gas distribution hazardous chemical

8/13/2019 Gas Distribution Hazardous Chemical

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MarafiqGas Distribution Department


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Hazardous Chemical Awareness

By: Masood Alam Farooqui

Operations Supervisor


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Agenda Definition,

Roles and Responsibilities,

Procedure Chart, Classification of Hazardous Chemicals.

Ethyl Mercaptan,

Specification,

MSDS,

Hazards,

Safety,

Handling & Storage .

Nitrogen,

Specification,

MSDS,

Hazards,

Safety,

Handling & Storage .

Natural GasNote: covered in separate awareness presentation.


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Definitions

MARAFIQ OHSMSSubstance Hazardous to Health means any chemical,substance either natural or artificial in a liquid, solid, andgaseous or vapor form, including preparations and micro-organisms capable of causing adverse health effects or disease

arising from work activities.

INTERNATIONAL OHSMS

Hazardous and toxic substances are defined as Thosechemicals present in the workplace which are capable of causing

harm.In this definition, the term chemicals includes dusts, mixtures,and common materials such as paints, fuels, and solvents.OSHA currently regulates exposure to approximately 400substances.


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Roles & Responsibilities Department Manager

will nominate a Hazardous Chemicals Controller and one or more

deputies to manage hazardous substances within their department.

will nominate one or more persons to assist the Hazardous Chemicals

Controller in carrying out hazardous substance risk assessments.

will ensure that their employees are informed of the hazards they face

from hazardous substances and the control measures required to work

safely.

Superintendents , Supervisors & Line Managers will co-operate with their departmentsHazardous Chemicals Controller to

ensure that all substances used or produced within their sections are

included in the inventory of hazardous substances and that they are risk

assessed.

will ensure that any control measures identified by the risk assessment

process are implemented within their sections. responsibility includes the storage of hazardous substances will ensure

that they are stored and handled in a safe and controlled manner.

will communicate control measures to their employees and ensure that

appropriate PPE and RPE are made available and are maintained.

will ensure that the control measures are applied correctly and that thePPE, RPE and other equipment required is provided.

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Roles & Responsibilities Hazardous Chemicals Controller (and deputies)

will establish an inventory of the hazardous chemicals and substances

available or produced within their department.

will also maintain copies of the associated MSDSs and copies of all

completed hazardous substance risk assessments.

will clearly link the substances, processes, locations, equipment and

people exposed and will be updated whenever a new substance is

acquired.

If a substance is used in more than one area or process then an

assessment must be carried out for each area or process.

Hazardous Substance Risk Assessors

will use the information from MSDSs, from the proposed work

location and method of use or application to assess the risks fromhazardous chemicals and substances used, present or generated on

Marafiq controlled sites.

will use best practice to identify hazards and appropriate control

measures. They will record the significant findings from their risk

assessments.

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Procedure ChartHazardous substance

proposed

Obtain MSDS

Assess the risks, identify

control measures

Implement Static

Control Measures

Write method statement

for specific use

Write SOPs for static

operations

Provide training,

information and

instruction

Implement task-specific

control measures

Identify correct PPE and

RPE

Original intended use,

storage and application

Identify correct PPE and

RPE

Provide training,

information and

instruction

Additional use, storage

or application

Step 1

Step 2

Step 3 Step 11

Step 4

Step 5

Step 6

Step 7

Step 8

Step 9

Step 6

Step 7

Step 10


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Classification of Chemicals

Hazard

Chemicals

Hazards

Physical

Hazards

Health

Hazards

Environmental

Hazards


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Classification of Hazardous Chemicals

(Physical Hazards) Explosives,

Flammable Gases,

Flammable Aerosols,

Oxidizing Gases,

Gases Under

Pressure,

Flammable Liquids,

Flammable Solids,

Self-Reactive

Substances,

Pyrophoric Liquids,

Pyrophoric Solids,

Self-Heating

Substances, Substances which, in

contact with water emit

flammable gases,

Oxidizing Liquids,

Oxidizing Solids,

Organic Peroxides,

Corrosive to Metals.


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Classification of Hazardous Chemicals

(Environmental Hazards)

) Hazardous to the Aquatic Environment Acute aquatic toxicity

Chronic aquatic toxicity

Bioaccumulation potential

Rapid degradability


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ETHYL MERCAPTAN(ODORIZING AGENT)


S ifi ti


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SpecificationHeading Description

Trade Name Ethyl Mercaptan

Chemical Name Ethanethiol

Synonyms C2-H6-S, C2H5SH, ethanethiol, ethyl hydrosulfide, ethyl

hydrosulphide, ethyl thioalcohol, ethyl sulfhydrate, ethyl

sulphhydrate,mercaptoethane, thioethanol, thioethyl alcohol,

Stenching agent for L.P.G.

