c184-e012 gas chromatograph system

8/14/2019 C184-E012 Gas Chromatograph System

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C184-E012

Gas Chromatograph System


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Speed and Accuracy

Gas Chromatograph System

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High Performance Sensitive, high-speed analysis with excellent repeatability

Application Systems Pretreatment units (headspace gas analysis, pyrolysis) Distillation GC, PONA-GC, trace sulfur analysis

Easy Operation

Self-diagnostic functions and easy-to-see large display Carrier gas constantlinear velocity mode

Data Management GCSolution Ver. 2 workstation Simple operation and comprehensive basicfunctions enhance analysis productivity GLP/GMP compliant, network-compatible

Flexibility Simultaneously mount up to three injection units and four detectors Dualinjection system

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FPD

Sensitivity is Up

fivefold!!(In comparison with Shimadzu GC-17A)

Lens FPD-2010 Chromatogram of 5 ppb Phosphorus-based Pesticide1: Dichlorvos (DDVP) 2: Ethoprophos 3: Malathion 4: Phenthoate (PAP) 5:Fensulfothion 6: Edifenphos

Photomultiplier

Time (min.)

FPD-2010 Flame Photometric Detector Nozzle Filter

FPD-17 Chromatogram of 50 ppb Phosphorus-based Pesticide1: Dichlorvos (DDVP) 2: Ethoprophos 3: Malathion 4: Phenthoate (PAP) 5:Fensulfothion 6: Edifenphos

Time (min.)

Column: DB1 30 m 0.25 mm ID; df = 0.25 m Column temperature: 60C(1min)20C/min200C10C/min270C Injection unit temperature: 260C Detectortemperature: 280C Carrier gas: He Carrier gas linear velocity: 40 cm/s (constantlinear velocity mode) Detector H2 flowrate: 80 mL/min. Detector air flowrate: 120mL/min. Sample injection volume: 2 L (high-pressure splitless analysis)

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Accurate Analysis ResultsGAS CHROMATOGRAPH

Greater SpeedHigh-speed analysis with a narrow-bore capillary column reduces operator time andincreases samplethroughput. But it places stringent demands on inlet design andcarrier gas pneumatics (through high column back pressures and high split flowrates). The new-generation AFC digital flow controller supports high-speed

analysis at a maximum pressure of 970 kPa and 1200 mL/minute maximum flow rate.High-speed Analysis of Coffee FlavoringAnalysis time of previous modelDB-WAX 0.25mm 60m, 0.25m ( He 25cm/s )

60 minutes6 12 Rtx-WAX 0.1mm 20m, 0.1m ( He 25cm/s )

20 minutes3 5

Shorter analysis time with GC-2010

4 ms sampling 40 ms sampling

Workstation Engineered for High-speed AnalysisThe rapid 250 Hz (40 ms) detector data sampling rate of the GCsolution GCworkstation ensures sharp, accurate peaks for narrow-bore-column analysis.

Rapid Column Oven Heating and CoolingThe high-power oven achieves rapid heating. The column-oven cooling rate is animportant factor when conducting consecutive programmed-temperature gaschromatography analyses. The GC-2010 allows cooling from 450C to 50C in about 6minutes. Adding the optional high-speed cooling unit makes cooling even quicker.

Column oven temperature (C)

With optional cooling unit Standard GC-2010

Time (min.)

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Easy Operation Saves Time and Total

Easy OperationAn information rich, large display is provided to show a lot of information. Thetext and graphic screen lets you set the analysis conditions quickly and easily.The built-in help functions make operation training almost unnecessary after theinstrument in installed. Digital setting of all parameters, including temperaturesand flowrates, allows accurate reproduction of the analysis conditions.

Large Display

Large DisplayGraphic user interface Text display Built-in help functions Chromatogram display

Intelligent Self-diagnostic FunctionsExtensive self-diagnostic functions check that the instrument is functioningcorrectly. These functions conduct a detailed diagnosis that includes the septumand glass insert operating status, temperature sensor errors, supplied gaspressure, control status for each gas, ignition operation, DC voltage, and ADconverter. Regular diagnosis prevents unexpected downtime.

Self-diagnostic FunctionsUnit control check Hardware diagnosis Save and check diagnosis log

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CostGAS CHROMATOGRAPH

Constant Linear Velocity Mode Quickly Determines Separation ConditionsShimadzu presents carrier gas control based on the carrier gas linear velocity,which bears a direct correlation to the separation performance, instead of theconventional method using column inlet pressure and column flowrate settings. Theconstant linear velocity mode reduces the time taken to determine the analysis

conditions needed to obtain the optimal separation chromatogram.

Comparison of chromatograms with constant linear velocity and constant columninlet pressure

Constant linear velocity

(Pesticides Analysis)

Constant Linear Velocity ModeQuickly determines optimal analysis conditions Convenient method transfer betweenGCs and GC/MS

Constant column inlet pressureColumn: DB1 30 m 0.32 m ID; df = 0.25 m Column temperature: 60C(1min)7C/min230C Injection unit temperature:240C Detector temperature:270CFIDCarrier gas: He Carrier gas linear velocity: 40 cm/s (44.0 kPa column inletpressure) Sample injection volume: 1L (splitless analysis)

Comparison of the GC-FID chromatogram and GCMS-QP2010 total ion chromatogram (TIC)is also simple in the carrier gas constant linear velocity mode. Using the sametype of column and setting the same carrier gas linear velocity values results ina virtually identical separation profile. Comparison of GC-FID and GC/MS-TICChromatograms (Grob Test Mixture Analysis)

GC-FID

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GC/MS TIC


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min

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Unit Expandability Supports all AnalSimultaneously Mount Up to Three Injection Units and Four Detectors*Select from three injection units and five detector types to suit the needs of theanalysis and the target components. GCsolution allows up to four detectors to bemounted simultaneously. Options such as injection units, detectors, and auto-injectors can be easily added after installing the unit.* The number of units which can simultaneously mount up is limited according to akind.

Top of GC-2010

8 7 6 5

4For detectors

Comprehensive Range of Injection UnitsObtaining superior data requires selection of the optimal sample injection methodto suit the aim of the analysis and the target components. The GC-2010 can selectthe optimal injection mode from three types of injection unit.

Split/Splitless Injection Unit

SPL-2010

Standard unit for high-speed analysis with a narrow bore column. Gas saverfunction can restrict the amount of split gas used. Support high-pressureinjection.

Direct Injection Unit

WBI-2010

Incorporates a septum purge flowpath to restrict solvent tailing. Sharing

glass inserts with splitless analysis simplifies use (patented). (Contact yourShimadzu representative about connecting a packed column.)

On-column/Programmable Temperature Vaporizer Injection unit

OCI/PTV-2010

Handles sample injection using both cold on-column and PTV methods. Usesinactive, heat-resistant quartz PTV inserts. The optional simple OCI insertpermits use of a small-ID capillary column for the cold on-column method without a0.53 mm id. pre-column press-tight connection. Supports the analysis ofcompounds with a high boiling point (straight-chain hydrocarbons with 100 carbonnumber) .

For injection units

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ysis TypesCompact, Highly Sensitive Detector RangeThe detectors have been re-designed to be more compact. All detectors can beinstalled under the instrument top cover to allow easy mounting of each option andpretreatment unit. Each detector incorporates an APC (Advanced PressureController) that permits digital setting of the detector gas flowrate.

TCD

Thermal Conductivity Detector

TCD-2010

For the analysis of inorganic gases and concentrated organic compounds. Microvolume cell handles sharp peaks. Shorter stabilization time than previousShimadzu instruments.

Flame Ionization Detector

FID-2010 FID FID

For the general detection of organic compounds. Enhanced machining accuracy ofthe individual components restricts instrumental errors and improves sensitivity. Automatic ignition, extinguishing, and re-ignition functions Feedback functionreduces gas supply pressure to zero when extinguishing the hydrogen flame. Optional flame monitor can be mounted.

