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     1 Nisshin Steel Quality Products

    Foreword ……………………………2

    Features ……………………………3

    Production Processes ……………4

    Examples of Uses …………………5

    Specifications ………………………9

    Properties …………………………13

    Steel Pipe …………………………23

    Standard Specification for

    Steel Sheet, Cold-Rolled,

    Aluminum-Coated Type 1 ………25

     Contents

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     2Nisshin Steel Quality Products

    Nisshin Steel Co., Ltd. is Japan's sixth largest producer of iron and steel, with an annual crude

    steel production capacity in excess of three million tons. The Company, a member of the

    International Iron and Steel Institute, has extensive experience in the production and marketing of ordinary, specialty, and stainless steel.

    Nisshin is particularly strong in coated and stainless steel and has also established a firm

    position in the ordinary and specialty steel markets. The Company has maintained the highest

    technological standards, developing innovative technology and marketing superior quality steel

    products for industry and the home.

    Nisshin Steel Co., Ltd., well-known for Moonstar brand galvanized sheet, galvannealed sheet, and

    spangle-free galvanized sheet, proudly introduces Alstar, a new type of aluminized steel sheet

    and coil that has more versatility than conventional aluminized steel sheet. Aluminized steel

    sheet had been produced by the roll-wiping method in Japan since 1962, but the gas-wiping

    method developed by Nisshin Steel in 1968 has improved the uniformity and appearance of

    aluminum-coated steel sheet. This new process has also widened the scope of aluminized steel

    sheet applications. Alstar metallurgically combines the strength of steel with the advantages

     of aluminum, and is extensively used where heat resistance is involved. Specific uses are in

    heat-resistant parts and products for automobiles, burners, and home appliances. Alstar now

    enjoys the largest share of the domestic aluminized steel sheet market.

     Foreword

    Aerial view of the Sakai Works

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     3 Nisshin Steel Quality Products

    Features

    1

    Uniform aluminum coating and free control of aluminum thickness.

    2

    Thin aluminum coating(40g/m2 on both sides). This means better weld-ability and formability and hence

    better productivity.

    3

    Even surface finish and silvery white appearance make Alstar useful in applications where a fine finish is

    important.

    4

    Nisshin's aluminizing line is in constant operation so Alstar is available where and when it is needed.

     Alstar features heat resistance, corrosion resistance at high temperature, heat reflectivity, attractive appearance, nonpollutingproperties, and other characteristics that are unique to aluminized steel sheet. The gas-wiping method developed by Nisshin Steel

    has been applied to Alstar production to offer the following additional features.

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     4Nisshin Steel Quality Products

    1.Annealing process

    Nonannealed cold-rolled steel strip is annealed and the oxide film formed on the surface is reduced in the furnace.

    2.Coating process

     After the strip is reduced to a clean sur face, it is passed through the aluminum coating bath. The weight of aluminum coating on

    the strip is regulated by the gas-wiping method.

    3.Posttreatment process

    The aluminum-coated strip is then treated by chromate solution to make it further corrosion resistant. After thorough drying, the

    sheet is wound back into a coil.

    4.Skin passing process

    The aluminum-coated strip is skin passed to make it suitable for specific uses, where such factors as surface conditions and age

    hardening are involved.

    Production Processes

    8.9.

    10.11.12.13.14.

    Cooling towerSkin pass millTension levellerPosttreatment tankShearRecoilerSkin pass mill

    1.2.3.4.5.6.7.

    UncoilerShearWelderLooperOxidizing, reducing, and annealing furnaceAluminum coating bathGas-wiping

    14

    Coil

    Coil

    Cut-length

    Cut-length

    Cold RolledSteel Coils

    Oxidizing, Reducing,and Annealing Furnace Aluminizing

    Cooling Posttreatment AluminumCoated Steel

    1

    23

    4

    1

    2 3

    4

    5

    6

    7

    8

    109 12

    11

    13

    Figure 1 : Production Processes

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     5 Nisshin Steel Quality Products

    Examples of Uses

    Kerosene heater Kerosene heater Kerosene heater

    Large-sized kerosene heater Large-sized kerosene heater Large-sized kerosene heater

    Kerosene heater Water heater

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     6Nisshin Steel Quality Products

    ■ Examples of Uses   ■

    Kitchen utensils Kitchen utensils Kitchen utensils

    Oven, toaster Gas oven Two-burner gas stove

    Gas range Smokestack

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     7 Nisshin Steel Quality Products

    ■ Examples of Uses  ■

    Muffler and converter

    Muffler

    Muffler

    Muffler Muffler

    Heat insulator Reactor part

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     8Nisshin Steel Quality Products

    ■ Examples of Uses   ■

    Manifold cover Manifold cover Manifold cover

    Charcoal stove Charcoal stove Chimney

    Barbecue grill Kerosene stove Fireplace

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     9 Nisshin Steel Quality Products

    Specifications

    1.Types of Alstar

    (1) Alstar is available in the following types which vary with the uses and the means of processing.

    2.Masses of Aluminum Coating

    Note : Minimum masses on both sides by the triple-spot test are based on the ASTM standards.

