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Current Status and Perspective of Research and Development on Coal Utilization Technology in Japan 20th Annual International Pittsburgh Coal Conference September 15-19, 2003 Ikuo Saito Institute for Energy Utilization National Institute of Advanced Industrial Science and Technology (AIST)

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Page 1: Current Status and Perspective of Research and Development

Current Status and Perspective of Research and Development on Coal Utilization Technology in Japan

20th Annual International Pittsburgh Coal Conference September 15-19, 2003

Ikuo SaitoInstitute for Energy Utilization

National Institute of Advanced Industrial Science and Technology (AIST)

Page 2: Current Status and Perspective of Research and Development

Presentation planCongratulations on the 20th anniversary

Japan’s Energy Situation

Japan’s Energy Policy

Current Status and Perspective of Research and Development on Coal Utilization Technology

Summary

Acknowledgement

Page 3: Current Status and Perspective of Research and Development

Japan US France Germany UKPrimary energy supply(million tons of oilequivalent) 515 2270 255 337 230Coal 17 24 6 24 15Oil 52 39 35 40 36Natural gas 12 23 14 21 36Nuclear 16 9 40 13 11Hydro 1.4 1.1 2.4 0.5 0.2Renewable energy, etc. 2 4 5 1 1

Self-supply rates (%) 20.2 74.4 50 39.4 122.5

Source: IEA “Energy Balances of OECD Countries 1998-1999”

Table 1 Primary energy supply in major countries (1999)

JapanJapan’’s Energy Situation Compared with the Worlds Energy Situation Compared with the World

The energy self-supply rate of Japan is still very low, at about 20%, compared with other major countries

Weakness of energy self-supply in Japan

Page 4: Current Status and Perspective of Research and Development

Fig. 1 Change in the final energy consumption by sectors

0

50

100

150

200

250

300

73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 00

Fiscal year

Index (FY1973 level = 100)

Source: Comprehensive Energy Statistics

Passenger vehicletransportation sector

Residential sectorTransportation sectorCommercial/residentialsectorCommercial sector

Freight & publictransportation sector

Industrial sector

268

225209207189

150

107

Page 5: Current Status and Perspective of Research and Development

(%)

FY1973 FY1990 FY2000 FY2010Primary energysupply (million kl ofcrude oil equivalent) 414 526 604

Targetcase602

Oil 77 58 52 about 45Coal 15 17 18 about 19Natural gas 2 10 13 about 14Nuclear 1 9 12 about 15Hydro 4 4 3 about 3Geothermal 0 0.1 0.2 about 0.2New energy 1 1 1 about 3

Table 2 Change in primary energy supply

Source: Comprehensive Energy Statistics

Target value of oil dependency rate is about 45% by FY 2010

Page 6: Current Status and Perspective of Research and Development

· Energy conservation / new energy measures

· Implementation of Keidanren’s independent action plan

· Promotion of nuclear power policy, etc.

Energy conservation: - 6 million t-C

New energy: - 9 million t-C

Fuel change, etc.: - 5 million t-C

Total: - 20 million t-C

Fig.2 Reduction of Energy-Originating CO2

250

270

290

310

330

350

1990 1995 2000 2005 2010 (Fiscal year)

Energy-originating CO

2emissions

When measures for 1998 and thereafter are not takenWhen measures decided so far are takenTarget

Impl

emen

tatio

nof

exi

stin

gm

easu

res

Actual level in FY1990:287 million t-C

Actual level in FY2000:316 million t-C

307million t-C

287million t-C

20million t-C:+ 7% A

dditi

onal

mea

sure

s

(million t-C) 347million t-C

29million t-C:10%

+

++

Japan’s Energy Policy(1)

Page 7: Current Status and Perspective of Research and Development

Japan’s Energy Policy(2)! Energy Conservation

• In addition to measures currently being implemented (approx. 50 million kl), further measures are to be implemented (approx. 7 million kl) focusing on items such as in the Residential Sector including passenger cars and the Commercial Sector including the Service Sector.

• Approximately 6 million t-C is expected to decrease.

