co-combustion of coal and spent coffee grounds blends in a...

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Eduardo Garcia*, Hao Liu Low Carbon Energy and Resources Technologies Research Group, Faculty of Engineering, University of Nottingham, University Park, Nottingham, NG7 2RD, UK *[email protected] Co-combustion of coal and spent coffee grounds blends in a fluidized bed reactor References [1] Guo, F., Zhong, Z. (2018). Co-combustion of anthracite coal and wood pellets: Thermodynamic analysis, combustion efficiency, pollutant emissions and ash slagging. Environmental Pollution, 239(2018) 21-29. [2] Sirisomboon, K., Kuprianov, V. (2017). Effects of fuel staging on the NO emission reduction during biomass-biomass co- combustion in a fluidized-bed combustor. Energy and Fuels, 31, 659−671. [3] Reddy, P., Clean coal Technologies – for power generation. CRC press. 2014. Co-combustion of coal and biomass is quite a promising alternative in the short-term to achieve major reductions in GHG emissions from coal power sector, but it still faces unsolved challenges [1] [2]. A higher biomass ratio than the currently used in most commercial applications, 5-10 % (energy basis) [3], means lower GHG emissions. However, higher ratios raise concerns about combustion efficiency, GHG emissions and ash issues. Spent coffee grounds (SCG), a by-product from the coffee industry, has similar heating values to low-rank coals. SCG is available in large quantities, and almost free in every soluble coffee plant and coffee shop. Its use represents a sustainable alternative to the increasing adverse environmental impact of this industrial sector in recent years. SCG used as a fuel in co-combustion with coal appears as a feasible sustainable alternative due to the increased combustion performance in fluidized bed combustion compared to pure coal, and STW and WP. Nevertheless, the fuel-N in SCG arises as a challenge that need to be addressed by the optimization of operational conditions. In future the effect of blending ratio on emissions and agglomeration tendency under extended operation time will be tested upon different conditions. Conclusions and Future work Background Figure 6. Schematic diagram of the bubbling fluidized bed (BFB) Preliminary Results Figure 7. Comparison of emissions (energy basis) from spent coffee grounds (SCG) compared to wheat straw (STW) and wood (WP), and pure coal (BC); CO2 emissions (a), CO emissions (b), NOx emissions (c), and efficiency losses due to unburned carbon (UBC) and CO emissions (d). Related UN sustainable goals a b c d Experimental setup The 30 kW BFB reactor, 15.4 cm ID and 2 m height. After initial heating up by the electric heaters, the fuel blends were fed by the screw feeder to start the combustion and adjusted to maintain the operational temperature. Blends of coal with commercial wheat straw (STW) and wood (WP) pellets were considered for comparison. Operational conditions: Bed material: Silica sand, 0.6 – 1.0 mm Fuel feeding rate: 2.2 -2.6 kg/h Bed Height: 20 cm (shallow bed) Excess air: 75 – 95 % Temperature: 900 °C Operational time: 20 hours The flue gas composition (CO, CO2,O2 and NOx) was analysed online using flue gas analysers. The ash and used bed particles were collected from the cyclone and reactor at the end of each experiment, respectively. To investigate the feasibility of co-combustion of spent coffee grounds with coal in a fluidized bed reactor in terms of the most representative emissions (CO2, CO and NOx), combustion performance and agglomeration tendency. Objective Discussion Co-combustion experiments of bituminous coal (12-20 mm) and in- house manufactured SCG pellets blended at 40 wt% were performed in a BFB. All the blends showed increased combustion performance compared to pure coal. It is attributed to higher volatile matter from biomass increasing the reactivity of coal. Combustion of blends of coal and SCG pellets showed lower CO emissions than the blend with WP, with similar values to the blend with STW and pure coal. Unlike blends with STW and WP, the blend with SCG did not show any decrease in NOx emissions in comparison with pure coal combustion. It is attributed to higher nitrogen content in SCG compared to the other fuels. No relevant difference was found among the blends with different biomass fuels in terms of CO2 emissions. Blends with SCG showed reduced efficiency loss due to CO emissions and unburned carbon compared to other biomass fuels and pure coal. No evidence of agglomeration was detected during operation for blends with SCG. Figure 2. Silica sand Figure 3. In-house manufactured SCG pellets Figure 4. Fuel blend 0 200 400 600 800 1000 0:00:00 0:42:30 1:25:00 2:07:30 2:50:00 3:32:30 4:15:00 4:57:30 5:40:00 6:22:30 7:05:00 7:47:30 Temperature (°C) Time (h) T2 T3 T4 T5 T6 Start-up Fuel combustion 0 100 200 300 400 500 0 5 10 15 20 NOx Conc. (ppm) CO2, CO, O2 Conc. (% vol.) Time (h) CO2 O2 CO NOx Start-up Fuel combustion Figure 5. Typical profiles: (left) Temperature (right) emissions Acknowledgement This work was supported by the Administrative Department of Science, Technology and Innovation of Colombia – COLCIENCIAS and The Newton-Caldas Fund. 73.18 86.75 72.69 71.13 0 20 40 60 80 100 100 BC 40 WP 40 STW 40 SCGP CO Emissions (ng/MJ) 409 322 300 407 0 100 200 300 400 500 100 BC 40 WP 40 STW 40 SCGP (NOx Emissions (ng/MJ) 8.68 6.57 7.85 1.22 0.14 0.15 0.13 0.09 0 2 4 6 8 10 12 100 BC 40 WP 40 STW 40 SCGP Efficiency loss (%) UBC CO emmissions 83.47 92.86 89.14 95.26 0 20 40 60 80 100 100 BC 40 WP 40 STW 40 SCGP CO2 Emissions (g/MJ) Heat Power Technical approach Figure 1. Schematic description of energetic use of spent coffee grounds

