communications devices hirohito yamada lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

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Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

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Page 1: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Communications Devices

Hirohito YAMADA

Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Page 2: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

About lecture

1. Schedule   6/23 Basic of semiconductor photonic devices   6/27 Matter-electromagnetic wave interaction based on semi-classical theory   6/30 Electromagnetic field quantization and quantum theory   7/7 Optical transition in semiconductor, Photo diode, Laser diode   7/14 Optical amplifier, Optical modulator, Optical switch,

Optical wavelength filter, and Optical multiplexer/demultiplexer   7/21 Summary

2. Textbook written in Japanese  米津 宏雄 著、光通信素子工学 - 発光・受光素子 - 、工学図書  霜田 光一 編著、量子エレクトロニクス、裳華房  山田 実著、電子・情報工学講座 15 光通信工学、培風館  伊藤弘昌 編著、フォトニクス基礎、朝倉書店 第 5 章

3. Questions   E-mail: [email protected], or ECEI 2nd Bld. Room 203

4. Lecture note dounload   URL: http://www5a.biglobe.ne.jp/~babe

Page 3: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

http://www.jpix.ad.jp/en/technical/traffic.html

Data traffic explosion on the Internet

Trend of data traffic processed by a domestic network node

Double/3 years

Rapid increase of double per 2.5 years

Dat

a ra

te (

Gbi

t/s)

M/D/Y

double/year

Double/5 years

Double/2.5 years

Page 4: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

year

2005 2006 2007 2008 2009 2010 20112004 20132012

Cited from: H26 年度版情報通信白書

Total download traffic in Japan

Total upload traffic in Japan

Daily average value

Growth of internet traffic in Japan

Total download traffic in Japan was about 2.6T bps at the end of 2013

Annual growth rate: 30%

Page 5: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Optical fiber submarine networks

Cited from http://www1.alcatel-lucent.com/submarine/refs/index.htm

Page 6: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Power consumption forecast of network equipments

Domestic internet traffic is increasing 40%/yearIf increasing trend continue, by 2024, power consumption of ICT equipments will exceed total power generation at 2007

http://www.aist-victories.org/jp/about/outline.html

Ann

ual p

ower

con

sum

ptio

n of

ne

twor

k eq

uipm

ents

1011

Wh)

year

Tot

al in

tern

et tr

affic

(T

bps)

Network traffic

Total power generation at 2007

Power consumption

Page 7: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Expanding applied area of optical communication

Backplane of a server(Orange color cables are optical fibers)

Nowadays, application area of optical communications are spreading from rack-to-rack of server to universal-bass-interface of PCs

Universal Bass interface (Light Peak)installed in SONY VAIO Z

Page 8: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Photonic devices used for optical communications

1. Passive optical device, Passive photonic device

2. Active optical device, Active photonic device

- Light-emitting diode (LED)- Semiconductor laser, Laser diode (LD)- Optical amplifier

- Optical waveguide, optical fiber- Optical splitter- Optical directional coupler- Optical wavelength filter- Wavelength multiplexer/demultiplexer (MUX/DEMUX)- Light polarizer- Wave plate- Dispersion control device- Optical attenuator- Optical isolator- Optical circulator- Optical switch, Photonic switch- Photo detector, Photo diode (PD)

Various optical devices for use in optical networks

3. Other devices(Wavelength converter, Optical coherent receiver, etc.)

: Treated in our lecture

Page 9: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Photonic devices: supporting life of 21st century

- charge-coupled device (CCD) image sensor- CMOS image sensor- solar cell, photovoltaic cell- photo-multiplier- image pick-up tube- CRT: cathode-ray tube, Braun tube- liquid crystal display (LCD)- plasma display- organic light emitting display- various recording materials (CD, DVD, BLD, hologram, film, bar-code)- various lasers (gas laser, solid laser, liquid laser)- non-linear optical devices

Various photonic devices used for applications other than optical communication

These devices collectively means “Photonic devices”

Page 10: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Electronics

Photonics

SpintronicsGMR HDDMRAM

Opto-spinics

Electron Tube, Diode, Tr, FET, LSITunnel effect devices

Magnetics

HDDLaser

LD, LED

magnet-optical disk

What is Photonic Device ?

