine Chilling Plant (-12°C Brine -MEG) 1

12 Chilled Water plant (7°C - Water) 1

13 Cooling Tower (32°C Supply Water) 4 to 6

14 Thermopack (200° / 300°C 1

15 Nutch Filters 4

16 Distillation Setup (For Toluene, Hexane, Methanol, DFM ,EDC) 5 to 8

17 DG Set 2 18 Transformer/PCC/MCC 1

19 Water Softener 1 to 2

20 DM Water plant 1 to 2

21 Instrumentation (Reactors with PLC Control) 6 to 10

22 Process Pumps 55 to 65

23 Scrubbers 4 to 5


LIMITED





Annexure 6: Manufacturing Processes

1. 4-Amino-3-Methoxy Azobenzene-3-Sulphuric Acid

Process Description

2-Methoxy aniline reacts with formaldehyde and sodium bisulphite to form Methanesulfonic acid, 1-[(2-

methoxyphenyl)amino]- sodium salt.

Next step is Metanilic acid under goes diazotization to form Metanilic acid diazo Hydrochloride. Then

Methanesulfonic acid, 1-[(2-methoxyphenyl)amino]- sodium salt & form Metanilic acid diazo Hydrochloride under

goes coupling to form Benzenesulfonic acid, 3-[2-[3-methoxy-4-[(sulfomethyl)amino]phenyl]diazenyl]-, sodium salt

which further under goes hydrolysis with sodium hydroxide to form product 4-Amino-3-Methoxy Azobenzene-3-

Sulphuric Acid.

Figure 3-1: Process flow diagram for 4-Amino-3-Methoxy Azobenzene-3-Sulphuric Acid

2-Methoxy aniline

Formaldehyde

Sodium Bisulphite

Sodium Nitrite

Hydrochloric acid

Water

Metanilic acid

Methanesulfonic acid,

1- [(2- methoxyphenyl)

amino] - sodium salt

Sodium Bicarbonate

Water

Water Step 4 - Hydrolysis

Sodium Hydroxide

Drying / Packing

Step 1 - Coupler

Step 2 -Diazo

Step 3 - Coupling

Intermediate 2

Intermediate 3

Gaseous Waste dust

collector

Gaseous Waste to

scrubber

Waste water to ETP

Gaseous Waste to

scrubber

Waste water to ETP

Gaseous Waste to

scrubber

Waste water to ETP

Waste water to ETP

Gaseous Waste to

scrubber

Table 3-5: Material Balance for 4-Amino-3-Methoxy Azobenzene-3-Sulphuric Acid

S. No. Input/MT of Product

Raw Materials Quantity (KG/KG)

1 metanilic acid 0.78

2 sodium bi sulfite 0.48

3 formal dehyde 0.36

4 sodium bi carbonate 0.70

5 sodium nitrate 0.32

6 sulfamic acid 0.02


LIMITED





8 Caustic lye 0.50

9 salt 6.58

10 ice 6.73

11 sulfuric acid 0.30

12 ortho anisidine 0.50

13 hyflow 0.01

14 water for process 30.00

15 water for product washings 4.00

16 Machinery washing 5.00

Total 56.27

S. No.

Output/MT of Product

Remark Product

Liquid Effluent

Air Emission

Recovery/ Product

Solid Waste

1 4-Amino-3-Methoxy Azobenzene-3-Sulphuric Acid

- - 1.00 final product

2 Process waste 0.04 CHWTSDF

3 Air emission - 3.23 - - scrubber

4 Effluent strong stream 22 MEE

5 Effluent weak stream 30 - - ETP

Total 52.00 3.23 1.00 0.04

56.27

2. 5-Nito 2-Amino Phenol

Process Description

2-Amino Phenol under goes acetylation with acetic anhydride to form Acetamide, N-(2-hydroxyphenyl) which further under goes nitration with nitric acid & sulphuric acid to form Acetamide, N-(2-hydroxy-4-nitrophenyl).

Further under it goes hydrolysis with sodium hydroxide to form desired quality product 2-Amino 5-Nitro phenol.

Figure 3-2: Process flow diagram for 5-Nito 2-Amino Phenol

4-Chloro amino PhenolGaseous Waste

ammonia recovery

Urea Technical grade

70% Nitric Acid

Ammonia

Activated carbon

SBS

Calasolene Oil Process Waste

Drying\PackingGaseous Waste dust

collector

Intermediate 2

Waste water to ETP

Step 1 -

Reaction/Process

Fusion

Intermediate 1

Step 2 -

Reaction/Process

Nitration

Step 3 -

Reaction/Process

Hydrolysis

Step 3 -

Reaction/Process

Hydrolysis

Gaseous Waste Ventury

Scrubber

Gaseous Waste Ventury

Scrubber

Waste water to ETP

Waste water to ETP

Recoverey Ammonia

Table 3-6: Material Balance for 5-Nito 2-Amino Phenol


LIMITED







1 Ortho Amino Phenol 1.07

2 Urea T.G 1.07

3 Sulphuric Acid 1.83

5 70% Nitric Acid 4.81

6 Ammonia gas 1.35

7 activated carbon 0.01

8

2.8

9 Sodium bi Sulphite 0.02


11 water for product washings 24.00

12 Machinery washing 5.00

Total 55.16

S. No.


Remark Product

Liquid Effluent

Air Emission

Recovery/ Product

Solid Waste

1 5 Nirto 2 Amino Phenol - - 1.00 Final Product

2 Process waste - - 0.06 CHWTSDF

3 Air emission - 5.10 - - scrubber



Total 49.00 2.30 1.00 0.06

55.16

3. 5-Amino 6 Methyl Benzimidazolone

Process Description

3,4 Diamino Toluene under goes uridation with urea to form 5-Methyl-2-benzimidazolinone and further under goes

nitration with nitric acid to form 2H-Benzimidazol-2-one,1,3-dihydro-5-methyl-6-nitro then under goes reduction

with iron to form desired quality product 5-Amino-6-Methyl Benzimidazolone.


LIMITED





Figure 3-3: Process flow diagram for Amino 6 Methyl Benzimidazolone

Ortho toludine Diamine

Toluene Recovered SolventRecovered

Toluene

Sodium hypo Phosphate

Urea Technical grade

Antifoam agent

Water

70% Nitric Acid

Water

Ni Catalyst Process Waste

Soda Ash

Hydrazine Hydrate

Hydrochloric Acid

Activated Carbon

Step 6 -

Drying/packing

Waste water to ETP

Step 1 -

Reaction/Process

purification

Intermediate 1

Intermediate 3

Gaseous waste to scrubber

ammonia recovery system

Gaseous waste to dust

collector

Step 2 -

Reaction/Process

Uridation


ammonia recovery system

Waste water to ETP

Intermediate 2

By product OTD

Step 3 -

Reaction/Process

Nitration

Gaseous Waste to ventury

scrubber

Waste water to

ETP

Step 4 -

Reaction/Process

Reduction

Table 3-7: Material Balance for Amino 6 Methyl Benzimidazolone



1 Ortho Toludine Diamine 2.50

2 Toluene 7.50

3 Urea TG 2.50

4 Nitric Acid 1.75

5 Ni+ Catalyst 0.01

6 Hydraazine Hydrate 0.90

7 Hydrochloric Acid 2.85

8 Activated Carbon 0.03

9 Soda Ash 0.75


11 Water for product washing 21.00

12 water for machinary washing 7.00

Total 61.34

S. No. Output/MT of Product

Remark Product Liquid Air Emission Recovery/ Solid Waste


LIMITED





Effluent Product

1 5 Amino 6 Methyl Benzimidazolone

- - 1.00 final product


3 Air emmission - 7.38 - scrubber

4 Effluent strong stream 8.643 MEE

5 Toluene 6.73 0.02 Distilled & Reused

in next batch


7 Byproduct (Ortho toludine Diamine)

1.5 TO SOLD

Total 44.64 7.38 9.23 0.09

61.34

4. 5-Chloro 8 Hdroxy quinolone

Process Description

4 chloro amino Phenol & 4-Chloro Nitro Phenol react with glycerine in presence of dil. H2SO4 to form product 5-

Chloro 8 Hydroxy quinolone.

Figure 3-4: Process flow diagram for Chloro 8 Hdroxy quinolone

4-Chloro Amino Phenol

4-Chloro Nitro Phenol

Glycerene

Sulfuric acid

Water

Hydrochloric Acid

Activated Carbon

Water

Caustic lye

water

Gaseous waste to

scrubber Dust

collector

Process sludge

Process sludge

Process sludge

Waste water to ETP

Step 3 -

Reaction/Process

Base preparation

Gaseous Waste to

ventury scrubber

Step 4 -

Drying/Packing

Step 1 -

Reaction/Process

Hydrolysis

Intermediate 1

Step 2 -

Reaction/Process

Hydrochloride

Gaseous waste to

scrubber

Waste water to ETP

Intermediate 2

Gaseous waste to

scrubber

Waste water to ETP

Table 3-8: Material Balance for Chloro 8 Hdroxy quinolone


Raw Materials Quantity (MT/MT)

1 4 Chloro Amino Phenol 0.72

2 4 Chloro Nitro Phenol 0.47

3 Glycerine 1.05


LIMITED





4 Sulfuric Acid 1.98

5 ICE 0.50

6 Hydrochloric Acid 30% 6.00

7 A. Carbon 0.06




Total 56.27

S. No.

Output/MT of Product Remark

Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 5 Chloro 8 Hdroxy quinolene 1.00 final productt


3 Air emmission 6.20 scrubber


5 Effluent weak stream 37 ETP

Total 48.94 6.20 1.00 0.13

56.27

5. 2,5 Dichloro p-Phenylene diamine

Process Description

2,5 Dichloro aniline undergoes acylation with acetic anhydride to form 2,5 Dichloro acetylamino benzene then under

goes nitration with nitric acid and sulphuric acid to form 2,5 Dichloro 4-Nitro acetylamino benzene.

Further 2,5 Dichloro 4-Nitro acetylamino undergoes reduction with iron to form 2,5 Dichloro 4-Amino acetylamino

benzene then under goes hydrolysis with sodium hydroxide to form product 2,5 Dichloro paraphenylene diamine.


LIMITED





Figure 3-5: Process flow diagram for 2,5 Dichloro p-Phenylene diamine

2,5 Dichloro Aniline

Glacial Acetic Acid

Acetic unhydride

Water

Oleum 23%

Sulfuric Acid

Nitric Acid 70%

Water

Ice

Toluene

Caustic Flakes

dichlone

Hydrazine Hydrade

Water

Gaseous waste to

scrubber Dust collector

Step 3 -

Reaction/Process

Reduction &

HdrolysisGaseous waste to

scrubber

Solvent recovery

Waste water

to ETP

Waste water to ETP

Toluene recovered

Step 4 -

Drying/Packing

Step 1 -

Reaction/Process

Acetylation

Intermediate 1

Step 2 -

Reaction/Process

Nitration

Gaseous waste to

scrubber Waste water to ETP

Intermediate 2

Gaseous waste to

Table 3-9: Material Balance for 2,5 Dichloro p-Phenylene diamine



1 2,5 Dichloroaniline 1.08

2 Glacial Acetic Acid 0.54

3 Acetic unhydride 0.82

4 0leum 23% 2.70


6 Nitric Acid 0.67

7 ice 7.00

8 Toluene 2.80

9 caustic flakes 0.80

10 dichlone 0.01

11 Hydrazine Hydrate 1.26




Total 57.53

S. No. Output/MT of Product

Remark Product

Liquid Effluent

Air Emission

Recovery/ Product

Solid Waste

1 2,5 Dichloro p-Phenylene diamine

1.00

final product

2 Air emmission

5.49

scrubber

3 Effluent strong stream 12.38

MEE


LIMITED





4 Toluene

2.650 0.01 Distilled & Reused

in next batch

5 Effluent weak stream 36

ETP

Total 48.38 5.49 3.650 0.01

57.53

6. 4-(2 Chloro-Ethyl Sulfonyl) Butric Acid

Process Description

Butyrolactone reacts with isopropanol and thionyl chloride to form Propan-2-yl 4-chlorobutanoate which further

reacts with 2-Mercapto ethanol & sodium hydroxide to form Propan-2-yl 4-Mercapto hydroxy butanoate.

Further Propan-2-yl 4-Mercapto hydroxy butanoate under chlorination with chlorine gas and hydrochloric acid to

form desired quality product (4-[(2-chloro ethyl ) sulfonyl] Butyric Acid.

Figure 3-6: Process flow diagram for 4-(2 Chloro-Ethyl Sulfonyl) Butric Acid

Gama butyl Lactone

Iso propyl Alcohol

Thionyl chloride

Caustic lye

Tetrabutyl ammonium

Bromine2 mercaptoethanol

Hydrochloric Acid

Chlorine gas

water

Step 3 -

Reaction/Process

Chlorination

Gaseous Waste to

scrubber

Drying\packingGaseous Waste dust

collector

Effluent to ETP

Intermediate 1

Step 2 -

Reaction/Process

condensation

Gaseous Waste to

scrubber

Intermediate 2

Step 1 -

Reaction/Process

Ring Closure

Gaseous Waste to

scrubber

Table 3-10: Material Balance for 4-(2 Chloro-Ethyl Sulfonyl) Butric Acid



1 Gama butyl lactone 0.52

2 Isopropyl Alcohol 0.54

3 Thionyl Chloride 0.81

4 caustic lye 0.80

5 Tertiary ammonium bromide 0.05

6 2 mercaptoethanol 0.57


LIMITED





7 Hydrochloric acid 0.15

8 Chlorine gas 1.00




Total 11.18

S. No. Output/MT of Product Remark

Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 4-(2 Chloro-Ethyl Sulfonyl) Butric Acid

1.00 final

product

2 Process waste 0



5 Effluent weak stream 4.5 ETP

Total 7.90 2.28 1.00 0.00

11.18

7. 2-Chloro 4-(2 Chloro Ethyl sulfonyl) Butric Acid

Process Description

Butyrolactone reacts with isopropanol and thionyl chloride to form Propan-2-yl 4-chlorobutanoate which further

reacts with 2-Mercapto ethanol & sodium hydroxide to form Propan-2-yl 4-Mercapto hydroxy butanoate.

Further Propan-2-yl 4-Mercapto hydroxy butanoate under chlorination with chlorine gas and hydrochloric acid to

form (4-[(2-chloro ethyl ) sulfonyl] Butyric Acid which is further reacted with thionyl chloride to form desired

quality product 2-Chloro,4-(2 Chloro Ethyl sulfonyl Butric Acid.