     Alstar is available in various masses of aluminum coating as shown in the following table.

    Table 1

    Type Symbol ASTM(A463) Surface Finish

    Commercial Quality C CQ Dull

    Drawing Quality D DQ Dull

    Deep Drawing Quality E DQSK Dull

    (2) Indication of product's standard is as follows:

    MSA C(D,E) D △△ ×××

    Posttreatment

    Productsymbol

    Quality

    Surface finish(Dull)

    (3) There are several kinds of posttreatment for various uses. These include ordinary chromate and oiling

    and oiling nonchromate.

    Table 3

    T1-25 T1-40 MSA-40 MSA-60 MSA-80 MSA-100 MSA-120

     ASTM(A463) Nisshin StandardSymbolItem

    Minimum mass on bothsides(triple-spot test)

    g/m2 (80) (120) 40 60 80 100 120

    ox/ft2 0.25 0.40 (0.13) (0.20) (0.25) (0.33) (0.40)

    Mass ofaluminum coating

    Posttreatment Symbol

    Chromate and oiling N0

    Oiling nonchromate M0

    Table 2

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     10Nisshin Steel Quality Products

    ■ Specifications  ■

    3.Mechanical Properties

    Tension and bend tests of Alstar produce the following values.

    (1) Tensile strength and elongation

    Table 4

    0.4 to 0.6excl.

    0.6 to 0.8excl.

    0.8 to 1.0excl.

    1.0 to 1.6excl.

    1.6 to 2.3incl.

    Elongation(%), Thickness(mm)TensileStrength

    (N/mm2)Type

    Commercial Quality (270) (23) (26) (28) (30) (31)

    Drawing Quality (270) 30 32 33 34 35

    Deep Drawing Quality (270) 34 36 37 38 39

    Notes : 1. The No.5 test specimen in JIS Z2201 is used for the tension test which is conducted in conformity with JIS Z2241.2. Values in parentheses for commercial quality sheet are for reference only.

    (2) Bend test

     A specimen taken from the aluminized steel sheet in the direction parallel to its rolling is bent through 180°over a radius of 0.5t at

    right angles to the rolling direction. The outside of the bend shall be free from flaking of the coating, and cracking and breaking in

    the base metal. This does not apply to those parts of the specimen which are within 7mm of both ends.

    Note : The bend test specified in the ASTM standards may be conducted on the product if requested.

    4.Available Dimensions

     Alstar is available in the dimensions shown in the chart below.

    600

    700

    800

    900

    1,000

    1,100

    1,200

     

       W   i   d   t   h    (  m  m    )

    0.3 0.4 0.5 0.6 0.7 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2.0 2.1 2.2 2.3

    Thickness(mm)

    under 600 or over 

    914

    700 orover 

    1,219 or under 

    1,000

    1,150 or under 

    1,070 or under 

     

    Figure 2

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     11 Nisshin Steel Quality Products

    ■ Specifications ■

    5.Dimensional Tolerances

    Dimensional tolerances are as shown below.

     Alstar can also be manufactured to the dimensional tolerances of the ASTM A463 standards.

    (1) Thickness tolerances

    Table 5

    Under 1,000 1,000 or Over  

    WidthThickness

    0.27 to 0.40 excl. ±0.06 ±0.06

    0.40 to 0.60 excl. ±0.07 ±0.07

    0.60 to 0.80 excl. ±0.09 ±0.09

    0.80 to 1.00 excl. ±0.10 ±0.11

    1.00 to 1.25 excl. ±0.11 ±0.12

    1.25 to 1.60 excl. ±0.13 ±0.14

    1.60 to 2.00 excl. ±0.14 ±0.15

    2.00 to 2.30 ±0.16 ±0.17

    Notes : 1.The thicknesses shown in the above table indicate sheet thicknesses plusthe thicknesses corresponding to aluminum coating masses.

    2.Thickness is measured at any point across the width not less than 50mmfrom a side edge.

    (2) Length and width tolerances

    Table 6

    (mm)

    (mm) (mm)Table 7Item Tolerance

    Length +12, −0

    Edge Tolerance Remarks

    Mill edge +10, −0 ─

    Slit edge ±0.5 Applies to widths less than 600mmNote : The length tolerances shown in

    Table 6 do not apply to coilproducts.

    (3) Flatness tolerances

    The flatness tolerance shall be less than the figures shown in Table 8.

    Table 8

    Panel Quality 5 5 3 3

    Commercial Quality 8 8 5 5

    Press Forming Quality 11 8 8 5

    Thickness

    Long Edge(maximum deviation from a horizontal flat surface)

    Center Buckle(maximum deviation from a horizontal flat surface)

    Under 0.5 0.5 or over Under 0.5 0.5 or over  

    Type

    (mm)

    Notes : 1. Flatness tolerances apply to cut length sheets.2. Consult us about tolerances for panel quality and commercial quality sheet when ordering.

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     12Nisshin Steel Quality Products

    ■ Specifications  ■

    (mm)Table 9

    (4) Camber tolerancesCamber is the greatest deviation of a side edge from a straight line. Camber measurement is taken as shown in Figure 3 for cut-

    lengths and Figure 4 for coils.

