bltn05038
TRANSCRIPT
AUTHORS
Alejandro Escalona � Institute for Geo-physics, Jackson School of Geosciences, Uni-versity of Texas at Austin, 4412 SpicewoodSprings Road, Building 600, Austin, Texas,78759; [email protected]
Alejandro Escalona is a postdoctoral researcherat the Institute for Geophysics, University ofTexas at Austin. He received his Ph.D. in ge-ology at the University of Texas at Austin in2003, where he focused on the stratigraphicand structural evolution of the Maracaibo Basin,Venezuela. He is currently interpreting re-gional seismic and well data from offshoreVenezuela to link offshore and on-land Cenozoicdepocenters.
Paul Mann � Institute for Geophysics, Jack-son School of Geosciences, University of Texasat Austin, 4412 Spicewood Springs Road,Building 600, Austin, Texas, 78759;[email protected]
Paul Mann is a senior research scientist at theInstitute for Geophysics, University of Texasat Austin. He received his Ph.D. in geology atthe State University of New York in 1983 andhas published widely on the tectonics of strike-slip, rift, and collision-related sedimentary ba-sins. His current focus area of research is theinterplay of tectonics, sedimentation, and hydro-carbon occurrence in Venezuela and Trinidad.
ACKNOWLEDGEMENTS
We thank Petroleos de Venezuela, S. A., forproviding seismic and well data used in thisstudy. This work was supported by Grant40499-AC8 from the Donors of the PetroleumResearch Fund of the American ChemicalSociety to P. Mann. We thank S. Talukdar,D. Goddard, and R. Erlich for valuable re-views. The authors acknowledge the financialsupport for publication costs provided by theUniversity of Texas at Austin’s Geology Founda-tion and the Jackson School of Geosciences.University of Texas, Institute for GeophysicsContribution 1775.
Editor’s Note
Color versions of figures may be seen in theonline version of this article.
An overview of the petroleumsystem of Maracaibo BasinAlejandro Escalona and Paul Mann
ABSTRACT
The geologically complex Maracaibo Basin in northwestern Vene-
zuela is one of the most prolific hydrocarbon basins in the world.
Having a basinal area of 50,000 km2 (19,300 mi2), the basin has
produced more than 30 billion bbl of oil, with estimated re-
coverable oil reserves of more than 44 billion bbl. The central
elements of the petroleum system of the basin include (1) a world-
class source rock (Upper Cretaceous La Luna Formation), depos-
ited on a shelf-to-slope environment under anoxic conditions and
modified by intermittent oxygenated periods and tectonic events;
(2) high-quality clastic reservoir rocks deposited in Eocene and
Miocene fluviodeltaic settings; (3) two main periods of rapid tec-
tonic subsidence responsible for two pulses of voluminous hydro-
carbon generation, first, during Paleogene Caribbean–South Ameri-
can oblique plate collision and, second, during the Neogene uplift
of the Sierra de Perija–Merida Andes; and (4) lateral and vertical
migration of oil along strike-slip, normal, and inverted faults, as
well as a regional unconformity of late Eocene–Oligocene age.
The maturation, migration, and trapping of hydrocarbons were
closely controlled by the tectonic evolution of the Maracaibo Basin.
During the Paleogene, the development of a foredeep along the
northeastern margin of the basin and the strike-slip reactivation of
the rift-related Jurassic faults on the Maracaibo platform controlled
the early structural setting of the source and reservoir rocks. Hy-
drocarbons migrated updip from source rocks beneath the north-
northeastern margin of the basin along north-south strike-slip faults
and into overlying Eocene clastic reservoirs in the south-central parts
of the basin. The second period of the Maracaibo Basin petroleum
system developed during subaerial exposure of most of the Mara-
caibo Basin during Oligocene–Miocene uplift of the adjacent Sierra
de Perija and Merida Andes. Uplift of mountain ranges surround-
ing the basin folded and depressed the interior of the basin to form
the extensive Maracaibo syncline. Because of the formation of the
Maracaibo syncline, oil generation began in the central and southern
parts of the synclinal basin and migrated northward. Hydrocarbons
migrated up the flanks of the Maracaibo syncline along reactivated
AAPG Bulletin, v. 90, no. 4 (April 2006), pp. 657–678 657
Copyright #2006. The American Association of Petroleum Geologists. All rights reserved.
Manuscript received February 19, 2005; provisional acceptance April 21, 2005; revised manuscriptreceived September 28, 2005; final acceptance October 14, 2005.
DOI:10.1306/10140505038
strike-slip faults and into Miocene rocks adjacent to
the uplifted mountain ranges. Escaping oil has formed
numerous surface seeps along the edges of the Mara-
caibo Basin.
INTRODUCTION
The Gulf Caribbean region currently contains 5% of
the total ultimate recoverable reserves of hydrocar-
bons on Earth (Horn, 2003) (Figure 1A). Venezuela
has the largest reserves of hydrocarbons of all the hy-
drocarbon regions of the western hemisphere, with
proved oil reserves of about 70 billion bbl oil and
proved gas reserves of 147 tcf (Figure 1) (U.S. Geo-
logical Survey, 2000; Audemard and Serrano, 2001).
These reserve estimates do not include the immense,
unconventional reserves of the Orinoco heavy oil belt,
with an estimated approximately 1200 billion bbl of
heavy and extra-heavy oil in place (Fiorillo, 1987;
U.S. Geological Survey, 2000).
The active tectonic setting of petroleum in Vene-
zuela is complex. Several tectonic belts that include
volcanic-arc, fore-arc, and back-arc basins are found off-
shore of the Venezuelan margin (Figure 2A). A west-to-
east younging pattern of thrusts and lateral ramp faults
and foreland basins onshore (Babb and Mann, 1999;
Mann, 1999) (Figure 2A) were produced by diachronous
oblique convergence between Caribbean arc terranes
and the South American continental margin from Late
Cretaceous (western area of Colombia) to the present
(eastern area of Trinidad) (Figure 2B). This ideal com-
bination of tectonic and stratigraphic events yielded
one of the most prolific petroleum systems in the world.
The 50,000-km2 (19,300-mi2) area of the Mara-
caibo Basin (Figure 3) is the most productive hydro-
carbon basin in the Caribbean–South America region
(Figure 1D). The ultimate total recoverable oil reserves
Figure 1. (A) Distribution of ultimate recoverable oil in the world; (B) distribution of recoverable oil in the world; (C) distribution ofgiant oil fields; and (D) ultimate oil reserves in the Caribbean and Gulf of Mexico (MMBOE). All data are from Horn (2003).
658 An Overview of the Petroleum System of Maracaibo Basin
Figure 2. (A) Topographic-bathymetric map showing six main tectonic belts observed along the northern margin of South America:1 = Venezuela basin; 2 = Leeward Antilles–Aves Ridge; 3 = Grenada-Bonaire-Falcon basins; 4 = Lesser Antilles arc–Cordillera de laCosta; 5 = Tobago-Carupano basins; 6 = Barbados accretionary prism–Columbus basin–Eastern Venezuela Basin–Maracaibo Basin.(B) Inferred position of the leading edge of the Great arc of the Caribbean at 90 Ma = Late Cretaceous; 60 Ma = Paleocene; 50 Ma =Eocene; 35 Ma = Oligocene; 15 Ma = Miocene; 0 Ma = Holocene (modified from Lugo and Mann, 1995).
Escalona and Mann 659
are 44,188 billion bbl of hydrocarbon (Horn, 2003), and
total cumulative oil production is more than 30 billion
bbl of oil during its last 80 yr of commercial production
history (Talukdar and Marcano, 1994). The Maracaibo
Basin is considered a supergiant oil field because it con-
tains more than 10 giant oil fields, each with ultimately
recoverable hydrocarbons greater than 500 million bbl
(Halbouty, 2001; Mann et al., 2003).
The Maracaibo Basin is located in a triangular in-
termontane depression bounded by the Merida Andes
and Sierra de Perija (Figure 3). Eocene clastic rocks of
the basin are the most prolific reservoirs for light and
medium oil and account for 50% of the basin’s re-
serves (Talukdar and Marcano, 1994). Miocene clas-
tic rock reservoirs include 44% of known reservoirs,
whereas Paleocene, Cretaceous, and basement rocks
Figure 3. Oil fields, oil seeps, and major faults of the Maracaibo Basin. Most oil fields are located along major subsurface strike-slip faults, including the Icotea and Pueblo Viejo faults (map modified from Zambrano et al., 1971; location of oil and gas seeps arefrom Link, 1952).
660 An Overview of the Petroleum System of Maracaibo Basin
include 6% of the known reservoirs (Talukdar and
Marcano, 1994). Eocene reservoirs are characterized by
complex stratigraphic and structural traps formed
during Eocene oblique convergence between the Ca-
ribbean and South American plates (Escalona, 2006;
Escalona and Mann, 2006a, b), Miocene reservoirs are
mainly found along the eastern edge (Bolivar Coast) of
the present-day Maracaibo syncline and are affected
mainly by east-west convergence (Taboada et al., 2000;
Guzman and Fisher, 2006) (Figure 3). Oil seeps fringing
the Maracaibo Basin are indicative of the prolific and
widespread petroleum system underlying the entire ba-
sin (Link, 1952) (Figure 3).
The main objective of this article is to provide an
overview of the petroleum system of the Maracaibo
Basin in the context of its tectonic history. In this article,
we summarize the most important tectonic events that
affected the generation, migration, and trapping of hy-
drocarbons and integrate relevant hydrocarbon and geo-
chemical observations presented by previous workers.
GEOLOGIC SETTING
The sedimentary history of the Maracaibo Basin began
during the Late Jurassic, with the deposition of rift-
related rocks (La Quinta Formation) in structural lows
or half grabens controlled by linear, north-northeast–
striking normal faults (Maze, 1984; Lugo and Mann,
1995). During the Early Cretaceous–Paleocene, a
mixed clastic-carbonate platform developed across
the area of present-day Maracaibo Basin (Figure 1).
Thermal subsidence and tectonic quiescence of the
passive margin led to sediment accumulation and the
absence of deformation of the basin during this period
(Lugo and Mann, 1995). The few structures present in
the Maracaibo Basin during the Cretaceous formed by
tectonic uplift of the Western and Central Cordilleras
of Colombia (Figure 1). This uplift is responsible for an
increase in subsidence by the end of the Cretaceous
that resulted in deposition of thick marine shale of the
Colon Formation during the Maastrichtian (Lugo and
Mann, 1995; Parnaud et al., 1995). During the late
Turonian–Campanian, the La Luna Formation was de-
posited in a shelf-slope setting under anoxic conditions.
The La Luna Formation became the main source rock
of northwestern South America (Renz, 1981; Bralower
and Lorente, 2003).
Late Paleocene and early to middle Eocene oblique
convergence between the Caribbean plate and the
northwestern margin of South America (Figure 2B)
produced a complex foreland wedge filled by clastic
sediments in the northeastern part of the Maracaibo
Basin (Stephan, 1977; Pindell and Barrett, 1990; Lugo
and Mann, 1995). The foreland basin was characterized
by an approximately 5-km (3.1-mi)-thick Eocene
wedge of fluvial-deltaic sedimentation (Misoa Forma-
tion), where the most prolific hydrocarbon reservoirs
of the Maracaibo Basin are concentrated. Paleogene
collision was characterized by northwest to southeast
migration of the depocenter through time over a lateral
distance of about 150 km (93 mi) (Stephan, 1985;
Lugo and Mann, 1995; Escalona and Mann, 2006a).
Isostatic rebound affected the central and eastern parts
of the Maracaibo Basin and produced the widespread
Eocene unconformity that exposed and subaerially
eroded the central and northeastern parts of the basin
until the end of the Oligocene (Escalona and Mann,
2003a, 2006a). Fluvial and shallow-marine sedimen-
tation continued in the south and southwest areas of
the Maracaibo Basin (Erlich et al., 1997). The Eocene
unconformity represents the main seal above Eocene
reservoirs, but it is locally breached by faulting, allowing
the upward ascent of hydrocarbons into Miocene res-
ervoirs at the basin edges (Figures 3, 4).
The Miocene–Holocene period is characterized by
the uplift and erosion of the Sierra de Perija and the
Merida Andes on the western and southeastern flanks
of the basin (Kohn et al., 1984; Shagam et al., 1984).
The formation of the north-south–trending Maracaibo
syncline (Castillo, 2001; Mann et al., 2006) represents
the final stage of this uplift and convergence. The Mar-
acaibo syncline closely controls the present-day geo-
graphic configuration of the basin and the location of its
marginal oil seeps (Figure 3). The convergent structural
styles seen on seismic lines at deeper levels in the basin
are controlled by Oligocene and Miocene inversion of
Eocene rift-related structures in the central part of the
basin (Escalona and Mann, 2003b; Castillo and Mann,
2006; Duerto et al., 2006). Eocene inversion of rift-
related structures also caused faulting of lower Mio-
cene rocks overlying Eocene reservoir rocks. Following
a period of isostatic rebound during the Oligocene
(Escalona, 2003; Escalona and Mann, 2006a), a phase
of rapid Miocene–Holocene subsidence began. Subsi-
dence was caused by the uplift of the bounding Sierra
de Perija and Merida Andes mountain ranges that is,
in turn, related to the convergence and subduction of
the Caribbean plate and collision of the Panama arc in
northwestern South America (Kellogg and Bonini,
1982; Taboada et al., 2000; Colmenares and Zoback,
2003; Cortes and Angelier, 2005).
Escalona and Mann 661
PETROLEUM SYSTEMS
Figure 3 shows the distribution of hydrocarbon res-
ervoirs in the Maracaibo Basin (Zambrano et al., 1971).
Most Eocene reservoir rocks are spatially aligned with
the north-south–striking Icotea and Pueblo Viejo faults,
whereas most Miocene reservoirs rocks are clustered
along the eastern and northeastern margin of the present-
day Lake Maracaibo (Figure 3). Ninety four percent of
hydrocarbon reservoirs in the Maracaibo Basin are found
within Eocene–Miocene clastic rocks (Talukdar and
Marcano, 1994). Only 6% of reservoirs are found within
underlying Cretaceous–Paleocene carbonate rocks and
basement.
Figure 4 shows an east-west and a north-south
interpreted seismic line in the central Maracaibo Ba-
sin, summarizing the main elements of the Mara-
caibo petroleum system from Cretaceous source
rock to Eocene and Miocene reservoirs. The two in-
terpreted seismic lines show the northeast thicken-
ing of the Eocene clastic wedge, the southwest thick-
ening of the Miocene–Holocene clastic wedge, and
the main structural and stratigraphic controls of the
basin inherited from the north-northeast–striking fault
family.
Source Rocks
Hydrocarbon source rocks in the Maracaibo Basin are
Upper Cretaceous marine carbonate rocks (calcare-
ous shales and argillaceous limestones) that make up
the La Luna Formation of Cenomanian–Campanian
age. Previous geochemical studies show that the La
Luna Formation is the source of 98% of the total
oil reserves found in the Maracaibo Basin (Zambrano
et al., 1971; Young et al., 1977; Renz, 1981; Talukdar
and Marcano, 1994). An additional 2% of the total oil
reserve was derived from nonmarine coals and shales
of the Paleocene Orocue Formation that are found in
the southwestern part of the basin (Talukdar and
Marcano, 1994; Yurewicz et al.1998). Gonzalez de
Juana et al. (1980) proposed that Eocene and Mio-
cene terrestrial source rocks, now deeply buried in
the southern part of the basin, may act as additional
source rock to the La Luna Formation. Geochemical
analysis of Tertiary sedimentary rocks indicates no
significant hydrocarbon potential for Eocene and Mio-
cene shale, nor is there any evidence for oils corre-
lated to this type of source rocks (Talukdar and Mar-
cano, 1994; Tocco and Margarita, 1999).