Optical diskMagnetic tape

Display

Optical fiber

solar cell

Photo-electronics(Opt-electronics)

Manipulating electron charge

Manipulating photon

Manipulating spin of materials

Energy and number

amplitude and phase

Electromagnetic wave

voltage and current

Photo detector, PD

CCD, CMOS sensor

?

Manipulating both spin and charge of electrons

Magnetic Recording

Manipulating photon and electron charge

Unexplored

Manipulating wavefunction of electron

Page 11: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Basis of semiconductor photonic devices

Properties required for semiconductor used as photonic devices

Optical absorption coefficient of major semiconductor materials

0.4 0.6 0.8 1.0 1.2 1.4 1.6

Wavelength: λ (μm)

Opt

ical

abs

orpt

ion

coef

ficie

nt: α

(cm

-1) T = 300K

105

104

103

102

Si

InP

GaAs

Ge

In0.53Ga0.47As

Passive devices(Non light-emitting devices)

・ Transparent at operating wavelength

Active devices(Light-emitting devices)

・ Moderately-opaque at operating wavelength

・ To be obtained pn-junction (To be realized current injection devices)

・ Small nonlinear optical effect  (as distinct from nonlinear optical devices)

・ Better for small material dispersion

・ High radiant transition probability in case of light-emitting devices (Direct transition semiconductor )

・ Small birefringence (polarization independence)

Page 12: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Band structure of semiconductors

Semiconductor and band structure

According to Bloch theorem, wave function of an electrons in crystal is described as a quantum number called “wave number” This predicts existing dispersion relation between energy and wave number of electron. This relation is called energy band (structure)

Dispersion relation of electron energy in Si

In bulk Si, holes distribute at around the Γ point, on the other hand, electrons distribute at around the X point (Indirect transition semiconductors)

Band gap ~1.1eV

Hole

Electron

Page 13: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Band structure of semiconductors

Band structure of compound semiconductors

GaAs InP

Both electrons and holes distribute at around the Γ point (Direct transition semiconductors)

Hole

Electron

Hole

Electron

Page 14: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Band structure of semiconductors

Band structure of Ge

Band structure of Ge

Ge which is group semiconductor is also Ⅳindirect transition type semiconductor, but by adding tensile strain, it changes a direct transition-like band structure

Recent year, Ge laser diode(RT, Pulse) was realized by current injection

1.6%tensile strain

Conduction band

Valence band Valence band

Indirect transition Direct transition

Conduction band

Page 15: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Basis of semiconductor photonic devices

Material dispersion

W. Sellmeier equation

Values of dielectric constant (refractive index), magnetic permeability depend on frequency of electromagnetic wave interacting with the material

)(),(),( n

Dielectric constant (refractive index) significantly changes at the resonance frequency of materials.In linear response, between real part and imaginary part of frequency response function holds Kramers-Kronig relation.

Phenomenologically-derived equation of relation between wavelength and refractive index

22

22 1

i

iAn

Here, λi = c/νi, c: light speed, νi: resonance frequency of material, Ai: Constant Calculation of dielectric function ε of Si

Rea

l par

tIm

agi

nary

par

t

Photon energy (eV)

Photon energy (eV)

Calc.

Calc.

HBED )(,)( Material equation

Page 16: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Basis of semiconductor photonic devices

Birefringence

In anisotropic medium, dielectric constant (refractive index), magnetic permeability are tensor

z

y

x

zzzyzx

yzyyyx

xzxyxx

z

y

x

E

E

E

D

D

D

(Material equation)

Crystal is optically anisotropic medium

Birefringence of calcite

In birefringence crystals, an incident direction where light beam does not split is called optical axis (correspond to c-axis of the crystal)

When light beam enter a crystal, it splits two beams (ordinary ray and extraordinary ray)

Optical axis

 

Incident ray

ordinary ray

extraordinary ray

Outgoing ray

Page 17: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Basis of semiconductor photonic devices

Nonlinear optical effect

Values of dielectric constant (refractive index), magnetic permeability depend on amplitude of electromagnetic field interacting with the material

)(),(),( HEnE

When strong electric field (light) applied to a material, nonlinear optical effects emerge. Wavelength conversion devices use this effects.

