cascadereactions · a cascade reaction is a process in which several bonds are formed in sequence...
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Cascade Reactions
Magnus Pfaffenbach Gaich-‐Group Seminar November 12, 2012
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Gaich-‐Group Seminar Magnus Pfaffenbach
Overview and Definition
Definition (strict): A cascade reaction is a process in which several bonds are formed in sequence without isolating intermediates, changing conditions or adding reagents.
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Gaich-‐Group Seminar Magnus Pfaffenbach
Pro and Contra
Practical Advantages: - Atom economy - Reduction of time, labor, waste and resources - „Green Chemistry“
Academic Considerations: - Fast access to structures with increased complexity - Aesthetic appeal to synthetic planning
Disadvantages: - Synthesis of precursors often far from trivial - Few examples of catalytic enantioselective cascade reactions
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Gaich-‐Group Seminar Magnus Pfaffenbach
Classic Examples
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Gaich-‐Group Seminar Magnus Pfaffenbach
Classic Examples
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Gaich-‐Group Seminar Magnus Pfaffenbach
Classic Examples
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Gaich-‐Group Seminar Magnus Pfaffenbach
Classic Examples
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Gaich-‐Group Seminar Magnus Pfaffenbach
Nucleophilic Cascades
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Gaich-‐Group Seminar Magnus Pfaffenbach
Nucleophilic Cascades
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Gaich-‐Group Seminar Magnus Pfaffenbach
Electrophilic Cascades
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Gaich-‐Group Seminar Magnus Pfaffenbach
Electrophilic Cascades
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Gaich-‐Group Seminar Magnus Pfaffenbach
Electrophilic Cascades
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Gaich-‐Group Seminar Magnus Pfaffenbach
Radical Cascades
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Gaich-‐Group Seminar Magnus Pfaffenbach
Radical Cascades
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Gaich-‐Group Seminar Magnus Pfaffenbach
Pericyclic Cascades
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Gaich-‐Group Seminar Magnus Pfaffenbach
Pericyclic Cascades
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Gaich-‐Group Seminar Magnus Pfaffenbach
Transition Metal-Catalyzed Cascades
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Gaich-‐Group Seminar Magnus Pfaffenbach
Diazo Compound Initiated Cascades
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Gaich-‐Group Seminar Magnus Pfaffenbach
Thank you for your attention!
Questions?