Depositional Setting of Source Rocks of the La Luna Formation
The La Luna Formation has been the subject of many
previous studies since the beginning of the petroleum
exploration in the Maracaibo Basin in the early 20th
century. Previous studies that describe the deposi-
tional setting and composition of the La Luna Forma-
tion include the pioneering study of Renz (1981) and
more recent works by Perez-Infante et al. (1996), Er-
lich et al. (1999a), Erlich et al. (2000), and a source
rock conference convened by SEPM and Petroleos de
Venezuela S.A. (PDVSA) (Bralower and Lorente, 2003).
Figure 5 shows a stratigraphic chart with the position
of the La Luna Formation in the Cretaceous sequences
of the Maracaibo Basin, its isopach, and its typical well-
log response.
The La Luna Formation was deposited over a pe-
riod of approximately 20 m.y., extending from the
upper Cenomanian to upper Campanian (Figure 5).
Its thickness ranges from 60 m (196 ft) beneath the
southern part of the basin to 150 m (492 ft) beneath
the northern part of the basin (Renz, 1981; Lugo and
Mann, 1995; Bralower and Lorente, 2003) (Figure 5B).
The La Luna Formation was deposited in oxygen-
depleted bottom-water conditions in a shelf-to-slope
marine environment (Perez-Infante et al., 1996), in-
fluenced by episodic bottom currents, debris flows,
turbidites, faulting, and intermittent upwelling condi-
tions (Macsotay et al., 2003; Zapata et al., 2003).
Paleowater depth of the La Luna Formation is inter-
preted to have been more than 40 m (131 ft) in a deep
shelf setting, ranging from below storm-wave base
(Macsotay et al., 2003) to a depth of several hundred
meters (Boesi and Goddard, 1991; Parra et al., 2003).
Figure 6 shows the paleogeographic reconstruc-
tions for the La Luna Formation in the Maracaibo
Basin during the Cenomanian–Campanian (Erlich et al.,
1999a). The structural configuration of the basin dur-
ing the Late Cretaceous was possibly influenced by
uplift of the Central Cordillera of Colombia (Renz, 1981;
Erlich et al., 1999a; Macsotay et al., 2003) (Figure 6).
Renz (1981), using cross sections from outcrops along
the mountain range bounding the Maracaibo Basin,
identified basement paleohighs (e.g., Merida arch)
and basins (e.g., Machiques, Uribante, and Barquisi-
meto) in the areas surrounding the Maracaibo Basin
(Figure 6A). These paleohighs produced the thickness
variations in Cretaceous passive-margin sediments, in-
cluding the La Luna Formation in the south and south-
western areas of the basin (Renz, 1981).
The most controversial of these geological features
is the Merida arch in the southern and central regions
662 An Overview of the Petroleum System of Maracaibo Basin
Figure
4.(A)Interpretedeast-westseismiclineintheMaracaibo
Basin.Thesectionshow
sthemainstructuralandstratigraphicfeatures
oftheMaracaibo
Basinandits
petroleum
system
s(see
Figure
3forlocation).Migrationpathsfrom
source
toreservoirarelocalized
alongmajor
faultsinthebasin(e.g.,Icotea
fault,PuebloViejo,andA,B
,and
Efaults).
Hydrocarbon
reservoirsareconcentrated
instructuralhighsbeneaththeEocene
unconformity
andintheMiocene
alongthenorthandeasternflanksof
theMaracaibo
syncline.
(B)Interpretednorth-southseismiclineintheMaracaibo
Basin(see
Figure3forlocation).H
ydrocarbon
reservoirsintheMiocene
areconcentrated
intheupdippartoftheMiocene
clastic
wedge.Eoceneturbiditesprovidegood
explorationtargetsnorthof
theBurroNegro
fault.
Escalona and Mann 663
664 An Overview of the Petroleum System of Maracaibo Basin
of the present-day Maracaibo Basin (Dewey and
Pindell, 1986; Salvador, 1986). The existence and ori-
entation of the Merida arch is significant for petroleum
systems because its existence likely controlled the dis-
tribution and thickness of Cretaceous source rock be-
neath the Maracaibo Basin. Two proposed orientations
for the Merida arch follow:
1. An arch perpendicular to the trend of the present-
day Merida Andes: This postulated arch would
be parallel to other arches in the region like the
northwest-southeast–striking Baul arch that out-
crops east of the Andes and separates the Barinas ba-
sin from the Guarico subbasin to the east (Figure 2).
Cross sections along the Merida Andes based on
outcrop mapping by Renz (1981) and Salvador
(1986) show thinning or absence of Lower Cre-
taceous rocks (Rıo Negro, Apon, and Aguardiente
formations), overlain by a thin section of Upper
Cretaceous rocks (Maraca, La Luna, and Colon for-
mations). Isopach maps of Cretaceous rocks beneath
the central Maracaibo Basin show Cretaceous rocks
thinning 10–20 m (33–66 ft) in the south and cen-
tral areas of Lake Maracaibo (Gonzalez de Juana
et al., 1980; Lugo and Mann, 1995). Figure 5B shows
an isopach of the La Luna Formation from Lugo and
Mann (1995). The La Luna Formation thins approxi-
mately 10 m (33 ft) in the south-central part of
Lake Maracaibo (dashed in Figure 5B). This subtle
change in thickness is interpreted by Lugo and
Mann (1995) as the continuation of the Merida
arch in the south and central areas of the Maracaibo
Basin.
2. An arch parallel to the trend of the present-day Me-
rida Andes and not affecting the area of the Mara-
caibo Basin: This proposed arch formed the Turo-
nian uplift of the Cordillera Central of Colombia
(Macsotay et al., 2003). This tectonic event might
have produced partial tectonic inversion along pre-
Cretaceous rift-related faults, which followed the
present-day strike of the Merida Andes (Macsotay
et al., 2003) and the trend of the Neogene right-
lateral Bocono strike-slip fault zone (Schubert, 1982;
Kellogg, 1984; Stephan, 1985; Dewey and Pindell,
1986; Audemard et al., 1999).
Small changes in thickness of passive-margin rocks
between 10 and 20 m (33 and 66 ft) in the south-
central areas of Maracaibo Lake might be attributed
to facies changes or depositional processes instead
of paleostructural relief above a northwest-southeast–
striking arch. Integration of outcrop and subsurface
data in both flanks of the Merida Andes foothills and
in southern Lake Maracaibo is required to solve the
extent and orientation of the Merida arch in the Mar-
acaibo Basin. Geologic data used for interpreting the
Merida arch have been limited to outcrops in the
Merida Andes (Renz, 1981; Salvador, 1986) or using
sparse wells and two-dimensional seismic lines in the
southern Maracaibo Basin (Audemard, 1991; Lugo,
1991).
A Santonian change in depositional environment to
more oxygenated and cooler waters in the La Luna
Formation (Tres Esquinas Member) suggests the ad-
vent of tectonic activity (Erlich et al., 2000; Bralower
and Lorente; 2003; Parra et al., 2003; Zapata et al.,
2003). Late Cretaceous tectonic activity was possibly
related to the reactivation of faults beneath the basin
or regional plate convergence in western Colombia
that caused abrupt changes in the paleotopography
and paleoclimate and ended passive-margin conditions.
An increase in upwelling and more oxygenation of
shelf waters of northern South America may be related
to (1) the migration of the South American plate to-
ward the Cretaceous intertropical convergence zone
(Villamil et al., 1999); (2) an increase in freshwater run-
off produced by the emergent Central Cordillera of Co-
lombia (Erlich et al., 2003); and (3) the establishment
of wet-dry cycles and submersion of paleobathymetric
barriers for ocean circulation (Erlich et al., 2003).
La Luna Source Rocks and Hydrocarbon Characteristics
The La Luna Formation is considered a good to ex-
cellent, oil-prone source rock (Talukdar et al., 1986;
Talukdar and Marcano, 1994; Yurewicz et al., 1998).
