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11,0002552

927

10400

022982439,022982442

022982425,022982765

e-mail:[email protected]

website:http://www.pcd.go.th,http://pops.pcd.go.th

//

Loading

/

1)

2)

/

PollutantReleaseandTransferRegister

1 1. 1

2. 2

3. 2

4. 3

2 6

3 9 1. (Measurement:M) 9

2. (MassBalance:B) 12

3. 14

(EmissionFactor:E)

4. (EngineeringCalculation:C) 17

4 19 1. 19

1) 19

2) 20

3) 20

4) 22

2. 22

5 24 1. 24

2. 31

3. 36

4. 40

51

53

54

55

56

59

60

1

1

1

1)

PRTRPollutant

ReleaseandTransferRegisters

P:Pollutant: PRTR

R:Release:

T:Transfer:

R:Registers:

2) PRTR ... .. 2535

2

2

/

3

//

PRTR loading

/ /

/

/

-/

/ - - - / - / - / / / - / / / /

3

PRTR

PRTR(fugitiveemission)

* M(measurement),E(emissionfactor),B(massbalance),C(engineeringcalculation)

4

..2550162550

1725502

.. 2551

11(3),(4)

11(6)

20

38(1) 50

(./)

*

(fugitive/nonpointsource) * * *

4

42(1) -

(NaCl)

Na2CO3,NaOH,HCl,Cl2,NaOCl

(BleachingPowder)

100

42,44

100

43

49

50(2)

57

59

100

59

(TotalCapacity)

5(batch)

60

50

88

10

101

-

-

-

105

106

(Recycle)

500

(

)

(BODLoadofInfluent)

100

5

BODCODSS

SO2NOxTSP

(fugitiveemission)2

6

50

()

6

2

1

1.1

-

-

//

- (Safety

Data Sheet: SDS)

( .1) (.2)

-

fitting

1.2

-

-

- /

( .1)

( .2)

(.3)

1.3

2.

/

3.

4.

5.

6./

9

3

4

(Measurement)(MassBalance/MaterialAccounting)

(Emission Factor)

(EngineeringCalculation / Engineering Judgement)

1.(Measurement:M)

(waste stream)

1)

1.1) (Direct Measurement / Direct Monitoring)

/

(1) (Continuous Emission Monitoring)

-

24

(2) (Periodic Emission Monitoring)

-

10

1.2) (Indirect Measurement)

(process control measurement)

/

1.3) (Detection Limit)

2 /

5 /

5 /

0.5 /

2.5/

11

2) /

2.1) /

(fugitive emission)

(ventilation system)

(emission)

(totalhydrocarbon)

U.S.EPAEmission factor for equipment leakofVOCsandHAPs

/

gate

valve, globe valve /

Sniffer

12

2.2)

2.2.1)

2.2.2)

(waste stream)

land farming

/

2(MassBalance:B)

(process)

1)

(system)

13

(boundary) (surrounding)

(universe)

-

-

-

-

=+

(Steady state)

+=

+/

+

/

14

=

=

(Input) (Output)

./

.

.

./

.

.

.

.

3

(EmissionFactor:E)

(Emission factor)

/Emissionfactor

/

Emission factor

(Activity data)

Emission factor

15

(Fugitive) Emission factor

Emission factor

Emissionfactor2

/ (chemical specific emission factor) emission factor

NOx,SOx,benzene

(non chemical specific emission factor) emission factor

(VOC)

Emission factor

Emission factor

emissionfactor

National Pollutant Inventory (http://www.npi.gov.au/publications/emission-

estimation-technique/index.html) Technology Transfer Network

Clearinghouse for Inventories & Emissions Factors (http://www.epa.gov/ttnchie1/ap42/)

Emission factor

Emission factor

3.1)

Emission factor

/ Emission factor

(fugitive)/

Emission factor /

/

16

/

Emission factor /

/

/

/

Emission factor //

3.2)

Emission factor

(Point source)

2 Emission factor

Emission factor

Emissionfactor(Chemicalloading)

