interim sanitary landfill groundwater monitoring report …/67531/metadc698428/m2/1/high_res... ·...

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WSRC-TR-97-0200 Unclassified INTERIM SANITARY LANDFILL GROUNDWATER MONITORING REPORT (U) Key Words barium LFW wells l,l,l-trichloroethane trichlorofluoromethane zinc First and Second Quarters I997 Publication Date: July 1997 Westinghouse Savannah River Company Savannah River Site Aiken, SC 29808 Prepared for the U.S. Department of Energy under Control Contract No. DE-AC09-89SR18035

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Page 1: INTERIM SANITARY LANDFILL GROUNDWATER MONITORING REPORT …/67531/metadc698428/m2/1/high_res... · WSRC-TR-97-0200 Unclassified INTERIM SANITARY LANDFILL GROUNDWATER MONITORING REPORT

. WSRC-TR-97-0200 Unclassified

INTERIM SANITARY LANDFILL GROUNDWATER MONITORING

REPORT (U)

Key Words barium LFW wells l,l,l-trichloroethane trichlorof luoromethane zinc

First and Second Quarters I997

Publication Date: July 1997

Westinghouse Savannah River Company Savannah River Site Aiken, SC 29808

Prepared for the U.S. Department of Energy under Control Contract No. DE-AC09-89SR18035

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WSRC-TR-97-0200 Unclassified

Prepared by

Environmental Protection Department Environmental Geochemistry Group

Westinghouse Savannah River Company Aiken, SC

and

Exploration Resources, Inc. Athens, GA

Interim Sanitary Landfill ii First and Second Quarters 1997

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DISCLAIMER

This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, make any warran@, expm or implied, or assumes any legal liabili- ty or mpomiity for the accuracy, completeness, or useiulness of any infomtion, appa- ratus, product, or p r o ~ s s disdosed, or represents that its use would not infringe privately owned rights Reference heroin to any spedfic commercial product, pmcgs, or service by trade name, trademark, manufactum, or otherwise daes not necessarily constitute or imply its endorsement, recommeodation, or favoring by the United States Government or any agency themf. The views and opinions of authors expressed herein do not necessar- ily state or reflect those of the United States Government or any agency thereof.

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DISCLAIMER

Portions of this document may be illegible electronic image products. Images are produced from the best available original document.

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WSRC-TR-97-0200 Unclassified

Contents Page

Key to Reading the Table ............................................................................................................... 1

Appendix A t a n d a r d s ............................................................................................................. A-1

Appendix B-Flagging Criteria .................................................................................................. B-1

Interim Sanitary Landfill iii First and Second Quarters 1997

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Interim Sanitary Landfill

WSRC-TR-97-0200 Unclassified

THIS PAGE LEFT BLANK INTENTIONALLY.

First and Second Quarters 1997

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Key to Reading the Tables The following abbreviations may appear in the data tables:

Constituents

Sp. conductance

Laboratories

EM

ES EX GE or GP QR TL WA

Sampling Codes

B C D E I L

N P

S W

X

Sampling Methods

B 0 P S v

Units

mg/L msl MSL NTU pCiL pCi/mL PH

specific conductance

WSRCTR-97-0200 Unclassified

Environmental Protection DepartmenVEnvironmental Monitoring

QST Environmental, Inc. EMAX Laboratories, Inc. General Engineering Laboratories, Inc. Quanterra, Inc. Triangle Laboratories, Inc. Recra LabNet Philadelphia

Section (EPD/EMS) Laboratory

blank sample was collected well was pumping continuously well was dry equipment blank was collected well went dry during sampling; insufficient water to collect all samples well went dry before sampling began; only depth to water can be

well was not stabilized before sampling began inaccessibility or mechanical failure prevented sample collection and

no water in standpipe; for water-level events only purged water must be containerized; only water-level measurements

well went dry during purging; samples collected after well recovered

determined

field analysis of the water

were obtained

sample collected using an open-bucket bailer sample collected by method other than bailer or pump sample collected using a bladder pump sample collected using a single-speed centrifugal downhole pump sample collected using a variable-speed pump

milligrams per liter mean sea level million structures per liter nephelometric turbidity unit picocuries per liter picocuries per milliliter pH unit

Interim Sanitary Landfill 7 First and Second Quarters 7997

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Other

cs DF E H Mod PDWS PVC ST TOC

WSRGTR-97-0200 Unclassified

micrograms per liter microsiemens per centimeter

carbon steel dilution factor column in data tables exponential notation (e.g., l.lE-09 = 1.1 x lo-' = 0.0000000011) ho/ding time column in data tables modifiercolumn in data tables Primary Drinking Water Standard polyvinyl chloride exceeded standard column in data tables top of casing

Results below Detection For radiological analyses, the analytical result field contains the result recorded on the analytical instrument and reported by the laboratory, even if it is negative. For nonradiological analyses, if the analyte is not detected, the sample-specific estimated quantitation limit (EQL) is entered into the result field and is reported with a less than [e] sign. The EQL is defined as the lowest concentration that can be achieved reliably within specified limits of precision and accuracy during routine laboratory operating conditions. The sample-specific EQL is modified for sample concentration or dilution or unusual aliquot size that affects analytical sensitivity.

Holding Times Standard analytical methods include a limit, called holding time, on the maximum elapsed time between sample collection and extraction or analysis by the laboratory. In the data tables, a large bullet (-) in the H (holding time) column indicates that holding time was exceeded. Analyses performed beyond holding times may not yield valid results. The South Carolina Department of Health and Environmental Control (SCDHEC) allows only 15 minutes to elapse between sampling and analysis for pH. Thus, only field pH measurements can meet the holding time criterion; laboratory pH analyses always will exceed it.

The laboratory procedure used for the determination of specific conductance allows one day to elapse between sampling and analysis. Thus, laboratory specific conductance measurements may exceed the holding time criterion.

Data Rounding A constituent result in the analytical results tables that is not marked in the STcolumn but appears to equal an Appendix A standard is below the standard in the database. Values stored in the database contain more significant digits than the reported results. Apparent discrepancies in the tables are due to the rounding of reported results.

Data Qualification The contract laboratories submit sample- or batch-specific quality assurance/quality control information either at the same time as analytical results or in a quarterly summary. Properly defined and used data modifiers (also referred to as qualifiers) can be a key component in assessing data usability. Modifiers designed by EPDIEMS and provided to the primary laboratories are defined below. These modifiers appear in the data tables under the column Mod. All lettered modifiers except €are based on EPA's STORET codes.

Interim Sanitary Landfill 2 First and Second Quarters 1997

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WSRC-TR-97-0200 Unclassified

Modifiers

(Blank) E

I

J

L

M R

T U

V Y

1 2 3

Data are not qualified. Numbers should be interpreted exactly as reported. The detected result is between the sample-specific EQL and the method

The value in the result field is the instrument reading, not the sample

Value is estimated because quantitation in the sample or in associated quality

Value is off-scale high. The actual value is not known but is known to be

Presence of the analyte is verified but not quantified. Result was rejected because performance requirements in the sample

Analyte was not detected; if present, it was below the criteria for detection. Material analyzed for but not detected. Analytical result reported is less than

Analyte was detected in an associated method blank. Result was obtained from an unpreserved or improperly preserved sample.

Result may be an underestimation of the true value due to analytical bias. Result may be an overestimation of the true value due to analytical bias. The associated result may be of poor precision (high variability) due to

detection limit.

quantitation limit. Always used with the result qualifier U.

control samples did not meet specifications.

greater than the value shown.

analysis or associated quality control analyses were not met.

the sample quantitation limit.

Data may not be accurate.

analytical bias.

Note: These are only some of the qualifiers present in the database. All modifiers associated with the data are published in the result tables of EPD/EMS’ quarterly groundwater monitoring reports, the official repository of the data.

Interim Sanitary Landfill 3 First and Second Quarters 1997

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WSRC-TR-97-0200 Unclassified

Table 1. Groundwater Monitoring Results for Individual Wells WELL LFW 28 SRS Coord. LatiLondmde

N86079.6 €45555.3

SAMPLE DATE

FIELD DATA

33.290475 "N 81.714056 "W

P m r

Water elevation

Sp. conductance Water temperature Alkalinity as CaC03 Turbidity Volumes purged Sampling code

PH

ANALYTICAL DATA

Parametel

Acetone Acrylonitrile Antimony, total recoverable Arsenic, total recoverable Barium, total recoverable Benzene beta-Benzene hexachloride Beryllium, total recoverable Bromochloromethane Bromodichloromethane Bromoform Bromomethane Cadmium, total recoverable Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroethene (Vinyl chloride) Chloroform Chloromethane Chromium, total recoverable Cobalt, total recoverable Copper, total recoverable Dibromochloromet hane 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Dibromomethane Di-n-butyl phthalate 1,2-DichIorobenzene 1 ,rl-Dichlorobenzene trans-1 ,4-Dichloro-2-butene 1.1 -Dichloroethane 1.2-Dichloroethane 1, I -Dichloroethylene cis-l,2-Dichloroethylene trans-l,2-Dichloroethylene Dichloromethane 1,2-Dichloropropane cis- 1,3-DichIoropropene trans-1.3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane (Methyl iodide) Lead, total recoverable Methyl ethyl ketone Methyl isobutyl ketone Nickel, total recoverable

Selenium, total recoverable PH

03/04/97

162.7 5.2 26 26.0 2 4 0.071 X

~ 7 . 0 <5.0 c27 <40

20 4.0

c1.6 (5.0 <5.0 c5.0 <IO 4.7 <5.0 c5.0 <5.0 d o 4 0 c5.0 c10 e7.0

0.47 31

<5.0 <5.0 c5.0 4 .0 4 .2 q5.0 <5.0 420 <5.0 <5.0 4.0 <5.0 c5.0 4.0 c5.0 ~ 5 . 0

<5.0 c10 <5.0

10 < lo < lo c26

5.5 c66

Screen Zone Elevation

162.1-141.1 ft rnsl

DE 1 1 1 1 1 1

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

Mod V

V

J

J

- ST H - 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0

0 0 0

Note: See Appendix B for flagging criteria. 0 = exceeded holding time. m = exceeded standard.