Comparison of gas-chromatographic and biomarker
characteristics of oils and La Luna source rock extracts
shows that the La Luna Formation is the source rock
for more than 98% of the oil accumulations in the Mara-
caibo Basin (Talukdar et al., 1986; Talukdar and Mar-
cano, 1994; Yurewicz et al., 1998; Erlich et al., 1999b;
Figure 5. (A) Regional-stratigraphic chart of the Albian to Maastrichtian stages in four different areas of the Maracaibo Basin (I toIV) (modified from Erlich et al., 1999a; Castillo, 2001). (B) Location map showing locations I to IV of the stratigraphic chart and thetotal thickness in meters of the La Luna Formation from well logs (modified from Lugo and Mann, 1995). (C) Gamma-ray log of awell in the south Lake Maracaibo area showing a typical response from Albian to Maastrichtian (modified from Castillo, 2001).
Escalona and Mann 665
Figure 6. Paleogeographic maps from Albian to Campanian (modified from Erlich et al., 1999a).The Cenomanian to Turonian period represents a mixed carbonate-clastic platform in the Mara-caibo Basin areas. The middle to outer shelf depositional environment characterized the centralMaracaibo Basin from the Albian to Campanian.
666 An Overview of the Petroleum System of Maracaibo Basin
Tocco and Margarita, 1999; Gallango et al., 2002). The
La Luna source rocks contain oil-prone type II kerogen
and are rich in hydrogen content, with the bulk of the
organic matter derived from algae and bacteria (Perez-
Infante et al., 1996). The average original total organic
carbon (TOC) of La Luna source rocks in the Mara-
caibo Basin is 5.6% (Talukdar and Marcano, 1994).
Maximum TOC values are locally as high as 16.7%
(Erlich et al., 1999b). In the southwestern area of the
basin, the average TOC is 4.3% (Catatumbo; Yurewicz
et al., 1998; Llanos et al., 2000). In the Sierra de Perija
area, TOC values range from 3.7 to 5.7% (Gallango
et al., 2002) (Figure 7). In the Merida Andes, TOC val-
ues range between 1.7 and 2% (Erlich et al., 1999b)
(Figure 7).
Oil quality variations in oils derived from La Luna
source rocks are controlled by thermal maturity and
in-reservoir alteration (Talukdar and Marcano, 1994).
Unaltered oils vary in oil quality (API) according to
their maturity: marginally mature oils range from
11 to 16j API; mature oils range from 20 to 39j API;
and highly mature oils range from 37 to 55jAPI. With
increasing maturity, API gravity and saturated hydro-
carbon content increase, whereas vanadium, sulfur, and
polar compounds decrease (Talukdar et al., 1986;
Talukdar and Marcano, 1994). Unaltered oils are wide-
ly distributed in the Maracaibo Basin. The oils mi-
grated into reservoirs during the Eocene and later
during the Miocene–Holocene (Talukdar and Mar-
cano, 1994).
Oil alteration in reservoirs occurred mainly as a
result of biodegradation and oil-oil mixing (Talukdar
et al., 1986; Talukdar and Marcano, 1994). Altered
oils mostly occur in the central and northeastern res-
ervoirs of the Maracaibo Basin (Figure 2). Biodegra-
dation of oils in shallow Eocene reservoirs occurred
during the Oligocene and in shallow Miocene reser-
voirs during the late Miocene–Holocene. Biodegraded
oils have low API (<25j), high sulfur, vanadium, polar
compounds, and low saturates content. Oil-oil mixing
occurred by natural mixing of oil that migrated in the
Miocene–Holocene. Strongly biodegraded oil is derived
form earlier migrated oil found in Eocene and Miocene
reservoirs (Figure 4). In addition to these alteration pro-
cesses, Tocco and Margarita (1999) observed alteration
of oils by migration fractionation in the Centro Lago
field (Figure 3).
Natural gas derived from the La Luna source in
the Maracaibo Basin is mainly solution gas (Talukdar
and Marcano, 1994). Free gas accumulations are un-
common in the Maracaibo Basin.
Burial History, Timing, and Amount of Petroleum Generated
Figure 8 shows an integration of burial-history curves,
compiled from several workers, and oil-generation
curves calculated by Horn (2002). The oil-generation
curves were derived using time-temperature indices
based on Lopatin (1971) and Arrhenius reaction rates
for oil generation using a type II kerogen as an Upper
Cretaceous source rock (Horn, 2002). These plots
illustrate the close relation between burial history, oil
generation, and distribution of hydrocarbons in the
basin. In the Maracaibo Basin, burial peak and matu-
ration of the La Luna Formation occurred in two ma-
jor pulses that were controlled by regional tectonic
events:
1. Paleogene (60–40 Ma) subsidence event: Creta-
ceous rocks were deeply buried to depths of 4–
5 km (2.5–3.1 mi) in the central and northeastern
areas of the Maracaibo Basin. These depths reach
the thermal maturation window (Zambrano et al.,
1971; Gonzalez de Juana et al., 1980) (Figure 8,
well locations A, E, G, and H). Paleogene tec-
tonically induced subsidence was responsible for
the creation of a depocenter along the northeastern
margin of the basin (Escalona and Mann, 2003a).
Overmature source rocks of the La Luna Formation
and the main Paleogene depocenter are located
along the northeastern margin of the Maracaibo
Basin, roughly parallel to the trace of the northwest-
striking Burro Negro fault zone (Figures 7, 8) (Taluk-
dar and Marcano, 1994; Escalona and Mann, 2003a,
2004, 2006a). By late Eocene–Oligocene, the north-
northeastern areas of the basin had generated most
of the oil that is now being exploited (Figures 7, 8,
well locations A, E, G, and H) (phase 1 of Talukdar
and Marcano, 1994).
2. Miocene–Holocene (20–0 Ma) subsidence event:
Cretaceous and Paleocene source rocks were buried
to depths of 2–6 km (1.2–3.7 mi) in the south-
western areas of the Maracaibo Basin. This burial
event initiated a post-Eocene period for hydrocar-
bon generation (Figure 8, well locations B–G). The
central and south-southwestern areas of the Mara-
caibo Basin have generated less than 50% of their
potential oil (Horn, 2002) (Figure 7). This part of
the basin entered its peak of oil generation during
the Miocene (�20–15 Ma, Figures 7, 8, well loca-
tions C–F). Total organic carbon values of more
than 2% in the south-southwest areas of the Mara-
caibo Basin (Figure 7) indicate high potential for
continuing oil generation in this region.
Escalona and Mann 667
Figure 7. Distribution in percentages of hydrocarbon generated by La Luna Formation source rocks in the Maracaibo Basin basedon calculations by Horn (2002). Total organic carbon (TOC) values were taken from the following sources: Llanos et al. (2000), Erlichet al. (1999b), Yurewicz et al. (1998), and Gallango et al. (2002). Distribution of oil seeps from Cretaceous and Paleocene sourcerocks is taken from Link (1952).
668 An Overview of the Petroleum System of Maracaibo Basin
Reservoir Rocks
Reservoir rocks in the Maracaibo Basin are found
throughout the stratigraphic section and range from
fractured basement metamorphic rocks to shallow, un-
consolidated, Miocene rocks. Structural traps are con-
trolled by a variety of features, including normal faults,
inverted faults on the flexed continental plate (Harding
and Tuminas, 1989; Escalona and Mann, 2003b), folds
in the foreland basin, and subsurface strike-slip faults
forming north-south anticlines (Escalona and Mann,
2003b). All trap types were charged with hydrocarbons
from underlying Cretaceous source rocks of the La
Luna Formation (Zambrano et al., 1971; Gonzalez de
Juana et al., 1980; Talukdar and Marcano, 1994; Erlich
et al., 1999a). Stratigraphic traps are found in hetero-
geneous, mixed fluvial, and tidal-dominated deltaic
systems defining regressive-transgressive cycles on the
Eocene Maracaibo shelf and nearshore to fluvial Mio-
cene sandstone rocks (Guzman and Fisher, 2006).