Emission factor (Process

Emission factor)

(total release) (Fugitive)

phthalic anhydide

phthalic anhydride

(Fugitive air emission)

(Leak rate emission factor) phthalic anhydide

phthalic anhydide

phthalicanhydide

3.3)

Emissionfactor

1

4(EngineeringCalculation:C)

/

()(idealgaslaw)

1) (Fugitive)

2) / (Removal rate)

/(Dryingrate)

bag house

99 1

3)

Idealgaslaw

4.1)

/

1

4.2)

4.3)

4.4)

19

4

1

1)

( )

pH

/

20

()

(Fugitiveairemission)

2)

(Input)

(Output) /

MSDS /

/

3)

Emission factor

Emission factor

(Fugitive)

21

/ 2

Emissionfactor

Emission factor (Leak)

Emission factor

Emission factor

Emissionfactor

/Emission factorEmission

factor/

Emission factor /

/

Emission factor

Emission factor

22

4)

mass transfer

(wastestream)

masstransfer

2.

23

1)

2)

Emission factor

3) /

/

/

4)

24

1.

/

//

1)

1 50../365/

200

./.

1

200./.

50..

2 (loading)

365/

3 ./

(./.)

1.=106.1..=

1,000.

5

/

=

/

/x

//

//

/=

//x

//

/x

25

= x / x

= x/

x x

=

200

x

50

x x

1

x

1,000

1 1

/=3,600./

2

1

1

2 (Loading)

(/)x

(../)

=(./)

8 918 1,570 1.44

12 700 1,490 1.04

10 815 1,580 1.28

15 683 1,660 1.13

9 787 1,380 1.09

13 840 1,290 1.08

=

200

x

50

x x

1

x

1

26

1(..3)=1,000(.)1(.)=109(.)

= x x

918 1,570 1,000 x 1

8 1= x x x

=1.44./

3 1.21 /

1 250 /

2

1.

C = ()

Cr = ()

Vm,STP =

(25oC760mmHg),()

(/)

x

(../)

=

(./)

11 865 1,730 1.50

10 643 1,600 1.03

8 958 1,750 1.68

12 681 1,560 1.06

10 680 1,800 1.22

8 627 1,630 1.02

1.21

=1.21.

X250

=304.

1 C = Cr/Vm,STP

/

2

(:ppm)

()2

mg/m3 = ,(/)

ppm = ,()

MW =

24.45 = 1

(25oC760mmHg)

2.

E = ,(/)

C = ,(/)

Qd = ,

(/)

0.0036 = 3,600/x0.000001/

= 60x60x1

1x11,000,000

T = ,(oC)

4

E = (/)

Qw = (/)

C = ,/

0.0036 = 3,600/x0.000001/

moistr = ,

273 = 273(K)

T = ,(oC)

2 mg /m3 = ppm x MW/24.45

3 E ! =! C x Qd x 0.0036 x [273/(273+T)]

4 E ! =! Qw x C x 0.0036 x [1-(moistr/100)] x [273/(273+T) ]

2

5

moistr = ()

gmoist = (moisturecollected),()

Vm,STP =

(25oC760mmHg),()

m,STP =

(STP),(/),

1.62/

273 = 273(K)

T = ,

Ekpyi = (i),(/)

Ei = (i),(/)5

OpHrs = (/)

Ekpti = (i),(./)

Ei = (i),(./)5

OpHrs = (/)

3 . 4/

dioxin 2.2 ng-TEQ/Nm3

340Nm3/h200/

0.46/3.1ng-TEQ/g

5 Moistr = 100% x gmoist gmoist + STP(1,000 x V m,STP) (1,000 x V m,STP)

6 Ekpyi = (Ei* OpHrs)

7 Ekpti = Ei/A

29

(ng-TEQ/)=

x

..

= 2.2 ng-TEQ x 340 Nm3 x 4 . x 200 x 1 .Nm3 1012 ng.

=5.98x10-7.-TEQ/

. ...

.= 3.1 ng-TEQ x 0.46 x 1,000 . x 1,000 x 1 .

