fundamentals of fiber modification chemistry
TRANSCRIPT
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Fundamentals of Fiber
Modification Chemistry
Art J. Ragauskas, Yunqiao Pu, Lenong AllisonInstitute of Paper Science and Technology
School of Chemistry and BiochemistryGeorgia Institute of Technology
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“If you want to succeed, you should strike out on new paths rather than travel the worn paths of accepted success.” – John D. Rockefeller
Process Research Publications: +140,000
Product-Platform Research Publications: ~9,000
Fundamentals of Fiber Modification Chemistry:Promising Research Patterns
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• Main group responsible for surface and bulk charge of kraft fibers.
• Important for pulp swelling.
• Increase pulp fiber softness and collapsibility.
• Improve pulp strength properties.
• Improve beatability.
• Capable of ion-exchange reactions.
Fundamentals of Fiber Modification Chemistry: Importance of Carboxylate Groups
COO
OOC COO
COO
COOH
HOOC
[-COOH]Kspecific =[-COO ][H ]
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Fundamentals of Fiber Modification Chemistry:Grafting - Acrylic Acid Groups
Lignin
OH
OCH3
(NH4)2Ce(NO3)6
CO2Me OH
H3COOCH3
O
OH
H3COOH
ONaOH
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Pulp [Acid] meq/g
WRV H2O g/od pulp
Tear IndexmNm2/g
Burst Index kPam2/g
TMP 0.083 1.9
2.8 1.1
Low Graft
0.146 2.3 2.8 2.3
High Graft
0.184 2.6 3.0 3.2
Fundamentals of Fiber Modification Chemistry:Grafting - Acrylic Acid Groups
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Fundamentals of Fiber Modification Chemistry:Grafting – Cationized Fibers
+
+
+
SW Mechanical
Linerboard Pulp
NaOH
ON Cl
HO
O
OH
OH
OCH3
OCH3
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Fundamentals of Fiber Modification Chemistry:Cationized SGW-Tear Index
0
0.5
1
1.5
2
Tea
r In
dex SGW
SGW-0.07%NSWG-0.10%NSWG-0.12%NSWG-0.19%N
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0
5
10
15
20
Ten
sile
Inde
x SGWSGW-0.07%NSWG-0.10%NSWG-0.12%NSWG-0.19%N
Fundamentals of Fiber Modification Chemistry:Cationized SGW-Linerboard Tensile Index
8
9
10
11
12
13
Ten
sile
Inde
x
Linerboard Linerboard-Graft1Linerboard-Graft2
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You Want to Put What in My Pulp Mill?!@#%
Need to Address
- Cost:Benefit- Waste treatment- What kind of grafting reactor will you use at 1000 tons/day
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Fundamentals of Fiber Modification Chemistry: Topochemistry of Acid Groups -ECF SW Kraft Pulp
0.2
0.6
1
1 2 3 4 5
Position
BLANK
BULK
SURFACE
Lumen
[-C
OO
- ]Experimental: Grafted acid groups on holocellulose,
controlling topochemistry
SEM
Barzyk, Page, and Ragauskas (1996)
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Fundamentals of Fiber Modification Chemistry: Topochemistry of Acid Groups -ECF SW Kraft Pulp
0
0.05
0.1
0.15
0.2
0.25
170 220 270 320 370
Light Scattering Coefficient (cm 2/ g)
BLANK
BULK
SURFACE
Scott- Bond (J)
Conclusion: Surface acid groups yield unique strength properties
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Fundamentals of Fiber Modification Chemistry:
