b. hilton - alstom ccs portfolio and cost analysis
TRANSCRIPT
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Robert G. Hilton
June 18. 2013
Alstom CCS Portfolio and CostAnalysis
RECS- Research Experience in
Carbon Sequestration, Birmingham,AL
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Equipment & services for powergeneration
Alstom Thermal PowerEquipment & services for rail transport
Alstom Transport
Three main activities in 4 sectors*
Equipment & services for powertransmissionAlstom GridAlstom Renewable Power
* Organisation as of 4 July 2011Alstom CO2 Capture Systems - P 2
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
CO2 capture technologiesInitially developed for CCS on Power Generation
Source: Vattenfall
Pre-combustion(New only)
Power Plant with CO2 capture
Post-combustion Oxy-combustion(New + retrofit) (New + retrofit)
Alstom CO2 Capture Systems - P 3
Alstom focuses on post and oxy to also address installedbase
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Technologies developed by Alstom
CO2 capture technologies pursued by Alstom
Post-combustion Oxy-combustion(New + retrofit) (New + retrofit)
Advanced Amines Process Chilled Ammonia Process Oxy-combustion with ASU
Alstom CO2 Capture Systems - P 4
Regenerative Calcium Cycle(RCC)
Chemical Looping Combustion(CLC)
2ndGeneration
2ndGeneration
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
CO2-EOR
Carbonates
Methanol
Urea
Underground
permanent
Storage
Food industry
CO2capture unit
Industrial fluegas with CO2:
Power Steel mill Cement factory Refinery Methanol
plant, Ethanol plant Fertilizer plant etc
Classic CCS(Saline Aquifers ordepleted Oil & Gasfields)
CCU Chemicalusage
Current prospectsin Fertilizer andcarbonates
CO2-EOR : hugepotential in the USA
CO2 utilizationCaptured CO2 for EOR or Chemical Production
CCU and EOR can stimulate CO2 capture market through valuation of CO2
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Advanced Amine ProcessTechnology Overview
Advantages
Proven in natural gas & syngaspurification
CO2 capture from flue gas is a newapplication
More efficient capture of CO2 and lesssolvent degradation than MEA
Higher tolerance against oxygen & tracecontaminants
Source: Alstom
Principle
An amine based solvent reacts with theCO2 in the flue gas
Raising the temperature reverses thisreaction, the CO2 is released and the
solvent recycled
A strong team to develop a new application
Alstom CO2 Capture Systems - P 6
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Pilot CommercialIndustrial / ValidationLarge-scale
demonstration
University of TexasUSA
2007 2009 2011
Advanced Amine ProcessUpdate on Alstom roadmap
Dow Chemical Co.USA - 2MWth, Coal
EdF Le HavreFrance - 5 MWth,Coal
Tests completedIn operation
Moving forward to scale-up the technologyAlstom CO2 Capture Systems - P 7
2020 &
beyond
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Advanced Amine ProcessC2A2Field Pilot - Le Havre (France)
Designed to capture 25 t CO2/ day,90% CO2 capture
Advanced flow scheme & operationvalidation
Flue gas: slipstream from 600 MWecoal plant (EdF host facility)
French funding by ADEME Project schedule
- Overall 2010-2013 program- Now in commissioning / start-up- Test from Q1 13 to Q1 14 (1
year)
Alstom CO2 Capture Systems - P 9
EdF Le Havre coal power plant(field pilot represented in
orange)
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Principle
Ammonium carbonate solution reacts withCO2 of cooled flue gas to form ammoniumbicarbonate
Raising the temperature reverses thisreaction, pressurized CO2 is released, thesolution is recycled
Chilled Ammonia ProcessTechnology Overview
Advantages
High CO2 purity Tolerant to oxygen and flue gas
impurities Stable reagent, no degradation nor
emission of trace contaminants
Low-cost, globally available reagentAlstom CO2 Capture Systems - P 10
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Roadmap to commercialization
Test Rigs ValidationPilots
CommercialIndustrialPilots
Large-scaledemonstration
Alstom
Vaxj
Sweden0.25 MWth
We Energies
Pleasant PrairieUSA - 5 MWth, Coal
EoN KarlshamnSweden - 5 MWth, Oil
AEP MountaineerUSA - 58 MWth, Coal
TCM MongstadNorway - 40 MWth, Gas
Getica Turceni FeasibilityRomania - >250 MWe net, Lignite
