as 12 quantumphenomena
TRANSCRIPT
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1.2 Electromagnetic Radiation and Quantum Phenomena
Quantum PhenomenaBreithaupt pages 30 to 43
December 5th, 2011
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AQA AS SpecificationLessons Topics
1 & 2 The photoelectric effect
Work function , photoelectric equation
hf = + Ek;
the stopping potential experiment is not required.
3 & 4 Collisions of electrons with atoms
The electron volt.
Ionisation and excitation; understanding of ionization and excitation in the
fluorescent tube.
5 & 6 Energy levels and photon emission
Line spectra (e.g. of atomic hydrogen) as evidence of transitions between
discrete energy levels in atoms.
hf = E1- E2
7 & 8 Wave-particle duality
Candidates should know that electron diffraction suggests the wave nature of
particles and the photoelectric effect suggests the particle nature of
electromagnetic waves; details of particular methods of particle diffraction are
not expected.
de Broglie wavelength = h / mv, where mv is the momentum.
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The photoelectric effect The photoelectric effect is the
emission of electrons from thesurface of a material due to theexposure of the material toelectromagnetic radiation.
For example zinc emits electrons
when exposed to ultraviolet radiation. If the zinc was initially negatively
charged and placed on a gold leafelectroscope, the electroscopes goldleaf would be initially deflected.
However, when exposed to the uvradiation the zinc loses electrons andtherefore negative charge.
This causes the gold-leaf to fall.PhetPhotoelectric effect
NTNUPhotoelectric effect
http://phet.colorado.edu/simulations/sims.php?sim=Photoelectric_Effecthttp://phet.colorado.edu/simulations/sims.php?sim=Photoelectric_Effecthttp://phet.colorado.edu/simulations/sims.php?sim=Photoelectric_Effecthttp://www.phy.ntnu.edu.tw/ntnujava/index.php?topic=342.0http://www.phy.ntnu.edu.tw/ntnujava/index.php?topic=342.0http://www.phy.ntnu.edu.tw/ntnujava/index.php?topic=342.0http://www.phy.ntnu.edu.tw/ntnujava/index.php?topic=342.0http://www.phy.ntnu.edu.tw/ntnujava/index.php?topic=342.0http://www.phy.ntnu.edu.tw/ntnujava/index.php?topic=342.0http://www.phy.ntnu.edu.tw/ntnujava/index.php?topic=342.0http://phet.colorado.edu/simulations/sims.php?sim=Photoelectric_Effecthttp://phet.colorado.edu/simulations/sims.php?sim=Photoelectric_Effecthttp://phet.colorado.edu/simulations/sims.php?sim=Photoelectric_Effecthttp://phet.colorado.edu/simulations/sims.php?sim=Photoelectric_Effect -
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Experimental observations
Threshold frequencyThe photoelectric effect only occurs if the frequency of theelectromagnetic radiation is above a certain threshold value, f0
Variation of threshold frequency
The threshold frequency varied with different materials.
Affect of radiation intensityThe greater the intensity the greater the number of electrons emitted,but only if the radiation was above the threshold frequency.
Time of emission
Electrons were emitted as soon as the material was exposed.
Maximum kinetic energy of photoelectrons
This depends only on the frequency of the electromagnetic radiationand the material exposed, not on its intensity.
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Problems with the wave theory
Up to the time the photoelectric effect was firstinvestigated it was believed that electromagneticradiation behaved like normal waves.
The wave theory could not be used to explain theobservations of the photoelectric effectin particularwave theory predicted: that there would not be any threshold frequencyall frequencies
of radiation should eventually cause electron emission
that increasing intensity would increase the rate of emission atall frequenciesnot just those above a certain minimum
frequency that emission would not take place immediately upon exposure
the weaker radiations would take longer to produce electrons.
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Photon energy (revision)
photon energy (E) = h x f
where h= the Planckconstant = 6.63 x 10-34Js
also as f = c / ;
E = hc /
Calculate the energy of a photon of ultraviolet light(f = 9.0 x 1014Hz) (h= 6.63 x 10-34Js)
E = h f= (6.63 x 10-34Js) x (9.0 x 1014Hz)
= 5.37 x 10-19J
http://en.wikipedia.org/wiki/Planckhttp://en.wikipedia.org/wiki/Planck -
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The photoelectric equation
hf = + EKmax
where:
hf= energy of the photons of electromagnetic radiation
= work function of the exposed material
EKmax= maximum kinetic energy of the photoelectrons
Work function,This is the minimum energy required for anelectron to escape from the surface of a material
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Threshold frequency f0
As: hf = + EKmax
If the incoming photons are of the thresholdfrequency f0, the electrons will have the minimumenergy required for emission
and EKmaxwill be zero
therefore: hf0=
and so: f0= / h
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Question 1
Calculate the threshold frequency of a metalif the metals work function is 1.2 x 10 -19J.
(h= 6.63 x 10-34Js)
f0= / h
= (1.2 x 10-19J) / (6.63 x 10-34Js)
threshold frequency = 1.81 x 1014Hz
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Question 2
Calculate the maximum kinetic energy of thephotoelectrons emitted from a metal of workfunction 1.5 x 10 -19J when exposed with photonsof frequency 3.0 x 1014Hz.
(h= 6.63 x 10-34Js)
hf = + EKmax(6.63 x 10-34Js) x (3.0 x 1014Hz) = (1.5 x 10-19J) + EKmaxEKmax = 1.989 x 10
-19- 1.5 x 10-19
= 0.489 x 10-19
J
maximum kinetic energy = 4.89 x 10 -20J
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hf = + EKmax
becomes:= hf - EKmax
but: f = c /= (3.0 x 108ms-1) / (2.0 x 10-7m)
= 1.5 x 1015Hz
= hf - EKmax= (6.63 x 10-34x 1.5 x 1015)(1.0 x 10-19)
= (9.945 x 10-19)(1.0 x 10-19)
work function = 8.95 x 10-19J
f0= / h
= 8.95 x 10-19J / 6.63 x 10-34Jsthreshold frequency = 1.35 x 1015Hz
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The vacuum photocell
Light is incident on a metalplate called thephotocathode.
If the lights frequency is
above the metals thresholdfrequency electrons areemitted.
These electrons passingacross the vacuum to the
anode constitute andelectric current which canbe measured by themicroammeter.
The photocell is an applicationof the photoelectric effect
PhetPhotoelectric effect
NTNUPhotoelectric effect
http://phet.colorado.edu/simulations/sims.php?sim=Photoelectric_Effecthttp://phet.colorado.edu/simulations/sims.php?sim=Photoelectric_Effecthttp://phet.colorado.edu/simulations/sims.php?sim=Photoelectric_Effecthttp://www.phy.ntnu.edu.tw/ntnujava/index.php?topic=342.0http://www.phy.ntnu.edu.tw/ntnujava/index.php?topic=342.0http://www.phy.ntnu.edu.tw/ntnujava/index.php?topic=342.0http://www.phy.ntnu.edu.tw/ntnujava/index.php?topic=342.0http://www.phy.ntnu.edu.tw/ntnujava/index.php?topic=342.0http://www.phy.ntnu.edu.tw/ntnujava/index.php?topic=342.0http://www.phy.ntnu.edu.tw/ntnujava/index.php?topic=342.0http://phet.colorado.edu/simulations/sims.php?sim=Photoelectric_Effecthttp://phet.colorado.edu/simulations/sims.php?sim=Photoelectric_Effecthttp://phet.colorado.edu/simulations/sims.php?sim=Photoelectric_Effecthttp://phet.colorado.edu/simulations/sims.php?sim=Photoelectric_Effect -
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Obtaining Plancks constantBy attaching a variable voltagepower supply it is possible tomeasure the maximum kineticenergy of the photoelectronsproduced in the photocell.
The graph opposite shows howthis energy varies with photon
frequency.hf = + EKmax
becomes:
EKmax= hf
which has the form y = mx +c
with gradient, m = hHence Plancks constant can befound.
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Ionisation
An ion is a charged atom Ions are created by adding or
removing electrons from atoms
The diagram shows thecreation of a positive ion fromthe collision of an incoming
electron. Ionisation can also be caused
by:
nuclear radiationalpha, beta,gamma
heating passing an electric current
through a gas (as in afluorescent tube)
incoming electron
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Ionisation energy
Ionisation energy is the energy
required to remove one electron from
an atom.
