asp g90 and asp - basf kaolin asp g90-g92 sellsheet.pdf · asp® g90 and asp ® g92 are microfine...
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At BASF, we nurture the seeds of
ingenuity. You’ll find it in how we apply
our expertise in surface and materials
science to an exhaust stream to
deliver cleaner air, or to crude oil to
transform it into gasoline. And our
ingenuity in performance minerals gives manufacturers the
edge they need in today’s competitive markets.
BASF is a recognized leader in the development and
manufacture of high quality mineral products for the paint
and coatings industry. Our surface and materials science
expertise has led to the development of a family of products
that improve performance and lower cost. These products
include Mattex® and Mattex® MX extenders, Ultrex® 98
kaolin, Satintone® kaolins and ASP® grades, as well as
Attagel® thickeners and Alsibronz® micas. Now, ASP® G90
and ASP® G92 high gloss kaolins join this list as two more
examples of how BASF products can cost-effectively
improve the performance and appearance of paints
and coatings.
ASP® G90 & ASP® G92high gloss kaolins feature:■ Up to 10% TiO2 reduction at equal opacity for
reduced total formula cost
■ Superior gloss and less haze compared with
competitive kaolin products
■ Lower cost and reduced VOC through resin reduction
■ Improved optical properties versus other competitive
kaolin products
■ Ease of dispersion
■ Better dry handling and less dusting
■ Improved mar and scuff resistance with excellent
clarity in clear varnish systems
ASP® G90 and ASP® G92High gloss kaolins
Product descriptionASP® G90 and ASP® G92 are
microfine particle size hydrous kaolins
produced by an innovative technology
developed by BASF and covered by
BASF US Patent Application
Publication 2006/0047047. This new technology produces
a very fine particle size product with a narrow particle size
distribution that provides high gloss and optical properties
that are superior to competitive kaolin products. ASP G90
high gloss kaolin is pulverized to provide ease of dispersion,
high Hegman grind and TiO2 extension in architectural and
industrial coatings. ASP G92 provides the same performance
in water-borne systems only and is available in spray-dried
bead form for easier handling and less dusting.
Application informationASP G90 high gloss kaolin is designed for use in architectural
and industrial, water-borne and solvent-borne gloss and
semigloss coatings. ASP G90 can also be used to provide
mar and scuff resistance in clear coat
varnishes without affecting clarity. ASP
G92 is specially designed for a broad
range of water-borne paints and
coatings.
Typical properties ASP® G90 ASP® G92
Physical form Highly pulverized powder Spray-dried bead
GE brightness (%) 90 min 90 min
Screen residue, 325 mesh (%) 0.01 0.01
Free moisture @ 105 deg C (%) as produced 1.0 max 1.0 max
pH (28% solids) 7 7
Specific gravity (g/cm3) 2.58 2.58
Avg. stokes equivalent particle diameter (µm) 0.18 0.18
Bulk density, loose (lbs/ft3 / kg/m3) 13 / 210 44/700
Bulk density, tamped (lbs/ft3 / kg/m3) 18 / 290 58/930
Oil absorption, rubout (ASTM D-281) 47 47
Hegman grind in organic 6.5 min NA
Hegman grind in water 6.5 min 6.5 min
Refractive index 1.56 1.56
Bulking value, lbs. per gal. / kgs. per liter 21.5 / 2.59 21.5/2.59
Interior semigloss latex paint with ASP® G90& ASP® G92 exhibit:■ 10% TiO2 reduction
■ Higher gloss than TiO2 and competitive kaolin
■ Significant cost savings
■ Improved opacity versus competitive gloss kaolin
With ASP® G90 and ASP® G92 high
gloss kaolins, TiO2 loadings were
reduced 10% while maintaining
opacity and gloss versus the control
for overall cost savings. Compared
to the competitive glossing kaolin
product most commonly used in the industry, ASP G90
and ASP G92 provide better opacity (see Chart 1) and
significantly better 20˚ and 60˚ gloss (see Charts 2 and 3).
In addition, ASP G92 in spray-dried bead form is easier to
handle with less dusting.
