comparative evaluation of eurasian natural chloride-sulphate waters.ppt

8/14/2019 COMPARATIVE EVALUATION OF EURASIAN NATURAL CHLORIDE-SULPHATE WATERS.ppt

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COMPARATIVE EVALUATION OF

EURASIAN NATURAL CHLORIDE-

SULPHATE WATERS`

COMPOSITION BY MEANS OF

MATHEMATICAL MODEL FOR

MINERAL WATERS`CLASSIFICATION

* Kornilov, N.I., ** Surdu O., *** Kornilova, E.N.,* Domnitsky D.A. **Surdu T-V

Stavropol State Agrarian University, Stavropol, Russia

** Ovidius University, Constanta, Romania,

*** OAO "Stavropol Elektronproekt", Stavropol, Russia


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Aims of the study

toestablish a quantitative dependences

connecting composition and properties of the

regional Eurasian mineral water on the basis

of a mathematical model;

to assess the composition of some mineral

waters, brine lakes, squeezed waters,

medicinal mud/clay/sediments in Russia andRomania.


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Materials

samples of chloride-sulphate mineral waters,

mud/clay/peat, from Russia, Romania,Germany, France, Italy, Spain, Ukraine and

other countries of the Eurasian continent


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1. Methods of work

statistical methods of the linear regressionequation

analytical dependences that connect characteristicindicatorsof the mineral waters structure ( , B, )

to independent variables of ionic composition andconcentration (total salinity, ionic composition, acid-base balance, conductivity and some othercharacteristics)

characteristic indicators", calculated from experimental data,refers to those functions of the system, through which, or

through whose derivatives, can expresses in explicit form thecomposition and mass properties of water-salt systems


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1.1. Parameters for the

mathematical description of

structure of water-salt systems

- the total mineralization of water

(g/dm3).- the gram-equivalent of a salt system

of mineral water, g/eqv

Cn -concentration of salts in solution(eqv/dm3)

M

nCM


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Whereratioof equivalent anions cloride and sulphate

functionof one variable

24SO

Cl

X

X

presented in the form of the equationwhere aand bare constants corresponding to mineral water

chloride-sulfate type

b)2

4

SOX

ClX

a(


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1.2.character ist ic indicator

well-definedvalue of the salt solution and depends

on: the natureof dissolved salts, the composition

and concentrationof ions, forming a salt solution

the dilutionof the solution with a given value ofdemineralized water does not change its value

Solutions of different concentrations with similar

values of belong to the same subgroup (class)

of water. Solutions with close relation of constitute a

certain class of mineralized water


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2. Results and Discussion2.1. Standard chloride-sulfate waters of

Russia The natural mineral waters of the chloride-sulfate

type included in the GOST R are water solutions ofchloride and sulfate saltsof sodium, magnesium andcalcium, the total content of which in solution is upto 90 eqv% or more

Processing array values in total mineralization andion composition was carried out on mean values ofthe variables listed in GOST R, subject to the

material balance of the anions Cl-, SO42-, HCO3-andcationsCa 2+, Mg 2+, Na+and K+, forming a saltysolution of mineral waters.


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M

MMineralization and ions composition of the reference mineral

chloride-sulphate waters of Russia

Title of waterMineralization ,

(g/dl)

Ion composition of water, mg-eqv/dl

HCO3- SO4

2- CI- Ca2+ Mg2+ Na+ + K+

1 Kashinskaja 2,825 0,76 35,43 7,13 20 10,28 13,04

2 Uglichskaja 4,094 1,56 45,31 15,49 14,59 10,79 36,98

3 Bujskaja 11,945 0,81 133,26 45,74 20 18,51 141,3

4 Igevskaja 4,350 3,28 46,88 16,90 20 18,57 28,78

5 Irkutskaja 2,050 4,67 17,71 9,30 13 8,23 9,78

6 Lipezkij bjuvet 3,301 4,32 27,21 17,81 3,75 2,06 43,48

7 Anapskaja 3,067 7,79 21,88 15,49 1,21 3,98 39,97

8 Lisogorskaja 18,165 7,7 159,9 118,9 65,8 195,7

9 Don 2,850 5,74 21,35 16,90 8,25 9,98 25,67

10 Nigne-Ivkinskaja 7,598 1,46 59,37 60,83 25 20,27 76,09

11 Ergeninskaja 5,700 6,56 40,62 42,25 27,5 12,34 50

12 Novo-Igevskaja 15,420 0,82 99,38 144,93 30 8,64 206,52

13 Kaspij 6,416 13,75 27,67 56,65 0,42 1,03 95,65

14 Solvichegodskaja 8,850 0,82 43,75 94,37 2,5 8,23 123,9

15 Hilovskaja 3,535 2,36 17,21 39,84 18,75 14,40 26,09


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Quant i ty o f general min eral izat ion , ratio and