Ionisation energy is often expressed in eV.
The above defines the FIRST ionisation
energythere are also 2nd, 3rdetc
ionisation energies.
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Question
An electron with 6 x 10-19J of kinetic energy can cause
(a) ionisation or (b) excitation in an atom.
If after each event the electron is left with
(a) 4 x 10-19
J and (b) 5 x 10-19
J kinetic energycalculate in eVthe ionisation and excitation energy of the
atom.
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Question
(a) Ionisation has required6 x 10-19J - 4 x 10-19J of electron ke
= 2 x 10-19J
= 2 x 10-19 /1.6 x 10-19J
ionisation energy = 1.25 eV
(b) Excitation has required
6 x 10-19J - 5 x 10-19J of electron ke
= 1 x 10-19J= 1 x 10-19 /1.6 x 10-19J
excitation energy = 0.625 eV
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Electron energy levels in atoms
Electrons are bound to thenucleus of an atom byelectromagnetic attraction.
A particular electron will occupythe nearest possible position to
the nucleus. This energy level or shell is called
the ground state.
It is also the lowest possibleenergy level for that electron.
Only two electrons can exist inthe lowest possible energy levelat the same time. Furtherelectrons have to occupy higherenergy levels.
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De-excitation
Excited states are usually
very unstable.
Within about 10 - 6 s the
electron will fall back to a
lower energy level.
With each fall in energy
level (level E1down to
level E2) a photon of
electromagnetic radiationis emitted.
em it ted pho ton energy
= hf = E1E2
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Energy level questionCalculate the frequencies of the photonsemitted when an electron falls to the ground
state (at 10.4 eV) from excited states (a) 5.4 eVand (b) 1.8 eV.(h= 6.63 x 10-34Js)
hf = E1E2(a) hf= 5.4 eV10.4 eV
= - 5.0 eV= 5.0 x 1.6 x 10-19J (droppingve sign)
= 8.0 x 10-19J
therefore f= 8.0 x 10-19J / 6.63 x 10-34Js
for -5.4 to -10.4 transition, f= 1.20 x 1015Hz
(b) h f = 1.8 eV10.4 eV)= - 8.6 eV
= 13.8 x 10-19J
therefore f= 13.8 x 10-19J / 6.63 x 10-34Js
for -1.8 to -10.4 transition, f= 2.08 x 1015Hz
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Complete:
transition photon
E1/ eV E2/ eV f/ PHz / nm
5.4 10.4 1.20 250
1.8 10.4 2.08 144
1.8 5.4 0.871 344
1.8 4.5 0.653 459
2501441.8
0.871
4.5
344
0.653
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Excitation using photons
An incoming photon may nothave enough energy to causephotoelectric emission but itmay have enough to causeexcitation.
However, excitation will onlyoccur if the photons energy isexactly equalto the differencein energy of the initial and finalenergy level.
If this is the case the photon willcease to exist once its energy isabsorbed.
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FluorescenceThe diagram shows an incoming
photon of ultraviolet light of energy5.7eV causing excitation.
This excited electron then de-excites intwo steps producing two photons.
The first has energy 0.8eV and will beof visible light. The second of energy4.9eV is of invisible ultraviolet of slightlylower energy and frequency than theoriginal excitating photon.
This overall process explains why
certain substances fluoresce withvisible light when they absorb ultravioletradiation. Applications include thefluorescent chemicals are added aswhiteners to toothpaste and washingpowder.
Electrons can fall back totheir ground states in steps.
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Fluorescent tubes A fluorescent tube consists of a
glass tube filled with lowpressure mercury vapour and aninner coating of a fluorescentchemical.
Ionisation and excitation of the
mercury atoms occurs as thecollide with each other and withelectrons in the tube.
The mercury atoms emitultraviolet photons.
The ultraviolet photons areabsorbed by the atoms of thefluorescent coating, causingexcitation of the atoms.
The coating atoms de-excite andemit visible photons.
