a rearrangement to a zirconium—alkenylidene in the insertion of dihalocarbenoids and acetylides...

2007 Cyclopentane derivatives Q 0030 A Rearrangement to a Zirconium—Alkenylidene in the Insertion of Dihalocar- benoids and Acetylides into Zirconacycles. — An efficient assembly of bicy- clooctenes (IV) is presented, involving the generation of a zirconacyclic intermediate from enyne (I), carbene (II) and a zirconacene complex followed by rearrangement to a zirconium—alkenylidene complex on reaction with the lithium acetylide. — (THOMAS, E.; DIXON, S.; WHITBY*, R. J.; Angew. Chem., Int. Ed. 45 (2006) 42, 7070-7072; Sch. Chem., Univ. Southampton, Southampton SO17 1BJ, UK; Eng.) — Mischke 09- 068

Upload: emma-thomas

Post on 06-Jun-2016

216 views

Category:

Documents

0 download

Report

Download

Embed Size (px):

TRANSCRIPT

Page 1: A Rearrangement to a Zirconium—Alkenylidene in the Insertion of Dihalocarbenoids and Acetylides into Zirconacycles

2007

Cyclopentane derivativesQ 0030 A Rearrangement to a Zirconium—Alkenylidene in the Insertion of Dihalocar-

benoids and Acetylides into Zirconacycles. — An efficient assembly of bicy-clooctenes (IV) is presented, involving the generation of a zirconacyclic intermediate from enyne (I), carbene (II) and a zirconacene complex followed by rearrangement to a zirconium—alkenylidene complex on reaction with the lithium acetylide. — (THOMAS, E.; DIXON, S.; WHITBY*, R. J.; Angew. Chem., Int. Ed. 45 (2006) 42, 7070-7072; Sch. Chem., Univ. Southampton, Southampton SO17 1BJ, UK; Eng.) — Mischke

09- 068

Parr Zirconium Corrosion Info

Why Zn Acetylides?

Name Reactions Homologations€¦ · Pinacol rearrangement Pummerer rearrangement Schmidt rearrangement Wagner-Meerwein rearrangement . Anionic rearrangement . Benzilic acid rearrangement

APPENDIX TWO The Cope Rearrangement A2.1 The Cope ...2A2)_WCb.pdf · The Cope Rearrangement A2.1 The Cope Rearrangement In 1940, Arthur Cope discovered a thermal rearrangement of

The Beckmann Rearrangement

CHOLESTERIC LIQUID CRYSTAL GLASS PLATINUM ACETYLIDES ... · Cholesteric liquid crystal glass platinum acetylides Thomas M. Cooper,1 Aaron R. Burke,1 Douglas M. Krein,1 Ronald F. Ziolo,2

Thermal rearrangement ESI - The Royal Society of Chemistry · · 2012-12-19Thermal rearrangement mechanisms in icosahedral carboranes and ... rearrangement, ... Microsoft Word -

Lossen Rearrangement Reaction of Aromatic and Aliphatic ... · PDF filediisocyanatobutane in three steps. ... Hofmann rearrangement ... Synthesis of PPDI by Lossen Rearrangement Reaction

Zirconium (Zr)

Guide for the FusionWelding of Zirconium and Zirconium …G2.5+G2.5M-2012.… · FusionWelding of Zirconium and Zirconium Alloys ... (AWS A1.1) and International Standard ISO 544,

The Element Zirconium