2006 2008 2009
Testssuc
cessful
Tests completed Key TargetsIn Operation
Chilled Ammonia ProcessUpdate on Alstom roadmap
CO2 Capture Mongstad (CCM)Norway- 280 MWe + 350 MWth,CCPP
Alstom CO2 Capture Systems - P 11
2020 &beyond
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Chilled Ammonia ProcessWe Energies Field Pilot Pleasant Prairie (WI, USA)
Operational June 2008 Oct 2009 7700+ hours of operation on flue gas
from PRB Coal through completion ofprogram in Oct 2009
Proof of Concept technology validation:90% CO2 capture efficiencyNH3 slip from DCC2 (~5 ppm)99+% CO2 purity; >10 ppm NH3;
>2,000 ppm H2O
Functional unit operationsConfirmation of process design toolsConfirmation of equipment design
methodsCO2 Field Pilot at Pleasant
Prairie
Alstom CO2 Capture Systems - P 12
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Chilled Ammonia ProcessField Pilot - Karlshamn (Sweden)
Designed to capture over 1,600 kg CO2/hr(~15,000 tonnes/yr at full capacity)
Operational Apr 2009 Test phase completed in 2010 Flue gases from sulfur fuel oil and from gas
combustion tested Located less than 60 miles (90 km) from
Alstoms Global Technology Center in Vaxjo
Proof of Concept technology validation:- 90% CO2 capture efficiency- NH
3slip from DCC2 (~5 ppm)
- 99+% CO2 purity;
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Designed to capture & store 100,000 tCO2/year Commenced engineering and permitting Oct07 First CO2 captured in Sept 09, Captured CO2 sequestered into through two wells on
the plant property, first injection started 1st of
October 2009Alstom responsible for CAP island (others by AEP) Test completed and succesful:
Approx 52000 tons of CO2 capturedApprox 37000 tons of CO2 storedCO2 product quality : 99.94%Capture rate: 90% validatedLow ammonia emissions observed
Chilled Ammonia ProcessValidation Pilot - AEP Mountaineer (WV, USA)
Alstoms Chilled Ammonia Process atAEPs PPTests completed - Technology validated Ready for scale-up
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Chilled Ammonia ProcessDemonstration project at Turceni
Integrated CCS demo: 1.5 Mtpa CO2 Capture: 85% minimum capture Transport: onshore pipeline Storage: deep saline aquifers (>800m) within
a radius of 50 km
Developers-Operators: Capture: Turceni Energy Complex Transport: Transgaz Storage: Romgaz
Technical Consortium: Project Management and Technical &
Financial Consultant: ISPE (Institute forStudies and Power Engineering)
Capture Plant: Alstom Storage: GeoEcoMar, Schlumberger
Alstom feasibility study completedTurceni Power Plant4x330 MW
Alstom CO2 Capture Systems - P 15
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
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LTS USC PC Power Plant with CAP PCCPlot Plan
LTS CAP PCC Plant Area
CO2 RegenerationArea
Back-PressureTurbine
EvaporativeCondenser
Flue Gas Cooling &CO2 AbsorptionArea
CO2 Compression
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
CCS on GasPost-combustion CO2 Capture solution for Combined Cycles
Gas-fired power plants with CCS - 6/27/13 - P 17
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
European CO2 Technology Centre Mongstad(TCM)
Flue gases from natural gas-fired CCPP anda catalytic cracker (refinery)
Designed to capture 80 000 tons CO2/year Cold commissioning initiated on some
systems that are mechanically complete
Currently in commissioning / start-up phase
CCS DevelopmentsCAP on Gas Validation Pilot Mongstadt, Norway 54 MWth
Gas-fired power plants with CCS - 6/27/13 - P 18
Post-combustion CO2 capture (Chilled Ammonia) technology
validation on-going for application to gas-fired power plants
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
European CO2 Technology Centre Mongstad NorwayChilled Ammonia Process
Unique Validation Features / Expectations Main validation facility for CO2 Capture
Mongstad
CO2 Sources: Flue gases from natural gas CHP plant Off-gases from the RCC
Validation plant, designed to capture: 80 ktons CO2/year (RCC) & 22 ktons CO2/year
(CHP)
First CAP pilot on industrial source Incorporation of know how from previous pilots Compact and efficient layout (1300 m2) Commissioning performed Testing on-going
Mongstad supports CAP validation on gas & industrialAlstom CO2 Capture Systems - P 19