Chart 1 – Opacity
98.9
98.8
98.7
98.6
98.5
98.4
98.3
C. ratio 3 mils Control 100% TiO2 ASP® G90 less 10% TiO2
Comp. A less 10% TiO2ASP® G92 less 10% TiO2
98.8
98.7 98.7
98.5
Chart 2 – 20 degree gloss data
25
20
15
10
5
0
Control 100% TiO2 ASP® G90 less 10% TiO2
Comp. A less 10% TiO2ASP® G92 less 10% TiO2
22 23 23
14
Chart 3 – 60 degree gloss data
666462605856545250
Control 100% TiO2 ASP® G90 less 10% TiO2
Comp. A less 10% TiO2ASP® G92 less 10% TiO2
6465 65
55
Low VOC interior semigloss vinyl acrylic formulation: 22 PVC
Raw material Control 100% Less 10% TiO2
TiO2Amount by kaolin volume
#/100 gal. Amount #/100 gal.
Water 150.0 150.0
KTPP 1.0 1.0
Kathon® LX 1 1.5 1.5
Natrosol® Plus 330 2 1.0 1.0
Tamol™ 1124 1 5.0 5.0
Pluracoat™ CF 10 6 3.0 3.0
AMP-95™ 3 2.0 2.0
Rhodoline® 643 4 1.0 1.0
Mix for 2 min., then add
TiO2 - Tronox® CR 828 5 250.0 225.0
Glossing Kaolin 0.0 16.1
Attagel® 50 6 5.0 5.0
Grind 6 - 7, then add
Water 113.1 113.1
UCAR™ 300 3 500.0 500.0
STRODEX™ PK 90 7 2.0 2.0
Ammonia 2.5 2.5
UCAR PHOLYPHOBE™ 116 3 1.0 1.0
UCAR POLYPHOBE™ 117 3 18.0 18.0
Rhodoline® 643 4 2.0 2.0
Total 1058.1 1049.2
Typical cost savings/100 gal. NA $20.00
Water-reducible alkyd high gloss enamelwith ASP® G90 exhibits:■ Higher gloss
■ Better opacity
■ Potential resin extension at equal gloss
ASP G90 high gloss kaolin was used
as a TiO2 extender in this water
reducible high gloss enamel without
affecting gloss. In the same formulation,
ASP G90 provides better opacity
(see Chart 4) and superior gloss (see
Charts 5 and 6) versus the competitive glossing kaolin.
Chart 4 – Opacity vs. Competitor A
9392.892.692.492.29291.891.691.491.291
C. ratio 3 mils ASP® G90 Competitor A
92.3
91.9
Chart 5 – 20 degree gloss data
43
41
39
37
35
33
31
29
27
25
ASP® G90 Competitor A
42
31
Chart 6 – 60 degree gloss data
81
79
77
75
73
71
69
67
65
ASP® G90 Competitor A
79
75
Water-reducible alkyd high gloss enamel formulation: 16 PVC
Raw material Amount #/100 gal.
Beckosol® 10-060 8 (70%) 72.0
Mineral Spirits 9.3
Bentone® SD-1 9 1.5
Mix well then add
Lorama16 LDA 100 2.0
TiO2 Ti-Pure® R 706 10 110.0
ASP® G90 6/Competitor A 15.0
Grind to 7, then add
Beckosol® 10-060 8 (70%) 44.5
Mineral Spirits 18.0
Mix well, then add
Beckosol® 10-060 8 (70%) 130.0
Mineral Spirits 92.4
Cobalt Octoate 12% 1.0
Zirconium Octoate 12% 4.0
Exkin® No. 2 11 1.0
Mix well, then add under agitation
Lorama16 LPR 76, 40.0Polysaccharide Resin 44%
Water 344.3
Total 888.0
Interior/exterior styrene acrylic gloss enamelwith ASP® G92 exhibits:■ Significantly higher gloss
■ Equal opacity
■ Potential resin extension at equal gloss
■ Total cost savings
■ Better dry handling and less dusting with ASP G92
ASP G92 high gloss kaolin helps
lower total cost by providing up to
10% TiO2 reduction in this interior/
exterior latex gloss formulation,
significantly improving gloss while
maintaining opacity. (see Charts 7, 8
and 9). In addition, ASP G92 is available in spray dried
bead form for better dry handling and less dusting.