Electron Capture Detector

ECD-2010

Upgraded cell thermal insulation and reduced contamination improve sensitivity. Compact design achieves shorter stabilization times. In some countries,registration with the Ministry of Education, Culture, Sports, Science and

Technology under the Law Concerning Prevention from Radiation Hazards due toRadio-Isotopes, is required before purchasing or using this detector. (Contactyour Shimadzu representative for details.)

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GAS CHROMATOGRAPH

FPDFlame Photometric Detector

FPD-2010

For analysis of organic sulfur compounds and organic phosphorus compounds such

as residual pesticides and malodorous components. Updated optics improvesensitivity 5 times, compared with previous instruments. Nozzle constructionprevents adhesion and decomposition of the sample. Designed for compactness andhigh maximum operating temperature (350C). No tools needed for filterreplacement.

Filter replacement

CollectorCollector replacement

FTDFlame Thermionic Detector (NPD)

For analysis of organic nitrogen compounds and organic phosphorus compounds suchas residual pesticides. New collector construction allows collector replacementwithout tools. Optional alkali source regeneration kit saves running costs.

FTD-2010Remove screw Replace collector

Dual Injector System AOC-20i AOC-20sA dual injector system can be configured with a combination of two AOC-20i and oneAOC-20s unit. Two-line simultaneous injection doubles the number of samples toimprove productivity.

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Shimadzu Gas Chromatograph Workstation

Next-generation Workstation Dramatically Raises Productivity in the AnalysisLaboratorySimple Operation32-bit software incorporating the latest Windows technologies supports long file

names and Common operation and layout with other LabSolution software, such as Assistant Bar and

right-click menus, etc.

Data Explorer, ensures an intuitive common user interface that can be easilylearned.

Better Analysis ProductivityHandles control and data processing for up to four GC systems

(GC-2010, GC-17A, or GC-14B) Supports simultaneous processing of two samples on a single instrument and dual injection system for the ultimate in high throughputanalyses.

Comprehensive Basic FunctionsInherits the popular, proven and robust Chromatopac and CLASS-GC10 integration

algorithm. Comprehensive functions for peak identification, quantitation, and data comparison. Flexible report generation functions with operation similar to MS-Word.

GLP/GMP complianceFull support of user management functions and GC-2010 self-diagnostic functions

to enhance

data reliability. Supports rigorous GLP/GMP requirements, including audit-trailfunctions for all method parameters.

Network-compatibilityPromotes the efficient use of the network environment, such as in-office data

analysis Provides file sharing and centralized data management tools. (CLASS-Agent)

and remote access from the office. (GCsolution Post-run software, pcANYWHERE)

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User InterfaceThe latest Windows technologies offer multifunctionality and simple operation.User interface including drag-and-drop and right-click menus offers quick andintuitive operation

Easy-to-operate Assistant Bar and Data Explorer Navigate operations with Assistant Bar Even novices can easily conduct analysisor re-analysis simply by sequentially clicking on icons. Data Explorer displays

a list of files by type. Intuitively handle file operations by double-clicking ordrag-anddrop.

Assistant Bar

Data Explorer

Batch Table Wizard Simplifies Consecutive Analyses Easily create batch tables for consecutive analysis of multiple samples usingthe Wizard. Simply fill in the prompts in the Wizard to create multi-pointcalibration curves and batch tables for repeated analyses.

File Search Function offers Convenient Previews

Search any data file or method file. Search by file name, date, operator'sname, sample name, or sample ID. Use the preview function to check thechromatogram in the searched data files before opening the file.

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Data Analysis / Report GenerationBuilds on the popular Chromatopac and CLASS-GC10 basic functions, includingintegration algorithms. Offers comprehensive functions for identification,quantitation, data comparison, and report generation.

