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  • Fo

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    650:351 Thermodynamics

    Chapter 1

    Mahsa Mortazavi

    Email: [email protected]

    Oce hours: Tuesday, 2:00 - 3:30 pm

    Summer 2015

    650:351 Thermodynamics Mahsa Mortazavi 1

  • Overview of Course

    Conservation of mass Conservation of momentum Conservation of energy Equation of state Property tables and charts

    All problems in this course are solved using the above

    650:351 Thermodynamics Mahsa Mortazavi 2

  • Fundamental Units

    All physical processes involve units The fundamental units in the SI system are

    Dimension Unit

    Length meter (m)

    Mass kilogram (kg)

    Time second (s)

    Temperature kelvin (K)

    Electric current ampere (A)

    Amount of light candela (cd)

    Amount of matter mole (mol)

    650:351 Thermodynamics Mahsa Mortazavi 3

  • Fundamental Units

    The fundamental units in the English system are

    Dimension Unit

    Length foot (ft)

    Mass slug (slug)

    Time second (s)

    Temperature rankine (R)

    Electric current ampere (A)

    650:351 Thermodynamics Mahsa Mortazavi 4

  • Fundamental Units

    The fundamental units can be converted between English and SI

    1 foot = 0.3048 meters

    1 slug = 14.5939029 kilograms

    1 deg R = 0.55556 deg K

    650:351 Thermodynamics Mahsa Mortazavi 5

  • Fundamental Units

    Derived unitsUnit English SI

    Force pound force (lbf) Newton (Nt)

    Energy British Thermal Unit (BTU) Joule (J)

    Power Horsepower (HP) Watt (W)

    650:351 Thermodynamics Mahsa Mortazavi 6

  • Fundamental Units

    Derived units can be converted between English and SI1 lbf = 4.44822162 Nt

    1 BTU = 1055.05585 J

    1 HP = 745.699872 W

    650:351 Thermodynamics Mahsa Mortazavi 7

  • