dow corning(r) 3140 rtv coating4.1 description of first aid measures general advice : in the case of...

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

DOW CORNING(R) 3140 RTV COATING

Version 2.2

Revision Date: 09.04.2016

SDS Number: 1308184-00008

Date of last issue: 16.03.2016 Date of first issue: 10.02.2015

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SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name

: DOW CORNING(R) 3140 RTV COATING

Product code

: 000000000001015788

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the Sub-stance/Mixture

: Adhesive, binding agents, Electrical industry and electronics

1.3 Details of the supplier of the safety data sheet

Company

: Dow Corning Europe S.A. rue Jules Bordet - Parc Industriel - Zone C B-7180 Seneffe

Telephone

: English Tel: +49 611237507 Deutsch Tel: +49 611237500 Français Tel: +32 64511149 Italiano Tel: +32 64511170 Español Tel: +32 64511163

E-mail address of person responsible for the SDS

: [email protected]

1.4 Emergency telephone number

Dow Corning (Barry U.K. 24h) Tél: +44 1446732350 Dow Corning (Wiesbaden 24h) Tél: +49 61122158 Dow Corning (Seneffe 24h) Tel: +32 64 888240

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Not a hazardous substance or mixture.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Not a hazardous substance or mixture.

Additional Labelling:

EUH210 Safety data sheet available on request.

EUH208 Contains Methyltrimethoxysilane. May produce an allergic reaction.



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2.3 Other hazards

None known.

SECTION 3: Composition/information on ingredients

3.2 Mixtures

Chemical nature

: Silicone elastomer

Hazardous components

Chemical name CAS-No. EC-No. Registration number

Classification Concentration (% w/w)

Methyltrimethoxysilane 1185-55-3 214-685-0 01-2119517436-40

Flam. Liq. 2; H225 Skin Sens. 1B; H317

>= 1 - < 10

For explanation of abbreviations see section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice

: In the case of accident or if you feel unwell, seek medical ad-vice immediately. When symptoms persist or in all cases of doubt seek medical advice.

Protection of first-aiders

: First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists.

If inhaled

: If inhaled, remove to fresh air. Get medical attention.

In case of skin contact

: In case of contact, immediately flush skin with soap and plenty of water. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.

In case of eye contact

: Flush eyes with water as a precaution. Get medical attention if irritation develops and persists.

If swallowed

: If swallowed, DO NOT induce vomiting. Get medical attention. Rinse mouth thoroughly with water.

4.2 Most important symptoms and effects, both acute and delayed

Risks : May produce an allergic reaction.



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4.3 Indication of any immediate medical attention and special treatment needed

Treatment

: Treat symptomatically and supportively.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media

: Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical

Unsuitable extinguishing media

: None known.

5.2 Special hazards arising from the substance or mixture

Specific hazards during fire-fighting

: Exposure to combustion products may be a hazard to health.

Hazardous combustion prod-ucts

: Carbon oxides Silicon oxides Formaldehyde Nitrogen oxides (NOx)

5.3 Advice for firefighters

Special protective equipment for firefighters

: In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.

Specific extinguishing meth-ods

: Use extinguishing measures that are appropriate to local cir-cumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions

: Use personal protective equipment. Follow safe handling advice and personal protective equip-ment recommendations.

6.2 Environmental precautions

Environmental precautions

: Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water.



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Local authorities should be advised if significant spillages cannot be contained.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up

: Soak up with inert absorbent material. For large spills, provide dyking or other appropriate contain-ment to keep material from spreading. If dyked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absor-bent. Local or national regulations may apply to releases and dis-posal of this material, as well as those materials and items employed in the cleanup of releases. You will need to deter-mine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.

6.4 Reference to other sections

See sections: 7, 8, 11, 12 and 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Technical measures

: See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.

Local/Total ventilation

: Use only with adequate ventilation.

Advice on safe handling

: Avoid inhalation of vapour or mist. Do not swallow. Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Keep away from water. Protect from moisture. Take care to prevent spills, waste and minimize release to the environment.

Hygiene measures

: Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers

: Keep in properly labelled containers. Store in accordance with the particular national regulations.