Interim Sanitary Landfill 4

TOD of Casing

192.4 ft msl

- Lab

WA WA WA WA WA WA

WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA

WA WA WA WA WA WA WA WA WA

Casino Screenzone

4'PVC s Upper Steed Pond

ft msl PH pS/cm "C m9k NTU well vols

First and Second Quarters 1997

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WELL LFW 28 (cont.) Silver, total recoverable Specific conductance Styrene 1.1 ,I ,Z-Tetrachloroethane 1 , I ,2,2-Tetrachloroethane Tetrachloroethylene Thallium, total recoverable Toluene 1 ,I ,1-Trichloroethane 1 , 1 ,2-Trichloroethane Trichloroethylene Trichlorofluoromethane 1,2,3-TrichIoropropane Vanadium, total recoverable Vinyl acetate Xylenes Zinc, total recoverable

4.0 32

c5.0 c5.0 4.0 4.0 c55 4.0 4.0 4.0 4.0 4.0 4.0 4 . 9 c10 4.0

35

1 1 1 1 1 1 1 1 1 1 1 I 1 1 1 1 1

Note: See Appendix B for flagging criteria. 0 = exceeded holding time. m = exceeded standard.

Interim Sanitary Landfill

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

J m 0

5

WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA

First and Second Quarters 1997

WSRC-TR-97-0200 Unclassified

~ ~ ~ ~

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WELL LFW 32 SRS Coord. LatLonaitude

N85836.8 33.288927 "N E44935.9 81.715214"W

SAMPLE DATE

FIELD DATA

Parameter

Water elevation

Sp. conductance Water temperature Alkalinity as CaC03 Turbid@ Volumes purged Sampling code

ANALYTICAL DATA

PH

Parameter

Acetone Acrylonitrile Antimony, total recoverable Arsenic, total recoverable Barium, total recoverable Benzene beta-Benzene hexachloride Beryllium, total recoverable Bromochloromethane Bromodichloromethane Bromoform Bromomethane Cadmium, total recoverable Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroethene (Vinyl chloride) Chloroform Chloromethane Chromium, total recoverable Cobalt, total recoverable Copper, total recoverable Dibromochloromethane 1,2-Dibromo-3-chloropropane 1,P-Dibromoethane Dibromomethane

Di-n-butyl phthalate 1 ,2-Dichlorobenzene 1 .4-Dchlorobenzene trans-l,4-Dichloro-2-butene 1 ,I-Dichloroethane 1 ,P-Dichloroethane 1 .I -Dichloroethylene cis-I ,P-Dichloroethylene trans-l,2-Dichloroethylene Dichloromethane 1 ,P-Dichloropropane cis-1.3-Dichloropropene trans-l,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane (Methyl iodide) Lead, total recoverable Methyl ethyl ketone Methyl isobutyl ketone Nickel, total recoverable DH

1Q97

c4.0 c5.0 c27 4 0 6.8

c5.0

c1.6 c5.0 c5.0 c5.0 c10 4 .7 45.0 c5.0 c5.0 c10 4 0 c5.0 c10 c7.0 c4.5 4.7

c5.0 c5.0 4.0 c5.0 c1.6 c5.0 45.0 c20 c5.0 c5.0 c5.0 c5.0 c5.0 c2.3 c5.0 c5.0

c5.0 c10 c5.0 4.9

c10 < lo c26

5.1 Selenium, total recoverable <66

03/04/97

- 1 Q97

161.8 4.4 22 25.0 1 0 8.4

Screen Zone Elevation

165.3-144.3 ft msl

TOD of Casinq

223.7 ft msl

- 2Q97

&&g Pumq ScreenZone

4'PVC s Upper Steed Pond

- Unit

R msl PH pS/cm "C m s n NTU well vols

- DF

1 1 1 1 1 1

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

V

V

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

J

J

0 0 0 0 0 0 0

e o 0

- Lab

WA WA WA WA WA WA

WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA

WA WA WA WA WA WA WA WA WA

2Q97

Note: See Appendix B for flagging criteria. 0 = exceeded holding time.

= exceeded standard.

Interim Sanitary Landfill 6 first and Second Quarters 7997

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WELL LFW 32 (cont.) Silver, total recoverable Specific conductance Styrene 1,1.1,2-Tetrachloroethane 1,1.2,2-Tetrachloroethane Tetrachloroethylene Thallium, total recoverable Toluene 1 ,l,l-Trichloroethane 1.1.2-Trichloroethane Trichloroethylene Trichlorofluoromethane 1,2,3-Tnchloropropane Vanadium, total recoverable Vinyl acetate Xylenes Zinc, total recoverable

-5.0 22 -5.0 4.0 4.0 4.0 e55 4.0

4.1 c5.0 4.0

4.0 <6.9 4 0 4.0

44.4

8.8

1 1 I 1 1 1 1 1 1 J 1 1 1 . 1 1 1 1 1 J

0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 2 WA 0 WA 0 WA 0 WA 0 WA 0 WA

Note: See Appendix B for flagging criteria. 0 = exceeded holding time. m = exceeded standard.

Interim Sanitary Landfill 7

WSRC-TR-97-0200 Unclassified

First and Second Quarters 1997

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WELL LFW 43C SRS Coord. LaVLonaitude

N86480.6 33.290838 "N E45234.9 81.715679 "W

SAMPLE DATE

FIELD DATA

Parameter

Water elevation PH Sp. conductance Water temperature Alkalinity as CaC03 Turbidity Volumes purged Sampling code

ANALYTICAL DATA

Parameter

Acetone Acrylonitrile Antimony, total recoverable Arsenic, total recoverable Barium, total recoverable Benzene beta-Benzene hexachloride Beryllium, total recoverable Bromochloromethane Bromodichloromethane Bromoform Bromomethane Cadmium, total recoverable Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroethene (Vinyl chloride) Chloroform Chloromethane Chromium, total recoverable Cobalt, total recoverable Copper. total recoverable Dibromochloromelhane 1,2-Dibromo-3-chloropropane 1.2-Dibromoethane Dibromomethane Di-n-butyl phthalate 1,2-Dichlorobenzene 1 ,4-Dichlorobenzene trans-l,4-Dichloro-2-butene 1 ,I-Dichloroethane 1,2-Dichloroethane 1,l-Dichloroethylene cis-l,2-Dichloroethylene trans-1.2-Dichloroethylene Dichloromethane 1,2-DichIompropane cis- 1,3-DichIoropropene trans-i,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane (Methyl iodide) Lead, total recoverable Methyl ethyl ketone Methyl isobutyl ketone Nickel, total recoverable

Selenium, total recoverable PH

03/05/97

164.4 4.6 1 20 24.0 1 0 2.8

<6.8 4.0 c27 c40

4.0

c0.22 4.0 6.0 c5.0 c10 c4.7 <5.0 ~5.0 <5.0 <lo 410 <5.0 < lo <7.0 c4.5 4 5 -5.0 4.0 4.0 c5.0 c1.2 <5.0 4.0 <20 4.0 <5.0 4.0 4.0 4.0 <9.1 c5.0 4.0

4.0 c10 -5.0 <47 < lo < lo <26

5.3 <66

- DF

1 1 1 1

1

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

1 1 1 1 1 1 1 1 1

Note: See Appendix B for flagging criteria. e = exceeded holding time.

= exceeded standard.

interim Sanitary Landfill

WSRC-TR-97-0200 Unclassified

Screen Zone Elevation Too of Casinq Casino Puma ScreenZone

138.5-128.5 ft msl 202.6 ft msl 4'PVC s Middle Steed Pond

- 2097

- ModaST-

V 0 0 0 0

0

V 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

V 0 0 0 0 0 0 0 0 0

V 0 0 0

0 0 0 0 0 0 0

0 J e o

- Lab

WA WA WA WA

WA

WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA

WA WA WA WA WA WA WA WA WA

8

- Unit

ft msl PH VStcm "C mgfl NTU well vols

First and Second Quarters 1997

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WSRC-TU-97-0200 Unclassified

WELL LFW 43C (cont.) Silver, total recoverable Specific conductance Styrene 1,1,1,2-TetrachIoroethane 1,1,2,2-TetrachIoroethane Tetrachloroethylene Thallium, total recoverable Toluene 1.1 ,l-Trichloroethane 1,1,2-Trichloroethane Trichloroethylene Trichlorofluorornethane 1.2,3-Trichloropropane Vanadium, total recoverable Vinyl acetate Xylenes Zinc, total recoverable

c5.0 14

c5.0 c5.0 c5.0 c5.0 c55 4.0 c5.0 c5.0 c5.0 c5.0 c5.0 c6.9 <lo c5.0 C53

1 1 v 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA

Note: See Appendix B for flagging criteria. = exceeded holding time.

m = exceeded standard.