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Conservative assumption based on today's CCStechnology and fully independent, not integrated auxiliary
system
Power Island
Additional cooling towers for CCS plant
Cooler / Blower
CO2 Capture Plant
ColumnAbsorption
ColumnRegeneration
FGR loop
CCS on GasCapture Ready: KA26 plant arrangement example
Gas-fired power plants with CCS - 6/27/13 - P 20
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Oxy-Combustion ProcessTechnology Overview
Advantages ReliabilityAdaptable to all boiler types and fuels Rapid scale-up to 1,000 MWe range Offers options for operational
flexibility Retrofit in Oxy can be addressed Higher efficiency with supercritical/
ultra-supercritical cycles
Principle
Fuel is burned in a mixture of oxygen and re-circulated flue-gas. Due to the absenceof Nitrogen, the resulting flue gas is enriched in CO2
After water condensing and further purification, CO2 is compressed and send tostorage
Alstom CO2 Capture Systems - P 21
A robust and competitive solution
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Moving forward to scale-up the technology
Oxy-Combustion ProcessUpdate on Alstom roadmap
Alstom CO2 Capture Systems - P 22
Targeted
Commercial
2020 &beyond
White Rose 426MWe g - Selby(UK)
1990s
R&D and Labscale Large scaledemonstration
Inoperation
Alstom BSFUSA - 15 MWth,
VattenfallSchwarze PumpeGermany - 30 MWth,
Total LacqFrance - 30 MWth,
GPU mobile pilot
Pilots
2008 2012
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
(source: Vattenfall)Schwarze Pumpe Pilot
Oxy-Combustion ProcessVattenfall Schwarze Pumpe 30 MWth pilot
Experience makes successpossible
Objective
Demonstration of the technology pathat pilot scale
Alstom-Scope
Oxy-boiler, ESP and othercomponents
Technology Partnership withVattenfall
Status of Operation Start of operation: Sept 2008 Test with Alstom Burners completed
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Main features
Retrofit to oxy-combustion of a 30 MWthexisting boiler (natural gas)
Located in SW of France Oxy-combustion process started Jul 09 End test expected end 2012 (18 mths
extension of the original programme)
Approx 120,000 t CO2 to be stored in adepleted gas field
ALSTOM scope : Boiler retrofit30 MWt retrofitted Boiler Lacq,
France
(source: Total)
First fully integrated CCS with pipeline transportation &storage
Oxy-Combustion ProcessTOTAL Lacq - 30 MWth Pilot
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
15 MWth Boiler SimulationFacility : multi-burner,tangentially-fired
Flexible operatingconditions :Air & oxy-firing, gas recycleconfiguration, oxygeninjection, firing system design
Generation ofdetaileddesign and performance
data : Combustion,emissions, heat transfer, ashdeposition, corrosion;
Project start : 2008,Duration : 5 years
Project Team:Alstom, DOE NETL, ICCI NDIC
Utility Advisory Group :
Oxy-Combustion ProcessAlstom Windsor 15 MW Pilot
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Oxy-Combustion ProcessGPU Pilot Tests in Alstoms CCS test centers
FTIRGas
Analysis
Controlroom
GPU in Windsor
GPU at the CCS test center Vaxjo
PurificationPilot
CompressionPilotVxj (Sweden) : synthetic gas test
program
Drying and cryogenic-purification Behaviour of SOx and NOx during
compression Dryer operation and desiccant and
regeneration
Mobile GPU Pilot in operation since2011
Windsor (CT-US) : coal & synthetic flue gastests
Drying, Ash, Hg and other heavy metals,VOC and cryogenic-purification
Behaviour of SOx and NOx duringcompression
Co-adsorption behaviour of SOx and NOx indesiccant and regenerationGPU pilot : an extensive validation programme
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Oxy-Combustion ProcessThe White Rose large scale OXY-Demo project, UK
Largest Oxyfuel CCS Demo
A new modern ultra-supercritical426MWe Gross Oxy-fuel Power Plant
Clean power generation with theentire flue gas treated to capture 2Million t/y CO2
Biomass co-firing option leading tozero (or negative!) CO2 emissions
Anchor project for National Grids(NG) regional CO2 transport &
offshore storage network Project development activities on-
going
Selected as one of the two preferredbidders for a FEED study under theUK CCS competition (1 Billion GBP
funding).
