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.FBTVSFNFOU
.BTT#BMBODF&NJTTJPO'BDUPST&OHJOFFSJOH$BMDVMBUJPO
.FBTVSFNFOU
.BTT#BMBODF&NJTTJPO'BDUPST&OHJOFFSJOH$BMDVMBUJPO
-
11,0002552
927
10400
022982439,022982442
022982425,022982765
e-mail:[email protected]
website:http://www.pcd.go.th,http://pops.pcd.go.th
-
//
Loading
/
1)
2)
/
PollutantReleaseandTransferRegister
-
1 1. 1
2. 2
3. 2
4. 3
2 6
3 9 1. (Measurement:M) 9
2. (MassBalance:B) 12
3. 14
(EmissionFactor:E)
4. (EngineeringCalculation:C) 17
4 19 1. 19
1) 19
2) 20
3) 20
4) 22
2. 22
5 24 1. 24
2. 31
3. 36
4. 40
51
53
54
55
56
59
60
-
1
1
1
1)
PRTRPollutant
ReleaseandTransferRegisters
P:Pollutant: PRTR
R:Release:
T:Transfer:
R:Registers:
2) PRTR ... .. 2535
-
2
2
/
3
//
PRTR loading
/ /
/
/
-/
/ - - - / - / - / / / - / / / /
-
3
PRTR
PRTR(fugitiveemission)
* M(measurement),E(emissionfactor),B(massbalance),C(engineeringcalculation)
4
..2550162550
1725502
.. 2551
11(3),(4)
11(6)
20
38(1) 50
(./)
*
(fugitive/nonpointsource) * * *
-
4
42(1) -
(NaCl)
Na2CO3,NaOH,HCl,Cl2,NaOCl
(BleachingPowder)
100
42,44
100
43
49
50(2)
57
59
100
59
(TotalCapacity)
5(batch)
60
50
88
10
101
-
-
-
105
106
(Recycle)
500
(
)
(BODLoadofInfluent)
100
-
5
BODCODSS
SO2NOxTSP
(fugitiveemission)2
6
50
()
-
6
2
1
1.1
-
-
//
- (Safety
Data Sheet: SDS)
( .1) (.2)
-
fitting
1.2
-
-
- /
( .1)
( .2)
(.3)
-
1.3
2.
/
3.
4.
-
5.
6./
-
9
3
4
(Measurement)(MassBalance/MaterialAccounting)
(Emission Factor)
(EngineeringCalculation / Engineering Judgement)
1.(Measurement:M)
(waste stream)
1)
1.1) (Direct Measurement / Direct Monitoring)
/
(1) (Continuous Emission Monitoring)
-
24
(2) (Periodic Emission Monitoring)
-
-
10
1.2) (Indirect Measurement)
(process control measurement)
/
1.3) (Detection Limit)
2 /
5 /
5 /
0.5 /
2.5/
-
11
2) /
2.1) /
(fugitive emission)
(ventilation system)
(emission)
(totalhydrocarbon)
U.S.EPAEmission factor for equipment leakofVOCsandHAPs
/
gate
valve, globe valve /
Sniffer
-
12
2.2)
2.2.1)
2.2.2)
(waste stream)
land farming
/
2(MassBalance:B)
(process)
1)
(system)
-
13
(boundary) (surrounding)
(universe)
-
-
-
-
=+
(Steady state)
+=
+/
+
/
-
14
=
=
(Input) (Output)
./
.
.
./
.
.
.
.