Interim Sanitary Landfill 9 First and Second Quarters 1997

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WELL LFW 430 SRS Coord. LaVLonaitude

~ a u 3 . 2 33.290771 "N E45244.5 ai.715xii ow SAMPLE DATE

flELD DATA

Parameter

Water elevation

Sp. conductance Water temperature Alkalinity as C a C 4 Turbidii Volumes purged Sampling code

ANALYTICAL DATA

Parameter

Acetone Acrylonitrile Antimony, total recoverable Arsenic, total recoverable Barium, total recoverable Benzene beta-Benzene hexachloride Beryllium, total recoverable Bromochloromethane Bromodichloromethane Bromoform Bromomethane Cadmium, total recoverable Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroethene (Vinyl chlonde) Chloroform Chloromethane Chromium, total recoverable Cobalt, total recoverable Copper, total recoverable Dibromochloromethane 1,2-Dibrorno-3-chloropropane 1,2-Dibromoethane Dibromomethane Di-n-butyl phthalate 1,P-Dichlorobenzene 1 ,CDichlorobenzene trans-1,4-Dichloro-P-butene 1,l -Dichloroethane 1,2-DichIoroethane 1 ,l-Dichloroethylene cis- 1 ,P-Dichloroethylene trans-1,2-Dichloroethylene Dichloromethane 1,P-Dichloropropane cts-l,3-Dichloropropene trans-I ,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane (Methyl iodide) Lead, total recoverable Methyl ethyl ketone Methyl isobutyl ketone Nickel, total recoverable PH Selenium. total recoverable

PH

WSRC-TR-97-0200 Unclassified

03/05

- 1 Q97

164.4

10 25.0

4.8

2 0 4.6

c14 4.0 <27 <40

6.1 4.0

~0.17 c5.0 c5.0 c5.0 C l O c4.7 4.0 e5.0 c5.0 < lo <IO 4.0 <IO c7.0 <4.5

6.4 c5.0 c5.0 <5.0 <5.0 < lo <5.0 <5.0 <PO c5.0 <5.0 45.0 c5.0 c5.0 c5.9 c5.0 c5.0

c5.0 4 0 c5.0 4 7 c10 <IO <26

c66 5.3

Note: See Appendix B for flagging criteria. 0 = exceeded holding time.

= exceeded standard.

Interim Sanitary Landfill

Pump Screenzone Screen Zone Elevation

170.9-150.9 ft msl 202.9 ft msl 4'PVC s Upper Steed Pond

TOO of Casinq

'9?

- DF

1 1 1 1 1 1

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

1 1 1 1 1 1 1 1 1

- Mod

V

V

J

V

J

STST-

0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0

* o 0

10

- Lab

WA WA WA WA WA WA

WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA

WA WA WA WA WA WA WA WA WA

- 2Q97 - Unit

ft msl

pS/cm "C

NTU well vols

PH

m s n

First and Second Quarters 1997

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WELL LFW 43D (cont.) Silver, total recoverable Specific conductance Styrene 1 , I , I ,2-Tetrachloroethane 1,1,2.2-TetrachIoroethane Tetrachloroethylene Thallium, total recoverable Toluene l,l,l-Trichloroethane 1,1,2-Trichloroethane Trichloroethylene Trichlorofluoromethane 1,2,3-TrichIoropropane Vanadium, total recoverable Vinyl acetate Xylenes Zinc, total recoverable

c5.0 12

c5.0 c5.0 c5.0 c5.0 c55 c5.0 c5.0 <5.0 c5.0 c5.0 c5.0 -4 .9 c10 c5.0

9.7

1 1 v 1 I 1 1 1 1

1 1 J

0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA

WSRC-TR-97-0200 Unclassified

Note: See Appendix B for flagging criteria. 0 = exceeded holding time.

= exceeded standard.

Interim Sanitary Landfill 11 First and Second Quarters 1997

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WELL LFW 74C SRS Coord. LaVLonaitude

N85813.8 33.289140 "N €45097.8 81.7 14743 "W

SAMPLE DATE

FIELD DATA

Parameter

Water elevation

Sp. conductance Water temperature Alkalinity as CaC03 Turbidity Volumes purged Sampling code

PH

ANALYTICAL DATA

Parameter

Acetone Acrylonitrile Antimony, total recoverable Arsenic, total recoverable Barium, total recoverable Benzene beta-Benzene hexachloride Beryllium, total recoverable Bromochloromethane Bromodihloromethane Bromoform Bromomethane Cadmium, total recoverable Carbon disulfide Carbon tetrachloride Chlorobenzene Chbroethane Chloroethene (Vinyl chloride) Chloroform Chloromethane Chromium, total recoverable Cobalt, total recoverable Copper, total recoverable Dibromochbromethane 1,2-Dibromo-3-chioropropane 1,2-Dibrornoethane Dibromomethane Di-n-butyl phthalate 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1 ,4-DichloroQ-butene 1 ,I-Dichloroethane 1,2-Dichloroethane 1.1 -Dichloroethylene cis-1.2-Dichloroethylene trans-1.2-Dichloroethylene Dichloromethane 1,2-DichIoropropane cis-1.3-Dichloropropene trans-l,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane (Methyl iodide) Lead, total recoverable Methyl ethyl ketone Methyl isobutyl ketone Nickel, total recoverable

Selenium, total recoverable PH

03/07/97

161.5 4.4 34 24.0 3 1 2.5

1Q97

c6.5 4 . 0 4 . 0 c8.0

5.3 c2.2 ~0.0060 c0.39 <5.0 12.2 c2.6 c3.5 c2.0 c5.0 c2.6 4 . 4 c8.2 c4.6 c2.5 c4.4 c7.0

1 .o 5.5

c2.3 4 . 0 c5.0 c5.0 c1 .o c4.0 c4.0 c5.0 c2.5 c2.5 c3.2 c2.4 c2.4 c2.2 <2.0 c2.0

c1.3 <IO 4.0 5.5 3.0

c10 4 . 0

5.2 c5.0

Screen Zone Elevation

116.0-101.0 ft msl

- DF

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

1 1 1 1 1 1 1 1 1

Note: See Appendix B for flagging criteria. 0 = exceeded holding time. m = exceeded standard.

Interim Sanitary Landfill

- Mod

V

V

J

V

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0

0 0

e o 0

12

TOO of Casinq

213.6 ft msl

!& WA WA ES ES ES ES ES WA WA ES ES ES ES WA ES ES ES ES ES ES WA WA ES ES WA WA WA ES ES ES ES ES ES ES ES ES WA ES ES

ES WA WA ES Wh WA ES ES ES

2Q97

WSRC-TU-97-0200 Unclassified

@&g PumD Screenzone

4'PVC s Middle Steed Pond

- Unit

R msl PH pS/cm "C m9k NTU well vols

First and Second Quarters 1997

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WSRC-TR-97-0200 Unclassified

WELL LFW 74C (cont.)

Silver, total recoverable Specific conductance Styrene 1,1,1,2-TetrachIoroethane 1,1,2,2-Tetrachloroethane Tetrachloroethylene Thallium, total recoverable Toluene I,l,l-Trichloroethane 1,1,2-Trichloroethane Trichloroethylene Trichlorofluoromethane 1,2,3-Trichloropropane Vanadium, total recoverable Vinyl acetate Xylenes Zinc, total recoverable

0.57 35 <0.50 ~5.0 <I .5 4 . 9 ~5.0 <I .7 <2.5 <2.8 <3.0 <4.6 ~ 5 . 0 <2.0 <IO <3.7

28

Note: See Appendix 8 for flagging criteria. 0 = exceeded holding time. m = exceeded standard.

Interim Sanitary Landfill

J 0 WA 0 WA 0 ES 0 WA 0 ES 0 ES 0 ES 0 ES 0 ES 0 ES 0 ES 0 ES 0 WA 0 ES 0 WA 0 ES 0 ES

13 First and Second Quarters 1997

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WSRC-TR-974200 Unclassified

WELL LFW 74D SRS Coord. Laaonaitude

N85828.1 33.289172 "N €45098.0 81.714771 "W

SAMPLE DATE

FIELD DATA

Parameter

Water elevation

Sp. conductance Water temperature Alkalinity as CaC03 Turbidity Volumes purged Sampling code

ANALYTICAL DATA

Parameter

Acetone Acrylonitrile Antimony, total recoverable Arsenic, total recoverable Barium, total recoverable Benzene beta-Benzene hexachloride Beryllium, total recoverable Bromochloromethane Bromodichloromethane Bromoform Bromomethane Cadmium, total recoverable Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroethene (Vinyl chloride) Chloroform Chloromethane Chromium, total recoverable Cobalt, total recoverable Copper, total recoverable Dibromochloromethane 1,2-Dibromo-3-chloropropane 1 ,2-Dibromoethane Dibromomethane Di-n-butyl phthalate 1,2-DichIorobenzene 1 ,4-Dichlorobenzene trans-1,4-Dichloro-P-butene 1,l-Dichloroethane 1,2-Dichloroethane 1,l-Dichloroethylene cis-1.2-Dichloroethylene trans-1.2-Dichloroethylene Dichloromethane 1,2-Dichloropropane cis-1,d-Dichloropropene trans-1.3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane (Methyl iodide) Lead, total recoverable Methyl ethyl ketone Methyl isobutyl ketone Nickel, total recoverable

Selenium, total recoverable

PH

PH

03/05/9

- 1 Q97

161.6 5.0 16 26.0 2 2 5.0

- 1Q97

c6.8 c5.0 <27 C40

4.4 <5.0

4 . 6 c5.0 4.0 4.0 <IO c4.7

2.0 4.0 c5.0 4 0 4 0 c5.0 < lo <7.0 <4.5 <I5 45.0 c5.0 c5.0 s5.0 4 . 7 <5.0 c5.0 <20 ~ 5 . 0 c5.0 c5.0 c5.0 4.0 <9.7 <5.0 4.0

<5.0 4 0 <5.0 <47 < lo c10 <26

5.4 c66

Screen Zone Elevation TOD of Casinq Casina Puma ScreenZone

167.7-152.7 ft msl 213.9 ft msl 4'PVC s Upper Steed Pond

17

- DF

1 1 1 1 1 1

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

1 1 1 1 1 1 1 1 1

Note: See Appendix B for flagging criteria. 0 = exceeded holding time. m = exceeded standard.