Page 8: Current Status and Perspective of Research and Development

Japan’s Energy Policy(3)! New Energy

• The target for the implementation of new energy is set at 19.1 million kl for FY2010.

• Moves for the approval of "the Law concerning Special Measures for Promotion of New Energy by General electricity supplier" with measures such as obligating General electricity supplier to use a minimum predetermined level of New Energy.

• Measures to reduce the burden on the person implementing New Energy (Household Sun Rooms/Advanced Household Solar Systems, Clean- Energy Motor Vehicles)

• Pushing the public sector to take the lead in implementing equipment and machinery using new energy.

• Advancement of technological development and verification tests for fuel cells.

• Increasing the range of new energy (biomass energy, cool energy)

• Approximately 9 million t-C is expected to decrease.

Page 9: Current Status and Perspective of Research and Development

490 494

58101

14

552

134

439

118

Fig. Actual Result of Introducing New Energy and Targets of IFig. Actual Result of Introducing New Energy and Targets of Introduction for FY 2010ntroduction for FY 2010

Waste power generation

Unused energy

Black liquid, waste material, etc.

Wind power Wind power generationgeneration

Solar thermal Solar thermal utilizationutilization

Photovoltaic Photovoltaic power generationpower generation

Biomass (power generation + thermal)

Overall new energy

7,220,000 7,220,000 klkl

19,100,000 19,100,000 klkl

Actual result in FY2000 Target for FY2010

About 3 times

About the same

1.2% of the total primary energy supply

3% of the total primary energy supply

Black liquid, waste material, etc.

Photovoltaic power generationSolar thermal utilizationWind power generation, etc.

Thermal utilization of waste

Page 10: Current Status and Perspective of Research and Development

Japan’s Energy Policy(4)

! Fuel Switching• Replace out-dated coal generated power stations with highly effective

LNG Combined Cycle power generation• Industrial boilers using coal will be converted to using natural gas.

• Approximately 5 million t-C is expected to decrease.

! Adding up the figures obtained by these measures, 20 million t-C is expected to decrease.

Page 11: Current Status and Perspective of Research and Development

Revision of revenue structure! Revision of oil tax ( Oil and Coal tax)

• Rearrangement of tax burden structure• New tax on coal, increase in tax of LNG and LPG

! Further promotion of energy conservation and new energy development (Reviewing expenditure program of special accounts for energy)

Oil (yen/kl) LNG (yen/t) LPG (yen/t) Coal (yen/t) *

Present 2,040 720 670

2003.10- 2,040 840 800 230

2005.4- 2,040 960 940 460

2007.4- 2,040 1,080 1,080 700

•Coal for steel manufacturing, coke making and cement making and coal for power generation in Okinawa prefecture is exempted from tax.

Japan’s Energy Policy(5)

Page 12: Current Status and Perspective of Research and Development

Natural energy Solar, Wind

Renewable energy Biomass

New Energy Introduction Technology

Wind turbine Gasification of Biomass

Waste/Municipal waste Plastics waste

Coal Ultra heavy oil

Gas hydrate

Natural gas

Oil

Green Technology Suppression of Dioxine Hydrogen production Coal GT-CC power generation Deep desulfurization

Zero emission

Stability for energy supply

Env

ironm

enta

l pre

serv

atio

nCompatibility between Environmental Preservation and Stability for Energy Supply

Page 13: Current Status and Perspective of Research and Development

Basic Research (funded by Ministry of Education, Culture, Sports, Science and Technology) related to coal

Specific Area Research (B) “Coal Utilization Technology Development Aiming for Solution of Global Environmental Problems from GlobalPerspective”

Professor K. Miura (Kyoto University) : Principal Investigator

Selected 12 research subjects out of 59 proposals from universities 1999.4 – 2003.3 (4years), about 440 million yen in total 1) Development of new pretreatment method 2) Development of in-situ treatment technology3) Basic research supporting enhanced flue gas treatment technology

Page 14: Current Status and Perspective of Research and Development

Fig. 3 Technology Development Strategy related to Coal for the 21st Century (related to METI)

