carbonyl condensation reactions...carbonyl condensation reactions. aldol reaction: step 1. aldol...

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Carbonyl condensation reactions

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Page 1: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Carbonyl condensation

reactions

Page 2: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Aldol reaction: step 1

Page 3: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Page 4: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Aldol reaction: step 2

Page 5: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Page 6: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Claisen reaction

Page 7: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Page 8: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Michael reaction

Page 9: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Page 10: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Robinson annulation

Page 11: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Page 12: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Directed aldol reaction: step 1

Page 13: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Page 14: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Directed aldol reaction: step 2

Page 15: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Page 16: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Intramolecular aldol reaction

With 1,4-dicarbonyl compounds

Page 17: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Page 18: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Intramolecular aldol reaction

With 1,5-dicarbonyl compounds

Page 19: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Page 20: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Dieckmann reaction

With 1,6-diesters

Page 21: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Page 22: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Dieckmann reaction

With 1,7-diesters

Page 23: Carbonyl condensation reactions...Carbonyl condensation reactions. Aldol reaction: step 1. Aldol reaction: step 2. ... step 2. Intramolecular aldol reaction With 1,4-dicarbonyl compounds

Aldol Reaction Time-Line · 1 The Selective Aldol Reaction Alan B. Northrup MacMillan Group Meeting September 18, 2002 A Brief Recent General Review: Palomo, C.; Oiarbide, M.; Garc

Myers Stereoselective, Directed Aldol Reaction Chem 115 · Myers Stereoselective, Directed Aldol Reaction Chem 115 ... chair-like, pericyclic process. In practice, the stereochemistry

Recent Advances on Asymmetric Nitroso Aldol Reaction · Recent Advances on Asymmetric Nitroso Aldol Reaction Pedro Merino,*a Tomás Tejero,a Ignacio Delsoa,b and Rosa Matutec a Laboratorio

CHAPTER 12 MECHANISM OF · PDF filereaction prior to the aldol condensation. ... driving force effect of deprotonation ... Thus, crossed aldol condensation is crossed aldol reaction

UNIT III: Carbonyl compounds (Name Reaction)

Stereoselective, Directed Aldol Reaction

II. Special Topics IIA. Enolate Chemistry & the Aldol Reactionccc.chem.pitt.edu/wipf/Courses//2320_06-files/IIA_Aldol.pdfClaisen-Schmidt reaction. A crossed aldol condensation in which

Multi-Step Application of Immobilized Reagents and ... · application of the asymmetric Mukaiyama aldol reaction de-veloped by Kiyooka (Scheme 3).[33] Aldol reaction, mediated by

Copper(I)-Catalyzed Enatio- and Diastereoselctive Tandem Reductive Aldol Reaction

Another Equilibrium: Reaction At The α-Position 17.pdf · 2008. 4. 10. · The Cannizaro Reaction H O Me KOH H2O Aldol reaction products H O KOH H2O HO O HO + 50% 50%. The Aldol

CARBONYL COMPOUNDS OXIDATION-REDUCTION REACTION · 2017-10-04 · Introduction Several functional groups contain the carbonyl group Carbonyl groups can be converted into alcohols

14.3 Aldol Reaction and Claisen Condensation in Biology Enol – Keto Tautomerization Aldol Reaction Claisen Condensation Main Menu

Applications of Mukaiyama aldol reaction

ABIKO MASAMUNE Asymmetric Aldol Reaction A - …booksite.elsevier.com/samplechapters/9780080966304... · ABIKO–MASAMUNE Asymmetric Aldol Reaction ... 1 Brown HC Tet Lett 1992 33

Application of Oxazolines in Asymmetric Aldol Reaction …shodhganga.inflibnet.ac.in/bitstream/10603/36788/10/10_chepter 3.pdf · Application of Oxazolines in Asymmetric Aldol Reaction

The Vinylogous Aldol Reaction - The Evans Group …evans.rc.fas.harvard.edu/pdf/smnr_2001-2002_Burch_Jason.pdf · The Vinylogous Aldol Reaction Synthesis and Methodology Evans Group

Development of catalytic asymmetric aldol reaction- a ...shodhganga.inflibnet.ac.in/bitstream/10603/93486/10/10_chapter1.pdf · developed.1,22 Their early applications in the aldol

I. LEWIS BASE-CATALYZED ALDOL REACTION IN THE TOTAL ...d-scholarship.pitt.edu/7211/1/Fu_Dezhi-4082011_1.pdf · i. lewis base-catalyzed aldol reaction in the total synthesis of erythronolide

Mechanism of MOF-505 and Cu-ZSM-5 Promoted Mukaiyama Aldol ... · The Mukaiyama aldol reaction, an acid-catalyzed aldol reaction between a silyl enol ether and a carbonyl compound,

Aldol Reaction Time-Line - Princeton University Selective Aldol Reaction Alan B ... Model Holds for a Variety of Enolates Both E ... One of the most reliable and predictable reactions

Aldol Reaction - Wikipedia, The Free Encyclopedia

Aldol Reaction Time-Linechemlabs.princeton.edu/.../sites/6/Northrup_aldol.pdf2 Racemic Aldol Technology Aldol Reaction Discovered Independently By Charles Adolphe Wurtz in Germany

Proline catalyzed aldol reaction

Enols and Enolates A major type of reaction with carbonyl

2. Reaction of Carbon Nucleophile with Carbonyl Group

Chiral Benzimidazoles as Hydrogen Bonding Organocatalysts · organocatalysts in aldol and amination reactions of carbonyl compounds. 1. Introduction Benzimidazole, firstly described

The Vinylogous Aldol Reaction: Application in Synthesissites.northwestern.edu/scheidt/files/2011/11/111604_CHan... · The Vinylogous Aldol Reaction: Application in Synthesis Audrey

Myers Stereoselective, Directed Aldol Reaction Chem 115 · 2014-02-24 · Myers Stereoselective, Directed Aldol Reaction Chem 115 M. Movassaghi Evans, D. A.; Takacs, J. M.; McGee,

α-Carbonyl Nucleophilesstaffnew.uny.ac.id/upload/132162017/pendidikan/KO+II.+Kondensasi+aldol.pdf1 α-Carbonyl Nucleophiles Michael and Stork reactions Aldol condensation Claisen

Reactions involving carbonyl compounds · The reactions of carbonyl compounds are one of the most important class of synthetically useful reaction in organic chemistry. The carbonyl

Development of Stereoselective Vinylogous Mukaiyama Aldol Reaction … · 2019-07-19 · Development of Stereoselective Vinylogous Mukaiyama Aldol Reaction and Application to Natural

Addition Reaction of Carbonyl

An efficient catalyst-free Mukaiyama-aldol reaction …1 An efficient catalyst-free Mukaiyama-aldol reaction of fluorinated enol silyl ethers with tryptanthrin Fu-Min Liao,† Yun-Lin

1 The Selective Aldol Reaction

Addition of Organochromium Reagents to Carbonyl Compoundschemistry-chemists.com/chemister/Polytom-English/organic-reaction… · Reactions of organochromium reagents with carbonyl