Advice on common storage

: Do not store with the following product types: Strong oxidizing agents

7.3 Specific end use(s)



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Specific use(s)

: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may re-quire added precautions. For further information regarding the use of silicones / organic oils in consumer aerosol applications, please refer to the guidance document regarding the use of these type of materi-als in consumer aerosol applications that has been developed by the silicone industry (www.SEHSC.com) or contact the Dow Corning customer service group.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure Limits

Components CAS-No. Value type (Form of exposure)

Control parameters Basis

Methyltrimethox-ysilane

1185-55-3 TWA 7.5 ppm DCC OEL

Occupational exposure limits of decomposition products

Components CAS-No. Value type (Form of exposure)

Control parameters Basis

Methanol 67-56-1 TWA 200 ppm 260 mg/m3

2006/15/EC

Further information Indicative, Identifies the possibility of significant uptake through the skin

TWA 200 ppm 266 mg/m3

GB EH40

Further information Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity.

STEL 250 ppm 333 mg/m3

GB EH40

Further information Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity.

Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:

Substance name End Use Exposure routes Potential health ef-fects

Value

Methyltrimethoxysilane Workers Skin contact Acute systemic ef-fects

0.38 mg/kg bw/day

Workers Inhalation Acute systemic ef-fects

25.6 mg/m3

Workers Skin contact Long-term systemic effects

0.38 mg/kg bw/day

Workers Inhalation Long-term systemic effects

25.6 mg/m3

Consumers Skin contact Acute systemic ef-fects

0.3 mg/kg bw/day

Consumers Inhalation Acute systemic ef-fects

6.25 mg/m3

Consumers Ingestion Long-term systemic effects

0.26 mg/kg bw/day



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Consumers Skin contact Long-term systemic effects

0.3 mg/kg bw/day

Consumers Inhalation Long-term systemic effects

6.25 mg/m3

Consumers Ingestion Acute systemic ef-fects

0.26 mg/kg bw/day

Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:

Substance name Environmental Compartment Value

Methyltrimethoxysilane Fresh water >= 1.3 mg/l

Marine water >= 0.13 mg/l

Fresh water sediment >= 1.1 mg/kg

Marine sediment >= 0.11 mg/kg

Soil >= 0.17 mg/kg

Sewage treatment plant > 6.9 mg/l

8.2 Exposure controls

Engineering measures

Processing may form hazardous compounds (see section 10). Ensure adequate ventilation, especially in confined areas. Minimize workplace exposure concentrations.

Personal protective equipment

Eye protection : Wear the following personal protective equipment: Safety glasses

Hand protection Material : Chemical-resistant gloves

Remarks

: For prolonged or repeated contact use protective gloves.

Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous sub-stance and specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday.

Skin and body protection : Select appropriate protective clothing based on chemical re-sistance data and an assessment of the local exposure poten-tial. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).

Respiratory protection : Use respiratory protection unless adequate local exhaust ven-tilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines.

Filter type : Self-contained breathing apparatus



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SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance

: liquid

Colour

: white, translucent

Odour

: slight

Odour Threshold

: No data available

pH

: No data available

Melting point/freezing point

: No data available

Initial boiling point and boiling range

: > 65 °C

Flash point

: > 101.1 °C Method: closed cup

Evaporation rate

: No data available

Flammability (solid, gas)

: Not applicable

Upper explosion limit

: No data available

Lower explosion limit

: No data available

Vapour pressure

: No data available

Relative vapour density

: No data available

Relative density

: 1.05

Solubility(ies) Water solubility

: No data available

Partition coefficient: n-octanol/water

: No data available

Auto-ignition temperature

: No data available

Decomposition temperature

: No data available

Viscosity Viscosity, dynamic

: 300 Poise

Explosive properties

: Not explosive

Oxidizing properties

: The substance or mixture is not classified as oxidizing.



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9.2 Other information

Molecular weight

: No data available

SECTION 10: Stability and reactivity

10.1 Reactivity

Not classified as a reactivity hazard.

10.2 Chemical stability

Stable under normal conditions.

10.3 Possibility of hazardous reactions

Hazardous reactions

: Use at elevated temperatures may form highly hazardous compounds. Can react with strong oxidizing agents. When heated to temperatures above 180 °C (356 °F) in the presence of air, trace quantities of formaldehyde may be re-leased. Adequate ventilation is required. Hazardous decomposition products will be formed upon con-tact with water or humid air. Hazardous decomposition products will be formed at elevated temperatures.