Major reservoir facies are stacked distributary channels
and tidal bars (Maguregui, 1990; Ambrose et al., 1995;
Escalona, 2003). Hydrocarbon reservoirs can be clas-
sified in three main types:
1. Sub-Eocene reservoirs (Figures 9, 10): These reser-
voirs are located in deeply buried Cretaceous lime-
stone and Paleocene sandstone in central and south-
ern Maracaibo Basin (Figure 9A, D) and in less deeply
buried Cretaceous limestone and basement rocks
in northwestern areas of the basin (Figure 10H).
Reservoirs include fractured rocks (basement and
Cretaceous limestone) associated with the reactiva-
tion of north-south strike-slip, northwest-southeast–
striking normal faults (Figure 10B, D) and thrusts
(Figure 9A, C) related to the uplift of the Merida
Andes (Castillo and Mann, 2006).
2. Eocene reservoirs (Figures 10, 11): These are the
most prolific reservoir rocks in the Maracaibo Basin.
They are characterized by structural traps associated
with anticlines formed by strike-slip reactivation
of north-northeast–striking faults (e.g., Icotea and
Pueblo Viejo faults and their related northwest-
southeast normal faults; Escalona and Mann, 2003b).
Traps also formed in fluvial-deltaic (tide-influenced)
sandstone facies traps truncated by the Eocene un-
conformity (cf. Figures 10E, H; 11K, L). The most
productive Eocene reservoirs are located in the cen-
tral and northeastern regions of the Maracaibo Basin.
3. Miocene reservoirs (Figure 11I, L): These form the
second most prolific reservoirs in the Maracaibo
Basin. The reservoirs are mainly fluvial sandstone
facies located in anticlines of early Miocene age (re-
activation of Eocene structures, Figure 11J, L) and
stratigraphic wedges beneath the Eocene unconfor-
mity (Figure 11I).These productions occur along the
northeastern shore of the Maracaibo Lake, near the
trace of the Burro Negro fault (Figures 3, 8). Where
no structural or stratigraphic traps existed, oil es-
caped to the surface and formed seeps that outline
the edges of the Maracaibo Basin (Figures 3, 8).
Migration and Trapping
The petroleum system evolution of the Maracaibo Ba-
sin is summarized in four schematic cross sections in
Figure 12. Hydrocarbon migration and trapping oc-
curred in two main, tectonically controlled phases as
previously proposed by Zambrano et al. (1971), Gon-
zalez de Juana et al. (1980), Talukdar et al. (1986),
and Talukdar and Marcano (1994).
1. Carbonate platform phase (Late Cretaceous–
Paleocene) (Figure 12A): During this phase, the La
Luna Formation source rock was deposited on a
shallow, passive-margin, shelf-to-slope environment.
It thickness ranges from 40 to 150 m (131 to 492 ft)
(Figure 5B). Carbonate thickness variations were
controlled by minor basement relief of underlying
pre-Cretaceous structures like the Merida arch.
2. Foreland phase (early Eocene) (Figure 12B): Oblique
collision between the Caribbean and South Ameri-
can plates formed an asymmetric wedge of fluvial-
deltaic Eocene rocks that were deposited in a foreland
basin (Lugo and Mann, 1995; Escalona and Mann,
2006a). Cretaceous source rocks were buried to
depths of 5 km (3.1 mi) in the north-northeastern
part of the Maracaibo Basin and reached the oil win-
dow. A pull-apart basin controlled by reactivated Ju-
rassic north-northeast–striking faults formed in the
central Maracaibo Basin (Icotea subbasin; Escalona
and Mann, 2003b). Strike-slip faults provided ver-
tical pathways for hydrocarbon migration from Cre-
taceous source rocks (La Luna Formation) to Eocene
reservoir sands.
The deeply buried Icotea pull-apart basin provides an
alternative setting for hydrocarbon generation above
deeply buried Cretaceous rocks (Figures 4; 12B, C)
(Escalona and Mann, 2003b). Vertical displacement
of major strike-slip faults bounding pull-aparts al-
lowed juxtaposition of Cretaceous source rocks and
Eocene reservoir rocks (Figure 4). Anticlinal traps
Escalona and Mann 669
670 An Overview of the Petroleum System of Maracaibo Basin
formed during creation of the pull-apart basin are
sealed by the Eocene unconformity (Escalona and
Mann, 2003b). The regional north-northeast dip of
the basin contributed to updip oil migration toward
the central areas of the Maracaibo Basin, where
higher quality fluvial and deltaic reservoir facies
are present (Escalona, 2003; Escalona and Mann,
2006). Trapping beneath the Eocene unconformity
in the south-central Maracaibo Basin also occurs in
fluvial-dominated reservoirs of Eocene age (Escalona
and Mann, 2006b) (Figures 4B, 10).
3. Isostatic rebound phase (late Eocene–Oligocene)
(Figure 12C): During the Oligocene, most of the
Maracaibo Basin was subaerially exposed and eroded
by isostatic rebound that followed the end of the
convergence foreland basin phase. This period of re-
bound and erosion lasted approximately 20 m.y. in
the central parts of the basin and is characterized by
the loss of hydrocarbons to the surface (Talukdar
and Marcano, 1994). Furthermore, biodegradation
of oils occurred because of the invasion of meteoric
waters into shallowly buried Eocene reservoirs
(Bockmeulen et al., 1983; Talukdar and Marcano,
1994) (Figure 12C).
4. Maracaibo syncline phase (Miocene–Holocene)
(Figure 12D): This phase of basin development was
characterized by uplift of the Sierra de Perija and the
Merida Andes, the formation of the north-south–
trending Maracaibo syncline (Castillo and Mann,
2006), and early Miocene inversion of Eocene struc-
tures in the central part of the basin. In contrast to
the Eocene, the Neogene depocenter was located in
the southern Maracaibo Basin, where continental
facies pinch out to the east-northeast to form major
stratigraphic traps (Figures 3, 4, 11).
The migration of depocenters from the northeast-
ern basin during the Eocene to the south-southeastern
basin in the Miocene–Holocene contributed to a sec-
ond pulse of maturation of Cretaceous source rocks of
the La Luna Formation in the central and southern parts
of the Maracaibo Basin (Figure 8). This new period of
oil generation charged reservoirs of Eocene and Mio-
cene age. For reservoir rocks younger than Eocene, hy-
drocarbon migration occurred along fault zones that
breached the Eocene unconformity (Figure 12). These
diverse migration paths allowed east-northeast up-
dip migration from the deep part of the basin to Mio-
cene reservoirs (Figures 4, 12D). In Miocene reservoir
rocks, hydrocarbons are mainly trapped by (1) inverted
structures (Figures 4, 11I, L; 12D); (2) stratigraphic
wedges to the northeast (Guzman and Fisher, 2006)
(Figures 4, 11); and (3) seeps to the east, west, and south
of the Maracaibo syncline (Zambrano et al., 1971;
Gonzalez de Juana et al., 1980) (Figures 3, 8).
CONCLUSIONS
The complex interplay of deformation, burial, and
sedimentation in the Maracaibo Basin during the Cre-
taceous and Tertiary combined to make the basin one
of the most effective and prolific petroleum systems on
Earth. Deposition and distribution of ideal source and
reservoir rocks were stratigraphically and structurally
controlled by multiple tectonic events that led to hydro-
carbon generation, migration, and accumulation. The
main conclusions of this review include the following:
1. Geochemical analysis reveals that more than 98% of
the oil accumulation of the Maracaibo Basin was
sourced by the Cenomanian–Campanian La Luna
Formation. The La Luna Formation was deposited
under anoxic conditions with intermittent tectonic
and depositional events, including reworking by bot-
tom currents, and entry of turbidites and debris flows
into the basin.