Location: DraxPower Station,
North Yorkshire,UK
Project Promoters
Oxy-fuel Power Plant CO2 Transport& Storage
ALSTOM DRAX NATIONAL GRIDBOC-Linde
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
CCS-evaluation of 2nd generation technologiesChemical Looping Combustion (CLC)
A promising breakthrough technology
Advantages
Potential for low CoE and low energypenalty by limiting the cryogenic ASU of 1stgeneration oxy process;
Development from Alstoms CFBexperience.
Principle OPERATION IN OXY-COMBUSTION Combustion occurs in an atmosphere free of nitrogen. In the Air Reactor, a solid carrier
absorbs oxygen from the air and is conveyed to the Fuel Reactor where the oxygen isreleased and combustion with the fuel occurs. Solid carrier is then taken back to the AirReactor, closing the loop.
Oxygen carriers can be metal oxide or limestone-based. Alstom works on both types.
Status 2 pilots in operation :
1 MWt (CLAIR in DarmstadtUniversity-Germany-RFCS funding) 3 MWt (Alstom Lab Windsor CT
sponsored by US DoE)
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
CCS-evaluation of 2nd generation technologiesRegenerative Calcium Cycle (RCC)
A new post-combustion system with potential for Power andIndustry
Advantages Promising energy penalty and CoE; RCC produces Power : no loss of net electrical output (value for retrofit and industry) Widely used feedstock, potential synergies with industries like cement).
Principle A POST-COMBUSTION SYSTEM In the Carbonator, CO2 from the flue gas reacts with lime (CaO) forming limestone. In the
Calciner, limestone is converted into lime and CO2, pure CO2 can then be easily captured;
Status 1 pilots in operation : 1 MWt (LISA in Darmstadt University-Germany-RFCS funding)
CARBONATOR
CaO + CO2 CaCO3
CALCINER
CaCO3 CaO + CO2
CO2-lean flue gasPure CO2 +
H2OMake-up CaCO3
(limestone)
Coal
Pure O2
CaOdeactivated lime
CaCO3
CaO
Flue gas from powerplant or industry
Lime is taken back to thecarbonator, closing theloop.
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
CompletedTESTS COMPLETE
AEP MountaineerUSA 58 MWthChilled Ammonia, Coal
EoN KarlshamnSweden - 5 MWthChilled Ammonia, Fuel
WE - Energie
USA WI - 5 MWthChilled Ammonia, Coal
DOW Chemical Co.USA, WV
Adv. Amines - Coal
CCS is happening
OPERATING
Vattenfall SchwarzePumpe, Germany30 MWth, Oxy - Lignite
Total LacqFrance - 30 MWthOxy - Gas
Alstom BSF Windsor
US - 15 MWthOxy - Coals
2nd Gen
DOE/Alstom WindsorUS - 3 MWthChemical Looping, Coal
Alstom Labs Vxj
Sweden 0.25 MWthPost C.-multi purpose
RFCS EU - DarmstadtGermany - 1 MWthChemical Looping - Coal
2nd Gen
TCM Mongstad Norway40 MWth, Chilled Ammonia,CHP & Refinery Offgas (RCC)
Alstom GPU Pilot (Mobile)0.3 MWth
OPERATING COMMISSIONING
EDF Le HavreFrance - 5 MWth Adv.