When intensity of incident light is weak, linear polarization P which proportional to the electric field E is induced.

EP 0),(),(

),(),(),()1(

),(),(),(

0

000

0

tt

ttt

ttt

ee

r

xPxE

xExExE

xExExD

Linear polarization

When intensity of incident light become strong, electric susceptibility become depended on the electric field E

EP )(0 E

: Electric susceptibility

EEEEEEE )4()3()2()1(0)(

HBED )(,)( HE Material equation

Page 18: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Basis of semiconductor photonic devices

Band structure of (a) GaAs and (b) Si

In case of indirect transition, phonon intervenes light emission or absorption

Electron transition in direct transition type and indirect transition type semiconductors

Page 19: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Light emission from materials

Light absorption and emission in material

All light come from atoms !

Sun light Nuclear fusion of hydrogen‥‥

Fluorescence of fireflies Chemical reaction of ‥‥organic materials

Light from burning materials Chemical reaction of ‥‥organic materials

Electroluminescence from LED Electron transition ‥‥in semiconductors

You have to learn about interaction mechanism of matter with electromagnetic field if you want to understand these phenomena

In the field of Quantum electronics

Ground state

Excited state

Excited state

Ground state

Nucleus

Light

Light

ΔE = hν

ΔEν

Why materials emit light?

Page 20: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Light emission from materials

+e

−eElectron

Proton

Rutherford atom model

m

r

According to classical electromagnetics, Rutherford atom model is unstable. It predicts lifetime of atoms are order of 10-11 sec. (See the final subject in my lecture note Electromagnetics )Ⅱ

In order to solve this antinomy, Quantum mechanics was proposed

+e

−eProton

Bohr hydrogen atom model

N. Bohr proposed an atom model which electrons exist as standing wave of matter-wave. The shape of the standing wave is defined by the quantum condition, and it is arrowed in several discreet states. When an electron transits from one steady state to other state, it emit / absorb photon which energy correspond to energy difference between the two states. (ΔE = hν)

Why electrons make transition between the states ?

Which process occur ? Light emission or absorption ?

Page 21: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Theory describing light absorption and emission

Energy of electrons in semiconductor is quantized (Band structure), Electromagnetic field is also quantized (Field quantization)

There are three methods describing interaction of matter with electromagnetic fields

1. Classical theory

2. Semi-classical theory

Energy of electrons in semiconductor is quantized (Band structure), On the other hand, energy of electromagnetic field is treated by classical electromagnetics

3. Quantum theory

Classical theory

Semi-classical theory

Quantum theory

Electromagnetic fieldMatterMethod

Optical absorption

Possible

Stimulated emission

Impossible

Spontaneous emission

Classical Classical

ClassicalQuantum

Quantum Quantum

Possible

Possible

Possible Possible Possible

Impossible

Impossible

Three methods and their applicable phenomena

Page 22: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Description of electromagnetic field

In order to understand interaction of matter with electromagnetic field, we need to describe electromagnetic field and to understand its fundamental characteristics

Maxwell equations

0),(

),(

),(1),(),(

),(),(

2

t

t

t

t

vt

tt

t

tt

e

ee

xB

xE

ixE

ixE

xB

xBxE

Electric field E and magnetic field B can be also described as follows with electromagnetic potential A(x, t) and ϕ(x, t)

ABA

E

,t

Therefore, Maxwell equations can be replaced to equations with A and ϕ as values of electromagnetic field, instead of E and B

Page 23: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Description of electromagnetic field

t

tttttt LL

),(),(),(),,(grad),(),(

xxxxxAxA

Electromagnetic potentials can be described as follows with arbitrary scalar function χ(x, t).

0),(

),(div

t

tt L

L

xxA

When χ(x, t) was selected as AL and ϕL satisfying the following relation,

the gauge is called “Lorenz gauge”. In this case, basic equations that describe electromagnetic phenomena is reduced to two simple equations regarding AL and ϕL as follows.

),(1

),(),,(),(2

2

2

2

ttt

ttt eLeL xxxixA

This function χ(x, t) is called a “gauge function”, and selecting these new electromagnetic potential AL and ϕL is called “gauge transformation”.