LIMITED





Figure 3-7: Process flow diagram for 2-Chloro 4-(2 Chloro Ethyl sulfonyl) Butric Acid

Gama butyl Lactone

Iso propyl Alcohol

Thionyl chloride

Caustic lye

Tetrabutyl ammonium

Bromine2 mercaptoethanol

Hydrochloric Acid

Chlorine gas

water

Thionyl Chloride

Intermediate 2

Gaseous Waste to

scrubber

Step 5 -

Reaction/Process

Acid chloride

formation

Gaseous Waste to

scrubber

Intermediate 3

Step 3 -

Reaction/Process

Chlorination

Gaseous Waste to

scrubber

Effluent to

ETP

PRODUCT

TOLUENE Recovery

Step 4

Drying

Gaseous Waste dust

collector

Step 1 -

Reaction/Process

Ring Closure

Intermediate 1

Step 2 -

Reaction/Process

condensation

Gaseous Waste to

scrubber

Table 3-11: Material Balance for 2-Chloro 4-(2 Chloro Ethyl sulfonyl) Butric Acid



1 Gama butyl lactone 0.52

2 Isopropyl Alcohol 0.54


4 caustic lye 0.80

5 Tertiary ammonium bromide 0.05

6 2 mercaptoethanol 0.57


8 Chlorine gas 1.00




Total 12.18



LIMITED





Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 2-Chloro 4-(2 Chloro Ethyl sulfonyl) Butric Acid

1.00 final

product

2 Process waste 0




Total 7.90 3.28 1.00 0.00

12.18

8. 2,4,6-Tri[ ( 2,4-Dihydroxy3-Methyl) Phenyl] 1,3,5- Trizine

Process Description

Cyanuric Chloride reacts with 2-Methyl resorcinol & aluminium chloride to form desired quality product 4,6-Tri [(2,4-

Dihydroxy 3-Methyl) Phenyl ] 1,3,5-Trizine

Figure 3-8: Process flow diagram for 2,4,6-Tri[ ( 2,4-Dihydroxy3-Methyl) Phenyl] 1,3,5- Trizine

Sulfolane

Cynuric chlorideRecovered

Solvent

Recovered

Sulfolane

Aluminium Chloride

2 Methyl Resorcinol

Caustic lye

water

hydrochloric Acid

Drying/Packing

Step 1 -

Reaction/Process

condensation

Gaseous Waste dust

scrubber

Gaseous Waste to

scrubber

Table 3-12: Material Balance for 2,4,6-Tri[ ( 2,4-Dihydroxy3-Methyl) Phenyl] 1,3,5- Trizine



1 Sulf0lane 3.10

2 Cynuric Chloride 0.48

3 Aluminium Chloride 0.52

4 2 Methyl Resorcinol 1.12

5 Cautic Lye 1.25





Total 76.77



LIMITED





Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 2,4,6-Tri[ ( 2,4-Dihydroxy3-Methyl) Phenyl] 1,3,5- Trizine

1.00 final

product




5 Sulfolane 2.790 0.01 Distilled & Reused in next batch


Total 70.17 2.00 3.790 0.81

76.77

9. 2-(4,6-Di Phenyl-1,3,5-Triazine-2-yl)-5(2-Hydroxyethoxy) Phenol

Process Description

Cyanuric Chloride react with 2 mol of benzene and 1 mol of resorcinol with aluminium chloride to give 2-

(2,4-dihydroxyphenyl)-4,6-diphenyl-1,3,5-triazine.

2-(2,4-dihydroxyphenyl)-4,6-diphenyl-1,3,5-triazine.reacts with ethylene carbonate to from 2-(4,6-Di

Phenyl-1,3,5-Triazine-2-yl)-5-(2-Hydroxyethoxy)Phenol which is further filtered & packed.

Figure 3-9: Process flow diagram for 2-(4,6-Di Phenyl-1,3,5-Triazine-2-yl)-5(2-Hydroxyethoxy) Phenol

Aluminium Chloride

Ortho Di Chloride BenzeneRecovered

SolventSulfolane

HydrochlorideOrtho di

Chloro

Cynuric Chloride

Benzene

Sulfolane

Resorcinol

water

Methanol Methanol

Cyclohexane

Ethylene Carbonate

Mono ethylene Glycol Methanol

Phosporic Acid

Methnol

water

Step 4 -

Drying/packing

Cyclo hexaneRecovered

Solvent

Waste water to ETP

Recovered

Solvent

Gaseous Waste to

scrubber

Step 3 -

Reaction/Process

Gaseous Waste

Gaseous Waste to dust

collector

Step 1 -

Reaction/Process

Condensation

Intermediate 1

Step 2 -

Reaction/Process

purification

Intermediate 2

Waste water to ETP


LIMITED





Table 3-13: Material Balance for 2-(4,6-Di Phenyl-1,3,5-Triazine-2-yl)-5(2-Hydroxyethoxy) Phenol



1 Aluminium Chloride 3.60

2 Ortho Di Chloro Benzene 5.80

3 Cynuric Chloride 0.89


5 Benzene 0.80

6 Sulfolane 5.00

7 Resorcinol 0.75

8 Methanol 28.70

9 Cyclohexanone 5.70

10 Ethylene Carbonate 0.67

11 Mono Ethylene Glycol 0.70

12 Phosphoric Acid 0.17




Total 109.28

S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid

Waste

1 2-(4,6-Di Phenyl-1,3,5-Triazine-2-yl)-5(2-Hydroxyethoxy) Phenol

1.00 final product

2 Process waste 0



5 Sulfolane 4.490 0.01 Distilled & Reused in

next batch

6 Ortho dichloro Benzene 5.490 0.01 Distilled & Reused in

next batch

7 Methanol 28.010 0.04 Distilled & Reused in

next batch

8 cyclohexane 5.790 0.01 Distilled & Reused in

next batch


Total 62.39 2.04 44.780 0.07

109.28

10. 2,3-Dibromo propanyl chloride

Process Description

Acrylic acid reacts with bromine and thionyl chloride to form 2,3 Dibromo propionyl chloride which is further

packed.


LIMITED





Figure 3-10: Process flow diagram for 2,3-Dibromo propanyl chloride

Ethylene Di Chloride

Gaseous

Waste to

scrubber

Acrylic AcidRecovered

Solvent

Ethylene di

Chloride

Catalyst SCPI

Bromine liquid

Thionyl Chloride

Step 1 -

Reaction/Process

Table 3-14: Material Balance for 2,3-Dibromo propanyl chloride



1 Ethylene di Chloride 0.33

2 Acrylic Acid 0.28

3 Catalyst SCPC 0.00

4 Bromine 0.66



Total 2.99


Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 2,3-Dibromo propanyl chloride 1.00 final

product

2 Process waste 0



5 EDC 0.26 0.01 Distilled & Reused in next batch


Total 1.00 0.72 1.26 0.01

2.99

11. 2-Amino 4[(2,3,-Di Bromo 1-oxypropyl)amine],Benzene Sulfonic Acid

Process Description

2-Amino 4 [(2,3,Dibromo 1- oxypropyl )amine], Benzene Sulphonic Acid condenses with 2,3 Dibromo Propionyl

Chloride to form desired quality product 2-Amino 4[(2,3-Di Bromo 1-oxopropyl) amine], Benzene sulfonic acid which

is further filtered & packed.


LIMITED





Figure 3-11: Process flow diagram for 2-Amino 4[(2,3,-Di Bromo 1-oxypropyl)amine],Benzene Sulfonic Acid

Ethylene Di Chloride

Gaseous

Waste to

scrubber

Acrylic AcidRecovered

Solvent

Ethylene Di

Chloride

Catalyst SCPI

Bromine Liquid

Thionyl Chloride

RA 225

Sodium Bi Carbonate

Hydrochloric Acid

Pure salt

water

Step 1 -

Reaction/Process

Intermediate 1

Step 2 -

Reaction/Process

Gaseous to scrubber

Waste water to ETP

Drying/packing

Gaseous Waste dust

scrubber

Table 3-15: Material Balance for 2-Amino 4[(2,3,-Di Bromo 1-oxypropyl)amine],Benzene Sulfonic Acid



1 Ethylene di Chloride 0.30

2 Acrylic Acid 0.26

3 Catalyst SCPC 0.00

4 Bromine 0.60


6 RA 225 0.54

7 Sodium Bicarbonate 0.54


9 Pure salt 0.54




Total 14.86


Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1

2-Amino 4[(2,3,-Di Bromo 1-oxypropyl)amine],Benzene Sulfonic Acid

1.00 final

product

2 Process waste 0




LIMITED





5 EDC 0.233 0.01 Distilled & Reused in next batch


Total 12.47 1.14 1.233 0.01

14.86

12. 3-Amino-4-[(4-Amino 2 sulfophenyl)-Diazynyl]5 hydroxynapthalene,2,7 Disulfonic acid

Process Description

Benzene sulfonic acid 2-amino-4-nitro undergoes diazotization with sodium nitrite to form Diazo m-nitro benzene

sulfonic acid hydrochloride which goes under coupling with 2R acid to form 7-Naphthalenedisulfonic acid, 5-amino-

4-hydroxy-3-[2-(4-nitro-2-sulfophenyl)diazenyl] which further goes under reduction with sodium hydrosulphite to

form desired product 3-Amino-4-[(4- amino 2 sulfophenyl)-Diazynyl]-5-hydroxynapthalene,2,7-Disulphonic Acid.

Figure 3-12: Process flow diagram for 3-Amino-4-[(4-Amino 2 sulfophenyl)-Diazynyl]5 hydroxynapthalene,2,7 Disulfonic acid

Sulfo gama acid

Caustic lye

PNAOSA

Hydrochloric Acid

NASA 53%

Sodium Nitrate

Sulfamic

Nash solution

Pure salt

Step 1 -

Reaction/Process

Diazotisation

Waste water to ETP

Gaseous Waste to

scrubber

Table 3-16: Material Balance for 3-Amino-4-[(4-Amino 2 sulfophenyl)-Diazynyl]5 hydroxynapthalene,2,7 Disulfonic acid



1 RA 224 0.58

2 Caustic lye 0.33

3 Para Nitro Amino Sulfonic Acid 0.41


5 NASA 53% 0.07

6 Sodium Nitrate 0.03

7 Sulfamic Acid 0.01

8 Nash Solution 0.56

9 Pure salt 2.35




Total 18.34



LIMITED





Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 3-Amino-4-[(4-Amino 2 sulfophenyl)-Diazynyl]5 hydroxynapthalene,2,7 Disulfonic acid

1.00 final

product

2 Process waste

3 Air emmission 1.50 Scrubber



Total 15.836 1.50 1.00 0.00

18.34

13. 4,4'-Diamino Diphenyl Amine Sulphate

Process Description

Diamino Diphenyl Sulphate undergoes desulphonation with water to form desired product 4,4’Diamino Diphenyl

Amine Sulphate which is further filtered & packed.

Figure 3-13: Process flow diagram for 4,4'-Diamino Diphenyl Amine Sulphate

RA 212Gaseous Waste

to scrubber

Sulfuric Acid

Water

Sulfuric Acid

Activated carbon

Stannous Chloride Process sludge

Step 1 -

Reaction/Process

sulfonation

Intermediate 1

Step 2 -

Reaction/Process

purification

Gaseous Waste to

scrubberWaste water to ETP

Step 3 -

Reaction/Process

Drying/Packing

Waste water to ETP


scrubber

Table 3-17: Material Balance for 4,4'-Diamino Diphenyl Amine Sulphate



1 RA 212 1.26



4 Stanus Chloride 0.02




Total 78.59



LIMITED





Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 4,4'-Diamino Diphenyl Amine Sulphate

1.00 final

product





Total 72.91 4.38 1.00 0.30

78.59

14. Anilino methane sulfonic acid

Process Description

Aniline reacts with formaldehyde and sodium bisulphite to form desired quality product Aniline methane sulfonic

acid which is further filtered & packed.

Figure 3-14: Process flow diagram for Anilino methane sulfonic acid

Aniline

Sodium Bicarbonate

Sodium bi Sulfate

Formaldehyde

Water

Step 1 -

Reaction/Process

condensationWaste water to ETP

Gaseous Waste to

scrubber

Table 3-18: Material Balance for Anilino methane sulfonic acid



1 Aniline 0.80

2 Sodium Bicarbonat 0.40

3 Sodium Bi Sulfate 1.09

4 Formaldehyde 0.82




Total 14.11


Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 Anilino methane sulfonic acid 1.00 final

product

2 Process waste 0




Total 12.61 0.50 1.00 0.00


LIMITED





14.11

15. Cuprate{2-[1-amino-4-hydroxyl 3-(2 hydroxyl-5-sulfophenyl)azo-4,5-dimethoxy phenyl]}azo-2-

Naphthalene sulfonic acid

Process Description

Process o-Anisidine is sulphonated with sulphuric acid to form o-Anisidine 4-Sulfonic Acid and it under goes

diazotisation to form Diazo of o-Anisidine Sulfonic Acid.

Further catechol reacts with dimethyl sulphate to form dimethoxy benzene which undergoes nitration with nitric

acid to from 4-Nitro veretrol then it undergoes reduction with sodium sulphide to form 4- Amino veretrol.

Next step Diazo of o-Anisidine Sulfonic Acid and 4- Amino veretrol reacts to form Monoazo CHU 447 which

undergoes diazotisation to form Diazo of Monoazo CHU 447.

Diazo of Monoazo CHU 447 reacts with J acid to form desired Cuprate {2-[1-amino-4- hydroxyl-3-(2-hydroxy-5-

sulfophenyl)azo-4,5-dimethoxy phenyl]}azo-2-Napthalene sulfonic acid.


LIMITED





Figure 3-15: Process flow diagram for Cuprate{2-[1-amino-4-hydroxyl 3-(2 hydroxyl-5-sulfophenyl)azo-4,5-dimethoxy phenyl]}azo-2-Naphthalene sulfonic acid

Ortho anisidine

Sulfuric acid

ice

water

Catechol

Dimethyl sulfate

ice

Caustic lye

Sodium sulphite

Unhydrous sodium sulfite

Water

Soda Ash

Nitric cid 70%

water

Sodium sulfide flakes

Sulfor powder

Sodium bisulfite

water

Ortho Anisidine Sulfonic

Acid

Water

Caustic lye

Hydrochloric Acid

Sodium Nitrate

Sulfamic Acid

J Acid

Ice

water

Caustic Lye

40% NSA solution

Copper Sulfate

Hydrochloric acid

Salt

Packing

Gaseous Waste to

scrubber

Process sludge to haz

waste site

Process Waste to

scrubber

Intermediate 5

Step 6 -

Reaction/Process

Diazo Coupling

Waste water to ETP

Intermediate 4

Step 5 -

Reaction/Process

Diazo coupling

Gaseous Waste to

scrubber

Waste water to ETP

Step 3 -

Reaction/Process

Nitration

Gaseous Waste to

scrubber

Intermediate 3

Step 4 -

Reaction/Process

reduction

Gaseous Waste

Scrubber

Waste water to ETP

Waste water to ETP

Process sludge to haz

waste site

Step 1 -

Reaction/Process

INT 1 sulfonation

Step 2 -

Reaction/Process

condensation

Waste water to ETP

Intermediate 2

Waste water to ETP

Gaseous Waste to

scrubber

Ortho anisidine

sulfonic acid


LIMITED





Table 3-19: Material Balance for Cuprate{2-[1-amino-4-hydroxyl 3-(2 hydroxyl-5-sulfophenyl)azo-4,5-dimethoxy phenyl]}azo-2-Naphthalene sulfonic acid



1 Ortho anisidine 0.33


3 Ice 16.50

4 RA 230 0.49

5 Cautic lye 1.40

6 Sodium Sulphite 0.09

7 Soda Ash 0.08

8 Hydros 0.03

9 Di Methyl Sulfate 1.40

10 Nitric Acid 0.74

11 Sodium Sulfide flakes 1.40

12 Sulfor Powder 0.33

13 Sodium Bi Sulfide 1.50

14 caustic lye 0.08

15 Hydrochoric Acid 2.04

16 Sodium Nitrate 0.19

17 Sulfamic 0.10

18 J Acid 0.58

19 40% NSA Solution 0.12

20 Copper Sulfate 0.53

21 Sodium Chloride 6.45




Total 96.05


Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1

Cuprate{2-[1-amino-4-hydroxyl 3-(2 hydroxyl-5-sulfophenyl)azo-4,5-dimethoxy phenyl]}azo-2-Naphthalene sulfonic acid

1.00 final

product





Total 83.16 11.84 1.00 0.05

96.05


LIMITED





16. 3-(4-Chloro-2-Fluro-5-mercaptophenyl)-1-Methyl-6- trifluromethyl,H-pyrinidine-2-,4-dione

Process Description

Aniline 2-Fluoro 4-chloro reacts with Ethyl chloroformate to form Ethyl N-(4-chloro-2-fluoro-phenyl)carbamate.