10.4 Conditions to avoid

Conditions to avoid

: Exposure to moisture

10.5 Incompatible materials

Materials to avoid

: Oxidizing agents Water

10.6 Hazardous decomposition products

Contact with water or humid air

: Methanol

Thermal decomposition

: Formaldehyde

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Information on likely routes of exposure

: Inhalation Skin contact Ingestion Eye contact

Acute toxicity

Not classified based on available information.



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Product:

Acute oral toxicity

: Acute toxicity estimate: > 2,000 mg/kg Method: Calculation method

Acute inhalation toxicity

: Acute toxicity estimate: > 20 mg/l Exposure time: 4 h Test atmosphere: vapour Method: Calculation method

Acute dermal toxicity

: Acute toxicity estimate: > 2,000 mg/kg Method: Calculation method

Components:

Methyltrimethoxysilane:

Acute oral toxicity

: LD50 (Rat): 12.3 ml/kg Assessment: The substance or mixture has no acute oral tox-icity Remarks: Information taken from reference works and the literature.

Acute inhalation toxicity

: LC50 (Rat): > 42.1 mg/l Exposure time: 6 h Test atmosphere: vapour Assessment: The substance or mixture has no acute inhala-tion toxicity Remarks: Based on test data

Acute dermal toxicity

: LD50 (Rabbit): > 9,500 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Remarks: Based on test data

Skin corrosion/irritation


Components:


Species: Rabbit Result: No skin irritation Remarks: Based on test data

Serious eye damage/eye irritation


Components:


Species: Rabbit Result: No eye irritation Remarks: Based on test data



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Respiratory or skin sensitisation

Skin sensitisation


Respiratory sensitisation


Product:

Assessment: Does not cause skin sensitisation. Test Type: Buehler Test Species: Guinea pig Remarks: Based on data from similar materials

Components:


Assessment: Probability or evidence of low to moderate skin sensitisation rate in humans Test Type: Buehler Test Species: Guinea pig Remarks: Based on test data

Germ cell mutagenicity


Components:


Genotoxicity in vitro

: Test Type: Bacterial reverse mutation assay (AMES) Result: negative Remarks: Based on test data

: Test Type: Mutagenicity (in vitro mammalian cytogenetic test) Result: positive Remarks: Based on test data

: Test Type: Chromosome aberration test in vitro Result: positive Remarks: Based on test data

Genotoxicity in vivo

: Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Ingestion Result: negative Remarks: Based on test data

Germ cell mutagenicity- As-sessment

: Animal testing did not show any mutagenic effects.



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Carcinogenicity


Reproductive toxicity


Components:


Effects on fertility

: Test Type: Combined repeated dose toxicity study with the reproduction/developmental toxicity screening test Species: Rat, male and female Application Route: Ingestion Symptoms: No effects on fertility Remarks: Based on test data

Effects on foetal develop-ment

: Test Type: Combined repeated dose toxicity study with the reproduction/developmental toxicity screening test Species: Rat, male and female Application Route: Ingestion Symptoms: No effects on foetal development Remarks: Based on test data

Reproductive toxicity - As-sessment

: No evidence of adverse effects on sexual function and fertility, or on development, based on animal experiments.

STOT - single exposure


STOT - repeated exposure


Components:


Exposure routes: inhalation (vapour) Assessment: No significant health effects observed in animals at concentrations of 1 mg/l/6h/d or less. Exposure routes: Ingestion Assessment: No significant health effects observed in animals at concentrations of 100 mg/kg bw or less.

