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FORM-1

for

PROPOSED EXPANSION OF DYES & CHEMICALS

MANUFACTURING PLANT IN EXISTING PREMISES

of

M/s. PREET DYES & CHEMICALS (Unit-1)

Plot No. 3026, Phase-III, GIDC Industrial Estate,

Panoli-394 116, Tal: Ankleshwar,

Dist: Bharuch, Gujarat

Prepared by:

Aqua-Air Environmental Engineers Pvt. Ltd.

(Pollution Control Consultants & Engineers)

Reg. Office: 403, Centre Point, Nr. Kadiwala School, Ring Road, Surat – 395 002, Gujarat, India Fax: +91 261 2707273 / 3987273

Tel: + 91 261 3048586 / 2460854 / 2461241

E-mail: [email protected] Visit us at: www.aqua-air.co.in

APPENDIX I

(See paragraph - 6)

FORM 1

Sr.

No.

Item Details

1. Name of the project/s M/s. Preet Dyes and Chemicals (Unit-1) 2. S. No. in the schedule 5 (f)

3. Proposed capacity/area/length/tonnage to

be handled/command area/lease

area/number of wells to be drilled

For detail Please refer Annexure – I

4. New/Expansion/Modernization Expansion

5. Existing Capacity/Area etc. For detail Please refer Annexure – I

6. Category of Project i.e. ‘A’ or ‘B’ A

7. Does it attract the general condition? If yes,

please specify.

Yes. Located within 5 km of critically polluted

area (Ankleshwar).

8. Does it attract the specific condition? If yes,

please specify.

No

9. Location

Plot/Survey/Khasra No. Plot No. 3026

Village GIDC Industrial Estate, Panoli

Tehsil Ankleshwar

District Bharuch

State Gujarat

10. Nearest railway station/airport along with

distance in kms.

Railway Station: Ankleshwar (5 km)

Airport: Surat (60 km)

11. Nearest Town, city, District Headquarters

along with distance in kms.

Panoli Village (1.95 km)

Bharuch (15.5 km)

12. Village Panchayats, Zilla Parishad, Municipal

Corporation, local body (complete postal

address with telephone nos. to be given)

Panoli Village, Taluka: Ankleshwar, Dist: Bharuch

(Gujarat)

13. Name of the applicant M/s. Preet Dyes & Chemicals (Unit-1)

14. Registered Address Plot No. 3026, GIDC Industrial Estate, Panoli, Tal:

Ankleshwar, Dist: Bharuch

15. Address for correspondence:

Name Mr. Kalpesh Vekaria

Designation (Owner/Partner/CEO) Proprietor

Address Plot No. 3026, GIDC Industrial Estate, Panoli, Tal:

Ankleshwar, Dist: Bharuch

Pin Code 394116

E-mail [email protected]

Telephone No. --

Fax No. --

Mobile No. +919925017547

16. Details of Alternative Sites examined, if any. NA

Location of these sites should be shown on a

topo sheet.

17. Interlinked Projects NA

18. Whether separate application of interlinked

project has been submitted?

NA

19. If yes, date of submission NA

20. If no, reason NA

21. Whether the proposal involves

approval/clearance under: if yes, details of

the same and their status to be given.

(a) The Forest (Conservation) Act, 1980?

(b) The Wildlife (Protection) Act, 1972?

(c) The C.R.Z. Notification, 1991?

No

22. Whether there is any Government

Order/Policy relevant/relating to the site?

No

23. Forest land involved (hectares) NA

24. Whether there is any litigation pending

against the project and/or land in which the

project is propose to be set up?

(a) Name of the Court

(b) Case No.

(c) Orders/directions of the Court, if any and

its relevance with the proposed project.

NA

• Capacity corresponding to sectoral activity (such as production capacity for manufacturing,

mining lease area and production capacity for mineral production, area for mineral exploration,

length for linear transport infrastructure, generation capacity for power generation etc.,)

(II) Activity

1. Construction, operation or decommissioning of the Project involving actions, which will cause

physical changes in the locality (topography, land use, changes in water bodies, etc.)

Sr.

No.

Information/Checklist confirmation Yes/No Details there of with approximate

quantities frates, wherever possible)

with source of information data

1.1 Permanent or temporary change in land use,

land cover or topography including increase

intensity of land use (with respect to local

land use plan)

No Proposed expansion project activity is

within the Panoli GIDC Industrial

Estate.

1.2 Clearance of existing land, vegetation and

Buildings?

Yes Minor site clearance activities shall be

carried out to clear shrubs and weed.

1.3 Creation of new land uses?

No The project site is located on level

ground, which does not require any

major land filling for area grading

work.

1.4 Pre-construction investigations e.g. bore

Houses, soil testing?

No

1.5 Construction works?

Yes Please refer Annexure – II.

1.6 Demolition works? No There will be not any demolition work

at the site.

1.7 Temporary sites used for construction works

or housing of construction workers?

No

1.8 Above ground buildings, structures or

earthworks including linear structures, cut

and fill or excavations

Yes Please refer Annexure – II.

1.9 Underground works mining or tunneling?

No

1.10 Reclamation works?

No

1.11 Dredging?

No

1.12 Off shore structures?

No

1.13 Production and manufacturing processes?

Yes Please refer Annexure –III.

1.14 Facilities for storage of goods or materials?

Yes Proposed expansion is within the

existing premises. Existing goods or

material is stored in existing storage

facilities. For Proposed Expansion,

additional raw material & finished

products storage area will be

developed.

1.15 Facilities for treatment or disposal of solid

waste or liquid effluents?

Yes For Facilities for treatment or disposal

of liquid effluents is referred as

Annexure-V.

For Hazardous waste detail please

refer Annexure – VI.

1.16 Facilities for long term housing of operational

workers?

No

1.17 New road, rail or sea traffic during

Construction or operation?

No

1.18 New road, rail, air waterborne or other

transport infrastructure including new or

altered routes and stations, ports, airports

etc?

No

1.19 Closure or diversion of existing transport

routes or infrastructure leading to changes in

Traffic movements?

No

1.20 New or diverted transmission lines or

Pipelines?

No

1.21 Impoundment, damming, culverting,

realignment or other changes to the hydrology

of watercourses or aquifers?

No

1.22 Stream crossings? No

1.23 Abstraction or transfers of water form ground

or surface waters?

Yes Water requirement will be met

through Panoli GIDC water supply.

1.24 Changes in water bodies or the land surface

Affecting drainage or run-off?

No

1.25 Transport of personnel or materials for

construction, operation or

decommissioning?

Yes Transportation of personnel or raw

material and products will be primarily

by road only.

1.26 Long-term dismantling or decommissioning

or restoration works?

No

1.27 Ongoing activity during decommissioning

which could have an impact on the

environment?

No

1.28 Influx of people to an area either

temporarily or permanently?

No

1.29 Introduction of alien species? No

1.30 Loss of native species or genetic diversity? No

1.31 Any other actions? No

2. Use of Natural resources for construction or operation of the Project (such as land, water,

materials or energy, especially any resources which are non-renewable or in short supply):

Sr.

No.

Information/checklist confirmation Yes/No Details thereof (with approximate

quantities /rates, wherever possible) with

source of information data

2.1 Land especially undeveloped or agricultural

land (ha)

No Proposed expansion project activity will be

within GIDC Industrial Area, Panoli, Dist:

Bharuch.

2.2 Water (expected source & competing users)

unit: KLD

Yes Water Source: Panoli GIDC Water Supply

For details please refer Annexure – IV.

2.3 Minerals (MT) No

2.4 Construction material - stone, aggregates,

and / soil (expected source - MT)

Yes Small Quantity of construction material

will be required for expansion and

addition of few equipments. Construction

materials, like steel, cement, crushed

stones, sand, rubble, etc. required for the

project shall be procured from the local

market of the region.

2.5 Forests and timber (source - MT) No.

2.6 Energy including electricity and fuels (source,

competing users) Unit: fuel (MT), energy (MW)

Yes FUEL:

Wood = 45 MT/Month (Existing &

discontinued after proposed expansion)

Bio-Coal = 60 MT/Month (Total Proposed)

ENERGY:

27 HP (Existing)

162 HP (Total Proposed)

2.7 Any other natural resources (use appropriate

standard units)

No

3. Use, storage, transport, handling or production of substances or materials, which could be

harmful to human health or the environment or raise concerns about actual or perceived risks to

human health.

Sr.

No.

Information/Checklist confirmation Yes/No Details there of (with approximate

quantities/rates, wherever possible) with


3.1 Use of substances or materials, which are

hazardous (as per MSIHC rules) to human

health or the environment (flora, fauna, and

water supplies)

Yes Please refer Annexure –VIII.

3.2 Changes in occurrence of disease or affect

disease vectors (e.g. insect or water borne

diseases)

No

3.3 Affect the welfare of people e.g. by changing

living conditions?

No

3.4 Vulnerable groups of people who could be

affected by the project e.g. hospital patients,

children, the elderly etc.

No

3.5 Any other causes No

4. Production of solid wastes during construction or operation or decommissioning (MT/month)

Sr.

No.

Information/Checklist confirmation Yes/No Details there of (with approximate

quantities/rates, wherever possible)


4.1 Spoil, overburden or mine wastes No

4.2 Municipal waste (domestic and or commercial

wastes)

No

4.3 Hazardous wastes (as per Hazardous Waste

Management Rules)

Yes Please refer Annexure – VI.

4.4 Other industrial process wastes Yes Please refer Annexure – VI.

4.5 Surplus product No

4.6 Sewage sludge or other sludge from effluent

treatment

No

4.7 Construction or demolition wastes No

4.8 Redundant machinery or equipment No

4.9 Contaminated soils or other materials No

4.10 Agricultural wastes No

4.11 Other solid wastes Yes

Please refer Annexure – VI.