    The camber tolerance for sheet with a width of 50mm or over and less than 200mm, and with a length of 2,000mm or over and

    less than 3,048mm, is measured as shown in Figure 4.

    Figure 3 Figure 4

    Length

    2,000mm

    Width

    Width

    Camber

    Camber

    The camber tolerance values apply to normal parts of coils and cut-lengths. Their camber tolerances must be less than the values

    shown below.

    Length over 2,000 to 3,658 excl.Length under 2,000CoilWidth

    Cut-length

    50 to 60 excl. ─ ─ 8 per 2,000

    60 to 200 excl. ─ ─ 4 per 2,000

    200 to 600 excl. ─ ─ 4 per 2,000

    600 or more 2 4 2 per 2,000

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     13 Nisshin Steel Quality Products

    Properties

    1.Heat Resistance

     Alstar has far greater heat resistance than galvanized and cold-rolled steel sheet and thus keeps its original fine surface luster 

    even when used for long periods at temperatures below 450℃*. If it is exposed to temperatures above 450℃, however, the iron

    and aluminum become alloyed through mutual diffusion and the surface gradually turns from gray to a darker color. Since this

    alloy layer has a high fusing point, it will not melt even if exposed to a temperature above the fusing point of aluminum.

    In addition, an oxide layer is produced on the coated surface by high temperature, which suppresses scale formation so that the

    sheet will not quickly become oxidized and worn until the diffusion progresses to the point where the aluminum coating becomes

    unable to control scale formation (approximately 600℃). The heat-resistant characteristics of Alstar are shown below.

    *We have high grade Alstar which can be used at approximately 500℃.

    (1) Heating behavior of aluminized steel sheet

    ………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………………

    ………………………………………………………………………………………………………………………………

    ×

    ×

    × ×

    × ×

    ×

    × ×

    ××

    ×

    × ×

    ×

    ×

    ×

    ××

    ×

    ××

    Fe (before heating) Fe (after heating) Fe (after more heating)

    Alloy layer

    Alloy layerAlloy layer

    Heating HeatingOxidized layer caused byhigh temperature

    Al Al

    Figure 5

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     14Nisshin Steel Quality Products

    ■ Properties  ■

    (2)Microscopic photographs of cross sections of MSA-40 kept at 500℃ for 100 hours and 1,000 hours,respectively

    (3) Heat resistance comparison of aluminized steel, stainless steel, and cold-rolled steel sheet

    Figure 6 shows a mass increase comparison of Alstar with 18-8 stainless steel and cold-rolled steel sheet after high-temperature

    oxidation. Alstar shows good heat resistance(at 500℃ to 600℃)similar to stainless steel sheet, and is over 20 times more heat-

    resistant than cold-rolled steel sheet.

    Before heating After 100 hours of heating at 500℃ After 1,000 hours of heating at 500℃

    Cross sectional structures of Alstar before and after heating to 500℃(Drawing Quality)

    Figure 6

                 C          o

                   l              d       -          r          o

                   l               l          e

                  d           s

                 t          e          e

                   l           s

                   h          e          e             t               (                 5

                 0             0      ℃

                   )   

        C   o     l    d

       -    r   o     l     l   e

        d     s    t   e

       e     l     s     h

       e   e    t      (     4

        0    0     ℃      ) 

     A l s t a r

      (  6 0 0  ℃

      )

    A l s ta r  (  5 0 0 ℃ )

    18-8 s tainless s teel shee t (50

    0 ℃ )

     1 8 - 8  s t a

     i n l e s s  s t

     e e l  s h e e

     t  (  6 0 0  ℃ )

    0 4 8 12 16 20 24 28 32 36 40 44 48 52Oxidation Time (hours)

    Heat resistance comparision of Alstar, stainless steel, and cold-rolled steel sheet

    10

    20

    30

    40

    50

    60

       O  x  y  g  e  n   P   i  c   k  u  p   (  m  g   /   d  m   2   )

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     15 Nisshin Steel Quality Products

    ■ Properties ■

    (4) Mass increase/decrease by oxidation through heating and cooling cyclesFigures 7 and 8 show a mass increase and decrease comparison of Alstar's different aluminum coating masses with other 

    materials after oxidation, and after being exposed to 10 cycles of heating to 600℃ and 750℃ and then cooled. It is clear from the

    diagrams that Alstar possesses greater oxidation resistance than cold-rolled and galvanized sheet even at temperatures of 600℃

    and 750℃, and can be satisfactorily used below 600℃ without any increase in oxidation.