Adv. Amines - Coal
LARGE-SCALE PROJECTS(under development)
White Rose CCS ProjectUK - 426 MWeOxy Hardcoal
CCM Mongstad(Gas Turbine based CHP)Norway 280 MWe + 350 M WthChilled Ammonia
Getica - CET TurceniRomania - >250 MWeChilled Ammonia-Lignite
CCS : a competitive clean power option February 11th, 2012 - P 30
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
CCS experience: 16 pilots/demos
Component manufacturer
Alstom know-how for a solidCoE study on CCS PP
IntroductionAlstom Cost of Electricity study on CCS
Plant integration experience(supply of turnkey power plants)Tests complete
VattenfallSchwarze-
Pumpe Germany-30 MWthOxy- Lig nite
Dow ChemicalCo.
US-2MWth
Adv.Amines- coal
Datang- ChinaOxy 350 MWelignite,
Post 350 MWeeq. coal
AlstomBSFWindsor
US- 15 MWthOxy - coals
Getica - CET TurceniRoumania >250MWeChilled
ammonia - Lignite
PGE BelchatowPoland 260 MWe
Adv.Amines- Lignite
DOE/AlstomWindsorUS 3 MWth
Chemical looping-
coal
2nd Gen
NER300
NER300
SelectedforreceivingEEPR funding
NER300: AppliedforEUETSNewEntrantReservefunding
EoNKarlshamnSweden - 5 MWth
ChilledAmmoniaFueloil
WE EnergieUS- 5 MWth
ChilledAmmonia, Coal
AEP MountaineerUS- 58 MWth
ChilledAmmonia, coal
TotalLacqFrance- 30 MWth
Oxy- Gas
Operating
AlstomLabsVxjSweden 0.25 MWth
Post C. multipurpose
Large-scaleprojects-underdevelopment
WhiteRoseCCSProjectUK- 426 MWe
Oxy coal
NER300
Incommissioning /start-up
TCM MongstadNorway- 40 MWth
ChilledAmmonia - Gas
EDF LeHavreFrance 5 MWth
Adv.Amines- Coal
RFCSEU -DarmstadtGermany 1 MWth
Chemical looping- coal
2 Gen
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is
given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
CCS Cost of Electricity studyMain assumptions
Reference plants: Coal & Lignite (without CCS)
Realistic set of assumptions by region
Base case at 7450 hrs per a. plus sensitivity analysis Performance improvement considered (e.g. double reheat ST) Cycle arrangement in 2020/30: 300b-600C-620C
EUR NAM SEA
Fuel type Bituminous Raw Lignite Dried Lignite PRB coal Bituminous
Fuel heating value KJ/Kg LHV 24 930 10 278 21 283 20 425 20 896
Carbon content UB mass% 65% 31% 57% 56% 53%
Fuel price 2011 Euro/t 78,2 24,3 24,3 25,7 53,4
Euro/GJ 3,14 2,37 2,13 1,26 2,56
Cycle argt 2020/30 bar/C/C 300b/600/620C 272b/600/605C 300b/600/620C 300b/600/620C 300b/600/620C
Cooling type C 13C - Direct C 18C - Direct C 18C - Direct C 19C - CT 28C - Direct C
Net Output MWe net 837 1 000 1 000 837 837
Net eff. 15/20/30 % LHV 46.2/48/48.4 % 44/-/- % w HR 47,6/48,8/49 % 44/46.2/46.7 % 41/42.7/43 %
EPC 2015/20/30 /KW net 1421/1518/1518 1583/-/- 2070/2200/2200 1612/1722/1722 814/869/869
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is
