treatment using electrical resistance heating (erh) of source

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Treatment Using Electrical Resistance Heating (ERH) of Source Area CVOCs at a Former Manufacturing Facility, Newtown, CT Art Taddeo

June 13, 2012

Overview

• Site Intro/Conceptual Site Model

• Remedial Approach

• Design and Construction

• Results and Lessons Learned

• Conclusions and Future Activities

• Questions

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Site Intro

• Former metal tubing manufacturing facility operated from

1950’s to 1986

• Site consists of 12 acre former facility and adjacent

undeveloped woodlands/wetlands in suburban area

• Former facility parcel abuts an active railroad line

• Groundwater classification GA/GAA

• Chlorinated solvents from manufacturing process released

to subsurface (TCE, other related compounds)

Page 3

Conceptual Site Model

• Residual NAPL observed in former facility building slab

area

• Source impacts observed in fine grained saturated soils

(till), minor permeable drift zones and in weathered bedrock

• Two dissolved plumes: one smaller one to the northwest of

the slab and a larger one northeast of the slab (off-site

plume)

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Conceptual Site Model – Plan View

Page 5

Upland

Source Area

Wetland Wetland

Stream

2 mg/L

750 mg/L

20 mg/L

2 mg/L

TCE Plume

RR Track

GW Flow

Conceptual Site Model – Cross Sectional Views

Page 6

Source Area

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Remedial Approach

• Targeted soil removal performed to achieve residential

direct exposure criteria (RDEC) in slab area

• SVE was performed on-site in the past with limited success

• A focused feasibility evaluation was performed as well as

an in situ bioremediation pilot study for the on-site slab area

• Remedial strategy: in situ thermal for treatment of slab

source area and in situ bioremediation (ERD) for the west

of slab and off-site plumes

• Slab area treatment goal (760 ppb) modeled TCE levels

that will not exceed surface water criteria off-site

• Technical Impracticability (TI) Waiver permit for the site and

adjacent properties will be pursued

Page 7

Permitting / Approvals

• Remedial action plan (off-site thermal impacts a concern)

• CTDEP Wastewater Discharge/UIC Permit

• General Permits for Discharge of Wastewater to Surface

Waters and Sanitary Sewer

• CT DEP air emissions permit applicability (permit

exemption and non-applicability)

• Local inland wetlands and building permits

• Local and State noise ordinances

• Access agreements – railroad and utility company

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Remediation Project Overview

Page 9

Staging

Area

Access

Road

Biobarriers

Thermal

Treatment Area Railroad Line

Bioremediation Area

High Voltage Electric

Transmission Lines

Design-Construction

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ERH Design

• Grid (20 ft on center) of 89 steel electrodes to weathered

bedrock (21 to 42 ft bgs)

• Co-located vapor recovery wells screened from 3 to 6 ft bgs

• 8 multi-depth temperature monitoring points (TMPs) with

thermocouples every 5 feet in depth

• Design treatment duration of a minimum of 4 months with

at least 30 days at 100 C to reach 760 ppb or less TCE

(reduction of 99.9% or greater)

Page 11

ERH Design

• Design of 4,330,000 kWh energy input

• 600 lbs TCE mass in subsurface slab area

• Thermal oxidizer with four backup 2,000 lb vapor carbon

filters

• Three 2,000 lb liquid carbon filters for condensate/scrubber

wastes

• Recyling of condensate for electrode re-wetting drip, if

necessary

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Power control Unit (PCU)

Condenser and Cooling Tower

Stack,

Scrubber,

Caustic

feed

Electrode field and vapor recovery piping

Vacuum

blower

Thermox

Unit

Vapor

GAC

vessels

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Safety Procedures

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Hot Media Sampling Procedures

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Results/Conclusions

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Thermal Remediation - Heating

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Thermal Remediation – TCE (ug/L) 3 Month post-treat

Page 48

11/09: 5,800

5/11: 5

12/09: 12,000

1/11: 140,000

5/11: 4 11/10: 14

1/11: 14,000

5/11: 2

2/10: 30,000

5/11: 2

2/10: 3,100

5/11: 8

6/10: 1,300

11/10: 11,000

5/11: 10

6/10: 1,600

8/11: 19

1/10: 2,200

5/11: 16,000

8/11: 1,400

6/10: 47,000

1/11: 22,000

10/11: 460

6/10: 1

2/11: 88,000

5/11: 39

2/10: 27,000

1/11: 50,000

8/11: 1,600

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Thermal Remediation

Page 49

Conclusions

• Temperatures rose above the boiling point of TCE and

water throughout most of the treatment area (exception of

the weathered bedrock where temperatures rose to 80 C

• Very little heat appears to have migrated in groundwater

off-site to the wetlands area (only MW-210WB reached

110 F for 1-2 months)

• TCE concentrations have significantly decreased in

groundwater to date. 19 of 22 wells are now below the TCE

cleanup goal

• The residual TCE mass is very low and the TCE mass flux

has been reduced significantly and is below the TCE mass

flux associated with the cleanup goal for the site

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Lessons Learned

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Conclusions and Future Activities

• Thermal remediation

– Fully heated zones were established

– Treatment of weathered bedrock is

challenging

– Treatment of aqueous and soil phase

CVOCs & residual DNAPL is being

achieved and mass flux reduced

– Stray voltage mitigated cost-effectively

– “All-Inclusive” Cost: $120/CY

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Conclusions and Future Activities

• Thermal remediation

– Future activities include:

• Continued monitoring for rebound and

migration of heated groundwater

• Abandonment of electrodes and TMPs

• Post-remediation monitoring

• Polishing with bio if necessary

• Technical impracticability waiver zone permit

Page 59

Acknowledgements

• John Albrecht, L.E.P. (AECOM, Rocky Hill, CT)

• Lucas Hellerich, Ph.D., P.E., L.E.P. (AECOM, Rocky Hill,

CT)

• Paul Dombrowski, P.E. (AECOM, Wakefield, MA)

• Brian Finnell, P.G., C.E.G. (AECOM, Chelmsford, MA)

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Art Taddeo

Senior Program Manager

978-905-2423

arthur.taddeo@aecom.com

Thank you!

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