1 . 1012 ng.

=1.426x10-6.-TEQ/

(Continuous Emission Monitoring

System (CEMs) Data)

CEMs

CEMs

CEMs

TimeO2content

%byvolume

(Concentration)

GasFlowRate(Q)

m3/s

ProductionRateof

Product(A)tonnes/hour

SO2

(ppmvd)

NOx

(ppmvd)

CO

(ppmvd)

VOC

(ppmvd)

1 10.3 150.9 142.9 42.9 554.2 8.52 290

2 10.1 144.0 145.7 41.8 582.9 8.48 293

3 11.8 123.0 112.7 128.4 515.1 8.85 270

30

SO21

150oC

Ei = (CxMWxQx3,600)/[22.4x{(T+273)/273}x106]

Eso2,1 = (150.9x64x8.52x3,600)/[22.4x{(150+273)/273}x106]

= 296,217,907/[22.4x{423/273}x106]

= 8.53./.

23

Eso2,2 = 8.11./.

Eso2,3 = 7.23./.

1 = 1,500.

2 = 2,000.

3 = 1,800.

Ekpy,SO2 = (EixOpHrs)

Ekpy,SO2i = (Eso2,1xOpHrs1)+(Eso2,2xOpHrs2)+(Eso2,3xOpHrs3)

Ekpy,SO2i = (8.53./.x1,500./)+(8.112x2,000)+(7.23x1,800)

Ekpy,SO2i = 42,021./

SO2 1

7

7

Ekpti = Eso2/A

Ekpti = 8.53/290

= 2.94x10SO2

231

6 CEMs SO2 6 /

24/48/SO2

31

E1 = 13.2./. E4 = 12.2./.

E2 = 12.6./. E5 = 14.0./.

E3 = 11.2./. E6 = 13.4./.

E =n1 (Eixt)

E = (./)

Ei = (t)

T =

N = 1

E =48

(Eixt)SO21=

SO2148=1,838.4x48=88,243./

E=[(13.2x24)+(12.6x24)+(11.2x24)+(12.2x24)+(14x24)+(13.4x24)]x48./=88,243./

2

/ (input/output)

1

(./)

(./)

(./)

E1 13.2 24 316.8

E2 12.6 24 302.4

E3 11.2 24 268.8

E4 12.2 24 292.8

E5 14 24 336

E6 13.4 24 321.6

1 1,838.4

32

(1) //

(2)

(3)

(4) (basisofcalculation)

(5) (Overallmaterialbalance)

(Componentmaterialbalance)

1) (Overall facililty mass balance)

Input =

Emission = /

Transfer =

Recycling

Products =

1 =

2 Inputs = Products + Transfers + Emission

= + / +

Input of substance i = amount of substance i in product + amount of substance i in waste + amount of substance i trasformed / consumed in process + emision of substance i

3

i = i + i +i / + i

33

2)

Ei = i(./)

Qa = a(../)

Qo = o(../)

Wa,I = ia

Wo,i = io

a, o = streamao(./..)1

A10,000B5,000

20,000 22,000 4,000 /

ABPRTR

PRTR

1

= A+B+

= 10,000+5,000+20,000=35,000

4 Ei = aWa,i - oWo,i

34

2

= +

= 22,000+4,000=26,000

3

=

=35,000-26,000=9,000/

4 /

2

electroplating trichloroethylene (TCE)14

13 (1 = 210 )

1.03/

TCE30%TCE

1 TCEreclaim

TCE air emission

input = output

A+B

+=

+

+

10,000+5,000+20,000 = 22,000+4,000+9,000

35,000 = 35,000

35

reclaimer

TCEreclaimer=

/TCEreclaimer=xx%TCE

=

2 TCE

TCE

ReclaimTCE

=TCE14reclaim0.844

=13.16

3 double effect

4% (lye) 25%

100

100kg

X

13 x210

= 2,730

2,730 x1.03.

x30

= 844. = 0.844 100

input = output

=

= +

14 = 0.844+13.16

100-X kg

NaOH 100 kg (4% wt) X kg (25% wt NaOH)

36

/

(EmissionRate)=

(ActivityData)x

(EmissionFactor)

(mass)=

(unitofactivity)x

(mass)

(time) (time) (unitofactivity)

2

1

2 NaOH

3.