given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Hardcoal CCS power plantEnergy Penalty (EP)
Energy penalty (EP) = (Ref PP net MWe CCS PP net MWe)(Ref PP net MWe)
Performance improvement and cooling temperature impacts
SEAEUR NAM&
Note : 90% capture of CCS PP CO2 emission, CCS plant and Reference plant at same net
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is
given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
EURCoE /MWh net
Hardcoal CCS power plantCoE base case (with T&S, without CO2 price)
NAM SEA
All with T&S, on-shore saline aquifer: impact on CoE: 4,8 to 7,2 /MWh netEUR 2032: CCS => +45% increase in CoE; NAM/SEA: lower CoE
CoE /MWh net CoE /MWh net
30
40
50
60
70
80
90
2015 2020 2025 2030 2035
Oxy
Post
Ref PP
+45%
(Post)
73,5 /MWh
(Post)
30
40
50
60
70
80
90
2015 2020 2025 2030 2035
Oxy
Post
Ref PP
30
40
50
60
70
80
90
2015 2020 2025 2030 2035
Oxy
Post
Ref PP
64 /MWh
(Post)62 /MWh
(Post)
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is
given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Hardcoal CCS power plantFuel, Capex/Opex and T&S contribution in CoE
POSTREF
/ MWh net
NAMEUR
POSTREF POSTREF
SEA
CoE Ref Plant & Incremental CCS in 2032
Regional differences in Fuel, Capex/Opex costs
High capex, expensive coal Cheap coal, lower efficiency Low Capex, expensive coal
0
10
20
30
40
50
60
70
80
90
100
50,5
73,5+45%
40,5
64
T&S
Fuel
Capex+Opex
40
62
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is
given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
-10% -5% 0% 5% 10%
CCS Opex
Re-boiler duty (1,8 GJ/tCO2)
CO2 compression
CCS Capex
Capex Storage
Ref plt net efficiency (48,4%)
Energy penalty (15,5% of Ref net)
Capex Transport (200 km)
Capture rate (90%)
WACC w/o inflation (6%)
Economic life (25 yrs)
Fuel cost (78,2 /t)
20 yrs40 yrs
-25% +25%
1,75 GJ 2,0 GJ
-20% 5%
-10% 10%
-10% 10%
-35% 50%
EP 14,7% EP 16,8%
Eff 49,4% Eff 47,4%
-50% 50%
Rate 80% Rate 92,7%
Wacc 7%
Base case
Wacc 5,5%
CCSConventional plant contribution
73,5 /MWh 77,2 /MWh69,8 /MWh
Hardcoal CCS power plantSensitivity analysis - CoE 2032 Europe
Base case: Post amine,on-shore T&S,no CO2 price
Fuel cost, Economic life, WACC have a strong impact
EUR 2032
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is
given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Gas Reference Combined-Cycle Power Plants (without CCS)
CCS Cost of Electricity studyMain assumptions
Combined cycles realistic set of assumptions
Base case combined cycle at 6570 hrs per a. Performance improvement considered
EUR NAM SEA
Fuel type Natural gas Natural gas Natural gas
Fuel heating value KJ/Kg LHV 50 000 50 000 50 000
Carbon content mass% 75% 75% 75%
Fuel price 2011 Euro/GJ 7,2 2,8 3,8 (subs.)