See pages 37 and 38 for further
details of the operation of a
fluorescent tube
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Line spectra
A line spectrum is produced from the excitation of a low
pressure gas.
The frequencies of the lines of the spectrum are
characteristic of the element in gaseous form.
Such spectra can be used to identify elements.
Each spectral line corresponds to a particular energy level
transition.
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The hydrogen atom
PhetModels of the hydrogen atom
- 21.8
http://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atom -
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PhetModels of the hydrogen atom
http://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atom -
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With only one electron, hydrogenhas the simplest set of energylevels and corresponding linespectrum.
Transitions down to the loweststate, n=1 in the diagram, give riseto a series of ultraviolet lines calledthe Lyman Series.
Transitions down to the n=2 stategive rise to a series of visible lightlines called the Balmer Series.
Transitions down to the n=3, n=4etc states give rise to sets of infra-red spectral lines.
PhetModels of the hydrogen atom
- 21.8
http://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atom -
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The discovery of helium
Helium was discovered in the Sun before it wasdiscovered on Earth. Its name comes from theGreek word for the Sun helios.
A pattern of lines was observed in the Suns
spectrum that did not correspond to any knownelement of the time.
In the Sun helium has been produced as theresult of the nuclear fusion of hydrogen.
Subsequently helium was discovered on Earthwhere it has been produced as the result ofalpha particle emission from radioactiveelements such as uranium.
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The wave like nature of light
Light undergoes diffraction(shown opposite) and displaysother wave properties such aspolarisation and interference.
By the late 19thcentury mostscientists considered light andother electromagnetic
radiations to be like waterwaves
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The particle like nature of light
Light also producesphotoelectric emissionwhich can only beexplained by treating
light as a stream ofparticles.
These particles withwave properties arecalled photons.
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The dual nature
of electromagnetic radiation Light and other forms of electromagnetic radiation
behave like waves and particles.
On most occasions one set of properties is the mostsignificant
The longer the wavelength of the electromagnetic wavethe more significant are the wave properties.
Radio waves, the longest wavelength, is the mostwavelike.
Gamma radiation is the most particle like Light, of intermediate wavelength, is best considered tobe equally significant in both
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Matter waves
In 1923 de Broglie proposed that particles such aselectrons, protons and atoms also displayed wave likeproperties.
The de Broglie wavelengthof such a particle depended
on its momentum, paccording to the de Broglie relation:= h / p
As momentum = mass x velocity= mv
= h / mv
This shows that the wavelength of a particle can be alteredby changing its velocity.
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Question 1
Calculate the de Broglie wavelength of an electronmoving at 10% of the speed of light. [me= 9.1 x 10
-31kg]
(h= 6.63 x 10-34Js; c= 3.0 x 108ms-1)
v= 10% of c
= 3.0 x 107ms-1
= h / mv
= (6.63 x 10-34Js) / [(9.1 x 10-31kg) x (3.0 x 107ms-1)]
de Broglie wavelength = 2.43 x 10 - 11m
This is similar to the wavelength of X-rays.
Particle properties dominate.
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Question 2
Calculate the de Broglie wavelength of a personof mass 70 kg moving at 2 ms-1.
(h= 6.63 x 10-34Js)
= h / mv= (6.63 x 10-34Js) / [(70 kg) x (2 ms-1)]
de Broglie wavelength = 4.74 x 10 - 36m
This is approximately 1020x smaller than thenucleus of an atom.
Wave like properties can be ignored!
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Question 3
Calculate the effective mass of a photon of redlight of wavelength 700 nm.(h= 6.63 x 10-34Js)
= h / mv
becomes: m = h /v
= (6.63 x 10-34Js) / [(7.0 x 10-7m) x 3.0 x 108ms-1)]
mass = 3.16 x 10 - 36kg
This is approximately 30 000 x smaller than the mass ofan electron.The mass of photons can normally be considered to bezero.
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Evidence for de Broglies hypothesis
A narrow beam of electrons in a vacuum tube is directed at a thinmetal foil. On the far side of the foil a circular diffraction pattern isformed on a fluorescent screen. A pattern that is similar to that formedby X-rays with the same metal foil.