2. Three main tectonic phases of deformation are re-
sponsible for the multiphase evolution of the pe-
troleum system in the Maracaibo Basin:� Phase 1: Paleogene oblique collision between the
Caribbean and northwestern South America: The
Maracaibo passive margin during the Paleocene–
early Eocene created an ideal mechanism for the
rapid burial and maturation of the source rock,
the La Luna Formation in the northeastern area
of the Maracaibo Basin (Figures 7, 8, 12). The
Paleogene foreland basin and a major right-lateral
ramp fault (Burro Negro fault) controlled the initial
generation and migration event of hydrocarbons
Figure 8. Burial histories of wells in the Maracaibo Basin based on data compiled by Horn (2002) from the following sources:(A) Sanchez (1993), (B) Delgado (1993), (C) Molina (1992), (D) Molina (1993), (E) Ramirez and Marcano (1992), and (F–H) Lugo andMann (1995). The percentage of hydrocarbon generation using Lopatin’s (1971) equations for a type II kerogen source rock basinis based on calculations by Horn (2002) for each well location. Shaded areas represent main periods of tectonic subsidence.
Escalona and Mann 671
Figure
9.Examples
offour
sub-Eocene
hydrocarbonreservoirsintheMaracaibo
Basin.Thesereservoirsarelocatedindeeplyburied
andfracturedmetam
orphicbasementrocks
andin
CretaceousandPaleocenesedimentary
rocks(>
5-km
[>3.1-mi]depth).Theinsetmap
intheupperrightcorner
(modified
from
PDVSApamphlets,1995
and1996,
unpublisheddata)provides
thelocationof
thesections.
672 An Overview of the Petroleum System of Maracaibo Basin
Figure
10.Examples
ofEocene
hydrocarbonreservoirsintheMaracaibo
Basin.Eocene
clastic
rocksarethemostprolificreservoirsintheMaracaibo
Basinandareconcentrated
mainlyinthecentraland
northeastern
areasofthebasinalongnorth-northeast–striking
faults.The
insetm
apintheupperrightcorner(m
odified
from
PDVSApamphlets,1995and
1996,unpublisheddata)provides
thelocationof
thesections.
Escalona and Mann 673
Figure
11.Exam
ples
ofMiocene
–Holocenehydrocarbonreservoirs
intheMaracaibo
Basin.
Thesereservoirs
arelocatedmainlyin
thenorthandnortheastern
areasof
the
Maracaibo
Basin.Themostprolificreservoirsarelocatedalongthenortheastern
coastline
ofthepresent-dayLake
Maracaibo
(BolivarCoast)andalongthetraceoftheBurroNegro
faultzone.Theinsetmap
intheupperrightcorner
(modified
from
PDVSApamphlets,1995
and1996,unpublisheddata)provides
thelocationof
thesections.
674 An Overview of the Petroleum System of Maracaibo Basin
in the Maracaibo Basin. The source rock entered
the oil window in the northeastern part of the
basin adjacent to the Burro Negro fault zone
(Figures 7, 8). The fault was the approximate
southern boundary of the Paleogene depocenter
and fold-thrust belt located north of the fault.
Hydrocarbons migrated updip and southward
into the platform using strike-slip and normal
Figure 12. Summaryof four main tectonicphases controllingthe petroleum systemof the Maracaibo Basin:(A) carbonate platformphase; (B) foreland basinphase; (C) isostatic re-bound phase; and (D)Maracaibo synclinephase.
Escalona and Mann 675
faults as pathways. Hydrocarbons were trapped
in reservoir facies located within different struc-
tural highs. The La Luna Formation source rock
in the northen part of the basin is presently in
an overmature stage because of its deep (>5 km;
>3.1 mi) burial (Figures 7, 8).� Phase 2: Late Eocene–Oligocene isostatic rebound:
Isostatic rebound was related to the release of con-
vergent stresses as the collision progressed east-
ward and southeastward of the Maracaibo Ba-
sin. Hydrocarbons trapped during this period
in near-surface settings may have undergone
biodegradation.� Phase 3: Uplift of the Sierra de Perija and Merida
Andes: This regional uplift is the main tectonic
mechanism responsible for the inversion of the
basin depocenter and creation of the second ma-
ture area of the La Luna source rock in the south-
ern part of the basin (Figure 7). The main clastic
depocenter tilted from the northeast to the south-
southwest during the Miocene to Holocene. The
La Luna Formation source rock entered the oil
window across the entire Maracaibo Basin. East-
west convergence formed the Maracaibo syn-
cline, reactivated major strike-slip faults as reverse
faults that breached the Eocene unconformity
(Figure 12D). The hydrocarbons used fault
breaches in the Eocene unconformity to migrate
updip from Eocene to Miocene reservoirs along
the flanks of the basin (Figure 4). The La Luna
source rocks in the south-central areas of the basin
are still in the mature to early mature stage and,
therefore, still have significant remaining hydro-
carbon generation potential (Figures 7, 8).
3. The Maracaibo Basin has a promising hydrocarbon
discovery potential in the mostly undrilled deeper
structural and stratigraphic traps of the central and
eastern basin (e.g., Icotea and Pueblo Viejo sub-
basins) (Figure 4A). More than 14 billion bbl of me-
dium to light oil of ultimate recoverable reserves
are predicted to be produced from these areas (U.S.
Geological Survey, 2000).
REFERENCES CITED
Ambrose, W., E. Ferrer, S. Dutton, F. Wang, A. Padron, W.Carrasquel, J. Yeh, and N. Tyler, 1995, Production optimiza-tion of tide-dominated deltaic reservoirs of the lower MisoaFormation (lower Eocene), LL-652 Area, Lagunillas field, LakeMaracaibo, Venezuela: University of Texas at Austin, Bureau ofEconomic Geology, Austin, Report of Investigations 226, 46 p.
Audemard, F. A., J.-C. Bousquet, and J. Rodriguez, 1999, Neo-tectonic and paleoseismicity studies on the Urumaco fault,northern Falcon Basin, northwestern Venezuela: Tectonophy-sics, v. 308, p. 23–35.
Audemard, F. E., 1991, Tectonics of western Venezuela: Ph.D.dissertation, Rice University, Houston, 245 p.
Audemard, F. E., and I. Serrano, 2001, Future petroliferousprovinces of Venezuela, in M. Downey, J. Threet, and W.Morgand, eds., Petroleum provinces of the twenty-firstcentury: AAPG Memoir 74, p. 353–372.
Babb, S., and P. Mann, 1999, Structural and sedimentary develop-ment of a Neogene transpressional plate boundary between theCaribbean and South America plates in Trinidad and the Gulfof Paria, in P. Mann, ed., Caribbean basins: Sedimentary basinsof the world: Amsterdam, Elsevier Science B. V., v. 4, p. 495–557.
Bockmeulen, H., C. Barker, and P. Dickey, 1983, Geology andgeochemistry of crude oils, Bolivar coastal fields, Venezuela:AAPG Bulletin, v. 67, p. 242–270.
Boesi, T., and D. Goddard, 1991, A new geological model related tothe distribution of hydrocarbon source rocks in the Falconbasin, northwestern Venezuela, in K. Biddle, ed., Active mar-gin basins: AAPG Memoir 52, p. 303–319.
Bralower, T., and M. Lorente, 2003, Paleogeography and stratigra-phy of the La Luna Formation and related Cretaceous anoxicdepositional systems: Palaios, v. 18, p. 301–304.
Castillo, M., 2001, Structural analysis of Cenozoic fault systemsusing 3D seismic data in the southern Maracaibo Basin,Venezuela: Ph.D. dissertation, University of Texas at Austin,Austin, 189 p.
Castillo, M. V., and P. Mann, 2006, Cretaceous to Holocene struc-tural and stratigraphic development in south Lake Maracaibo,Venezuela, inferred from well and three-dimensional seismicdata: AAPG Bulletin, v. 90, p. 529–565.
Colmenares, L., and M. Zoback, 2003, Stress field and seismotec-tonics of northern South America: Geology, v. 31, p. 721–724.
Cortes, M., and J. Angelier, 2005, Current states of stress in thenorthern Andes as indicated by focal mechanisms of earth-quakes: Tectonophysics, v. 403, p. 59–75.
Delgado, I., 1993, Lama field–Venezuela, Maracaibo Basin, Zuliastate, in N. H. Foster and E. A. Beaumont, compilers, Struc-tural traps VIII: AAPG Treatise of Petroleum Geology, Atlasof Oil and Gas Fields, p. 271–294.
Dewey, J., and J. Pindell, 1986, Neogene block tectonics of easternTurkey and northern South America; continental applicationsof the finite difference method: Discussion and reply: Tec-tonics, v. 5, p. 697–705.
Duerto, L., A. Escalona, and P. Mann, 2006, Deep structure of theMerida Andes and Sierra de Perija mountain fronts, MaracaiboBasin, Venezuela: AAPG Bulletin, v. 90, p. 505–528.
Erlich, R., D. Pocknall, C. Yeilding, and M. Lorente, 1997, Chro-nostratigraphy, depositional environments, and reservoir po-tential of Eocene rocks, southern and central Merida Andes(Maracaibo and Barinas/Apure basins), western Venezuela, inK. Shanley and B. Perkins, eds., Shallow marine and nonmarinereservoirs: Gulf Coast Section SEPM Foundation 18th AnnualResearch Conference, Houston, p. 93–106.
Erlich, R., O. Macsotay, A. Nederbragt, and M. Lorente, 1999a,Palaecology, palaeogeography and depositional environmentsof Upper Cretaceous rocks of western Venezuela: Palaeogeog-raphy, Palaeoclimatology, Palaeoecology, v. 153, p. 203–238.
Erlich, R., S. Palmer-Koleman, and M. Lorente, 1999b, Geochem-ical characterization of oceanographic and climatic changesrecorded in upper Albian to lower Maastrichtian strata, West-ern Venezuela: Cretaceous Research, v. 20, p. 547–581.
Erlich, R., O. Macsotay, A. Nederbragt, and M. Lorente, 2000,
676 An Overview of the Petroleum System of Maracaibo Basin
Birth and death of the Late Cretaceous ‘‘La Luna Sea,’’ andorigin of the Tres Esquinas phosphorites: Journal of SouthAmerican Earth Sciences, v. 13, p. 21–45.
Erlich, R., T. Villamil, and J. Keen-Dumas, 2003, Controls on thedeposition of Upper Cretaceous organic carbon-rich rocksfrom Costa Rica to Suriname, in C. Bartolini, R. Buffler, andJ. Blickwede, eds., The circum-Gulf of Mexico and the Ca-ribbean: Hydrocarbon habitats, basin formation, and plate tec-tonics: AAPG Memoir 79, p. 1–45.
Escalona, A., 2003, Regional tectonics, sequence stratigraphy andreservoir properties of Eocene clastic sedimentation, Mara-caibo Basin, Venezuela: Ph.D. dissertation, University of Texasat Austin, Austin, 222 p.
Escalona, A., 2006, Petrophysical and seismic properties of lowerEocene clastic rocks in the central Maracaibo Basin: AAPGBulletin, v. 90, p. 679–696
Escalona, A., and P. Mann, 2003a, Paleogene depocenter alongthe northeast margin of the Maracaibo Basin: Structure alongan exhumed Eocene age lateral ramp fault in western Vene-zuela (abs.): AAPG Annual Meeting Program, v. 12, p. A50–51.
Escalona, A., and P. Mann, 2003b, Three-dimensional structuralarchitecture and evolution of the Eocene pull-apart basin,central Maracaibo Basin, Venezuela: Marine and PetroleumGeology, v. 20, p. 141–161.
Escalona, A., and P. Mann, 2004, Regional tectonics, sequencestratigraphy and reservoir properties of Eocene clastic sedi-mentation, Maracaibo Basin, Venezuela (abs.): AAPG AnnualMeeting Program, v. 13, p. A41.
Escalona, A., and P. Mann, 2006a, Tectonic controls of the right-lateral Burro Negro tear fault on Paleogene structure andstratigraphy, northeastern Maracaibo Basin: AAPG Bulletin,v. 90, p. 479–504.
Escalona, A., and P. Mann, 2006b, Sequence-stratigraphic analysisof Eocene clastic foreland basin deposits in central Lake Mar-acaibo using high-resolution well correlation and 3-D seismicdata: AAPG Bulletin, v. 90, p. 581–623.
Fiorillo, G., 1987, Exploration and evaluation of the Orinoco oilbelt, in R. Meyer, ed., Exploration for heavy crude oil andnatural bitumen: AAPG Studies in Geology 25, p. 103–144.
Gallango, O., E. Novoa, and A. Bernal, 2002, The petroleum sys-tem of the central Perija fold belt, western Venezuela: AAPGBulletin, v. 86, p. 1263–1284.
Gonzalez de Juana, C., J. Iturralde, and X. Picard, 1980, Geologıade Venezuela y de sus Cuencas Petrolıferas: Caracas, EdicionesFoninves, Tomos I y II, 1031 p.
Guzman, J., and W. L. Fisher, 2006, Early and middle Miocene de-positional history of the Maracaibo Basin, western Venezuela:AAPG Bulletin, v. 90, p. 625–655.
Halbouty, M., 2001, Giant oil and gas fields of the decade 1990–2000:http://www.searchanddiscovery.com/documents/halbouty03/index.htm (accessed June 2003).
Harding, T., and A. Tuminas, 1989, Structural interpretation ofhydrocarbon traps sealed by basement normal block faults atstable flank of foredeep basins and at rift basins: AAPGBulletin, v. 73, p. 812–840.
Horn, M., 2002, Burial histories/basin subsidence, data on a CD-ROM, available from [email protected].
Horn, M., 2003, Giant fields 1868–2003, data on a CD-ROM, inM. Halbouty, ed., Giant oil and gas fields of the decade 1990–1999: AAPG Memoir 78, 340 p.
Kellogg, J., 1984, Cenozoic tectonic history of the Sierra de Perija,Venezuela–Colombia, and adjacent basins, in W. Bonini, R.Hargraves, and R. Shagam, eds., The Caribbean–South Ameri-can plate boundary and regional tectonics: Geological Societyof America Memoir 162, p. 239–261.
Kellogg, J., and W. Bonini, 1982, Subduction of the Caribbean plateand basement uplifts in the overriding South American plate:Tectonics, v. 1, p. 251–276.
Kohn, B., R. Shagam, and T. Subieta, 1984, Results and preliminaryimplications of sixteen fission-track ages from rocks of westernCaribbean mountains, in W. Bonini, R. Hargraves, and R.Shagam, eds., The Caribbean–South American plate boundaryand regional tectonics: Geological Society of America Memoir162, p. 415–421.
Link, W., 1952, Significance of oil and gas seeps in world oil ex-ploration: AAPG Bulletin, v. 36, p. 1505.
Llanos, Y., C. Camposano, and F. Marcano, 2000, Modeladogeoquımico en el sur de la cuenca de Maracaibo, estado Zulia,Venezuela: VIII Simposio Bolivariano Exploracion Petroleraen las Cuencas Subandinas, Caracas, p. 537–546.
Lopatin, N., 1971, Temperature and geologic time as factors incoalification: Izvvestiya Akademii Nauk SSSR, Seriya Geolo-gicheskaya, v. 3, p. 95–106.
Lugo, J., 1991, Cretaceous to Neogene tectonic control on sedi-mentation: Maracaibo Basin, Venezuela: Ph.D. dissertation,University of Texas at Austin, Austin, 219 p.
Lugo, J., and P. Mann, 1995, Jurassic–Eocene tectonic evolution ofMaracaibo Basin, Venezuela, in A. Tankard, S. Suarez, and H.Welsink, eds., Petroleum basins of South America: AAPGMemoir 62, p. 699–725.
Macsotay, O., R. Erlich, and T. Peraza, 2003, Sedimentary struc-tures of the La Luna, Navay and Querecual formations, UpperCretaceous of Venezuela: Palaios, v. 18, p. 334–348.