    Figure 7 : Heating and Cooling Cycle

    750℃

    600℃

    Hours

       T  e  m  p

      e  r  a   t  u  r  e   (    ℃   )

    200

    400

    600

    800

    0 4 8 12 16 20 24

    Figure 8 : Oxidation Increase/Decrease by 600℃ and 750℃ Heating/Cooling Cycles

    600℃ 750℃

    TI-25CQ (MSA-80)

    TI-25CQ

    SUS430

    SUS430

    SPC (Cold-rolled steel sheet)

    SPC

    Galvanized sheetGalvannealed sheet

    Galvanized sheet

    Galvannealed sheet

    2 5 10

    Number of Cycles

       O  x   i   d  a   t   i  o  n   I  n  c  r  e  a  s  e   /   D  e  c  r  e  a  s  e   (  g   /  m   2   )

    10

    -10

    -20

    -30

    -50

    -70

    -100

    -200

    -300

    -500

    30

    50

    100

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     16Nisshin Steel Quality Products

    ■ Properties  ■

    2.Heat Reflectivity

     Alstar possesses not only a finely finished surface, but also excellent heat reflectivity. Because Alstar has a very high thermal

    efficiency, it is useful for making highly effective heat reflecting plates for toasters, ovens, driers, and other consumer durables.

    For reference, here is a surface luster comparison of Alstar with other steel sheets.

    Table 10

    Type Surface Finish Surface Luster  (%) Surface Roughness(μ)

     Alstar Dull 15 Hmax 8 to 9

    Stainless steel sheet 2B 15 Hmax 1.2

    Stainless steel sheet BA 60 Hmax 0

    Cold-rolled steel sheet coated with silver paint Dull 6 Hmax 8

    Notes : 1. Surface luster measured(with gloss meter Model GM-3)in conformity with JIS 8741.2. 1/10 light filter Gs(60)is used.

    3.Corrosion Resistance

     Aluminum has a more active ionization trend than Mn, Mo, Cr, W, Cd, Fe, and Zn and is more easily corroded. Because aluminum

    has the characteristic of easily forming a fine oxide film when exposed to air, or a hydroxide film when exposed to water, a

    corrosion resistance effect by galvanic action, such as is exhibited in galvanized sheet, cannot be expected.

    Because aluminum's oxide film is stable, the aluminum coated surface of Alstar is considerably more corrosion-resistant than that

    of galvanized sheet except in certain environments. The corrosion resistance of Alstar under various conditions is shown in the

    following pages.

    (1) Corrosion resistance in various pH solutions

    Unlike zinc, aluminum is relatively resistant to weak acids but not to alkalis. The corrosion resistance of aluminum in pH solutions

    is as shown in Figure 9.

    Figure 9

    Corrosion resistancein pH Solutions

    10

    20

    30

    40

    50

    60

    70

    80

    90

    100

    110

    120

    130

    pHAlkalinity

    Alstar (room temperature)

    Alstar (60℃)

    Galvanized sheet (room temperature)

    Galvanized sheet (60℃)

    Acidity

    1 2 3 4 5 6 7 8 9 10 11 12 13 14

       C  o  r

      r  o  s   i  o  n   (  g   /  m   2   /   d  a  y   )

    Source : Metal Surface Technology Vol.7, No.7.

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    Pretest Treatment 24 Hours 72 Hours 240 Hours 360 Hours

     17 Nisshin Steel Quality Products

    ■ Properties ■

    (2) Saltwater spray test Aluminum shows a lower potential than iron in saltwater and, in an Fe-Al electrolyte cell with an aluminum anode and steel

    cathode, the aluminum, as a sacrificial anode, protects the steel from corrosion.

    Table 11 shows the results of a continuous saltwater spray test on Alstar.

    TI-25DQ Alstar (MSA-80 Drawing Quality)

    Room temperature250℃×24 hours

    Other manufacturers'electro-galvanized sheet

    Room temperature250℃×24 hours

    Red rust10%

    Red rust60%

    Red rust60%

    Red rust90%

    Red rust100%

    Red rustin 384hours

    Table 11

    Chemicals Alstar Galvanized Sheet

    Light oil E G

    Palm oil E E

    Machine oil E G

    Boiled oil E E

    Spindle oil E E

    Glycerine E E

    Formalin F G

     Alcohol G G

     Acetone E E

    Carbon tetrachloride E E

    Coal tar E E

    Printing ink E E

    Phthalide E G

     Aqueous ammonia P F

    5% caustic soda P F

    5% nitric acid F P

    5% sulfuric acid P P

    5% acetic acid F P

    Table 12

    Note : Evaluation scale : E = ExcellentG=GoodF =Fair P=Poor 

    (3) Atmospheric exposure test

     Aluminized steel sheet develops oxides on the aluminum surfaces when exposed to air, but the stable oxides protect the

    aluminum layer and prevent discoloring of the surfaces. Exposed steel parts, such as cut sections and pinholes, however,

    develop red rust.

    If Cl− is present in a wet state, as in seawater, for example, the oxidized aluminum film is destroyed and starts a sacrificial

    corrosion protection action.

    Because aluminum has a lower electrolytic solubility than zinc, aluminized steel sheet has greater corrosion resistance in, for 

    example, coastal areas.[If the coating mass is the same, the ratio is said to be five or six(aluminum)to approximately one(zinc)].

    (4) Resistance to chemicals

     Alstar has less resistance to alkaline industrial chemicals, but greater resistance to acid industrial chemicals than galvanized

    sheet.

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     18Nisshin Steel Quality Products

    ■ Properties  ■

    Notes : 1. Test method:Chrysler's spec. 461H-83.