State (@ 25oC) Liquid Specific Gravity @ 20 C 0.839

Boiling Range (F) 95 Vapor Pressure @ 20 C 440.286 mmHg

Flash Point (F)


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MSDS


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HAZARDS(PHYSICAL, HEALTH & ENVIRONMENT)

Ethyl Mercaptan

H d Ph i l


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Hazard -Physical

Liquid and vapor are highly flammable.

Severe fire hazard when exposed to heat, flame and/or oxidizers.

Vapor forms an explosive mixture with air.

Severe explosion hazard, in the form of vapor, when exposed to flame or

spark.

Vapor may travel a considerable distance to source of ignition.

Heating may cause expansion / decomposition with violent rupture of

containers. On combustion, may emit toxic fumes of carbon monoxide (CO)

Combustion products include: carbon dioxide (CO2), sulfur oxides (SOx),

other pyrolysis products typical of burning organic material.

Contains low boiling substance: Closed containers may rupture due to

pressure buildup under fire conditions.

H d H lth


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Hazard -Health

SWALLOWED Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than

150 gram may be fatal or may produce serious damage to the health of the individual.

EYE There is some evidence that material may produce eye irritation in some persons and produce eye damage

24 hours or more after

instillation. Moderate inflammation may be expected with redness; conjunctivitis may occur with prolonged

exposure.

SKIN There is some evidence to suggest that the material may cause mild but significant inflammation of the skin

either following direct contact

or after a delay of some time. Repeated exposure can cause contact dermatitis which is characterized by

redness, swelling and blistering.

The degree of the injury produced by ethyl mercaptan will depend on the amount of material that gets onto

the skin and the speed and

thoroughness of the first aid treatment. Symptoms may include pain, itching, discoloration, swelling, and

blistering. Not expected to be

harmful to internal organs if absorbed through the skin.

Open cuts, abraded or irritated skin should not be exposed to this material.

Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury

with harmful effects. Examine

the skin prior to the use of the material and ensure that any external damage is suitably protected.

H d H lth


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Hazard -Health INHALED

Inhalation of vapors or aerosols (mists, fumes), generated by the material during

the course of normal handling, may be harmful.

There is some evidence to suggest that the material can cause respiratoryirritation in some persons. The body's response to such irritation can cause

further lung damage.

Human volunteers exposed to ethyl Mercaptan at 10 mg/m3 (4 ppm) for 5-10

days experienced a rise in olfactory threshold and altered taste reaction to bitter

and sweet substances, periodic nausea, irritation of mucous membranes of the

lips, mouth and nose, and fatigue. Exposure to lower levels (1 mg/m3 - 0.5 ppm) did not elicit unpleasant

symptoms.

Sub-chronic inhalation studies with rabbits, rats and mice (100 mg/m3 - 40 ppm -

for 5 months) showed minimal deviation in cardiovascular

system regulation and organ weights. 40 ppm was considered to be the

threshold effect concentration. Thiols (particularly ethyl Mercaptan) produce lethargy or sleepiness. Exposure to

high levels may result in nausea, vomiting, restlessness, muscle incoordination

and or paralysis, bluing of skin, depression of breathing, coma and death.

The use of a quantity of material in an unventilated or confined space may result

in increased exposure and an irritating atmosphere developing. Before starting

consider control of exposure by mechanical ventilation.

H d H lth


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Hazard -Health

Limited evidence suggests that repeated or long-term

occupational exposure may produce cumulative health

effects involving organs, or, biochemical systems.

Chronic exposure to mercaptans may result in damage

to the lungs, kidneys and liver.

H d E i t


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Hazard -Environment Very toxic to aquatic organisms, may cause long-term adverse effects in the

aquatic environment.

Do NOT allow product to come in contact with surface waters or to intertidal

areas below the mean high water mark. Do not contaminate water whencleaning equipment or disposing of equipment wash-waters.

Wastes resulting from use of the product must be disposed of on site or at

approved waste sites.