(activitydata)(/)/

(Emission factor)

(/)

/ =

()

X

= +lye

100kg = +Xkg

= 100Xkg

NaOH = NaOH

()(NaOH) = ()(NaOH)

100(0.04) = X(0.25)

X = 16kg

10016 = 84kg

input = output

NaOH = NaOH

NaOH = lye+NaOH

100 = 16+84

3

E=AxOpHrsxEf

E = (./)

A = (/3/)

OpHrs = (/)

Ef = (././..)

E=AxEf

E = (./)

A = (/)

Ef = (./)

E=AxOpHrsxEf

E=AxEf

E=AxOpHrsxEfx

E=AxEfx

E = (./)

A = (/)

OpHrs = (/)

1-CE

100

1-CE

100

3

Efi =

(./)

CEi = (%)

UncontrolledEmissionfactorforpolyvinylchloridemanufacture

(fugitiveairemission)

- methyl ethyl ketone (MEK)

toluenexylene

- (dryer)

(extrusion) (rolling)

(negative pressure)

(flare)

- 4,000 /

0.0180%

-

- gassafetyreliefvalve1

- inlinerelievevalve2

- liquidvalve18

- gasvalve12flare

- safetyseal

Emissionfactor

PM10(kg/toneofPVCProduced) vinylchloride(kg/toneofPVCProduced)

17.5 8.5

Emissionfactor(./)

Compressorseals(leaking) 3.54

GasSafety-reliefvalve 0.098

In-Linevalve(gas) 0.0132

InLinevalve(lightliquid) 0.0038

39

Compressorseals(leaking)

-MEK =3.54./0.01.MEK/.x400/

-MEKCompressorseals

=141.6./

-polymertoluenexylene

-toluenexylene

=141.6/2=70.8./

GasSafety-reliefvalve

-MEK =0.098./x0.01.MEK/.x400/

-toluene&xylenemixture =3.92./

=1.96./

Gasvalvebeforecondenser

-MEK =2x0.00132.//x0.01.MEK/.

x400/

-toluene&xylene =1.056./

=0.528./

Gasvalveaftercondenser

-MEK =12x0.00132.//

x0.01(1-0.8).MEK/.x400/


=0.625./

Liquidvalves

-MEK =18x0.0038.//x400/


=136.8./

40

MEK=141.6+3.92+1.056+1.27+273.6422./

toluene&xylene211./

4.

/ (

)(idealgaslaw)

1 (NaOH)

(Cu)

0.9

1

(Cu)(NaOH)2

Cu+++2(NaOH)Cu(OH)2+2Na+ pH= 7.7

pH=8

- (Cu)=63.5/-

- (NaOH)=40/-

[(Na=22.99)+(O=15.99)+(H=1.00)=40]

2

2NaOH1Cu2tonne-molesNaOH1tonne-moleCu

80tonnesNaOH63.5tonnesCuNaOH80Cu63.5

/ =

//

x//

/

40tonesNaOHx2tone-moleNaOH 1tone-moleCux 63.5tonesCu

tone-moleNaOH tones-moleCu

41

3 Cu NaOH 0.9

NaOH80Cu = 63.5Cu

NaOH0.9Cu = 63.5Cux0.9NaOH

80NaOH

Cu = 0.71Cu710.

NaOHCu

2

(masstransfertheory)

1oilwaterseparator

12

2masstransfer(storageunits)

Sludge hopper

outletinlet

skimmer

oil layer

Water layer

Slot pipe

42

12

3masstransfer

1.Mass-transferequations

EquationNumber

Equation

1

Individual Liquid (kl) and Gas (kg)-Phase Mass-Transfer Coeffcients

kl(m/s)=2.78x10-6(Dw /Dether)2/3

for03.25m/sandF/D

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