hints from the daimon project - helcom 6-2018-539...2018/04/05 · hints from the daimon project...
TRANSCRIPT
Hints from the DAIMON project
M.Sc. MICHAŁ CZUB | Institute of Oceanology, Polish Academy of Sciences
Prof. JACEK BEŁDOWSKI
HELCOM SUBMERGED 04.05.2018
Munition Status Examination
Modelling of possible release
Pollution of sediments and water
Impact on biota assessment
Risk categorization procedure
PILOTSTUDIES
S/YOceania,R/VWaltherHerwigIII,R/VAranda
SURVEYS
S/YOceania,R/VImor,R/VWaltherHerwigIII,R/VLittorina,R/VAranda,R/VAkademik NikolayStrakhov
MAINAREASOFINTEREST
BornholmDeep– CWdumpsite | Kolberger Heide - Explosivesdumpsite | Skagerrak - Wrecks
ADDITIONALAREASOFINTEREST
Gdańsk Deep– CW,GulfofFinland– Explosives
EQUIPMENT
ROV– RemotelyOperatedVehicle,AUV - AutonomousUnderwaterVehicle(+magnetometer),SSS - SideScanSonar
Progress in bottom mapping
Habitat description
CWA Dumpsites
BornholmDeep
GotlandDeep
GdańskDeep
CWDumpsites
70mdepth
Hypoxiczonesin2012
Anoxiczonesin2012
50 100 250km
0 100km25 50
Balti
cSea
Bornholm Deep
Blablabla+ corrosion studies
+ passive samplers
Kolberger Heide
+ caging experiments
+ biomarkers research
Skagerrak
+ NEMO – ocean model
+ VRAKA model
+ bioaccummulation
CWA detection in sediments + High Res. Model
Initial state and situation after about ~100 seconds of estimated potential leakage.Horizontal and vertical axes represent distance in relative units. Color scale can beinterpreted as the level of contamination.
Passive samplers
March – April 2018 (approx., 28 days)
Daphnia magna
Phenyldichlorarsine – Pfiffikus – 50% – LC50 = 125 µg∙dm⁻³
Diphenylchlorarsine – Clark I – 35% – LC50 = 38,2 µg∙dm⁻³ ± 1,507
Triphenylarsine – TPA – 5% – NOEC = 4 mg∙dm⁻³ (max. solubility)
Arsine trichloride– 5% – LC50 = 10 mg∙dm⁻³
Arsine oil – LC50 = 110 µg∙dm⁻³ (35% ∙ 110 = 38,5 µg∙dm⁻³)
Lewisite A, B, C – LC50 = 11,731 µg∙dm⁻³
Adamsite – LC50 = 46,726 µg∙dm⁻³
Lewisite, Clark I, Adamsite, PDCA and Arsine Oil remain very toxic when transferred into aquatic systems.
TPA has no toxic effects, while AsCl3 is potentially harmful.
Toxicity studies
Fish studies
DSS – Decision Supporting System
https://shared.egeos.de/amucad/english/#g=1&p=map
Blimp
Next DAIMON meeting
Klajpeda / Lithuania: 26.09.2018 – 28.09.2018
Thank you.