    2. Test outline:(a)A mixed solution of 180°F(82℃)0.01N hydrobromic acid and 0.05N sulfuric acid was used for the test.(b)Cold muffler conditions. After immersing the test pieces in the test solution for five seconds, they were kept

    over the solution surface for one hour. This was repeated 20 times(20 hours).(c)Hot muffler conditions. Then the test pieces were heated in a furnace at 1,000°F(538℃)for two hours.(d)Steps(b)and(c)were repeated for 240 hours.

    3. Test results judgment:(a)Amounts of decrease before and after the test were measured.(b)Decreased amounts were converted into decrease in sheet thickness.(c)Converted sheet thickness decrease must be less than 0.002 in.(0.051mm).

    4. Test results:

    The test simulated a running Chrysler car. Sheet thickness decreased in inverse proportion to aluminum coatingmass Alstar passed this test.

    (5) Resistance to automobile exhaust gas Alstar demonstrates good corrosion resistance in auto exhaust part uses. The results of an exhaust gas test by the Chrysler 

    Corporation of the U.S. are shown in Table 13.

    Decrease in Mass(g)Decrease in Thickness

    (converted from the mass decrease)

    R in. mm−x

    TI-25DQ Alstar (MSA-80 Drawing Quality) 0.260 0.011 0.0007 0.018

    TI-25CQ Alstar (MSA-80 Commercial Quality) 0.191 0.035 0.0005 0.013

    Table 13

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     19 Nisshin Steel Quality Products

    ■ Properties ■

    4.Weldability

     Alstar differs slightly from cold-rolled steel sheet under welding conditions. Since aluminum is soft, flexible and has good electric

    conductivity, aluminized steel sheet generates less heat at welds than cold-rolled steel sheet. Alstar does not require as high a

    current as galvanized sheet due to the aluminum coating which has a higher melting point, less fluidity, and less spread of molten

    area.

    Conditions for spot, seam, and other kinds of welding are given below.

    (1) Spot welding

    Table 14 shows an example of spot welding conditions for Alstar.

    Table 14 : MSA-40 Commercial Quality

    Electrode Force(N)

    Time( )

    Current(A)

    Shear Strength(N)

    Thickness(mm)

    Electrode FaceD R

    0.6 16 25 1,800 9 8,700 1,900

    0.8 16 25 2,000 10 9,500 2,500

    1.0 16 50 2,500 11 10,500 4,100

    1.2 16 50 3,100 12 12,000 5,900

    1.4 16 50 3,900 14 13,000 7,800

    2.0 16 50 5,400 18 14,000 12,700

    Note : With a low welding current, sufficient strength cannot be expected. With an overcurrent, the aluminum coating deteriorates morethan necessary and dark gray stripes appear around welds. Suitable welding conditions between these extremes must beselected. The scope of correct welding conditions narrows in inverse proportion to sheet thickness. Chromium copper alloy electrode tips may be used and, as with galvanized sheet, aluminum pickup poses a problem. Good water-cooling tominimize pickup and periodic dressing are necessary. As in the case of welding mild steel, radius-face tips or truncated cone

    face(120°to 140°)tips are recommended.

    Figure 10 shows the results of a spot welding test on MSA-40 and MSA-80, which differ in aluminum coating mass. While MSA-40

    shows a sharp drop in shear strength after approximately 900 spot welds, MSA-80 develops the same phenomenon after 

    approximately 600 spot welds. proximately 600 spot welds.

    Figure 10 : Electrode Life in Spot Welding Alstar

    1,000

    0

    2,000

    2,900

    3,900

    4,900

    5,900

    6,900

    7,800

    8,800

    9,800

    1,000

    0

    2,000

    2,900

    3,900

    4,900

    5,900

    6,900

    7,800

    8,800

    9,800

       S   h  e  a  r   S   t  r  e  n  g   t   h   (   N   )

    0

    2

    4

    6

    8

    0

    2

    4

    6

    8

       D   i  a  m  e   t  e  r  o   f   E   l  e

      c   t  r  o   d  e

       F  o  r  c  e   M  a  r   k   (  m

      m   φ   )

    0 100 200 300 400 500 600 700 800 900 1,000

    Number of Welds

    Shear strength

    Diameter of electrode force mark

    MSA-80 1.0mm

    MSA-40 1.0mm(Commercial Quality)

    Notes : Welding conditions: Electrode force: 2,000NWelding current: 11,200A to 14,500A. Welding time: 7 .

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     20Nisshin Steel Quality Products

    ■ Properties  ■

    (2) Seam weldingTable 15 shows an example of seam welding conditions for Alstar.

    Table 15

    Thickness(mm)

    Electrode Width(mm)

    Electrode Force(N)

    Welding Speed(cm/min.)

    Current(A)On Off

    Time

    0.8 7 3,900 3 2 150 17,000 to 19,000

    0.95 7 4,200 3 3 150 16,000 to 18,000

    0.95 7 4,200 3 2 230 18,000 to 21,000

    1.2 7 4,400 3 2 150 18,000 to 20,000

    1.2 7 4,900 4 2 230 18,000 to 21,000

    (3) Gas welding and arc welding

    Gas welding is difficult and requires a certain amount of skill. It is recommended that a two-stage regulator be used for assuring

    the correct gas flow. Use killed steel wire for satisfactory results. Flux for stainless steel is suitable for the purpose.