5. Release of pollutants or any hazardous, toxic or noxious substances to air (Kg/hr)

Sr. No. Information/Checklist confirmation Yes/No Details there of (with approximate



5.1 Emissions from combustion of fossil fuels

from stationary or mobile sources

Yes Please refer Annexure – VII.

5.2 Emissions from production processes Yes Please refer Annexure – VII.

5.3 Emissions from materials handling storage or

transport

No

5.4 Emissions from construction activities

including plant and equipment

No

5.5 Dust or odours from handling of materials

including construction materials, sewage and

waste

No

5.6 Emissions from incineration of waste No

5.7 Emissions from burning of waste in open air

e.g. slash materials, construction debris) No

5.8 Emissions from any other sources Yes Please refer Annexure – VII.

6.Generation of Noise and Vibration, and Emissions of Light and Heat:



source of information data with source of

information data

6.1 From operation of equipment e.g. engines,

ventilation plant, crushers

Yes The Noise level will be within the prescribed

limit. At noisy areas adequate preventive &

control measures will be taken. No

significant noise, vibration or emission of

light & heat from the unit.

6.2 From industrial or similar processes Yes -Do-

6.3 From construction or demolition No

6.4 From blasting or piling No

6.5 From construction or operational traffic No

6.6 From lighting or cooling systems No

6.7 From any other sources No

7. Risks of contamination of land or water from releases of pollutants into the ground or into sewers, surface waters, groundwater, coastal waters or the sea:




7.1 From handling, storage, use or spillage of

hazardous materials

Yes Please refer Annexure – VIII.

7.2 From discharge of sewage or other effluents

to water or the land (expected mode and

place of discharge)

Yes For details please refer Annexure – V.

7.3 By deposition of pollutants emitted to air into

the and or into water

No

7.4 From any other sources No

7.5 Is there a risk of long term build up of

pollutants in the environment from these

sources?

No

8. Risk of accidents during construction or operation of the Project, which could affect human

health or the environment

S.No. Information/Checklist confirmation Yes/No Details there of (with approximate



8.1 From explosions, spillages, fires etc from

storage, handling, use or production of

hazardous substances

Yes Please refer Annexure – VIII.

8.2 From any other causes No

8.3 Could the project be affected by natural

disasters causing environmental damage

(e.g. floods, earthquakes, landslides,

cloudburst etc)?

No

9. Factors which should be considered (such as consequential development) which could lead to

environmental effects or the potential for cumulative impacts with other existing or planned

activities in the locality

Sr. No.

Information/Checklist confirmation

Yes/No

Details there of (with approximate



9.1 Lead to development of supporting. utilities, ancillary development or development stimulated by the project which could have impact on the environment e.g.

• Supporting infrastructure (roads, power

supply, waste or waste water treatment, etc.)

• housing development

• extractive industry

• supply industry

• other

Yes Please refer Annexure – IX.

9.2 Lead to after-use of the site, which could

have an impact on the environment

No

9.3 Set a precedent for later developments No

9.4 Have cumulative effects due to proximity to

other existing or planned projects with

similar effects

No

(II) Environmental Sensitivity

Sr. No. Areas Name/

Identity

Aerial distance (within 15km.) Proposed

project location boundary

1 Areas protected under international

conventions, national or local legislation for

their ecological, landscape, cultural or other

related value

NA Proposed expansion project site is within the

GIDC Industrial Estate, Panoli.

2 Areas which important for are or sensitive Ecol

logical reasons - Wetlands, watercourses or

other water bodies, coastal zone, biospheres,

mountains, forests

NA

3 Area used by protected, important or sensitive

Species of flora or fauna for breeding, nesting,

foraging, resting, over wintering, migration

NA No protected area or sensitive species within 15

km from the proposed project boundary.

4 Inland, coastal, marine or underground waters NA No inland, costal or marine within 15 km from

the project.

5 State, National boundaries NA N.A.

6 Routes or facilities used by the public for access

to recreation or other tourist, pilgrim areas

Yes Public transportation

7 Defense installations NA

8 Densely populated or built-up area Panoli and

Ankleshwar

Panoli village 1.85 km and Ankleshwar City

around 7 km from the proposed project site.

9 Area occupied by sensitive man-made land uses

Hospitals, schools, places of worship,

community facilities)

No

10 Areas containing important, high quality or

scarce resources (ground water resources,

surface resources, forestry, agriculture,

fisheries, tourism, minerals)

No

11 Areas already subjected to pollution

environmental damage. (those where existing

legal environmental standards are exceeded)or

No NA

12 Areas susceptible to natural hazard which could

cause the project to present environmental

problems (earthquake s, subsidence ,landslides,

flooding erosion, or extreme or adverse climatic

conditions)

No NA

IV). Proposed Terms of Reference for EIA studies:Please refer Annexure - X

LIST OF ANNEXURES

SR. NO. NAME OF ANNEXURE

I List of Products and Raw materials along with their Production Capacity

II Layout Map of the Plant

III Brief Manufacturing Process Description

IV Details of water consumption & waste water generation

V Details of Effluent Treatment Scheme

VI Details of Hazardous Waste Generation and Disposal

VII Details of Stacks and Vents, Fuel & Energy Requirements

VIII Details of Hazardous Chemicals Storage & Handling

IX Socio-economic Impacts

X Proposed Terms of Reference

ANNEXURE-I

____________________________________________________________________ __

LIST OF PRODUCTS ALONG WITH THEIR PRODUCTION CAPACITY WITH RAW MATERIALS

SR.

NO. PRODUCTS

PRODUCTION CAPACITY (MT/MONTH)

EXISTING

QUANTITY

ADDITIONAL

QUANTITY

TOTAL

QUANTITY

1 Sodium Nitrite

100 -- 100

2 Sodium Nitrate

3 Potassium Nitrate

4 Sodium Sulphate

5 Sodium Bisulphite

6 Sodium Sulphite

7 Magnesium Sulphate

8 Manganese Sulphate

9 Calcium Chloride

10 Sodium thiosulphate

11 Copper Sulphate 25 -- 25

Total 125 -- 125

Proposed

1 Acid Orange-7

--

11 11

2 Acid Red-88

3 Acid Red-18

4 Acid Yellow-36

5 Acid Blue-113

6 Acid Black-1

7 Direct Orange-26

8 Direct Red-31

9 Direct Yellow-4

10 Direct Violet-9

11 Direct Green-8

12 Direct Black-29

13 Reactive Yellow-7 ( Yellow M -GR)

14 Reactive Blue-4 (Brilliant Blue M-R)

15 Benzidine Yellow-13G (Pigment Yellow)

16 Pigment Lake Red-C

17 Sulphanilic Acid

18 Salicylic Acid

19 Hydrazobenzene

TOTAL -- 11 11

TOTAL

(EXISTING+PROPOSED) 125 11 136

RAW MATERIAL CONSUMPTION

EXISTING

Sr.

No.

Name of Products Raw Materials Consumption

MT/Month

1 Sodium Nitrite OR Caustic Lye 95.24

Nitrous Acid 270.00

2 Sodium Nitrate OR Nitric Acid 74.00

Soda Ash 62.00

3 Potassium Nitrate OR Nitric Acid 63.00

Potassium Hydroxide 56.00

4 Sodium Sulphate OR Caustic Lye 93.60

Sulfuric Acid 56.00

5 Sodium BisulfiteOR Caustic Flakes 38.40

Sulfur 30.80

Oxygen 30.80

6 Sodium sulfiteOR Caustic Flakes 63.40

Sulfur 25.40

Oxygen 25.40

7 Magnesium Sulphate

OR Sulfuric Acid 81.60

Magnesium Oxide 33.30

8 Mangenese Sulphate

OR Sulfuric Acid 65.30

Mangenese Oxide 47.30

9 Calcium Chloride OR Calcium Oxide 25.40

Dil. HCl 110.00

10 Sodium Thiosulphate Caustic Flakes 50.60

Sulfur 40.40

Oxygen 20.20

11 Copper Sulphate Copper 7.81

Sulfuric Acid 12.50

PROPOSED

Sr.

No.