Further Ethyl trifluoro Aceto Acetate reacts with Ammonium acetate to form Ethyl-3-amino-4,4,4-trifluorocrotonate.

Then Ethyl N-(4-chloro-2-fluoro-phenyl)carbamate reacts to Ethyl-3-amino-4,4,4-trifluorocrotonate to form 3(4

Chloro-2-Fluorophenyl)-6-trifluoromethyl-1H-pyrimidine-2,4 dione & it under goes methylation to form 3-(4-Chloro-

2-Fluorophenyl)-1Methyl-6-trifluoromethyl-1H-Pyrimidine-2,4Dione.

Next 3-(4-Chloro-2-Fluorophenyl)-1Methyl-6-trifluoromethyl-1H-Pyrimidine-2,4Dione undergoes chlorination with

thionyl chloride to form 2-Chloro 4 Fluoro 5-(3-Methyl2,6 Dioxo-4Trifluoromethyl 3,6 Dihydro-2Hpyrimidine-1-

yl)Benzene Sulfonyl Chloride which further undergoes reduction to form 3-(4-Chloro-2-Fluro-5-mercaptophenyl)-1-

methyl-6-trifluoromethyl,H-pyrinidine-2-4dione.


LIMITED





Figure 3-16: Process flow diagram for 3-(4-Chloro-2-Fluro-5-mercaptophenyl)-1-Methyl-6- trifluromethyl,H-pyrinidine-2-,4-dione

Ethyl Trifluro acetoacetateGaseous Waste to

scrubber

Cyclohexane Recovered Solvent

Recovered

Cyclohexane and Ethyl

trifluro aceto acetate

Ammonia Process Waste

Water

2-Fluro aniline

Ethylene Dichloride

Ethyl chloroformate

Sulfuryl Chloride Recovered Solvent

Recovered Ethyl

chloro

formate..Methanol..

Ethylene Dichloride

Methanol

Water Process Waste

EATC

Potasium Carbonate

Dimethyl Formamide

Hexane Process Waste

Isopropyl Alcohol

Ice

Water Dying dust to dust collector

Chloro sulfonic acid

Thionyl chloride

Sdium bi carbonate

Methylene Di Chloride Process Waste

Salt

water

Ice Recovered SolventRecovered

Dichloromethane

Process Waste

Acetic Acid

Red Phosphorus

Iodine

Hydrochloric acid

Iso propyl Alcohol Process Waste

Hexane

Water

Step 6 -

Drying/Packing

Dust to dust collector

Intermediate 4

Step 5 -

Reaction/Process

reduction

Gaseous Waste to scrubber

Recovered Solvent

Recovered Solvent Iso

propyl

Alcohol..Hexane..Iodine

Step 3 -

Reaction/Process

MPDH


Recovered Solvent

Recovered Solvent

..Ethanol..Hexane…Iso

Propyl Alcohol

Intermediate 3

Step 4 -

Reaction/Process

chloro sulfonation


Recovered SolventRecovered Methyle Di

chloride

Step 1 -

Reaction/Process

ammonylysis

Step 2 -

Reaction/Process

chloroformate


Waste water to ETP

Intermediate 2

Waste water to ETP

Product EATC

Table 3-20: Material Balance for 3-(4-Chloro-2-Fluro-5-mercaptophenyl)-1-Methyl-6- trifluromethyl,H-pyrinidine-2-,4-dione


Raw Materials Quantity (MT/MT) 1 Ethyl Trifluro aceto acetate 1.13 2 Cyclohexane 5.24 3 Ammonia 1.45


LIMITED





4 2-Fluro Aniline 0.69 5 Ethylene Dichloride 7.89

6 Ethyl chloroformate 0.76 7 Sulfuryl Chloride 1.17 8 Methanol 2.44 9 ECFC 1.10 10 EATC 0.92

11 Pottasium Carbonate 1.70 12 Dimethyl Formamaide 5.76 13 Dimethyl Sulfate 1.37 14 Hexane 3.12

15 Iso Propyl Alchohol 2.61 16 Ice 7.39 17 Chlorosulfonic Acid 3.50 18 Thionyl Chlooride 0.17 19 Sodium bicarbonate 0.10

20 Methylene Dichloride 14.22 21 Pure salt 1.73

22 Acetic Acid 4.11 23 Red phosporus 0.30 24 Iodine 0.03 25 1 N Hydrochloric Acid 0.82 26 water for process 31.84



Total 139.12

S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid

Waste

1

3-(4-Chloro-2-Fluro-5-mercaptophenyl)-1-Methyl-6- trifluromethyl,H-pyrinidine-2-,4-dione

1.00 final product




5 EATC 0.912 0.01 Distilled & Reused in next

batch

6 Cyclohexane 4.963 0.01 Distilled & Reused in next

batch

7 ECFC 1.088 0.01 Distilled & Reused in next

batch

8 Methanol 2.302 0.01 Distilled & Reused in next

batch

9 Ethylene Dichloride 7.479 0.015 Distilled & Reused in next

batch

10 Hexane 2.955 0.01 Distilled & Reused in next

batch

11 Isopropyl Alcohol 2.468 0.01 Distilled & Reused in next

batch

12 Ethanol 0.454 0.01 Distilled & Reused in next

batch

13 Methylene Dichloride 13.489 0.015 Distilled & Reused in next

batch

14 Acetic Acid 2.320 0.01 Distilled & Reused in next

batch


Total 98.415 0.867 39.430 0.410

139.12


LIMITED





17. 3(2-Chloro ropionyl aniline)propionic acid methyl ester

Process Description

Beta Alanine undergoes esterification with methanol and thionyl chloride to form β-aminomethylpropionate.

Further β-aminomethylpropionate reacts with 2,2 dichloropropionyl chloride to form β-Alanine, N-(2-chloro-1-

oxopropyl)-, methyl ester.

Figure 3-17: Process flow diagram for 3(2-Chloro ropionyl aniline)propionic acid methyl ester

Beta Alanine

MethanolRecovered

Solvent

Thionyl Chloride

Methylene Dichloride Process Waste

Methanol

2-Chloro propionyl chloride

Methylene di chloride

Sodium bi Carbonate

Activated carbon Process Waste

Water

Methylene Di

chloride

Packing

Recovered Thionyl

chloride…Ethanol..Met

hylene Dichloride

Gaseous Waste to

scrubber

Step 1 -

Reaction/Process

sulfonation

Intermediate 1

Step 2 -

Reaction/Process

Gaseous waste to

scrubberWaste water to ETP

Recovered

Solvent

Table 3-21: Material Balance for 3(2-Chloro ropionyl aniline)propionic acid methyl ester



1 BA 0.56

2 Thionyl Chloride 1.06 3 Methanol 0.67 4 Methylene Di Chloride 6.45

5 TEA 1.28 6 CPC 0.80

7 Hydrochloride 0.32


9 Water for product washing 8.65 10 water for machinary washing 3.00

Total 22.79

S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 CPPM 1.00 final product

2 Air emission 0.60 scrubber 3 Effluent strong stream 2.8 MEE 4 Methanol 0.610 0.01 Distilled & Reused in next batch 5 Methylene di chloride 6.114 0.01 Distilled & Reused in next batch 6 Effluent weak stream 11.65 ETP

Total 14.45 0.60 7.724 0.02

22.79


LIMITED





18. Diamino Benzoic Acid

Process Description

4-Chloro Benzoic acid is nitrated with nitric acid & sulphuric acid to form product 3-Nitro 4-Chloro Benzoic acid.

Then 3-Nitro 4-Chloro Benzoic acid undergoes ammonolysis to form 3-Nitro 4-Amino Benzoic acid.

Further 3-Nitro 4-Amino Benzoic acid undergoes reduction with iron to form 3,4 Diamino Benzoic acid.

Figure 3-18: Process flow diagram for Diamino Benzoic Acid

Para Chloro benzoic acidGaseous Waste to

scrubber

Oleum 23%

Sulfuric Acid

Nitric acid

Ice

Water

Iron Powder

Glacial Acetic Acid

Sodium bi sulfide Process Waste

hydros

Caustic lye

Sulfuric acid

water

Liquar ammonia

Hydrochloric acid

Water

Hydrochloric acid

Activated Carbon

Water

Soda Ash

Step 6 -

Drying/packing

Intermediate 4

Step 5 -

Reaction/Process

purification


Process Waste

Waste water to ETP

Waste water to ETP

Step 3 -

Reaction/Process

Hydrolysis

Gaseous Waste ammonia

recovery system

Intermediate 3

Step 4 -

Reaction/Process

Acidification


Waste water to ETP

Step 1 -

Reaction/Process

sulfonation/Nitrati

on

Intermediate 1

Step 2 -

Reaction/Process

Reduction


Waste water to ETP

Intermediate 2

Waste water to ETP

Table 3-22: Material Balance for Diamino Benzoic Acid



1 Para chloro benzoic acid 1.11 2 Oleum 23% 1.57 3 Sulfuric Acid 6.44 4 Nitric Acid 0.47


LIMITED





5 ICE 10.00 6 Iron Powder 1.50

7 Glacial Acetic Acid 0.21 8 Sodium bi sulfate 0.03 9 Hydros 0.08 10 Caustic lye 0.50 11 Liq Ammonia 3.50

12 Hydrochloric Acid 1.83 13 activated carbon 0.08 14 Soda Ash 0.80 15 water for process 44.50


Total 108.62

S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid

Waste 1 Diamino Benzoic Acid 1.00 final product

2 Process waste 3.4 CHWTSDF 3 Air emmission 11.45 scrubber 4 Effluent strong stream 6.774 MEE 5 Effluent weak stream 86 ETP

Total 92.77 11.45 1.00 3.40

108.62

19. 3,3 Dinitro di Phenyl Sulfone

Process Description

Diphenyl Sulfone is nitrated with nitric acid & sulphuric acid to form desired quality product Dinitro Diphenyl Sulfone

which is further filtered & packed.

Figure 3-19: Process flow diagram for 3,3 Dinitro di Phenyl Sulfone

Di Phenyl SulfoneGaseous Waste to

scrubber

Sulfuric Acid

Glauber Salt

98% Nitric Acid

Water

ICE

DMSO

Methanol

Process Waste

Drying/ Packing

Recovered Solvent

methanol…DMSO

Step 1 -

Reaction/Process

sulfonation/nitrati

on

Intermediate 1

Step 2 -

Reaction/Process

purification


Intermediate 2

Waste water to ETP

Recovered Solvent


collector

Table 3-23: Material Balance for 3,3 Dinitro di Phenyl Sulfone



1 Diphenyl Sulfone 0.75 2 Sulfuric Acid 3.35 3 Glaubber salt 0.06 4 98% Nitric Acid 0.59 5 ICE 9.00 6 DMSO 2.10


LIMITED





7 Methanol 0.30 6 water for process 1.50


Total 33.65

S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 3,3 Dinitro di Phenyl Sulfone 1.00 final product 2 Process waste 0.1 CHWTSDF 3 Air emmission 0.68 scrubber 4 Effluent strong stream 13.597 MEE

5 Methanol 0.267 0.005 Distilled & Reused in next

batch

6 DMSO 1.985 0.01 Distilled & Reused in next

batch 7 Effluent weak stream 16 ETP

Total 29.60 0.68 3.252 0.115

33.65

20. 2,2-Bis(4-hydroxy-3-nitrophenol,hexafluro) propane

Process Description

Hexafluoro Bisphenol A is nitrated with nitric acid & sulphuric acid to form desired quality product 2,2-Bis(4-

hydroxy-3-nitrophenol,hexafluro) Propane which is further filtered & packed.

Figure 3-20: Process flow diagram for 2,2-Bis(4-hydroxy-3-nitrophenol,hexafluro) propane

Sulfuric acid

BPAF

Nitric acid

Ice

Caustic lye

Water

water

Methanol

Activated carbon

Water

Process Waste

Intermediate 3

Drying/packingDust waste to dust

Intermediate 2

Step 3 -

Reaction/Process

purification

Gaseous Waste to

scrubber

Recovered

Solvent

Recovered

Solvent

Methanol

Step 1 -

Reaction/Process

Nirtation

Intermediate 1

Step 2 -

Reaction/Process

Reslurry

Gaseous waste to

scrubber

Waste water to ETP

Gaseous Waste to

scrubber

Table 3-24: Material Balance for 2,2-Bis(4-hydroxy-3-nitrophenol,hexafluro) propane


LIMITED







1 BPAF 0.92


3 Nitric Acid 0.59

4 Ice 6.12

5 Caustic lye 0.58

6 Methanol 5.82





Total 52.177


Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 2,2-Bis(4-hydroxy-3-nitrophenol,hexafluro) propane

1.00 final

product




5 Methanol 5.515 0.01 Distilled & Reused in next batch


Total 45.34 0.27 6.515 0.046

52.177

21. 3-(Dibromo Propionyl)Amido-Benzoyl K Acid

Process Description

2,7-Naphthalenedisulfonic acid, 4-[(3-aminobenzoyl)amino]-5-hydroxy reacts with 2, 3 Dibromo Propionyl Chloride

to form 2,7-Naphthalenedisulfonic acid, 4-[[3-[(2,3-dibromo-1-oxopropyl)amino]benzoyl]amino]-5-hydroxy product


LIMITED





Figure 3-21: Process flow diagram for 3-(Dibromo Propionyl)Amido-Benzoyl K Acid

Ethylene DichlorideGaseous Waste to

scrubber

Acrylic Acid Recovered Solvent

Recovered

Ethylene Di

chloride

Catalyst SCPI Process Waste

Bromine

Thionyl Chloride

Europeon Acid

Water

Sodium Bi carbonate

salt

Intermediate 2

Drying/PackingDust waste to dust collector

Step 1 -

Reaction/Process

bromination

Intermediate 1

Step 2 -

Reaction/Process

crystalisation


Waste water to ETP

Table 3-25: Material Balance for 3-(Dibromo Propionyl)Amido-Benzoyl K Acid



1 Ethylene Di Chloride 0.17 2 Acrylic Acid 0.14 3 Catalyst SCPI 0.00

4 Bromine 0.33 5 Thionyl Chloride 0.35

6 Europeon Acid 0.80 7 Sodium bi carbonate 0.40

8 Salt 1.00 9 water for process 4.00

11 water for machinary washing 3.00 Total 10.193

S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 3-(Dibromo Propionyl)Amido-Benzoyl K Acid

1.00 final product



4 Ethylene Di Chloride 0.130 0.005 Distilled & Reused in next

batch 5 Effluent weak stream 3 ETP

Total 8.67 0.39 1.130 0.005

10.193

22. 3,7-Diamino-2-,8-Dimethyl dibenzothiophenne 5,5 dioxide hydrochloride

Process Description

O- Toluedine Diamine reacts with oleum to form o – Toluidine diamine sulfone.