    Shielded arc electrodes may be used for arc welding, but care must be taken in selecting the right kind of electrode. Ilmenite or 

    high titanium type electrodes produce blow holes. For the best results, select a low hydrogen type electrode. If a corrosion-

    resistant characteristic is required, use stainless steel. When oxidation of welds must be reduced to a minimum, argon arc

    welding(TIG)produces good results.

    Tables 16 and 17 show examples of arc welding and TIG welding.

    Table 16 : Example of Arc Welding

    Thickness(mm)

    Welding Rod WeldabilityJIS Rating of

     X-ray ResultsTensile Strength

    (N/mm2)Elongation

    (%)Rupture PointSheet Welded

    T1-25CQMSA-80CommercialQuality

    SPCC

    1.2 D4313 Poor 6 387 24.2 Weld

    1.2 D4316 Good 1 368 28.9 Base metal

    1.2 Excellent 1 379 28.0 Base metal

    1.2 D4316 Good 1 327 28.4 Base metal

    D30816Stainless steel

    Table 17:Example of TIG Welding

    Sheet WeldedThickness(mm)

    Welding RodWeldingCurrent

    WeldabilityJIS Rating of

     X-ray ResultsTensile Strength

    (N/mm2)Elongation

    (%)Rupture Point

    T1-25CQMSA-80

    CommercialQuality

    1.6

    GA(gas-welding rodfor mild steel)

    DM-2(gas-welding rodfor Si-Mn alloy)

    D308(18-8 stainlesssteel rod)

    GA 

    DM-2

    D308

    DC Poor 4 400 24 Base metal

    DC Good 1 380 28 Base metal

    DC Excellent 1 398 26 Base metal

     AC Poor 2 380 24 Base metal

     AC Good 1 389 28 Base metal

     AC Good 1 393 24 Base metal

    Notes : 1. Argon gas flow rate: 6 l/min2. AC power source: Pure tungsten electrode 3.2φ3. DC power source: Thorium-containing tungsten electrode 3.2φ

    (4) Weld repairs

    Welds and damaged aluminum coating can be repaired with silver paint or with molten aluminum spray.

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     21 Nisshin Steel Quality Products

    ■ Properties ■

    5.Formability

     Aluminized steel sheet is generally said to have poor formability as compared with cold-rolled and galvanized sheet because it

    has a hard alloy layer of steel and aluminum between the base metal and the aluminum coating. However, Alstar offers good

    formability comparable to other steel sheets if proper consideration is taken of its characteristics.

    (1) Deep drawing

    (a)Die and punch radii and clearances must be used where appropriate to prevent

    aluminum exfoliation on the parts pressed by deep drawing.

    (b)Die radii 6t to 10t and punch radii similar to those used in cold-rolled steel

    sheet drawing may be used, although the figures vary with forms to be drawn.

     A clearance of about 1.2t is appropriate.

    (c)If redrawing is necessary , a drawing ratio of more than 60 percent is

    recommended per drawing.

    A sample(0.55mm)formed by a 6

    ton cushion pressure

    (2) Burring

    (a)The hole enlarging ratio of Alstar ranges from 0.3 to approximately 0.8, depending on the forming process

    (This compares with 0.5 to 0.9 for cold-rolled steel sheet).

    (b)The hole enlarging operation can be improved by observing the following instructions:・Direct burrs inward.

    ・Use an enlarging punch that has a greater taper.

    ・Add embossing during the enlarging process.

     An example of hole enlarging and drawing is shown below.

    Drawn sample(1.2mm)auto muffler end plate

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     22Nisshin Steel Quality Products

    ■ Properties  ■

    6.Paintability

     Alstar requires chemical treatment before painting to assure good adhesion of paint.

    (1) Pretreatment

    Degreasing alone is insufficient to assure good adhesion. For the best results, the following process is recommended.

    ・Take note of pH.

    ・Use trichloroethylene or other 

    neutral chemicals.

    (2) Paint

    The same paint as used in painting other steel sheets may be used for Alstar if it is pretreated. To obtain satisfactory corrosion

    resistance, adhesion and other qualities, the right paint for the intended use should be selected.

    The following are examples of paint that may be used for Alstar:

    ・Vinyl resin paint.

    ・Silicon resin paint.

    ・Polyurethane resin paint.

    ・Phenol resin paint.

    ・Alkyd resin paint.

    ・Lacquer.

    Degreasing Chemical Treatment Painting

    7.Food Sanitation

    The aluminum coating consists of aluminum, silicon and iron. Tests conducted by prefectural governments in Japan, under the

    Food Sanitation Law, have proved that even if these elements enter the human body, they are harmless and will be completely

    discharged. An example of analysis of the aluminum coating of a utensil made from Alstar is shown below.

     Aluminum(77.2%)

    Silicon(7.4%)

    Iron(15.4%)

    Caution : Chromate treatment for preventing white rust on the aluminum surface is harmful, and therefore only oiling without

    chromate is recommended.

    ・Chromate treatment or phosphate

    treatment is recommended.

