cheminform abstract: a general method for the direct α-arylation of aldehydes with aryl bromides...
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2008
AldehydesQ 0320 A General Method for the Direct α-Arylation of Aldehydes with Aryl Bromides
and Chlorides. — An efficient and general method for the α-arylation of linear and α-branched aldehydes with aryl bromides and chlorides is presented. The axially chiral ligand is varied depending on the choice of aryl bromides or chlorides and depending on the steric bulk of aldehyde. A wide range of functional groups is tolerated on both aldehyde and aryl halide. — (MARTIN, R.; BUCHWALD*, S. L.; Angew. Chem., Int. Ed. 46 (2007) 38, 7236-7239; Dep. Chem., MIT, Cambridge, MA 02139, USA; Eng.) — Mischke
02- 072
2008
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