Name of Products Raw Materials Consumption

Kg/Kg of Product

[1] ACID ORANGE-7

OR

Sulfuric Acid 0.500

Caustic Flakes 0.190

HCl 0.350

NaNO2 0.200

Beta Napthol 0.420

Soda Ash 0.060

Salt 1.000

[2] ACID RED-88

OR Sodium Napthonate 0.612

Soda Ash 0.050

HCl 0.480

NaNO2 0.172

Beta Napthol 0.360

Soda Ash 0.170

Salt 0.800

[3] ACID RED-18

OR Sodium Napthonate 0.404

HCl 0.320

NaNO2 0.114

Soda Ash 0.320

G. Salt 0.750

Salt 0.750

[4] ACID YELLOW-18

OR Metanilic Acid 0.474

Soda Ash 0.390

Caustic 0.252

NaNO2 0.190

Diphenyl Amine 0.462

Emulsifier 0.066

Salt 1.500

[5] ACID BLUE-113

OR

Metanilic Acid 0.272

HCl 0.848

NaNO2 0.228

Napthyl Amine 0.224

Soda Ash 0.344

Acetic Acid 0.156

Salt 0.620

Phenyl Peri Acid 0.466

[6] ACID BLACK-1

OR Para Nitro Aniline 0.224

HCl 0.960

NaNO2 0.224

Aniline 0.150

H. Acid 0.520

Soda Ash 0.150

Salt 0.500

[7] DIRECT ORANGE-26

OR

Aniline Oil 0.124

HCl 0.400

NaNO2 0.092

J-Acid Urea 0.666

Soda Ash 0.300

Salt 0.500

[8] DIRECT RED-31

OR

Aniline 0.130

HCl 0.424

NaNO2 0.098

Rohduline Acid 0.646

Soda Ash 0.300


Sodium Acetate 0.216

Salt 0.600

[9] DIRECT YELLOW-4

OR DASDA 0.600

HCl 0.850

NaNO2 0.220

Phenol 0.300

Caustic 0.120

Soda Ash 0.250

Salt 0.400

[10] DIRECT VIOLET-9

OR Sulfanilic Acid 0.250

HCl 0.860

NaNO2 0.100

P-Cresidine 0.200


Salt 0.700

Phenyl J-Acid 0.454

Soda Ash 0.150

[11] DIRECT GREEN-8

OR

Vinyl Sulphone 0.360

HCl 0.780

NaNO2 0.180

H. Acid 0.410

Caustic 0.100

Phenol 0.120

Sodium bicarbonate 0.050

Soda Ash 0.100

Salt 0.500

[12] DIRECT BLACK-29

OR F.C. Acid 0.408

HCl 0.500

NaNO2 0.184

H. Acid 0.420

Soda Ash 0.080

M.P.D. 0.144

Salt 0.400

[13] REACTIVE YELLOW-7

OR

NASDA 0.454

HCl 0.340

NaNO2 0.080

N-Methyl J-Acid 0.290


Soda Ash 0.088

Cynuric Chloride 0.188

Salt 0.600

[14] REACTIVE BLUE-4

OR

MPDSA 0.294

HCl 0.970

Bromamine Acid 0.600

Nitrogen 0.010

Calsonil Oil 0.018

Octanol Oil 0.012

Sodium Bicarbonate 0.100

NaCl 0.370

Cynuric Chloride 0.288

Soda Ash 0.100

Salt 0.200

[15] Benidine Yellow -13G

(Pigment Yellow) OR

Di Chloro Benzidine 0.385

HCL 0.600

NaNO2 0.214

Aceto Acetanilide 0.528

Caustic Soda 0.314

[16] Pigment Lake Red-C OR C-Acid 0.400

HCl 0.600

NaNO2 0.224

Beta Napthol 0.260


[17] SULPHANILIC ACID

OR Sulphuric Acid 0.580

Aniline Oil 0.550

[18] SALICYLIC ACID

OR Phenol 0.834

Caustic Lye 0.740

Carbon Dioxide 0.416

[19] Hydrazobenzene

OR

Methanol 0.374

Caustic 0.050

Nitro Benzene 0.426

Diclone 0.040

Formaldehyde 0.430

ANNEXURE-II

_______________________________________________________________________

LAYOUT OF MAP OF THE PLANT

ANNEXURE-III

MANUFACTURING PROCESS, CHEMICAL REACTION & MASS BALANCE:

Existing:

EXISTING:

[1] SODIUM NITRITE [NaNO2]: MANUFACTURING PROCESS:

First charge Caustic Lye into the closed reaction vessel.Then start addition of Nitrous Acid

(20%) under stirring and adjust ph 7.0.Then start heat the reaction mass to 100

0C

temperature and make the density 1.25 of the reaction mass. Then cool and settle for

crystallization. Now , centrifuge the crystal and packed it into the bags for dispatch.ML

recycles to the reaction vessel for use next batch.

PROCESS FLOW DIAGRAM:

Reaction Vessel

Crystallization

Finished Product:

1260Kg

Caustic Lye:1200Kg

Nitrous Acid(20%):

3400 Kg

EvaporationLoss

:3300 lit

ML recycles for use in next

batch:40 lit

[2] SODIUM NITRATE [NaNO3]: MANUFACTURING PROCESS:

First charge Nitric Acid into the reaction vessel then charge Soda Ash.Than apply

heating.After evaporation dry material is pulverized and packed in drums / bags for sale.


Reaction Vessel

Crystallization

Finished Product:

1000Kg

Soda Ash: 620Kg

Nitric Acid:740 Kg EvaporationLoss

:360 lit

[3] POTASSIUM NITRATE [KNO3]: MANUFACTURING PROCESS:

First charge Nitric Acid into the reaction vessel then charge Potassium hydroxide.Than apply

heating upto 800C to 90

0C for 2 hours.Then after completion of reaction unload in SS open

pan and evaporate water completely and cool it then dry material is pulverized and packed

in bags for sale.


Reaction Vessel

Open Pan

Finished Product:

1000Kg

KOH: 560Kg

Nitric Acid:630 Kg

EvaporationLoss

:190 lit

Pulverizor

[4] SODIUM SULPHATE [Na2SO4]: MANUFACTURING PROCESS:

First charge Caustic Lye(48%) into the closed reaction vessel.Then start addition of Sulphuric

Acid and adjust ph 7.0 under stirring.Then start heat the reaction mass to 100

0C

temperature and evaporate water from the reaction mass. Then cool the reaction mass and

settle for crystallization. Now , centrifuge the crystal and packed it into the bags for

dispatch.ML recycles to the reaction vessel for use next batch.


Reaction Vessel

Crystallization

Finished Product:

1250Kg

Caustic Lye:1170Kg

Sulphuric Acid: 700

Kg

EvaporationLoss

:600 lit

ML recycles for use in next

batch:20 lit

[5] SODIUM BISULPHITE [NaHSO2]: MANUFACTURING PROCESS:

First charge Caustic Flakes and Sulfur into the reaction vessel.Then pass air (oxygen) and

heat it to 90

0C to 95

0C temperature. Maintain it for 4 hours.Then cool the reaction mass and

dry it. Then packed in bags for dispatch.


Caustic Flakes:384Kg

Sulphur: 308 Kg Reaction Vessel

Reaction Mass

Finished Product:

1000Kg

Oxygen: 308 Kg

[6] SODIUM SULPHITE [Na2SO3]: MANUFACTURING PROCESS:


heat it to 90

0C to 95

0C temperature. Maintain it for 4 hours.Then cool the reaction mass and

dry it . Then packed in bags for dispatch.


Reaction Vessel

Reaction Mass

Finished Product:

1000Kg


Sulphur: 254 Kg

EvaporationLoss

:142 Kg Oxygen: 254 Kg

[7] MAGNESIUM SULPHATE [MgSO4]: MANUFACTURING PROCESS:

First charge Sulphuric Acid into the reaction vessel.Then charge Magnesium Oxide under

stirring and heat it to 95

0C to 100

0C temperature. Maintain it for 2 hours.Then cool to RT .

Then packed in bags for dispatch.


Reaction Vessel

Heat to 950C -100

0C

Finished Product:

1000Kg

Sulphuric Acid:816Kg

MgO: 333 Kg

EvaporationLoss

:149 Kg

[8] MANGANESE SULPHATE [MnSO4]: MANUFACTURING PROCESS:

First charge Sulphuric Acid into the reaction vessel.Then charge Manganese Oxide under

stirring and heat it to 1000C temperature. Maintain it for 2 to 3 hours.Then cool to RT .

Then packed in bags for dispatch.


Reaction Vessel

Heat to 950C -100

0C

Finished Product:

1000Kg

Sulphuric Acid:653Kg

MnO: 473 Kg

EvaporationLoss

:126 Kg

[9] CALCIUM CHLORIDE [CaCl2]: MANUFACTURING PROCESS:

First charge Calcium Oxide and Dil. HCl into the reaction vessel.Heat it to evaporation

temperature.Then cool to RT . Then packed in bags for dispatch.


Reaction Vessel

Heat to 950C -100

0C

Finished Product:

1000Kg

Calcium Oxide:254Kg

Dil. HCl(30%):1100Kg

EvaporationLoss

:854 Kg

[10] SODIUM THIOSULPHITE [Na2S2O3]: MANUFACTURING PROCESS:


heat it to 150

0C temperature. Maintain it for 6 hours.Then cool the reaction mass to RT and

packed in bags for dispatch.


Reaction Vessel

Reaction Mass

Finished Product:

1000Kg


Sulphur: 404 Kg

EvaporationLoss

:112 Kg Oxygen: 202 Kg

[11] COPPER SULPHATE [Cu2SO4]: MANUFACTURING PROCESS:

Required quantity of copper is taken in the reaction vessel.Then add water and Sulphuric

Acid into the reaction vessel.Then apply heating upto 900C to 95

0C. The reaction is

continued till the whole copper is converted to the copper Sulphate. Then reaction mass is

transferred to crystallizer and keeps for crystallizaton.Then crystals of copper Sulphate are

filtered through centrifuge and mother liquor is reycled in the next batch.


Reaction Vessel

Heating

Packing and Dispatch of

Copper Sulphate

Unsaturated

solution

: 230 Kgs

EvaporationLoss

:190 Kg

Unsaturated

wash: 110 Kgs

Crystallization

Filtration

Copper:100 Kgs

Sulphuric Acid:160 Kgs

Water:200 Kgs

Water:50 Kgs

320Kg

Recycle :340 Kgs

PROPOSED:

[1] ACID ORANGE -7

MANUFACTURING PROCESS: Sulphanilic Acid HCl and NaNO2 are diazotised in presence of water and Ice. Beta Napthol , Caustic

flakes and Soda ash are dissolved in presence of water. Above both diazotised and dissolved mass

are coupled in coupling vessel and water is added. The mass is than Isolated and filtered followed by

drying and pulverisation to obtain finished product.

Diazotizati

Sulphanilic Acid : 250

Kg.

HCl : 175

Kg.

NaNO2 : 100

Kg.

Water : 1000

Coupling

Filtration

Drying

Finished Product

:500 Kg.

Evaporation

Loss : 660

Kgs.

3360

E.T.P

Waste water

: 3500 Kg.

Salt: 500

Kg.

Pulverisatio

n

500

Dissolution

Beta Napthol : 210 Kg.