characteristic indicators of composition ,Band of the

reference mineral chloride-sulphate waters of Russia

Title of water(g/dl)

CI

-/ XSO4

2-(g/eqv)

(g2 / eqv2)

(g2 / eqv2)

1 Kashinskaja 2,825 0,201 65,21 2126 10580

2 Uglichskaja 4,094 0,342 65,65 2155 6320

3 Bujskaja 11,945 0,345 66,43 2207 6396

4 Igevskaja 4,350 0,360 64,92 2107 5854

5 Irkutskaja 2,050 0,525 65,39 2138 4072

6 Lipezkij bjuvet 3,301 0,654 66,97 2243 3429

7 Anapskaja 3,067 0,708 67,87 2306 3257

8 Lisogorskaja 18,165 0,744 63,40 2010 2701

9 Don 2,850 0,791 64,78 2099 2653

10 Nigne-Ivkinskaja 7,598 1,024 62,45 1950 1904

11 Ergeninskaja 5,700 1,040 63,61 2023 1945

12 Novo-Igevskaja 15,420 1,458 62,91 1979 1357

13 Kaspij 6,416 2,047 65,42 2140 1045

14 Solvichegodskaja 8,850 2,157 61,54 1894 878

15 Hilovskaja 3,535 2,315 59,50 1770 765

24SO

Cl

XX

M

M


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2. Results and Discussion2.1. Standard chloride-sulfate waters of

Russia Mathematical treatment of the values of the characteristic

parameter , allowed obtaining an analytical expression

for the function lnin the form of a linear regression

equation:

ln )]XX

[ln(f24SO

Cl

=

24SO

ClX

X

7,6302 1,0511

r = 0,9974 where: r - correlation coefficient.

ln

=


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2. Results and Discussion

2.1. Standard chloride-sulfate waters of Russia.Graphic dependence of function ln = f [ln(CI- / XSO4 2- )]for standard chloride-sulfate mineral water of Russia


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2. Results and Discussion2.2. Eurasian regional chloride-sulfate water

Title of water (g/dl)

CI

-

/ XSO4

2-(g/eqv)

(g2 / eqv2)

1 2 3 4 5 6

1 Acqua de Cavabaa (Spain) 86,550 0,061 71,20 41550

2 Batalinskay (Ru) 20,949 0,131 65,82 16540

3 Rubeg (Ru) 7,982 0,197 65,28 10820

4 Lake B. Solenoje-mud (Ru) 243,68 0,201 65,13 10550

5 Lake Sengileevskoje (Ru) 0,234 0,204 65,21 11570

6Kissinger Bitterwasser Heilwasser

(G)34,890 0,234 60,32 7770

7 Staroeletskaja (Ru) 4,110 0,256 68,94 9280

8Slanic Moldova 8-bis

(Romania)0,193 0,263 65,87 8250

9 Nickolina Balka (Ru) 10,052 0,356 61,54 5719

10 Lake M. Solenoje (Ru) 145,65 0,426 63,26 4697

11 Nezlobinskaja (Ru) 2,980 0,454 73,93 6071

12 Krakowianka (Pol) 2,714 0,460 65,71 4693

13 Feodosiiskaja (Ukr) 3,957 0,540 59,7 4067

14Lake B. Tambykan, (mud mortars)

(Ru)17,724 0,543 62,52 3643

15 Lake B. Tambykan (Ru) 22,982 0,547 62,90 3573

M


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2. Results and Discussion2.2. Eurasian regional chloride-sulfate water

Title of water(g/dl)

CI

-/ XSO4

2-(g/eqv)

(g2 / eqv2)