Interim Sanitary Landfill

V

J

V

V

J

- H W

0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0

e o 0

14

- Lab

WA WA WA WA WA WA

WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA

WA WA WA WA WA WA WA WA WA

- 2Q97

- Unit

ft msl DH pS/cm "C

NTU well vols

mgR

First and Second Quarters 1997

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WELL LFW 74D (cont.) Silver, total recoverable Specific conductance Styrene 1 , 1 , 1,2-Tehachloroethane 1.1.2,2-Tetrachloroethane Tetrachloroethylene Thallium, total recoverable Toluene 1,l .I-Trichloroethane 1,1,2-Trichloroethane Trichloroethylene Trichlorofluoromethane 1,2,3-Trichloropropane Vanadium, total recoverable Vinyl acetate Xylenes Zinc, total recoverable

1.6 21

c5.0 c5.0 c5.0 c5.0 c55 4.0 4.0 c5.0 c5.0

3.9 c5.0 c6.9 c10 c5.0

15

1 J 1 v 1 1 1 1 1 1 1 1 1 1 J 1 1 1 1 1 J

0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA

Note: See Appendix B for flagging criteria. 0 = exceeded holding time. m = exceeded standard.

lnterim Sanitary Landfill 15

WSRC-TR-97-0200 Unclassified

First and Second Quarters 1997

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WSRGTR-97-0200 Unclassified

WELL LFW 75C SRS Coord. LatRonaitude

N85856.8 33.289658 "N €45357.0 81.714145 "W

SAMPLE DATE

FIELD DATA

Parameter

Water elevation PH Sp. conductance Water temperature Alkalinity as CaC03 Turbidity Volumes purged Sampling code

ANALYTICAL DATA

Parameter

Acetone Acrylonitrile Antimony, total recoverable Arsenic, total recoverable Barium, total recoverable Benzene beta-Benzene hexachloride Beryllium, total recoverable Bromochloromethane Bromodichloromethane Bromoform Bromomethane Cadmium, total recoverable Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroethene (Vinyl chloride) Chloroform Chloromethane Chromium, total recoverable Cobalt, total recoverable Copper, total recoverable Dibromochloromethane 1,2-Dibromo-3-chloropropane 1.2-Dibromoethane Dibromornethane Di-n-butyl phthalate 1,2-Dichlorobenzene 1.4-Dichlorobenzene trans-1 ,4-DichIoro-P-butene 1,l-Dichloroethane 1,2-Dichloroethane 1,l-Dichloroethylene cis-1.2-Dichloroethylene trans-1.2-Dichloroethylene Dichloromethane 1,2-Dichloropropane cis-l,3-Dichloropropene trans-l,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane (Methyl iodide) Lead, total recoverable Methyl ethyl ketone Methyl isobutyl ketone Nickel, total recoverable

Selenium, total recoverable PH

03/05/97

- 1 Q97

161.7 4.0 28 26.0 2 1 2.4

e10 e5.0 e27 c40

6.5 4 . 0

eo.19 4 . 0 e5.0 4.0 e10 e4.7 -5.0 4 . 0 c5.0 e10 e10 c5.0 e10 c7.0

e15 c5.0 e5.0 e5.0 c5.0 c1.6 4.0 4 . 0 c20 4 . 0 e5.0 4.0 4.0 c5.0 c3.3 e5.0 4.0

4 . 0 c10 4 . 0 c47 c10 e10 e26

5.1 c66

0.53

Screen Zone Elevation

115.6-100.6ftmsl

- DF

1 1 1 1 1 1

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

1 1 1 1 1 1 1 1 1

Note: See Appendix B for flagging criteria. 0 = exceeded holding time.

= exceeded standard.

_ . - Mod ST H 0 0 0 0 0 0

V 0 0 0 0 0 0 0 0 0 0 0 0 0 0

J 0 0 0 0 0 0

V 0 0 0 0 0 0 0 0 0

V 0 0 0

0 0 0 0 0 0 0

J 0 0 0

TOD of Casinq @&g Pumg Screenzone

197.8 ft msl 4'PVC s Middle Steed Pond

- Lab

WA WA WA WA WA WA

WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA

WA WA WA WA WA WA WA WA WA

- 2Q97

- 2097

- Unit

R msl

USlcm "C

NTU well vols

PH

msn

Interim Sanitary Landfill 16 First and Second Quarters 1997

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WELL LFW 7% (cont.) Silver, total recoverable Specific conductance Styrene l,l,l,Z-Tetrachloroethane 1 ,I ,2,2-Tetrachloroethane Tetrachloroethylene Thallium, total recoverable Toluene 1 ,l,l-Trichloroethane 1,1,2-Trichloroethane Trichloroethylene Trichlorofluoromethane 1,2,3-TrichIoropropane Vanadium, total recoverable Vinyl acetate Xylenes Zinc, total recoverable

c5.0 31

c5.0 c5.0 c5.0 <5.0 c55 c5.0 c5.0 c5.0 4.0 ~5.0 <5.0 4 . 9 <IO c5.0 24

1 1 v 1 1 1

1 1 1 1 1 1 1 J

0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA

Note: See Appendix B for flagging criteria. 0 = exceeded holding time.

= exceeded standard.

Interim Sanitary Landfill 17 First and Second Quarters 1997

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WELL LFW 75D SRS Coord. Latkonaitude

N85868.0 33.289681 "N €45355.6 81.714170 "W

SAMPLE DATE

FIELD DATA

Parameter

Water elevation

Sp. conductance Water temperature Alkalinity as CaC03 Turbidity Volumes purged Sampling code

ANALYTICAL DATA

PH

Parameter

Acetone Acrylonitrile Antimony, total recoverable Arsenic, total recoverable Barium, total recoverable Benzene beta-Benzene hexachloride Beryllium, total recoverable Bromchloromethane Bromodichloromethane Bromoform Bromomethane Cadmium, total recoverable Ca&on disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroethene (Vinyl chloride) Chloroform Chloromethane Chromium, total recoverable Cobalt. total recoverable Copper, total recoverable Dibromochloromethane 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane Dibromomethane Di-n-butyl phthalate 1,2-Dichlorobenzene 1.4-Dichlorobenzene trans-1.4-Dichloro-2-butene 1,l-Dichloroethane 1.2-Dichloroethane 1,l -Dichloroethylene cis-l,2-Dichloroethylene trans-1.2-Dichloroethylene Dichloromethane 1,2-Dichloropropane cis- 1.3-Dichloropropene trans- 1,3-Dichbropropene Ethylbenzene 2-Hexanone lodomethane (Methyl iodide) Lead, total recoverable Methyl ethyl ketone Methyl isobutyl ketone Nickel. total recoverable

Selenium, total recoverable PH

03/05/97

161.8 5.2 22 27.0 3 1 4.8

- 1 497

c4.0 -5.0 c27 c40

9.4 c5.0

4 . 6 4.0 4.0 4.0 4 0 c4.7 4.0 c5.0 c5.0 4 0 4 0 c5.0 4 0 c7.0

4 5 c5.0 c5.0 c5.0 4.0 c2.7 c5.0 4.0 c20 4.0 c5.0 c5.0 c5.0 c5.0 c2.6 c5.0 4.0

0.99

c5.0 4 0 c5.0

5.6 c10 4 0 c26

5.4 c66

Q& Pump Screenzone Screen Zone Elevation

166.0-151.0ft msl 198.2 ft msl 4'PVC s Upper Steed Pond

TOD of Casing

- DF

1 1 1 1 1 1

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

1 1 1 1 1 1 1 1 1

Note: See Appendix B for flagging criteria. 0 = exceeded holding time. B = exceeded standard.

Interim Sanitary Landfill

WSRC-TR-97-0200 Unclassified

Mod ST - - V 0

0 0 0 0 0

J

V

V

J

J

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0

0 0 0

18

- Lab

WA WA WA WA WA WA

WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA WA

WA WA WA WA WA WA WA WA WA

- 2497

- 2497

- Unit

W msl

pS/cm "C

NTU well vols

PH

mgR

First and Second Quarters 1997

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WSRc-rR-97-0200 Unclassified

WELL LFW 75D (cont.) Silver, total recoverable Specific conductance Styrene 1,1,1,5-Tetrachloroethane 1 .I .2,2-Tetrachloroethane Tetrachloroethylene Thallium. total recoverable Toluene l.l,l-Trichloroethane I, 1.2-Trichloroethane Trichloroethylene Trichlorofluorornethane 1,2,3-TrichIoropropane Vanadium, total recoverable Vinyl acetate Xylenes Zinc, total recoverable

<5.0 30

<5.0 <5.0 <5.0 e5.0 <55 <5.0 <5.0 <5.0 <5.0

1.4 <5.0 0.90

<lo ~5.0

26

1 1 v 1 1 1 1 1 1 1 I 1 1 J 1 1 J 1 1 1 J

0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA 0 WA

Note: See Appendix B for flagging criteria. 0 = exceeded holding time.

= exceeded standard.