These equations indicate that electromagnetic potential AL and ϕL caused by ie or e propagate as wave with light speed.

Page 24: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Description of electromagnetic field

AB

AE

t

Therefore, E and B is derived from A with the following relations

the gauge is called “Coulomb gauge”.

0 A

iA

tt 2

2

Other than Lorenz gauge, when A was selected as satisfying condition,

In this case, basic equations that describe electromagnetic phenomena is as follows

In free space where both electric charge ρe and electric current ie do not exist,

0,Const.2

2

At

By selecting Coulomb gauge, electromagnetic fields can be described by only vector potential A, because scalar potential ϕ is constant in whole space when electric charge dose not exist in the thinking space.

Page 25: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Interaction of charged particles with electromagnetic fields

When single charged particle (electron) is in electromagnetic field, Hamiltonian of the particle is described as follows

eVem

H 2)(2

1Ap

Here, p is the momentum operator, m is electron mass, V is potential of electron, e is elementary charge, and A is vector potential. Hamiltonian H can be also written as,

The last term in Hint is proportional to A2, and it reveals higher order effects (nonlinear optical effect). Here, we ignore it because the contribution is small.

Here, H0 is an Unperturbed Hamiltonian which is for an electron in space without electromagnetic field, and Hint is an Interaction Hamiltonian which is originated by interaction between an electron and electromagnetic field.

22

int

20

int02

2)(

2

2

1

)(2

1

ApAAp

p

Ap

m

e

m

eH

eVm

H

HHeVem

H

Page 26: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Electrical-dipole approximation of the interaction

Position of a charged particle is described astiti ee *

00 rrr

Momentum of a charged particle is described as

)( *00

titi eieimm rrrp

Vector potential is described astiti ee *

00 AAA

Electric field is

titi eieit

*00 AA

AE

Therefore,

ER

Er

ArArpAAp

e

iimm

e

m

eH )()(

2 0*

0*00int

Here, R = er, and it called electric dipole moment

E

+e

−e

e−iωt

e+iωt

r

Electrical dipole

Terms “ei2ωt ” or “e−i2ωt ” disappear when integrating for time

Polarization of atom

EPolarization of electron cloud

r

Page 27: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Electrical-dipole approximation of the interaction

)(2int pAAp

m

eH

Interaction Hamiltonian

only include effect by electric field “RE” although the derived interaction equation for a charged particle include effects by both electric field (Coulomb force) and magnetic field (Lorentz force). The reason is that we assume the motion of a charged particle as which is vibration at a limited place. If we assume parallel motion for it, effect by magnetic field will be also included.

titi ee *00 rrr

In this way, when the interaction only depend on electric field, and the interaction can be described as RE, it is called electric dipole approximation.In some case, higher order polarization “multipolar” (such as electric quadrupole or electric octopole) occasionally emerge.

工学で扱う物理現象は非常に複雑なものが多い。従って、全ての物理現象を取り入れた完璧な理論を構築することは不可能である。良きエンジニアとは、それら複雑な物理現象の中で、何が本質的に重要かを見極め、近似をうまく使い、無視できる物理現象は思い切って無視し、シンプルな理論を構築できる人である。ただし、どんな近似を使ったのかは決して忘れてはいけない。

皆さんへのメッセージ

Page 28: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Electrical dipole in semiconductor

In semiconductor, an electron and hole pair forms a electrical dipole

+

Hole

Electron −e Electrical dipole

+e

Electrical dipole in semiconductor

Conduction band

Valence band

Hole

Electron

Electrical dipole

E

Page 29: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Quantum statistics and density matrix

Physical quantities involving many particles (electrons) such as electrical current are statistical average values for the particles. Furthermore, expected values for multiple measurements of a single event is needed statistical treatments. We discuss about statistical nature for many particles or multiple measurements. State for ν th particle or ν th measurement can be described as

n

n nC )()( .

Here,    is an energy eigenstate for single particle. It is assumed to form complete space. Therefore, any can be formed by linear combination of .  does not required the suffix (ν).

nn)(

n

mn

mn mAnCCA,

)()*()()(

If operator for a physical quantity is assumed as A, expected value for ν th particle is

.