16 Dax (France) 0,987 0,575 67,13 3940

17 Slanic-Moldova, 5 (Rom) 0,658 3300

18 Lake Techirghiol (mud mortars), (Rom) 75,346 2,107 60,64 873

19 Kaspij Sea (Ru) 10,547 2,300 59,44 768

20 Antonius Heilwasser (G) 2,136 2,331 66,08 937

21 Press water of dark-grey clay, sample 10 (Ru) 15,499 4,091 62,40 476

22 Lake Techirghiol (Rom) 73,238 4,320 58,90 402

23 Kujalnik 6 (Ukr) 3,197 5,348 62,67 367

24 Maxbrunner Heilwasser (Ger) 6,926 5,889 66,15 372

25 Black Sea (Ru) 16,031 6,572 58,82 263

26 Witjaevskij Liman (Ru) 70,579 8,442 57,79 198

27 Thermal Baths Scrajo (Italy) 14,159 8,877 61,29 212

28 Press water of dark-grey clay, sample .11 (Ru) 17,382 9,364 59,53 189

29 World`s Ocean 35,080 9,745 58,01 173

30 Lake Solenoe (Ru) 79,988 12,657 57,47 131

31 Lake Golybitskoe (Ru) 26,250 23,528 58,83 74

M


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-4 -3 -2 -1 0 1 2 3 4

ln (XCI-/ XSO2-4)

4

5

6

7

8

9

10

11

ln

Lake (mud mortars)B. TambykanLakeB.Tambykan

Aqua de cavabana

Batalinskay

Lake B. SolenojeLake Sengileevskoje

Kissinger Bitterwasser Heilwasser

StaroeletskajaSlanic-Moldova, N8 bis

Nickolina BalkaLake M.Solenoje

Nezlobinskaja

Krakowianka

Slanic-Moldova, N5

Lake Golubitskoe

Lake Solenoe

Lake Techirhiol, mud mortars

Kaspij Sea

Antonius Heilwasser

World's Ocean

Lake TechirghiolKujalnik N6

Maxbrunner Heilwasser

Black Sea

Witjaevskij Liman

Thermal Baths ScrajoPress water of dark-gray clay number 11.

Press water of dark-grey clay number 10

FeodosiiskajaDax

2. Results and Discussion

2.2. Eurasian regional chloride-sulfate water

Graphic dependence of the function ln = f [ln(CI-/ XSO42-)]

for the Eurasian regional mineral waters


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2. Results and Discussion2.3. Comparative estimate of the Eurasian regional

and standard water Russia chloride-sulphate type

The coefficients A, Dand r for the Eurasian regional

and standard mineral waters Russia chloride-sulfate type

Mineral

waters

Coefficients Correlation coefficient

r D

The reference waters of

Russia

2059 1,0511 0,9974

The Eurasianregionalwaters

2025 1,0549 0,9987

Association of the

reference watersof

Russia and Eurasia

regional waters

2040 1,0572 0,9986


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2. Results and Discussion2.3. Comparative estimate of the Eurasian regional

and standard water Russia chloride-sulfate type

Statistical analysis of the data showed that in allcases r = 0,997 - 0,999, and the error of calculationsdoes not exceed the stdv 5% (level of confidenceinterval).

Analysis of numerical datafor characteristic index ,showed that natural mineral waters of differentsources of the Eurasian continent, irrespective of theirgeographical location, form a class of waters with

similar ionic composition, which shows the unity of thegenesis and metamorphism of hydro mineralresources (mineral waters and mud).


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Systematic of Eurasian Mineral chloride-

sulphate waters on the value of the

characteristic indicator

and the ratio

Group

of mineral

waters

Index

subgroup

(classes)

Title of water,

ordinal number

(g/dl)

(g2

/ eqv2

)1 2 3 4 5 6 7

I Sulphate

IAcqua de Cavabaa

(Spain) (1)86,550 0,061 41550

BI Batalinskay (Ru) (2) 20,949 0,131 16540

CI

Rubeg (Ru)( 3) 7,982 0,197 10820

Lake B. Solenoje

(Ru)(4) 243,68 0,201 10550

Kashinskaja (Ru) (5) 2,825 0,201 10580

Lake Sengileevskoje

(Ru)(6)0,234 0,204 11570

M

2

4SO

Cl

X

X

24SO

Cl

XX


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Group

of

mineral

waters

Index

subgroup

(classes)

Title of water,

ordinal number

(g/dl)

(g2 / eqv2)

IIChloride

-sulfate

AII

Kissinger Bitterwasser Heilwasser (G) (7) 34,890 0,234 7770

Staroeletskaja (Ru) (8) 4,110 0,256 9280

Slanic Moldova 8 bis (Rom) (9) 0,193 0,263 8250

BII

Ugeichskaja (Ru) (10) 4,094 0,342 6320

Bujskaja (Ru) (11) 11,945 0,345 6396

Nickolina Balka (Ru) (12) 10,052 0,356 5719

Igevskaja (Ru) (13) 4,350 0,360 5854

CII

Lake M. Solenoje (Ru) (14) 145,65 0,426 4697

Nezlobinskaja (Ru) (15) 2,980 0,454 6071

Krakowianka (Pol) (16) 2,714 0,460 4693

DII

Irkutskaja (Ru) (17) 2,050 0,525 4072

Feodosiiskaja (Ukr) (18) 3,957 0,540 4067

Lake (mud mortans) B. Tambykan (Ru) (19) 17,724 0,543 3643

Lake B. Tambykan (Ru) (20) 22,982 0,547 3573

Dax (France) (21) 0,987 0,575 3940

EIILipezkij bjuvet (Ru) (22) 3,301 0,654 3429

Slanic-Moldova, 5 (Rom) (23) 0,658 3300

FII

Anapskaja (Ru) (24) 3,067 0,708 3257

Lisogorskaja (Ru) (25) 18,165 0,744 2701

Don (Ru) (26) 2,850 0,791 2653

24SO

Cl

X

XM


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Group

of mineral

waters

Index subgroup

(classes)

Title of water,

ordinal number

(g/dl)

(g2 / eqv2)

III Sulfate-

chloride

AIII

Nigne-Ivkinskaja

(Ru) (27)7,599 1,024 1904

Ergeninskaja

(Ru) (28)5,700 1,040 1945

BIII Novo-Igevskaja(Ru) (29) 15,420 1,458 1357

CIII

Kaspij (Ru) (30) 6,416 2,047 1045

(mud mortans),

(Rom) (31)75,346 2,107 873

DIIISolvichegodskaja

(Ru) (32)8,850 2,157 878

EIII

(Ru) (33) 10,547 2,300 768

Hilovskaja (Ru(34) 3,535 2,315 765

Antonius Heilwasser

(Ger) (35) 2,136 2,331 937

M

2

4SO

Cl

X

X


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Group

of mineral

waters

Index

subgroup

(classes)

Title of water,

ordinal number

Mineralization,

(g/dl)

Ratio Characteristic

indicator

,

g2 / eqv2

IV Chloride

AIV

Press water of dark-gray clay,

sample 10 (Ru) (36) 15,499 4,091 476

(Rom) (37)73,238 4,320 402

BIV

Kujalnik 6

(Ukr) (38) 3,197 5,348 367

Maxbrunner Heilwasser (Ger)

(39) 6,926 5,889 372

(Ru) (40) 16,031 6,572 263

DIV

Witjaevskij Liman (Ru) (41)70,579 8,442 198

Thermal Baths Scrajo (42)14,159 8,877 212

Press water of dark-gray clay,

sample 11 (Ru)( 43) 17,382 9,364 189

World`s Ocean ( 44)35,080 9,745 173

EIV (Ru)( 45) 79,988 12,657 131

FIV (Ru)(46) 26,250 23,528 74

M

24SO

Cl

X

X


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3. Conclusion

a) Characteristic parameters , B and with a high

degree of reliabilityallow the identification of watersof

different ionic composition and mineralization,

regardless of geographical coordinatesof the locationof their sources;

b) Characteristic parameters , B and (calculated

from the experimental data of chemical analysis of

water) allow to assess water qualityand can be usedto organize national and pan-European monitoring

systems of natural waters;


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3. Conclusion

)Analytical dependence of the function

ln

= 7,6209

1,0572

allows the quantitative identificationof the

various regional water on their correspondinganalogues of standard mineral waters and

their subsequent certification and

standardization.

2

4SO

Cl

X

X


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comparative evaluation of eurasian natural chloride-sulphate waters.ppt

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