Electrons forming a diffraction pattern like that formed by X-rays
shows that electrons have wave properties.
The radii of the circles can be decreased by increasing the speed ofthe electrons. This is achieved by increasing the potential differenceof the tube.
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Energy levels and electron waves
An electron in an atom hasa fixed amount of energythat depends on the shell itoccupies.
Its de Broglie wavelengthhas to fit the shape and sizeof the shell.
FendtBohr Hydrogen Atom
PhetModels of the hydrogen atom
http://www.walter-fendt.de/ph11e/bohrh.htmhttp://www.walter-fendt.de/ph11e/bohrh.htmhttp://www.walter-fendt.de/ph11e/bohrh.htmhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://phet.colorado.edu/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://www.walter-fendt.de/ph11e/bohrh.htmhttp://www.walter-fendt.de/ph11e/bohrh.htmhttp://www.walter-fendt.de/ph11e/bohrh.htmhttp://www.walter-fendt.de/ph11e/bohrh.htm -
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Internet Links Photoelectric Effect- PhET - See how light knocks electrons off a metal target, and recreate
the experiment that spawned the field of quantum mechanics.
Photoelectric Effect- NTNU
Photoelectric Effect- Fendt
Neon Lights- PhET - Produce light by bombarding atoms with electrons. See how the
characteristic spectra of different elements are produced, and configure your own element's
energy states to produce light of different colours.
Lasers- PhET - Create a laser by pumping the chamber with a photon beam. Manage the
energy states of the laser's atoms to control its output.
Bohr Atom- Fendt
Bohr Atom- 7stones
Quantum Mechanics - A Summary- Powerpoint presentation by Mrs Andrew - July 2004
Models of the Hydrogen Atom- PhET - How did scientists figure out the structure of atoms
without looking at them? Try out different models by shooting photons and alpha particles at
the atom. Check how the prediction of the model matches the experimental results.
Davisson-Germer Electron Diffraction- PhET - Simulate the original experiment that proved
that electrons can behave as waves. Watch electrons diffract off a crystal of atoms, interfering
with themselves to create peaks and troughs of probability.
http://phet.colorado.edu/new/simulations/sims.php?sim=Photoelectric_Effecthttp://subscription.echalk.co.uk/Science/chemistry/atomicStructure/atomicStructure.htmlhttp://www.phy.ntnu.edu.tw/ntnujava/index.php?topic=342.0http://www.walter-fendt.de/ph11e/photoeffect.htmhttp://subscription.echalk.co.uk/Science/chemistry/atomicStructure/atomicStructure.htmlhttp://phet.colorado.edu/new/simulations/sims.php?sim=Neon_Lights_and_Other_Discharge_Lampshttp://subscription.echalk.co.uk/Science/chemistry/atomicStructure/atomicStructure.htmlhttp://phet.colorado.edu/new/simulations/sims.php?sim=Lasershttp://subscription.echalk.co.uk/Science/chemistry/atomicStructure/atomicStructure.htmlhttp://www.walter-fendt.de/ph11e/bohrh.htmhttp://www.7stones.com/Homepage/Publisher/Bohr.htmlhttp://www.ktaggart.com/physics/PowerPoint/QuantumMechanics.ppthttp://subscription.echalk.co.uk/Science/chemistry/atomicStructure/atomicStructure.htmlhttp://phet.colorado.edu/new/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://subscription.echalk.co.uk/Science/chemistry/atomicStructure/atomicStructure.htmlhttp://phet.colorado.edu/new/simulations/sims.php?sim=DavissonGermer_Electron_Diffractionhttp://phet.colorado.edu/new/simulations/sims.php?sim=DavissonGermer_Electron_Diffractionhttp://phet.colorado.edu/new/simulations/sims.php?sim=DavissonGermer_Electron_Diffractionhttp://phet.colorado.edu/new/simulations/sims.php?sim=DavissonGermer_Electron_Diffractionhttp://subscription.echalk.co.uk/Science/chemistry/atomicStructure/atomicStructure.htmlhttp://phet.colorado.edu/new/simulations/sims.php?sim=Models_of_the_Hydrogen_Atomhttp://subscription.echalk.co.uk/Science/chemistry/atomicStructure/atomicStructure.htmlhttp://www.ktaggart.com/physics/PowerPoint/QuantumMechanics.ppthttp://