3
(EmissionFactor:E)
(Emission factor)
/Emissionfactor
/
Emission factor
(Activity data)
Emission factor
-
15
(Fugitive) Emission factor
Emission factor
Emissionfactor2
/ (chemical specific emission factor) emission factor
NOx,SOx,benzene
(non chemical specific emission factor) emission factor
(VOC)
Emission factor
Emission factor
emissionfactor
National Pollutant Inventory (http://www.npi.gov.au/publications/emission-
estimation-technique/index.html) Technology Transfer Network
Clearinghouse for Inventories & Emissions Factors (http://www.epa.gov/ttnchie1/ap42/)
Emission factor
Emission factor
3.1)
Emission factor
/ Emission factor
(fugitive)/
Emission factor /
/
-
16
/
Emission factor /
/
/
/
Emission factor //
3.2)
Emission factor
(Point source)
2 Emission factor
Emission factor
Emissionfactor(Chemicalloading)
Emission factor (Process
Emission factor)
(total release) (Fugitive)
phthalic anhydide
phthalic anhydride
(Fugitive air emission)
(Leak rate emission factor) phthalic anhydide
phthalic anhydide
phthalicanhydide
3.3)
Emissionfactor
-
1
4(EngineeringCalculation:C)
/
()(idealgaslaw)
1) (Fugitive)
2) / (Removal rate)
/(Dryingrate)
bag house
99 1
3)
Idealgaslaw
4.1)
/
-
1
4.2)
4.3)
4.4)
-
19
4
1
1)
( )
pH
/
-
20
()
(Fugitiveairemission)
2)
(Input)
(Output) /
MSDS /
/
3)
Emission factor
Emission factor
(Fugitive)
-
21
/ 2
Emissionfactor
Emission factor (Leak)
Emission factor
Emission factor
Emissionfactor
/Emission factorEmission
factor/
Emission factor /
/
Emission factor
Emission factor
-
22
4)
mass transfer
(wastestream)
masstransfer
2.
-
23
1)
2)
Emission factor
3) /
/
/
4)
-
24
1.
/
//
1)
1 50../365/
200
./.
1
200./.
50..
2 (loading)
365/
3 ./
(./.)
1.=106.1..=
1,000.
5
/
=
/
/x
//
//
/=
//x
//
/x
-
25
= x / x
= x/
x x
=
200
x
50
x x
1
x
1,000
1 1
/=3,600./
2
1
1
2 (Loading)
(/)x
(../)
=(./)
8 918 1,570 1.44
12 700 1,490 1.04
10 815 1,580 1.28
15 683 1,660 1.13
9 787 1,380 1.09
13 840 1,290 1.08
=
200
x
50
x x
1
x
1
-
26
1(..3)=1,000(.)1(.)=109(.)
= x x
918 1,570 1,000 x 1
8 1= x x x
=1.44./
3 1.21 /
1 250 /
2
1.
C = ()
Cr = ()
Vm,STP =
(25oC760mmHg),()
(/)
x
(../)
=
(./)
11 865 1,730 1.50
10 643 1,600 1.03
8 958 1,750 1.68
12 681 1,560 1.06
10 680 1,800 1.22
8 627 1,630 1.02
1.21
=1.21.
X250
=304.
1 C = Cr/Vm,STP
/
-
2
(:ppm)
()2
mg/m3 = ,(/)
ppm = ,()
MW =
24.45 = 1
(25oC760mmHg)
2.
E = ,(/)
C = ,(/)
Qd = ,
(/)
0.0036 = 3,600/x0.000001/
= 60x60x1
1x11,000,000
T = ,(oC)
4
E = (/)
Qw = (/)
C = ,/
0.0036 = 3,600/x0.000001/
moistr = ,
273 = 273(K)
T = ,(oC)
2 mg /m3 = ppm x MW/24.45
3 E ! =! C x Qd x 0.0036 x [273/(273+T)]
4 E ! =! Qw x C x 0.0036 x [1-(moistr/100)] x [273/(273+T) ]
-
2
5
moistr = ()
gmoist = (moisturecollected),()
Vm,STP =
(25oC760mmHg),()
m,STP =
(STP),(/),
1.62/
273 = 273(K)
T = ,
Ekpyi = (i),(/)
Ei = (i),(/)5
OpHrs = (/)
Ekpti = (i),(./)
Ei = (i),(./)5
OpHrs = (/)
3 . 4/
dioxin 2.2 ng-TEQ/Nm3
340Nm3/h200/
0.46/3.1ng-TEQ/g
5 Moistr = 100% x gmoist gmoist + STP(1,000 x V m,STP) (1,000 x V m,STP)
6 Ekpyi = (Ei* OpHrs)
7 Ekpti = Ei/A
-
29
(ng-TEQ/)=
x
..
= 2.2 ng-TEQ x 340 Nm3 x 4 . x 200 x 1 .Nm3 1012 ng.