Then o – Toluidine diamine sulfone reacts with hydrochloric acid to form 3,7 Diamino 2,8 Dimethyl

dibenzothiophene 5,5 dioxide hydrochloride product.

Figure 3-22: Process flow diagram for 3,7-Diamino-2-,8-Dimethyl dibenzothiophenne 5,5 dioxide hydrochloride


LIMITED





OT Base

Oleum 65%

Oleum 23%

Ice

Water

Caustic lye

water

Hydro Chloric Acid

water

Activated carbon

Process Waste

Gaseous Waste to

scrubber

Step 3 -

Reaction/Process

Hydrochloride

Gaseous Waste to

scrubber

packing

Waste water to ETP

Step 1 -

Reaction/Process

sulfonation

Intermediate 1

Step 2 -

Reaction/Process

free base

Gaseous waste to

scrubber

Waste water to ETP

Intermediate 2

Waste water to ETP

Table 3-26: Material Balance for 3,7-Diamino-2-,8-Dimethyl dibenzothiophenne 5,5 dioxide hydrochloride



1 OT base 1.00 2 Oleum 65% 1.75

3 Oleum 23% 12.80 4 Ice 40.00

5 Caustic Lye 0.40 6 HydroChloric Acid 1.75

7 Activated Carbon 0.20 8 water for process 46.50 9 Water for product washing 20.00


S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 3,7-Diamino-2-,8-Dimethyl dibenzothiophenne 5,5 dioxide hyrochloride

1.00 final product

2 Process waste 0.4 CHWTSDF 3 Air emmission 4.60 scrubber 4 Effluent strong stream 48.4 MEE


Total 131.40 4.60 1.00 0.40

137.40

23. 3-(2,4-Dichlorophenyl)-6-Fluroquinazoline-2,4 (1H,3H-Dione)

Process Description

3-Fluoro Benzoic acid is nitrated with nitric acid & sulphuric acid to form 3-Fluoro 6-Nitro Benzoic acid.

3-Fluoro 6-Nitro Benzoic acid undergoes condensation with 2,4 Dichloro Aniline to form N-(2,4-Dichlorophenyl)-5-

fluoro-2-nitrobenzamide.


LIMITED





N-(2, 4-Dichlorophenyl)-5-fluoro-2-nitrobenzamide undergoes reduction in the presence of Iron and formic acid to

form N-(2,4-Dichlorophenyl)-5-fluoro-2-Amino benzamide.

N-(2,4-Dichlorophenyl)-5-fluoro-2-Amino benzamide undergoes with condensation with ethyl chloroformate to form

the desired quality product 3-(2,4 Dichlorophenyl ) 6-Fluoro quinazoline - 2,4 (1H,3H)Dione.

Figure 3-23: Process flow diagram for 3-(2,4-Dichlorophenyl)-6-Fluroquinazoline-2,4 (1H,3H-Dione)

3 fluro benzoic acid

Sulfuric acid

Nitric acid

Water

2,4 dichloro Aniline Waste water

to ETP

Toluene

Thionyl Chloride

Water

Iron Powder

Formic Acid

Toluene

Water

Ethyl Chloroformate

Toluene

Water

Methanol

Sodium Methoxide

Activated Charcoal

Hydrochloric acid

Water

Step 4 -

Reaction/Process

Condensation

Intermediate 4

Step 4 -

Reaction/Process

Cyclisation

Step 3 -

Reaction/Process

Reduction

Dust waste to dust

collector

Recovered Toluene

Gaseous Waste to

scrubber

Step 1 -

Reaction/Process

Nitration

Intermediate 1

Step 2 -

Reaction/Process

Condensation

Waste water to ETP

Gaseous Waste to

scrubber

Recovered Toluene

Gaseous Waste to

scrubber

Recovered Methanol

Gaseous Waste to

scrubber

Recovered

Toluene

Intermediate 3

Intermediate 2

Waste water to ETP

Drying/Packing

Waste water to ETP

Table 3-27: Material Balance for 3-(2,4-Dichlorophenyl)-6-Fluroquinazoline-2,4 (1H,3H-Dione)


Raw Materials Quantity (MT/MT) 1 Flurobenzoic acid 0.68 2 Sulfuric acid 95% 3.76 3 Nitric acid 60% 0.61 4 Toluene 24.63

5 Thionyl Chloride 0.74 6 Iron Powder 1.84 7 Formic Acid 0.92

8 Ethyl chloroformate 0.46


LIMITED





9 Methanol 5.95

10 Sodium Methoxide 0.04 11 Water for product washing 10.00


Total 54.612

S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid

Waste

1 3-(2,4-Dichlorophenyl)-6-

Fluroquinazoline-2,4 (1H,3H-Dione 1.00 final product




5 Methylene Di Chloride 25.857 0.03 Distilled & Reused in

next batch

6 Thionyl Chloride 0.437 0.01 Distilled & Reused in

next batch

7 Methanol 2.353 0.01 Distilled & Reused in

next batch 8 Effluent weak stream 10 ETP

Total 21.90 2.943 29.647 0.122

54.612

24. Di Phenyl Sulfone

Process Description

Benzene is sulphonated with presence of Dimethyl sulphate & sulphur trioxide gas to get the desired product

Diphenyl Sulphone.

Figure 3-24: Process flow diagram for Di Phenyl Sulfone

BenzeneGaseous

Waste

di methyl sulphate

Oleum 65%

Sulfur Trioxide

Water

Ice

Step 1 -

Reaction/Process

Intermediate 1

Step 2 -

Reaction/Process

Drowning

Waste water to ETP

Dust waste to dust

collector

Drying/Packing

Table 3-28: Material Balance for Di Phenyl Sulfone



1 Benene 0.85 2 Dimethyl sulfate 0.97 3 oleum 65% 6.00


LIMITED





4 Boric Acid 0.02 5 Actic unhydride 0.01

6 sulfuric acid 6.90

7 water for process 17.00 8 Water for product washing 2.50


S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 ADMT 1.00 final product 2 Air emission 0.90 scrubber


4 oleum 23% 11.80 Reused in other

product 5 Effluent weak stream 21.5 ETP

Total 23.565 0.90 12.80 0.00

37.265

25. 2-Amino di methyl terephthalate

Process Description

Dimethyl Terephthalalte is nitrated with nitric acid and in the presence of catalyst sulphuric acid to form 2-Nitro

dimethyl terephthalalte.

Further 2-Nitro dimethyl terephthalalte undergoes reduction in the presence of Iron to form the desired quality

product 2-Amino Dimethyl terephthalate which is further filtered & packed.

Figure 3-25: Process flow diagram for 2-Amino di methyl terephthalate

Dimethyl Terephthalalte

Sulfuric Acid

98% Nitric Acid

Ice

Water

23% Oleum

Iron

ortho dichloro benzene

Formic acid

Activated Carbon

Water

Drying/ PackingDust waste to dust

collector

Step 1 -

Reaction/Process

Nitration

Intermediate 1

Step 2 -

Reaction/Process

Reduction

Waste water to ETP

Waste water to ETP

Gaseous Waste

Recovered ortho

dichloro benzene

Process Waste

Table 3-29: Material Balance for 2-Amino di methyl terephthalate



1 Di methyl terephthalate 1.18

2 sulfuric acid 1.90 3 23% oleum 0.76 4 98% Nitric acid 0.62


LIMITED





5 Ice 7.00 6 ortho dichloro benzene 7.65

7 Iron powder 0.70 8 Formic acid 0.17 9 A.carbon 0.08 10 water for process 5.00 11 Water for product washing 10.00


S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 2-Amino di methyl terephthalate 1.00 final product 2 Process waste 1.29 CHWTSDF 3 Air emmission 1.94 scrubber


5 ortho di chloro benzene 7.247 0.02 Distilled & Reused

in next batch 6 Effluent weak stream 22 ETP

Total 25.555 1.94 8.247 1.310

37.052

26. Zinc tetraisopropyl bis(dithiophosphate)

Process Description

Phosphorous pentasulfide is alkylated with the help of zinc chloride & Isopropanol along with the base sodium

hydroxide to form the desired product Zinc tetraisopropyl bis(dithiophosphate) which is further filtered & packed.

Figure 3-26: Process flow diagram for Zinc tetraisopropyl bis(dithiophosphate)

Phosphorus penta

sulfide

Gaseous

Waste

zinc chloride

Iso propyl alcohol

Caustic flakes

Water

TolueneRecovered Iso propyl

alcohol

Dust waste to dust

collector

Step 1 -

Reaction/Process

Intermediate 1

Drying / Packing

Waste water to ETP

Recovered Toluene

Table 3-30: Material Balance for Zinc tetraisopropyl bis(dithiophosphate)

S. No.

Input/MT of Product Raw Materials Quantity (MT/MT)

1 Phosphorus penta sulfide 0.50 2 Toluene 1.23 3 Iso propyl alcohol 0.56 4 Caustic flakes 0.23 5 zinc chloride 0.31

6 water for process 2.66 8 water for machinery washing 3.00

Total 8.484 S.

No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid

Waste

1 Zinc tetraisopropyl bis(dithiophosphate) 1.00 final product


LIMITED





2 Air emission 0.768 scrubber 3 Effluent strong stream 0


in next batch 5 Effluent weak stream 5.5 ETP

Total 5.50 0.768 2.206 0.01

8.484

27. Zink O,O- Dibutyl (DiThiophosphate)

Process Description

Phosphorous Pentasulfide is alkylated with the help of zinc chloride & n- butanol along with the base sodium

hydroxide to form the main product Zinc O,O-dibutyl (dithiophosphate) which is further filtered & packed.

Figure 3-27: Process flow diagram for Zink O,O-Dibutyl DiThiophosphate

phosprous penta sulfide

zinc chloride

n- Butanol

caustic flakes

Water

Toluene

Recovered n-butanol

Recovered Toluene

Gaseous Waste

Step 1 -

Reaction/Process

Drying / Packing

Waste water to ETP

Dust waste to dust

collector

Table 3-31: Material Balance for Zink Dibutyl DiThiophosphate



1 phosprous penta sulfide 0.99 2 Toluene 0.44

3 n- Butanol 0.57 4 caustic flakes 0.21 5 zinc chloride 0.26

6 water for process 1.39 7 Water for product washing 1.00 8 water for machinary washing 2.00

Total 6.851

S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid

Waste 1 Zink Dibutyl DiThiophosphate 1.00 final product 3 Air emission 0.44 scrubber 4 Effluent strong stream 0

5 Toluene 0.403 0.01 Distilled & Reused in


Total 5.00 0.44 1.403 0.01

6.851

28. Dipropyleneglycol methyl-n-propylether

Process Description

Dipropylene Glycol monomethyl ether reacts with 1 – bromopropane in the presence of base sodium hydroxide to

form the main product Dipropylene glycol methyl propylene ether which is further filtered & packed.


LIMITED





Figure 3-28: Process flow diagram for Dipropyleneglycol methyl-n-propylether

Di propylene glycol mono

methyl ether

Gaseous

Waste

1 - bromopropane

caustic flakes

citramide

n-hexane

Water

Packing

Step 1 -

Reaction/Process

Recovered

hexane

Waste water to ETP

Table 3-32: Material Balance for Dipropyleneglycol methyl-n-propylether

S. No.

Input/MT of Product


1 Di propylene glycol mono methyl ether 1.05

2 1 bromo propane 3.48

3 caustic flakes 0.47

4 citramide 0.01

5 n-hexane 0.24


Total 7.245

S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid

Waste

1 Dipropyleneglycol methyl-n-propylether 1.00 final product 2 Process waste 0.105 CHWTSDF


4 hexane 0.206 0.005 Distilled & Reused in

next batch

5 1 bromo propanol 2.470 0.01 Distilled & Reused in

next batch

6 sodium bromide 0.70 0.005 Distilled & Reused in

next batch

7 Effluent weak stream 2 Distilled & Reused in

next batch

Total 2.00 0.744 4.376 0.125 ETP

7.245

29. 2,3 Dichloro 6-quinoaline carbonyl chloride

Process Description

2, 3-Dioxo, 1, 2, 3,4tetrahydro Quixoline-6-Carboxylic Acid is chlorinated with the help of Thionyl chloride to form

the main product 2,3 Dichloro 6-quinoaline carbonyl chloride which is further filtered & packed.

Figure 3-29: Process flow diagram for 2,3 Dichloro 6-quinoaline carbonyl chloride


LIMITED





2,3-

Dioxo,1,2,3,4tetrahydro

Quixoline-6-Carboxylic Acid

Thionyl Chloride

Dibutyl formamide

Packing Gaseous Waste

Step 1 -

Reaction/Process

Gaseous Waste

Recovered thionyl

chloride

Table 3-33: Material Balance for 2,3 Dichloro 6-quinoaline carbonyl chloride

S. No.

Input/MT of Product


1 1,2,3,4 tetra hydro 2,3 dioxoquinoxaline 6 caboxylic acid 0.83


3 Dibutyl formamide 0.03


Total 6.824

S. No.


Remark

Product

Liquid Effluent

Air Emission

Recovery/ Product

Solid Waste

1 2,3 Dichloro 6-quinoaline carbonyl chloride

1.00

final product

3 Air emmission

1.16

scrubber

5 Thionyl Chloride

2.67

scrubber

6 Effluent weak stream 2

ETP

Total 2.00 3.824 1.00 0.00

6.824

30. Direct yeoolw F6GZ

Process Description

Gamma Picolin reacts with Diethyl Sulphate to form Pyridinium, 1,4-dimethyl-, methyl sulfate (1:1).

Further this intermediate compound Pyridinium, 1,4-dimethyl-, methyl sulfate (1:1) undergoes in reaction with 4-

Amino Benzaldehyde another compound Pyridinium, 4-[2-(4-aminophenyl)ethenyl]-1-methyl-, methyl sulfate

Pyridinium, 4-[2-(4-aminophenyl)ethenyl]-1-methyl-, methyl sulfate further reacts with Cyanuric Chloride to

Cynurated Dimethyl ptidinium-methyl sulphate of the reaction & emission of ammonia gas. The Cynurated Dimethyl

ptidinium-methyl sulphate compound thus formed reacts with diethanol amine to form the main product Direct

yeoolw F6GZ which is further filtered & packed along with the emission of ammonia gas.