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     23 Nisshin Steel Quality Products

    Steel Pipe

     Alstar steel pipe is made from Alstar steel sheet by high-frequency welding. It has all the features of Alstar steel sheet. Beinghighly heat resistant, Alstar steel pipe is used in large quantities in the automobile industry as exhaust pipe.

    1.Features

    1)Evenly coated with aluminum

    2)Thin aluminized Alstar steel pipe is available.

    3)Highly heat resistant

    4)High workability

    5)Excellent weldability

    6)Smooth, aesthetically pleasing surface

    2.Quality

    (1) Appearance

     Alstar steel pipe has an aesthetically pleasing surface peculiar to aluminum. Bare metal is exposed on the outer surface of welded

     joints in an area 3mm to 5mm wide after bead cutting but can be aluminized to order. Slight beads are built on the inner surface

    of welded joints but can be cut away as necessary.

    (2) Workability

     Alstar steel pipe has the same workability as the JIS G3445 machine-structure carbon steel pipe STKM-11A.

    (3) Effect of pipe production on aluminum coats

    Pipe production has little if any detrimental effect on the aluminum coating of Alstar steel sheet.

    (4) Corrosion resistance of welds

    Since bare metal is exposed at the welds after bead cutting, rust forms at an early stage of the salt spray test. Alstar steel pipe is

    generally used unfinished after bead cutting as heat-resistant parts but has not posed any problem in such applications.

    3.Mechanical properties

    Typical mechanical properties of Alstar steel pipe made of MS-40(drawn material)are shown in Table 18.

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     24Nisshin Steel Quality Products

    ■ Steel Pipe  ■

    Table 18

    Number ofTest Cycles

    Flattening Test(2/3D)

    Flaring TestBending Test

    (3D)Test Piece Size Tensile Strength

    (N/mm2)Elongation

    (%)

    Tensile Test

    35.0φ×1.2mm1 366 45 Good 1.39 ─

    2 ─ ─ Good 1.38 ─

    38.1φ×1.2mm1 361 46 Good 1.39 Creases occurred

    2 ─ ─ Good 1.30 ─

    42.7φ×1.2mm1 362 45 Good 1.37 ─

    2 ─ ─ Good 1.40 ─

    Notes : 1. Tensile test: JIS No.11 test piece2. Flattening test: 2/3D, the welded portion is placed at right angles to the direction of compression.3. Flaring test: Using a 60°cone punch, pipe end openings are widened until cracks occur.

    4. Flaring ratio: Diameter after flaring/initial diameter 

    Thickness(mm)

    Outside Diameter or Side Length

    (mm)

    Length(mm)

    Round Pipe 0.6∼2.3 12.7∼63.5 3,500∼6,100

    Sharp EdgeSquare 0.8∼2.0 16×16∼25×25

    Rectangle 0.8∼2.3 22×10∼60×303,500∼6,000Square Pipe

    Rounded EdgeSquare 0.8∼2.3 25×25∼50×50

    Rectangle 0.8∼2.3 25×12∼60×30

    Table 19: Available Dimensions of Alstar Steel Pipe

    Note : Dimensions other than those listed above can be negotiated.

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     25 Nisshin Steel Quality Products

    Extracts from ASTM A 463-83

    Standard Specification for

    Steel Sheet, Cold-Rolled, Aluminum-Coated Type 1

    1. Scope1.1 This specification covers aluminum-coated steel sheet

    Type 1 in coils and cut lengths coated with an aluminum-

    silicon alloy by the hot-dip process. The aluminum-silicon

    alloy for coating has 5% to 11% silicon added to promote

    better adherence. It is intended principally for heat-resisting

    applications and also for uses where corrosion resistance

    and heat are involved. The weight of coating expressed as

    the total coating on both sides may be specified in

    accordance with Table 1. Aluminum-coated steel sheet is

    available in the following quality designations: Commercial

    Quality, Drawing Quality, Drawing Quality Special Killed, and

    Structural(Physical)Quality.

    Notes : 1. values stated in U.S. customary units are to beregarded as the standard.

    3. Description of Terms

    3.1 Quality Designations:

    3.1.1 Commercial Quality -This material is intended for 

    parts where bending, moderate forming, or moderate

    drawing may be involved.

    3.1.2 Drawing Quality -This material is intended for 

    fabricating identified parts where drawing or severe forming

    may be involved. Care should be taken to ensure that thecoating designation is compatible with the end use.

    3.1.3 Drawing Quality Special Killed -This material is

    intended for fabricating identified parts where particularly

    severe drawing or forming may be involved or essential

    freedom from aging is required. Care should be taken to

    ensure that the coating designation is compatible with the

    end use.

    3.1.4 Structural (Physical)Quality -This material is produced

    when mechanical properties are specified or required. Such

    properties or values include those indicated by tension,

    hardness, or other commonly accepted mechanical tests.

    Care should be taken to ensure that the coating designation

    is compatible with the end use.

    4. General Requirements for Delivery

    4.2 Aluminum-coated steel sheet shall be ordered to a

    decimal thickness for both coils and cut lengths. The

    thickness is the total of the base metal and the coating.