=5.98x10-7.-TEQ/
. ...
.= 3.1 ng-TEQ x 0.46 x 1,000 . x 1,000 x 1 .
1 . 1012 ng.
=1.426x10-6.-TEQ/
(Continuous Emission Monitoring
System (CEMs) Data)
CEMs
CEMs
CEMs
TimeO2content
%byvolume
(Concentration)
GasFlowRate(Q)
m3/s
ProductionRateof
Product(A)tonnes/hour
SO2
(ppmvd)
NOx
(ppmvd)
CO
(ppmvd)
VOC
(ppmvd)
1 10.3 150.9 142.9 42.9 554.2 8.52 290
2 10.1 144.0 145.7 41.8 582.9 8.48 293
3 11.8 123.0 112.7 128.4 515.1 8.85 270
-
30
SO21
150oC
Ei = (CxMWxQx3,600)/[22.4x{(T+273)/273}x106]
Eso2,1 = (150.9x64x8.52x3,600)/[22.4x{(150+273)/273}x106]
= 296,217,907/[22.4x{423/273}x106]
= 8.53./.
23
Eso2,2 = 8.11./.
Eso2,3 = 7.23./.
1 = 1,500.
2 = 2,000.
3 = 1,800.
Ekpy,SO2 = (EixOpHrs)
Ekpy,SO2i = (Eso2,1xOpHrs1)+(Eso2,2xOpHrs2)+(Eso2,3xOpHrs3)
Ekpy,SO2i = (8.53./.x1,500./)+(8.112x2,000)+(7.23x1,800)
Ekpy,SO2i = 42,021./
SO2 1
7
7
Ekpti = Eso2/A
Ekpti = 8.53/290
= 2.94x10SO2
231
6 CEMs SO2 6 /
24/48/SO2
-
31
E1 = 13.2./. E4 = 12.2./.
E2 = 12.6./. E5 = 14.0./.
E3 = 11.2./. E6 = 13.4./.
E =n1 (Eixt)
E = (./)
Ei = (t)
T =
N = 1
E =48
(Eixt)SO21=
SO2148=1,838.4x48=88,243./
E=[(13.2x24)+(12.6x24)+(11.2x24)+(12.2x24)+(14x24)+(13.4x24)]x48./=88,243./
2
/ (input/output)
1
(./)
(./)
(./)
E1 13.2 24 316.8
E2 12.6 24 302.4
E3 11.2 24 268.8
E4 12.2 24 292.8
E5 14 24 336
E6 13.4 24 321.6
1 1,838.4
-
32
(1) //
(2)
(3)
(4) (basisofcalculation)
(5) (Overallmaterialbalance)
(Componentmaterialbalance)
1) (Overall facililty mass balance)
Input =
Emission = /
Transfer =
Recycling
Products =
1 =
2 Inputs = Products + Transfers + Emission
= + / +
Input of substance i = amount of substance i in product + amount of substance i in waste + amount of substance i trasformed / consumed in process + emision of substance i
3
i = i + i +i / + i
-
33
2)
Ei = i(./)
Qa = a(../)
Qo = o(../)
Wa,I = ia
Wo,i = io
a, o = streamao(./..)1
A10,000B5,000
20,000 22,000 4,000 /
ABPRTR
PRTR
1
= A+B+
= 10,000+5,000+20,000=35,000
4 Ei = aWa,i - oWo,i
-
34
2
= +
= 22,000+4,000=26,000
3
=
=35,000-26,000=9,000/
4 /
2
electroplating trichloroethylene (TCE)14
13 (1 = 210 )
1.03/
TCE30%TCE
1 TCEreclaim
TCE air emission
input = output
A+B
+=
+
+
10,000+5,000+20,000 = 22,000+4,000+9,000
35,000 = 35,000
-
35
reclaimer
TCEreclaimer=
/TCEreclaimer=xx%TCE
=
2 TCE
TCE
ReclaimTCE
=TCE14reclaim0.844
=13.16
3 double effect
4% (lye) 25%
100
100kg
X
13 x210
= 2,730
2,730 x1.03.
x30
= 844. = 0.844 100
input = output
=
= +
14 = 0.844+13.16
100-X kg
NaOH 100 kg (4% wt) X kg (25% wt NaOH)
-
36
/
(EmissionRate)=
(ActivityData)x
(EmissionFactor)
(mass)=
(unitofactivity)x
(mass)
(time) (time) (unitofactivity)
2
1
2 NaOH
3.