Identification and Quantitation Functions using Various Types of Calibration Curve Support for six quantitation methods, such as external and internal standardmethods, and seven types of calibration curve, including linear, point to point

and polynomial fits, ensures compatibility with an extensive range ofrequirements. Calibration curves can be created by dragging and dropping datafiles into the calibration window.

Data Comparison Function Display and compare up to eight chromatograms. Convenient for comparison ofprevious data and investigation of changes in time-course data. Selectsuperimposed or split-screen display. Conduct detailed analysis using addition,subtraction, differential, and second-order differential operations.

Flexible Report Generation Functions Highly flexible report generation. Paste and freely edit chromatograms andpeak tables. Save report formats as templates.

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GLP/GMP-FunctionsTo be compliant with management requirements and regulations such as GLP/GMP, avariety of sophisticated demands related to: analyzer reliability, methoddevelopment, analysis method validation, and electronic file management must besatisfied to ensure data integrity GCsolution Ver. 2 features even furtherstrengthened validation-related and user management functions. A Part11compatibility kit is available to provide full support for FDA 21 CFR Part 11compatibility.

User Management Functions to Control User Access Limit user access to operations by setting operation restrictions for theAdministrator, Method Developer, and Operator default user groups. Add or editgroups to create security that matches your laboratory work format.

Validation Support - fully supports GC-2010 self-diagnostic functions Fully supports the GC-2010 self-diagnostic functions. Periodic checks of the GCstatus supports superior analysis and greater confidence in your results. Includes software-validation functions to check for software modifications. QA/QC functions offer pass/fail evaluation based on repeatability of componentconcentrations, recovery rate, or check of concentration upper/lower limit.

Audit Trail including Parameter Setting Log The changes and the reasons for the changes to instrument parameters and data-processing parameters can be saved to confirm the traceability of consecutiveanalysis results. Data files contain the method used for data acquisition andthe latest data, allowing data to be reverted to the pre-analysis state.

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Network-compatibilityUsing a network such as an in-house LAN or the Internet allows centralized datamanagement and the sharing of files containing data or analysis methods. Inaddition to the basic workstation software, GCsolution offers a range of networktools to enhance analysis efficiency.

Other office PCInternet data browser (CLASS-Agent Web Manager)

Browsing data over the Internet

Internet

PC Server DB PCDatabase PC server

GC-LAN connection LAN adaptor Data acquisition over LAN (GC-LAN connectionsoftware)

GC

Factory

PC GC Automatic data archive (GCsolution Agent) Data approval and browsing PCDatabase browsing (CLASS-Agent Manager) GCsolution Ver.2

GC GCRS -23 2C

Analysis laboratory

PCEth erN

GC Control of four GC units

GCsolution Ver.2ET -LA N

PC

Access to LAN PC

Remote access Office PC

Post-run software (GCsolution Ver. 2)

Remote access software (pcANYWHERE)

CLASS-Agent for Centralized Data ControlCLASS-Agent Data Management System Software for centralized data management.

Measured data automatically saved in the database. Browsing software easilyfinds target data. Browse data over the Internet. Compatible with Oracle,Access, and SQL databases. GCsolution Ver. 2 Post-run Software Install the post-run software in a separate PC on the LAN to allow data analysis in theoffice.

Remote PC and GC Access


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pcANYWHERE* remote access software Dedicated software for remote access of a laboratory PC from an office PC. GC-LAN connection software Offers remote GC control and data acquisition in a LAN environment. Connects the GC instrument toPCs over a LAN using a LAN adaptor.

*pcANYWHERE is a product of Symantec Corporation.