Caustic flakes : 95 Kg.

Soda Ash : 30 Kg.

Water : 500 Kg.

252

83

5

Isolation

4160

466

116

Ice: 800

Kg.

CHEMICAL REACTION:

MASS BALANCE:

Material Input Qty(Kg) Material Output Qty(Kg)

Sulphanilic Acid 250 Effluent 3500

HCl 175 Evaporation loss 660

NaNO2 100 Acid Orange-7 500

Water 1500

Ice 1800

Beta Napthol 210

Caustic flakes 95

Soda Ash 30

Salt 500

Total 4660 Total 4660

+

NH2

SO3 H

NaNO2 + HCl

N=N

+ +NaCl 2H2O

Sulphanilic Acid [ I ]

M.W.175 Kgs 69 Kgs 365 Kgs 184 Kgs 58.5 Kgs 36 Kgs

1.

2.

SO3

N=N

SO3

+

OH

+ NaOH NaO 3 S N=N

OH

+ H 2O

M.W. 184 Kgs

B-Nepthol[ I ]

144 Kgs

Orange-7

40 Kgs 350 Kgs 18 Kgs

[2] ACID RED-88 MANUFACTURING PROCESS: Sodium Napthonate ,HCl and NaNO2 are diazotised in presence of water and ice. Beta Napthol,

Caustic Flakes and Soda Ash are dissolved in presence of Ice & water. Above both diazotised and

dissolved mass are coupled in coupling vessel. The mass is than isolated and filtered followed by

drying and pulverization to obtain finished product

Beta Napthol

:180 Kg

Soda Ash: 25Kg

Caustic Flakes:85 Kg

Water:500 Kg

Ice:500 Kg

Sodium

Napthonate:306 Kg

HCl: 240 Kg

NaNO2: 86 Kg

Water: 1000 Kg

Ice: 1000 Kg

Diazotisation Dissolution

Coupling

Isolation

Filtration

Drying

Pulverisation

Finished Product:

500 Kg

C.E.T.P

Ice: 500Kg

Salt: 400Kg

Evaporation Loss

:822Kg

Wastewater

:3500Kg

2632 1290

4422

4822

1322

500

CHEMICAL REACTION:

MASS BALANCE:


Sodium Napthonate 306 Effluent 3500

HCl 240 Evaporation Loss 822

NaNO2 86 Acid Red-88 500

Water 1500

Ice 2000

Beta Napthol 180

Soda Ash 25

Caustic flakes 85

Salt 400


1. NH 2

SO 3Na

+ NaNO 2 + 2HCl

N=N

SO 3

+ 2NaCl + 2H 2O

Napthonic Acid

M.W. 245 Kgs 69 Kgs 2(365)

Kgs

2.

234 Kgs 2(585) Kgs

2(18) Kgs

N=N

SO 3

+

OH

+ 1/ Na2 CO 3

M.W. 234 Kgs 144 Kgs 1/2(106)

Kgs

1/2 H2 O + 1/2 CO 2+ SO 3Na N=N

OH

M.W. 1/2(15) Kgs

1/2(44)

Kgs

Red-88 400 Kgs

[3] ACID RED-18

MANUFACTURING PROCESS:

Sodium Napthonate ,HCl and Sodium Nitrite are diazotised in presence of water and ice. Take water

and Soda Ash in coupling vessel and charge above diazotised mass slowly and G.Salt is added in

coupling vessel. Than isolated and filtered followed by drying and pulverization to obtain finished

product.

Diazotisation

Coupling

Isolation

Filtration

Drying

Pulverisation

Finished Product

:500 Kg

C.E.T.P

Water :500Kg

Soda Ash :160Kg

G.Salt :375 Kg

Ice :1000Kg

Salt: 585Kg

Evaporation Loss

:839Kg

Wastewater

:3000Kg

1719

3754

4339

1339

500

2035

Sodium Napthonate

:202 Kg

HCl: 160 Kg

NaNO2: 57 Kg

Water: 500 Kg

Ice: 800 Kg

CHEMICAL REACTIONS:

MATERIAL BALANCE:


Sodium Napthonate 202 Effluent 3000

HCl 160 Evaporation Loss 839

NaNO2 57 Acid Red-18 500

Water 1000

Ice 1800

Soda Ash 160

G. Salt 375

Salt 585


1. NH2

SO 3 Na

+ NaNO2 + 2HCl

N=N

SO 3

+ 2NaCl + 2H 2 O

Sodium Napthonate

M.W. 245 Kgs 69 Kgs 2(365)Kgs

73Kgs

2.

234 Kgs 2(58)Kgs

117Kgs

2(18)

36Kgs

N=N

SO 3

+

OH

+ 1 (1/2) Na 2 CO 3

M.W. 234 Kgs 304 Kgs 1(1/2)(106)

159 Kgs

1(1/2) H 2O + 1(1/2)CO 2 + NaO3S N=N

OH

M.W.

1(1/2)(44 Kgs)

66 Kgs

Red-18

604 Kgs

SO 3 H

SO 3 H

SO 3 Na

NaO3 S

G-Salt

1(1/2)(18Kgs)

27 Kgs

[4] ACID YELLOW-36

MANUFACTURING PROCESS: Metallic Acid ,Soda Ash ,Caustic Flakes and NaNO2 are diazotised in presence of water and

ice.Diphenyl Amine, Caustic, Emulsifier and Soda Ash are dissolved in presence of Ice & water. Above

both diazotised and dissolved mass are coupled in coupling vessel. The mass is than isolated and

filtered followed by drying and pulverization to obtain finished product.

Diphenyl Amine:231 Kg

Soda Ash: 120Kg

Caustic: 66 Kg

Emulsifier: 33Kg

Water: 1000 Kg

Ice: 600 Kg


Coupling

Isolation

Filtration

Drying

Pulverisation

Finished Product:

500 Kg

Ice: 500Kg

Salt: 750Kg

Wastewater

:3500Kg

1867 2050

4417

5167

1667

500

Metallic Acid:237Kg

Soda Ash: 75 Kg

Caustic Flakes:60 Kg

NaNO2: 95 Kg

Water: 1000 Kg

Ice: 400 Kg

C.E.T.P

Evaporation Loss

:1167Kg

CHEMICAL REACTION:

1.

SO

3 H

+ NaNO

2

+ HCl

N=N

SO 3

+ NaCl + 2H

2

O

M.W. 173 Kgs 69 Kgs 365

Kgs

2.

184 Kgs 58.5

Kgs

2(18) 36 Kgs

N=N

SO 3

+

+ 1/2 Na 2

CO

3

M.W. 184 Kgs

169 Kgs 1/2(106)

53 Kgs

1/2 H

2

O + 1/2 CO

2 N=N

M.W.

1/2(44)

22Kgs

375 Kgs

1/2(18)

9 Kgs

NH

2

Metallic Acid

NH

Diphenyl Amine(D.P.A.)

NH +

Acid Yellow-36

SO 3

Na

MATERIAL BALANCE:


Metallic Acid 237 Effluent 3500

Diphenyl Amine 231 Evaporation Loss 1167

NaNO2 95 Acid Yellow-36 500

Water 2000

Ice 1500

Soda Ash 195

Caustic flakes 60

Caustic 66

Emulsifier 33

Salt 750


[5] ACID BLUE-113

MANUFACTURING PROCESS: Metallic Acid ,HCl and NaNO2 are diazotised in presence of water and ice. Napthyl Amine, Acetic

acid, HCl and Soda Ash are dissolved in presence of Ice & water. Above both diazotised and dissolved

mass are coupled in coupling vessel.The mass is than isolated and dissolved by soda ash.Then

diazotised the mass again with HCl and NaNO2 and coupled with the solution of Phenyl Peri Acid and

Soda Ash. The mass is than isolated again and filtered followed by drying and pulverization to obtain

finished product.

Metallic Acid:136 Kg

HCl: 290 Kg

NaNO2: 54 Kg

Water: 500 Kg

Ice: 1000 Kg

Napthyl Amine:112

Kg

Soda Ash: 78Kg

Acetic acid: 78 Kg

HCl: 134Kg

Water: 500lit


Coupling

Isolation

Filtration

Drying

Pulverisation

Finished Product:

500 Kg

C.E.T.P

Ice: 500Kg

Salt: 200Kg

Evaporation Loss

:713Kg

Wastewater

:3500Kg

1980 902

3382

3582

1213

500

Dissolution

Soda Ash:55Kg 3637

Ind Diazo

Ind Coupling

Isolation

3831

4603

4713

HCl:134Kg

NaNO2:60Kg

Salt: 110Kg

Phenyl Peri Acid:233 Kg

Soda Ash:39Kg

Ice:500Kg

772

CHEMICAL REACTON:

NH

2

OC Nepthail Amine

365 Kgs

SO

3 H

+ NaNO

2

+ HCl

N=N

SO

3

+ NaCl + 2H 2

O

M.W. 173 Kgs 69 Kgs 36.5 Kgs

184 Kgs 58.5 Kgs

2(18)

36 Kgs

N=N

SO

3

+

+ HCl

M.W. 184 Kgs 143 Kgs

M.W.

NH 2

Metanillic Acid

N=N

SO

3 HNH

2 HCl

363.5 Kgs

1.

2.

N=N

SO 3 H

NH

2

HCl

+ NaNO

2

+ H

2 SO

4

N=N

SO

3 HN=NCl

+ NaHSO

4 + 2H

2 O

363.5 Kgs 69 Kgs 98 Kgs 374.5 Kgs 120 Kgs 2(18)Kgs

36 Kgs

3.

MASS BALANCE:


Metallic Acid 136 Effluent 3500

Napthyl Amine 112 Evaporation Loss 713

NaNO2 114 Acid Blue-113 500

Water 1000

Ice 2000

Soda Ash 172

Phenyl Peri acid 233

Acetic Acid 78

HCl 558

Salt 310


M.W.