Figure 3-30: Process flow diagram for Direct yeoolw F6GZ


LIMITED





Gamma PicolinGaseous

Waste

Diethyl Sulphate

4-Amino Benzaldehyde

iso propyl Alchohol

Water

Diethanol Amine

Cyanuric Chloride

Soda Ash

Water

pure salt

formic acid

Acetic acidStep 4 -

Reaction/Process

Gaseous Waste

Packing

Waste water to ETP

Intermediate 2

Step 3 -

Reaction/Process

Waste water to ETP

Intermediate 3

Gaseous Waste

Step 1 -

Reaction/Process

Intermediate 1

Step 2 -

Reaction/Process

Gaseous Waste

Waste water to ETP

Recovered iso propyl

alcohol

Table 3-34: Material Balance for Direct yeoolw F6GZ



1 para amino benzaldehyde 0.13 2 gama picolene 0.21 3 Diethyl sulfate 0.40 4 iso propyl Alchohol 0.13

5 pyridine 0.01 6 Cynuric chloride 0.10 7 Diethanol amine 0.40 8 Soda Ash 0.10

9 pure salt 0.16 10 Acetic acid 0.47 11 formic acid 0.20 12 water for process 29.49 14 water for machinary washing 3.00

Total 34.803

S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 Direct yeoolw F6GZ 1.00 final product 2 Air emission 0.79 scrubber 3 Effluent strong stream 4.887 MEE

4 Iso propyl alcohol 0.122 0.005 Distilled & Reused in


Total 32.887 0.79 1.122 0.005

34.803


LIMITED





31. Diethyl sulfate

Process Description

Ethanol is sulphonated with the help of sulphuric acid to form the main product Diethyl sulphate which is further

filtered & packed.

Figure 3-31: Process flow diagram for Diethyl sulfate

EthanolGaseous

Waste

Sulfuric acid

Magnisium sulfate

Water

Step 1 -

Reaction/Process

Drying / Packing

Waste water to ETP

Dust waste to dust

collector

Table 3-35: Material Balance for Diethyl sulfate


Raw Materials Quantity (MT/MT) 1 Ethanol 0.74 2 Sulfuric acid 0.65 3 Magnisium sulfate 0.11


S. No.


Remark Product

Liquid Effluent

Air Emission

Recovery/ Product

Solid Waste

1 Di Ethyl Sulfate 1.00 final product 2 Process waste 0.12 CHWTSDF

3 Air emmission 0.08 scrubber 4 Effluent strong stream 0.3 MEE


Total 2.30 0.08 1.00 0.12

3.498

32. 4,4`Thio diphenol

Process Description

Phenol undergoes reaction with sulphur dichloride to form the main product 4,4 Thiobisphenol which is further

filtered & packed.

Figure 3-32: Process flow diagram for 4,4`Thio diphenol

Phenol Gaseous Waste

Formaamide Process waste

Sulfur dichloride

Toluene

Water Waste water to ETP

Step 1 -

Reaction/Process

Drying / Packing

Recovered Toluene

Dust waste to dust collector


LIMITED





Table 3-36: Material Balance for 4,4`Thio diphenol



1 phenol 1.43

2 Formaamide 0.07

3 Sulfor di chloride 1.00

4 Toluene 24.97




Total 39.646


Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 4,4`Thio diphenol 1.00 final

product




5 Toluene 23.70 0.02 Distilled & Reused in next batch


Total 13.24 1.676 24.70 0.03

39.646

33. 1,3,benzene diol 4 ( 4,6,bis 2 dimethyl phenyl) 1,3,5 triazine 2-yl

Process Description

Cyanuric chloride is reacted with Resorcinol & m-Xylene with the presence of aluminium chloride to form the main

product 1,3 Benzenediol 4 [ 4,6 bis 2-dimethyl phenyl ]1,3,5 triazine2-yl which is further filtered & packed.

Figure 3-33: Process flow diagram for 1,3,benzene diol 4 ( 4,6,bis 2 dimethyl phenyl) 1,3,5 triazine 2-yl


LIMITED





Cyanuric Chloride Gaseous Waste

Resorcinol Process waste

hydrochloric acid

m-Xyleneortho di chloro

benzeneSulfolane

aluminium chloride

water Waste water to ETP

Process waste

di methyl aceta

amide

Drying / packingDust waste to dust

collector

Step 1 -

Reaction/Process

Intermediate 1

Recovered ortho di chloro

benzene

Recovered sulfolane

Recovered di methyl aceta

amide

Step 2 -

Reaction/Process

Table 3-37: Material Balance for 1,3,benzene diol 4 ( 4,6,bis 2 dimethyl phenyl) 1,3,5 triazine 2-yl



1 cynuric chloride 0.63 2 aluminium chloride 3.00

3 ortho di chloro benzene 5.44 4 hydrochloric acid 18.40

5 metaxylene 0.72 6 resorcinol 0.53

7 Sulfolane 3.40 8 di methyl aceta amide 4.18

9 water for process 18.40 10 Water for product washing 100.00 11 water for machinary washing 5.00

Total 159.70

S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 1,3,benzene diol 4 ( 4,6,bis 2 dimethyl phenyl) 1,3,5 triazine 2-yl

1.00 final product

2 Process waste 1 CHWTSDF 3 Air emission 2.65 scrubber 4 Effluent strong stream 7.683 MEE

5 ortho di chloro benzene 5.158 0.01 Distilled & Reused

in next batch

6 dimethyl aceta amide 3.958 0.01 Distilled & Reused

in next batch

7 sulfolane 3.220 0.01 Distilled & Reused

in next batch


Total 142.683 2.651 13.336 1.030

159.70


LIMITED





34. 2-(2-hydroxy,4- methoxy phenyl) 4,6 diphenyl 1,3,5 triazine

Process Description

2-(2,4 dihydroxyphenyl)-4,6-diphenyl-1,3,5-triazine reacts with Potassium Carbonate & Dimethyl Sulphate to form

its derivate compound 2-(2-Hydroxy-4-methoxyphenyl)-4,6-diphenyl-1,3,5-triazine which is further filtered &

packed.

Figure 3-34: Process flow diagram for 2-(2-hydroxy,4- methoxy phenyl) 4,6 diphenyl 1,3,5 triazine

2-(2,4 dihydroxyphenyl)-

4,6-diphenyl-1,3,5-triazine

Potassium Carbonate

Dimethyl Sulphate

dimethyl formaamide

Water

Gaseous Waste

Dust waste to dust

collectorDrying / Packing

Step 1 -

Reaction/Process Waste water to ETP

Recovered dimethyl

foramide

Table 3-38: Material Balance for 2-(2-hydroxy,4- methoxy phenyl) 4,6 diphenyl 1,3,5 triazine

S. No.

Input/MT of Product


1 BR 1.11

2 pottasium carbonate 1.24

3 di methyl sulfate 0.80

4 dimethyl formaamide 5.56




Total 21.83

S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 2-(2-hydroxy,4- methoxy phenyl) 4,6 diphenyl 1,3,5 triazine

1.00 final product



4 Dimethyl formamaide 5.272 0.01 Distilled & Reused

in next batch


Total 15.27 0.278 6.272 0.01

21.83

35. BTCA(1,2,3,4-Butanetetracarboxylic acid)

Process Description

Tetrahydro Phthalic anhydride undergoes oxidation reaction with hydrogen peroxide to form the product Butane

tetracarboxylic acid which is further filtered & packed.


LIMITED





Figure 3-35: Process flow diagram for BTCA(1,2,3,4-Butanetetracarboxylic acid)

Tetrahydro Phthalic

anhydride

Hydrogen Peroxide Process waste

Activated Carbon

Water

1,4 di oxane

hyflow

Dust waste to dust

collector

Recovered 1,4 di

oxane

Step 1 -

Reaction/Process

Waste water to ETP

Drying / Packing

Table 3-39: Material Balance for BTCA(1,2,3,4-Butanetetracarboxylic acid)

S. No.

Input/MT of Product


1 Tetra hydro phthalic unhydride 1.15

2 Hydrogen peroxide 50% 3.11

3 Activated carbon 0.22

4 1,4 di oxane 3.00

5 hyflow 0.15



Total 10.775

S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 BTCA(1,2,3,4-Butanetetracarboxylic acid) 1.00 final product


3 Air emission 0.825 scrubber


5 1,4 Dioxane 2.840 0.01 Distilled & Reused in

next batch Effluent weak stream 2 ETP

Total 5.50 0.825 3.840 0.61

10.775

36. 2 anilino 6 dibutyl amino, 3 methyl fluoran

Process Description

m-Amino phenol is reacted with n-butyl bromide to form derivative of phenol compound i.e. Phenol ( 3-dibutyl

amino ).

Further Phenol ( 3-dibutyl amino ) under goes reaction with Phthalic Anhydride and the product formed is 2-[4-

(Dibutylamino)-2-hydroxybenzoyl] benzoic acid.

Then 2-[4-(Dibutylamino)-2-hydroxybenzoyl] benzoic acid is reacted with 4-methoxy 2-methyl Diphenyl amine to

give the main product 2-anilino-6-dibutylamino-3-methylfluoran.

Figure 3-36: Process flow diagram for 2 anilino 6 dibutyl amino, 3 methyl fluoran


LIMITED





meta amino phenolGaseous

Waste

n-Butyl bromide

caustic lye Process waste

Sodium carbonate

sodium bi carbonate

phthalic anhydride

Toluene

Water

4-methoxy 2-methyl

Diphenyl amine

Sulfuric acid

ICE

N-hexane

Iso propyl alcohol

Recovered Toluene

Drying / Packing

Intermediate 2

Step 3 -

Reaction/Process

Recovered hexane

Dust waste to dust

collector

Recovered iso propyl

alcohol

Step 1 -

Reaction/Process

Intermediate 1

Step 2 -

Reaction/Process

Incinerable Waste

Waste water to ETP

Waste water to ETP

Table 3-40: Material Balance for 2 anilino 6 dibutyl amino, 3 methyl fluoran

S. No.

Input/MT of Product


1 meta amino phenol 0.50 2 n-butyl bromide 1.54

3 caustic lye 0.82 4 Sodium carbonate 0.06 5 sodium bi carbonate 0.00 6 phthalic unhidride 0.95

7 Toluene 3.82 8 Sulfuric acid 4.25

9 methoxy methyl di phenyl amine 0.67 10 N-hexane 2.39 11 Iso propyl alcohol 8.74

12 ICE 35.62 13 water for process 0.74 14 Water for product washing 3.20 15 water for machinary washing 3.00

Total 66.29

S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 2 anilino 6 dibutyl amino, 3 methyl fluoran

1.00 final product

2 Air emission 2.75 scrubber



in next batch

5 N-hexane 2.257 0.01 Distilled & Reused

in next batch

6 Iso propyl Alchohol 8.290 0.01 Distilled & Reused

in next batch 8 Effluent weak stream 46.203 ETP


LIMITED





Total 48.342 2.75 15.168 0.03

66.29

37. IPFENCARBAZONE

Process Description

2,4 Dichloro Aniline reacts with hydrochloric acid & nitrite to get diazotized product which reacts with

sodium sulphide to get adduct product, after hydrolysis gives 2,4 Dichloro Phenyl Hydrazine. This hydrazine

product react with formaldehyde to give hydrazone. This hydrazone reacts with sodium cynate to give

cyclisation product which after oxidation with sodium hypochlorite gives 1(2,4 Dichloro Phenyl) - 5 Oxo -

,4H -1,2,4 triazolene (Intermediate A).

2,4 Difluoro Aniline reacts with isopropyl bromide to give N-isopropyl 2,4 Difluoro Aniline which reacts with

bis tri chloro methyl carbonate to give N-isopropyl 2,4 Difluoro Acid Chloride (Intermediate B).

1(2,4 Dichloro Phenyl) - 5 Oxo -,4H -1,2,4 triazolene(Intermediate A) condenses with N-isopropyl 2,4

Difluoro Acid Chloride (Intermediate B) to give Ipfencarbazone

Figure 3-37: Process flow diagram for IPFENCARBAZONE

2,4 Dichloro Aniline2,4 Difluoro

Aniline

Hydrochloric AcidIsopropyl

Bromide

Sodium Nitrite Caustic lye

2,4 Dichloro Aniline

Hydrochloriden hexane

water water

2,4 Difluoro

Aniline

Isopropyl

Bromide

Caustic lye

toluene

Sodium sulfite Water

Sulfuric Acid

Sodium Hydroxide Triphosgene

toluene

Formaldehyde

Tertiary butanol Intermediate 2

Sodium cynate

Sodium acetate unhydrous

Glacial Acetic Acid

13% Sodium hypochlorite

Ethylene dichloride

Water

Caustic Lye

Methanol

n-hexane

Drying / Packing Dust waste to dust

Intermediate 2

Tetra Butyl ammonnium

bromide

toluene

Water

Bis chloro methyl carbonte

Caustic Lye

Step 1 -

Reaction/Process

Diazotisation

Intermediate 1A

Step 2 -

Reaction/ProcessWaste water to ETP

Waste water to ETP

Intermediate 1B

Step 3 -

Reaction/Process

Intermediate 1

Waste water to ETP

Recovered

Ethylene

dichloride

Waste water to ETP

Recovered

toluene

Step 3 -

Reaction/Process

Gaseous Waste

Recovered methanol

Recovered n-hexane

Recovered toluene

Step 6 -

Reaction/Process

Step 1 -

Reaction/Process

Step 5 -

Reaction/Process

Waste water to ETP

Intermediate2A

Recovered n-

hexane

Recovered

Tertiary

butanol

Step 1 -

Reaction/Process

Waste water to ETP

Intermediate 2A

Step 2 -

Reaction/Process

Table 3-41: Material Balance for IPFENCARBAZONE


LIMITED







1 2,4 Dichloro aniline 0.750

2 sodium Nitrate 0.750

3 Toluene 0.750

4 Hydrochloride 15.399

5 Sodium sulfite photo grade 1.493

6 Sulfuric 0.047

7 Caustic lye 10.886

8 Tertiary butanol 3.920

9 Formaldehyde 0.359

10 Sodium acetate unhydrous 0.018

11 Glacial Acetic Acid 0.005

12 Sodium cynate 0.483

13 ACOH 0.554

14 13% NaOCL 2.632

15 Ethylene dichloride 4.218

16 Tertiary butanol 3.503

17 2,4 Difluro aniline 0.319

18 Iso propyl bromide 0.362

19 n hexane 0.158

20 Toluene 0.250

21 Tetra Butyl ammonnium bromide 7.100

22 Triphosgene 0.397

23 Methanol 0.119




Total

116.970

S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid Waste

1 IPFENCARBAZONE

1.00

final product

2 Process waste

0.214 CHWTSDF

3 Air emmission

10.057

scrubber

4 Effluent strong stream 12.88

MEE

5 Toluene

6.764 0.01 Distilled & Reused in

next batch

6 Ethylene di chloride


next batch

7 Tert butanol recovery


next batch

8 Methanol


next batch 9 Effluent weak stream 75

ETP

Total 87.88 9.660 18.779 0.254

116..970


LIMITED





38. m-cresol pure

Process Description

6-Tertiary Butyl m-cresol reacts in the presence of para toluene sulfonic acid to form product m-Cresol which is

further filtered & packed.