CO2 Reduction Rate

203020201990 2000

10%

High Efficiency1st Generation

10 - 20%

High Efficiency2nd Generation

2010

20 - 30%

HighEfficiency

Hybrid Generation

30 - 40%

Zero Emission

Generation

PFBC,USC

IGCC,SCOPE21,

DIOS

IGFC,Hypr-RingHyperCoal

H2 production Technology from Coal

Page 15: Current Status and Perspective of Research and Development

Promotion structure of the program related to METI

METI

NEDO

CCUJ

Private sector, universities, etc.

AIST

Joint research project

Project Funding

METI:Ministry of Economy, Trade and Industry

NEDO:New Energy and Industrial Technology Development Organization

AIST:National Institute of Advanced Industrial Science Technology

CCUJ:Center for Coal Utilization, Japan

Page 16: Current Status and Perspective of Research and Development

CCT RD&D in Japan (1)

Power Generation Technology

Integrated Coal Gasification Combined Cycle Power Generation System (IGCC)

Super Coke Oven for Productivity and Environmental enhancement toward 21st Century (SCOPE21)

High Efficiency Combustion Technology

Advanced Pressurized Fluidized Bed Combustion Technology (A-PFBC)

HyperCoal Power Generation System

Integrated Coal Gasification Fuel Cell Combined Cycle Power Generation System (IGFC)

Industrial Technology

Page 17: Current Status and Perspective of Research and Development

CCT RD&D in Japan (2)

Substitute Oil Production Technology

Dimethyl Ether Production Technology

Multi Purpose Coal Utilization Technology

Coal Liquefaction Technology (BCL, NEDOL)

Substitute Natural Gas Production Technology

Technology of Hydrogen Production from Coal with CO2 Recovery System (Hyper-RING)

Page 18: Current Status and Perspective of Research and Development

PFBC! Bubbling type PFBC has been commercialized

! RD&D71 MW as a national project at Wakamatsu Coal Utilization Technical Center

of J-power (Electric Power Development Co., Ltd.) (started its operation in Sep. 1994) Gross thermal efficiency: 37.5%

! Commercialized85MW Tomato-Atsuma Power Plant No. 3 Unit of the Hokkaido Electric

Power Co., Inc. (started its operation in March 1998) 40.1%250MW Ohsaki Power Plant No. 1 Unit of the Chugoku Electric Power Co.,

Ltd. (started its operation in Dec. 2000) 41.5%360 MW Karita New No. 1 Unit of Kyushu Electric Power Co., Ltd.

(started its operation in July 2001) 42.8%

Page 19: Current Status and Perspective of Research and Development

Fig. 4 Super Coke Oven for Productivity and Environmental enhancement toward 21st Century (SCOPE21)Fine coal

350~400

Coarse coal

Hot briquetting machine

Emission free transporting system

Emission free charging system

Closedtransportingsystem

CDQ withreheating system

Coke150~200

RegeneratorDryer

Fuel

Hot gas generatorWaste gas

350~400℃ ℃

Coal

Rapid heatingpreheater Emission gas

free pusher 1000℃Coke oven

Tightly sealed door750~850℃

Advanced Coke Making Process (SCOPE21)

Page 20: Current Status and Perspective of Research and Development

Pilot Plant Test

FundamentalTechnologyDevelopment

Basic Research

1994

Bench Scale Tests

Construction

Test Operation

19951993 19971996 1998 1999 20012000 2002

Fig. 5 Schedule of SCOPE21 Project

Page 21: Current Status and Perspective of Research and Development

Fig. 6 SCOPE21 Pilot Plant

Page 22: Current Status and Perspective of Research and Development

IGCC

! Based on the test results by a pilot plant using an air-blown pressurized two-stage entrained gasification furnace with a coal processing amount of 200 t/d from 1991 through 1996

! Demonstration Plant (Nakoso, Iwaki City, Fukushima Prefecture, about 200 km north of Tokyo)