N=N

SO 3

H

N=NCl

+

N=N

SO

3

H

N=N

+ NaCl + 1/2H

2

O +1/2O

3.

SO 3

H NH

+1/2Na

2

O 3

374.5 Kgs 299 Kgs 1/2 (106)Kgs

53 Kgs

Phenyl Peri

Acid

SO 3

H

NH

(Blue-113)

637 Kgs

585 Kgs

9 Kgs

22 Kgs

[6] ACID BLACK-1

MANUFACTURING PROCESS: Para Nitro Aniline ,HCl and NaNO2 are diazotised in presence of water and ice. Above both diazotised

and dissolved mass are coupled in coupling vessel and H.Acid, Soda Ash , Caustic Lye ,Ice and water

are added. The mass is than isolated with Salt. The mass is than filtered followed by drying and

pulverization to obtain finished product.

2479

1035

Salt:250Kg

Para Nitro Aniline:112

Kg

HCl: 250 Kg

NaNO2: 56 Kg

Water: 500 Kg

Ice: 500 Kg

NaNO : 56 Kg

HCl: 230Kg

Aniline: 75 Kg

Water: 200 Kg

Ice: 500 Kg

Diazotisation Diazotisation

Coupling

Isolation

Filtration

Drying

Pulverisation

Finished Product:

500 Kg

E.T.P

H. Acid: 260Kg

Water: 200 Kg

Ice: 500Kg

Soda Ash:75 Kg

Evaporation Loss

:764Kg

Wastewater

:2500Kg

1418 1061

3514

3764

1264

500

CHEMICAL REACTIONS:

69 Kgs

+ NaNO

2

+ 2HCl

N=NCl

+ NaCl + 2H 2 O

M.W. 138 Kgs 69 Kgs 2(36.5) Kgs

73 Kgs

NH

2

184 Kgs 58.5 Kgs

2(18)

36 Kgs

M.W. 93 Kgs

2(36.5) Kgs

NH 2

ParaNitroAniline

N=NCl

1405 Kgs

1.

2.

NO

2 NO

2

+ NaNO

2 + 2HCl

+ NaCl + 2H 2

O

73 Kgs

58.5 Kgs 2(18) Kgs

36 Kgs

NO

2

M.W.

N=NCl

+

N=NCl

+ 2Na

2 CO

3

3.

NH

2 OH

185.5 Kgs 319 Kgs 140.5 Kgs 2(106)Kgs

212Kgs

H-Acid

SO

3 H SO

3 H

+

OH

NH

2

N=N

NO

2

N=N

2H

2 O + 2CO

2 + 2NaCl +

SO 3

Na

NaO

3 S

2(18)Kgs

36Kgs

2(44)Kgs

88Kgs

2(58.5)Kgs

117Kgs

Black-1

615Kgs

MASS BALANCE:

Input Qty(Kg) Output Qty(Kg)

Aniline 75 Effluent 2500

Para Nitro Aniline 112 Evaporation Loss 764

NaNO2 112 Acid Black-1 500

Water 900

Ice 1500

Soda Ash 75

H. acid 260

HCl 480

Salt 250


[7] DIRECT ORANGE-26

MANUFACTURING PROCESS: Aniline oil ,HCl and NaNO2 are diazotised in presence of water and ice. J-Acid urea and Soda Ash are

dissolved in presence of Ice & water. Above both diazotised and dissolved mass are coupled in

coupling vessel. The mass is than isolated and filtered followed by drying and pulverization to obtain

finished product.

Aniline oil:62 Kg

HCl: 200 Kg

NaNO2: 46 Kg

Water: 500 Kg

Ice: 700 Kg

J-Acid Urea: 333 Kg

Soda Ash: 150 Kg

Water: 1000 Kg

Ice: 500 Kg

3491


Coupling

Isolation

Filtration

Drying

Pulverisation

Finished Product:

500 Kg

C.E.T.P

Ice: 500Kg

Salt: 250Kg

Evaporation Loss

:741Kg

Wastewater

:3000Kg

1508 1983

3991

4241

1241

500

CHEMICAL REACTIONS:

+ NaNO

2

+ 2HCl

N=NCl

+ NaCl + 2H

2

O

M.W. 93 Kgs 69 Kgs 2(36.5) Kgs

73 Kgs

140.5 Kgs 58.5 Kgs

2(18)

36 Kgs

NH 2

Aniline Oil

1.

2.

M.W.

N=NCl

+ 2Na 2 CO

3

504 Kgs 2(140.5) Kgs 2(106)Kgs

281 Kgs 212Kgs

SO

3 H SO 3

H

+

N=N

N=N

2H

2

O + 2CO

2 + 2NaCl

SO

3

Na

2(18)Kgs

36Kgs

2(44)Kgs

88Kgs

2(58.5)Kgs

117Kgs

Orange-26

756 Kgs

OH

NH-CO-NH

OH

2

J-Acid Urea

SO 3 Na

NH-CO-NH

OH

+

M.W.

OH

MASS BALANCE:


Aniline oil 62 Effluent 3000

J- Acid Urea 333 Evaporation Loss 741

NaNO2 46 Direct Orange-26 500

Water 1500

Ice 1700

Soda Ash 150

HCl 200

Salt 250


[8] DIRECT RED-31

MANUFACTURING PROCESS: Aniline ,HCl and NaNO2 are diazotised in presence of water and ice. Rohduline Acid, Caustic Flakes,

Sodium Acetate and Soda Ash are dissolved in presence of Ice & water. Above both diazotised and

dissolved mass are coupled in coupling vessel. The mass is than isolated and filtered followed by

drying and pulverization to obtain finished product.

RohdulineAcid: 323 Kg

Soda Ash: 150Kg

Caustic flakes: 33 Kg

Sodium Acetate :108Kg

Water: 500 Kg

Ice: 500 Kg

Aniline: 65 Kg

HCl: 212Kg

NaNO2: 49 Kg

Water: 1000 Kg

Ice: 500 Kg


Coupling

Isolation

Filtration

Drying

Pulverisation

Finished Product:

500 Kg

C.E.T.P

Ice: 500Kg

Salt: 300Kg

Evaporation Loss

:740Kg

Wastewater

:3000Kg

1826 1614

3940

4240

1240

500

3440

CHEMICAL REACTIONS:

+ NaNO

2

+ 2HCl

N=NCl

+ NaCl + 2H

2

O

M.W. 93 Kgs 69 Kgs 2(36.5) Kgs

73 Kgs

140.5 Kgs 58.5 Kgs

2(18)

36 Kgs

NH 2

Aniline Oil

1.

2.

M.W.

N=NCl

+ 2Na

2

CO

3

461 Kgs 2(140.5) Kgs 2(106)Kgs

281 Kgs 212Kgs

SO

3

H SO 3

H

+

N=N

N=N

2H

2 O + 2CO

2 + 2NaCl

SO

3 Na

2(18)Kgs

36Kgs

2(44)Kgs

88Kgs

2(58.5)Kgs 117Kgs

Red-31

713 Kgs

OH

HN

OH

2

RohdulineAcid

SO

3

Na

NH

OH

+

M.W.

OH

MASS BALANCE:


Aniline 65 Effluent 3000

Rohduline Acid 323 Evaporation Loss 740

NaNO2 49 Direct Red-31 500

Water 1500

Ice 1500

Soda Ash 150

Caustic flakes 33

Sodium Acetate 108

HCl 212

Salt 300


[9] DIRECT YELLOW-4

MANUFACTURING PROCESS: DASDA (Di Amino Stilbene Di Sulphonic Acid) ,HCl and NaNO2 are diazotised in presence of water and

ice. Phenol, Caustic and Soda Ash are dissolved in presence of Ice & water. Above both diazotised

and dissolved mass are coupled in coupling vessel. The mass is than isolated and filtered followed by

drying and pulverization to obtain finished product.

DASDA: 300 Kg

HCl: 425Kg

NaNO2: 110 Kg

Water: 500 Kg

Ice: 1000 Kg

Phenol: 150 Kg

Soda Ash:125Kg

Caustic : 60 Kg

Water: 500 Kg

Ice: 500 Kg


Coupling

Isolation

Filtration

Drying

Pulverisation

Finished Product:

500 Kg

E.T.P

Ice: 500Kg

Salt: 200Kg

Evaporation Loss

:870Kg

Wastewater :3500Kg

2335 1335

4170

4370

1370

500

3670

Water: 500Kg

CHEMICAL REACTIONS:

+ 2NaNO 2 + 4HCl + 2 NaCl +4 H2O

M.W. 370 Kgs 2(69) Kgs 4(36.5) Kgs

138 Kgs 146 Kgs

465 Kgs 2(58.5) Kgs

117 Kgs

4(18)

72 Kgs

1.

2.

M.W.

N=NCl

+ Na 2 CO3

465 Kgs 2(94) Kgs 2(40) Kgs 106Kgs

188 Kgs 80 Kgs

SO3 H SO3 H

+

N=N N=N

3H2O + CO 2 + 2NaCl

SO3Na

3(18)Kgs

54Kgs

44Kgs

2(58.5)Kgs

117Kgs

Yellow-4

624 Kgs

OH

2

SO3 Na

CH=CH

OH

M.W.

OH

SO3H SO3H SO3 H SO3 H

NH 2 NH2

CH=CH CH=CH

N=NCl N=NCl

DASDA

CH=CH

N=NCl

Phenol

+ 2NaOH

+

MASS BALANCE:


DASDA 300 Effluent 3500

Phenol 150 Evaporation Loss 870

NaNO2 110 Direct Yellow-4 500

Water 1500

Ice 2000

Soda Ash 125

Caustic 60

HCl 425

Salt 200


[10] DIRECT VIOLET-9

MANUFACTURING PROCESS: Sulfanillic Acid , NaOH , HCl and NaNO2 are diazotised in presence of water and ice. Para

Cresidine and HCl are dissolved in presence of water. Above both diazotised mass are

coupled in coupling vessel than Sodium Acetate , HCl , V. Salt and Ice are added and

filtered.