Repeated dose toxicity

Components:


Species: Rat Application Route: inhalation (vapour) Remarks: Based on test data Species: Rat Application Route: Ingestion



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Remarks: Based on test data

Aspiration toxicity


Product:

No aspiration toxicity classification

SECTION 12: Ecological information

12.1 Toxicity

Components:


Toxicity to fish

: LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203

Toxicity to daphnia and other aquatic invertebrates

: EC50 (Daphnia sp.): > 100 mg/l Exposure time: 48 h Method: OECD Test Guideline 202

Toxicity to algae

: ErC50 (Pseudokirchneriella subcapitata (green algae)): > 3.6 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: No toxicity at the limit of solubility

EC10 (Pseudokirchneriella subcapitata (green algae)): > 3.6 mg/l Exposure time: 72 h Method: OECD Test Guideline 201 Remarks: No toxicity at the limit of solubility

Toxicity to bacteria

: EC50 : > 100 mg/l Method: OECD Test Guideline 209

12.2 Persistence and degradability

Components:


Stability in water

: Degradation half life: 2.2 h pH: 7

12.3 Bioaccumulative potential

Components:


Partition coefficient: n-octanol/water

: log Pow: -2.36



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12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

Not relevant

12.6 Other adverse effects

No data available

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product : Dispose of in accordance with local regulations. According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities.

Contaminated packaging : Empty containers should be taken to an approved waste han-dling site for recycling or disposal. If not otherwise specified: Dispose of as unused product.

SECTION 14: Transport information

14.1 UN number

Not regulated as a dangerous good

14.2 UN proper shipping name


14.3 Transport hazard class(es)


14.4 Packing group


14.5 Environmental hazards


14.6 Special precautions for user

Not applicable

14.7 Transport in bulk according to Annex II of Marpol and the IBC Code

Remarks : Not applicable for product as supplied.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mix-ture

Regulation (EC) No 649/2012 of the European Parlia-ment and the Council concerning the export and import

: Not applicable



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of dangerous chemicals REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59).

: Not applicable

Regulation (EC) No 1005/2009 on substances that de-plete the ozone layer

: Not applicable

Regulation (EC) No 850/2004 on persistent organic pol-lutants

: Not applicable

Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. Not applicable

The components of this product are reported in the following inventories:

NZIoC

: All ingredients listed or exempt.

TSCA

: All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances.

AICS


IECSC


ENCS/ISHL

: All components are listed on ENCS/ISHL or exempted from inventory listing.

KECI

: All ingredients listed, exempt or notified.

PICCS


DSL

: All chemical substances in this product comply with the CEPA 1999 and NSNR and are on or exempt from listing on the Ca-nadian Domestic Substances List (DSL).

REACH

: For purchases from Dow Corning EU legal entities, all ingredi-ents are currently pre/registered or exempt under REACH. For purchases from non-EU Dow Corning legal entities with the intention to export into EEA please contact your DC repre-sentative/local office.

TCSI


15.2 Chemical safety assessment

A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

Full text of H-Statements

H225 : Highly flammable liquid and vapour.



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H317 : May cause an allergic skin reaction.

Full text of other abbreviations

Flam. Liq. : Flammable liquids Skin Sens. : Skin sensitisation 2006/15/EC : Europe. Indicative occupational exposure limit values DCC OEL : Dow Corning Guide GB EH40 : UK. EH40 WEL - Workplace Exposure Limits 2006/15/EC / TWA : Limit Value - eight hours DCC OEL / TWA : Time weighted average GB EH40 / TWA : Long-term exposure limit (8-hour TWA reference period) GB EH40 / STEL : Short-term exposure limit (15-minute reference period)

ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways; ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regula-tion; Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Cana-da); ECHA - European Chemicals Agency; EC-Number - European Community number; ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - In-ternational Air Transport Association; IBC - International Code for the Construction and Equip-ment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentra-tion; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Mari-time Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisa-tion for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-es; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evalua-tion, Authorisation and Restriction of Chemicals; RID - Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TRGS - Technical Rule for Hazardous Substances; TSCA - Toxic Substances Control Act (United States); UN - United Nations; vPvB - Very Persistent and Very Bioaccumulative

Further information

Sources of key data used to compile the Safety Data Sheet

: Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen-cy, http://echa.europa.eu/

Items where changes have been made to the previous version are highlighted in the body of this doc-ument by two vertical lines.



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The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information is designed only as a guidance for safe han-dling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific mate-rial identified at the top of this SDS and may not be valid when the SDS material is used in combina-tion with any other materials or in any process, unless specified in the text. Material users should re-view the information and recommendations in the specific context of their intended manner of han-dling, use, processing and storage, including an assessment of the appropriateness of the SDS mate-rial in the user’s end product, if applicable.

GB / EN

dow corning(r) 3140 rtv coating4.1 description of first aid measures general advice : in the case of...

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