chapter 3 smith and van ness
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CHAPTER 3 SMITH ANVAN NESSCHE123 CPMONTEROLA
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Variation of volume it!tem"erature an# "re$$ure
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I% E%%ICIENC& IS '()
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I% E%%ICIENC& IS '()
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THE THROTTLIN* PROC
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RE%RI*ERATOR THERMO
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CAR AIRCON S&STEM
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H+P,T-
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ISENTHALPIC PROCESS+CONSTA
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.O/LE0THOMSON COE%%I
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.O/LE0THOMSON COE%%
2.30(a) !en a ertain freon u$e# in refriea$ e4"an#e# a#ia5atiall6 from an initial "of 32 atm an# (7C to a 8nal "re$$ure of 19((t!e tem"erature fell 56 22 :9 Calulate t!e .
T!om$on oeffiient, <, at (7C, a$$umin it on$tant over t!i$ tem"erature rane9
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ISENTHALPIC PROCESS+CONSTA
2 =>? Conern$ over t!e !armful e
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29=>? Conern$ over t!e !armful e!lorouoroar5on$ on $trato$"!eri oBomotivate# a $ear! for ne refrierant$9 alternative i$ 2,20#i!loro01,1,10triu
+refrierant 123-9 &ounlove an# MLin#en "om"en#ium of t!ermo"!6$ial "ro"ertie$$u5$tane +.9 P!6$9 C!em9 Ref9 Data 23, +1!i! "ro"ertie$ $u! a$ t!e .oule;T!om$on
< an 5e om"ute#9+a- Com"ute < at 19(( 5ar an# >(7C iven t!a 392 J 1(3 . MPa1 mol1 an# C",m 1mol19 +5- Com"ute t!e tem"erature !ane taom"an6 a#ia5ati e4"an$ion of 29( m
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ASPEN H&S&S %L/ID PAC:A*E
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K an# C are !emial $"eie$ #e"en#ent9
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COMPRESSIKILIT& %ACTOR,
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ISOTHERMS O% METHANE
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VIRIAL E/ATION O% STA
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VIRIAL E/ATION O% ST
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KENEDICT EKK ROKIN
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REDLICH0:ON* E/ATION
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THE
CORRESPONDING STATE THEORY
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THE ACENTRIC %ACTOR, O
•
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*ENERALIED COMPRESSIKILIT& %ACTOR CORRELATLEE0:ESLER CORRELATION
( an# 1 are funtion$ of Tr an# Pr9
Ta5le$ for inter"olation are foun# in a""en#i4 E ofSmit! an# Van Ne$$9
i$ in a""en#i4 C of t!e $ame 5ooQ9
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PERR& PA*E 20>(2 LEE0:
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391(
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APPENDI K VAN
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PITER CORRELATION
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PERR& PA*E =01(
PERR& PA*E =
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PERR& PA*E =0
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391(
THIRD VIRIAL COE%%ICIEN
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THIRD VIRIAL COE%%ICIENHAT PERR& PA*E =01(
THIRD VIRIAL COE%%ICI
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THIRD VIRIAL COE%%ICIHAT PERR& PA*
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391(
REDLICH0:ON* EOS PERR& PA*E =
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R:
PEN* ROKINSONEOS
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EOSPERR& PA*E =0
11
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PEN*0ROKINSON EOS
'9 +1( "t$- &ou are a$Qe# to #e$in a $teel tanQ in CO2 ill 5e $tore# at 2( :9 t!e tanQ i$ 1(9= m3 inan# 6ou ant to $tore =( Q of CO2 in it9 !at "rill t!e CO2 e4ert /$e Pen0Ro5in$on eUuation toan$er9
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LOO:IN* %OR PRESS/RE /SIN*
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R: E/ATION
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ASPEN H&S&S %L/ID PAC:A*E
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RE%RI*ERATORS EPANSION
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