Figure 3-38: Process flow diagram for m-cresol pure

6-Tertiary Butyl m-cresol Gaseous Waste

Para toluene sulfonic acid Gaseous Waste to scrubber

Sodium bi carbonate

Hyflow Process waste

Ethyl Acetate

Conc. HCL

Castic lye

Activated carbon

Dust waste to dust collector

Recovered Isobutylene gas

Step 1 -

Reaction/Process

Drying / Packing

Table 3-42: Material Balance for m-cresol pure



1 6 tertiary butyl phenol 1.87

2 Para toluene sulfonic acid 0.04

3 Sodium bi carbonate 0.02

4 Castic lye 0.93

5 Activated carbon 0.09

6 Hyflow 0.02

7 Ethyl Acetate 0.28

8 Conc. HCL 1.36




Total 7.616

S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid

Waste

1 m-cresol pure 1.00 final product




5 Isobutyl gas 0.322 0.005 Distilled & Reused in

next batch

6 Ethyl Acetate 0.260 0.005 Distilled & Reused in

next batch


Total 5.424 0.389 1.582 0.221

7.616


LIMITED





39. Oligomer of Phenyl phthalimide para bis phenol

Process Description

Phenolpthalein condensed with aniline oil to form Phthalimidine para bis phenol which reacts with Terephthaloyl

Chloride in the presence of Methylene dichloride & Triethylamine and product formed is Oligomer of Phenyl

phthalimide para bis phenol which is further filtered & packed.

Figure 3-39: Process flow diagram for Oligomer Phenyl phthalimide para bis phenol

Phenolpthalein

Aniline oil

Hydrochloric acid

Terephthaloyl

Chloride Triethylamine

Caustic lye

Activated carbon

WaterMethylene di

chloride

Drying / Packing

Gaseous waste to

scrubber

Dust waste to dust

collector

Gaseous Waste

Step 1 -

Reaction/Process

Intermediate 1

Step 2 -

Reaction/Process

Gaseous waste to

scrubber Waste water to ETP

Recovered Methylene

di chloride

Table 3-43: Material Balance for Oligomer of Phenyl phthalimide para bis phenol



1 Phenophthalein 1.000


3 Caustic lye 0.400

4 Aniline oil 1.000

5 A carbon 0.600




Total 49.947

S. No.


Product Liquid

Effluent Air

Emission Recovery/

Product Solid

Waste

1 Phenyl phthalimide para bis phenol 1.00 final product



4 Methylene Di Chloride 3.390 0.01 Distilled & Reused

in next batch

5 Tertiary ehthylene amine dichloride 0.937 0.01 Distilled & Reused

in next batch


LIMITED







Total 42.00 1.40 5.327 1.22

49.947


LIMITED





Annexure 7: Raw Material & Product Storage Details

Table 3-44: Storage Details

S.

No. Chemical State Means of Storage

Capacity of

Storage Means,

MT

No. of

Storage

means

Total

Capacity,

MT

Pressure Temperature

RAW MATERIAL

1 EATC liquid HDPE drums 5 1 5 ATM Room Temp.

2 1 bromo propane liquid HDPE drums 1 1 1 ATM Room Temp.

3 1 N Hydrochloric Acid liquid HDPE drums 2 1 2 ATM Room Temp.

4 1,2,3,4 tetra hydro 2,3 dioxoquinoxaline 6

caboxylic acid liquid HDPE drums 0.5 1 0.5 ATM Room Temp.

5 1,4 di oxane liquid MS tank 10 1 10 ATM Room Temp.

6 13% NaOCl liquid HDPE drums 2 1 2 ATM Room Temp.

7 2 mercaptoethanol liquid HDPE drums 5 1 5 ATM Room Temp.

8 2 Methyl Resorcinol solid fibre drums 10 1 10 ATM Room Temp.

9 2,4 Dichloro aniline liquid HDPE drums 5 1 5 ATM Room Temp.

10 2,4 Difluro aniline liquid HDPE drums 1 1 1 ATM Room Temp.

11 2,5 Dichloroaniline liquid HDPE drums 3 1 3 ATM Room Temp.

12 2-Fluro Aniline liquid HDPE drums 5 1 5 ATM Room Temp.

13 4 Chloro Amino Phenol solid HDPE bags 5 1 5 ATM Room Temp.

14 4 Chloro Nitro Phenol solid HDPE bags 5 1 5 ATM Room Temp.

15 40% NSA Solution liquid HDPE drums 0.2 1 0.2 ATM Room Temp.

16 98% Nitric Acid liquid Aluminium tank 10 1 10 ATM Room Temp.

17 A carbon solid HDPE bags 5 1 5 ATM Room Temp.

18 Acetic acid liquid HDPE TANK 10 1 10 ATM Room Temp.

19 Acetic unhydride liquid SS tank 15 1 15 ATM Room Temp.

20 ACOH liquid HDPE drums 2 1 2 ATM Room Temp.

21 Acrylic Acid solid HDPE bags 2 1 2 ATM Room Temp.

22 Aluminium Chloride solid MS pp liner bags 5 1 5 ATM Room Temp.

23 Ammonia liquid MS tank 20 1 20 ATM Room Temp.


LIMITED





S.


Capacity of

Storage Means,

MT

No. of

Storage

means

Total

Capacity,

MT


24 Ammonia gas gas MS cylinders 2.5 1 2.5 12 kg/cm2 Room Temp.

25 Aniline oil liquid MS drums 3 1 3 ATM Room Temp.

26 BA liquid HDPE drums 3 1 3 ATM Room Temp.

27 Benzene liquid MS tank 10 1 10 ATM Room Temp.

28 Boric Acid solid HDPE bags 5 1 5 ATM Room Temp.

29 BPAF solid HDPE bags 2 1 2 ATM Room Temp.

30 BR solid HDPE bags 2 1 2 ATM Room Temp.

31 Bromine liquid glass bottles 2 1 2 ATM Room Temp.

32 Catalyst SCPC solid HDPE bags 0.1 1 0.1 ATM Room Temp.

33 Catalyst SCPI solid HDPE bags 0.1 1 0.1 ATM Room Temp.

34 Caustic lye liquid MS tank 20 1 20 ATM Room Temp.

35 caustic flakes solid HDPE bags 5 1 5 ATM Room Temp.

36 Chlorine gas gas MS Tonner 3.6 1 3.6 10 kg/cm2 Room Temp.

37 Chlorosulfonic Acid liquid MS tank 15 1 15 ATM Room Temp.

38 citramide liquid HDPE drums 0.42 1 0.42 ATM Room Temp.

39 Copper Sulfate solid HDPE bags 5 1 5 ATM Room Temp.

40 CPC solid HDPE bags 3 1 3 ATM Room Temp.

41 Cyclohexanone liquid MS tank 20 1 20 ATM Room Temp.

42 Cynuric chloride solid pp liner MS drums 5 1 5 ATM Room Temp.

43 Di methyl aceta amide liquid HDPE drums 5 1 5 ATM Room Temp.

44 Di Methyl Sulfate liquid HDPE drums 5 1 5 ATM Room Temp.

45 Di methyl terephthalate liquid HDPE drums 5 1 5 ATM Room Temp.

46 Di propylene glycol mono methyl ether liquid HDPE drums 2 1 2 ATM Room Temp.

47 Dibutyl formamide liquid HDPE drums 0.93 1 0.93 ATM Room Temp.

48 dichlone liquid HDPE drums 1 1 1 ATM Room Temp.

49 Diethanol amine liquid HDPE drums 5 1 5 ATM Room Temp.

50 Diethyl sulfate solid HDPE bags 5 1 5 ATM Room Temp.


LIMITED





S.


Capacity of

Storage Means,

MT

No. of

Storage

means

Total

Capacity,

MT


51 Dimethyl formaamide liquid HDPE drums 10 1 10 ATM Room Temp.

52 Dimethyl sulfate liquid HDPE drums 5 1 5 ATM Room Temp.

53 Diphenyl Sulfone solid HDPE bags 5 1 5 ATM Room Temp.

54 DMSO liquid HDPE drums 5 1 5 ATM Room Temp.

55 ECFC liquid HDPE drums 5 1 5 ATM Room Temp.

56 Ethanol liquid MS tank 20 1 20 ATM Room Temp.

57 Ethyl chloroformate liquid HDPE drums 5 1 5 ATM Room Temp.

58 Ethyl Trifluro aceto acetate liquid HDPE drums 5 1 5 ATM Room Temp.

59 Ethylene Carbonate solid HDPE bags 5 1 5 ATM Room Temp.

60 Ethylene Di Chloride liquid MS tank 20 1 20 ATM Room Temp.

61 Europeon Acid liquid HDPE drums 2 1 2 ATM Room Temp.

62 Flurobenzoic acid liquid HDPE drums 0.5 1 0.5 ATM Room Temp.

63 Formaldehyde liquid HDPE drums 5 1 5 ATM Room Temp.

64 Formic Acid liquid HDPE drums 4 1 4 ATM Room Temp.

65 Gama butyl lactone liquid HDPE drums 4 1 4 ATM Room Temp.

66 Gama picolene liquid HDPE drums 3 1 3 ATM Room Temp.

67 Glaubber salt solid HDPE bags 1.14 1 1.14 ATM Room Temp.

68 Glycerine liquid HDPE drums 10 1 10 ATM Room Temp.

69 Hexane liquid MS tank 20 1 20 ATM Room Temp.

70 Hydrazine Hydrate liquid HDPE drums 10 1 10 ATM Room Temp.

71 Hydrochloric Acid liquid HDPE TANK 30 1 30 ATM Room Temp.

72 Hydrogen peroxide 50% liquid HDPE drums 5 1 5 ATM Room Temp.

73 Hydros solid pp liner MS drums 0.4 1 0.4 ATM Room Temp.

74 Hyflow solid HDPE bags 2 1 2 ATM Room Temp.

75 ICE NA NA NA NA NA NA NA

76 Iodine liquid glass bottles 1 1 1 ATM Room Temp.

77 Iron Powder solid HDPE bags 10 1 10 ATM Room Temp.


LIMITED





S.


Capacity of

Storage Means,

MT

No. of

Storage

means

Total

Capacity,

MT


78 Iso Propyl Alchohol liquid MS tank 20 1 20 ATM Room Temp.

79 J Acid solid HDPE bags 2 1 2 ATM Room Temp.

81 Magnisium sulfate solid HDPE bags 5 1 5 ATM Room Temp.

82 Meta amino phenol liquid HDPE drums 10 1 10 ATM Room Temp.

83 Metanilic acid solid HDPE bags 10 1 10 ATM Room Temp.

84 Metaxylene liquid HDPE drums 2 1 2 ATM Room Temp.

85 Methanol liquid MS tank 20 1 20 ATM Room Temp.

86 Methoxy methyl di phenyl amine liquid HDPE drums 5 1 5 ATM Room Temp.

87 Methylene Di Chloride liquid MS tank 20 1 20 ATM Room Temp.

88 Mono Ethylene Glycol liquid HDPE drums 4 1 4 ATM Room Temp.

89 n- Butanol liquid MS tank 10 1 10 ATM Room Temp.

90 NASA 53% liquid HDPE drums 0.2 1 0.2 ATM Room Temp.

91 Nash Solution liquid HDPE drums 2 1 2 ATM Room Temp.

92 n-butyl bromide liquid HDPE drums 5 1 5 ATM Room Temp.

93 Ni+ Catalyst solid pp liner MS drums 0.3 1 0.3 ATM Room Temp.

94 Nitric acid 60% liquid SS tank NA 1 NA ATM Room Temp.

95 Nitric Acid 70% liquid SS tank 30 1 30 ATM Room Temp.

96 Oleum 23% liquid MS tank 30 1 30 ATM Room Temp.

97 Oleum 65% liquid MS tank 30 1 30 ATM Room Temp.

98 Ortho Amino Phenol solid HDPE bags 20 1 20 ATM Room Temp.

99 Ortho anisidine liquid HDPE drums 5 1 5 ATM Room Temp.

100 Ortho Di Chloro Benzene liquid HDPE drums 5 1 5 ATM Room Temp.

101 Ortho Toludine Diamine liquid HDPE drums 50 1 50 ATM Room Temp.

102 OT base solid HDPE bags 5 1 5 ATM Room Temp.

103 Para amino benzaldehyde liquid HDPE drums 4 1 4 ATM Room Temp.

104 Para chloro benzoic acid liquid HDPE drums 0.01 1 0.01 ATM Room Temp.

105 Para Nitro Amino Sulfonic Acid solid HDPE bags 2 1 2 ATM Room Temp.


LIMITED





S.


Capacity of

Storage Means,

MT

No. of

Storage

means

Total

Capacity,

MT


106 Phenol liquid HDPE drums 5 1 5 ATM Room Temp.

107 Phenophthalein liquid HDPE drums 10 1 10 ATM Room Temp.

108 Phosphoric Acid liquid HDPE drums 2 1 2 ATM Room Temp.

109 Phosphorus penta sulfide liquid HDPE drums 5 1 5 ATM Room Temp.

110 Phthalic unhidride liquid HDPE drums 5 1 5 ATM Room Temp.

111 Pottasium carbonate solid HDPE bags 5 1 5 ATM Room Temp.

112 Pyridine liquid HDPE drums 0.2 1 0.2 ATM Room Temp.

113 RA 212 liquid HDPE drums 5 1 5 ATM Room Temp.




117 Red phosporus solid pp liner MS drums 5 1 5 ATM Room Temp.

118 Resorcinol solid HDPE bags 10 1 10 ATM Room Temp.

119 Salt solid HDPE bags 50 1 50 ATM Room Temp.

120 Soda Ash solid HDPE bags 25 1 25 ATM Room Temp.

121 Sodium acetate unhydrous solid HDPE bags 5 1 5 ATM Room Temp.

122 Sodium bi carbonate solid HDPE bags 10 1 10 ATM Room Temp.

123 Sodium bi sulfate solid HDPE bags 5 1 5 ATM Room Temp.

124 Sodium Bi Sulfide solid HDPE bags 5 1 5 ATM Room Temp.

125 Sodium cynate solid HDPE bags 5 1 5 ATM Room Temp.

126 Sodium Methoxide solid HDPE bags 0.36 1 0.36 ATM Room Temp.

127 Sodium Nitrate solid HDPE bags 5 1 5 ATM Room Temp.

128 Sodium Sulfide flakes solid HDPE bags 5 1 5 ATM Room Temp.

129 Sodium sulfite photo grade solid HDPE bags 5 1 5 ATM Room Temp.

130 Stanus Chloride liquid HDPE drums 0.1 1 0.1 ATM Room Temp.

131 Sulfamic Acid solid HDPE bags 1 1 1 ATM Room Temp.

132 Sulfolane liquid HDPE drums 20 1 20 ATM Room Temp.


LIMITED





S.