Capacity 250 MW(1600 ton/day)Gasifier air-blown, entrained flow gasifier/ 2.5MPaGas clean-up Cold gas clean-up using MDEA Gas turbine 1200 C

Page 23: Current Status and Perspective of Research and Development

1999 20062000 20052004 2009200320022001 2007 2008Fiscal year

Preparatory verification tests

Demonstration plant tests

DesignOperation

testsConstruction

Environmental impact assessment

Fig. 7 Schedule of IGCC Demonstration Plant Program

Page 24: Current Status and Perspective of Research and Development

Fig. 8 Integrated Coal Gasification Combined Cycle Power Generation System (IGCC)

Conceptual Drawing of IGCC Demonstration Plant

GasifierGas Turbine

Gas Clean Up1,200 OCGas Turbine

MDEA,Lime stone

Gas clean up

Air blown,entrained

flow gasifier

Gasifier

40.5%Net Efficiency

250MW(1,600t/d)Capacity

Specifications

Page 25: Current Status and Perspective of Research and Development

IGFC (EAGLE Project)

! Integrated coal Gasification Fuel Cell combined cycle (IGFC)

! Coal Energy Application for Gas, Liquids and Electricity

! Pilot Plant (Wakamatsu, Fukuoka Prefecture in Kyushu)Coal feed 150 ton/dayGasifier oxygen-blown entrained flow gasifier (two-stage

tangential flow type in a single chamber) /2.5MPaGas clean-up Cold gas clean-up using MDEA

Sulfur compound <1 ppm, Halogen compound <1 ppmAmmonia compound <1 ppm, Dust <1 mg/m3N

Page 26: Current Status and Perspective of Research and Development

Flow Diagram of the EAGLE Pilot Plant

GComp. GT

Gas Clean Gas Clean -- Up UnitUp UnitCoal Gasification UnitCoal Gasification Unit

PulverizedCoal

Gasifier Syngas Cooler Precise Desulfurizer

COS Converter

Water Scrubber MDEA

Absorber

MDEA Regenerator

Acid Gas Furnace

Limestone Absorber

Incinerator HRSGStack

Gas Turbine UnitGas Turbine UnitAir Separation UnitAir Separation Unit

Filter

GGH

CharSlag

Nitrogen

Oxygen

AirRectifier

Air Compressor

Page 27: Current Status and Perspective of Research and Development

Fig. 9 Integrated Coal Gasification Fuel Cell Combined Cycle Power Generation System (IGFC)

(Fiscal year)1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006

FS/ Component Test

Operational Studies

'02.3 Charging coal

'03.3 Start of operationBasic design/Detail Design

Fabrication/Construction

Schedule of EAGLE Project

Page 28: Current Status and Perspective of Research and Development

Fig. 10 View of EAGLE Plant (IGFC) in Fukuoka

Specification

Coal Feed

Pressure

Coal Gasifica-

tion

150 t/d

2.5MPa

Oxygen-Blown

EntrainedFlow

Gasification

Page 29: Current Status and Perspective of Research and Development

CoalCoal

ResidueResidue(organic+ash)(organic+ash)

Minerals Minerals (ash)(ash)

Extract Extract (organic matter)(organic matter)

Feedstock forFeedstock for

Gas Gas TurbineTurbine

HyperCoalHyperCoal(ashless coal)(ashless coal)

> 60%> 60%

OrganicOrganicsolvent solvent extractionextraction

High Net Power OutputHigh Net Power Output

COCO22 Emission ReductionEmission Reduction

Net : 48%Net : 48%

HyperCoalHyperCoal power generation systempower generation system

Page 30: Current Status and Perspective of Research and Development

Net thermal Net thermal efficiencyefficiency::4848%% (HHV)(HHV)

(350(350ooC, C, 1.5MPa)1.5MPa)

5050ooCC

130130ooCC

StackStack

NN22

1.5 1.5 MPaMPaBurnerBurner

Combusted gas Combusted gas ((13501350ooC)C)

AirAir

GasGasturbineturbine

CombustorCombustor(1350(1350ooC)C)AirAir

Temp < 90Temp < 90ooC C

De-SOxunit.