www.ktaggart.com/physics/PowerPoint/QuantumMechanics.ppthttp://www.ktaggart.com/physics/PowerPoint/QuantumMechanics.ppthttp://www.ktaggart.com/physics/PowerPoint/QuantumMechanics.ppthttp://www.ktaggart.com/physics/PowerPoint/QuantumMechanics.ppthttp://www.7stones.com/Homepage/Publisher/Bohr.htmlhttp://www.7stones.com/Homepage/Publisher/Bohr.htmlhttp://www.walter-fendt.de/ph11e/bohrh.htmhttp://subscription.echalk.co.uk/Science/chemistry/atomicStructure/atomicStructure.htmlhttp://phet.colorado.edu/new/simulations/sims.php?sim=Lasershttp://subscription.echalk.co.uk/Science/chemistry/atomicStructure/atomicStructure.htmlhttp://phet.colorado.edu/new/simulations/sims.php?sim=Neon_Lights_and_Other_Discharge_Lampshttp://subscription.echalk.co.uk/Science/chemistry/atomicStructure/atomicStructure.htmlhttp://www.walter-fendt.de/ph11e/photoeffect.htmhttp://www.walter-fendt.de/ph11e/photoeffect.htmhttp://www.phy.ntnu.edu.tw/ntnujava/index.php?topic=342.0http://subscription.echalk.co.uk/Science/chemistry/atomicStructure/atomicStructure.htmlhttp://phet.colorado.edu/new/simulations/sims.php?sim=Photoelectric_Effect -
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3.1 Photoelectricity
Notes from Breithaupt pages 30 & 31
1. What is the photoelectric effect?2. Explain how the observations made from photoelectric
experiments contradict the wave theory of electromagneticradiation.
3. Show how the photoelectric equation, hf = Ekmax+ , follows fromEinsteins explanation of the photoelectric effect.
4. Define: (a) threshold frequency (b) work function. Give therelationship between these two quantities.
5. A metal emits photoelectrons with a maximum kinetic energy of2.0 x 10-19J when exposed with photons of wavelength 300 nm.Calculate the work function and threshold frequency of the metal.
6. Try the summary questions on page 31
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3.3 Collisions of electrons with atoms
Notes from Breithaupt pages 34 & 35
1. Define what is meant by ionisation and list the variousways in which ionisation may occur.
2. Define the electron-volt.
3. What is excitation? Why are all the excitation energies
of a particular atom less than its ionisation energy?
4. Describe how ionisation energy can be measured.
5. Try the summary questions on page 35
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3.4 Energy levels in atoms
Notes from Breithaupt pages 36 to 38
1. Copy figure 1 on page 36 and define what is meant by (a) groundstate and (b) excited state
2. Explain the process of de-excitation showing how the energy andfrequency of emitted photons is related to energy level changes.
3. What condition must be satisfied for a photon to cause excitation?
4. What is fluorescence? Explain how this occurs in terms of energylevel transitions.
5. Explain how the processes of ionization and excitation occur in afluorescent tube.
6. Explain the operation of a fluorescent tube.
7. Try the summary questions on page 38
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3.5 Energy levels and spectra
Notes from Breithaupt pages 39 & 40
1. What is a line spectrum? Draw a diagram.
2. Explain how line spectra are produced.
3. Calculate the wavelength of the spectral line produced
by the energy level transition from6.4eV to15.2eV.4. Use the equation on page 40 to work out (in eV) the
first four energy levels of a hydrogen atom.
5. Explain how Helium was first discovered.
6. Try the summary questions on page 40
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3.6 Wave particle duality
Notes from Breithaupt pages 41 to 43
1. What observations indicate that light behaves as (a) awave? (b) a particle?
2. What are matter waves? State the de Broglie relation.
3. What evidence is there of the wave nature of particles?
4. Show that electrons moving at 50% of the speed oflight have a de Broglie wavelength similar to that of X-rays.
5. How do the energy levels in atoms tie up with the wave
like properties of electrons?6. Try the summary questions on page 43