(activitydata)(/)/
(Emission factor)
(/)
/ =
()
X
= +lye
100kg = +Xkg
= 100Xkg
NaOH = NaOH
()(NaOH) = ()(NaOH)
100(0.04) = X(0.25)
X = 16kg
10016 = 84kg
input = output
NaOH = NaOH
NaOH = lye+NaOH
100 = 16+84
-
3
E=AxOpHrsxEf
E = (./)
A = (/3/)
OpHrs = (/)
Ef = (././..)
E=AxEf
E = (./)
A = (/)
Ef = (./)
E=AxOpHrsxEf
E=AxEf
E=AxOpHrsxEfx
E=AxEfx
E = (./)
A = (/)
OpHrs = (/)
1-CE
100
1-CE
100
-
3
Efi =
(./)
CEi = (%)
UncontrolledEmissionfactorforpolyvinylchloridemanufacture
(fugitiveairemission)
- methyl ethyl ketone (MEK)
toluenexylene
- (dryer)
(extrusion) (rolling)
(negative pressure)
(flare)
- 4,000 /
0.0180%
-
- gassafetyreliefvalve1
- inlinerelievevalve2
- liquidvalve18
- gasvalve12flare
- safetyseal
Emissionfactor
PM10(kg/toneofPVCProduced) vinylchloride(kg/toneofPVCProduced)
17.5 8.5
Emissionfactor(./)
Compressorseals(leaking) 3.54
GasSafety-reliefvalve 0.098
In-Linevalve(gas) 0.0132
InLinevalve(lightliquid) 0.0038
-
39
Compressorseals(leaking)
-MEK =3.54./0.01.MEK/.x400/
-MEKCompressorseals
=141.6./
-polymertoluenexylene
-toluenexylene
=141.6/2=70.8./
GasSafety-reliefvalve
-MEK =0.098./x0.01.MEK/.x400/
-toluene&xylenemixture =3.92./
=1.96./
Gasvalvebeforecondenser
-MEK =2x0.00132.//x0.01.MEK/.
x400/
-toluene&xylene =1.056./
=0.528./
Gasvalveaftercondenser
-MEK =12x0.00132.//
x0.01(1-0.8).MEK/.x400/
-toluene&xylene =1.27./
=0.625./
Liquidvalves
-MEK =18x0.0038.//x400/
-toluene&xylene =273.6./
=136.8./
-
40
MEK=141.6+3.92+1.056+1.27+273.6422./
toluene&xylene211./
4.
/ (
)(idealgaslaw)
1 (NaOH)
(Cu)
0.9
1
(Cu)(NaOH)2
Cu+++2(NaOH)Cu(OH)2+2Na+ pH= 7.7
pH=8
- (Cu)=63.5/-
- (NaOH)=40/-
[(Na=22.99)+(O=15.99)+(H=1.00)=40]
2
2NaOH1Cu2tonne-molesNaOH1tonne-moleCu
80tonnesNaOH63.5tonnesCuNaOH80Cu63.5
/ =
//
x//
/
40tonesNaOHx2tone-moleNaOH 1tone-moleCux 63.5tonesCu
tone-moleNaOH tones-moleCu
-
41
3 Cu NaOH 0.9
NaOH80Cu = 63.5Cu
NaOH0.9Cu = 63.5Cux0.9NaOH
80NaOH
Cu = 0.71Cu710.
NaOHCu
2
(masstransfertheory)
1oilwaterseparator
12
2masstransfer(storageunits)
Sludge hopper
outletinlet
skimmer
oil layer
Water layer
Slot pipe
-
42
12
3masstransfer
1.Mass-transferequations
EquationNumber
Equation
1
Individual Liquid (kl) and Gas (kg)-Phase Mass-Transfer Coeffcients
kl(m/s)=2.78x10-6(Dw /Dether)2/3
for03.25m/sandF/D