Fiber Acid Groups: Key parameter to enhance fiber-fiber bonding, swelling, wet-end chemical retention
0
1
2
3
4
5
170 220 270 320 370
Light Scattering Coefficient (cm2/ g)
BLANK
BULK
SURFACE
Bre
akin
g L
engt
h (k
m)
Light Scattering (cm2/g)
Barzyk, Page, and Ragauskas (1996)
C O–
O
Attachment of CMC onto Kraft ECF Fiber (Lindstrom, 2000)- pH 8, 0.05 M CaCO3, csc 2.5%, 120oC, 2h - 1 – 4% charge
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Current Pulp Mill
Status
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Fiber Modification: Fiber Charge - Mill Status
0
0.01
0.02
0.03
0.04
0.05
0.06
0.07
0.08
Kraft-C
(SW
)Kraf
t-C (S
W)
Kraft-C
(SW
(PS/AQ))
Kraft-C
(SW
)Kraf
t-C (S
W)
Kraft-C
(SW
)
Kraft-C
(Euc
alyptu
s)Kraf
t-C (S
W)
Sulfite
Sulf
ite
Kraft-C
(SW
post-
D2)
Acid
con
tent
(meq
/gr)
0
0.005
0.01
0.015
0.02
0.025
0.03
0.035
Kraft-A Kraft-A Kraft-A Kraft-A Kraft-A Kraft-A Kraft-B Kraft-B
Acid
con
tent
(meq
/gr)
Little, if any, control of Fiber charge 0.016 – 0.07 meq/gr
Fiber resource only current control mechanism
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50
55
60
65
70
75
80
85
90
95
100
Refere
nce C
ookBro
wn StockO2 F
eedO2 W
asher M
atD0 M
at(E
OP) Mat
D1 Mat
(R1-3
)*
D1 Transfe
r (R1-3)
*D1 M
at (R
4)*
D1 Transfe
r (R4)*
Stage
Tens
ile In
dex
0
20
40
60
80
100
120
Aci
d C
onte
nt, µ
eq/g
Tensile IndexBulk Acid
Fundamentals of Fiber Modification: Mill Status
• OD(EOP)D Mill Tensile Strength and Bulk/Surface Acid Groups
peroxide
Gradual loss of acid groups due in partto degradation of lignin
Finally P increases BrightnessStrength-acid groups
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Fundamentals of Fiber Modification: Mill Status
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
Kraft-A Kraft-A Kraft-A Kraft-A Kraft-A Kraft-A Kraft-B Kraft-B
Cu
#
0
0.5
1
1.5
2
2.5
Kraft-C
(SW)
Kraft-C
(SW)
Kraft-C
(SW (P
S/AQ))
Kraft-C
(SW)
Kraft-C
(SW)
Kraft-C
(SW)
Kraft-C
(Euc
alyptu
s)Kraf
t-C (S
W)Sulf
ite
Sulfite
Kraft-C
(SW po
st-D2)
Cu
#
Cu # Tensile Index Tear Index
Bl. Kraft 0.22 20.5 16.3NaBH4 0.03 21.1 16.7
Bl. Kraft 2.30 9.90 12.0NaBH4 0.04 17.2 14.6
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The Fate of Fiber Charge During Peroxide Bleaching and Oxygen Delignification
What Contributes to Fiber ChargeUnbleached Kraft Pulps
- Lignin- Polysaccharides
> Uronic Acids> Hexenuronic Acids> Oxidized Reducing Ends
ECF Bleached Pulps
- Polysaccharides> Uronic Acids> Oxidized Reducing Ends> Oxidized Fragments??
- Oxidized Lignin Fragments ??1um
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The Fate of Fiber Charge: Peroxide Stage
333435363738394041424344
meq
/kg
pulp
ECF Pulp
E
EOP-70C
EOP-105C
EOP-0.5% MgSO4
EOP-0.1% MnSO4
EOP-0.1% FeSO41% H2O2, 1% NaOH
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The Fate of Fiber Charge: Peroxide Stage
333435363738394041424344
meq
/kg
pul
ECF Pulp
E
EOP (1% H2O2)
EP (1% H2O2)
EP-(1% H2O2/0.5%MgSO4)EP- (1% H2O2/0.1%FeSO4) EP (2% H2O2)
1% H2O2, 1% NaOH, 70oC
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The Fate of Fiber Charge: Peroxide Stage
35
35.5
36
36.5
37
37.5
38
38.5
39
39.5
40
meq
/kg
pulp
ECF Pulp (E+P) 40C (E+P) 50C (E+P) 60C (E+P) 70C (E+P) 80C