Chart 7 – Opacity
98.598.498.398.298.19897.997.897.797.697.5
C. ratio 3 mils Control 100% TiO2 ASP® G92 less 10% TiO2
98.398.2
Chart 8 – 20 degree gloss data
55545352515049484746454443424140
Control 100% TiO2 ASP® G92 less 10% TiO2
43
52
Chart 9 – 60 degree gloss data
8583817977757371696765
Control 100% TiO2 ASP® G92 less 10% TiO2
73
79
Low VOC interior/exterior acrylic gloss enamel formulation: 18.7 PVC VOC < 100 g/l
Raw material Control 100% Less 10% TiO2
TiO2Amount by ASP® G92 Vol.
#/100 gal. Amount #/100 gal.Water 62.6 62.6Kathon® LX 1 1.5% 1.6 2.0Tamol™ 1124 1 5.5 5.5Surfynol® 104E 12 1.0 1.0Igepal® CTA-639W 4 1.0 1.0BYK® 022 13 1.0 1.0Mix for 2 min, then addTiO2 - Ti-Pure® R 706 10 225.0 202.5ASP® G92 6 0.0 14.5Grind 6 - 7, then addPropylene Glycol 30.3 30.3Rhoplex® HG-700 1 618.1 618.1Water 21.5 21.5Texanol® 14 21.5 21.5Triton™ X 405 3 3.5 3.5Ammonia 1.0 1.0Premix last three ingredients, then addWater 22.0 22.0Acrysol® RM 5 1 22.0 22.0BYK® 024 13 2.0 2.0Total 1039.5 1031.5Typical cost savings/100 gal. NA $18.00
Interior/exterior 100% acrylic semiglosspaint with ASP® G92 exhibits:■ 10% TiO2 reduction
■ Total cost savings
■ Improved gloss
■ Equal opacity
■ Better dry handling and less dusting with ASP G92
ASP G92 high gloss kaolin provides
improved gloss, while maintaining
opacity for total cost savings in this
100% acrylic semigloss paint.
(see Charts 10, 11 and 12).
Chart 10 – Opacity vs. control
98.598.498.398.298.19897.997.897.797.697.5
C. ratio 3 mils Control 100% TiO2 ASP® G92 less 10% TiO2
98.398.2
Chart 11 – 20 degree gloss data
39
37
35
33
31
29
27
25
Control 100% TiO2 ASP® G92 less 10% TiO2
32
35
Chart 12 – 60 degree gloss data
75747372717069686766656463626160
Control 100% TiO2 ASP® G92 less 10% TiO2
69
72
Interior/exterior 100% acrylic semigloss formulation, 23 PVC
Raw material Control 100% Less 10% TiO2
TiO2Amount by ASP® G92 Vol.
#/100 gal. Amount #/100 gal.
Water 20.0 20.0
Kathon® LX 1 2.0 2.0
Tamol™ SG-1 1 8.0 8.0
Igepal® 639A 4 2.0 2.0
Propylene Glycol 60.0 60.0
Acrysol® RM 825 1 0.5 0.5
BYK® 022 13 1.0 1.0
TiO2 Ti-Pure® R706 10 263.0 225.0
ASP® G92 6 0.0 24.5
Grind to 6, then add
Water 160.7 160.7
Rhoplex® SG-10M 1 489.2 489.2
Texanol® 14 24.5 24.5
Acrysol® RM 8W 1 16.0 16.0
Colloid 640 3.0 3.0
Total 1049.9 1036.3
Typical cost savings/100 gal. NA $32.00
Solvent-borne clear varnish with ASP® G90exhibits:■ Improved mar and scuff resistance
■ Improved chemical resistance
■ Excellent clarity
■ Better gloss than the competitive gloss kaolin
Historically, kaolins have not typically
been used in clear varnish coats due
to their adverse effect on clarity.
However, because of its microfine
particle size and very narrow particle
size distribution, ASP G90 high gloss
kaolin is recommended for use in clear varnish industrial
applications for improved abrasion, mar and scuff resistance
while maintaining excellent clarity. ASP G90 provides higher
gloss (see Charts 13 and 14) compared with the competitive
kaolin in this solvent-borne clear varnish formula.
Solvent-borne clear varnish formulation
Raw material Amount #/100 gal.
Amberlac® 3704-V-60 8 153.8
Mineral Spirits 36.4
Tixogel® VP 15 8.0
Ethanol 3.0
Mix until smooth
Lecithin 5.0
Rhodafac® LO 529 4 2.0
Anti-Float Powder 6.0
ASP® G90 6/Competitor B 40.0
BYK® 370 13 1.0
Grind to 7 Hegman, then add
Amberlac® 3704-V-60 8 380.0
VM&P 62.0
Cobalt 12% 1.0
Zirco 24% 3.0
Exkin® No. 2 11 1.0
Hold for viscosity
VM&P 56.0
Total 755.2
Chart 13 – 20 degree gloss data
70
68
66
64
62
60
Competitor B ASP® G90
64
70Chart 14 – 60 degree gloss data
95
90
85
80
9093
Competitor BASP® G90
Contact us today to learn how BASF’s performance
minerals can help you get the competitive edge.
Just call customer support 800-781-8966 or
973-245-7444.
About BASFBASF is the world’s leading chemical company: The
Chemical Company. Its portfolio ranges from chemicals,
plastics, performance products, agricultural products and
fine chemicals to crude oil and natural gas. As a reliable
partner to virtually all industries, BASF’s high-value products
and intelligent system solutions help its customers to be
more successful. BASF develops new technologies and
uses them to meet the challenges of the future and open
up additional market opportunities. It combines economic
success with environmental protection and social responsibility,
thus contributing to a better future.
Registered trademark information:1 Kathon, Rhoplex, Acrysol are registered trademarks of Rohm and Haas Tamol is a trademark of
Rohm and Haas2 Natrosol is a registered trademark of Hercules, Aqualon Division3 AMP-95, UCAR, UCAR POLYPHOBE are trademarks of Dow Chemical Company4 Rhodoline, Igepal, Rhodafac are registered trademarks of Rhodia5 Tronox is a registered trademark of Kerr McGee Chemical LLC6 Pluracoat, Attagel, ASP are registered trademarks of BASF Catalysts LLC7 STRODEX is a registered trademark of Dexter Chemical LLC8 Beckosol, Amberlac are registered trademarks of REICHOLD9 Bentone is a registered trademark of ELEMENTIS SPECIALTIES
10 Ti-Pure is a registered trademark of DuPont11 Exkin is a registered trademark of CONDEA Servo12 Surfynol is a registered trademark of AIR PRODUCTS13 BYK is a registered trademark of BYK Chemie14 Texanol is a registered trademark of Eastman Chemical15 Tixogel is a registered trademark of SUD-CHEMIE16 Lorama is a registered trademark of Lorama Chemicals
BASF Catalysts LLC100 Campus DriveFlorham Park, NJ 07932Tel: 800-781-8966 or 973-245-7444 Fax: 800-781-8953 or 864-332-5084Web: www.basf-corp.com
All trademarks are the property of BASF AG, BASF Corporation, or BASF Catalysts LLC
Although all statements and information in this publication are believed to be accurate and reliable, they are presented gratis and for guidance only, and risks and liability for resultsobtained by use of the products or application of the suggestions described are assumed by the user. THERE ARE NO WARRANTIES OF ANY KIND. ALL EXPRESS AND IMPLIEDWARRANTIES ARE DISCLAIMED. Statements or suggestions concerning possible use of the products are made without representation or warranty that any such use is free ofpatent infringement and are not recommendations to infringe any patent. The user should not assume that toxicity data and safety measures are indicated or that other measuresmay not be required.
©2007 BASF Catalysts LLC BF-8315