The lower molecular weight mercaptans exhibit high vapor pressure and

therefore surface transport (by volatilization) to the atmosphere is expected to

be an important fate process. Volatilization is expected to be an important

transport process for these mercaptans in water. Alkyl mercaptans are

expected to exist primarily in the vapor-phase in where readily degrade readily

in the atmosphere due to reaction with photo-chemically produced hydroxyl

radicals.

Sorption to is though to be low; the extent of sorption however may be directlycorrelated to the level of organic material within different soil types

Biodegradation processes involving methanogen bacteria may occur.

The mercaptans exhibit high to moderate toxicities towards aquatic species;

there is little evidence of bio-concentration or bio-magnification through the

food chain.

DO NOT discharge into sewer or waterways.


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SAFETY(PHYSICAL, HEALTH & ENVIRONMENT)

Ethyl Mercaptan

S f t Ph i l


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Safety -Physical General

Alert Emergency Responders and tell them location and nature of hazard.

May be violently or explosively reactive.

Wear full body protective clothing with breathing apparatus.

Prevent, by any means available, spillage from entering drains or water course.

Consider evacuation (or protect in place).

Fight fire from a safe distance, with adequate cover.

If safe, switch off electrical equipment until vapor fire hazard removed.

Use water delivered as a fine spray to control fire and cool adjacent area.

Avoid spraying water onto liquid pools.

DO NOT approach containers suspected to be hot.

Cool fire exposed containers with water spray from a protected location.

If safe to do so, remove containers from path of fire.

FIRE FIGHTING Alert Emergency Responders and tell them location and nature of hazard.

May be violently or explosively reactive.

Wear full body protective clothing with breathing apparatus.


Consider evacuation (or protect in place).

Fight fire from a safe distance, with adequate cover.

If safe, switch off electrical equipment until vapor fire hazard removed.

Use water delivered as a fine spray to control fire and cool adjacent area.

Avoid spraying water onto liquid pools.

DO NOT approach containers suspected to be hot.

Cool fire exposed containers with water spray from a protected location.

If safe to do so, remove containers from path of fire.

Safet Health


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Safety -Health SWALLOWED

IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBL E,

WITHOUT DELAY.

Where Medical attention is not immediately available or where the patient is

more than 15 minutes from a hospital or unless instructed

otherwise:

For advice, contact a Poisons Information Center or a doctor.

Urgent hospital treatment is likely to be needed.

If conscious, give water to drink.

INDUCE vomiting with fingers down the back of the throat, ONLY IFCONSCIOUS. Lean patient forward or place on left side (head-down position, if

possible) to maintain open airway and prevent aspiration.

NOTE: Wear a protective glove when inducing vomiting by mechanical means.

In the mean time, qualified first-aid personnel should treat the patient following

observation and employing supportive measures as

indicated by the patient's condition. If the services of a medical officer or medical doctor are readily available, the

patient should be placed in his/her care and a copy of the

MSDS should be provided. Further action will be the responsibility of the medical

specialist.

If medical attention is not available on the worksite or surroundings send the

patient to a hospital together with a copy of the MSDS.

Safety Health


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Safety -Health EYE

If this product comes in contact with the eyes:

Wash out immediately with fresh running water.

Ensure complete irrigation of the eye by keeping eyelids apart and away from eye andmoving the eyelids by occasionally lifting the upper and lower lids.

If pain persists or recurs seek medical attention.

Removal of contact lenses after an eye injury should only be undertaken by skilled

personnel.

SKIN

If skin contact occurs: Immediately remove all contaminated clothing, including footwear

Flush skin and hair with running water (and soap if available).

Seek medical attention in event of irritation.

INHALED If fumes or combustion products are inhaled remove from contaminated area.

Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where

possible, prior to initiating first aid procedures.

Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-

valve mask device, or pocket mask as trained.

Perform CPR if necessary.

Transport to hospital, or doctor.

Safety Health


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Safety -Health BASIC TREATMENT

Establish a patent airway with suction where necessary.

Watch for signs of respiratory insufficiency and assist ventilation as necessary.

Administer oxygen by non-rebreather mask at 10 to 15 l/min.

Monitor and treat, where necessary, for pulmonary edema .

Monitor and treat, where necessary, for shock.

Anticipate seizures .

DO NOT use emetics. Where ingestion is suspected rinse mouth and give up to 200 ml water

(5 ml/kg recommended) for dilution where

patient is able to swallow, has a strong gag reflex and does not drool. ADVANCED TREATMENT

Consider orotracheal or nasotracheal intubation for airway control in unconscious patient or

where respiratory arrest has occurred.