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Page 1: Co-combustion of coal and spent coffee grounds blends in a ...ukccsrc.ac.uk/sites/default/files/documents... · Co-combustion of coal and biomass is quite a promising alternative

Eduardo Garcia*, Hao Liu

Low Carbon Energy and Resources Technologies Research Group, Faculty of Engineering, University of Nottingham, University Park, Nottingham, NG7 2RD, UK

*[email protected]

Co-combustion of coal and spent coffee grounds blends in a fluidized bed reactor

References[1] Guo, F., Zhong, Z. (2018). Co-combustion of anthracite coal and wood pellets: Thermodynamic analysis, combustion efficiency, pollutant emissions and ash slagging. Environmental Pollution, 239(2018) 21-29.

[2] Sirisomboon, K., Kuprianov, V. (2017). Effects of fuel staging on the NO emission reduction during biomass-biomass co-combustion in a fluidized-bed combustor. Energy and Fuels, 31, 659−671.[3] Reddy, P., Clean coal Technologies – for power generation. CRC press. 2014.

Co-combustion of coal and biomass is quite a promising alternative in the short-term to achieve major reductions in GHG emissionsfrom coal power sector, but it still faces unsolved challenges [1] [2]. A higher biomass ratio than the currently used in mostcommercial applications, 5-10 % (energy basis) [3], means lower GHG emissions. However, higher ratios raise concerns aboutcombustion efficiency, GHG emissions and ash issues. Spent coffee grounds (SCG), a by-product from the coffee industry, has similarheating values to low-rank coals. SCG is available in large quantities, and almost free in every soluble coffee plant and coffee shop.Its use represents a sustainable alternative to the increasing adverse environmental impact of this industrial sector in recent years.

SCG used as a fuel in co-combustion with coal appears as a feasiblesustainable alternative due to the increased combustionperformance in fluidized bed combustion compared to pure coal, andSTW and WP. Nevertheless, the fuel-N in SCG arises as a challengethat need to be addressed by the optimization of operationalconditions. In future the effect of blending ratio on emissions andagglomeration tendency under extended operation time will betested upon different conditions.

Conclusions and Future work

Background

Figure 6. Schematic diagram of the bubbling fluidized bed (BFB)

Preliminary Results

Figure 7. Comparison of emissions (energy basis) from spent coffee grounds (SCG) compared to wheatstraw (STW) and wood (WP), and pure coal (BC); CO2 emissions (a), CO emissions (b), NOx emissions

(c), and efficiency losses due to unburned carbon (UBC) and CO emissions (d).

Related UN sustainable goals

a b

c d

Experimental setupThe 30 kW BFB reactor, 15.4 cm ID and 2 mheight. After initial heating up by the electricheaters, the fuel blends were fed by the screwfeeder to start the combustion and adjusted tomaintain the operational temperature. Blends ofcoal with commercial wheat straw (STW) and wood(WP) pellets were considered for comparison.

Operational conditions:

• Bed material: Silica sand, 0.6 – 1.0 mm• Fuel feeding rate: 2.2 -2.6 kg/h• Bed Height: 20 cm (shallow bed)

• Excess air: 75 – 95 %• Temperature: 900 °C• Operational time: 20 hours

The flue gas composition (CO, CO2, O2 and NOx)was analysed online using flue gas analysers. Theash and used bed particles were collected from thecyclone and reactor at the end of each experiment,respectively.

To investigate the feasibility of co-combustion of spent coffee groundswith coal in a fluidized bed reactor in terms of the mostrepresentative emissions (CO2, CO and NOx), combustionperformance and agglomeration tendency.

Objective

DiscussionCo-combustion experiments of bituminous coal (12-20 mm) and in-house manufactured SCG pellets blended at 40 wt% wereperformed in a BFB. All the blends showed increased combustionperformance compared to pure coal. It is attributed to highervolatile matter from biomass increasing the reactivity of coal.Combustion of blends of coal and SCG pellets showed lower COemissions than the blend with WP, with similar values to the blendwith STW and pure coal. Unlike blends with STW and WP, the blendwith SCG did not show any decrease in NOx emissions incomparison with pure coal combustion. It is attributed to highernitrogen content in SCG compared to the other fuels. No relevantdifference was found among the blends with different biomass fuelsin terms of CO2 emissions. Blends with SCG showed reducedefficiency loss due to CO emissions and unburned carbon comparedto other biomass fuels and pure coal. No evidence of agglomerationwas detected during operation for blends with SCG.

Figure 2. Silica sand

Figure 3. In-house manufactured SCG

pellets

Figure 4. Fuel blend

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Figure 5. Typical profiles: (left) Temperature (right) emissions

Acknowledgement

This work was supported by the Administrative Department of Science, Technology and Innovation of Colombia – COLCIENCIAS and The Newton-Caldas Fund.

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Technical approach

Figure 1. Schematic description of energetic use of spent coffee grounds