Than wet cake is dissolved in presence of water and ice and diazotised with HCl and

NaNO2. Phenyl J-Acid , Soda Ash are dissolved in presence of water and ice. Above both

diazotised and dissolved mass are coupled in coupling vessel. Than above mass is

isolated with salt and filtered followed by drying and pulverization to obtain finished

product.

Sulfanillic Acid:

125 Kg

HCl: 100Kg

NaNO2: 50 Kg

Water: 500 Kg

Ice: 500Kg

Ice: 1000 Kg

P. Cresidine:100Kg

HCl : 160 Kg

Water: 500 Kg

Diazotisation Diazotisation

1st Coupling

Slurry Preparation and

Diazotisation

Filtration

Drying

Pulverisation

Finished Product:

500 Kg

E.T.P

Ice: 500Kg

Sod. Acetate:33 Kg

HCl: 90Kg

Salt: 180 Kg

Evaporation Loss

:1000Kg

Wastewater

:1500Kg

1275 760

1148

1102

2035

Salt: 100Kg

Filtration

2838

Salt: 100 Kg

HCl : 10 Kg

Water:200 Kg

E.T.P

Ice: 500 Kg

HCl : 100 Kg

NaNO2:50 Kg

Isolation

Wastewater

:2000Kg

2nd

Coupling

500

1500

3000

2900

2900

Dissolution

1798 Phenyl J-Acid:

227 Kg

Soda Ash :75

Kg

Water:300 Kg

Ice: 500 Kg

CHEMICAL REACTIONS:

O

1.NH 2

SO 3H

+

NaNO 2 + HCl

N=N

SO3

+ NaCl + 2 H 2O

Sulphanilic Acid

M.W. 173 Kgs 69 Kgs 36.5 Kgs

184

Kgs 58.5 Kgs

2(18)Kgs

36 Kgs

2.N=N

SO 3 CH3

NH 2

OCH 3 N=N

CH 3

OCH 3

NH 2

SO 3H

+

P-Cresidine

M.W. 184

Kgs 137 Kgs 321 Kgs

3.

N=N

NH 2

OCH 3

CH 3

SO3H

+

NaNO2 + 2HCl

M.W. 321

Kgs 69 Kgs 2(36.5) Kgs 368.5 Kgs 58.5 Kgs 2(18) Kgs

36 Kgs

SO 3H

N=NCl

OCH 3

CH3

N=N

73 Kgs

+ NaCl + 2 H2

MASS BALANCE:


Sulfanilic Acid 125 Effluent 3500

P. Cresidine 100 Evaporation Loss 1000

Phenyl J-Acid 227 Direct Violet-9 500

Sodium Acetate 33

NaNO2 100

Water 1500

Ice 2000

HCl 460

Soda Ash 75

Salt 380


4.

N=N

N=NCl

OCH 3

CH 3

SO3H SO3H

+

OH

NH

+ 1(1/2)Na2 CO 3

M.W. 368.5 Kgs 315 Kgs 1(1/2)(106) Kgs 159 Kgs

Phenyl J-Acid

SO3Na

CH 3

N=N

N=N OCH 3

OH

SO3Na

NH+ NaCl + 1(1/2)CO2 + 1(1/2)H 2O

66 Kgs 27 Kgs

Violet-9 M.W. 691 Kgs 58.5 Kgs

1(1/2)(44)Kgs

1(1/2)(18)Kgs

[11] DIRECT GREEN-8

MANUFACTURING PROCESS: Vinyl Sulphone , HCl and NaNO2 are diazotised in presence of water and ice. H-Acid , Caustic , Soda

Ash are dissolved in presence of water. Above both diazotised and dissolved mass are coupled in

coupling vessel. In other reactor charge above wet cake and prepare slurry and diazotised with HCl

and NaNO2 in presence of water & ice. Coupled the above mass with the solution of Phenol Sodium

Bicarbonate and Soda Ash.Then isolate and filter the mass followed by drying and pulverization to

obtain finished product.

V.S. :180 Kg

HCl :200 Kg

NaNO2 :45 Kg

Water :1000 Kg

Diazotisation

Dissolution

H.Acid :205 Kg

Caustic :50 Kg

Water :500 Kg

1425 755

1st Coupling

2180

Ice: 500Kg

Slurry Preparation and

Diazotisation

2680

HCl :190 Kg

NaNO2 :45 Kg

Ice :1000 Kg

12353915

2nd

Coupling

Phenol :60 Kg

NaHCO3 :25 Kg

Soda Ash:50 Kg

Ice :500

Kg

635

Filtration

Drying

Pulverization

Finished Product:

500 Kg

E.T.P

Evaporation Loss

:800Kg

Wastewater

:3500Kg

Isolation

500

1300

4800

4550

Salt: 250Kg

CHEMICAL PROCESS:

(1)

NH 2

SO 2 OCH 2 SO 3 H

+ NaN 2 + 2HCl

N=NCl

SO 2 OCH 2 CH 2 SO 3 H

+ NaCl + 2H 2 O

Vinyl Sulphone (V.S.)

M.W. 281 Kgs 69 Kgs

2(36.5)

73 Kgs 328.5 Kgs 58.5 Kgs 36 Kgs

2(18)

(2)


N=NCl NH 2 O

SO 3 H S03H

+

N=N


N 2

O

+ 2HCl

M.W. 328.5 Kgs 319 Kgs 611 Kgs 36.5 Kgs

SO3H

SO3H

(3)

N=N

SO 2OCH 2CH 2 SO 3H

SO3H SO 3H

NH 2 OH

+ NaNO 2 +2HCl +2H 2O+ NaCl

OHN=NCl

SO 3H SO3H

SO 2OCH 2CH 2SO 3H

N=N

N=N

SO 2OCH 2CH 2SO 3H

SO 3H SO 3 H

N=NCl OH

611 Kgs 69 Kgs

2(36.5)

73 Kgs 658.5 Kgs 58.5 Kgs

2(18)

36 Kgs

(4)

+

OH

+ 2Na 2CO 3 +

OHN

SO 3Na SO3Na

SO 2OCH 2CH 2SO 3Na

N=N

N OH

NaCl +2CO 2

+ 2H 2O

658.5 Kgs 94 Kgs 212 Kgs 782 Kgs 58.5 Kgs

2(44)

88 Kgs

2(18)

36 Kgs

Green-8

MASS BALANCE:


Vinyl Sulphone 180 Effluent 3500

H.Acid 205 Evaporation Loss 800

Phenol 60 Direct Green-8 500

NaHCO3 25

NaNO2 90

Caustic 50

Water 1500

Ice 2000

HCl 390

Soda Ash 50

Salt 250


[12]DIRECT BLACK-29

MANUFACTURING PROCESS: FC Acid , HCl and NaNO2 are diazotised in presence of water and ice. H-Acid and soda ash are

dissolved in presence of water.Above both diazotised and dissolved mass are coupled in coupling

vessel. In other reactor charge above wet cake and prepare slurry and diazotised with HCl and

NaNO2 in presence HCl and NaNO2 in presence of water and ice. Coupled the above mass with the

solution of Meta Phenyl Diamine than isolate and filter the mass followed by drying and pulverisaton

to obtain finished product.

CHEMICAL REACTIONS:

NO2 NH

NH 2

+ NaNO2 +2HCl NaCl +2H2O+

N=NCl

NH NO2

SO 3H SO3H

F.C. Acid 2(36.5 ) 2(18)

M.W. 309 Kgs 69 Kg 73 Kgs 356.5 Kgs 58.5 Kgs 36 Kgs

(1)

(2)

SO 3H

NO2 NH

N=NCl

+

OH NH2

SO3H SO 3H

+ NaOHSO3H

NH2 OH

N=N

NHNO2SO 3H

+NaCl+2H 2O

356.5 Kgs H-Acid

319 Kgs

40 Kgs 639 Kgs 58.5 Kgs 18 Kgs

(3)

NO 2 NH

N=N

SO3H SO3H

OHNH2

+ NaNO2 + 2HCl + 2H2O+ NaCl

N=NCl OH

SO3HSO3H

N=N

NH NO 2

639 Kgs 69 Kgs 73 Kgs

2(36.5)

686.5 Kgs 58.5 Kgs 36 Kgs

(4)

686.5 Kgs

NO2 NH

N=N

SO 3H SO3H

OHN=NCl

+

NH 2

NH 2

N=N OH

SO 3HSO3H

N=N

NH NO2

NH 2

NH2

+ HCl

M.P.D

108 Kgs 758 Kgs

(Black -29)

36.5 Kg

[13] REACTIVE YELLOW -7 (YELLOW M-GR)

MANUFACTURING PROCESS: NASDA, HCl and NaNO2 are diazotized in presence of water. N-M ethyl J- Acid and Sodium Acetate

are dissolved in presence of Ice & water. Above both diazotized and dissolved mass are coupled in

coupling vessel. Then acid Soda Ash, Cynuric Chloride for cynuration of the mass. Than Isolated and

filtered followed by drying and pulverization to obtain finished product.

Flow Diagram:

Diazotization NASDA : 227 Kg.

HCl : 170 Kg.

NaNO2 : 40 Kg.

Water : 500 Kg.

Coupling

Filtration

Drying

Finished Product

:500 Kg.

Evaporation Loss

: 570Kgs.

Soda Ash : 44 Kg.