DeDe--SOSOxxunitunit..

ExhaustExhaust(180(180--200200ooC)C)

Heat exchangeHeat exchange

CompressorCompressor

HyperCoalfeeder

Ash Ash < 200ppm< 200ppm

HyperCoalHyperCoal firing power firing power generationgeneration systemsystem

Particle Particle --7474µµm (m (>95>95%%))

GG

Steam turbineSteam turbineGG

Heat recoveryHeat recovery

Page 31: Current Status and Perspective of Research and Development

HyPr-Ring•H2 production process from coal with high efficiency•Integration of water carbon reaction, water gas shift reaction and CO2 absorbing reaction in a single reactor

•Temperature : 650C, reaction pressure : 6MPa or more •Absorption of CO2 using calcium oxide (CaO)•Existence of absorbent moves equilibrium of shift reaction and internally gives the energy into water gas reaction.

•Cold gas efficiency : over 75%, S contents in gas : <1 ppm•CO2 emission : same level as natural gas

Water

Hydrogen

CO2HyPr-RING

Heat

Coal (Biomass, Heavy oil)

Page 32: Current Status and Perspective of Research and Development

Fig. 11 Outline of Hypr-RING process flow

Coal

Water

Hydrogen rich clean gas

CO2

Reactor

SeparatorRecycle water

Calcination furnaceof CaCO3

CaO

CaCO3Ash

Page 33: Current Status and Perspective of Research and Development

Summary! Japan’s energy situation and energy policy were

introduced. To clear COP3 agreement, necessity of further effort of energy conservation and new energy development were emphasized.

! Current status of research and development on coal utilization technology in Japan were presented. Environment around coal is getting worse from the point of view of environmental preservation, but it is emphasized that coal energy is still very important and development of highly efficient coal utilization technology should be sustained.

Page 34: Current Status and Perspective of Research and Development

Acknowledgement! New and Renewable Energy Division, Agency of Natural Resources

and Energy (ANRE), METI! Coal Division, ANRE, METI! Environmental Industry Office, Industrial Science Technology Policy

and Environment Bureau, METI! New Energy and Industrial Technology Development Organization

(NEDO)! Center for Coal Utilization, Japan (CCUJ)! Japan Coal Energy Center (JCOAL)! J-Power (EPDC)! Mr. Yusuke Tadakuma (NEDO)! Dr. Koji Ukegawa (AIST)! Dr. Hiroyuki Hatano (AIST)! Mr. Kenji Kato (Nippon Steel Corporation)

! Professor Masakatsu Nomura (Osaka University)

Page 35: Current Status and Perspective of Research and Development

Thank you for your attention

Page 36: Current Status and Perspective of Research and Development
Page 37: Current Status and Perspective of Research and Development

Basic Research Grant Fundamental Research Project

METI

NEDO

RITE

Private sector, universities, etc.

Seeds discovery

METI

RITE, etc

Global environment conservation related to industrial technological development promotion project (seeds discovery)

Leading research project on global environment industrial technology

Program-based development of CO2 fixation and effective utilization technologies

Research and development for geological storage technologies of CO2

Study of Technology for Environmental Assessment in CO2 Ocean Sequestration to mitigate the Climate Change

Research and Development of efficient energy utilization and CO2 fixation technologies for effective reuse of paper wastes

Development of CO2 recovery and utilization technology using coal and natural gas

Development of large-scale carbon dioxide fixation technology

Promotion Scheme based on National Support System(1)

11

Page 38: Current Status and Perspective of Research and Development

Practical Application

METI

NEDO

RITE and Private organizations

Support of technological development for practicalapplication

Technological development for practical application of CO2 fixation and effective utilization

Industrial technological developmentpromotion project for achieving the Kyoto Protocol targets

Promotion Scheme based on National Support System(2)

11

Achievement of the Kyoto Protocol targets

International Cooperation

METI

NEDO

RITE and Private organizations, etc.

