Transcript
Page 1: One Source Many Solutions One Purpose · One Source Many Solutions One Purpose Circulating Dry Scrubbers for PM 2.5 Compliance Terence Ake ... • Proposed Area and Major Source Industrial

© 2011 Babcock Power Inc. All rights reserved. www.babcockpower.com 1

Presentation for the:

McIlvaine Company Hot Topic Hour on

Compliance Strategies for PM2.5

Thursday, May 12, 2011

One Source Many Solutions One Purpose

Circulating Dry Scrubbers for PM2.5 Compliance

Terence Ake

Turbosorp® CDS Product Manager

Page 2: One Source Many Solutions One Purpose · One Source Many Solutions One Purpose Circulating Dry Scrubbers for PM 2.5 Compliance Terence Ake ... • Proposed Area and Major Source Industrial

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Circulating Dry Scrubbers for PM2.5 Compliance

A. EPA Regulations

B. Particulate Measurement Methods

C. Circulating Dry Scrubbers

Outline

Page 3: One Source Many Solutions One Purpose · One Source Many Solutions One Purpose Circulating Dry Scrubbers for PM 2.5 Compliance Terence Ake ... • Proposed Area and Major Source Industrial

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• National Ambient Air Quality Standards

(NAAQS)

• New Source Performance Standards

(NSPS)

• Proposed Utility Maximum Achievable

Control Technology (MACT)

• Proposed Area and Major Source Industrial

Boiler MACT

EPA Regulations

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EXAMPLE

Coal-Fired Units (Except Lignite)

0.00

0.05

0.10

0.15

0.20

Total PM Non-Hg Metal HCl SO2 Hg

Em

iss

ion

(lb

/10

6 B

tu)

Existing

New

Proposed Utility MACT Limits

Total PM = Filterable (PM2.5) + Condensibles

CEMS

required

if not

testing

for HAP CEMS

required

if no

scrubber

SO2

may be

surrogate

for HCl

with

scrubber

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EXAMPLE

Coal Fired Units (Coals Except Lignite)0.000000001

0.00000001

0.0000001

0.000001

0.00001

0.0001

0.001

0.01

0.1

Total PM

Non-Hg

Metal HCl SO2 Hg

Em

iss

ion

(lb

/10

6 B

tu)

Existing

New

Proposed Utility MACT Limits

Reverse Logarithmic Scale

(Bigger Bar Means Much Smaller Limit)

Measure

every 2

months if

no PM

CEMS

Hg or

sorbent

trap

CEMS

required

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• 30-day Rolling Averages of Continuous Monitor

Readings Compared to Limits

• Limits are All Pollutants for All-Times

No Provisions for Startup Shutdown or Malfunction

• Total PM =

Filterable (PM2.5) +Condensibles (SO3, NH4Cl, etc.)

• Measurement programs mandated within 30 days of

compliance date

• Operating practices must be defined and established

Proposed Utility MACT Limits

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A. EPA Regulations

• National Ambient Air Quality Standards (NAAQS)

• New Source Performance Standards (NSPS)

• Proposed Utility Maximum Achievable Control Technology

(MACT)

• Proposed Area and Major Source Industrial Boiler MACT

B. Particulate Measurement Methods

C. Circulating Dry Scrubbers

Page 8: One Source Many Solutions One Purpose · One Source Many Solutions One Purpose Circulating Dry Scrubbers for PM 2.5 Compliance Terence Ake ... • Proposed Area and Major Source Industrial

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Particulate Matter Measurement Methods

Method 5

Method

202

• Method 5 for PM2.5

• Method 17 for Total PM

• Method 202 for Condensibles

EPA issued New Method 202 in Dec-10

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A. EPA Regulations

• National Ambient Air Quality Standards (NAAQS)

• New Source Performance Standards (NSPS)

• Proposed Utility Maximum Achievable Control Technology

(MACT)

• Proposed Area and Major Source Industrial Boiler MACT

B. Particulate Matter Measurement Methods

C. Circulating Dry Scrubbers

• Process

• Chemistry

• Emissions

Page 10: One Source Many Solutions One Purpose · One Source Many Solutions One Purpose Circulating Dry Scrubbers for PM 2.5 Compliance Terence Ake ... • Proposed Area and Major Source Industrial

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Circulating Dry Scrubbers

Internal Solids

Recirculation

Enhances

Reactions

Turbosorp® CDSFlue Gas and Solids Path Diagram

High Solids

Recirculation

Turbulent

Reactor Mixing

No Slurry

Handling

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Chemistry

Circulating Dry Scrubbers

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CaSO ½ H O3 2

Ca(OH)2

CaSO ½ H O3 2

Ca(OH)2

CaSO ½ H O3 2

Ca(OH)2

Reaction after

first pass

Water added to

surface during

recirculation

Sulfite crystal

forms, exposing

fresh surfaces

Formation of reaction

products layer

Circulating Dry Scrubbers

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Coal-Fired Units

0.000

0.005

0.010

0.015

0.020

0.025

0.030

EPA Total Total PM Total PM PM PM

PM Limit Plant 1 Plant 2 Plant 3 Plant 4

Em

iss

ion

(lb

/10

6 B

tu)

Existing

New

Turbosorp® CDSPM Emission Data Compared to Utility MACT

Circulating Dry Scrubbers

Total Filter-

able

1 CMPT

OOS

All

CMPTS

Condensibles

Not Measured with

New Method 202

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Turbosorp® CDS Emissions Summary(Conclusion)

SO2 95 – 98 %

SO3 95 – 99 %

HCl 95 – 99 %

HF 95 – 99 %

Mercury 90 – 95 %

• Coals up to 6 lbs of SO2/106Btu

• SO2 down to 0.03 lb/106Btu

Circulating Dry Scrubbers

Reduces PM

Condensibles


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