    8. Mechanical Requirements8.1 Base Meta l Bend Test -Commerci al quali ty(CQ),

    drawing qua lity(DQ), or drawing qual ity spec ial kil led

    (DQSK) shall be capable of being bent at room temperature

    in any direction through 180 deg. flat on itself without

    fracturing of the base metal. Bend test requirements for 

    structural(physical)quality are subject to negotiation.

    9. Coating Tests

    9.1 Weight of Coating:

    9.1.1 The weight of coating shall conform to the re-

    quirements for triple- and single-spot minimum checksprescribed in Table 1 for the specific coating designation.

    The weight of coating is the total amount on both sides of a

    sheet, expressed in ounces per square foot(or grams per 

    square meter)of sheet.

    9.2 Coating Bend Test:

    9.2.1 For all qualities other than structural(physical)

    quality, the bend test specimens of coated metal shall be

    capable of being bent through 180 deg. over a diameter 

    equal to twice the thickness in any direction without flaking

    of the coating on the outside of the bend only. A hand-

    operated vise with smooth jaws should be used for makingthe tests, unless excessive thickness makes this impractical.

     Any other method used to make the bend test should not

    involve impact. Flaking of coating within 1/4 in.(6.4mm)of

    the edge of the bend specimen shall not be cause for 

    rejection. Bend tests are not required of coils or cut lengths

    ordered extra-smooth or stretcher-leveled.

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    in. mm in. mm

     26Nisshin Steel Quality Products

    This Standard is issued under the fixed designation A 463; the number immediately

    following the designation indicates the year of original adoption or, in the case of revision,

    the year of last revision. A number in parentheses indicates the year of last reapproval.

    TABLE 1 Coating Designation and Minimum Coating Test Limits for Aluminum-Coated Steel Sheet Type1Note : The weight of coating in ounces per square foot and coating thickness in inches refer to the total coating on both surfaces.

    The coating designation is the term by which this product is specified.

    Calculated Coating ThicknessBased on Minimum

    Single Spot Test,a in.

    CoatingDesignation

    Triple-Spot TestTotal Both Sides

    Single-Spot TestTotal Both Sides

    oz/ft2 g/m2 oz/ft2 g/m2

    TI 40(regular) 0.40 120 0.30 90 0.0013

    TI 25(light) 0.25 75 0.20 60 0.0008a Calculation based on aluminum density of 0.0975 lb/in.

    11. Dimensions, Weights, and Tolerances11.1 Aluminum-coated steel sheet is produced to decimal thickness only. The density of aluminum is 0.0975 lb/in. as compared

    to that of zinc which is 0.258 lb/in.; hence, the weight equivalents are different. Table 3 gives the thickness and weight equivalents

    of aluminum-coated steel sheet Type1.

    11.2 Thickness tolerances and all other dimensional tolerances are given in Tables 4 through 16.

    TABLE 4 Thickness Tolerances of Aluminum-Coated Steel Sheet Type1

    Notes : 1. Thickness is measured at any point across the width not less than 3/8 in.(9.5mm)from a side edge.2. Regardless of whether total thickness tolerance is specified equally or unequally, over and under, the total tolerance

    should be equal to twice the tabular tolerance.

    Over 0.101to 0.187, incl

    Over 0.075to 0.101, incl

    Over 0.061to 0.075, incl

    Over 0.043to 0.061, incl

    Over 0.023to 0.043, incl

    0.023 andthinner 

    Thickness Tolerances for Widths and Thicknesses, Over and Under, in.

    Specified Thickness, in.Specified Width, in.

    To 32 incl 0.008 0.007 0.006 0.005 0.004 0.003

    Over 32 to 40, incl 0.008 0.008 0.006 0.005 0.004 0.003

    Over 40 to 60, incl 0.009 0.008 0.006 0.005 0.004 0.003

    TABLE 5 Width Tolerances of Aluminum-Coated

    Steel Sheet Type1(Coils and Cut Lengths Not

    Resquared)

    Tolerance Over Specified

    Width, No Tolerance Under 

    Specified Width, in.

    (mm)in. mm

    Over 12(300)to 30(760), incl 1/8 3.2

    Over 30 to 48(760 to 1,220), incl 3/16 4.8

    Over 48 to 60(1,220 to 1,520), incl 1/4 6.4

    Appendix A1. Metric Equivalents

     A1.1 The metric equivalents for the tolerances given in the

    tables are shown in Table A1.

    TABLE A1 Metric Equivalentsa

    0.001 0.0254 3/16 4.762

    0.005 0.127 1/4 6.350

    0.010 0.254 5/16 7.938

    0.050 1.270 3/8 9.525

    0.100 2.540 1/2 12.700

    0.200 5.080 3/4 19.050

    1/16 1.588 7/8 22.225

    1/8 3.175 1 25.400aConversion factor : 1 in.×25.4=mm.

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    Technical information in this booklet, while every reasonable

    effort was made to ensure the accuracy at the time of this

    publication, is general information relating to our products

    only and is not meant as any warranty, expressed or implied.

    Such technical information does not guarantee that any of our

    products are suitable for your particular application or

    purpose. Use of any information contained in this booklet shall

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