Cynuric Chloride : 94 Kg.

Water : 1000 Kg.

Ice : 500 Kg.

1632

E.T.P Waste water : 2500Kg.

Salt: 300 Kg.

Pulverization

500

Dissolution

N-Methyl J- Acid : 145Kg.

Sodium Acetate : 50 Kg.

Water : 500 Kg.

937 695

Isolation

3270

3570

1070

CHEMICAL PROCESS:

(1)

HO 3S

NO2

CH=CH

NH2

SO 3H + NaNO2 + 2HCl SO 3 H

N2

CH=CH

N=NCl

HO 3S + NaCl +

N.A.S.D.AM.W. 400 Kgs

69 Kgs 2(36.5)

73 Kgs

447.5 Kgs 58.5 Kgs2(18)36 Kgs

(2)

447.5 Kgs

N=NCl

CH=CH

N2

SO3H SO3H +

OH NHCH3

SO3H

N.M.J Acid253 Kgs

SO3H

NO 2

CH

CH

SO 3H

N N

NHCH 3

SO 3H

OH

HCl

664 Kgs

36.5 Kg

+

+2H2O

MASS BALANCE:


NASDA 227 Effluent 2500

N-Methyl J-Acid 145 Evaporation Loss 570

Sodium Acetate 50 Reactive Yellow-7 500

Cynuric Chloride 94

NaNO2 40

Water 2000

Ice 500

HCl 170

Soda Ash 44

Salt 300


2 Na 2 CO3+

ClCl

Cl

CN

C

N

C

N+

NO 2

CH

SO 3H

CH

SO 3 H

N=N

NHCH 3

SO 3H

OH

664 Kgs

(3)

OH

N=N

SO 3 Na

CH

SO 3

CH

NO 2

Na

SO 3 Na

NCH 3

Cl

C N

CN C

N Cl

Yellow-4

878 Kgs

+2H 2 O +2CO 2 + NaCl

36 Kgs 88 Kgs

2(18) 2(44) 58.5 Kgs

Cynuric Chloride

184.5 Kgs

2(106)

212 Kgs

[14] REACTIVE BLUE -4 (BRILLIANT BLUE M-R)

MANUFACTURING PROCESS: First take MPDSA, HCl and Bromamine Acid in the reaction vessel with water than apply heating and

change nitrogen gas. Now add Calsonil oil, Octanol oil and Sodium bicarbonate. Now transfer this

reaction mass in wooden tab of HCl and NaCl solution with stirring. Now filter the material. Now

transfer the wet cake into cynuric chloride and soda ash solution with stirring. Then isolate and filter

the mass followed by drying and pulverization to obtain finished product.

Reactor

MPDSA : 147Kg.

HCl: 240 Kg.

Bromamine Acid: 300 Kg.

Nitrogen : 5 Kg.

Calsonil Oil : 9 Kg.

Octanol Oil : 6 Kg.

NaHCO3: 50 Kg.

Water: 1000 Kg.

Wooden Tab

1757

Filtration

Reactor

887

E.T.P

Drying

Finished Product

:500 Kg.

Evaporation Loss

: 681Kgs.

2681

2581

Water : 1500 Kg.

Cynuric Chloride: 144 Kg.

Soda Ash : 50 Kg.

Waste water

: 1500 Kg.

Isolation

1181

NaCl : 185 Kg.

HCl : 245 Kg.

430

2187

E.T.P

Waste water

: 1300 Kg.

Salt: 100 Kg.

Filtration

Pulverization

500

CHEMICAL PROCESS:

MASS BALANCE:


MPDSA 147 Effluent 2800

Bromamine 300 Evaporation Loss 681

Nitrogen 5 Reactive Blue-4 500

Calsonil Oil 9

Octanol Oil 6

NaHCO3 50

NaCl 185

Cynuric Chloride 144

Water 2500

HCl 485

Soda Ash 50

Salt 100


O

O

NH 2SO 3H

NHNH 2

SO 3 H

(2)

+

489 Kgs

Na2CO 3N N

C C

C

Cl

Cl

NCl

Cynuric Chloride

184.5 Kgs

1 2

(106)

+2

1

O

ONH 2

SO 3H

NH

NH

SO 3 H

C

Cl

N

Cl

C

C N

N

+

637 Kgs585 Kgs22 Kgs 9 Kgs

(44)21 (18)

2 1

+ NaCl(O2 )2 1 +H 2O

21

SO 3H

NH2

NH 2

+

O

O

NH2SO3H

Br

+ NaHCO3

M.P.D.S.A. 188 Kgs

Bromamine Acid 385 Kgs 84Kgs

NH2

SO 3H

NH

SO3H

NH2

+

O

O

NaBr +CO2 +H 2O

489 Kgs

18 44 103

(1)

[15] BENZIDINE YELLOW -13G (PIGMENT YELLOW)

MANUFACTURING PROCESS: Di Chloro Benzidine, HCl and NaNO2 are diazotized in presence of water and ice in wooden vessel. In

coupling vessel aceto acetanilide is dissolved in presence of water and ice then adds caustic soda lye.

Now charge above diazotized mass in coupler for coupling and filtered the mass followed by drying

and pulverization to obtain finished product.

Flow Diagram:

Diazotization

DCB : 250 Kg.

HCl : 420 Kg.

NaNO2 : 150 Kg.

Ice : 1000 kg

Water : 1000 Kg

Coupling

Filtration

Drying

Finished Product

:700 Kg.

Evaporation Loss

: 800Kgs.

Aceto Acetanilide: 370 Kg.

Caustic Soda : 220 Kg.

Water : 1000 Kg.

Ice : 1000 Kg.

2820

E.T.P Waste water: 4200Kg.

Pulverization

700

5410

1500

Waste: 290Kg.

[16] REACTIVE LAKE RED-C

MANUFACTURING PROCESS: C-Acid, HCl and NaNO2 are diazotized in presence of water and ice. Beta Napthol and caustic flakes

are dissolved in presence of Ice & water. Above both diazotized and dissolved mass are coupled in

coupling vessel. Than Isolated and filtered followed by drying and pulverization to obtain finished

product.

Flow Diagram:

Diazotization

C-Acid : 200 Kg.

HCl : 300 Kg.

NaNO2 : 112 Kg.

Water : 1000 Kg.

Ice : 1000 Kg

Coupling

Filtration

Drying

Finished Product

: 500 Kg.

Evaporation Loss:

500Kgs.

4326

E.T.P Waste water: 3500Kg.

Pulverization

500

Dissolution

Beta Napthol: 130Kg.

Caustic flakes: 84 Kg.

Water : 500 Kg.

Ice : 1000 Kg

2612 1714

1000

Water: 174 Kg.

[17] SULPHANILIC ACID

MANUFACTURING PROCESS:

First take Sulphuric Acid in Ball Mill and than charge Aniline Oil slowly. Apply heating upto

18000C temperature.After 2 hours check the material and dry it followed by pulverization to

obtain finished product for sale.

Ball Mill

Pulverizor

Drying

Finished Product:

500 Kg

Evaporation Loss:65 Kg

Sulphuric Acid: 290 Kg

Aniline Oil: 275 Kg

CHEMICAL REACTIONS:

MASS BALANCE:


Sulphuric Acid 290 Evaporation Loss 65

Aniline Oil 275 Sulphanilic Acid 500

Total 565 Total 565

NH2

Aniline Oil

+ H2SO 4

NH2

SO 3 H

+ H 2 O

Sulphanlic Acid

M.W. 93 Kgs 98 Kgs 173 Kgs 18 Kgs

[18] SALICYLIC ACID

MANUFACTURING PROCESS: First take Phenol and Caustic Lye in a Ball Mill then apply heating upto 1800

0C under vacuum. Now,

cool to 10000C temperature and charge CO2 gas. Maintain temperature upto 14 hrs. Than transfer

the mass into another reactor and charge water with stirring. Filter the crystal of Salicylic Acid

followed by drying to obtain finished product for sale.

Phenol: 417 Kg

Caustic Lye: 370 Kg

CO2 : 208 Kg

Ball Mill

Filtration

Reactor

Evaporation Loss:295

Kg

Finished Product:

500 Kg

Water:1000 Lit

Drying

E.T.P.

Wastewater:

1200 Lit

CHEMICAL REACTIONS:

MASS BALANCE:


Phenol 417 Effluent 1200

Caustic Lye 370 Evaporation Loss 295

CO2 208 Salicylic Acid 500

Water 1000


+ NaOH

ONa

+ H 2O

M.W. 94 Kgs 40 Kgs 116 Kgs 18 Kgs

OH

Phenol

ONa

M.W. 116 Kgs 44 Kgs 160 Kgs

OH

+ CO2

1.

2. COONa

3.OH

M.W. 160 Kgs 1/2(98) Kgs 138 Kgs 1/2(47.4)

+ 1/2 Na 2SO 4

OH

+ 1/2H2SO 4

COONa COOH

49 Kgs

Salicylic Acid

71 Kgs

[19] HYDRAZOBENZENE

MANUFACTURING PROCESS: First take Methanol in a Reaction Vessel then add NaOH and Nitrobenzene slowly.Now , apply

heating upto 9500C temp.Than add Diclone and maintain temperature upto 12 hrs. Now , add

Formaldehyde with stirring.After completion of reaction mass and filter it followed by drying to

obtain finished product.

Mass Balance:

Reactor

Filtration

Condensation

Methanol: 1500Kg

NaOH: 600Kg

Nitrobenzene : 670 Kg

Diclone: 10Kg

Formaldehyde: 160 Kg

Finished Product:

500 Kg

Recovery of Methanol

:1470 Kg

Reuse in next batch

Centrifuge

E.T.P.