Positive-pressure ventilation using a bag-valve mask might be of use.

Monitor and treat, where necessary, for arrhythmias.

Start an IV D5W TKO. If signs of hypovolemia are present use lactated Ringers solution.Fluid overload might create complications.

Drug therapy should be considered for pulmonary edema.

Hypotension with signs of hypovolemia requires the cautious administration of fluids. Fluid

overload might create complications.

Treat seizures with diazepam.

Proparacaine hydrochloride should be used to assist eye irrigation.

Safety Environment


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Safety -Environment MINOR SPILL

Remove all ignition sources.

Clean up all spills immediately.

Avoid breathing vapors and contact with skin and eyes.

Control personal contact by using protective equipment.

Contain and absorb small quantities with vermiculite or other absorbent material.

Wipe up.

Collect residues in a flammable waste container.

WARNING: Never use dry, powdered hypochlorite or other strong oxidizer for Mercaptan

spills, as auto-ignition can occur.

Safety Environment


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Safety -Environment MAJOR SPILL

Clear area of personnel and move upwind.

Alert Emergency Responders and tell them location and nature of hazard.

May be violently or explosively reactive. Wear full body protective clothing with breathing apparatus.


Consider evacuation.

No smoking, naked lights or ignition sources.

Increase ventilation.

Stop leak if safe to do so.

Water spray or fog may be used to disperse / absorb vapor.

Contain spill with sand, earth or vermiculite.

Use only spark-free shovels and explosion proof equipment.

Collect recoverable product into labeled containers for recycling.

Absorb remaining product with sand, earth or vermiculite.

Collect solid residues and seal in labeled drums for disposal.

Wash area and prevent runoff into drains.

If contamination of drains or waterways occurs, advise emergency services.

Use extreme caution to avoid a violent reaction.

Following material can be use to collect major spill;

Wood fiber particulate

Absorbent clay (Bentonite) - particulate

Polypropyleneparticulate

PERSONAL PROTECTION


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PERSONAL PROTECTION EYE

Safety glasses with side shields.

Chemical goggles.

Contact lenses pose a special hazard; soft lenses may absorb irritants and all

lenses concentrate them. DO NOT wear contact lenses.

HANDS/FEET

Wear chemical protective gloves, eg. PVC.

Wear safety footwear or safety gumboots, eg. rubber.

Suitability and durability of glove type is dependent on usage. Important factors

in the selection of gloves include: such as: frequency and duration of contact,

chemical resistance of glove material,

glove thickness and dexterity

Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739).

When prolonged or frequently repeated contact may occur, a glove with a

protection class of 5 or higher (breakthrough time greater than 240 minutes

according to EN 374) is recommended. When only brief contact is expected, a glove with a protection class of 3 or higher

(breakthrough time greater than 60 minutes according to EN 374) is

recommended.

Contaminated gloves should be replaced.

Gloves must only be worn on clean hands. After using gloves, hands should be

washed and dried thoroughly. Application of a non-perfumed moisturizer isrecommended.

PERSONAL PROTECTION


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PERSONAL PROTECTION Personal Protection Equipment

Overalls.

PVC Apron.

PVC protective suit may be required if exposure severe.

Eyewash unit.

Ensure there is ready access to a safety shower.

Some plastic personal protective equipment (PPE) (e.g. gloves, aprons,

overshoes) are not recommended as they may produce static electricity.

For large scale or continuous use wear tight-weave non-static clothing (no

metallic fasteners, cuffs or pockets), non sparking safety footwear.


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HANDLING & STORAGE

Ethyl Mercaptan

Handling


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Handling Containers, even those that have been emptied, may contain explosive vapors.

Do NOT cut, drill, grind, weld or perform similar operations on or near containers.

Contains low boiling substance:

Storage in sealed containers may result in pressure buildup causing violent rupture of containers not rated

appropriately. Check for bulging containers.

Vent periodically

Always release caps or seals slowly to ensure slow dissipation of vapors

DO NOT allow clothing wet with material to stay in contact with skin

Avoid all personal contact, including inhalation.

Wear protective clothing when risk of exposure occurs.

Use in a well-ventilated area.

Prevent concentration in hollows and sumps.

DO NOT enter confined spaces until atmosphere has been checked.

Avoid smoking, naked lights, heat or ignition sources.

When handling, DO NOT eat, drink or smoke.

Vapor may ignite on pumping or pouring due to static electricity.