Capacity of

Storage Means,

MT

No. of

Storage

means

Total

Capacity,

MT


133 Sulfor di chloride liquid HDPE drums 1 1 1 ATM Room Temp.

134 Sulfor Powder solid HDPE bags 3 1 3 ATM Room Temp.

135 Sulfuric Acid liquid MS tank 60 1 60 ATM Room Temp.

136 Sulfuryl Chloride liquid HDPE drums 10 1 10 ATM Room Temp.

137 TEA liquid HDPE drums 10 1 10 ATM Room Temp.

138 Tertiary ammonium bromide liquid HDPE drums 1 1 1 ATM Room Temp.

139 Tertiary butanol liquid HDPE drums 5 1 5 ATM Room Temp.

140 Tetra Butyl ammonnium bromide liquid HDPE drums 2 1 2 ATM Room Temp.

141 Tetra hydro phthalic unhydride liquid HDPE drums 2 1 2 ATM Room Temp.

142 Thionyl Chlooride liquid HDPE drums 10 1 10 ATM Room Temp.

143 Toluene liquid MS tank 20 2 40 ATM Room Temp.

144 Tri phosgene solida HDPE drums 2 1 2 ATM 10 c

145 Urea T.G solid HDPE bags 10 1 10 ATM Room Temp.

146 Zinc chloride solid HDPE drums 2 1 2 ATM Room Temp.

FINISHED GOODS

1 4-Amino-3-Methoxy Azobenzene-3-Sulphuric Acid Solid HDPE Bags 10 1 10 ATM Room Temp.

2 5-Nito 2-Amino Phenol Solid HDPE Bags 10 1 10 ATM Room Temp.

3 5 Amino 6 Methyl Benzimidazolone Solid HDPE Bags 15 1 15 ATM Room Temp.

4 5 Chloro 8 Hdroxy quinolene Solid HDPE Bags 20 1 20 ATM Room Temp.

5 2,5 Dichloro p-Phenylene diamine Solid HDPE Bags 10 1 10 ATM Room Temp.

6 4-(2 Chloro-Ethyl Sulfonyl) Butric Acid Solid HDPE Bags 5 1 5 ATM Room Temp.

7 2-Chloro 4-(2 Chloro Ethyl sulfonyl) Butric Acid liquid HDPE DRUMS 15 1 15 ATM Room Temp.

8 2,4,6-Tri[ ( 2,4-Dihydroxy3-Methyl) Phenyl] 1,3,5-

Trizine Solid HDPE Bags 12 1 12 ATM Room Temp.

9 2-(4,6-Di Phenyl-1,3,5-Triazine-2-yl)-5(2-

Hydroxyethoxy) Phenol Solid HDPE Bags 5 1 5 ATM Room Temp.

10 2,3-Dibromo propanyl chloride liquid HDPE drums 5 1 5 ATM Room Temp.


LIMITED





S.


Capacity of

Storage Means,

MT

No. of

Storage

means

Total

Capacity,

MT


11 2-Amino 4[(2,3,-Di Bromo 1-oxypropyl) amine],

Benzene Sulfonic Acid Solid HDPE Bags 5 1 5 ATM Room Temp.

12 3-Amino-4-[(4-Amino 2 sulfophenyl)-Diazynyl]5

hydroxynapthalene,2,7 Disulfonic acid Solid HDPE Bags 5 1 5 ATM Room Temp.

13 4,4'-Diamino Diphenyl Amine Sulphate Solid HDPE Bags 5 1 5 ATM Room Temp.

14 Anilino methane sulfonic acid Solid HDPE Bags 5 1 5 ATM Room Temp.

15

Cuprate{2-[1-amino-4-hydroxyl 3-(2 hydroxyl-5-

sulfophenyl)azo-4,5-dimethoxy phenyl]}azo-2-

Naphthalene sulfonic acid

Solid HDPE Bags 5 1 5 ATM Room Temp.

16 3-(4-Chloro-2-Fluro-5-mercaptophenyl)-1-Methyl-

6- trifluromethyl,H-pyrinidine-2-,4-dione Solid HDPE Bags 20 1 20 ATM Room Temp.

17 3(2-Chloro ropionyl aniline) propionic acid methyl

ester liquid HDPE drums 20 1 20 ATM Room Temp.

18 Diamino Benzoic Acid Solid HDPE Bags 3 1 3 ATM Room Temp.

19 3,3 Dinitro di Phenyl Sulfone Solid HDPE Bags 3 1 3 ATM Room Temp.

20 2,2-Bis(4-hydroxy-3-nitrophenol,hexafluro)

propane Solid HDPE Bags 3 1 3 ATM Room Temp.

21 3-(Dibromo Propionyl)Amido-Benzoyl K Acid Solid HDPE Bags 3 1 3 ATM Room Temp.

22 3,7-Diamino-2-,8-Dimethyl dibenzothiophenne 5,5

dioxide hyrochloride Solid HDPE Bags 3 1 3 ATM Room Temp.

23 3-(2,4-Dichlorophenyl)-6-Fluroquinazoline-2,4

(1H,3H-Dione Solid HDPE Bags 3 1 3 ATM Room Temp.

24 Di Phenyl Sulfone Solid HDPE Bags 10 1 10 ATM Room Temp.

25 2-Amino di methyl terephthalate Solid HDPE Bags 10 1 10 ATM Room Temp.

26 Zinc tetraisopropyl bis(dithiophosphate) Solid HDPE Bags 10 1 10 ATM Room Temp.

27 Zink Dibutyl DiThiophosphate Liquid M S drums 10 1 10 ATM Room Temp.

28 Dipropyleneglycol methyl-n-propylether Solid HDPE Bags 3 1 3 ATM Room Temp.


LIMITED





S.


Capacity of

Storage Means,

MT

No. of

Storage

means

Total

Capacity,

MT


29 2,3 Dichloro 6-quinoaline carbonyl chloride Solid HDPE Bags 10 1 10 ATM Room Temp.

30 Direct yeoolw F6GZ Solid HDPE Bags 10 1 10 ATM Room Temp.

31 Diethyl sulfate Solid HDPE Bags 10 1 10 ATM Room Temp.

32 4,4`Thio diphenol Solid HDPE Bags 10 1 10 ATM Room Temp.

33 1,3,benzene diol 4 ( 4,6,bis 2 dimethyl phenyl)

1,3,5 triazine 2-yl Solid HDPE Bags 10 1 10 ATM Room Temp.

34 2-(2-hydroxy,4- methoxy phenyl) 4,6 diphenyl

1,3,5 triazine Solid HDPE Bags 10 1 10 ATM Room Temp.

35 BTCA (1,2,3,4-Butanetetracarboxylic acid) Solid HDPE Bags 10 1 10 ATM Room Temp.

36 2 anilino 6 dibutyl amino, 3 methyl fluoran Solid HDPE Bags 20 1 20 ATM Room Temp.

37 IPFENCARBAZONE Solid HDPE Bags 10 1 10 ATM Room Temp.

38 m-cresol pure Solid HDPE Bags 2 1 2 ATM Room Temp.

39 Phenyl phthalimide para bis phenol Solid HDPE Bags 10 1 10 ATM Room Temp.

Total


LIMITED





Table 3-45: Transportation Details

S. No. Chemical State Means of

Transportation Source

RAW MATERIAL

1 EATC liquid ROAD LOCAL

2 1 bromo propane liquid ROAD LOCAL

3 1 N Hydrochloric Acid liquid ROAD LOCAL

4 1,2,3,4 tetra hydro 2,3 dioxoquinoxaline 6

caboxylic acid liquid ROAD LOCAL

5 1,4 di oxane liquid ROAD LOCAL

6 13% NaOCL liquid ROAD LOCAL

7 2 mercaptoethanol liquid ROAD LOCAL

8 2 Methyl Resorcinol solid ROAD/SEA IMPORTED

9 2,4 Dichloro aniline liquid ROAD LOCAL

10 2,4 Difluro aniline liquid ROAD LOCAL

11 2,5 Dichloroaniline liquid ROAD LOCAL

12 2-Fluro Aniline liquid ROAD LOCAL

13 4 Chloro Amino Phenol solid ROAD/SEA IMPORTED

14 4 Chloro Nitro Phenol solid ROAD LOCAL

15 40% NSA Solution liquid ROAD LOCAL

16 98% Nitric Acid liquid ROAD LOCAL

17 A carbon solid ROAD LOCAL

18 Acetic acid liquid ROAD LOCAL

19 Acetic unhydride liquid ROAD LOCAL

20 ACOH liquid ROAD LOCAL

21 Acrylic Acid solid ROAD LOCAL

22 Aluminium Chloride solid ROAD LOCAL

23 Ammonia liquid ROAD LOCAL

24 Ammonia gas gas ROAD LOCAL

25 Aniline oil liquid ROAD LOCAL

26 BA liquid ROAD Imported

27 Benzene liquid ROAD LOCAL

28 Boric Acid solid ROAD LOCAL

29 BPAF solid ROAD/SEA IMPORTED

30 BR solid ROAD/SEA IMPORTED

31 Bromine liquid ROAD LOCAL

32 Catalyst SCPC solid ROAD LOCAL

33 Catalyst SCPI solid ROAD LOCAL

34 Caustic lye liquid ROAD LOCAL

35 caustic flakes solid ROAD LOCAL

36 Chlorine gas gas ROAD LOCAL

37 Chlorosulfonic Acid liquid ROAD LOCAL

38 citramide liquid ROAD LOCAL

39 Copper Sulfate solid ROAD LOCAL

40 CPC solid ROAD LOCAL

41 Cyclohexanone liquid ROAD LOCAL


LIMITED







42 Cynuric chloride solid ROAD/SEA IMPORTED

43 di methyl aceta amide liquid ROAD LOCAL

44 Di Methyl Sulfate liquid ROAD LOCAL

45 Di methyl terephthalate liquid ROAD LOCAL

46 Di propylene glycol mono methyl ether liquid ROAD LOCAL

47 Dibutyl formamide liquid ROAD LOCAL

48 dichlone liquid ROAD LOCAL

49 Diethanol amine liquid ROAD LOCAL

50 Diethyl sulfate solid ROAD LOCAL

51 dimethyl formaamide liquid ROAD LOCAL

52 Dimethyl sulfate liquid ROAD LOCAL

53 Diphenyl Sulfone solid ROAD LOCAL

54 DMSO liquid ROAD LOCAL

55 ECFC liquid ROAD LOCAL

56 Ethanol liquid ROAD LOCAL

57 Ethyl chloroformate liquid ROAD LOCAL

58 Ethyl Trifluro aceto acetate liquid ROAD LOCAL

59 Ethylene Carbonate solid ROAD LOCAL

60 Ethylene Di Chloride liquid ROAD LOCAL

61 Europeon Acid liquid ROAD LOCAL

62 Flurobenzoic acid liquid ROAD LOCAL

63 Formaldehyde liquid ROAD LOCAL

64 Formic Acid liquid ROAD LOCAL

65 Gama butyl lactone liquid ROAD LOCAL

66 gama picolene liquid ROAD LOCAL

67 Glaubber salt solid ROAD LOCAL

68 Glycerine liquid ROAD LOCAL

69 Hexane liquid ROAD LOCAL

70 Hydrazine Hydrate liquid ROAD/SEA LOCAL\imported

71 Hydrochloric Acid liquid ROAD LOCAL

72 Hydrogen peroxide 50% liquid ROAD LOCAL

73 Hydros solid ROAD LOCAL

74 hyflow solid ROAD LOCAL

75 ICE NA ROAD LOCAL

76 Iodine liquid ROAD LOCAL

77 Iron Powder solid ROAD LOCAL

78 Iso Propyl Alchohol liquid ROAD LOCAL

79 J Acid solid ROAD LOCAL

81 Magnisium sulfate solid ROAD LOCAL

82 meta amino phenol liquid ROAD LOCAL

83 metanilic acid solid ROAD LOCAL

84 metaxylene liquid ROAD LOCAL

85 Methanol liquid ROAD LOCAL

86 methoxy methyl di phenyl amine liquid ROAD LOCAL


LIMITED







87 Methylene Di Chloride liquid ROAD LOCAL

88 Mono Ethylene Glycol liquid ROAD LOCAL

89 n- Butanol liquid ROAD LOCAL

90 NASA 53% liquid ROAD LOCAL

91 Nash Solution liquid ROAD LOCAL

92 n-butyl bromide liquid ROAD LOCAL

93 Ni+ Catalyst solid ROAD LOCAL

94 Nitric acid 60% liquid ROAD LOCAL

95 Nitric Acid 70% liquid ROAD LOCAL

96 oleum 23% liquid ROAD LOCAL

97 Oleum 65% liquid ROAD LOCAL

98 Ortho Amino Phenol solid ROAD LOCAL

99 Ortho anisidine liquid ROAD LOCAL

100 Ortho Di Chloro Benzene liquid ROAD LOCAL

101 Ortho Toludine Diamine liquid ROAD LOCAL

102 OT base solid ROAD LOCAL

103 para amino benzaldehyde liquid ROAD LOCAL

104 Para chloro benzoic acid liquid ROAD LOCAL

105 Para Nitro Amino Sulfonic Acid solid ROAD LOCAL

106 phenol liquid ROAD LOCAL

107 Phenophthalein liquid ROAD LOCAL

108 Phosphoric Acid liquid ROAD LOCAL

109 Phosphorus penta sulfide liquid ROAD LOCAL

110 phthalic unhidride liquid ROAD LOCAL

111 pottasium carbonate solid ROAD LOCAL

112 pyridine liquid ROAD LOCAL

113 RA 212 liquid ROAD LOCAL




117 Red phosporus solid ROAD LOCAL

118 Resorcinol solid ROAD LOCAL

119 Salt solid ROAD LOCAL

120 Soda Ash solid ROAD LOCAL

121 Sodium acetate unhydrous solid ROAD LOCAL

122 sodium bi carbonate solid ROAD LOCAL

123 Sodium bi sulfate solid ROAD LOCAL

124 Sodium Bi Sulfide solid ROAD LOCAL

125 Sodium cynate solid ROAD LOCAL

126 Sodium Methoxide solid ROAD LOCAL

127 Sodium Nitrate solid ROAD LOCAL

128 Sodium Sulfide flakes solid ROAD LOCAL

129 Sodium sulfite photo grade solid ROAD LOCAL

130 Stanus Chloride liquid ROAD LOCAL


LIMITED







131 Sulfamic Acid solid ROAD LOCAL

132 Sulfolane liquid ROAD/SEA LOCAL\IMPORTED

133 Sulfor di chloride liquid ROAD LOCAL

134 Sulfor Powder solid ROAD LOCAL

135 Sulfuric Acid liquid ROAD LOCAL

136 Sulfuryl Chloride liquid ROAD LOCAL

137 TEA liquid ROAD LOCAL

138 Tertiary ammonium bromide liquid ROAD LOCAL

139 Tertiary butanol liquid ROAD LOCAL

140 Tetra Butyl ammonnium bromide liquid ROAD LOCAL

141 Tetra hydro phthalic unhydride liquid ROAD LOCAL

142 Thionyl Chlooride liquid ROAD LOCAL

143 Toluene liquid ROAD LOCAL

144 Urea T.G solid ROAD LOCAL

148 zinc chloride solid ROAD LOCAL

FINISHED GOODS

1 4-Amino-3-Methoxy Azobenzene-3-

Sulphuric Acid Solid ROAD/SEA/AIR LOCAL

2 5-Nito 2-Amino Phenol Solid ROAD/SEA/AIR LOCAL

3 5 Amino 6 Methyl Benzimidazolone Solid ROAD/SEA/AIR LOCAL

4 5 Chloro 8 Hdroxy quinolene Solid ROAD/SEA/AIR LOCAL

5 2,5 Dichloro p-Phenylene diamine Solid ROAD/SEA/AIR LOCAL

6 4-(2 Chloro-Ethyl Sulfonyl) Butric Acid Solid ROAD/SEA/AIR LOCAL

7 2-Chloro 4-(2 Chloro Ethyl sulfonyl) Butric

Acid liquid ROAD/SEA/AIR LOCAL

8 2,4,6-Tri[ ( 2,4-Dihydroxy3-Methyl) Phenyl]