Next, we develop an average of expected values for the group of particle (ensemble average). We assume the contribution from the ν the particle (probability for finding n th particle) as P(ν) , and normalize it.

1)(P

Page 30: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Quantum statistics and density matrix

Statistical average (ensemble average) of the expected value is described as

mn

mn mAnCCPAPA,,

)()*()()()()(

Here, we rewrite as below

mnmnmnnm CCCCPmAnAAA *)()*()(,,

Matrix ρ having ρmn as its elements is called density matrix

2221

1211

Using density matrix

mm n

mnmnnmmn

mAmmAnnm

mAnnmAA

,,

.

n

nnI is identity operator

m

mAm is summation of on-diagonal elements of ρA, that is Trace.

)(Tr AmAmAm

, and 1)(Tr

Page 31: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Motion equation of density matrix

密度行列 ρ の性質が分かれば、集団内の個々の粒子についての状態 や抽出確率 P(ν) を知らなくても、統計性を含めた期待値 を知ることがで

きる。そこで、密度行列  ρ を表現する方程式、つまり  ρ が従うべき方程式を求めてみる。

)(A

nPmnPm

mnPCCP mnmn

)()()()()()(

)()()()()*()(

従って密度行列は、               と書くことができる。

まず、密度行列の行列要素の定義式を、以下のように書き直す。

)()()( P

この式の両辺を時間 t で微分すると、

dt

dPP

dt

d

dt

d)(

)()()()(

)(

となる。

ただし、抽出確率 P(ν) の時間依存性はないとしている。

Page 32: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

Motion equation of density matrix

,11

)()()()()()(

Hi

HHi

i

HPP

i

H

dt

d

)()( Hdt

di Schroedinger equation        and its Hermitian conjugate

Hdt

di )()( より、

となる。

これは、密度行列の時間発展を表す式であり、密度行列の運動方程式或いは、量子リウヴィル (Liouville) 方程式もしくはリウヴィル - フォン・ノイマン方程式とも呼ばれる。

Page 33: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

双極子との相互作用がある場合の密度行列

電子系の主ハミルトニアンを H0 とし、電気双極子能率を R とする。前に述べたように、電場が存在するときの相互作用ハミルトニアン Hint は、− RE と

なり、電子系全体のハミルトニアン H は、REHHHH 0int0 となる。

これを、密度行列の運動方程式に代入すると、

ERRi

HHi

REREi

HHi

HHidt

d

11

111

00

00

となる。

ここで、最後の ≈ では、1個の電子が存在する領域が電磁波の波長に比べて十分に小さく、その範囲内で電場の分布は一定と見なせることを仮定している。実際、気体原子に束縛されている電子の存在範囲はせいぜい数 Å 程度であり、また半導体中の電子に至ってもせいぜい数十 Å 程度である。それに対して、相互作用する光の波長は数千 Å もあるので、この仮定は妥当である。

Page 34: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

双極子との相互作用がある場合の密度行列

次に、密度行列の行列要素に対する方程式を導出する。エネルギー固有状態には時間依存性が無いので、

ndt

dmnm

dt

d

dt

d mn と表すことができ、従って、

ll

ll

ll

ll

mn

EnllRmi

EnRllmi

nHllmi

nllHmi

EnllRmi

EnRllmi

nHllmi

nllHmi

EnRmi

EnRmi

nHmi

nHmidt

d

11

11

11

11

1111

00

00

00

と書くことができる。なお。ここで用いている固有状態は、主ハミルトニアン H0 の固有状態である。

Page 35: Communications Devices Hirohito YAMADA Lecture on 6/23, 6/27, 6/30, 7/7, 7/14, 7/21 in 2015

双極子との相互作用がある場合の密度行列

従って、状態   は、エネルギー固有値 Wn をとり、状態間には直交性があるので、n

llnmllnmlnmmn

llnml

llnmlnmmn

llnm

mn

ERRi

i

ERi

ERi

WWi

EnllRmi

EnRllmi

Wnmi

nmWidt

d

1

111

1111

となる。

ただし ωmn は、順位 m と順位 n とのエネルギー差に対応する角周波数であり、

nmmn WW で与えられる。