Interim Sanitary Landfill 19 First and Second Quarters 7997

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Appendix A

WSRC-PR-97-0200 Unclassified

~~~~ -

Standards

Interim Sanitary Landfill A- 1 First and Second Quarters 1997

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Interim Sanitary Landfill

WSRC-TR-974200 Unclassified

THIS PAGE LEFT BLANK INTENTIONALLY.

A-2 First and Second Quarters 1997

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WSRGTR-97-0200 Unclassified

Standards

Analyte Acetone Acrylonitrile Antimony Arsenic Barium Benzene Beta-benzene hexachloridea Beryllium Bromochloromethaneb Bromodichloromethane Bromoform 2-Butanone (Methyl ethyl ketone) Cadmium Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chromium Cobalt Copper Dibromochloromethane 1,2-Dibromo-3-chloropropane 1 ,e-Dibromoethane Di-n-butyl phthlatea 1,2-DichIorobenzene 1 +Dichlorobenzene trans-1 ,4-DichIoroQ-butene 1,l-Dichloroethane 1,2-Dichloroethane 1,l-Dichloroethylene cis-1,2-Dichloroethylene' trans-I ,2-Dichloroethylene 1,2-DichIoropropane cis-l,3-Dichloropropene trans- 1,3-DichIoropropene Ethylbenzene 2-Hexanone lodomethane Lead Methyl bromide (Bromomethane) Methyl chloride (Chloromethane) Methylene bromide (Dibromomethane) Methylene chloride (Dichloromethane) 4-Methyl-2-pentanone (Methyl isobutyl ketone) Nickel PH S e I e n i u m Silver Specific conductance Styrene 1,1,1,2-TetrachIoroethane 1,1,2,2-TetrachIoroethane Tetrachloroethylene Thallium To I uene 1 ,I ,I-Trichloroethane 1,1,2-Trichloroethane

Interim Sanitary Landfill

Level 100 5 30 10 20 5 0.05 3

5 5 100 40 5 5 5 10 5 70 70 29.8' 5 5 5 10 10 10 5 5 5 5

5 5 5 5 5 50 5 18' 10 10 5 10 50 50 4.1 1-6.1 5' 20 70 10.6-37.0' 5 5 5 5 10 5 5 5

-

-

A-3

Method EPA 8240 EPA 8240 EPA 7041 EPA 7060 EPA 601 0 EPA 8240 EPA 8081 EPA 6010

EPA 8240 EPA 8240 EPA 8240 EPA 601 0 EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 601 0 EPA 601 0

-

€PA 8240 EPA 8240 EPA 8240 EPA 8270 EPA 8270 EPA 8270 EPA 8240 EPA 8240 EPA 8240 EPA 8240

EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 8240

-

EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 601 0

EPA 7740 EPA 601 0

EPA 8240 EPA 8240 EPA 8240 EPA 8240 EPA 7841 EPA 8240 EPA 8240 EPA 8240

First and Second Quarters 1997

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WSRC-TR-97-0200 Unclassified

Analyte Trichloroethylene Trichlorofluoromethane 1,2,3-TrichIoropropane Vanadium Vinyl acetate Vinyl chloride (Chloroethene) Xylene Zinc

Level 5 5 5 80 5 10 5 29.3”

Method EPA 8240 EPA 8240 EPA 8240 EPA 601 0 EPA 8240 EPA 8240 EPA 8240

a The PQL for this consitituent is not identified in the lnterim Sanitary Landfill Groundwater Monitoring Program (WSRC, 1994). The PQL cited for this constituent is for the method used by the primary laboratory. No PQL is available for this constituent. Tolerance limits for copper, lead, pH, specific conductance, and zinc are set according to the lnterim Sanitary Landfill Groundwater Monitoring Program, Table 2-4.

Interim Sanitary Landfill A 4 First and Second Quarters 1997

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Appendix B Flagging Criteria

Interim Sanitary Landfill B- 7 first and Second Quarters 1997

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WSRC-TR-97-0200 Unclassified

THIS PAGE LEFT BLANK INTENTIONALLY.

Interim Sanitary Landfill 8-2 First and Second Quarters 1997

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WSRC-TR-97-0200 Unclassified

Flagging Criteria Beginning first quarter 1992, flagging criteria were established for all constituents analyzed as part of the EPD/EMS Groundwater Monitoring Program. Only the flagging criteria for environmental screening analyses are used to trigger scheduling for designated wells in the environmental screening program, while all flagging criteria in Table B-1 are used to flag constituents in the analytical results tables.

The following rules are used in determining flagging criteria and scheduling sampling: 0 Flag 0: Analysis for a constituent below Flag 1 is classified as Flag 0. Constituents

classified as Flag 0 in each well series will be scheduled for analyses only by custodian request or as part of the triennial environmental screening program for wells designated as environmental screening wells.

Flag 1 : The Flag 1 criterion for a constituent equals half of the EPA primary drinking water standard (PDWS), the EPA proposed PDWS, or the EPA secondary drinking water standard (SDWS) for that constituent. If a constituent does not have an EPA drinking water standard, the Flag 1 criterion equals 5 times a recently published 90th percentile detection limit obtained by one of the primary laboratories. If a constituent exceeds Flag 1 in a monitoring well series, environmental screening wells in that series are sampled and analyzed for that constituent once a year. If a constituent falls below Flag 1 for three consecutive sampling episodes, the well’s flag is reduced from Flag 1 status to Flag 0 status and follows the rules for Flag 0.

Flag 2: The Flag 2 criterion for a constituent equals the EPA PDWS, the EPA proposed PDWS, or the EPA SDWS for that constituent. If a constituent does not have a drinking water standard, the Flag 2 criterion equals 10 times a recently published 90th percentile detection limit obtained by one of the primary laboratories. If a constituent exceeds Flag 2 in a monitoring well series, environmental screening wells in that series are sampled and analyzed for that constituent once a year. If a constituent falls below Flag 2 for three consecutive sampling episodes, the well’s flag is reduced from Flag 2 status to Flag 1 or Flag 0 status and follows the rules for the lower flag.

The following constituents are exceptions to the flagging rules: 0

0

0

Specific conductance and pH, which are indicator parameters, have flagging criteria but do not trigger the scheduling mechanism. No flags are set for alkalinity, 5-day biochemical oxygen demand, calcium, carbonate, chemical oxygen demand, magnesium, potassium, silica, sodium, total dissolved solids, total phosphates (as P), and total phosphorous because they are indicator parameters or major cations. Analyses for these constituents are conducted as part of the triennial environmental screening program or by special request.

Aesthetic analyses such as color, odor, corrosivity, turbidity, and surfactants are not assigned flagging criteria but are analyzed by special request.

Common laboratory contaminants and cleaners including phthalates, dichloromethane, ketones, and toluene are not assigned flagging criteria unless they have a PDWS. These constituents are analyzed by special request.

0

Table B-1. Flagging Criteria Analyte Unit Flag 1 Flag 2 Source Acena phthene pglL 5.1 10.2 EPA Method 8270 Acenaphthylene pg/L 5.1 10.2 EPA Method 8270 Acetone pg1L 500 1,000 €PA Method 8240 (Set by EPDIEMS) Acetonitrile (Methyl cyanide) Ps/L 50 100 EPA Method 8240

Interim Sanitary Landfill 6-3 First and Second Quarters 1997

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WSRC-TR-97-0200 Unclassified

Analyte Acetophenone 2-Acetylaminof luorene Acrolein Acrylonitrile Actinium-228 Alachlor Aldicarb Aldicarb sulfone Aldicarb sulfoxide Aldrin Alkalinity (as CaC03) Allyl chloride Aluminum Aluminum, dissolved Aluminum, total recoverable Americium-241 Americium-243 4-Aminobipheny l Ammonia Ammonia nitrogen Aniline Anthracene Antimony Antimony, dissolved Antimony, total recoverable Antimony-1 24 Antimony-1 25 Aramite Arsenic Arsenic, dissolved Arsenic, total recoverable Asbestos Atrazine Azobenzene Barium Barium, dissolved Barium, total recoverable Barium-1 33 Barium-140a Benzene alpha-Benzene hexachloride beta-Benzene hexachloride delta-Benzene hexachloride Benzidine BenzoIaIanthracene Benzo[b]fluoranthene Benzo[qfluoranthene Benzoic acid Benzo[g,h,ilpetylene Benzo[a]pyrene 1,4-Benzoquinone Benzyl alcohol

