cheminform abstract: amidocarbonylation of aldehydes utilizing cobalt oxide-supported gold...
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Aminocarboxylic acids (hydrazinocarboxylic acids) and estersP 0270 Amidocarbonylation of Aldehydes Utilizing Cobalt Oxide-Supported Gold Nano-
particles as a Heterogeneous Catalyst. — The transformation of aldehydes (I) and their equivalents (V) and (VII) affords N-acyl-α-amino acid derivatives (IV), (VI) and (VIII). The desired products are obtained in moderate to high yields under milder reac-tion conditions with respect to pressure and temperature compared to previous reports employing octacarbonyldicobalt as a catalyst. — (HAMASAKI, A.; LIU, X.; TOKUNAGA*, M.; Chem. Lett. 37 (2008) 12, 1292-1293; Dep. Chem., Fac. Sci., Kyushu Univ., Higashi, Fukuoka 812, Japan; Eng.) — M. Paetzel
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ChemInform 2009, 40, issue 19 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim