cvru new guide book 2012-13-science group 14-01-2013apps.aisect.org/e-learning/english/pdf/guide...

PROGRAMME GUIDE DISTANCE EDUCATION PROGRAMMES (2012-13)

FACULTY OF SCIENCE

INSTITUTE OF OPEN AND DISTANCE EDUCATION (IODE) DR. C.V.RAMAN UNIVERSITY KARGI ROAD, KOTA, BILASPUR, CHATTISGARH PHONE : 07753-253737, 8827920016, 8827920019 FAX : 07753-253728

E-mail: [email protected] Website: www.cvru.ac.in

CVRU-IODE PROGRAMME GUIDE (2012-13) - FACULTY OF SCIENCE

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INDEX Faculty of Science BACHELOR OF SCIENCE (B. Sc.) -BIO .............................................................................................................................. 9 BACHELOR OF SCIENCE (B. Sc.) -MATHS ..................................................................................................................... 20 MASTER OF SCIENCE (M. Sc.) - MATHS ......................................................................................................................... 31 MASTER OF SCIENCE (M. Sc.) - PHYSICS ....................................................................................................................... 39 MASTER OF SCIENCE (M. Sc.) - CHEMISTRY ................................................................................................................ 46


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ABOUT UNIVERSITY Dr. C.V. Raman University was established on 3 November, 2006, in the district of Bilaspur, Chhattisgarh by the All India Society for Electronics and Computer Technology (AISECT), the Sponsoring Body. The University was named after the first Nobel Laureate of the country in the field of science – Dr. C.V. Raman, an Indian physicist whose work was influential in the growth of science in our country. The University's principal goal is to evolve a new cadre of highly skilled technical professionals with deep academic insights and a strong sense of Indian values and ethos, commemorating our forefathers who helped shape this nation. The Sponsoring Body of the University All India Society for Electronics and Computer Technology (AISECT) is an ISO 9001:2008 certified organization, established in 1985, is today one of India's most reputed and trusted Education Groups which houses private universities, engineering colleges, professional institutions & education centres across the country. Till date, AISECT has transformed the lives of over 10 lakh students and has uplifted the lives of millions of people in the community. AISECT has been lauded for its exceptional work and has won awards from the World Bank, NASSCOM, TiE, Government of India, Government of Madhya Pradesh and several others on account of its commitment to high quality education over the last 25 years. AISECT is also a partner institution with Gol, GoMP and GoCG in their Common Service Centre Program and several other projects of state and national concern. MAIN OBJECTIVES: • Provide quality higher education and make provisions for research • Create higher levels of intellectual abilities among our students • Establish state-of-the-art facilities for education, training and examination,

including online training • Carry out teaching, research and offer comprehensive learning for a bright

professional career • Create centres of excellence for R&D to promote an environment of innovation

and research • Provide consultancy to public organizations and the Industry • Award and maintain the standard of degrees, diplomas, certificates and other

academic distinctions in accordance with the norms laid down by UGC, AICTE, BCI, MCI and other regulatory bodies.

RECOGNITIONS • The University is recognized under Section 2(f) of the UGC Act • Other recognitions include AICTE, NCTE, BCI and DEC • It is the first University in the state of Chhattisgarh to be awarded an ISO:9001-

2008 Certification THE FACULTIES OF STUDIES The University has wide range of faculties which offers the traditional as well as the new era job oriented courses. The main emphasis is on providing a wide choice of courses at different levels. The following faculties currently are in operation in the University: • Faculty of Arts • Faculty of Commerce


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• Faculty of Science • Faculty of Engineering • Faculty of Information Technology • Faculty of Education • Faculty of Law ACADEMIC PROGRAMMES OFFERED BY THE UNIVERSITY IN OPEN & DISTANCE LEARNING MODE The University offers through the Institute of Open and Distance Education (IODE) both short terms and long term programmes leading to Certificates, Diploma and Degrees, which are conventional as well as innovative.. Most of these programmes have been developed after an initial survey of the demand for such Programmes in the job market. They are launched with a view to fulfil the learner's needs for: • Certification, • Improvement of skills, • Acquisition of professional qualifications, • Continuing education and professional development at work place, • Self-enrichment, • Diversification and updation of knowledge, and • Empowerment. PROMINENT FEATURES OF THE OPEN & DISTANCE EDUCATION AT CVRU The open and distance education at the Dr. C. V. Raman University has certain unique features such as • Individual study – flexible in terms of place, pace and duration of study. • Use of latest information and communication technologies • Nationwide student support service network • Modular approach to programmes • Cost-effective programmes • Socially and academically relevant programmes based on student need • Convergence of open and conventional education systems • Take higher-education to the unreached sections of the society through the use

of information technology • Provide need and knowledge-based professional education • Set the national standards for Distance Education PROGRAMME DELIVERY MODE The methodology of instruction in the distance learning mode in the University is different from that of the conventional regular courses. The system adopted for this is more learner-oriented and the learner is an active participant in the pedagogical (teaching and learning) process. Most of the instructions are imparted through distance education methodology and face-to-face mode as per the requirement. The programme delivery methodology used in the distance learning mode follows a multimedia approach for instruction, which comprises: • Self Instructional Written Material: The printed study material (written in self-

instructional style) for both theory and practical components of the programmes is supplied to the learners in batches for every course.

• Audio-Visual Material Aids: The learning package contains audio and video CDs which have been produced by the University for better clarification and enhancement of understanding of the course material given to the learners. A


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video programme is normally of 25-30 minutes duration. The video cassettes are screened at the study centres during specific sessions which are duly notified for the benefit of the learners.

• Counseling Sessions: Normally counseling sessions are held as per schedule drawn by the Study Centres. These are mostly held outside the regular working hours of the host institutions where the study centres are located.

• Teleconferences: Live teleconferencing sessions are conducted via satellite through interactive Video Conferencing facility (available at some places) from the University studios, the schedule of which is made available at the study centres.

• Industrial Training/Practicals/Project Work: Some programmes have industrial training/ practical/ project component also. Practicals are held at designated institutions for which schedule is provided by the Study Centres. Attendance at practicals is compulsory. For project work, comprehensive project guide, in the form of a booklet, is provided to the student alongwith the study materials.

• The printed study material will be dispatched periodically to the enrolled students for each paper of study. These materials will be as guide for the students for effective learning. The Assignments for internal assessment shall also be dispatched along with the study material. Online modules are also available for some of the courses. These are in progress and as and when available, these will be available on the website of the students for registered candidates.

• The counseling sessions will be of 30 days duration for a course in a year. The actual schedule and place of contact program shall be announce and communicated to students in-time.

EVALUATION SYSTEM The system of evaluation in Open and Distance Learning System is also different from that of conventional system. CVRU has a multi-tire system of evaluation.

1. Self-assessment exercises within each unit of study. 2. Continuous evaluation mainly through assignments which are tutor-marked,

practical assignments and seminar/workshops/extended contact programmes.

3. The term-end examinations. 4. Project works

The evaluation of learners depends upon various instructional activities undertaken by them. A learner has to write assignment responses compulsorily before taking term-end examination from time to time to complete an academic programme. A learner has to submit TMA responses to the Coordinator of the Study Centre concerned to which s/he is attached. A learner should keep duplicate copies of assignment responses of TMA that may be required to be produced at Student Evaluation Division on demand. Term-end examination is conducted at various examination centers spread all over the country and abroad in July and January. For Bachelors' and Masters' degree programmes, normally the assignments carries 30% weightage. TERM-END EXAMINATION AND PAYMENT OF EXAMINATION FEE The University conducts Term-end Examination once in a year in the months of May/June. Students will be permitted to appear in term-end examination subject to the conditions that 1) registration for the courses, in which they wish to appear is


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valid, 2) minimum time to pursue these courses is elapsed, and 3) they have also submitted the required number of assignment( s), if any, in those courses by the due date. Students can also submit on-line examination form as per guidelines through CVRU website at www.cvru.ac.in. Examination fee is required to be paid either through Demand Draft issued in Favour of "Registrar, Dr. C. V. Raman University" Payable at Bilaspur(CG) / online payment gateway as per the fee table. COURSES OFFERED BY IODE

Programmes offered by Institute of open and distance education (UnderGraduate, Post Graduate and Select Diploma Programmes) are as follows FACULTY OF INFORMATION TECHNOLOGY 1. Diploma in Computer Application (DCA) 2. Post Graduate Diploma in Computer Application (PGDCA) 3. Post Graduate Diploma in Computer Aidid Fashion Designing (PGDFD) 4. Post Graduate Diploma in Computer Hardware and Maintenance (PGDCHME) 5. Bachelor of Computer Application (BCA) 6. Master of Science in Information Technology (MSCIT) FACULTY OF MANAGEMENT 1. Post Graduate Diploma in Rural Development (PGDRD) 2. Post Graduate Diploma in Business Management (PGDBM) 3. Post Graduate Diploma in Marketing Management (PGDMM) 4. Post Graduate Diploma in Financial Management (PGDFM) 5. Post Graduate Diploma in Human Resource Management (PGDHRM) 6. Post Graduate Diploma in Insurance and Risk Management (PGDIRM) 7. Bachelor of Business Administration (BBA) 8. ** Master of Business Administration (MBA) [Proposed] FACULTY OF COMMERCE 1. Diploma in Accountancy (DIA) 2. Bachelor of Commerce (B.Com.) [Plain/Banking/Computer Applications] 3. Bachelor of Business Administration (BBA) 4. Master of Commerce (M.Com.) FACULTY OF ARTS 1. Bachelor of Art (BA) 2. Bachelor of Journalism and Mass Communication (BJMC) 3. Bachelor of Library & Information Sciences (B.Lib.Sc.) 4. Master of Art (English Literature) (MA EL) 5. Master of Art (Hindi Literature) (MA HL) 6. Master of Art (Political Science) (MA PS) 7. Master of Art (Sociology) (MA SOCIO) 8. Master of Art (Economics) (MA ECO) 9. Master of Art (Education) (MA EDU) 10. Master of Social Walfare (MSW) FACULTY OF SCIENCE 1. Bachelor of Science (Maths) (BSC MATH) 2. Bachelor of Science (Bio) (BSC BIO)


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3. Master of Science (Physics) (MSC PHY) 4. Master of Science (Chemistry) (MSC CHE) 5. Master of Science (Maths) (MSC MATH) FACULTY OF VOCATIONAL EDUCATION Information Technology Certificate In Computer Application (CCA) Certificate In Word Processing/Typewriting (CWP) Certificate For Data Entry Operator (CDEO) Certificate In Office Automation And Internet (COA) Certificate For Internet Kiosk Operators (CIKO) Advance Diploma In Computer Hardware And Networking (ADCHN) Commerce Certificate In Computerized Financial Accounting (CCFA) Engineering & Technology Diploma In Electrical Technician (DET) Certificate In Motor And Transformer Winding (CMTW) Certificate In Mobile And Telephone Instruments Repairing (CMTIR) Certificate In Photocopy Operation And Maintenance (CPOM) Certificate In Basic Assembling And Maintenance Of PC (CBAMP) Certificate In Repair And Maintenance Of Inverter, UPS And Power

Supply(CRMIUP) Education Diploma In Early Chidlhood Care And Education (DECCE) Diploma In Cutting, Tailoring And Dress Making (DCTDM) Please do all correspondence regarding the courses admission and other details at the following address :

The Director, Institute of Open And Distance Education (IODE)

Dr. C.V.Raman University Kargi Road, Kota, Bilaspur, Chattisgarh

Phone : 07753-253737, 8827920016, 8827920019 Fax : 07753-253728 E-mail: [email protected]

Student Support Desk :

Phone:8359050061, 8359050064

e-mail: [email protected]

PROGRAMME GUIDE DISTANCE EDUCATION PROGRAMMES

BACHELOR OF SCIENCE (B. Sc.) -BIO

• Scheme of Examination • Detailed Syllabus • Counseling and Study Structure • Study Modules & Books Information • Date Schedule & Instructions for Submitting Assignments




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BACHELOR OF SCIENCE (B.SC.) – BIO GROUP Duration:36 Months Eligibility:12th Pass from Science Subjects Scheme of Examination

(FIRST YEAR) Course Code

Name of the Course Credit Total Marks

Theory Practical Marks

Assignments

Max Min Max Min Max Min First Semester 1BSC1 Hindi Language 2 70 50 17 - - 20 7 1BSC2 English Language 2 70 50 17 - - 20 - 1BSC3 Environmental Studies 3 50 50 17 - - 1BSC4 Physical Chemistry 3 120 50 17 50 25 20 7 1BSC5 Zoology-I (Cell Biology &

Invertebrates) 3 70 50 17 - - 20 7

1BSC6 Botany-I (General Diversity Of Microbes And Cryptogams)

3 70 50 17 - - 20 7

Total 450 300 50 100 Second Semester 2BSC1 Environmental

Studies(Project) 4 70 - 50 25 20 7

2BSC2 Organic Chemistry 3 70 50 17 - - 20 7 2BSC3 Inorganic Chemistry 3 70 50 17 - - 20 7 2BSC4 Zoology–II (Vertebrates &

Embryology) 3 120 50 17 50 25 20 7

2BSC5 Botany–II (Cell Biology And Genetics )

3 120 50 17 50 25 20 7

Total 450 200 150 100

Evaluation Scheme 1. 33% in each theory, practical, project, dissertation & internal assessment

2. 36% Aggregate marks to pass

DETAILED SYLLABUS vk/kkj ikBÓØe

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bZdkbZ 2 eqgkojsa Ykkd¨fä;k] ’kCn ’kqf)] okD; ’kqf)] ’kCn Kku] i;kZ;okph] foYk¨e] 10 vad

vusdkFkÊ] le&Jqr ¼leku a pfjr½ vusd ’kCn a ds fYk, ,d ’kCnA

bZdkbZ 3 nsoukxjh fYkfi dh fo’¨"krk] nsoukxjh fYkfi, oa orZuh dk ekud #iA 10 vad

bZdkbZ 4 dEI;wVj esa fgUnh dk vuqÁ;¨x] fgUnh esa inukeA 10 vad

bZdkbZ 5 fgUnh vifBr la{¨i.k fgUnh esa laf{kIrhdj.kA 10 vad


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ENGLISH LANGUAGE

Unit--1 Basic Language Skills : Grammar and Usage. 10 Marks

Grammar and Vocabulary based on the Prescribed text.

To be assessed by objective/multiple choice tests.

Unit--2 Comprehension of an unseen passage. 10 Marks

This should imply not (a) and understanding of the passage in question, but also.

(b) a grasp of general language skills and issues with reference to words and usage. within the passage and

(c) the power of short independent composition based themes and issued in the passage.

Unit--3 Comprehension: Paragraph writing - 10 Marks

Unit--4 Letter writing (The formal and one informal) 10 Marks

Two letters to be attempted of 5 marks each one formal and one informal.

Unit--5 Texts : 10 Marks

Short prose pieces (Fiction and nonfiction) short poems the precis

should cover a range of authors, subject and contexts, With poetry it may sometimes be advisable to include précis from earlier periods, which are often simpler than modern examples in all cases, the language should be accessible(with a minimum of explanation and reference to standard dictionaries) to the general body of students schooled in the medium of an Indian language Students should be able to grasp the contents of each piece, explain specific words, phrases and allusions; and comment on general points of narrative or argumental. Formal Principles of Literary criticism should not be taken up at this stage.

ENVIRONMENTAL STUDIES UNIT-I General: Environmental segments, environmental degradation, environmental impact assessment.Concept of Ecosystem: Fundamental of Ecology and Ecosystem, components of ecosystem, food-chain, food-web, trophic levels, energy flow, cycling of nutrients, major ecosystem types (forest, grass land and aquatic ecosystem).

UNIT-II Air Pollution: Atmospheric composition, energy balance, classification of air pollutants, source and effect of pollutants – Primary (CO, SOx, NOx, particulates, hydrocarbons), Secondary [photochemical smog, acid rain, ozone, PAN (Peroxy Acetyl Nitrate)], green house effect, ozone depletion, atmospheric stability and temperature inversion, Techniques used to control gaseous and particulate pollution,

UNIT-III Water Pollution: Hydrosphere, natural water, classification of water pollutants, trace element contamination of water, sources and effect of water pollution, types of pollutants, determination and significance of D.O., B.O.D., C.O.D. in waste water, Eutrophication, methods and equipment used in waste water treatment preliminary, secondary and tertiary.

UNIT-IV Land Pollution & Noise Pollution: Lithosphere, pollutants (agricultural, industrial, urban waste, hazardous waste), their origin and effect, collection of solid waste, solid waste management, recycling and reuse of solid waste and their disposal techniques (open dumping, sanitary land filling, thermal, composting). Noise Pollution: Sources, effect, standards and control.


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UNIT-V Environmental Biotechnology: Definition, current status of biotechnology in environmental protection, bio-fuels, bio-fertilize, bio-surfactants, bio-sensor, biochips, bio-reactors. Pollution Prevention through Biotechnology: Tannery industry, paper and pulp industry, pesticide industry, food and allied industry.

PHYSICAL CHEMISTRY UNIT-I Mathematical Concepts

Logarithmic relations, curves stretching, linear graphs and calculation of slopes, Differentiation of functions like Kx, ex, xn, sinx, logx; maxima and minima, partial differentiation and reciprocity relations. Integration of some useful / relevant functions; permutations and combinations. Factorials, Probability.

Unit-II Computers

General introductions to computers, different components of a computers. Hardware and software, Input-output devices, binary numbers and arithmetic; introduction to computer languages. Programming and operating systems.

Unit-III Gaseous States

Postulates of kinetic theory of gases, deviation from ideal behaviour, vander Waals equation of State.

Critical phenomenon: PV isotherms of ideal gases, continuity of states, the isotherms of van der Waals equations, relationship between critical constants and van der Waals constants, the law of corresponding states, reduced equation of states.

Unit-IV Colloidal State

Definition of colloids, classification of colloids. Solids in liquids (sols): properties- Kinetic, optical and electrical ; stability of colloids, protective action, Hardy-Schulz law, gold number. Liquids in liquids (emulsions), types of emulsions, preparation. Emulsifier. Liquids in solids (gels): classification, preparation and properties, inhibition, general applications of colloids.

UNIT-V Chemical Kinetics-I

Chemical kinetics and its scope, rate of a reaction, factors influencing the rate of a reaction concentration, temperature, pressure, solvent, light, catalyst concentration dependence of rates, mathematical characteristics of simple chemical reactions- zero. order, pseudo order, half life and mean life Determination of the order of reaction differential method, method of integration, method of half life period and isolation method.

PRACTICAL- CHEMISTRY SYLLABUS

PRACTICAL - SEMESTER I Duration of practical during the semester: 90 hrs Examination: 4 hours

Analysis:

Physical Chemistry

1. Calibration of thermometer

2. Determination of melting point


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3. Determination of boiling point


5. Preparation of solutions of various concentrations, NaOH, HCl, H2SO4

6. To determine the velocity constant (specific reaction rate) of hydrolysis of methyl acetate /ethyl acetate catalyzed by hydrogen ions at room temperature.

7. To study the effect of acid strength on the hydrolysis of an ester.

8. To compare the strength of HCl and H2 SO4 by studying the kinetics of hydrolysis of ester.

9. To study kinetically the reaction rate of decomposition of iodide by H2O2.

10. Determination of surface tension / percentage composition of given organic mixture using surface tension method.

11. Determination of viscosity / percentage composition of given organic mixture using viscosity method.

Organic Chemistry:

1. Detection of elements (N, S and halogens) 2 elements

2. Functional groups (phenolic, carboxylic, carbonyl, esters, carbohydrates, amines, amides, nitro and aniline) in simple organic compounds.

Inorganic:

1.Macro/semi-micro analysis- Cation analysis, separation of ions from group I -VI, anion analysis

2 Separation of cations by paper chromatography.

3. Preparation of ferrous alum.

BOTANY-I (GENERAL DIVERSITY OF MICROBES AND CRYPTOGAMS)

UNIT-I Viruses and Bacteria: General account of Viruses and Mycoplasma; Bacteria structure; nutrition, reproduction and economic importance; general account of Cyanobacteria.

UNIT-II Algae: General characters. Classification and economic importance: important features and life history of Chlorophyceae- Volvox, Oedogonium, Coleochaete; Xanthophyceae-Vaucheria; Phaeophyceae- Ectocarpus, Sargassum; Rhodophyceae- Polysiphonia.

UNIT-III Fungi: General characters, classification and economic importance; important features and life history of Mastigomycotina- Pythium, Phytophthora; Zygomycotina- Mucor, Ascomycotina-Sachromyces, Eurotium, Chaetomium, Peziza; Basidiomycotina-Puccinia, Agaricus; Deuteromycotina-Cercospora, Colletotrichum; general account of Lichens.

UNIT-IV Bryophyta: Amphibians of plant kingdom displaying alternation of generations; structure, reproduction and classificalton of Hepaticopsida (e.g. Riccia Marchantia); Anthocerotopsida (e.g. Anthoceros), Bryopsida (e.g. Funaria).

UNIT-V Pteridophyta: The first vascular plants; important characteristics of Psilopsida, Lycopsida, Sphenopsida and Pteropsida; Structure, Reproduction in Rhynia, Lycopodium Selaginella, Equisetum, Pteris and Marsilea.


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ZOOLOGY-I (CELL BIOLOGY & INVERTEBRATES)

UNIT-I The Cell (Prokaryotic & Eukaryotic), Methods in Cell biology (Microscopy Light & Electron) Organisation of cell extranuclear and nuclear (Plasma Membrane, Mitochondria, Chromosomas, E.R. Golgi bodies, Ribosome).

UNIT-II Cell divisions (Mitosis & Meiosis) An elementary idea of cell transformation & Cancer Immunity (Elementary idea).

UNIT-III General Characteristics & Classification of Invertebrates upto orders with examples, Protozoa- type study Paramecium, Protozoa & disease Porifera - type study- Sycon, Coelenterata- type study Obelia.

UNIT-IV Helminthes: type study- Fasciola, Annelida: type study -Pheretima, Arthopoda: type study- Palaemon.

UNIT-V Mollusca: type study - Asterias (Starfish) Protochordata: type study- Balanoglossus.

SEMESTER. II PAPER-II INORGANIC CHEMISTRY

UNIT-I Atomic Structure

Idea of de Broglie matter waves, Heisenberg uncertainty principle, atomic orbitals, Schrödinger wave equation, significance of ψ1 and ψ2, quantum numbers, radial and angular wave functions and probability distribution curves, shapes of s, p, and d orbitals. Aufbaus and Pauli exclusion principles, Hund.s multiplicity rules. Electronic configurations of the elements, effective nuclear charge.

UNIT-II Periodic Properties

Atomic and ionic radii, ionization energy, electron Affinity and electronegativity: definition, method of determination, trends in periodic table and applications.

UNIT-III Chemical Bonding –

Covalent bond- valence bond theory and its limitations, directional characteristic of covalent bond. Hybridization and shapes of simple molecules and ions. Valence Shell Electron Pair Repulsion (VSEPR) theory to NH3, SF4, ClF3, ICl4 -.and H2O, Molecular Orbital theory for homonuclear and heteronuclear (CO and NO) diatomic molecules,

UNIT-IV S Block Elements

Comparative study, diagonal relationships, salient features of hydrides, salvation and Complexation tendencies including their function in biosystems, an introduction to alkyls and aryls.

UNIT-V P Block Elements

Comparative study (including diagonal relationship) of groups 13-17 elements,

compounds like hydrides, oxides, oxyacids and halides of groups 13-16

Hydrides of boron-diborane, basic properties of halogens, interhalogens.


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SEMESTER II ORGANIC CHEMISTRY

UNIT-I Structure and Bonding

Hybridizations, Bond lengths and bond angles, bond energy : Localized and delocalized chemical bond, vander Waals interactions, inclusion compounds, clatherates, charge transfer complex, resonance, hyperconjugation, aromaticity, inductive and field effects, hydrogen bonding.

UNIT-I I Types of Reagents

Electrophiles and nucleophiles. Types of organic reactions. Energy consideration. Reactive intermediates- carbocations, carbanions, free radicals and carbenes. Methods of determination of reaction mechanism.

UNIT-III Stereo-chemistry

Concept of isomerism, types of isomerism, optical isomerism, elements of symmetry, molecular chirallity, enantiomers, stereogenic centres, optical activity, properties of enantiomers, chiral and achiral molecules with two stereogenic centres, distereoisomers, mesocompounds, resolution of enantiomers, inversion, retention and racemization.

Relative and absolute configurations, sequence rules, D & L, R & S systems of nomenclature. Nomenclature E and Z system, conformational analysis of ethane and n-butane

UNIT-IV Alkanes, Alkenes and Alkynes

IUPAC nomenclature, classification, isomerism in alkanes, sources, and methods of preparation (with special reference to Wurtz, Kolbe acids). Physical properties and chemical reactions of alkanes. Mechanism of free radical halogination of alkanes.

Nomenclature of alkenes, methods of formation, Chemical reactions of alkenes mechanisms involved in hydrogenation, electrophilic and free radical additions, Markownikoff.s rule, peroxide effect. Nomenclature, structure and bonding

in alkynes. Methods of formation. Chemical reactions of alkynes, acidity of alkynes.

UNIT-V Arenes, Aromaticity, Dienes

Benzene, resonance structure. MO picture. Aromaticity the Huckel rule, aromatic ions. Aromatic electrophilic substitution, mechanism, Mechanism of nitration, halogenation. sulphonation. and Friedel-Crafts reaction.

Energy profile diagrams. Activating and deactivating substituents. orientation and ortho/para

ratio. alkynylbenzenes and biphenyl. Nomemclature and classification of dienes: isolated conjugated and cumulated dienes.Structure of allenes and butadiene, methods of formation, polymerization. Chemical reactions-1, 2 and 1, 4 additions, Diels Alder reaction..

BOTANY-II CELL BIOLOGY AND GENETICS

UNIT-I The cell envelope: Plasma membrane; Bilayer lipid structure; functions: the cell wall. Ultra structure and function of Nucleus: nuclear membrane; nucleolus and other organelles: Golgi bodies, ER, Peroxisomes, and Vacuoles.


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UNIT-II Chromosome organization: Morphology; Centromere and- telomere; Chromosome Alterations; deletions, duplications, translocations, inversions; variations in chromosome number aneuploidy, polyploidy; sex chromosomes. Cell division: Mitosis; meiosis.

UNIT-III DNA the genetic material: DNA structure; replication; DNA- protein interaction; the. nucleosome model; genetic code; satellite and repetitive DNA. Extra nuclear genome: Presence and function of mitochondria and plastid DNA; plasmids.

UNIT-IV Gene expression: Structure of gene.; Transfer of genetic information; transcription, translation, Protein synthesis; t-RNA; Ribosomes; regulation of gene expression in prokaryotes and eukaryotes; proteins, 1 D, 2D and 3D structure.

UNIT-V Genetic Variations: Mutations, I spontaneous and induced; transposable genetic elements; DNA damage and repair: Genetic inheritance: Mendelism; Laws of segregation, Law of Independent assortment: Linkage analysis; allelic and non-allelic interactions.

BOTANY PRACTICAL Practical work will be based on the syllabus prescribed in the Theory paper.

1) Major exercise- a Anatomical study of Pteridophytes- a. Stem & Cone of Equisetum, b. Stem & strobilus of Selaginella, c. Anatomical study of Marsilea, d. Stem & strobilus of Lycopodium and Ferns sori & vegetation portion.

2) Minor exercise- To study & identify the given materials of Algae.

Volvox, Oedogonium, Ectocarpus, Chara, Polysiphonia, Batrochospermum, Spirogyra, Ultothrix, Ulva, Caulerpa, Nostoc, Anabaena & Vaucheria.

3) To study & indentify the plant material of fungi: Agaricus, Mucor, Peziza, Puccinia,

Cercospora, Sacchromyces and Pythium.

4) Studies on the external & internal features of Riccia, Marchantia & Anthoceros

5) Exercise on the Monohybrid & Dihybrid Cross.

6) Exercise on the Test Cross & Incomplete Dominance.

7) Plant specimens – based on Algae, Fungi, Bryophyta & Pteridophyta.

8) Slides & Models- Meiosis, Mitosis, Double Helix model & Chromosomes.

9) To identify the following plant diseases specimens: Tikka disease of groundnut, red rot of sugarcane, early blight of potato, late blight of potato, mosaic disease of virus, black rust of wheat, agaricus fruiting body, lycoperdon & morchella, red stripe of sugarcane, lichen crustose, fruticose & foliose

ZOOLOGY -II (VERTEBRATES & EMBRYOLOGY)

UNIT-I Origin and Classification of Chordates. Protochordata - type study Amphioxus. A comparative account of Petromyzon & Myxine.


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UNIT-II Fishes - Skin and scales Migration in fishes Parental care

Amphibia - Parental care, Neoteny.

Reptilia - Poisonous & non poisonous snakes, Poison apparatus, snake venom.

UNIT-III Aves - Flight adaptation in Birds.

Discuss - Birds are glorified Reptiles.

Mammals- comparative account of Prototheria, Metatheria & Eutheria & its affinities.

UNIT-IV Gametogenesis, Fertilitation & Parthenogenesis.

Development of Frog upto formation of three germ layers.

UNIT-V Development of Chick upto formation of three germ layer, Extra embryonic membranes, Placenta in Mammals. Embryonic induction organizers & differentiation.

ZOOLOGY-II PRACTICAL

The practical work in general shall be based on the syllabus prescribed in theory and the candidates will be required to show knowledge of the following.

Dissection of Earthworm.

Dissection of Cockroach, Palaemon, Pila.

Minor Dissection- Appendages of Prawn & hastate plate, Mouth-parts of Insects, Radula of Pila.

Mounting-Setae, Spermatheca, Septal Nephridia, Nerve ring & ovary of earth worm/Parapodia of Neris Salivary gland of Cockroach, Malpighian tubules.

Cytological preparation- Onion root-tip Squash preparation for Mitosis/Grasshopper, Testis squash for Meiosis.

Osteology-Frog & Rabbit

Museum specimen: invertebrate & Vertebrate, Frog embryology.

Slides- Chick embryology, Cytology, Mammal Histology, Bird feather & Invertebrate slides.


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COUNSELING AND STUDY STRUCTURE

Sl. No.

Course Code

Title of the Course

Credit Total Hours of Study

Counselling and Study Structure (hours) Project Face to Face Counselling

Self study

Practical Assignments

Semester I 1 1BSC1 Hindi

Language 2 60 8 34 18 -

2 1BSC2 English Language

2 60 8 34 18 -

3 1BSC3 Environmental Studies

3 90 12 51 - 27 -

4 1BSC4 Physical Chemistry

3 90 12

33 18 27 -

5 1BSC5 Zoology-I (Cell Biology & Invertebrates)

3 90 12 51 - 27 -

6 1BSC6 Botany-I (General Diversity Of Microbes And Cryptogams)

3 90 12 51 - 27 -

Semester II 7 2BSC1 Environmental

Studies(Project) 4 120 16 - - - 104

8 2BSC2 Organic Chemistry

3 90 12 51 - 27 -

9 2BSC3 Inorganic Chemistry

3 90 12 51 - 27 -

10 2BSC4 Zoology–II (Vertebrates & Embryology)

3 90 12

33 18 27 -

11 2BSC5 Botany–II (Cell Biology And Genetics )

3 90 12

33 18 27 -

STUDY MODULES AND BOOKS INFORMATION

Course Code

Name of the Course Books / Module to be used

SEMESTER-I 1BSC1 Hindi Language Òkjrh;rk ds Loj lk/ku /kuat; oekZ e/;Áns’k vdkneh

dEI;wVj v©j fgUnh, gfje¨gu, r{kf’kYkk Ádk’ku] fnYYkhA

1BSC2 English Language English Language and Indian Culture - Published by M.P. Hindi Granth Academy Bhopal

1BSC3 Environmental Studies A Textbook of Environmental Chemistry and Pollution Control by S.S. Dara (S. Chand and Company)

Environment and Ecology by Piyush Kant Pandey and Dipti Gupta (Sum India Publication)

1BSC4 Physical Chemistry Unified Chemistry Dr. M. M. N. Tandon, Shivlal Agrawal & Co.

Unified Practical Chemistry Dr. M. M. N. Tandon, Shivlal Agrawal & Co.

1BSC5 Zoology-I (Cell Biology & Invertebrates)

Unified Zoology, Tiwari & Singh, Shivlal Agrawal & Co.

1BSC6 Botany-I (General Diversity Of Unified Botany, S.B.Agrawal, Shivlal Agrawal &


19

Microbes And Cryptogams) Co. SEMESTER-II

2BSC1 Environmental Studies(Project) • A Textbook of Environmental Chemistry and Pollution Control by S.S. Dara (S. Chand and Company)

2BSC2 Organic Chemistry • Unified Chemistry, Dr. M. M. N. Tandon • Unified Practical Chemistry Dr. M. M. N. Tandon

2BSC3 Inorganic Chemistry • Unified Chemistry, Dr. M. M. N. Tandon • Unified Practical Chemistry Dr. M. M. N. Tandon

2BSC4 Zoology–II (Vertebrates & Embryology) • Unified Zoology, Tiwari & Singh, Shivlal Agrawal & Co.

• Practical Book : Shivlal Agrawal & Co. • Laboratory Techniques by Swaroop, Arora &

Pathak.2BSC5 Botany–II (Cell Biology And

Genetics ) • Unified Botany, S.B.Agrawal, Shivlal Agrawal &

Co. • B P Pandey Modern Practical Botany Vol . I S.

Chand

DATE SCHEDULE & INSTRUCTIONS FOR SUBMITTING ASSIGNMENTS

DUE DATE OF SUBMISSION OF ALL ASSIGNMENTS AT THE STUDY CENTRE

Semester Assignment No. Due Date First Semester 1BSC1 1BSC2 1BSC3 1BSC4 1BSC5 1BSC6

• April 30 (for January Session ) • October 31 (for July session)

Second Semester 2BSC1 2BSC2 2BSC3 2BSC4 2BSC5 • October 31 (for July Session ) • April 30 (for January session)

Note: Assignments of the course are available for download at the CVRU Website http://www.cvru.ac.in . You can download the assignments as per your course, follow the instructions given and submit it before due dates at the study centre.


BACHELOR OF SCIENCE (B. Sc.) -MATHS





21

BACHELOR OF SCIENCE (B.SC.) – MATHS GROUP Duration:36 Months Eligibility:12th Pass from Science Subjects Scheme of Examination




Assignments

Max Min Max Min Max Min First Semester 1BSC1 Hindi Language 2 70 50 17 - - 20 7 1BSC2 English Language 2 70 50 17 - - 20 7 1BSC3 Environmental Studies 3 50 50 17 - - 1BSC4 Physical Chemistry 3 120 50 17 50 25 20 7 1BSC5 Maths –I

Algebra And Trigonometry 3 70 50 17 - - 20 7

1BSC6 Physics -I 3 70 50 17 - - 20 7 Total 450 300 50 100 Second Semester 2BSC1 Environmental

Studies(Project) 1 50 - 50 25

2BSC2 Organic Chemistry 3 70 50 17 - - 20 7 2BSC3 Inorganic Chemistry 3 70 50 17 - - 20 7 2BSC4 Maths–II Calculus

3 70 50 17 - - 20 7

2BSC5 MATHS-III Vector Analysis And Geometry

3 70 50 17 - - 20 7

2BSC6 Physics -II 3 120 50 17 50 25 20 7 Total 450 250 100 100



DETAILED SYLLABUS vk/kkj ikBÓØe

ch-,l-lh- ¼ÁFke lsesLVj½

fgUnh Òk"kk

ikBÓ fo"k; %&

bZdkbZ 1 iYYkou] i«kkpkj rFkk vuqokn, oa ifjÒkf"kd ’kCnkoYkhA 10 vad

bZdkbZ 2 eqgkojsa Ykkd¨fä;k] ’kCn ’kqf)] okD; ’kqf)] ’kCn Kku] i;kZ;okph] foYkë] 10 vad

vusdkFkÊ] le&Jqr ¼leku a pfjr½ vusd ’kCnä ds fYk,, d ’kCnA

bZdkbZ 3 nsoukxjh fYkfi dh fo’¨"krk] nsoukxjh fYkfi, oa orZuh dk ekud #iA 10 vad

bZdkbZ 4 dEI;wVj esa fgUnh dk vuqÁ;¨x] fgUnh esa inukeA 10 vad

bZdkbZ 5 fgUnh vifBr la{ï.k fgUnh esa laf{kIrhdj.kA 10 vad

ENGLISH LANGUAGE Unit--1 Basic Language Skills : Grammar and Usage. 10 Marks

Grammar and Vocabulary based on the Prescribed text.

To be assessed by objective/multiple choice tests.


22

Unit--2 Comprehension of an unseen passage. 10 Marks

This should imply not (a) and understanding of the passage in question, but also.

(b) a grasp of general language skills and issues with reference to words and usage. within the passage and

(c) the power of short independent composition based themes and issued in the passage.

Unit--3 Comprehension: Paragraph writing - 10 Marks

Unit--4 Letter writing (The formal and one informal) 10 Marks

Two letters to be attempted of 5 marks each one formal and one informal.

Unit--5 Texts : 10 Marks

Short prose pieces (Fiction and nonfiction) short poems the precis

should cover a range of authors, subject and contexts, With poetry it may sometimes be advisable to include précis from earlier periods, which are often simpler than modern examples in all cases, the language should be accessible(with a minimum of explanation and reference to standard dictionaries) to the general body of students schooled in the medium of an Indian language Students should be able to grasp the contents of each piece, explain specific words, phrases and allusions; and comment on general points of narrative or argumental. Formal Principles of Literary criticism should not be taken up at this stage.

ENVIRONMENTAL STUDIES UNIT-I General: Environmental segments, environmental degradation, environmental impact assessment.Concept of Ecosystem: Fundamental of Ecology and Ecosystem, components of ecosystem, food-chain, food-web, trophic levels, energy flow, cycling of nutrients, major ecosystem types (forest, grass land and aquatic ecosystem).

UNIT-II Air Pollution: Atmospheric composition, energy balance, classification of air pollutants, source and effect of pollutants – Primary (CO, SOx, NOx, particulates, hydrocarbons), Secondary [photochemical smog, acid rain, ozone, PAN (Peroxy Acetyl Nitrate)], green house effect, ozone depletion, atmospheric stability and temperature inversion, Techniques used to control gaseous and particulate pollution,

UNIT-III Water Pollution: Hydrosphere, natural water, classification of water pollutants, trace element contamination of water, sources and effect of water pollution, types of pollutants, determination and significance of D.O., B.O.D., C.O.D. in waste water, Eutrophication, methods and equipment used in waste water treatment preliminary, secondary and tertiary.

UNIT-IV Land Pollution & Noise Pollution: Lithosphere, pollutants (agricultural, industrial, urban waste, hazardous waste), their origin and effect, collection of solid waste, solid waste management, recycling and reuse of solid waste and their disposal techniques (open dumping, sanitary land filling, thermal, composting). Noise Pollution: Sources, effect, standards and control.

UNIT-V Environmental Biotechnology: Definition, current status of biotechnology in environmental protection, bio-fuels, bio-fertilize, bio-surfactants, bio-sensor, biochips, bio-reactors. Pollution Prevention through Biotechnology: Tannery industry, paper and pulp industry, pesticide industry, food and allied industry.

PHYSICAL CHEMISTRY UNIT-I


23

Mathematical Concepts

Logarithmic relations, curves stretching, linear graphs and calculation of slopes, Differentiation of functions like Kx, ex, xn, sinx, logx; maxima and minima, partial differentiation and reciprocity relations. Integration of some useful / relevant functions; permutations and combinations. Factorials, Probability.

Unit-II Computers

General introductions to computers, different components of a computers. Hardware and software, Input-output devices, binary numbers and arithmetic; introduction to computer languages. Programming and operating systems.

Unit-III Gaseous States

Postulates of kinetic theory of gases, deviation from ideal behaviour, vander Waals equation of State.

Critical phenomenon: PV isotherms of ideal gases, continuity of states, the isotherms of van der Waals equations, relationship between critical constants and van der Waals constants, the law of corresponding states, reduced equation of states.

Unit-IV Colloidal State

Definition of colloids, classification of colloids. Solids in liquids (sols): properties- Kinetic, optical and electrical ; stability of colloids, protective action, Hardy-Schulz law, gold number. Liquids in liquids (emulsions), types of emulsions, preparation. Emulsifier. Liquids in solids (gels): classification, preparation and properties, inhibition, genera applications of colloids.

UNIT-V Chemical Kinetics-I

Chemical kinetics and its scope, rate of a reaction, factors influencing the rate of a reaction concentration, temperature, pressure, solvent, light, catalyst concentration dependence of rates, mathematical characteristics of simple chemical reactions- zero. order, pseudo order, half life and mean life Determination of the order of reaction differential method, method of integration, method of half life period and isolation method.

PRACTICAL- CHEMISTRY SYLLABUS PRACTICAL - SEMESTER I

Duration of practical during the semester: 90 hrs Examination: 4 hours

Analysis:

Physical Chemistry

1. Calibration of thermometer


3. Determination of boiling point


5. Preparation of solutions of various concentrations, NaOH, HCl, H2SO4

6. To determine the velocity constant (specific reaction rate) of hydrolysis of methyl acetate /ethyl acetate catalyzed by hydrogen ions at room temperature.

7. To study the effect of acid strength on the hydrolysis of an ester.

8. To compare the strength of HCl and H2 SO4 by studying the kinetics of hydrolysis of ester.


24

9. To study kinetically the reaction rate of decomposition of iodide by H2O2.

10. Determination of surface tension / percentage composition of given organic mixture using surface tension method.

11. Determination of viscosity / percentage composition of given organic mixture using viscosity method.

Organic Chemistry:

1. Detection of elements (N, S and halogens) 2 elements

2. Functional groups (phenolic, carboxylic, carbonyl, esters, carbohydrates, amines, amides, nitro and aniline) in simple organic compounds.

Inorganic:

1.Macro/semi-micro analysis- Cation analysis, separation of ions from group I -VI, anion analysis

2 Separation of cations by paper chromatography.

3. Preparation of ferrous alum.

MATHEMATICS -I ALGEBRA AND TRIGONOMETRY

UNIT-I Mapping, Equivalence Realation & Partitions, Congruence modulo n. Symmetric. Skew Symmetric. Hermitian & skrew hermitian matrices. Elementry operations on matrices. Inverse of a matrix. Linear independence of row and column matrices. Row rank, column rank and rank of a matrix. Equivalence of column & row ranks.

UNIT-II Eigen values, Eigen vectors and the characteristic equation of a matrix. Cayley-Hamilton theorem & its use in finding inverse of a matrix. Application of matrices to a system of linear (both homogenous and non-homogenous) Equations. Theorem on consistency of a system of linear equations.

UNIT-III Relation between the roots & coefficients of general polynomial equations in one variable. Transformation of equations, Solution of cubic equation(Cardon method). Biquadratic Equations.

UNIT-IV Definition of a group with examples and simple properties. Subgroups, Generation of groups, Coset decomposition. Lagrange’s theorem and its consequences. Fermat’s and Eulers Theorem. Homomorphism & Isomorphism. Normal subgroups. Quotient groups. The Fundamental theorem on homorphism. Permutation groups. Even and odd permutations. Introduction to rings, Subrings, Integral domains & fields. Characteristic of a ring.

UNIT-V De Movire’s theorem & its application. Direct & inverse circular & hyperbolic functions. Logarithm of a complex quantity. Expantion of a trigonometrical functions. Gregory’s series. Summational of Series.

PHYSICS-I

UNIT-:- I MECHANICS:- Laws of motion, motion in a uniform field. Motion under a central force, Kepler’s law, Gravitational law and field. System of particles, centre of mass, equation of motion, conservation of linear and angular momenta, conservation of energy. Rigid body motion, rotational motion, moment of inertia and their products.


25

UNIT:- II PROPERTIES OF MATTER: Kinematics of moving fluids, equation of continuity, Euler’s equation, Bernaulli’s theorm, viscous fluids, streamline and turbulent flow, Poiseulle’s law, Capillary tube flow, Reynold’s number, Stoke’s law.Surface tension and surface energy, molecular interpretation of surface tension, pressure on a curved liquids surface, wetting.

UNIT: - III Oscillations:-Case of harmonic oscillations; differential equation and its solution, kinetic and potential energy, spring and mass system, simple and compound pendulum, torsional pendulum, Helmholtz resonator. Interference, superposition of two mutually perpendicular simple harmonic vibrations of the same frequency, Lissajous figures, case of defferent frequencies. Damped harmonic oscillators.

UNIT:-IV Waves:-Speed of transverse waves on a uniform string, speed of longitudinal waves in a fluid. Linear homogeneous equations and the superposition principle nonlinear superposition and consequences. Standing waves as normal modes of bounded systems, examples, Harmonic; and the quality of sound; examples. Chaldni’s figures and vibrations of a drum. Production and detection of ultrasonic and infrasonic waves and applications.

UNIT:- V Acoustics:- The human ear and its responses; limits of human audibility, intensity and loudness, bel and decibel, the musical scale, temperament and musical instruments.Acoustic impedance of a medium, impedance matching for transducers, diffraction of sound, principle of a sonar system, sound ranging.Transducers and their characteristics: Recording and reproduction of sounds, reverberation, Measurements of frequency, wave form, intensity and velocity, The acoustics of halls, reverberation period, Sabine’s formula.

SEMESTER-II PAPER-II INORGANIC CHEMISTRY

UNIT-I Atomic Structure

Idea of de Broglie matter waves, Heisenberg uncertainty principle, atomic orbitals, Schrödinger wave equation, significance of ψ1 and ψ2, quantum numbers, radial and angular wave functions and probability distribution curves, shapes of s, p, and d orbitals. Aufbaus and Pauli exclusion principles, Hund.s multiplicity rules. Electronic configurations of the elements, effective nuclear charge.

UNIT-II Periodic Properties

Atomic and ionic radii, ionization energy, electron Affinity and electronegativity: definition, method of determination, trends in periodic table and applications.

UNIT-III Chemical Bonding –

Covalent bond- valence bond theory and its limitations, directional characteristic of covalent bond. Hybridization and shapes of simple molecules and ions. Valence Shell Electron Pair Repulsion (VSEPR) theory to NH3, SF4, ClF3, ICl4 -.and H2O, Molecular Orbital theory for homonuclear and heteronuclear (CO and NO) diatomic molecules,

UNIT-IV S Block Elements

Comparative study, diagonal relationships, salient features of hydrides, salvation and Complexation tendencies including their function in biosystems, an introduction to alkyls and aryls.

UNIT-V P Block Elements


26

Comparative study (including diagonal relationship) of groups 13-17 elements,

compounds like hydrides, oxides, oxyacids and halides of groups 13-16

Hydrides of boron-diborane, basic properties of halogens, interhalogens.

SEMESTER II ORGANIC CHEMISTRY

UNIT-I Structure and Bonding

Hybridizations, Bond lengths and bond angles, bond energy : Localized and delocalized chemical bond, van-der Waals interactions, inclusion compounds, clatherates, charge transfer complex, resonance, hyper conjugation, aromaticity, inductive and field effects, hydrogen bonding.

UNIT-I I Types of Reagents

Electrophiles and nucleophiles. Types of organic reactions. Energy consideration. Reactive intermediates- carbocations, carbanions, free radicals and carbenes. Methods of determination of reaction mechanism.

UNIT-III Stereo-chemistry

Concept of isomerism, types of isomerism, optical isomerism, elements of symmetry, molecular chirallity, enantiomers, stereogenic centres, optical activity, properties of enantiomers, chiral and achiral molecules with two stereogenic centres, distereoisomers, mesocompounds, resolution of enantiomers, inversion, retention and racemization.

Relative and absolute configurations, sequence rules, D & L, R & S systems of nomenclature. Nomenclature E and Z system, conformational analysis of ethane and n-butane

UNIT-IV Alkanes, Alkenes and Alkynes

IUPAC nomenclature, classification, isomerism in alkanes, sources, and methods of preparation (with special reference to Wurtz, Kolbe acids). Physical properties and chemical reactions of alkanes. Mechanism of free radical halogination of alkanes.

Nomenclature of alkenes, methods of formation, Chemical reactions of alkenes mechanisms involved in hydrogenation, electrophilic and free radical additions, Markownikoff.s rule, peroxide effect. Nomenclature, structure and bonding

in alkynes. Methods of formation. Chemical reactions of alkynes, acidity of alkynes.

UNIT-V Arenes, Aromaticity, Dienes

Benzene, resonance structure. MO picture. Aromaticity the Huckel rule, aromatic ions. Aromatic electrophilic substitution, mechanism, Mechanism of nitration, halogenation. sulphonation. and Friedel-Crafts reaction.

Energy profile diagrams. Activating and deactivating substituents. orientation and ortho/para

ratio. alkynylbenzenes and biphenyl. Nomemclature and classification of dienes: isolated conjugated and cumulated dienes.Structure of allenes and butadiene, methods of formation, polymerization. Chemical reactions-1, 2 and 1, 4 additions, Diels Alder reaction..


27

MATHS - II CALCULUS

UNIT-I Є-δ Definition of the limit of a function. Basic properties of the limits. Continious function & classification of discontinuous. Differentiability. Successive differentiation. Libnitz theorem. Maclaurin & Taylor Series expansions.

UNIT-II Asymptotes curvature. Tests for concavity points of inflexion. Multiple points. Tracring of curves in Cartesian and polar coordinates.

UNIT-III Algebraic functions and transcendental functions. Reduction formulas. Definite integrals. Quadratic rectification. Volume and surface of solids of revolution.

UNIT-IV Degree and order of a differential equation. Equation of first order and first degree. Equations inwich the variables are separable. Homogenous equations.Linear equations and equations reducible to the linear form. Exact differential equations First order higher degree equations solvable for x, y, p. Linear differential equations with constant coefficients. Homogenous linear ordinary differential equations.

UNIT-V Linear differential equations of second order. Transformation of the equation by changing the dependent variable. Method of variation of parameters.Ordinary simultaneous differential equations.

MATHS -III VECTOR ANALYSIS AND GEOMETRY

UNIT-1 Scalar and vector product of three vectors.Product of four vectors. Reciprocal vectors. Vector differentiation. Gradient, divergence and curl.

UNIT-2 Vector integration. Theorem of Gauss, Stokes and problems based on these.

UNIT-3 General equation of second degree. Tracing of conics. System of conics. Confocal conics. Polar equation of a conic.

UNIT-4 Plane. The Straight line and the plane. Sphere. Cone. Cylinder.

UNIT-5 Central conicoids. Paraboloids.Plane Sectioon of Conicoids. Generating lines. Confocal Conicoids. Reduction of Second degree equation.

PHYSICS - II UNIT:- I Ideal Gas: Kinetic model, deduction of Boyle’s law, interpretation of temperature, estimation of r.m.s. speeds of molecules. Brownian motion, estimate of the Avogadro number, equipartition of energy, specific heat of monoatomic gas, extension to diatomic- and triatomic gases, Behavior at low temperatures, applications to atmospheric physics.

UNIT:- II Real Gas: Vander Waals gas, equation of state, nature of Vander Waals forces, comparison with experimental P-V curves, the critical constants, gas and vapour. Joule expansion of ideal gas and of a Vander Waals gas, Joule coefficient, estimation of J-T cooling.

UNIT:- III


28

Liquefaction of gases: Boyle temperature and inversion temperature, principle of regenerative cooling and of cascade cooling, liquefaction of hydrogen and helium. refrigeration cycles, meaning of efficiency.

UNIT:- IV Transport phenomena in gases: Molecular collisions, mean free path and collision cross sections. Estimates of molecular diameter and mean free path. Transport of mass, momentum and energy and interrelationship, dependence on temperature and pressure.

UNIT-:- V Thermodynamics:- The Zeroth law, first law of thermodynamics, reversible and irreversible changes, Carnot cycle and its efficiency, Carnot theorem and the second law of thermodynamics. Entropy, third law of thermodynamics. Thermodynamics relationships: Thermodynamic variables; Maxwell’s general relationships, application to Joule-Thomson cooling, Stefan-Boltzmann law. Special distribution of BB rediation, Wien’s displacement law, Rayleigh-Jean’s law, Planck’s quantum postulates,

PRACTICAL (PHYSICS SYLLABUS) PRACTICAL - SEMESTER II

EXPERIMENT LIST:- 1. Bar Pendulum.

2. Keter’s Pendulum.

3. Flywheel.

4. Bending of beam.

5. Surface tension (Capillary ries Mathod).

6. Study of Brownian motion.

7. Thermal conductivity of a bad conductor in the form of a disc by the Lees and Chorlton method.

8. Thermal conductivity of a good conductor by Searle’s method.

9. Sonometer.

10. Characteristics of a microphone.


29

COUNSELING AND STUDY STRUCTURE Sl. No.

Course Code

Title of the Course

Credit

Total Hours of Study

Counselling and Study Structure (hours) Project Face to

Face Counselling

Self study

Practical

Assignments

Semester I 1 1BSC1 Hindi

Language 2 60 8 34 - 18 -

2 1BSC2 English Language

2 60 8 34 - 18 -

3 1BSC3 Environmental Studies

3 90 12 51 - 27 -

4 1BSC4 Physical Chemistry

3 90 12

33 18 27 -

5 1BSC5 Maths –I Algebra And Trigonometry

3 90 12 51 - 27 -

6 1BSC6 Physics -I 3 90 12 51 - 27 - Semester II 7 2BSC1 Environmental

Studies(Project) 1 30 3 - - - 27

8 2BSC2 Organic Chemistry

3 90 12 51 - 27 -

9 2BSC3 Inorganic Chemistry

3 90 12 51 - 27 -

10 2BSC4 Maths–II Calculus

3 90 12 51 - 27 -

11 2BSC5 MATHS-III Vector Analysis And Geometry

3 90 12 51 - 27 -

12 2BSC6 Physics -II 3 90 12

33 18 27 -


Course Code


Semester-I 1BSC1 Hindi Language Òkjrh;rk ds Loj lk/ku /kuat; oekZ e/;Áns’k

vdkneh dEI;wVj v©j fgUnh, gfje¨gu, r{kf’kYkk Ádk’ku]

fnYYkhA 1BSC2 English Language English Language and Indian Culture -

Published by M.P. Hindi Granth Academy Bhopal

1BSC3 Environmental Studies A Textbook of Environmental Chemistry and Pollution Control by S.S. Dara (S. Chand and Company)

Environment and Ecology by Piyush Kant Pandey and Dipti Gupta (Sum India Publication)

1BSC4 Physical Chemistry Unified Chemistry Dr. M. M. N. Tandon, Shivlal Agrawal & Co.

Unified Practical Chemistry Dr. M. M. N. Tandon, Shivlal Agrawal & Co.

1BSC5 Maths –I Algebra And Trigonometry

Algebra, Trigonometry & Geometry, Dr. H.K. Pathak, Shikha Sahitya Prakashan

1BSC6 Physics –I Unified Physics, R.P. Goyal, Shivlal Agrawal & Co.

Semester-II


30

2BSC1 Environmental Studies(Project) A Textbook of Environmental Chemistry and Pollution Control by S.S. Dara (S. Chand and Company)

2BSC2 Organic Chemistry Unified Chemistry, Dr. M. M. N. Tandon Unified Practical Chemistry Dr. M. M. N. Tandon

2BSC3 Inorganic Chemistry Unified Chemistry, Dr. M. M. N. Tandon Unified Practical Chemistry Dr. M. M. N. Tandon

2BSC4 Maths–II Calculus

Calculus, Differential Equations & Vector Calculus, Dr. H.K. Pathak, Shikha Sahitya Prakashan

2BSC5 MATHS-III Vector Analysis And Geometry

Calculus, Differential Equations & Vector Calculus, Dr. H.K. Pathak, Shikha Sahitya Prakashan

2BSC6 Physics –II Unified Physics, R.P. Goyal, Shivlal Agrawal & Co.



Semester Assignment No. Due Date First Semester 1BSC1 1BSC2 1BSC3 1BSC4 1BSC5 1BSC6

• April 30 (for January Session ) • October 31 (for July session)

Second Semester 2BSC1 2BSC2 2BSC3 2BSC4 2BSC5 2BSC6

• October 31 (for July Session ) • April 30 (for January session)



MASTER OF SCIENCE (M. Sc.) – MATHS





32

MASTER OF SCIENCE (M.SC.) – MATHS (MODIFIED) Duration:24 Months Eligibility:Graduation with Maths Subject Scheme of Examination (FIRST YEAR)

Course Code



Assignments

Max Min Max Min Max MinFirst Semester

1MSC1 Advanced Abstract Algebra-I

3 120 100 40 - - 20 07

1MSC2 Real Analysis-I 3 120 100 40 - - 20 07 1MSC3 Topology-I 3 120 100 40 - - 20 07 1MSC4 Complex Analysis-I 3 120 100 40 - - 20 07 1MSC5 Differential Equations-I 4 120 100 40 - - 20 07 Total 600 500 50 - - 100

Second Semester 2MSC1 Advanced Abstract

Algebra-II 4 120 100 40 - - 20 07

2MSC2 Real Analysis-II 3 120 100 40 - - 20 072MSC3 Topology-II 3 120 100 40 - - 20 07 2MSC4 Complex Analysis-II 3 120 100 40 - - 20 07 2MSC5 Differential Equations-II 3 120 100 40 - - 20 07

Total 600 500 50 - 100



M. SC. PREVIOUS [MATHEMATICS]

DETAILED SYLLABUS SEMESTER-I

ADVANCED ABSTRACT ALGEBRA-I UNIT-I Groups, Subgroups Definition, Examples & elementary properties, Normal subgroup and quotient group, Group homomorphism, Isomorphism Theorems and the correspondence theorem.

UNIT-II Normal and subnormal series of group, composition series of group, Jordan- holder theorm.

UNIT-III Field & subfield definition & Examples, Extension fields, Algebraic extensions , Separable and Irseparable extensions Normal extension, Perfect fields

UNIT-IV Class equation of finite group, cauchy’s theorem for finite groups, Sylow Theorem, Wilson’s Theorem, Lagrange’s Theorem.

UNIT-V

Schroeder- bernstion theorem, hillebert basic theorem, wedderburn - artin theorem, nother - laskar theorem.


33

REAL ANALYSIS-I

UNIT-I Sequences & subsequences, Convergent sequence, divergent sequence and some theorems, Real Valued function & Theorems, Cesaros’s Theorem, Nested Interval theorem, Limit superior and Limit Inferior.

UNIT-II Series of Non-negative terms, comparison test, cauchy’s condensation test, comparison of ratios, Logarithmic test, D’morgan and bertrand’s test.

UNIT-III General Principal of convergence, pringsheims Method, Merten’s Theorem, Abel’s Theorem, Euler’s constant Theorem.

UNIT-IV Neighbourhoods, open set and closed set & properties, Bolzano-weierstranss Theorem, Baire category theorem for R, covering Theorem.

UNIT-V Limit and continuity Theorems on continuity, Bolzano’s theorem on continuity, continuity of inverse function, Geometrical meaning of a derivative, chain Rule of Derivative, Darboux Theorem and cauchy’s mean value Theorems.

TOPOLOGY-I

UNIT-I Definition and examples of topological space, Opensets, Closed sets , Closure , Dense subsets.

UNIT-II Neighborhoods , Interiors ,exteriors and boundry .Accumulation point and derived sets ,bases and sub-bases,subspaces and relative topology .

UNIT-III Continuous Maps, Continuous Maps into R, open and closed maps, Homeomorphism, Finite product spaces, projection maps.

UNIT-IV Connected space and disconnected spaces, separated sets, component, locally connected space, Path connectedness, separation axioms : T0, T1 and T2 Spaces.

UNIT-V Introduction of compactness, compact subspace, Finite intersection property, Bolzano-weierstrass property, countable, sequential and local compactness.

COMPLEX ANALYSIS-I

UNIT-I Complex Number, Analytic Functions, Cauchy – Riemann Equations, Harmonic Functions, Conjugate functions.

UNIT-II Conformal mappings, Bi-linear transformations, Geometrical interpretations of the transformations ω = z+α, ω = βz, ω = γz. Bi-linear transformation of a circle.

UNIT-III Complex integration, complex integrals as sum of two real line integrals, Cauchy’s Theorem, Extension of cauchy’s Theorem to multi – connected region Cauchy.

UNIT-IV Cauchy integral formula, Extension of cauchy’s integral formula to multiconnected regions, Liouville’s Theorem, Morea’s theorem.


34

UNIT-V Taylor’s Theorem, Laurent’s Theorem with examples.

ADVANCED DIFFERENTIAL EQUATIONS-I

UNIT-I Total Differential Equation, Necessary and sufficient condition for integrability of single differential equation Pdx + Qdy + Rdz = 0, Method for Solving Pdx + Qdy + Rdz = 0.

UNIT-II Integration in series, General method of solving a differential equation in different cases.

UNIT-III Partial Differential Equations of the first order, Derivation of partial differential equation, Lagrange’s Linear Equation and its solutions.

UNIT-IV Partial differential Equations with constant coefficients, Particular Integrals.

UNIT-V Partial Differential equations of the second order, Monge’s Methods.

SEMESTER-II

ADVANCED ABSTRACT ALGEBRA-II UNIT-I

Defination of Ring and Subring, Factor Ring with Examples, Homomorphism of ring, IsomorphismTheorem, polynomial Ring R[x] over a Ring R in an indeterminate X, Primitive polynomial.

UNIT-II Definition of integral domain, principal of ideal domain, Euclidean domain, the ring of Gaussian integers as an Euclidean domain, fermat’s Theorem, Unique Factorization domain.

UNIT-III Definition and examples of vector spaces, subspaces, sum and direct sum of subspaces, Linear span, Linear independence and their basic properties, Finite dimensional vector space, Dimension of sum of subspaces.

UNIT-IV Eigen values and eigen vectors of a linear transformation, Diagonalization,

UNIT-V Finite generate modules, Fundamental structure theorem for finitely generated moduls over aprincipal ideal domain its application of finitely generated abelian group.

REAL ANALYSIS-II

UNIT-I Defination of Riemann-Stieltses Integral & theorems, The Rs-Integral as limit of sums, Some classes of Rs-Integrable function, Algebra of Rs-Integrable function, The Interval of integration, The Rs-Integrability of composite function.

UNIT-II Relation between R- Integral & Rs-Integral, Integration of vector valued function, some more Theorems on integration.

UNIT-III


35

Continuity of function of two variables, Partial Derivatives, Differentiability of two variables, Differentiability of composite function.

UNIT-IV Differentiation, Differentiation of vector-valued function, Differentiation in Rn, The implicit function Theorem.

UNIT-V Definition of Jacobians’, Case of function of function, Jacobian of implicit functions, Necessary and Sufficient condition for a Jacobian to Vanish Identically.

TOPOLOGY-II

UNIT-I Separation Axioms: Regular and T3 spaces, normal and T4 spaces, Urysohn’s Lemma, Tietze’s, Extension theorem, completely regular and Tychonoff spaces, completely normal and T5 spaces.

UNIT-II Countablility Axioms: First and second axioms of countablility, Lindelof spaces , Separable spaces , Coutably compact spaces, Limit point compact spaces.

UNIT-III Convergence in Topology: Sequences and subsequences, convergence in topology, sequential compactness, local compactness, one point compactification, Stone-Cech compactification.

UNIT-IV Metric Spaces and Metrizability: Separation and countability axioms in metric spaces, convergence in metric spaces, complete metric spaces.

UNIT-V Product Spaces: Arbitrary product spaces, product invariance of certain separation and countability axioms, Tychonoff’s Theorem, product invariance of connectedness.

COMPLEX ANALYSIS-II UNIT-I Residues, Cauchy’s residue theorem, Evaluation of real definite integrals by contour integration, Integration round the unit circle.

UNIT-II Fundamental theorem of integral calculus for complex functions, uniqueness theorem, The zero of an analytic function, Singularities of an analytic function.

UNIT-III

Evaluation of the integral

( )f x d x∞

− ∞

. Evaluation of the integrals of the form

( )( )

P xdx

Q x

∞

−∞

, ( )( ) cos

P xmxdx

Q x

∞

−∞

, m>0, where P(x),Q(x) are polynomials,deg Q(x) > deg P(x) Q(x)=0 has no real roots.

UNIT-IV Fixed points or Invariant points of a Bilinear transformation, Normal form of a Bilinear transformation, Elliptic, Hyperbolic and parabolic transformations, some special Bilinear transformations.

UNIT-V Analytic, Holomorphic and Regular function, Polar form of Cauchy-Riemann Equations, Derivative of w = f(z) in polar form, orthogonal System, Multiple Valued function.


36

ADVANCE DIFFERENTIAL EQUATIONS-II UNIT - I Classification of Linear Partial Differential equation of second order, Homogenous Linear equation, Singular solution, Equation of Particular forms.

UNIT - II Definition Of Exact Differential Equation, Condition of Exactness of a linear equation of order n, Integrating Factor, Non-linear equation and Equation of the form

( ) ( )2 2

2 1, , , , 0n n n

n n n

d y d y d y d yf x f y xdx dx dx dx

−

−= = =.

UNIT – III Numerical Integration, Simpson’s Rule, Numerical approximation, Legendre Polynomial, Solution of Legendre Polynomial, General Solution of Legendre Equation, Laplace integral for Pn(x), Recurrence formula.

UNIT - IV Christofis Summation formula, Rodrigues Formula, Even and odd Functions, Trigonometrically series for Pn(x), Legendre function of the second kind Qn(x).

UNIT - V Definitions of Bessel’s function and solution’s, Recurrence formula of Bessel’s equation, Harmit Differential equation and solution, Generating function of Harmit’s polynomials, Recurrence formula of Harmit Polynomial, Laguerre polynomials.


Course Code

Title of the Course

Credit

Total Hours of Study

Counselling and Study Structure (hours) Project Face to

Face Counselling

Self study

Practical

Assignments

Semester I 1 1MSC1 Advanced

Abstract Algebra-I

3 90 12 51 - 27 -

2 1MSC2 Real Analysis-I 3 90 12 51 - 27 - 3 1MSC3 Topology-I 3 90 12 51 - 27 - 4 1MSC4 Complex

Analysis-I 3 90 12 51 - 27 -

5 1MSC5 Differential Equations-I

4 120 16 68 - 36 -

Semester II 6 2MSC1 Advanced

Abstract Algebra-II

4 120 16 68 - 36 -

7 2MSC2 Real Analysis-II 3 90 12 51 - 27 - 8 2MSC3 Topology-II 3 90 12 51 - 27 - 9 2MSC4 Complex

Analysis-II 3 90 12 51 - 27 -

10 2MSC5 Differential Equations-II

3 90 12 51 - 27 -


37

STUDY MODULES AND BOOKS INFORMATION Course Code


Semester-I 1MSC1 Advanced Abstract Algebra-I • S. K. Jain, P. B. Bhattacharya and S. R.

Nagpaul, Basic Abstract Algebra, Cambridge University Press (1997)

1MSC2 Real Analysis-I • Real Analysis, J. N. Sharma and A. R. Vasishtha, Krishna Prakashan media (P) Ltd. Meerut Delhi.

• Real Analysis, H. K. Pathak, Shiksha Sahitya prakashan.

1MSC3 Topology-I • Topology by J.N. Sharma 1MSC4 Complex Analysis-I • Functions of a complex variable, By B. S. Tyagi,

Kedarnath, Ramnath, Delhi. • Complex Functions, J. N. Sharma, Krishna pub.

1MSC5 Differential Equations-I • Differential Equations, R. K. Gupta and J. N. Sharma, Krishna Prakashan, Meerut.

• Linear differential Equations, R. K. Gupta and D. C. Agrawal.

Semester-II 2MSC1 Advanced Abstract Algebra-II • S. K. Jain, P. B. Bhattacharya and S. R.

Nagpaul, Basic Abstract Algebra, Cambridge University Press (1997)

2MSC2 Real Analysis-II • Real Analysis, J. N. Sharma and A. R. Vasishtha, Krishna Prakashan media (P) Ltd. Meerut Delhi.

• Real Analysis, H. K. Pathak, Shiksha Sahitya prakashan.

2MSC3 Topology-II • Topology by J.N. Sharma, 2MSC4 Complex Analysis-II • Functions of a complex variable, By B. S. Tyagi,

Kedarnath, Ramnath, Delhi. • Complex Functions, J. N. Sharma, Krishna pub.

2MSC5 Differential Equations-II • Differential Equations, R. K. Gupta and J. N. Sharma, Krishna Prakashan, Meerut.

• Linear differential Equations, R. K. Gupta and D. C. Agrawal.



Semester Assignment No. Due Date First Semester 1MSC1 1MSC2 1MSC3 1MSC4 1MSC5 • April 30 (for January Session ) • October 31 (for July session)

Second Semester 2MSC1 2MSC2 2MSC3 2MSC4 2MSC5 • October 31 (for July Session ) • April 30 (for January session)


38



MASTER OF SCIENCE (M. Sc.) - PHYSICS





40

MASTER OF SCIENCE (M.SC.) – PHYSICS Duration:24 Months Eligibility:Graduation with Maths Subjects Scheme of Examination




Assignments

Max Min Max Min Max Min First Semester

PHY 101 Mathematical Physics 4 100 80 25 - - 20 07 PHY 102 Classical Mechanics 3 100 80 25 - - 20 07 PHY 103 Quantum Mechanics I 3 100 80 25 - - 20 07 PHY 104 Electronic Devices 3 100 80 25 - - 20 07 PHY 105 Laboratory 3 200 - - 200 100 Total 600 320 200 80

Second Semester PHY 201 Quantum Mechanics II 4 100 80 25 - - 20 07 PHY 202 Statistical Mechanics 3 100 80 25 - - 20 07 PHY 203 Electrodynamics & Plasma

Physics 3 100 80 25 - - 20 07

PHY 204 Atomic & Molecular Physics

3 100 80 25 - - 20 07

PHY 205 Laboratory 3 200 - - 200 100 Total 600 320 200 - 80

Evaluation Scheme • Minimum passing marks in theory & assignment 32%. • Minimum passing marks in practical 50%. • Aggregate 40% in each theory paper and each semester.

SEMESTER–I

PHY 101- MATHEMATICAL PHYSICS UNIT I: VECTOR SPACE AND MATRICES: Linear independence; Bases; Dimensionality; Inner product; Linear transformation; Matrices; Inverse; Orthogonal and Unitary matrices; Independent element of a matrix; Eigenvalues and Eigenvectors; Diagonalization; Complete orthonormal sets of functions.

UNIT II: COMPLEX VARIABLE: Cauchy-Riemann condition; Analytic functions; Cauchy’s theorem; Cauchy integral formula; Laurent series; singularities; Residue theorem; Contour integration; Evaluation of definite integrals.

UNIT III: SPECIAL FUNCTIONS: Legendre; Bessel; Hermite and Laguerre functions with their physical applications; Generating functions; Orthogonality conditions; Recursion relations.

UNIT IV: INTEGRAL TRANSFORMS: Fourier and integral transforms; Inversion theorem; Fourier transform of derivatives; Convolution theorem; Laplace Transform (LT); LT of Derivatives; Inverse LT; Fourier series; properties and applications; Discrete Fourier transform.

PHY 102 - CLASSICAL MECHANICS UNIT I: Preliminaries; Newtonian mechanics of one and many particles systems; Conservation law; Constraints & their classification; Principle of virtual work; generalized coordinates; D Alembert’s principle and Lagrange’s equations; velocity-dependent potentials and the dissipation function; simple applications of the Lagrangian formulation. Hamilton’s


41

principle; Lagrange’s equations from Hamilton’s principle; Conservation theorems and symmetry properties; Energy function and the Conservation of energy.

UNIT II: The Hamiltonian formulation of mechanics; Langrange’s equation and the Hamilton’s equations of motion; Cyclic coordinates and Conservation theorems; Hamilton’s equations from Hamilton’s principle; the principle of least action. Canonical transformations with examples; the Harmonic oscillator; Poisson’s brackets; Equation of motion and conservation theorems in the Poisson Brackets formulation.

UNIT III: Hamilton-Jacobi (HJ) theory and action- angle variables; the HJ equation for Hamilton’s principle function; Harmonic oscillator as a example of the HJ method; the HJ equation for Hamilton’s characteristic function; seperation of variables in the HJ equation and the action- angle variables.

UNIT IV: The Central force problem; Two- body problem and its reduction to the equivalent one-body problem; the equations of motion and first integrals; the equivalent one- dimensional problem and classification of orbits; the differential equation of the orbit; closure and stability of orbits; the Kepler problem; Scattering in a central force field; Rutherford scattering; transformation of the scattering problem to laboratory coordinates.

PHY 103 - QUANTUM MECHANICS UNIT I: Inadequacy of Classical mechanics; Schrodinger equation; Continuity equation; Ehrenfest theorem; Stationary States; One-dimensional problems; Potential Step, Potential wells and Potential barrier; Schrodinger equation for Harmonic oscillator and its solution; Uncertainty relations of x and p; States with minimum uncertainty products.

UNIT II: Superposition principle; General formalism of wave mechanics; Commutation relations; Representation of states and dynamical variables; Completeness of eigen functions, Dirac- delta function; Bra & Ket notation; Matrix representation of an operator; Harmonic oscillator and its solution by matrix method.

UNIT III: Angular momentum in quantum mechanics; Commutation relationship; Eigan value; Spin angular momentum; Pauli’s matrices; Addition of angular momentum; Clebsch- Gordon coefficients.

UNIT IV: Time- independent perturbation theory; Non- degenerate case; first and second order perturbations with the example of an oscillator; degenerate case; Removal of degeneracy in second order; Zeeman effect without electron spin; First- order Stark effect in hydrogen; Perturbed energy levels; Occurrence of permanent electric dipole moments.

PHY 104 - ELECTRONIC DEVICES UNIT-I: ELECTRONIC COMPONENTS & SEMICONDUCTOR: Active and passive components, Introduction to electronic materials, Energy bands, Fermi level in intrinsic and extrinsic semiconductors, EHP theory, Resistivity and conductivity, P-N Junction, IV characteristics , Zener diode, SCR, ICs.

UNIT-II: TRANSISTORS: UJT, BJT, JFET, MOSFET and MESFET: Structure, working, derivation of the equation of the IV characteristics under different conditions.

UNIT-III: MICROWAVE AND PHOTONIC DEVICES: Tunnel diode, Transfer electron devices (Gunn Diode) Impact Diode, Radiative and Non-radiative transistors, Optical absorption, Bulk and Thin film, Photo conductive devices ( LDR), Solar Cell, LED.

UNIT-IV: MEMORY DEVICES & OTHER ELECTRONIC DEVICES:


42

Static and Dynamic Random Access Memory (SRAM & DRAM) CMOS & NMOS, Electro Optic , Magneto optic and acousto Optic effects, Properties of electro- optic and magneto-optic and acousto-optic material. Ferroelectric, Piezoelectric, Magnetostrictive, Electrostrictive effects. Important materials, exhibiting these properties and their application in Sensor, Relaxor and Actuators.

PHY 105 –LABORATORY COURSE (ANY TEN WILL BE ASKED IN EXAMINATION OF WHICH TWO IS TO BE PERFORMED)

1. Regulated power supply.

2. Common emitter transistor amplifiers (Voltage and Currents series / shunt).

3. A stable, Mono stable bi stable multivibrators.

4. Characteristics and application of SCR.

5. Measurement of Hall Coefficient of given semiconductor: identification of type of semiconductor and estimation of charge carrier concentration.

6. Solving Booleans expression.

7. Transistor Characteristics

8. Study of FET

9. Semiconductor device Kit (All in One)

10. Zener diode

SEMESTER-II PHY 201 - QUANTUM MECHANICS-II

UNIT I: Variational method, Expectation value of energy, application to excited states, ground sate of H-atom, Vander-Walls interaction, the W.K.B. approximation, approximate solutions, solution near turning point, connection formulae, energy levels of a potential well and quantization rule.

UNIT II: Theory of scattering, scattering cross section, differential and total scattering cross section, wave mechanical picture of scattering the scattering amplitude, Green’s functions and formal expression for scattering amplitude. The Born approximation and its validity, Partial wave analysis , asymptomatic behavior of partial waves and phase shifts, Optical theorem, scattering by square well potential, scattering by hard sphere, scattering by Coulomb potential.

UNIT III: Time- dependent perturbation theory, first order perturbation, Harmonic perturbation, Fermi’s Golden rule, Ionization of a H-atom, absorption and induced emission, Selection rules. Identical particles, symmetric and anti symmetric wave function.

UNIT IV: Relativistic quantum mechanics, formulation of relativistic quantum theory, Klein-Gordon equation; plane wave solutions, charge and current densities, The Dirac equation for a free particle, matrices alpha and beta, Lorentz covariance of the Dirac equation, free particle solutions and the energy spectrum, charge and current densities.

PHY 202 - STATISTICAL MECHANICS UNIT I: Foundation of statistical mechanics: Macroscopic and microscopic states, contact between statistics and thermodynamics, Classical gas, Entropy of mixing and Gibb’s paradox, Phase space, Liouville’s theorem and its consequences.


43

UNIT II: Theory of simple gases - Ideal gas in various quantum mechanical ensembles, Partition function, Maxwell-Boltzmann, Bose- Einstein, Fermi- Dirac distributions, Statistics of occupation number. Properties of ideal-Bose and Fermi gas, Bose Einstein condensation.

UNIT III: Thermodynamic behavior of an ideal Fermi gas, Non- relativistic and relativistic degenerate electron gas, theory of white dwarf stars. Landau theory of phase transition, critical indices, scale transformation and dimensional analysis.

UNIT IV: Cluster expansion for classical gas, Virial equation of state, Ising model and mean field theories of Ising model in three, two and one dimension. Exact solution in one dimension. Correlation of space-time dependent fluctuation, Fluctuations and transport phenomenon, Brownian motion, Einstein and Langevin’s theory of Brownian motion.

PHY 203 - ELECTRODYNAMICS AND PLASMA PHYSICS UNIT I: Gauge transformations, Lorenz gauge, Coulomb gauge, Green function for the wave equation, four-vectors, Mathematical properties of the space-time in special relativity, Matrix representation of Lorentz transformation, covariance of electrodynamics and transformation of electromagnetic fields.

UNIT II: Radiation by moving charge, Lienard-Wiechert potential and fields for a point charge, total power radiated by an accelerated charge. Larmor’s formula and its relativistic generalization, angular distribution of radiation emitted by an accelerated charge, radiation emitted by a charge in arbitrary extremely relativistic motion, distribution of energy radiated by accelerated charge in terms of frequency and angle.

UNIT III: Motion of charge particle in electromagnetic field, Uniform E and B Fields, Non-Uniform fields, Diffusion across magnetic fields, Time varying E and B Fields, Adiabatic invariance; First, Second and third adiabatic invariants.

UNIT IV: Plasma: definition and general properties, Plasma Parameters, Plasma diagnostics, Townsend theory of ionization Debye shielding phenomenon and criteria for plasma, Magneto-plasma, Plasma confinement, Plasma oscillation, Appleton-Hartee formula and propagation through ionosphere and magnetosphere.

PHY 204 - ATOMIC AND MOLECULAR PHYSICS UNIT I: Quantum states of one H-atoms, atomic orbital’s, Fine structure of hydrogen atom spectrum, Spectra of alkali elements, fine structure in alkali spectra, Pauli’s principle, Two electrons systems, interaction energy in L-S and J-J coupling, Hyperfine structure, line broadening mechanisms (general ideas).

UNIT II: Zeeman effect, Normal and anomalous Zeeman effect, Vector models of one electron system in a weak magnetic field, magnetic moment of a bound electron, magnetic interaction energy, selection rules, intensity rules, Paschen-Back (PB) effect. Stark effect Stark effect in hydrogen, orbital model, weak and strong effect in hydrogen.

UNIT III: Types of molecules-diatomic linear symmetric top, asymmetric top and spherical top molecules, Rotational spectra of diatomic molecule as a rigid rotor, Energy level and spectra of non rigid rotor, Intensity of rotational lines, Stark modulated microwave spectrometer (Qualitative).

UNIT IV:


44

Vibrational energy of diatomic molecule, Diatomic molecule as a simple harmonic oscillator, Energy levels and spectrum, Morse potential energy curve, Molecules as vibrating rotator, Vibration spectrum of diatomic molecule, PQR branches, IR spectrometer (Qualitative).

PHY 205 - LABORATORY – SEMESTER-II

(Any ten will be asked in examination of which two is to be performed)

Characterization and application of FET and MOSFET.

Study of Uni – Junction Transistor and its application.

Basic Logic Gates, TTL, NAND, and NOR.

Digital II: Combinational Logic.

Flip-Flops.

Operational Amplifier (741).

Differential Amplifier.

Resistivity of a semiconductor by four probe method at different temperature and determination of band gap.

Verification of DeMorgan’s theorem.

Study of Adder / Subtractor.

Measurement of Hall coefficient of semiconductor and identification of semiconductor estimation of charge carriers concentration.

Determination of Lande factor of DPPH by ESR.

To study of fluorescence spectrum of DCM dye and determination of quantum yield of fluorescence using monochromatic

Study of Faraday effect using He-Ne Laser

Op amp differentiator.