Support of international cooperation and collaborativeresearch on the global environment

Global environment international research promotion project

Energy environment international collaborativeresearch support project

Global environment international cooperation promotion project

International research onthe global environment

Page 39: Current Status and Perspective of Research and Development

Selection of site and targeted layer for injectionFukasawa-cho, Nagaoka City, Niigata Prefecture, Japan

Drilling of injection wellDrilling of observation wellThree observation wells have been drilled for monitoring the behavior of injected carbon

dioxide, such as migration, in the aquiferConstruction of injection facilityInjection and observation experimentThe injection of carbon dioxide : from early July 2003, 10,000 tones in total over 18 months Injection rate : 20 tones/day.

Research and development for geological storage technologies of CO2

Page 40: Current Status and Perspective of Research and Development

Study of Technology for Environmental Assessment in CO2 Ocean Sequestration to mitigate the

Climate Change (SEA-COSMIC)

! Clarification of behaviors of liquid CO2-seawater at injection

! Research on technologies of CO2 transport to intermediate depths of the ocean and dilution

! Laboratory experiment on CO2 impacts on marine organisms

! Development of models to assess environmental impacts near the area of CO2 injection

! International joint research of CO2 injection at the open ocean site as one of the CTI activities

! Supporting survey • Study on the research trends concerning CO2 ocean sequestration in Japan and

abroad

• Study on the optimization of the total system

Page 41: Current Status and Perspective of Research and Development

Expected CCT for 21st Century (1)

High Efficiency 1st Generation (1990-2000)

Pressurized Fluidized Bed Combustion (PFBC)

Supercritical Steam Power Generation System (USC)

High Efficiency 1st Generation (2000- 2010)

Integrated Coal Gasification Combined Cycle Power Generation System (IGCC)

Super Coke Oven for Productivity and Environmental enhancement toward 21st Century (SCOPE21)

Direct Iron Ore Smelting Technology (DIOS)

Page 42: Current Status and Perspective of Research and Development

Expected CCT for 21st Century (2)

Zero Emission Generation (2020- )

Hydrogen Production from Coal with CO2 Recovery System (Hyper-RING)

Technology to support Integration of Power Generation, Steel Making and Chemical Industry

High Efficiency Hybrid Generation (2010-2020)

Integrated Coal Gasification Fuel Cell Combined Cycle Power Generation System (IGFC)

Hydrogen Production Technology from Coal to support CO2 Free Energy

Co-production Technology with Power and Chemical Raw Materials

Page 43: Current Status and Perspective of Research and Development

Dimethyl Ether ProductionTechnology (DME)

Design and Evaluation of Commercial Plant

Back-up Study

100t/d Pilot PlantOperation

100t/d Pilot PlantConstruction

20032002 2004 2005 2006

Schedule of DME SynthesisPlant Construction and Operation

Page 44: Current Status and Perspective of Research and Development

Dimethyl Ether Production Technology (DME)

View of Pilot Plant (5 t/d) in Hokkaido

Compressor HouseCompressor House

DME Storage TankDME Storage Tank

Pump HousePump House

Synthesis Gas ProductionSynthesis Gas Production

Solvent Tank, OthersSolvent Tank, Others

Thermal Oil UnitThermal Oil UnitCO2 RemovalDME SynthesisDME Separation

/ Purification

Grand FlareGrand Flare

Page 45: Current Status and Perspective of Research and Development

Advanced Pressurized Fluidized Bed Combustion Technology (A-PFBC)

Basic Plan

Elementary Test / FS

Design

Manufacturing

Installation

Test Run / Evaluation

1996 1997 1998 1999 2000 2001 2002

Test Project Schedule A-PFBC PDU

Page 46: Current Status and Perspective of Research and Development

Advanced Pressurized Fluidized Bed Combustion Technology (A-PFBC) PDU of A-PFBC

PartialGasifier

Desulfurizer

Oxidizer

Page 47: Current Status and Perspective of Research and Development

Variation of ash content in HyperCoalVariation of ash content in HyperCoal

Target Level Target Level 0.02%0.02%

(200ppm)(200ppm)