Cycle argt 2020/30 1-1 SS 2-1 MS 1-1 SS
Cooling type C 13C - Direct C 19C - CT 28C - Direct C
Net Output 15/20/30 MWe net 600/650/700 850/900/950 538/583/628
Net eff. 15/20/30 % LHV 61/62/63 % 60/61/62 % 60/61/62 %
EPC cost 15/20/30 /KW net 558/544/529 452/441/429 473/461/449
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is
given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Gas Combined Cycle CCS Power PlantCoE base case (with T&S, without CO2 price)
EURCoE /MWh net NAM SEACoE /MWh net CoE /MWh net
Lowest gas price at 2,8 /GJ Subsidized gas price 3,8 /GJ=> offsets Capex advantage
Gas price at 7,2 Euro/GJ
-5 % reduction with FGR
Difference in gas price between regions drives CoE level
Note : 90% capture of CCS PP CO2 emissions, CCS plant net output de-rated vs Reference plant (energy penalty)
25
30
35
4045
50
55
60
65
70
75
80
2015 2020 2025 2030 2035
Post FGR, 90% capt
Ref plant
25
30
35
4045
50
55
60
65
70
75
80
2015 2020 2025 2030 2035
Post FGR, 90% capt
Ref plant
25
30
35
4045
50
55
60
65
70
75
80
2015 2020 2025 2030 2035
Post FGR, 90% capt
Ref plant
COE - NAM COE - ASIACOE - EUROPE
Ref plant
Ref plant
Ref plant+28%
+42%
+32%
68,5/MWh )
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is
given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
POSTREF POSTREF POSTREF
Gas Combined Cycle CCS Power PlantFuel contribution in CoE
NAMEUR SEA
/ MWh net CoE Ref Plant & Incremental CCS in 2032
Smaller % increase in CoE than for coal due tohigher fuel cost contribution
0
10
20
30
40
50
60
70
80
90
100
53,6
68,5+28%
26,6
37,7+42%
Fuel
Capex+O&M+T&S
34,4
45,4+32%
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is
given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
-15% -10% -5% 0% 5% 10% 15%
CCS OpexCO2 compression
Re-boiler duty (1,8 GJ/tCO2)
Capex Storage
CCS Capex
Capex Transport (200 km)
Ref plt net efficiency (63%)
Energy penalty (10,1%)
WACC w/o infl. (5,95%)
Capture rate (90%)
Economic life (20 yrs)
Fuel cost ( 7.2 /GJ)
68,5 /MWh
16 yrs25 yrs
-25% +25%
1,75 GJ 2,0 GJ
-20% 5%-10% 10%
-10% 10%
-35% 50%
EP 9, 4% EP 11,1%
Eff 64% Eff 62%
-50% 50%
70% 92,7%
Wacc 5,5% Wacc 6,85%
72 /MWh61,6 /MWhBase case
CCSConventional plant contribution
Gas price will remain an essential sensitivity parameter
Gas Combined Cycle CCS Power PlantSensitivity analysis on CoE 2032
Base case: Post aminew FGR, on-shore T&S,
no CO2 price
EUR 2032
Note: w CO2 price 82/t => +4.3% on CoE => 71,5 /MWh
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is
given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
CCS is already competitive on coal and gas from 2017 tocomplement other low carbon alternatives to reduce CO2
footprint
Low carbon technologies in Europe in the next 5years
Source : Alstom analysis 2012. CCS w Post amine 2017 costs, reference value with on shore T&S, CO2 price and Flue Gas Recirculation for CCS Gas CC.Upper range includes off-shore storage. CoE do not include externalities of Intermittent power (Back-up cost, balancing cost, grid enhancement if required)
7986
0
50
100
150
200
250
300
Hardcoal w
CCS Post
2017
Gas CCPP
w CCS
2017
Nuclear Hydro Geo-
thermal
Wind
Onshore
Wind
Offshore
Solar
Thermal
Solar PV
0
50
100
150
200
250
300
/ MWhCoE Low Carbon technologies New PP over next 5 years
Reference case
EUROPE
Low case
CSP Tower
with storage
no stor.
4 hrs sto
Up to 45cents/kWh
(82 for Ref
CCS Oxy)
Alstom CO2 Capture Systems - P 41
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ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is
given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.
Conclusion
Alstom: a key partner in CCS!
Fossil Plants will still remain for several decades Reducing CO2emissions from these plants is an
absolute need to limit global warming to 2 C (thecurrent path leads to 6C !)
CCS is the only alternative to significantly reduce fossilplant CO2. It is competitive and affordable on both gasand coal
Alstom is currently developingCO2 capturetechnologiesand is on the good path to commercialisethe technology before 2020
Alstom CO2 Capture Systems - P 42
Large scale demonstrations must happen now to validate the technology ontime
Pro-activeness on reduction targets, regulations and policy instruments areneeded to support demonstration and early commercial phase (ex: FITs,capacity mechanism...)
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