Course Code

Title of the Course


Counselling and Study Structure (hours)

Project

Face to Face Counselling

Self study


Semester I 1 PHY-

101 Mathematical Physics

4 120 16 68 - 36 -

2 PHY-102

Classical Mechanics

3 90 12 51 - 27 -

3 PHY-103.

Quantum Mechanics I

3 90 12 51 - 27 -

4 PHY-104

Electronic Devices

3 90 12 51 - 27 -

5 PHY-105

Laboratory 3 90 - - 90 - -

Semester II 6 PHY-

201 Quantum Mechanics II

4 120 16 68 - 36 -

7 PHY-202

Statistical Mechanics

3 90 12 51 - 27 -


45

8 PHY-203

Electrodynamics & Plasma Physics

3 90 12 51 - 27 -

9 PHY-204

Atomic & Molecular Physics

3 90 12 51 - 27 -

10 PHY-205

Laboratory 3 90 - - 90 - -


Course Code


Semester-I PHY-101 Mathematical Physics Mathematical Physics By B.S.Rajput,Meerut

Publication PHY-102 Classical Mechanics Classical Mechanics By Gupta & Kumar,

Meerut Publication PHY-103 Quantum Mechanics I Quantum Mechanics By Satya Prakash, Meerut

Publication PHY-104 Electronic Devices Electronic Devices By Gupta & Kumar, Meerut

Publication PHY-105 Laboratory

SEMESTER-IIPHY-201 Quantum Mechanics II Quantum Mechanics By Satya Prakash, Meerut

Publication PHY-202 Statistical Mechanics Statistical Mechanics By Satya Prakash, Meerut

Publication PHY-203 Electrodynamics & Plasma

Physics Electrodynamics & Plasma Physics By Gupta &

Kumar, Meerut Publication PHY-204 Atomic & Molecular Physics Atomic & Molecular Physics By Gupta & Kumar,

Meerut Publication PHY-205 Laboratory



Semester Assignment No. Due Date First Semester PHY-101 PHY-102 PHY-103 PHY-104 PHY-105 • April 30 (for January Session ) • October 31 (for July session)

Second Semester PHY-201 PHY-202 PHY-203 PHY-204 PHY-205 • October 31 (for July Session ) • April 30 (for January session)



MASTER OF SCIENCE (M. Sc.) - CHEMISTRY





47

MASTER OF SCIENCE (M.SC.) – CHEMISTRY Duration:24 Months Eligibility : Graduation with Science Subjects Scheme of Examination




Assignments

Max Min Max Min Max Min First Semester

1MSC1 Inorganic Chemistry.-I 4 200 80 25 100 50 20 07 1MSC2 Organic Chemistry.-I 4 100 80 25 - - 20 07 1MSC3 Physical Chemistry-I. 4 200 80 25 100 50 20 07 1MSC4 Analytical Chemistry-I. 4 100 80 25 - - 20 07 Total 600 320 200 80

Second Semester 2MSC1 Inorganic Chemistry - II. 4 100 80 25 - - 20 07 2MSC2 Organic Chemistry.-II 4 200 80 25 100 50 20 07 2MSC3 Physical Chemistry-II 4 100 80 25 - - 20 07 2MSC4 Analytical Chemistry-II 4 200 80 25 100 50 20 07 Total 600 320 100 200 80

Evaluation Scheme • Minimum passing marks in theory & assignment 33%. • Minimum passing marks in practical 50%. • Aggregate 40% in each theory paper and each semester.

DETAILED SYLLABUS SEMESTER–I

INORGANIC CHEMISTRY – I UNIT-I Wave mechanics

Origin of quantum theory, black body radiation, atomic spectra, photoelectric effect, uncertainty principle, matter waves, wave nature of the electron, the wave equation, the theory of hydrogen atom, particle in one dimensional box, transformation of coordinates, Separation of variables and their significance.

UNIT-II Stereo-chemistry and Bonding in main group compounds

VSEPR theory &drawbacks, Walsh diagram (tri and penta atomic molecules dπ-pπ bonds, Bent rule, and energetic of hybridization, some simple reactions of covalently bonded molecules.

Unit-III Chemistry of transition elements

General characteristic properties of transition elements, co-ordination chemistry Of transition metal ions, stereochemistry of coordination compounds, ligand field Theory, splitting of d orbital’s in low symmetry environments, John- Teller effect, Interpretation of electronic spectra including charge transfer spectra, Spectrochemical series, nephelauxetic series, metal clusters, sandwich compounds, metal carbonyls.

UNIT-IV Bioinorganic Chemistry

Role of metal ions in biological processes, structure and properties of


48

metalloproteinase in electron transport processes, cytochromes, ferrodoxins and iorn sulphur proteins, ion transport across membranes, Biological nitrogen fixation, PS-I, PS – II, Oxygen uptake proteins.

UNIT-V Symmetry and group theory in chemistry

Symmetry elements and symmetry operations, definition of group and and sub group, relation between order of finite group and its sub group. Congugacy relation and classes, point symmetry group, (representation for Cn, Cnv, Cnh, Dnh etc. Groups to be worked out explicitly). Character of representation.

ORGANIC CHEMISTRY-1 UNIT-I Reaction Mechanism: Structure and Reactivity

Types of reactions, potential energy diagrams, transition states and intermediates. Hard and soft acids and bases, strength of acids and bases. Generation, structure, stability and reactivity of carbocations and carbanions.

b) Aliphatic Nucleophilic substitutions: The SN2, SN1 reactions with respects to mechanism and stereochemistry. Reactivity effect of substrate structure, effect of attacking nucleophiles, leaving groups and reaction medium, Neighbouring Group Participation. Nucleophilic aromatic substitutionreactions SN1, SN2.

UNIT-II Aromatic Electrophilic Substitutions:

Introduction, Concept of Aromaticity, the arenium ion mechanism, orientation and reactivity in Nitration, Sulphonation, Friedel-Crafts and Halogenation in aromatic systems, energy profile diagrams. The ortho/para ratio, ipso attack, orientation in their ring systems. Diazo-coupling, Vilsmeir reaction, Gatterman- Koch rection, Von Richter rearrangement.

UNIT-III Addition to Carbon–Carbon Multiple Bonds

Mechanism and steriochemical aspects of the addition reactions involving electrophiles and free radicals, regio and chemo-selectivity, orientation and reactivity. Hydrogenation of double and triple bonds, hydrogenation of aromatic rings. Michael reaction.

UNIT-IV Elimination Reactions:

The E1, E2 and E1CB mechanisms. Orientation in Elimination reactions.

Reactivity: effects of substrate structures, attacking base the leaving group the nature of medium on elimination reactions. Pyrolytic elimination reactions.

UNIT-V Study of following reactions:

Beckman, Fries, Benzilic acid, Hoffman, Schmidt, Curtius, Lossen & Benzilic acid, Stereochemistry:

Concept of Chirality and molecular dissymmetry, Recognition of symmetry elements and chiral centers, Prochiral relationship, homotopic, enantiotopic and diasteriotopic groups and faces. Recemic modifications and their resolution, R and S nomenclature. Geometrical isomerism E and Z. Nomenclature. Conformational analysis : cyclohexane derivatives, stability and reactivity,

PHYSICAL CHEMISTRY UNIT-I THERMODYNAMICS-I


49

1. Introduction, revision of basic concepts.

2. Second law of thermodynamics: Physical significance of entropy (Direction of spontaneous change and dispersal of energy ), Carnot cycle, efficiency of heat engine, coefficient of performance of heat engine, refrigeration and problems.

3. Maxwell relations, thermodynamic equation of state, chemical potential, variation of chemical potential with temperature & pressure. Applications of chemical potential, phase rule, lowering of vapor pressure (Rault’s law) and elevation in boiling point.

UNIT-II THERMODYNAMICS-II

1. Ideal solutions, Rault’s law, Duhem-Margules equation and its applications to Vapour pressure curves( Binary liquid mixture ), determination of activity coefficients from vapour pressure measurements, Henry’s law.

2. Nonideal solutions : deviations from ideal behaviour of liquid mixtures, liquidvapor compositions, conditions for maximum.

UNIT-III KINETIC THEORY OF GASSES

1. Postulates of kinetic theory of gases, P-V-T relations for an ideal gas, non-ideal behavior of gases, equation of state, compressibility factor, virial equation, vander Waal’s equation, excluded volume and molecular diameter, relations of vander Waal’s constants with virial coefficients and Boyle temperature.

2. Molecular statistics, distribution of molecular states, deviations of Boltzmann law for molecular distribution, translational partition function, Maxwell- Boltzmann law for distribution of molecular velocities, physical significance of the distribution law, deviation of expressions for average, root mean square and most probable velocities, experimental verification of the distribution law.

3. Molecular collision in gases, mean free path, collision diameter and collision number in a gas and in a mixture of gases, kinetic theory of viscosity and diffusion.

UNIT-IV COLLOIDS AND MACROMOLECULES

1. Sols, Lyophilic and lyophobic sols, properties of sols, coagulation. Sols of surface active reagents, surface tension and surfactants, critical micelle concentration.

2. Macromolecules: Mechanism of polymerization, molecular weight of a polymer (Number and mass average ) viscosity average molecular weight, numerical problems. Degree of polymerization and molecular weight, methods of determining molecular weights( Osmometry, viscometry, light scattering, diffusion and ultracentrifugation) 05

3. Chemistry of polymerization: Free radical polymerization(Initiation, propagation and termination ), kinetics of free radical polymerization, step growth polymerization( Polycondensation ), kinetics of step polymerization, cationic and anionic polymerization.

( More stress should be given to solving numerical problems )

UNIT-V Phase rule

Distribution Law: Partition of iodine between water and carbon tetrachloride. Equilibrium constant of I-+ I2 = I3. Concentration of unknown potassium iodide. Partition of ammonia between water and chloroform. Partition of aniline between benzene and water. Hydrolysis constant of aniline hydrochloride. Association of benzoic acid in Naphthalene.

Solid-Liquid Equlibria: Construction of phase diagrams of simple eutectics, systems with congruent melting points and solid solutions. Determination of composition of unknown mixtures. Analytical and synthetic methods for the determination of solubilities


50

ANALYTICAL CHEMISTRY –I UNIT-I Errors and treatment of Analytical Chemistry

Errors, Determinant, constant and indeterminate. Accuracy and precision

Distribution of random errors. Average derivation and standard derivation, variance and confidance limit. Significance figures and computation rules. Least square method. Methods of sampling: samples size. Techniques of sampling of gases, fluid, solids, and particulates.

UNIT-II Chromatographic methods:

General principle, classification of chromatographic methods. Nature of partition forces. Chromatographic behavior of solutes. Column efficiency and resolution.

Gas Chromatography: detector, optimization of experimental conditions. Ion exchanges chromatography. Thin layer chromatography: coating of materials, prepative TLC. Solvents used and methods of detection Column chromatography. Adsorption and partition methods. Nature of column materials.Preparation of the column. Solvent systems and detection methods.

UNIT-III Electroanalytical Techniques

Polarography: Introduction, Instrumentation, Ilkovic equation and its verification.

Derivation of wave equation, Determination of half wave potential, qualitative and quantitative applications. Amperometry: Basic principals, instrumentation, nature of titration curves, and analytical applications.

UNIT-IV Theory of Volumetric and Gravimetric Analysis

Standard solutions Indicators, theory of indicators, types of titrations, Acid, base,

precipitation, Redox and complexometric titrations, Acid–base titrations in nonaqueous media, solvent characterisation, living effect, applications of non –aqueous titrations, MnO2

in pyrolusite, Na2CO3 + NaHCO3 and NaOH + Na2CO3 Mixture analysis, Gravimetric Analysis purity of the precipitate – coprecipitation’s and post precipitations from homogenous solution, organic precipitation

UNIT-V Computer Science:

Introduction: History etc. Hardware: Central processor unit. Input devices. Storage devices. Periferals, Software: Overview of the key elements of basic program structure, loops, arrays, mathematical function. User defined functions, conditional statements, string. Applications. Data representation, Computerized instruments system. Microcomputer interfacing.

PRACTICAL - INORGANIC CHEMISTRY

Qualitative analysis of mixture containing. Eight radical including some less common metal ions among the following by common method (preferably semi-micro method)

Basic radicals :- Ag, Pb, Hg, Cu, Cd, Bi, As, Sb, Sn, Fe, Al, Cr, Zn, Mn, Co, Ni, Ba, Sr, Ca, Mg, Na, K, NH4, Ce, Th, Zr, w, Te, Ti, Mo, O, V, Be, Li, Au, Pt, Acid Radicals: - Co3, SO4, SO3, NO3, F, Cl, Br, I, NO2, BO3, C2O4, PO4, SiO4, Thiosulphate, Ferroeynide, Ferricyanide, Chromate, Arsenite, Arsenate, Permanganate, Quantitative Analysis :-Involving two of the following in ores, alloys or mixture in solution – one by volumetric and other by gravimetric method Ag, Cu, Fe, Cr, Mn, Ni, Zn, Ba, Ca, Mg, chloride, Sulphate.

Estimation of : Phosphoric acid in commercial orthophosphoric acid, Boric acid in borax, Ammonium lon in Ammonium salt, MnO2 in pyrolusite


51

Available chlorine in bleaching powder, H2O2 in commercial sample, Preparation of selected Inorganic compounds and study of their properties by various method including IR, Electronic Spectra, Mossbaur, ESR, Spectra magnetic susceptibility etc.

Vo(acac)2

Cis & Trans K [Cr (C2O4)2(H2O)2]. 2H2O

Na[cr(NH3)2(SCN)4]

Mn (acac)

K3[Fe(C2O4)3]

Prussian Blue Turnbulls Blue

[Co(NH3)6][Co(NO2)6]

Hg [Co (SCN)4]

[Ni (NH3)4] Cl2

Ni (DMG)2

[Cu(NH3)4]SO4

Mohr’s salt

Nickel ammonium Sulphate

PRACTICAL - PHYSICAL CHEMISTRY Asorption:-Verification of Freundlich’s Adsorption Isotherm, Chemical Kinetics:Determination of effect of –Change of temperature Change of concentrations of reactants and catalyst.