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The Fate of Fiber Charge: Peroxide Stage
+ 12%+ 10%46.00H2O2 bleaching
with 0.5% MgSO4
+ 11%+ 10%45.40H2O2 bleaching without MgSO4
37.00Original(fully bleached pulp)
Tear Index Tensile Index
Carboxylic Acid Content (meq./kg O.D. pulp)
Conditions of H2O2Bleaching
1% H2O2, 2% NaOH, 80 oC, 1 h
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The Fate of Fiber Charge: O Delignification
0 10 20 30 40 50 6050
60
70
80
90
100
110
120
Car
boxy
lic a
cid,
µm
ol/g
fibe
r
Reaction time, min
1.5% NaOH 2.5% NaOH 3.5% NaOH 640 kPa O2 800 kPa O2 960 kPa O2
85 oC 100 oC 115 oC
Kraft Pulps0 20 40 60 80100
120
140
160
180
200
220 Acid content Kappa number
Time,min
Aci
d, µ
mol
/g,re
sidu
al li
gnin
14
16
18
20
22
24
26
28
30
Kappa num
ber
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The Fate of Fiber Charge: O Delignification
0 10 20 30 40 50 6085
90
95
100
105
110
Acid
, µm
ol/g
,fibe
r
Time, min
640 kPa 800 kPa 969 kPa
0 10 20 30 40 50 6010
15
20
25
30
Kap
pa n
umbe
r
Time, min
640 kPa 800 kPa 960 kPa
0 10 20 30 40 50 6010
15
20
25
30
Kap
pa n
umbe
r
Time, min
85 0C 100 0C 115 0CHigher O2 Pressure
Better Delignification
Higher TemperatureBetter Delignification
Holocellulose PulpHigher O2 PressureSome Benefit
Holocellulose PulpHigher TemperatureLess Fiber Charge
0 10 20 30 40 50 6085
90
95
100
105
110
Aci
d,µm
ol/g
,fibe
r
Time, min
85 oC 100 oC 115 oC
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The Fate of Fiber Charge: O Delignification
14 16 18 20 22 24 26 28 3030
40
50
60
70
80
90
100
110
120
130 Bulk pulp Holocellulose Residual lignin
Kappa number
Aci
d, µ
mol
/g, f
iber
or h
oloc
ellu
lose
160
180
200
220
240
260
280
300
320
340
360
380
400
Acid, µm
ol/g, residual lignin
Tensile strength
02
46
810
12
34.82 38.64 55.40Acid groups content in holocellulose,mmol/g
Tens
ile in
dex,
N.m
/g
1. 30 – 50% Delignification
2. Holocellulose
OCH2OH
OROH
OR
OH
OCH2OH
OROH
OR
O
OCH2OH
RO
OR
O-OH
OCH2OH
OR
OOH
OCH2OH
OR
OO
- RO-
OCH2OH
OR
HO COOH
O2/HO-
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The Fate of Fiber Charge: O Delignification
Kraft SW pulp
OD pulp
Screened a Series of Carboxylic Acid Generating Catalysts:
• Compatible with O-Chemistry• Maintained or improved O-Delignification• No negative effect of cellulose D.P.
OO
O
OH
HOOH
Cellulose
Cellulose
Oxidant
OO
O
OH
HOOH
Cellulose
Cellulose
O
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The Fate of Fiber Charge: O Delignification
Selective Oxidation of Polysaccharides
Catalyst: Ruthenium pyrochlore oxide (Bi2RuxO7-x)
Reported by Arts et al to be good for monosaccharides only!Journal of Carbohydrate Chemistry 15 (1996) 317-29.
OHO
HO
OH
OHMeO
OHO
H
OH
HOMe
OO
OHO
-O
OH
O-OMe
OO
O
-O
OO OH
OMe
O-
H
OO-
OxidantFast
OxidantSlow
Oxidant
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The Fate of Fiber Charge: O Delignification
18.715.40.39
18.815.40.18-15.50.10
19.215.50
Viscosity/mPa.sKappa #Catalyst %
Oxygen Delignified Pulp Properties
10% csc, 2.5% NaOH, 800 kPa O2,100 oC
0.0 0.1 0.2 0.3 0.420
30
40
50
60
70
80
Car
boxy
lic a
cid,
µm
ol/g
,Hol
oPul
p
Catalyst, %
O-Catalyst forFiber Charge Development!