Wastewater:

970 Kg

2940

1470

740

500

730

240

CHEMICAL REACTIONS:

MASS BALANCE:


Methanol 100 Effluent 1040

NaOH 600 Hydrazobenzene 500

Nitrobenzene 670

Diclone 10

Formaldehyde 160


260 Kgs

ONaNaO

NN + 2HCHO NH NH + 2HCOONa

Hydrazobenzene 2(68) Kgs

136 Kgs184 Kgs

2(30 ) Kgs

60 Kgs

1.

2CH 3OH + 2NaOH +2

NO2

N N

NaO ONa

+2 CH 3 OH +1 1

2O 2 + H2O

2(32) Kgs 2(40) Kgs

Nitrobenzene

2(123) Kgs

246 Kgs

260 Kgs 2(32) Kgs

64 Kgs

1 12

( 96) Kgs

48 Kgs

18 Kgs

2.

Annexure -4

Details of Water Consumption and Wastewater generation

Water Consumption

S. No. Particulars

Water Consumption (KL/Day)

Existing Additional Total

1. Domestic 0.8

1.2 2.0

2. Gardening 0.8 0.2 1.0

3. Industrial 4. Process 0.5 2.5 3.0 5. Boiler 0.4 1.6 2.0

6. Cooling (Make-up) 00 2.0 2.0

7. Washing 00 0.5 0.5

8. Sub-Total: Industrial 0.90 6.60 7.50

9. Grand Total 2.50 8.00 10.50

Wastewater generation

S.No. Particulars Waste Water Generation (KL/Day)

Existing Additional Total

1. Domestic 0.7 0.8 1.5

2. Gardening 00 00 00

3. Industrial 4. Process 00 2.3 2.3 5. Boiler (Blow down) 00 0.1 0.1

6. Cooling (Blow down) 00 0.1 0.1

7. Washing 00 0.5 0.5

8. Sub-Total: Industrial 00 3.0 3.0

9. Grand Total 0.7 3.8 4.5

Water Balance (After Proposed Expansion):

Water – 10.5 KL/Day

Domestic- 2.0 Gardening- 1.0 Industrial – 7.5

1.5 KL/Day �

Septic

tank/soak pit Process- 3.0 Washing- 0.5 Boiler- 2.0 Cooling- 2.0

Process- 2.3 Washing- 0.5 Boiler- 0.1 Cooling- 0.1

ETP CETP for further

treatment

Annexure -5:

Details of ETP

PROCESS DESCRIPTION: ETP (EFFLUENT TREATMENT PLANT)

Proposed

1) Primary Treatment:

The waste water from unit will be brought to the treatment plant via a series of

underground pipelines. The waste water will be collected in the equalization tank. Two

numbers of tanks are proposed. One will in filling mode for equalization of waste water

while the other will be in pumping mode. The equalized wastewater is pumped to the flash

mixer for addition of chemicals like lime. From the flash mixer the waste water flows into

the flocculator where chemical flocs are formed by coagulation and flocculation by addition

of Alum/Ferrous sulphate and polyelectrolyte. These flocs are removed in the primary

settling tank. Treated effluent will be sent to CETP, Panoli for further treatment. The

underflow (sludge) from the primary settling tank is taken to sludge dewatering unit (Sludge

Drying Bed).

The Domestic wastewater is disposed of through septic tank & soak pit.

Effluent Treatment Plant (Dimension):

Sr. No. Name of the Unit Dimension Volume (m3) MOC

1. Collection Tank (2 Nos.) 1.5(m) x 1.5(m)x

1.0(m)

3.0 m3 RCC

2. Dosing Tank (1 Nos.) 1.0(m) x 1.0(m )x

1.0(m)

1.0 m3 RCC

3. Flash Mixer 1.0(m) x 1.0(m )x

1.0(m)

1.0 m3 RCC

4. Flocculator 1.0(m) x 1.0(m )x

1.0(m)

1.0 m3 RCC

5. Neutralization Tank 1.5(m) x 1.5(m)x

1.0(m)

3.0 m3 RCC

6. Primary Settling Tank 1.5(m) x 1.5(m)x

1.0(m)

3.0 m3 RCC

Flow Diagram:

EXPECTED CHARACTERISTICS OF WASTEWATER BEFORE & AFTER TREATMENT

Sr.

No.

Parameter

Characteristics (mg/L) CETP Inlet Norms

(mg/L) Untreated Treated

1. pH 3 - 9 6.5-8.5 5-9

2. SS 190 85 100

3. COD 2250 950 1000

4. BOD3 1000 280 300

Raw

Effluent

Collection Tank Neutralization

Tank

Primary

Settling Tank Final Collection

Tank

CETP for

further

Treatment in

future

DST FMT Floc.

Annexure -6

___________________________________________________________________________

Details of hazardous waste generation, storage & disposal

Type of waste Category Existing

MT/Month

Additional

MT/Month

Total

MT/Month

Disposal Method

Discarded

Containers/Bags/

Liners

33.1 0.5 2 2.5 Collection, storage,

transportation,

reuse/sale to authorize

vendors

Used oil 5.1 -- 0.01 0.01 Collection, storage,

transportation,

reuse/sale to authorize

vendor

ETP Sludge 35.1 -- 10 10 Collection, storage,

transportation and

dispose common TSDF

site

Annexure -7

Details of flue gas & proposed pollution control equipment

Particulars Fuel Fuel

Quantity

Stack

height

Emission

Norms

APCM

Existing scenario

Closed Furnace (2

Nos.)

Fire wood 45

MT/Month

11 SPM-150 mgNm3

SO2-262 mgNm3

Nox -94 mgNm3

--

Non-IBR Boiler

(Capacity-300 Kg)

11

Proposed Scenario after expansion (Flue Gas Emission)

Closed Furnace (2

Nos.)

Bio-coal 45

MT/Month

11 SPM-150 mgNm3

SO2-262 mgNm3

Nox -94 mgNm3

Cyclone &

Water

scrubber

Non-IBR Boiler

(Capacity-300 Kg)

Steam Boiler

(Capacity-800

Kg/Hr)

Bio-coal 15

MT/Month

21 SPM-150 mgNm3

SO2-262 mgNm3

Nox -94 mgNm3

Multicyclone

Separator

with bag

filter

Annexure -8

Storage Details of Hazardous Chemicals

Sr.

No.

Raw Materials Storage

Capacity

(MT)

Type of

Storage &

MOC

No. of

Vessel

Vessel

Capacity

(MT)

Type of

Hazard

1. Sulfuric acid -

98%

5 MS Tank 1 5 Corrosive

2. Caustic Lye 5 MS Tank 1 5 Corrosive

3. HCl 5 HDPE Tank 1 5 Corrosive

4. Aniline 5 MS Tank 1 5 Flammable

5 Methanol 1 Drum 5 200 Kg Flammable

6 Formaldehyde 1 Drum 5 200 Kg Flammable

Annexure – 9

Socio - Economic Impacts

1) Employment Opportunities

The manpower requirement for the proposed expansion project is being expected to

generate some permanent jobs and secondary jobs for the operation and maintenance of

plant. This will increase direct / indirect employment opportunities and ancillary business

development to some extent for the local population.

This phase is expected to create a beneficial impact on the local socio-economic

environment.

2) Industries

Required raw materials and skilled and unskilled laborers will be utilized maximum from the

local area. The increasing industrial activity will boost the commercial and economical status

of the locality, to some extent.

3) Public Health

The company regularly examines, inspects and tests its emission from sources to make sure

that the emission is below the permissible limit. Hence, there will not be any significant

change in the status of sanitation and the community health of the area, as sufficient

measures have been taken and proposed under the EMP.

4) Transportation and Communication

Since the existing factory is having proper linkage for the transport and communication, the

development of this project will not cause any additional impact.

In brief, as a result of the proposed there will be no adverse impact on sanitation,

communication and community health, as sufficient measures have been proposed to be

taken under the EMP. The proposed scenario is not expected to make any significant change

in the existing status of the socio - economic environment of this region.

Annexure-10

__________________________________________________________________________

Proposed Terms of Reference for EIA Studies

1. Project Description

• Justification of project.

• Promoters and their back ground

• Project site location along with site map of 5 km area and site details providing various

industries, surface water bodies, forests etc.

• Project cost

• Project location and Plant layout.

• Existing infrastructure facilities

• Water source and utilization including proposed water balance.

• List of Products & their capacity

• Details of manufacturing process of proposed products

• List of hazardous chemicals

• Mass balance of each product

• Storage and Transportation of raw materials and products.

2. Description of the Environment and Baseline Data Collection

• Micrometeorological data for wind speed, direction, temperature, humidity and rainfall

in 10 km area.

• Existing environmental status Vis a Vis air, water, noise, soil in 10 km area from the

project site.

• Ground water quality at 8 locations within 10 km.

• Complete water balance

3. Socio Economic Data

• Existing socio-economic status, land use pattern and infrastructure facilities available in

the study area were surveyed.

4. Impacts Identification And Mitigatory Measures

• Identification of impacting activities from the proposed project during construction and

operational phase.

• Impact on air and mitigation measures including green belt

• Impact on water environment and mitigation measures

• Soil pollution source and mitigation measures

• Noise generation and control.

• Solid waste quantification and disposal.

• Control of fugitive emissions

5. Environmental Management Plan

• Details of pollution control measures

• Environment management team

• Proposed schedule for environmental monitoring including post project

6. Risk Assessment

• Objectives, Philosophy and methodology of risk assessment

• Details on storage facilities

• Process safety, transportation, fire fighting systems, safety features and emergency

capabilities to be adopted.

• Identification of hazards

• Consequence analysis

• Recommendations on the basis of risk assessment done

• Disaster Management Plan.

7. Information for Control of Fugitive Emissions

8. Information on Rain Water Harvesting

9. Green Belt Development plan

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