Ionic strength of the media on the velocity constant of hydrolysis of ester.

Determination of order of reaction for reaction between K2S2O8 and KI.

Electrochemistry

Conductometry

Determination of solubility of sparingly soluble salt (e.g., PbSO4, BaSO4) conductometrically.

Determination of the strength of strong and weak acids in a given mixture conductometrically.

Determination of dissociation constant of weak electrolyte by conductometer.

pH metry/Potentiometry

Determination of the strength of strong and weak acid in a given mixture using pH meter/potentiometer.

Determination of dissociation constant of weak acid by pH meter.

Determination of concentration of acid in given buffer solution by pH meter.

Polarimetry:-Determination of rate constant for hydrolysis/inversion of sugar using polarimeter

Solubility and partition coefficient

Effect of temperature on solubility of electrolyte.

Determination of partition coefficient of between carbon tetrachloride and water.

Find out atomic parachor of carbon and hydrogen.

Colorimety :-Verification of beer’s and lamberts law and find out the concentration of unknown solution


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SEMESTER – II INORGANIC CHEMISTRY – II

UNIT-I Chemistry of non – Transition elements

General discussion on the properties of the non – transition elements, special features of individual elements, synthesis, properties and structure of halides and oxides of the non – transition elements, Polymorphism in carbon, phosphorous and sulphur, Synthesis, properties and structure of boranes, carboranes, silicates, carbides, phosphazenes, sulphur – nitrogen compounds, peroxo compounds of boron, carbon, sulphur, structure and bonding in oxyacids of nitrogen, phosphorous, sulphur and halogens, interhalogens, pseudohalides.

UNIT-II Organometallic Chemistry of transition elements

Ligand hapticity, electron count for different types of organometallic compounds, 18 and 16 electron rule, synthesis, structure and bonding, organometallic reagents in organic synthesis and in homogeneous catalytic reactions (Hydrogenation, hydroformylation, isomerisation and polymerisation), pimetal complexes, b) Metal – ligand equilibria in solution Stepwise and overall formation constants and their interaction, trends in stepwise constants, factors affecting the stability of metal complexes with reference to nature of metal ion and ligand, chelate effect.

UNIT-III Studies and applications of Lanthanides and Actinides

Spectral and magnetic properties, use of lanthanide compounds as shift reagents, Modern methods of separation of lanthanides and actinides, Organometallic chemistry applications of lanthanide and actinide compounds in Industries.

UNIT-IV Chemistry in Non- aqueous solvents

Classification of solvents, properties, leveling effect, type reactions in solvents, chemistry of liquid ammonia, liquid dinitrogen tetraoxide and anhydrous sulphuric acid with respect to properties, solubilities and reactions.

UNIT-V Nuclear and radiochemistry

Radioactive decay and equilibrium, nuclear reactions, Q value, cross-sections, types of reactions, chemical effects of nuclear transformation, fission and fusion, fission products and fission yield

ORGANIC CHEMISTRY-II UNIT-I Study of following reactions:

Mechanism of condensation reaction involving enolates Mannich, Benzoin, Stobbe, Dieckmann, Diels-Alder, Robinson annulation Reimer-Tieman, Chichibabin, Baeyer Villiger oxidation

UNIT-II a) Alkylation and Acylation

Introduction, Types of alkylation and alkylating agents: C-Alkylation and Acylation of active methylene compounds and Applications.

b). Hrdroboration and Enamines : Mechanism and Synthetic Applications.

UNIT-III a) Reductions


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Study of following reductions- Catalytic hydrogenation using homogeneous and heterogeneous catalysts. Study of following reactions: Wolff-Kishner, Birch,Clemmensen, Sodium borohydride, Lithium Aluminium hydride (LAH) and Sodium in alcohol, Fe in HCl.

b) Oxidation

Application of following oxidizing agents: KMnO4, chromium trioxide, Manganese dioxide, Osmium tetraoxide, DDQ, Chloranil.

UNIT-IV a) Study of Organometallic compounds

Organo-magnesium, Organo-zinc and Organo-lithium, Hg and Sn reagents; Use of lithium dialkyl cuprate their addition to carbonyl and unsaturated carbonyl compounds.

UNIT-V Methodologies in organic synthesis

ideas of synthones and retrones. Functional group transformations and interconversions of simple functionalities.

PHYSICAL CHEMISTRY – II UNIT-I PHOTOCHEMISTRY

Absorption of light and nature of electronic spectra, electronic transition, Frank-Condon principle, selection rules, photodissociation, predissociation, photochemical reactions: photoreduction, photooxidation, photodimerization, photochemical substitution, photoisomerization, photochemistry of environment: Green house effect.

UNIT-II Photo physical phenomena - I:

Electronic structure of molecules, molecular orbital, electronically excited singlet states, designation based on multiplicity rule, life time of electronically excited state, construction of Jablonski diagram, electronic transitions and intensity of absorption bands, photphysical pathways of excited molecular system( radiative and non-radiative ).

UNIT-III Photo physical phenomena - II

Fluorescence, delayed fluorescence, and phosphorescence, fluorescence quenching: concentration quenching, quenching by excimer and exciplex emission, fluorescence resonance enrgy transfer between photexcited donor and acceptor systems. Stern-Volmer relation, critical energy transfer distances, energy transfer efficiency, examples and analytical significance, bimolecular collisional V quenching and Stern-Volmer equation.

UNIT-IV. ELECTROCHEMISTRY

1. Arrhenius theory of electrolytic dissociation (Evidences and limitations), revision of basic electrochemistry( Types of electrodes and cells).

2. Electrochemical cells with and without transference, determination of activity coefficients of an electrolyte, degree of dissociation of monobasic weak acid (approximate and accurate ), instability constant of silver ammonia complex.

Acid and alkaline storage batteries.

UNIT-V CHEMICAL KINETICS

Experimental methods of following kinetics of a reaction, chemical and physical (measurement of pressure, volume, EMF, conductance, diffusion current and absorbance) methods and examples. Order and methods of determination( Initial rate, Integration, graphical and half life methods), rate determining step, steady state approximation and study of reaction between NO2 and F2, decomposition of ozone, and nitrogen pentoxide.


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2. Kinetics of complex reactions, Simultaneous (first order opposed by first order), Parallel and Consecutive reactions. Examples and numericals.

ANALYTICAL CHEMISTRY- II

UNIT-I a) Ultraviolet and visible spectrophotometry (UV-VIS)

Introduction, Beer Lambert’s law, instrumentation, calculation of absorption maxima of dienes, dienones and polyenes, applications.

b) Infrared Spectroscopy (IR)

Introduction, instrumentation, sampling technique, selection rules, types of bonds, absorption of common functional groups. Factors affecting frequencies, applications.

UNIT-II Nuclear Magnetic Resonance (NMR)

Magnetic and non magnetic nuclei, Larmor frequency, absorption of radio frequency. Instrumentation (FT-NMR). Sample preparation, chemical shift, anisotropic effect, spin spin coupling, coupling constant, applications to simple structural problems

UNIT-III Mass spectroscopy

Principle, working of mass spectrometer (double beam). Formation of different types of ions, Mclafferty rearrangements, fragmentation of alkanes, alkyl aromatics, alcohols and ketones, simple applications, simple structural problems based on IR, UV, NMR and MS

UNIT-IV Nephlometry and Turbidometry

a) Introduction, Theory, Instruments, working and Applications

b) Radiochemical Analysis, NAA: Scintillation counter and G.M. Counter (08)

UNIT-V a) Atomic Absorption Spectroscopy

Introduction, Principal, difference between AAS and FES, Advantages of AAS over FES, advantages and disadvantages of AAS. Instrumentation, Single and double beam AAS, detection limit and sensitivity, Interferences applications.

b) Inductively coupled Plasma Spectroscopy

Introduction, Nebulisation Torch, Plasmsa, Instrumentation, Interferences, Applications

PRACTICAL - ORGANIC CHEMISTRY • Qualitative Analysis :- Separation, Purification and identification of binary mixture (One

liquid and one solid) using TLC and column chromatography. Chemical text, IR spectra may be used for functional group identification.

• Organic Synthesis :- Acetylation : of Cholesterol and separation of Cholesterol acetate by Column Chromatography.

• Oxidation : Adipic acid by chromic acid, oxidation of cyclohexanol.

• Grignard’s reaction : Triphenyl methanol from Benzoic acid.

• Aldol condensation : Dibenzalacetone from Benzaldehyde

• Sandmeyer reaction : P-chloro Toluene from Toluidine.

• Friediel Craft’s reaction : P-Benzoyl propanoic acid from succinic anhydride and Benzene.


55

• Aromatic electrophilic substitution : P-nitro aniline from p-bromo aniline.

• Product may be Characterised by Spectral techniques.

• Quantitative analysis :- Determination of the percentage number of hydroxyl groups by acetylation method.

• Estimation of amine/phenols using Bromate Bromide method of Acetylation method.

• Estimation of Carbonyl group by hydrazone method.

• Estimation of Glycine by titration.

• Determination of equivalent weight of carboxylic compounds.Estimation of carboxyl group by titration/Silver salt method.

PRACTICAL - ANALYTICAL CHEMISTRY (INSTRUMENTATION AND COMPUTERS) Error analysis & Statistical data analysis :- Error, types of errors, minimization of errors, statistical treatment for error analysis standard deviation, Relative standard, Linear Least Squares.

Calibration of Volumetric apparatus, burettes, pipettes, standard flask, weight box etc.

Volumetric analysis :- Basic principles. Determination of iodine and saponification values of oil sample Determination of DO, COD, BOD, Hardness of water samples.

Gravimetric analysis :- Determination of metal ions eg. Ni, Cu etc. by gravimetric methods using organic precipitants such as dimethyglyoxime dithizone, 8-hydroxyguinoline, etc.

Chromatography :-Separation of cations and anions by-

Paper chromatography (b) Column Chromatography

pH metry / potentiometry : Determination of strength of acids etc.

Flame Photometry / AAS/ FIA/ Colorimetrty :-Determination of cations/anions and metal ions, e.g. Na+, K+, Ca2+, SO2-, NO2-, Fe, Mo, Ni, Cu, Zn, etc.

Spectrophotometry :-Verification of Beer-Lambert Law. Molar absorptivity calculation, plotting graph to obtain ��max etc. Effect of pH in aqueous coloured systems. Determination of metal ions, e.g. Fe, Cu, Zn, Pb, etc. using inorganic reagent like SCN and organic chelating agent like dithizone, cuferron 8-hydroxyquinoline, etc. in aqueous/organic phase in the presence of surface active agents.

Nephelometry / Turbidimetry :-Determination of chloride, sulphate, phosphate, turbidity, etc.

Application of computers in chemistry :-As specified in theory paper in Sect. II (a)


Course Code

Title of the Course


Counselling and Study Structure (hours)

Project

Face to Face Counselling

Self study


Semester I 1 1MSC1 Inorganic

Chemistry.-I 4 120 16 40 24 40 -

2 1MSC2 Organic Chemistry.-I

4 120 16 68 - 36 -

3 1MSC3 Physical Chemistry-I.

4 120 16

40 24 40 -

4 1MSC4 Analytical Chemistry-I.

4 120 16 68 - 36 -


56

Semester II 5 2MSC1 Inorganic

Chemistry - II. 4 120 16 68 - 36 -

6 2MSC2 Organic Chemistry.-II

4 120 16

40 24 40 -

7 2MSC3 Physical Chemistry-II

4 120 16 68 - 36 -

8 2MSC4 Analytical Chemistry-II

4 120 16 40 24 40 -


Course Code


Semester-I 1MSC1 Inorganic Chemistry.-I

• Advanced Inorganic Chemistry – Gurdeep Raj

Volume – I, Publisher Jewel. Advanced Inorganic Chemistry – Malic Madan – Tulic Publication – Schand & Company.

1MSC2 Organic Chemistry.-I • Reaction & Reagent – O. P. Agrawal – Krishna Publication, Advanced Organic Chemistry – Jerry Mars – Tata M. C. Graw Hill

1MSC3 Physical Chemistry-I. • Advanced Physical Chemistry – Gurdeep Raj – Jewel Publication, Advanced Physical Chemistry – J. P. Yadav – Pragti Publication

1MSC4 Analytical Chemistry-I. • Instrumental Method Of Analysis – Chatwal & Anand – Himalya Publication, Spectroscopic Technique In Organic Chemistry – H. Kour – Pragti Publication

Semester-II 2MSC1 Inorganic Chemistry - II.

• Advanced Inorganic Chemistry – Gurdeep Raj

Volume – I, Publisher Jewel. Advanced Inorganic Chemistry – Malic Madan – Tulic Publication – Schand & Company.

2MSC2 Organic Chemistry.-II • Reaction & Reagent – O. P. Agrawal – Krishna Publication, Advanced Organic Chemistry – Jerry Mars – Tata M. C. Graw Hill

2MSC3 Physical Chemistry-II • Advanced Physical Chemistry – Gurdeep Raj – Jewel Publication, Advanced Physical Chemistry – J. P. Yadav – Pragti Publication

2MSC4 Analytical Chemistry-II • Instrumental Method Of Analysis – Chatwal & Anand – Himalya Publication, Spectroscopic Technique In Organic Chemistry – H. Kour – Pragti Publication



Semester Assignment No. Due Date First Semester 1MSC1 1MSC2 1MSC3 1MSC4 • April 30 (for January Session ) • October 31 (for July session)

Second Semester 2MSC1 • October 31 (for July Session )


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2MSC2 2MSC3 2MSC4 • April 30 (for January session)


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