1.5 50 1000 1000 1000 7.6E-07 4.5E-08 2.5 0.15 0.25 0.25 83.5 0.05 0.1 0.1 5 5.1 0.1 50 5

Flag 2 170 162 333 500 3.27E-06 2 3 2 4 0.8 No flag 833 50 50 50 6.34E-09 6.37E-09 162 500 1,000 162 10.2 6 6 6 6E-08 3E-07 162 50 50 50 7,000,000 3 100 2,000 2,000 2,000 1.52E-06 9E-08 5 0.3 0.5 0.5 167 0.1 0.2 0.2 10 10.2 0.2 100 10

Source EPA Method 8270 EPA Method 8270 EPA Method 8240 EPA Method 8240 Proposed DWS (EPA, 1991 a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) EPA Method 8080 Set by EPDIEMS EPA Method 8240 Secondary DWS (CFR, 1996b) Secondary DWS (CFR, 1996b) Secondary DWS (CFR, 1996b) Proposed DWS (EPA, 1991a) Proposed DWS (EPA, 1991a) EPA Method 8270 APHA Method 41 78 EPA Method 350.1 EPA Method 8270 EPA Method 8270 Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Interim Final DWS (EPA, 1977) Interim Final DWS (EPA, 1977) EPA Method 8270 Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) EPA Method 625 Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Proposed DWS (EPA, 1991a) Interim Final DWS (EPA, 1977) Final DWS (CFR, 1996a) EPA Method 8080 EPA Method 8080 EPA Method 8080 EPA Method 8270 Proposed DWS (EPA, 1990) Proposed DWS (EPA, 1990) Proposed DWS (EPA, 1990) EPA Method 8270 EPA Method 8270 Final DWS (CFR, 1996a) EPA Method 8270 EPA Method 8270

Interim Sanitary Landfill 8-4 First and Second Quarters 1997

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Analyte Beryllium Beryllium, dissolved Beryllium, total recoverable Beryllium-7 5-day Biochemical oxygen demand Bis(2-chloroethoxy) methane Bis(2-chloroethyl) ether Bis(2-chloroisopropyI) ether Bis(chloromethy1) ether Bis(2-ethylhexyl) phthalate Bismuth-214 Boron Boron, dissolved Boron, total recoverable Bromide Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane (Methyl bromide) 4-Bromophenyl phenyl ether n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Butylbenzyl phthalate 2-sec-Butyl-4,6-dinitrophenol Cadmium Cadmium, dissolved Cadmium, total recoverable Calcium Calcium, dissolved Calcium, total recoverable Carbofuran Carbon disulfide Carbon tetrachloride Carbon-1 4 Carbonate Cerium-I 4 ia Cerium-144 cesium-134’ Cesium-1 37 Chemical oxygen demand Chlordane alpha-Chlordane gamma-Chlordane Chloride 4-Chloroaniline Chlorobenzene Chlorobenzilate 4-Chloro-m-cresol Chloroethane Chloroethene (Vinyl chloride) Chloroethyl vinyl ether

2,500 2,500 2,500 5,000 25 5 50 50 10 5.1 5 5 5 No flag 3.5 2.5 2.5 2.5 No flag No flag No flag 20 25 2.5

Flag 2 4 4 4 6E-06 No flag 10.2 10.2 200 7 00 6 1.89E-05 5,000 5,000 5,000 10,000 50 10 100 100 20 10.2 10 10 10 No flag 7 5 5 5 No flag No flag No flag 40 50 5 2E-06 No flag 3E-07 2.61 E 4 7 8.1 3E-08 2E-07 No flag 2 0.5 0.5 250,000 10 100 162 10.2 20 2 10

WSRCT~-97-0200 Unclassified

Source Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Interim Final DWS (EPA, 1977) Set by EPDIEMS EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 Final DWS (CFR, 1996a) Proposed DWS (EPA, 1991 a) EPA Method 6010 EPA Method 6010 EPA Method 6010 EPA Method 300.0 EPA Method 8260 EPA Method 8260 Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) EPA Method 8240 EPA Method 8270 EPA Method 8260 EPA Method 8260 EPA Method 8260 Set by EPDIEMS Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Set by EPDIEMS Set by EPDIEMS Set by EPDIEMS Final DWS (CFR, 1996a) EPA Method 8240 Final DWS (CFR, 1996a) Interim Final DWS (EPA, 1977) Set by EPDIEMS Interim Final DWS (EPA, 1977) Proposed DWS (EPA, 1991a) Proposed DWS (EPA, 1991 a) Interim Final DWS (EPA, 1977) Set by EPDJEMS Final DWS (CFR, 1996a) EPA Method 8080 EPA Method 8080 Secondary DWS (CFR, 1996b) EPA Method 8270 Final DWS (CFR, 1996a) EPA Method 8270 EPA Method 8270 EPA Method 8240 Final DWS (CFR, 1996a) EPA Method 8240

Interim Sanitary Landfill B-5 First and Second Quarters 1997

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Analyte 2-Chloroethyl vinyl ether Chloroform Chloromethane (Methyl chloride) 2-Chloronaphthalene 2-Chlorophenol 4-Chlorophenyl phenyl ether Chloroprene 2-Chlorotoluene 4-Chlorotoluene Chromium Chromium, dissolved Chromium, total recoverable Chromium-51 a

Chrysene Cobalt Cobalt, dissolved Cobalt, total recoverable Cobalt-57 Cobalt-58 Cobalt-60 Color Copper Copper, dissolved Copper, total recoverable Corrosivity m-Cresol (3-Methylphenol) 0-Cresol (2-Methylphenol) p-Cresol (4-Methylphenol) Curium-242 Curium-243 C~rium-243/244~ Curium-244 Curium-2451246' Curium-246 Cyanide Dalapon p,p'-DDD p,p'-DDE p,p'-DDT Diallate Dibenz[a,h]anthracene Di benzof uran Dibromochloromethane 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane

Flag 1 50 50 10 5.1 5.1 5.1 1,665 25 5 50 50 50

PCiImL 3E-06

pg1L 50 pg/L 50 pg1L 50 PCimL 5E-07 pCi/mL 4.5E-06 pCi/mL 5E-08

No flag pg/L 500 pg/L 500 pg/L 500

Pg/L 50 Pg/L 5 ILdL 60

pg/L 0.1

No flag

pCi/mL 6.65E-08 pCi/mL 4.1 5E-09 pCi/mL 4.15E-09 pCi/mL 4.92E-09 PCiImL 3.12E-09 pCi/mL 3.14E-09

Dibromomethane (Methylene bromide) FLS/L Di-n-butyl phthalate 1,2-DichIorobenzene Ps/L 1,3-DichIorobenzene P91L 1 ,.Q-Dichlorobenzene Ps/L

trans-1 ,4-DichIoroQ-butene PSIL 33-Dichlorobenzidine

100 100 0.55 0.25 0.85 81 0.15 5 50 0.1 0.025 10 No flag 300 81 37.5 5.1 250

Flag 2 100 100 20 10.2 10.2 10.2 3,330 50 10 100 100 100 6E-06 0.2 100 100 100 1 E-06 9E-06 1 E-07 No flag 1,000 1,000 1,000 No flag 100 10 120 1.33E-07 8.3E-09 8.3E-09 9.84E-09 6.23E-09 6.27E-09 200 200 1 . I 0.5 1.7 162 0.3 10 100 0.2 0.05 20 No flag 600 162 75 10.2 500

WSRC-TR-97-0200 Unclassified

Source EPA Method 8240 Final DWS (CFR, 1996a) EPA Method 8240 EPA Method 8240 EPA Method 8270 EPA Method 8270 EPA Method 8240 EPA Method 8260 EPA Method 8260 Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Interim Final DWS (EPA, 1977) Proposed DWS (EPA, 1990) EPA Method 601 0 EPA Method 601 0 EPA Method 601 0 Interim Final DWS (EPA, 1977) Interim Final DWS (EPA, 1977) Interim Final DWS (EPA, 1977) Set by EPD/EMS Primary DWS (SCDHEC, 1981) Primary DWS (SCDHEC, 1981) Primary DWS (SCDHEC, 1981) Set by EPDIEMS €PA Method 8270 EPA Method 8270 EPA Method 8270 Proposed DWS (EPA, 1991a) Proposed DWS (EPA, 1991a) Proposed DWS (EPA, 1991a) Proposed DWS (EPA, 1991a) Proposed DWS (EPA, 1991a) Proposed DWS (EPA, 1991a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) EPA Method 8080 EPA Method 8080 EPA Method 8080 EPA Method 8270 Proposed DWS (EPA, 1990) EPA Method 8270 Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) EPA Method 8240 Set by EPDIEMS Final DWS (CFR, 1996a) EPA Method 8270 Final DWS (CFR, 1996a) EPA Method 8270 €PA Method 8240

Interim Sanitary Landfill 6-6 First and Second Quarters 1997

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Analyte Dichlorodifluoromethane 1,l-Dichloroethane 1,2-Dichioroethane cis-l,2-Dichloroethylene 1 ,I-Dichloroethylene 1 ,2-Dichloroethylene trans-l,2-Dichloroethylene Dichloromethane (Methylene chloride) 2,4-Dichlorophenol 2,6-Dichlorophenol 2,4-Dichlorophenoxyacetic acid 1,2-DichIoropropane 2,2-Dichloropropane cis-l,3-Dichloropropene trans-1 ,&Dichloropropene Dieldrin Diethyl phthalate Di(2-ethylhexyl) adipate Dimethoate 2,4-Dimethyl phenol Dimethyl phthalate p-Dimethylaminoazobenzene p-(Dimethy1amino)ethylbenzene 7,12-Dimethylbenz[a]anthracene 3,3’-Dimethylbenzidine a,a-Dimethylphenethylamine 1,8Dinitrobenzene 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Di-n-octyl phthalate 1 +Dioxane Diphenylamine 1,2-DiphenyIhydrazine Diquat dibromide Dissolved organic carbon Disulfoton Endosulfan I Endosulfan II Endosulfan sulfate Endothall Endrin Endrin aldehyde Endrin ketone Ethyl ether Ethyl methacrylate Ethyl methanesulfonate Ethylbenzene Europium-1 52 Europium-1 54 Europium-1 55 Fam p h u r

Interim Sanitary Landfill

Flag 1 10 10 2.5 35 3.5 25 50 2.5 5.1 83.5 35 2.5 5 10 10 4.15 No flag 200 81 5.1 No flag 81 50 81 81 81 81 51 0.5 0.5 No flag 500 81 83.5 10

Flag 2 20 20 5 70 7 50 100 5 10.2 167 70 5 10 20 20 8.3 No flag 400 162 10.2 No flag 1 62 100 1 62 162 162 162 1 02 1 1 No flag 1,000 162 167 20

WSRC-TR-97-0200 Unclassified

Source EPA Method 8240 EPA Method 8240 Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) EPA Method 8240 Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) EPA Method 8270 EPA Method 8270 Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) EPA Method 8260 EPA Method 8240 EPA Method 8240 EPA Method 8080 Set by EPDIEMS Final DWS (CFR, 1996a) EPA Method 8270 EPA Method 8270 Set by EPDIEMS EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 Set by EPDIEMS EPA Method 8270 EPA Method 8270 EPA Method 8270 Final DWS (CFR, 1996a)

10,500,000 21,000,000 EPA Method 9060 81 0.25 0.55 0.55 50 1 0.85 No flag 50 2.5 81 350 3E-08 1 E-07 3E-07 81

8-7

1 62 0.5 1.1 1.1 100 2 1.7 No flag 100 5 1 62 700 6E-08 2E-07 6E-07 162

EPA Method 8270 EPA Method 8080 EPA Method 8080 EPA Method 8080 Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) EPA Method 8080 Set by EPDIEMS EPA Method 8260 EPA Method 8270 EPA Method 8270 Final DWS (CFR, 1996a) Interim Final DWS (EPA, 1977) Interim Final DWS (EPA, 1977) Interim Final DWS (EPA, 1977) EPA Method 8270

First and Second Quarters 7997

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WSRC-TR-97-0200 Unclassified

Analyte Fluoranthene Fluorene Fluoride Glyphosate Gross alpha Heptachlor Heptachlor epoxide Heptachlorodibenzo-p-dioxin isomers

Heptachlorodibenzo-p-furan isomers

Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachlorodibenzo-p-dioxin isomers

Hexachlorodibenzo-p-furan isomers

Hexachloroethane Hexachlorophene Hexachloropropene 2-Hexanone Indeno[112,3-c,dJpyrene Iodine Iodine-129 iodine-131a lodomethane (Methyl iodide) Iron Iron, dissolved Iron, total recoverable ~ron-%a lr0n-59~ Isobutyl alcohol lsodrin lsophorone lsopropylbenzene p-lsopropyltoluene lsosafrole Kepone Lanthanum-1 40a Lead Lead, dissolved Lead, total recoverable Lead-21 2 Lindane Lithium Lithium, dissolved Lithium, total recoverable Magnesium Magnesium, dissolved Magnesium, total recoverable Manganese

1,2,3,4,6,7,8-HPCDD

1,2,3,4,6,7,8-HPCDF

1,2,3,4,7,8-HXCDD

1,2,3,4,7,8-HXCDF

Interim Sanitary Landfill

Flag 1 5.1 5.1 2,000 350 7.5E-09 0.2 0.1 0.007 0.007 0.008 0.008 0.5 5 25 0.008 0.01 05 0.006 0.0085 0.5 83.5 81 50 0.5 250 5E-10 1.5E-09 125 150 150 150 1 E-06 1 E-07 834.5 81 5.1 5 5 81 81 3E-08 25 25 25 6.2E-08 0.1 125 125 125 No flag No flag No flag 25

Flag 2 10.2 10.2 4,000 700 1.5E-08 0.4 0.2 0.01 4 0.014 0.01 6 0.01 6 1 10 50 0.01 6 0.021 0.012 0.01 7 1 167 162 100 1 500 1 E-09 3E-09 250 300 300 300 2E-06 2E-07 1,669 162 10.2 10 10 162 162 6E-08 50 50 50 1.23E-07 0.2 250 250 250 No flag No flag No flag 50

B-8

Source EPA Method 8270 EPA Method 8270 Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) EPA Method 8280 EPA Method 8280 EPA Method 8280 EPA Method 8280 Final DWS (CFR, 1996a) EPA Method 8270 Final DWS (CFR, 1996a) EPA Method 8280 EPA Method 8280 EPA Method 8280 EPA Method 8280 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8240 EPA Method 8270 APHA Method 41 5A Interim Final DWS (EPA, 1977) Interim Final DWS (EPA, 1977) EPA Method 8240 Secondary DWS (CFR, 1996b) Secondary DWS (CFR, 1996b) Secondary DWS (CFR, 1996b) Interim Final DWS (EPA, 1977) Interim Final DWS (EPA, 1977) EPA Method 8240 EPA Method 8270 EPA Method 8270 EPA Method 8260 EPA Method 8260 EPA Method 8270 EPA Method 8270 Interim Final DWS (EPA, 1977) Final DWS (SCDHEC, 1981) Final DWS (SCDHEC, 1981) Final DWS (SCDHEC, 1981) Proposed DWS (EPA, 1991a) Final DWS (CFR, 1996a) EPA Method 601 0 EPA Method 601 0 EPA Method 601 0 Set by EPDIEMS Set by EPDIEMS Set by EPDIEMS Secondary DWS (CFR, 1996b)

First and Second Quarters 7997

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Analyte Manganese, dissolved Manganese, total recoverable Manganese-54 Mercury Mercury, dissolved Mercury, total recoverable Methacrylonitrile Methapyrilene Methoxychlor Methyl tert-butyl ether Methyl ethyl ketone Methyl isobutyl ketone Methyl methacrylate Methyl methanesulfonate 3-Methylcholanthrene 2-Methyl-4,6-dinitrophenol 2-Methylnaphthalene Molybdenum Molybdenum, dissolved Molybdenum, total recoverable Naphthalene 1,4-Naphthoquinone 1 -Naphthylamine 2-Naphthylamine Neptunium-237 Neptunium-239 Nickel Nickel, dissolved Nickel, total recoverable Nickel-59 Nickel-63 Niobium-95= Nitrate as nitrogen Nitrate-nitrite as nitrogen Nitrite as nitrogen m-Nitroaniline o-Nitroaniline p-Nitroaniline Nitrobenzene Nitrogen by Kjeldahl method 2-Nitrophenol 4-Nitrophenol 4-Nitroquinoline-1 -oxide N-Nitrosodi-n-butylamine N- Nitrosodiethylamine N-Nitrosodimethylamine N-Nitrosodiphenylamine N- Nitrosodipropylamine N-Nitrosomethylethylamine N-Nitrosomorpholine N-Nitrosopiperidine N-Nitrosopyrrolidine

~

Flag 2 50 50 3E-07 2 2 2 833 162 40 10 No flag No flag 100 1 62 162 102 10 500 500 500 167 162 162 162 7.06E-09 1.68E-06 1 00 100 100 3E-07 5E-08 3E-07

5,000 10,000 5,000 10,000 500 1,000 5 10 5 10 5 10 5.1 10.2 500 1,000 5.1 10.2 5.1 10.2 81 1 62 81 162 81 162 83.5 167 5.1 10.2 5.1 10.2 81 162 81 162 81 1 62 81 162

WSRC-TR-97-0200 Unclassified

Source Secondary DWS (CFR, 1996b) Secondary DWS (CFR, 1996b) Interim Final DWS (EPA, 1977) Final DWS (CFR, 1996a) Final DWS’(CFR, 1996a) Final DWS (CFR, 1996a) EPA Method 8240 EPA Method 8270 Final DWS (CFR, 1996a) EPA Method 8260 Set by EPDIEMS Set by EPDIEMS EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 601 0 EPA Method 601 0 EPA Method 601 0 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 Proposed DWS (EPA, 1991a) Proposed DWS (EPA, 1991a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Interim Final DWS (EPA, 1977) Interim Final DWS (EPA, 1977) Interim Final DWS (EPA, 1977) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 351.2 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 8270

Interim Sanitary Landfill B-9 First and Second Quarters 1997

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WSRC-TR-97-0200 Unclassified

Anaiyte 5-Nitro-0-toluidine Nonvolatile beta Octachlorodibenzo-p-dioxin isomers Octachlorodibenzo-p-furan isomers Odor Oil and grease Oxamyl Parathion Parathion methyl PCB 1016 PCB 1221 PCB 1232 PCB 1242 PCB 1248 PCB 1254 PCB 1260 PCB 1262 Pentachlorobenzene Pentachlorodibenzo-p-dioxin isomers

Pentachlorodibenzo-p-furan isomers

Pentachloroethane Pentachloronitrobenzene Pentachlorophenol

1,2,3,7,8-PCDD

1,2,3,7,8-PCDF

PHa PHa Phenacetin Phenanthrene Phenol Phenols p-Phenylenediamine Phorate Picloram 2-Picoline Plutonium-238 Plutonium-239 Piutonium-239/240~ Plutonium-240 Plutonium-241 a

Plutonium-24za Potassium Potassium, dissolved Potassium, total recoverable Potassium-40 Promethium-1 44 Promethium-1 46 Promethium-1 47 Pronamid Propionitrile n-Propylbenzene Pyrene

Flag 1 81 2.5E-08 0.0085 0.0065 No flag 8,350 100 0.4 0.4 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 81 0.008 0.0075 0.0085 0.0085 81 81 0.5 8 4 81 5.1 83.5 50 81 0.85 250 81

3.11E-08 3.11E-08 3.1 1 E-08 3.13E-08 3.27E-08 No flag No flag No flag 1.5E-07 5E-08 5E-08 2.62E-06 81 1,665 5 5.1

3.51 E-09