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Analysis Systems for Every ApplicationHeadspace Analysis System A sample sealed in a vial is heated for a certain time before the vapor phase inthe headspace is analyzed. Used to analyze the volatile components in solid orliquid samples.System Configuration (GC with headspace sampler)

GC-2010 + AOC-5000

Analysis Applications

Measurement of residual solvents in pharmaceuticals Measurement of aromaticcomponents in foods

Pyrolysis System Decomposes samples at high temperatures and analyzes the pyrolytic decompositionproducts. Used to analyze high molecular weight compounds such polymers,forensic samples etc.System Configuration (GC with double-shot pyrolyser)

GC-2010 + PY-2020D Autosampler and cryotrap accessories available.Analysis Applications

Characterization of high molecular weight compounds Measurement of outgassingfrom inorganic samples, such as ceramics

Trace Sulfur Impurity Analysis System Incorporates a high-sensitivity SCD (Sulfur Chemiluminescence Detector) thatsuppresses the quenching phenomenon. Used to analyze sulfur compounds in mainlyhydrocarbon samples.System Configuration (GC with SCD)

GC-2010 + SCD (manufactured by Antek) SCD: Sulfur Chemiluminescence DetectorAnalysis Applications

Measurement of trace sulfur in oils such as gasoline and kerosene. Evaluationof desulfurization catalysts.

Distillation GC System Measures the boiling point distribution of petroleum fractions using therelationship between retention time and boiling point. Prints formatted reportsafter analysis of distillation characteristics.System Configuration (Distillation GC)

GC-2010 + WBI-2010, or OCI-2010 + GCsolution + distillation GC software (Selectsample injection unit and column to suit the target sample.)Analysis Applications

Petroleum fractions

PONA Analysis System Separates gasoline or other hydrocarbon compounds; identifies the peaks;classifies them by carbon number, paraffin, olefin, naphthene, and aromaticseries; and conducts quantitation.System Configuration (PONA GC)

GC-2010 + CRG-2010 + GCsolution + PONAsolution + MS Excel (Select sampleinjection unit and column to suit the target sample.)Analysis Applications


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Categorization of naphtha, gasoline and gasoline-based materials by carbonnumber and quantitation by type. (Also offers calculation of mean specificgravity, mean molecular weight, and octane value.)

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Direct injection mode

GC-2010 SpecificationsColumn Oven

Temperature range: room temperature + 4C to 450C (using liquid CO2 gas*: -50Cto 450C) Dimensions: 280 (w) x 280 (H) x 175 (D) mm Oven volume: 13.7 LTemperature accuracy: set value (K) 1% (calibration at 0.01C) Temperature

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trail, software validation, security, Part11 compatibility kit (option) Post-runapplication software (option, secondary right of use), GC-LAN connectability(option)Network Compatibility GLP/GMP-related Hardware Functions Files Report Generation Data Processing and Data Analysis Data Acquisition Instrument Control Software Specification

Temperature range: room temperature + 5C to 450C

Direct Injection Unit (WBI-2010)

Temperature range: room temperature + 5C to 450COn-column/Programmable Temperature Vaporizer Injection Unit (OCI/PTV-2010)

Temperature range: room temperature + 5C to 450C Heating rate: 50C to 450Cwithin 3 minutes Cooling rate: 450C to 50C within 8 minutes (for 50C columntemperature) Heating program: max. heating rate 250C/minute, heating in 7 stepsSwitching possible between on-column and programmable temperature vaporizerinjection units (requires split piping re-connection between OCI and PTV) To keepinstrument specifications, max. 2 injection ports shall be heated simultaneously.Four detectors can be installed simultaneously and individually temperaturecontrolled. Detector gas is electronically controlled by APC (Advanced Pressure

Control).Flame Ionization Detector (FID) Detectors

Temperature range: to 450C Minimum detected quantity: 3 pgC/s (dodecane) Dynamicrange: 107Thermal Conductivity Detector (TCD)

Temperature range: to 400C Sensitivity: 20000 mV.mL/mg (decane) Dynamic range:105Electron Capture Detector (ECD)

Temperature range: to 350C Minimum detected quantity: 8 fg/s (g-BHC) Dynamicrange: 104

Flame Photometric Detector (FPD)

Temperature range: to 350C Minimum detected quantity: P 0.2 pgP/s (tributylphosphate) S 4 pgS/s (dodecane thiol) Dynamic range: Phosphorus mode: 104 Sulfurmode: 103Flame Thermionic Detector (FTD, also called NPD or TSD)

Temperature range: to 450C Minimum detected quantity: N 0.3 pgN/s (azobenzene) P0.03 pgP/s (malathion) Dynamic range: N, P 103 To keep instrument performance,max. 2 detectors shall be operated simultaneously.Flow Control Unit Split/splitless mode

PC Requirements for GCsolution

(1) CPU: Celeron, 600 MHz or faster, RAM: 128 MB or greater HDD: 10.2 GB orgreater 24x speed CD-ROM, OADG keyboard 100BASE-TX/10BASE-T LAN interface (2)Software Windows NT 4.0 (SP5) or Windows 2000 (3) Display (4) 1 x RS-232C cable 2mfor connecting to GC-2010

Advanced Flow Controller (AFC) Pressure setting range: 0 to 970 kPa Programmablesteps: 7 (cooling program possible) Programmed rate setting range: -400 to 400kPa/min. Split ratio setting range: 0 to 9999.9 Total flowrate setting range: 0 to1200 mL/min. Column average linear velocity can be kept constant while temperatureis increasing.


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GCMS-QP2010 Gas Chromatograph-Mass SpectrometerThe QP2010 provides optimum performance analysis for all GCMS measurements. High-speed GCMS capability and optimum separation are standard with every QP2010. OurGCMS with Lab Solutions software can analyze more unattended samples than anyother product. Unique system checking verifies ideal operation. QP2010 and GC-2010continue the tradition of performance and maintenance simplicity - Shimadzutrademarks. Scan Sensitivity over 60/1 for 1pg OFN Superior High-Speed GCMS. 20 Temperature Ramps and patented Constant Linear Velocity for optimum separation.

Front access for easy maintenance and direct probe for flexibility. Pump downin under 4 minutes and input up to 15mL/min flow into the ion source. Optionalpositive and negative chemical ionization. Optional direct inlet kit

SHIMADZU CORPORATION. International Marketing Division

3. Kanda-Nishikicho 1-chome, Chiyoda-ku, Tokyo 101-8448, Japan Phone: 81(3)3219-5641 Fax. 81(3)3219-5710 Cable Add.:SHIMADZU TOKYOSHIMADZU SCIENTIFIC INSTRUMENTS, INC.

7102 Riverwood Drive, Columbia, Maryland 21046, U.S.A. Phone: 1(410)381-1227 Fax.1(410)381-1222 Toll Free: 1(800)477-1227SHIMADZU DEUTSCHLAND GmbH

Albert-Hahn-Strasse 6-10, D-47269 Duisburg, F.R. Germany Phone: 49(203)7687-0 Fax.49(203)766625SHIMADZU (ASIA PACIFIC) PTE LTD.

16 Science Park Drive #01-01 Singapore Science Park, Singapore 118227, Republic ofSingapore Phone: 65-778 6280 Fax. 65-779 2935SHIMADZU SCIENTIFIC INSTRUMENTS (OCEANIA) PTY. LTD.

Units F, 10-16 South Street Rydalmere N.S.W. 2116, Australia Phone: 61(2)9684-4200Fax. 61(2)9684-4055SHIMADZU DO BRASIL COMERCIO LTDA.

Rua Cenno Sbrighi, 25, Agua Branca, Sao Paulo, CEP 05036-010, BRAZIL Phone:(55)11-3611-1688 Fax. (55)11-3611-2209SHIMADZU (HONG KONG) LIMITED

Suite 1028 Ocean Center, Harbour City, Tsim Sha Tsui, Kowloon HONG KONG Phone:(852)2375-4979 Fax. (852)2199-7438Overseas Offices

Istanbul, Beijing, Shanghai, Guangzhou, Shenyang, Chengdu, Moscow

URL http://www.shimadzu.com

Printed in Japan 3295-12203-50ATD

The contents of this brochure are subject to change without notice.


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c184-e012 gas chromatograph system

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