DO NOT use plastic buckets.

Earth and secure metal containers when dispensing or pouring product.

Use spark-free tools when handling. Avoid contact with incompatible materials.

Keep containers securely sealed.

Avoid physical damage to containers.

Always wash hands with soap and water after handling.

Work clothes should be laundered separately.

Use good occupational work practice.

Observe manufacturer's storing and handling recommendations. Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions.

Storage


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Storage RECOMMENDED STORAGE METHODS

Packing as supplied by manufacturer. Plastic containers may only

be used if approved for flammable liquid.

Check that containers are clearly labeled and free from leaks.

For low viscosity materials

Drums and jerry cans must be of the non-removable head type.

Where a can is to be used as an inner package, the can must

have a screwed enclosure. Where combination packages are used, and the inner packages are

of glass, there must be sufficient inert cushioning material in contact

with inner and outer packages,

In addition, where inner packaging are glass and contain liquids of

packing group I there must be sufficient inert absorbent to absorbany,

spillage, unless the outer packaging is a close fitting molded plastic

box and the substances are not incompatible with the plastic.

Storage


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Storage STORAGE REQUIREMENTS

Store in original containers in approved flame-proof area.

No smoking, naked lights, heat or ignition sources.

DO NOT store in pits, depressions, basements or areas where vapors may

be trapped.


Store away from incompatible materials in a cool, dry well ventilated area.

Protect containers against physical damage and check regularly for leaks.

Observe manufacturer's storing and handling recommendations.


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NITROGEN GAS(INERT GAS)


Specification


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SpecificationHeading Description

Trade Name Nitrogen

Chemical Name Nitrogen

Synonyms Nitrogen (dot); Nitrogen gas; Nitrogen NF, LIN,

Cryogenic Liquid Nitrogen, Liquid Nitrogen

State (@ 25oC) Gas Specific Gravity @ 20 C 0.839

Boiling Point (F) -320.4 Gas Density (lb/ft3) 0.072

Flash Point (F) Inert Molecular Weight 28.02

Auto-ignition Temp (F) Nil NFPA CODE (Gas)

Lower Exp. Limit (%) Nil

Upper Exp. Limit (%) Nil

00

0

SA

MSDS


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MSDS


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HAZARDS(PHYSICAL, HEALTH & ENVIRONMENT)

Nitrogen Gas

Hazard -Physical


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Hazard -Physical

Available in high pressure containers.

Sudden release of gas may cause; Frosting,

Skin or flash damage,

Asphyxiation.

Hazard -Health


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Hazard -Health

EYE

Contact with rapidly expanding gas may cause burns or frostbite.Contact with cryogenic liquid can cause frostbite and cryogenic

burns.

SKIN

Contact with rapidly expanding gas may cause burns or frostbite.

Contact with cryogenic liquid can cause frostbite and cryogenicburns.

Inhalation Acts as a simple asphyxia. Nitrogen is nontoxic, but may cause

suffocation by displacing the oxygen in air. Lack of sufficientoxygen can cause serious injury or death.

Ingestion Ingestion is not a normal route of exposure for gases. Contact

with cryogenic liquid can cause frostbite and cryogenic burns

Hazard -Environment


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Hazard Environment

No known significant effects or critical hazards.

No data on toxicity to environment is available.


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SAFETY(PHYSICAL, HEALTH & ENVIRONMENT)

Nitrogen Gas

Safety -Physical


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Safety -Physical General

Plenty of ventilation helps decimates Nitrogen Gas quickly in to

the air.

FIRE FIGHTING

Being inert gas does aggravates fire.

Fire protection is considered by surrounding possible

combustion material

Safety -Health


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Safety -Health EYE

If this product comes in contact with the eyes:

Wash out immediately with fresh running water.

Ensure complete irrigation of the eye by keeping eyelids apart and away from eye andmoving the eyelids by occasionally lifting the upper and lower lids.

If pain persists or recurs seek medical attention.

Removal of contact lenses after an eye injury should only be undertaken by skilled

personnel.

SKIN

If skin contact occurs: Immediately remove all contaminated clothing, including footwear

Flush skin and hair with running water (and soap if available).

Seek medical attention in event of irritation.

INHALED If fumes or combustion products are inhaled remove from contaminated area.

Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where

possible, prior to initiating first aid procedures.

Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-

valve mask device, or pocket mask as trained.

Perform CPR if necessary.

Transport to hospital, or doctor.