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The Fate of Fiber Charge: O Delignification
18.35
21.42
16
17
18
19
20
21
22
Tensile index(N.m/g)
44.82 61.79Carboxylic acid, µmol/g Holopulp
0.0 0.1 0.2 0.3 0.4 0.520
30
40
50
60
70
80
Car
boxy
lic a
cid,
µm
ol/g
,Hol
oPul
p
Catalyst, %
1. 0 – .18% Catalyst/O
2. Holocellulose
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The Fate of Fiber Charge: O Delignification
44.8 67.02 80.0400000000000160
65
70
75
80
85 Tensile strength Stretch
Carboxylic acid, µmol/g HoloPulp
Tens
ile in
dex,
mN
/g
2
3
4
5
Stre
tch,
%
Impact of Fiber Charge on Physical Properties
Holocellulose PFI Refined 600 CSFImproved Charge – Improved Tensile Index
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The Fate of Fiber Charge: O Delignification
44.8 67.02 80.04
6
7
8
9
10
11
12Tensile stiffnessUltrasonic in Plane specific stiffness:longitudial Ultrasonic in Plane specific stiffness:shear
Carboxylic acid, µmol/g HoloPulp
Stif
fnes
s,kN
/mm
2 or k
m2 /s
ec2
3.0
3.5
4.0
4.5
5.0
Shea
r,km
2 /sec
2
Impact of Fiber Charge on Physical Properties
Holocellulose PFI Refined 600 CSFImproved Charge – Improved Stiffness
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The Fate of Fiber Charge: O Delignification
0.00
20.00
40.00
60.00
80.00
100.00
120.00
140.00
O*
O*D0
O*D0(E
O)O*D
0(EO)D
1O*D
0(EO)D
1D2
O*D0(E
O)DP
Car
boxy
lic a
cid,
µm
ol/g
fibe
r
k.f.=0.18
k.f.=0.22
k.f.=0.26
2% Catalyst in O-stage
12%+ 14%42.2O*D0(EOP)D1
35.1OD0(EOP)D1
µmol/g fiber
Tensile Stiffness
TensileIndexCarboxylic acid
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Innovative Cellulosic Fiber-Design:Dielectric Breakdown Discharge
Research Objective: Understand the fundamental DBD interactionswith pulp fibers to improve bonding
Experimental Parameters Examined:• Use of cold plasma to:
• Improve wet/dry strength of TMP/Kraft• Developing New Coatings Technologies• Sheet Chemistry and Barrier Properties
Electrodes
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Innovative Cellulosic Fiber-Design:Dielectric Breakdown Discharge
AFM: BKP at Various DBD Treatment Levels
BKP Reference Low (0.20 kW) Medium (8.0 kW) High (22.4 kW) 3 µm x µm phase images.
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Innovative Cellulosic Fiber-Design:Dielectric Breakdown Discharge - ESCA
282284286288290Binding Energy (eV)
C1: C-C, C-H: C-C, C-C2: C-O-RC3: O-C-O, C=OC4: R-O-C=O
ESCA C(1s)
2.53
3.54
4.55
0 1 2 3 4 5
DBD (kW/m2/min)
O-C
=O(%
Car
bon)
BKP BKP-ext
25
30
35
40
45
0 2 4 6 8 10
DBD (kW/m2/min)
Acids (µeq/g)
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Innovative Cellulosic Fiber-Design: DBD - Wet Stiffness/Strength
0.5
0.6
0.7
0.8
0.9
1
0 2 4 6 8 10
DBD (kW/m2/min)
Wet Tensile (Nm/g)
Bleached SW Kraft
0.6
1.1
1.6
2.1
2.6
0 2 4 6 8 10DBD (kW/m2/min)
Wet Tensile (Nm/g)
Extracted TMPUnextracted TMP
0
2
4
6
8
10
0 2 4 6 8 10
DBD (kW/m2/min)
Wet
Stif
fnes
s (N
/mm
)
SW TMP
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Innovative Cellulosic Fiber-Design: DBD - Wet Strength
0
1
2
3
4
0 2 4 6 8 10 12 14
Dose (kW/m²/min)
TI (N
*m/g
)
5.000000006 484 719 1022 1523 4667
Wetting time (in)
121 g/m2 handsheetsSW kraft linerboard
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Innovative Cellulosic Fiber-Design: BioGrafting SW Linerboard Fibers
LaccaseEnzymatic Grafting
Phenolic AdditivesDyesCharged structures
NewProperties
OCH3
O
80
85
90
95
100
105
110
ControlVanillic
Syringic4-HBA
ControlLaccase
Kappa #
0.080.1
0.120.140.160.18
0.20.220.24
ControlVanillicSyringic4-HBA
ControlLaccase
Carboxylic Acids (meq/g)
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42
43
44
45
46
47
48
49
Con
tact
Ang
le (d
egre
es)
Con Lac GA LGA
20
25
30
35
40
45
Tens
ile In
dex
(N.m
/g)
Con Lac GA LGA
Tensile Improvement
COOH
OH
OH OH
Future Opportunities• Enzymatic control of fiber/sheet properties• Functional paper• Printing
1.51.71.92.12.32.52.72.93.1
kPa.
m2/
g
Con Lac HbaLac
+Hba
Burst ImprovementsCO2H
OH
Innovative Cellulosic Fiber-Design: BioGrafting SW Linerboard Fibers
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A Few Good Fibers
Concluding Remarks
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A Few Good Fibers: Conclusions• A modern pulp mill has little, if any, control over fiber
charge or oxycellulose content
• Surface charge is preferred but increases in bulk are also beneficial with respect to strength properties
• Improvements in fiber charge are possible via current bleaching protocols
• Surface treatments, biografting, absorption of charged polymers are potentially viable approaches
• More innovative research is needed!
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AcknowledgmentsDavid Barzyk, Derek Page
Richard Chandra
NSF, USDA, DOEIPST@GT Research Consortium/Fellowship