hono retrievals in beijing and xianghe f. hendrick 1, k. clémer 1,*, c. fayt 1, c. hermans 1, y....
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HONO retrievals in Beijing and Xianghe
F. Hendrick1, K. Clémer1,*, C. Fayt1, C. Hermans1, Y. Huan1,2, T. Vlemmix1, P. Wang2, and M. Van Roozendael1
1Belgian Institute for Space Aeronomy (IASB-BIRA), Brussels, Belgium
2Institute of Atmospheric Physics, Beijing, China
*Now at Institute of Astrophysics, KU Leuven, Belgium
NORS/NDACC UV-VIS meeting, Brussels, 3-4 July 2012 1
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Nitrous acid (HONO) in the troposphere
• HONO is a source of OH radicals through its photolysis, especially in the early morning:
HONO + h → OH + NO
• HONO sources and sinks:
Li et al., ACP, 2012
NORS/NDACC UV-VIS meeting, Brussels, 3-4 July 2012 2
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Why it is important to measure HONO ?
•Formation mechanisms not well understood and poorly quantified, especially during daytime
Realistic simulations of HONO levels are difficult
Measurements can contribute to improve the modeling of the HONO and OH chemistry
•HONO measurements are sparse in time because mainly resulting from field campaigns
Continuous MAX-DOAS measurements of HONO can be highly valuable
NORS/NDACC UV-VIS meeting, Brussels, 3-4 July 2012 3
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Observation sites
Institute of Atmospheric Physics (06/2008 - 04/2009)
(03/2010 till now )
NORS/NDACC UV-VIS meeting, Brussels, 3-4 July 2012 4
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DOAS settings
• The following settings are used for the DOAS analysis:
− Fitting window: 337-375 nm
− Fitted species: HONO, NO2, O3, O4, BrO, HCHO, Ring
effect
− HONO XS: Stutz et al. (2000) at 296 K
• For each scan, DSCDoff-axis = SCDoff-axis – SCDzenith of the scan used
by the profiling algorithm
NORS/NDACC UV-VIS meeting, Brussels, 3-4 July 2012 5
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MAX-DOAS retrieval algorithm
MAXDOAS measurements
LIDORT
O4 DSCDDI
HONO DSCD
DOAS
DSCDDI
Weighting functions
Apriori
Atm: P,TSurface albedoTrace gas: , profileAerosol: optical prop.
Optimal estimation
Aerosol vertical extinction profiles
Tropospheric HONO vertical profiles
Clémer et al., AMT, 2010
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Aerosol extinction profile retrievalBeijing 21/01/2009 AM
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Comparison with AERONET data
NORS/NDACC UV-VIS meeting, Brussels, 3-4 July 2012 8
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HONO vertical profile retrievalBeijing 21/01/2009 AM
A priori:
SH
z
HONO eSH
VCD
with SH = 0.5 km
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Impact of SH on the retrieval (1)Beijing 21/01/2009 AM
A priori Retrieval
NORS/NDACC UV-VIS meeting, Brussels, 3-4 July 2012 10
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Impact of SH on the retrieval (2)Beijing 21/01/2009
NORS/NDACC UV-VIS meeting, Brussels, 3-4 July 2012 11
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HONO VCD time-series
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HONO VCD time-series
HONO VCD
Tropospheric NO2 VCD (geometrical approximation)
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HONO and NO2 VCD correlation
Beijing
Xianghe
NORS/NDACC UV-VIS meeting, Brussels, 3-4 July 2012 14
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Diurnal variation of surface HONO vmr (1)
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Comparison to CAREBeijing2006 data (1)
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Comparison to CAREBeijing2006 data (2)
CAREBeijing2006 HONO measurements at Yufa: in-situ long-path absorption photometry (LOPAP); see Lu et al., ACPD, 2012
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Concluding remarks
•First HONO retrievals from MAX-DOAS observations at Beijing and Xianghe show promising results
HONO columns larger at Beijing
Good correlation between HONO and NO2 tropospheric columns, especially in the afternoon
Diurnal variation of HONO vmr in the 0-200m altitude range; Good agreement with CAREBeijing2006 data
•On-going work:
NO2 profiles retrieval; correlation HONO and NO2 vmr in the 0-200m altitude range
Investigation of the [HONO]/[NO2] ratio
Estimation of the OH production from [HONO] and photolysis rate
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