Maguregui, J., 1990, Evolution and reservoir rock properties ofmiddle Eocene tide-dominated deltaic sandstones in easternLagunillas field, Maracaibo Basin, Venezuela: M.Sc. thesis,University of Texas at Austin, Austin, 172 p.
Mann, P., 1999, Caribbean sedimentary basins: Classification andtectonic setting from Jurassic to present, in P. Mann, ed., Ca-ribbean basins. Sedimentary basins of the world: Amsterdam,Elsevier Science B. V., v. 4, p. 3–31.
Mann, P., L. Gahagan, and M. Gordon, 2003, Tectonic setting ofthe world’s giant oil and gas fields, in M. Halbouty, ed., Giantoil fields of the decade 1990–1999: AAPG Memoir 78, p. 15–105.
Mann, P., A. Escalona, and M. V. Castillo, 2006, Regional geologicand tectonic setting of the Maracaibo supergiant basin, westernVenezuela: AAPG Bulletin, v. 90, p. 445–477.
Maze, W., 1984, Jurassic La Quinta Formation in the La Sierra dePerija, northwestern Venezuela; geology and tectonic environ-ment of red beds volcanic rocks, in W. Bonini, R. Hargraves,and R. Shagam, eds., The Caribbean–South American plateboundary and regional tectonics: Geological Society ofAmerica Memoir 162, p. 263–282.
Molina, A., 1992, Rosario field–Venezuela, Maracaibo Basin, Zuliastate, in N. H. Foster and E. A. Beaumont, compilers, Struc-tural traps VI: AAPG Treatise of Petroleum Geology, Atlas ofOil and Gas Fields, p. 293–304.
Molina, A., 1993, Tarra field–Venezuela, Maracaibo Basin, Zuliastate, in N. H. Foster and E. A. Beaumont, compilers, Struc-tural traps VI: AAPG Treatise of Petroleum Geology, Atlas ofOil and Gas Fields, p. 255–269.
Parnaud, Y., Y. Gou, J. Pascual, M. Capello, I. Truskowski, and H.Passalacqua, 1995, Stratigraphic synthesis of western Vene-zuela, in A. Tankard, S. Suarez, and H. Welsink, eds., Pe-troleum basins of South America: AAPG Memoir 62, p. 681–698.
Parra, M., L. Moscardelli, and M. Lorente, 2003, Late Cretaceousanoxia and lateral microfacies changes in the Tres EsquinasMember, La Luna Formation, western Venezuela: Palaios,v. 18, p. 321–333.
Escalona and Mann 677
Perez-Infante, J., P. Farrimond, and M. Furrer, 1996, Global andlocal controls influencing the deposition of the La Luna For-mation (Cenomanian–Campanian), western Venezuela: Chemi-cal Geology, v. 130, p. 271–288.
Pindell, J., and S. Barrett, 1990, Geological evolution of theCaribbean region: A plate tectonic perspective, in G. Dengoand J. Case, eds., The Caribbean region: Boulder, GeologicalSociety of America, The geology of North America, v. H,p. 405–432.
Ramirez, E., and F. Marcano, 1992, Ceuta-Tomoporo field, Vene-zuela, in M. Halbouty, ed., Giant oil and gas fields of thedecade: AAPG Memoir 54, p. 163–173.
Renz, O., 1981, Venezuela, in R. Reyment and P. Bengstone, eds.,Aspects of mid-Cretaceous regional geology: New York, Aca-demic Press, p. 197–220.
Salvador, A., 1986, Comments on ‘‘Neogene block tectonics of easternTurkey and northern South America: Continental applicationsof the finite difference method’’ by J. F. Dewey and J. L. Pindell:Tectonics, v. 5, p. 697–701.
Sanchez, N., 1993, Los Lanudos field, Venezuela, Maracaibo Basin,Zulia state, in N. H. Foster and E. A. Beaumont, compilers,Structural traps VIII: AAPG Treatise of Petroleum Geology,Atlas of Oil and Gas Fields, p. 217–229.
Schubert, C., 1982, Neotectonics of Bocono fault, western Vene-zuela: Tectonophysics, v. 85, p. 205–220.
Shagam, R., B. Kohn, P. Banks, L. Dasch, R. Varagas, G. Rodriguez,and N. Pimentel, 1984, Tectonic implications of Cretaceous–Pliocene fission-track ages from rocks of the circum-MaracaiboBasin region of western Venezuela and eastern Colombia, inW. Bonini, R. Hargraves, and R. Shagam, eds., Caribbean–South American plate boundary and regional tectonics: Geo-logical Society of America, p. 385–412.
Stephan, J., 1977, El contacto Cadena Caribe–Andes Meridenosentre Carora y el Tocuyo (edo. Lara): Observaciones sobre elestilo y la edad de las deformaciones Cenozoicas en el occi-dente Venezolano: Memorias V Congreso Geologico Venezo-lano, Caracas, p. 789–815.
Stephan, J., 1985, Andes et Chaine Caraibe sur La Transversal deBarquisimeto (Venezuela), Evolution geodynamique: Geody-namique des Caraibes, Symposium, Paris, Editions Technip,p. 505–529.
Taboada, A., L. Rivera, A. Fuenzalida, A. Cisternas, H. Phillip, H.Bijwaard, J. Olaya, and C. Rivera, 2000, Geodynamics of thenorthern Andes: Subductions and intracontinental deforma-tion (Colombia): Tectonics, v. 19, p. 787–813.
Talukdar, S., and F. Marcano, 1994, Petroleum systems of theMaracaibo Basin, Venezuela, in L. Magoon and W. Dow,eds., The petroleum system—From source to trap: AAPGMemoir 60, p. 463–481.
Talukdar, S., O. Gallango, and M. Chin-A-Lien, 1986, Generation andmigration of hydrocarbons in the Maracaibo Basin, Venezuela:An integrated basin study, in D. Leythaeuser and J. Rullkotter,eds., Advances in organic geochemistry 1985: Part I: OrganicGeochemistry, v. 10, p. 201–279.
Tocco, R., and A. Margarita, 1999, Geochemical study of Misoa For-mation crude oils, Centro Lago field, Lake Maracaibo, WesternVenezuela basin: Marine and Petroleum Geology, v. 16, p. 135–150.
U.S. Geological Survey, 2000, U.S. Geological Survey World Petro-leum Assessment 2000—Description and results: U.S. Geolog-ical Survey digital data series DDS-60 multidisc set version 1.12000, U.S. Geological Survey World Energy Assessment Team.
Villamil, T., C. Arango, and W. Hay, 1999, Plate tectonic pa-leoceanographic hypothesis for Cretaceous source rocks andcherts of northern South America, in E. Barrera and C. Johnson,eds., Evolution of Cretaceous ocean-climate system: GeologicalSociety of America Special Paper 332, p. 191–202.
Young, A., P. Monaghan, and R. Schweisberger, 1977, Calculationof ages of hydrocarbon oils—Physical chemistry applied topetroleum geochemistry I: AAPG Bulletin, v. 61, p. 573–600.
Yurewicz, D., D. Advocate, H. Lo, and E. Hernandez, 1998, Sourcerocks and oil families, southwest Maracaibo Basin (Catatumbosubbasin), Colombia: AAPG Bulletin, v. 82, p. 1329–1352.
Zambrano, E., E. Vasquez, B. Duval, M. Latreille, and B. Cof-finieres, 1971, Sıntesis paleogeografica y petrolera del occi-dente de Venezuela: Memorias Cuarto Congreso GeologicoVenezolano, Caracas, p. 483–552.
Zapata, E., V. Padron, I. Madrid, V. Kertznus, I. Truskowski, and M.Lorente, 2003, Biostratigraphic, sedimentologic, and chemo-stratigraphic study of the La Luna Formation (late Turonian–Campanian) in the San Miguel and Las Hernandez sections,western Venezuela: Palaios, v. 18, p. 367–377.
678 An Overview of the Petroleum System of Maracaibo Basin