Safety -Health


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Safety -Health BASIC TREATMENT

Establish a patent airway with suction where necessary.

Watch for signs of respiratory insufficiency and assist ventilation as necessary.

Administer oxygen by non-rebreather mask at 10 to 15 l/min. Monitor and treat, where necessary, for pulmonary edema .

Monitor and treat, where necessary, for shock.

Anticipate seizures .

DO NOT use emetics. Where ingestion is suspected rinse mouth and give up to 200 ml water

(5 ml/kg recommended) for dilution where

patient is able to swallow, has a strong gag reflex and does not drool. ADVANCED TREATMENT

Consider orotracheal or nasotracheal intubation for airway control in unconscious patient or

where respiratory arrest has occurred.

Positive-pressure ventilation using a bag-valve mask might be of use.

Monitor and treat, where necessary, for arrhythmias.

Start an IV D5W TKO. If signs of hypovolemia are present use lactated Ringers solution.

Fluid overload might create complications.

Drug therapy should be considered for pulmonary edema.

Hypotension with signs of hypovolemia requires the cautious administration of fluids. Fluid

overload might create complications.

Treat seizures with diazepam.

Proparacaine hydrochloride should be used to assist eye irrigation.

Safety -Environment


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Safety -Environment MINOR SPILL

Remove all ignition sources.

Clean up all spills immediately.

Avoid breathing vapors and contact with skin and eyes.

Control personal contact by using protective equipment.

Contain and absorb small quantities with vermiculite or other absorbent material.

Wipe up.

Collect residues in a flammable waste container.

WARNING: Never use dry, powdered hypochlorite or other strong oxidizer for Mercaptan

spills, as auto-ignition can occur.

PERSONAL PROTECTION


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PERSONAL PROTECTION Personal Protection Equipment

Overalls.

PVC Apron.

PVC protective suit may be required if exposure severe.

Eyewash unit.

Ensure there is ready access to a safety shower.

Some plastic personal protective equipment (PPE) (e.g. gloves, aprons,overshoes) are not recommended as they may produce static electricity.

For large scale or continuous use wear tight-weave non-static clothing (no

metallic fasteners, cuffs or pockets), non sparking safety footwear.


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HANDLING & STORAGE

Nitrogen Gas

Handling


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Handling Containers, even those that have been emptied, may contain explosive vapors.

Do NOT cut, drill, grind, weld or perform similar operations on or near containers.

Contains low boiling substance:

Storage in sealed containers may result in pressure buildup causing violent rupture of containers not rated

appropriately.

Check for bulging containers.

Vent periodically

Always release caps or seals slowly to ensure slow dissipation of vapors

DO NOT allow clothing wet with material to stay in contact with skin

Avoid all personal contact, including inhalation.

Wear protective clothing when risk of exposure occurs.

Use in a well-ventilated area.

Prevent concentration in hollows and sumps.

DO NOT enter confined spaces until atmosphere has been checked.

Avoid smoking, naked lights, heat or ignition sources.

When handling, DO NOT eat, drink or smoke.

Vapor may ignite on pumping or pouring due to static electricity.

DO NOT use plastic buckets.

Earth and secure metal containers when dispensing or pouring product.

Use spark-free tools when handling. Avoid contact with incompatible materials.


Avoid physical damage to containers.

Always wash hands with soap and water after handling.

Work clothes should be laundered separately.

Use good occupational work practice.


Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions.

Storage


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Storage RECOMMENDED STORAGE METHODS

Packing as supplied by manufacturer. Plastic containers may only

be used if approved for flammable liquid.

Check that containers are clearly labeled and free from leaks.

For low viscosity materials

Drums and jerry cans must be of the non-removable head type.

Where a can is to be used as an inner package, the can must

have a screwed enclosure. Where combination packages are used, and the inner packages are

of glass, there must be sufficient inert cushioning material in contact

with inner and outer packages,

In addition, where inner packaging are glass and contain liquids of

packing group I there must be sufficient inert absorbent to absorbany,

spillage, unless the outer packaging is a close fitting molded plastic

box and the substances are not incompatible with the plastic.

Storage


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Storage STORAGE REQUIREMENTS

Store in original containers in approved flame-proof area.

No smoking, naked lights, heat or ignition sources.

DO NOT store in pits, depressions, basements or areas where vapors may

be trapped.


Store away from incompatible materials in a cool, dry well ventilated area.

Protect containers against physical damage and check regularly for leaks.



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THE END



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THANK YOU

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