Flag 2 162 5E-08 0.01 7 0.013 No flag 16,700 200 0.8 0.8 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 162 0.01 6 0.01 5 0.017 0.01 7 162 162 1 10 3 162 10.2 167 100 162 1.7 500 162 7.02E-09 6.21 E-08 6.21 E 4 8 6.22E-08 6.26E-08 6.54E-08 No flag No flag No flag 3E-07 1 E-07 1 E 4 7 5.24 E-06 162 3,330 10 10.2

Source EPA Method 8270 Interim Final DWS (EPA, 1977) EPA Method 8280 EPA Method 8280 Set by EPDIEMS EPA Method 41 3.1 Final DWS (CFR, 1996a) EPA Method 8080 EPA Method 8080 Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) EPA Method 8270 EPA Method 8280 EPA Method 8280 EPA Method 8280 EPA Method 8280 EPA Method 8270 EPA Method 8270 Final DWS (CFR, 1996a) Set by EPDIEMS Set by EPDIEMS EPA Method 8270 EPA Method 8270 EPA Method 8270 EPA Method 420.1 EPA Method 8270 EPA Method 8080 Final DWS (CFR, 1996a) EPA Method 8270 Proposed DWS (EPA, 1991a) Proposed DWS (EPA, 1991 a) Proposed DWS (EPA, 1991a) Proposed DWS (EPA, 1991a) Proposed DWS (EPA, 1991a) Proposed DWS (EPA, 1991a) Set by EPDIEMS Set by EPDIEMS Set by EPDIEMS Proposed DWS (EPA, 7986a) EPA Method 901.1 EPA Method 901.1 Proposed DWS (EPA, 1991 a) EPA Method 8270 EPA Method 8240 EPA Method 8260 EPA Method 8270

Interim Sanitary Landfill B-10 First and Second Quarters 1997

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Analyte Pyridine Radium, total alpha-emitting Radium-226 Radium-228 Radon-222 Ruthenium-1 03a Ruthenium-1 06 Safrole Selenium Selenium, dissolved Selenium, total recoverable Silica Silica, dissolved Silica, total recoverable Silver Silver, dissolved Silver, total recoverable Simazine Sodium Sodium, dissolved Sodium, total recoverable Sodium-22 Specific conductanceu Strontium-89 Strontium-89/90c Strontium-90 Styrene Sulfate Sulfide Sulfotepp Surfactants 2,3,7,8-TCDD 2,3,7,8-TCDF Technetium-99 1,2,4,5-TetrachIorobenzene Tetrachlorodibenzo-p-dioxin isomers Tetrachlorodibenzo-p-furan isomers 1,1,1 ,FTetrachloroethane 1,1,2,2-TetrachIoroethane Tetrachloroethylene 2,3,4,6-Tetrachlorophenol Thallium Thallium, dissolved Thallium, total recoverable Thionazin Thorium-228 Thorium-230 Thorium-232 Thorium-234= Tin Tin, dissolved Tin, total recoverable Tin-1 13

Unit Flag 1 Pg/L 81 pCi/mL 1E-08 pCi/mL 1E-08 pCi/mL 1E-08 pCi/mL 1 X - 0 7 pCi/mL 1E-07 pCi/mL 1.5E-08 Ps/L 81 pgfL 25 pg/L 25 pg/L 25

No flag No flag No flag

pg/L 50 PdL 50 Pg/L 50 Pg/L 2

No flag No flag No flag

pCi/mL 2.33E-07 pS/cm 250 pCi/mL 1E-08 pCi/mL 4E-09 pCi/mL 4E-09 Ps/L 50 pg/L 200,000 pg/L 8,350 pg/L 81

pg/L 0.007 ps/L 0.00425 pCi/mL 4.5E-07

pg/L 0.007 pg/L 0.0055

pg/L 50 pg/L 2.5 ps/L 83.5 Ps/L 1 PgJL 1 Pg/L 1 Pg/L 81

No flag

Ps/L 81

pg/L 10

pCi/mL 6.25E-08 pCi/mL 3.96E-08 pCi/mL 4.4E-08 pCi/rnL 2E-07 ps/L 250 pg/L 250 ps/L 250 pCimL 1.5E-07

Flag 2 1 62 2E-08 2E-08 2E-08 3E-07 2E-07 3E-08 162 50 50 50 No flag No flag No flag 100 100 100 4 No flag No flag No flag 4.66E-07 500 2E-08 8E-09 8E-09 100 400,000 16,700 1 62 No flag 0.014 0.0085 9E-07 162 0.014 0.01 1 20 100 5 167 2 2 2 162 1.25E-07 7.92E-08 8.8E-08 4.01 E-07 500 500 500 3E-07

WSRGTR-97-0200 Unclassified

Source EPA Method 8270 Proposed DWS (EPA, 1991 a) Proposed DWS (EPA, 1991 a) Proposed DWS (EPA, 1991 a) Proposed DWS (EPA, 1991 a) Interim Final DWS (EPA, 1977) Interim Final DWS (EPA, 1977) EPA Method 8270 Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Set by EPD/EMS Set by EPD/EMS Set by EPD/EMS Secondary DWS (CFR, 1996b) Secondary DWS (CFR, 1996b) Secondary DWS (CFR, 1996b) Final DWS (CFR, 1996a) Set by EPD/EMS Set by EPD/EMS Set by EPD/EMS Proposed DWS (EPA, 1991a) Set by EPD/EMS Interim Final DWS (EPA, 1977) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Proposed DWS (EPA, 1990) EPA Method 9030 EPA Method 8270 Set by EPDlEMS Final DWS (CFR, 1996a) EPA Method 8280 Interim Final DWS (EPA, 1977) EPA Method 8270 EPA Method 8280 EPA Method 8280 EPA Method 8240 EPA Method 8240 Final DWS (CFR, 1996a) EPA Method 8270 Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) EPA Method 8270 Proposed DWS (EPA, 1991 a) Proposed DWS (EPA, 1991 a) Proposed DWS (EPA, 1991 a) Proposed DWS (EPA, 1991 a) EPA Method 282.2 EPA Method 282.2 EPA Method 282.2 Interim Final DWS (EPA, 1977)

Interim Sanitary Landfill B-11 First and Second Quarters 1997

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WSRC-TR-97-0200 Unclassified

Analyte Toluene o-Toluidine Total carbon Total coliform Total dissolved solids Total hydrocarbons Total inorganic carbon Total organic carbon Total organic halogens Total organic nitrogen Total petroleum hydrocarbons Total phosphates (as P) Total phosphorus Toxaphene 2,4,5-TP (Silvex) Tributyl phosphate 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene l,l,l-Trichloroethane 1 ,I ,2-Trichloroethane Trichloroethylene Trichlorofluoromethane 2,4,5-TrichlorophenoI 2,4,6-TrichlorophenoI 2,4,5-Trichlorophenoxyacetic acid 1,2,3-TrichIoropropane Trichlorotrifluoroethane O,O,O-Triethyl phosphorothioate 1,2,4-Trirnethylbenzene 1,3,5-Trimethylbenzene 1,3,5-Trinitrobenzene Tritium Turbiditye Uranium Uranium alpha activity Uranium, dissolved Uranium, total recoverable Urani~m-233/234~ Uranium-234 Uranium-235 Uranium-238 Vanadium Vanadium, dissolved Vanadium, total recoverable Vinyl acetate mlp-Xylene o-Xylene Xylenes Yttrium-88 Zinc Zinc, dissolved Zinc, total recoverable

Interim Sanitary Landfill

Unit PdL PdL

NIA

Flag 1 500 81 5,000 0 No flag 5,000 8,350 500,000 50 500 8,350 No flag No flag 1.5 25 86 5 35 100 2.5 2.5 10 5 0.5 0.25 10 50 81 5 5 81 1 E-05 No flag 10 1.5E-08 10 10 6.9E-09 6.95E-09 7.25E-09 7.3E-09 66.5 66.5 66.5 50 81 5 5,000 5E-08 2,500 2,500 2,500

Flag 2 1,000 162 10,000 0 No flag 10,000 16,700 1,000,000 100 1,000 16,700 No flag No flag 3 50 172 10 70 200 5 5 20 10 1 0.5 20 100 162 10 10 1 62 2E-05 No flag 20 3E-08 20 20 1.38E-08 1.39E-08 1.45E-08 1.46E-08 133 133 133 100 162 10 10,000 1E-07 5,000 5,000 5.000

Source Final DWS (CFR, 1996a) €PA Method 8270 EPA Method 9060 Final DWS (CFR, 1996a) Set by EPDJEMS EPA Method 418.1 €PA Method 9060 EPA Method 9060 EPA Method 9020 APHA Method 420 EPA Method 41 8.1 Set by EPDJEMS Set by EPDIEMS Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) EPA Method 8270 EPA Method 8260 Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) Final DWS (CFR, 1996a) EPA Method 8240 EPA Method 8270 EPA Method 8270 EPA Method 8150 EPA Method 8240 EPA Method 8260 EPA Method 8270 EPA Method 8260 EPA Method 8260 EPA Method 8270 Final DWS (CFR, 1996a) Set by EPD/EMS Proposed DWS (EPA, 1991a) Proposed DWS (EPA, 1991 a) Proposed DWS (EPA, 1991a) Proposed DWS (EPA, 1991a) Proposed DWS (EPA, 1991 a) Proposed DWS (EPA, 1991a) Proposed DWS (EPA, 1991 a) Proposed DWS (EPA, 1991 a) EPA Method 601 0 EPA Method 601 0 EPA Method 601 0 EPA Method 8240 EPA Method 8260 EPA Method 8260 Final DWS (CFR, 1996a) EPA Method 901.1 Secondary DWS (CFR, 1996b) Secondary DWS (CFR, 1996b) Secondary DWS (CFR, 1996b)

8-72 First and Second Quarters 1997

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WSRC-TR-97-0200 Unclassified

Analyte Unit Flag 1 Flag2 Source Zinc-65 pCi/mL 1.5E-07 3E-07 Interim Final DWS (EPA, 1977) Zirconium-95 pCi/mL 1E-07 2E-07 Interim Final DWS (EPA, 1977) Zir~onium/Niobium-95~ pCi/mL 1E-07 2E-07 Interim Final DWS (EPA, 1977)

a EMS discontinued monitoring this radionuclide because it is inappropriate for the SRS groundwater monitoring program. EPD/EMS set this flagging criterion using the 1991 proposed DWS because the final DWS in 1977 may have been in error. When radionuclide analyses are combined, the lower DWS of the two isotopes is used for flagging. Will not trigger scheduling. The primary maximum contaminant level range for turbidity is 1-5 NTU, which is inappropriate for the SRS groundwater monitoring program.

e

lnterim Sanitary Landfill 8-13 First and Second Quarters 1997