1,3,5- Trizine Solid ROAD/SEA/AIR LOCAL

9 2-(4,6-Di Phenyl-1,3,5-Triazine-2-yl)-5(2-

Hydroxyethoxy) Phenol Solid ROAD/SEA/AIR LOCAL

10 2,3-Dibromo propanyl chloride liquid ROAD/SEA/AIR LOCAL

11 2-Amino 4[(2,3,-Di Bromo 1-

oxypropyl)amine],Benzene Sulfonic Acid Solid ROAD/SEA/AIR LOCAL

12

3-Amino-4-[(4-Amino 2 sulfophenyl)-

Diazynyl]5 hydroxynapthalene,2,7

Disulfonic acid

Solid ROAD/SEA/AIR LOCAL

13 4,4'-Diamino Diphenyl Amine Sulphate Solid ROAD/SEA/AIR LOCAL

14 Anilino methane sulfonic acid Solid ROAD/SEA/AIR LOCAL

15

Cuprate{2-[1-amino-4-hydroxyl 3-(2

hydroxyl-5-sulfophenyl)azo-4,5-dimethoxy

phenyl]}azo-2-Naphthalene sulfonic acid


16

3-(4-Chloro-2-Fluro-5-mercaptophenyl)-1-

Methyl-6- trifluromethyl,H-pyrinidine-2-,4-

dione


17 3(2-Chloro ropionyl aniline)propionic acid

methyl ester liquid ROAD/SEA/AIR LOCAL

18 Diamino Benzoic Acid Solid ROAD/SEA/AIR LOCAL


LIMITED







19 3,3 Dinitro di Phenyl Sulfone Solid ROAD/SEA/AIR LOCAL

20 2,2-Bis(4-hydroxy-3-nitrophenol,hexafluro)

propane Solid ROAD/SEA/AIR LOCAL

21 3-(Dibromo Propionyl)Amido-Benzoyl K Acid Solid ROAD/SEA/AIR LOCAL

22 3,7-Diamino-2-,8-Dimethyl

dibenzothiophenne 5,5 dioxide hyrochloride Solid ROAD/SEA/AIR LOCAL

23 3-(2,4-Dichlorophenyl)-6-Fluroquinazoline-

2,4 (1H,3H-Dione Solid ROAD/SEA/AIR LOCAL

24 Di Phenyl Sulfone Solid ROAD/SEA/AIR LOCAL

25 2-Amino di methyl terephthalate Solid ROAD/SEA/AIR LOCAL

26 Zinc tetraisopropyl bis(dithiophosphate) Solid ROAD/SEA/AIR LOCAL

27 Zink Dibutyl DiThiophosphate Liquid ROAD/SEA/AIR LOCAL

28 Dipropyleneglycol methyl-n-propylether Solid ROAD/SEA/AIR LOCAL

29 2,3 Dichloro 6-quinoaline carbonyl chloride Solid ROAD/SEA/AIR LOCAL

30 Direct yeoolw F6GZ Solid ROAD/SEA/AIR LOCAL

31 Diethyl sulfate Solid ROAD/SEA/AIR LOCAL

32 4,4`Thio diphenol Solid ROAD/SEA/AIR LOCAL

33 1,3,benzene diol 4 ( 4,6,bis 2 dimethyl

phenyl) 1,3,5 triazine 2-yl Solid ROAD/SEA/AIR LOCAL

34 2-(2-hydroxy,4- methoxy phenyl) 4,6

diphenyl 1,3,5 triazine Solid ROAD/SEA/AIR LOCAL

35 BTCA(1,2,3,4-Butanetetracarboxylic acid) Solid ROAD/SEA/AIR LOCAL

36 2 anilino 6 dibutyl amino, 3 methyl fluoran Solid ROAD/SEA/AIR LOCAL

37 IPFENCARBAZONE Solid ROAD/SEA/AIR LOCAL

38 m-cresol pure Solid ROAD/SEA/AIR LOCAL

39 Phenyl phthalimide para bis phenol Solid ROAD/SEA/AIR LOCAL


LIMITED





Annexure 8: Water Consumption and Wastewater Generation Details

Total water requirement for the proposed project is 832.1 KLD out of which 553.1 KLD will be sourced fresh water

from GIDC water supply system and 279 KLS will be recycled water.

Table 3-46: Water Consumption

S. No. Area of Consumption Fresh Water

Quantity, KLD

Recycled Water

Quantity, KLD Source of Water

1 Processing 133.9 0 GIDC

2 Product Washing 59.9 79 MEE & RO

3 Machinery Washing 45.3

4 Boiler 30 180 Heat Recovery System

5 Cooling Tower 194 0 GIDC

6 Gardening 60 20 GIDC & STP Outlet

7 Domestic 30 0 GIDC

Total 553.1 279

832.1

Table 3-47: Waste Water Generation

S. No.

Area of Generation Wastewater generation

in KLD Remark

1 Domestic 20 Will be sent to STP and treated water will be used for gardening.

2 Processing 77 77 KLD process effluent will be sent to MEE. From that 5.1 mt

salt and 1.9 mt organic will convert and 79 KLD MEE condensate will be used for washing and processing..

3 Processing weak

stream

365

365 KLD effluent generated from washing (Reactor & Floor) and from product washing along with processing having weak

organic load. Note: In process we are using high quantity of ice. So total 365 KLD will be sent to ETP for treatment and treated water will be

disposed in to sea through NCTL pipeline

4 Product washing

5 Machinery & floor

Washing

6 Boiler 15 will be sent to ETP for treatment and treated water will be

disposed in to sea through NCTL pipeline 7 Cooling Tower 15

Total 492 out of which 77 KLD sent to MEE-RO and 395 KLD will be

treated in ETP & 20 KLD domestic wastewater will be treated in STP.

Total Industrial 395 395 KLD effluent will be sent to ETP for treatment and treated water will be disposed in to sea through NCTL

pipeline


LIMITED





Water Balance Diagram

553.1

133.9 105.2 30 194 30 60

77

20 20

20

7 90 MEE condensate

365 15 15

79 RO Permeate 395

All Values are in KLD

11

RO Reject

Raw water from GIDC

Washing (Product+ Machinery)

(105.2+79= 184.2)

Boiler Domestic

STP

Treated Sewage for Gardening

Cooling Tower Processing Gardening 60+20=80

ETP

MEE

RODry Salts sendto TSDF

Effluent

Raw Water

Recycled Water

Disposed in to sea through NCTL pipeline

Water from Ice added in process


LIMITED





Annexure 9: Details of Waste Water Treatment Plan

The total wastewater generation from the proposed manufacturing activity will be 492 KLD out of which 77 KLD industrial wastewater sent to MEE-RO and 395 KLD industrial waste water will be treated in proposed ETP & 20 KLD domestic wastewater will be treated in proposed STP.

Details of Effluent Treatment Plant

Inlet and Outlet Characteristics of Effluent Treatment Facility

Table 3-48: Inlet and Outlet Characteristics of ETP

Parameters Inlet Characteristics Outlet Characteristics

pH 5000-5500 200-250

COD 1500--1700 90-100

BOD 2000-2100 2000-2100

TDS 140-150 50-60

Suspended Solids 1 to 14 6.5-8

Description of ETP:

Effluent management:- Effluent generated at process has different qualitative nature. Mainly depends of their

COD and TDS.. We derived it as Strong stream and Weak stream. From process to effluent collection tank both

stream collected separately with dedicated tanks and drainage system.

Weak Stream:

Weak stream 500 m3/day will be provide to treat in conventional effluent treatment plant consisting primary,

secondary and tertiary system. Weak stream effluent collected in collection tank through oil and grease chamber

having mechanical oil and grease Collection belt with scrapper.

Effluent then transfer to equalization tank. where PH will be maintained. About four hrs retention will be provide. It

is then ALUM and poly treatment will be given for coagulation and thickening of sludge. Sludge separating will be

done in primary settling tank.

Mother liquar will be transferred to Anoxic tank for ammonical nitrogen treatment. Anoxic and aerated tank design

such a way that ammonical nitrogen will treat on the process of nitrification and denitrification.

Effluent then treated in biological secondary treatment plant having two nos. membrane bio reactor followed by

secondary settling tank. Biological sludge removed will be sent to CHWS.

Secondary treated effluent will be then treated in tertiary treatment plant having sand and carbon filters. From then

transferred to sea via NCLT pipe line.

All electronic controls will be provided to measure and dosage of chemicals.. Final treated effluent quality monitored

electronically within the limits provided by state pollution control boards.

Strong Stream:

Strong stream will treated in Four stage Multiple effect evaporator. MEE daily capacity will be 100 CM per day. The

wastewater will be pumped to the solvent stripper to remove the solvents with the help of steam.

The solvent stripped wastewater will be pumped to the Multiple Effect Evaporator for the removal of dissolved

solids. Steam will be used for heating the wastewater.


LIMITED





The condensate from the evaporator will be pumped to the bioreactor for further treatment. Salts and organic to be

disposed in CHWIS.

Condensate treated in reverse osmosis (RO) where permeate will be reused in process and rejection will transferred

to MEE.


LIMITED





Figure 3-40: ETP Process Block Diagram

WEAK STREAM

NCLT Pipe line to sea

WeakStream Oil and Grease

Collection Equalisation Clarification

Precipitation

Alum Dosing

Thickning

Poly Dosing

Primary Settling

Primary

Sludge sepn

site Solid Waste to hazardous waste

Anoxic Treatment

1st

bioreactor

Secondary

settling 1st

Poly Dosing

Alum Dosing

FP for secondary sludge removing

V- Notch Carbon Filter

Sand Filter

Lime /

NaoH

2nd bio

reactor

Secondary

settling tank 2nd

Haz.Waste to CHWS


LIMITED





STRONG STREAM, EFFLUENT TREATMENT SCHEME

Condensate

Rejection

StrongStream O & G Collection & Neutralisation

Clarification

R OReuse in Process

Centrifuge

Salt to CHW facility

Organic Residue CHW

Sludge to CHW

Four Stage MEE


LIMITED





Sewage Treatment Plant

Domestic effluent generated daily will be treated in sewage treatment plant having with MBBR technology. Sludge

separation will be done by settling process. Sludge will be dried in beds and will be used for manure.

Carbon and sand media will be used for suspended solid separation and reduction of BOD further. Plant will

operated fully electronically. Treated water will be used for gardening.

Figure 3-41: Block Diagram of Proposed STP

DOMESTIC EFFLUENT

Gardening

Collection MBBRSludge Setting Tank

Hypo Dosing Tank

Sludge Drying Bed

Dual mode sand / Carbon filter


LIMITED





Annexure 10: Fuel Consumption

Table 3-49: Details of Fuel Consumption

S.

No. Stack Attached to Capacity

No. of

working hrs

Type of Fuel

used

Fuel consumption in

Hr

1 Boiler 6 TPH 24 Coal 1 MT/h

2 DG set 1000 kVA stand by HSD 150 ltr/h

3 Thermic Fluid Heater 6 lakh Kcal/Hr 12 FO 68 kg/h

4 Boiler 3 TPH stand by FO 300 kg/h

*Note: DG Sets will be used only during Power failure.


LIMITED





Annexure 11: Hazardous Waste Generation

Table 3-50: Details of Hazardous Waste Generation

S. No.

Type of Waste

Hazardous Waste

Category

Quantity per Year MT

Source Method of Collection

Treatment / Disposal

1 Process waste

sludge 26.1 805.3 From process

Manual in HDPE bags

TSDF for landfill

Distillation Residue

20.3 81.05 Solvent recovery

plant In HDPE drums CHWIF for incineration

2 MEE salt 35.3 1862 MEE Manual in In HDPE bags

TSDF for landfill

3 MEE organic 37.3 694 MEE rejects In HDPE drums CHWIF for incineration

4 ETP sludge 35.3 666 Waste water treatment

In HDPE bags TSDF for landfill

5 Spent carbon 36.2 46 Waste water

tertiary treatment In HDPE bags TSDF for landfill

6 Empty bags 33.1 10000 nos /

200gm per bag Raw material Lot wise

Reused or hazardous waste collection

7 Empty barrels 33.1 2000 nos / 18

kg/barrel Raw material Lot wise

Cleaned and sold to GPCB authorized

vendor


LIMITED





Annexure 12: Stack Details

Table 3-51: Flue Gas Stacks

S.

No. Stack Attached to Capacity

No. of

working

hrs

Type of

Fuel used

Fuel

consumption in

Hr

Stack

Height,

m

Stack

Diameter,

m

1 Boiler 6 TPH 24 Coal 1 MT/h 30 0.57 m

2 DG set 1000 kVA stand by HSD 150 ltr/h 10 0.23 m

3 Thermic Fluid Heater 6 lakh Kcal/Hr 12 FO 68 kg/h 25 0.57 m

4 Boiler 3 TPH stand by FO 300 kg/h 40 0.57 m

*Note: DG Sets will be used only during Power failure. Stacks of adequate height as per Environment Protection Rules will be

provided.

Table 3-52: Process Vents

S.

No.

Stack Attached

to

Nos. of

Stacks

Stack Height in

m

Pollutants

Emitted

Air Pollution Control Measures

Attached

1 Process vessels 6 30 SO2 Caustic Scrubber

2 Process vessels 3 30 NOx Caustic Scrubber

3 Process vessels 3 30 HCl Caustic Scrubber

4 Storage tank 1 10 SO3 Acid Scrubber

5 Storage tanks 1 10 NOx Caustic Scrubber

6 storage vessels 1 10 HCL Caustic Scrubber

Details of Air Pollution Control Measures

Different types of scrubbers will be installed to scrub the emitted gas from process vessels. Following diagram

shows the general function of scrubbers. Every hour media is monitored by on line system and rectified or

replacement as required.

CONTACT DETAILS

Vadodara (Head Office)

871/B/3, GIDC Makarpura, Vadodara, India – 390 010.

E: [email protected]; T:+91-265-6131000

Delhi / NCR

Spaze IT Park, Unit No. 1124, 11th Floor, Tower B-3, Sector 49, Near Omaxe

City Center Mall, Sohna Road, Gurgaon, India – 122 002

E: [email protected]; T: 0124-424 2430-436

Kadam Environmental Consultants w w w . kad am en v i r o . c o m

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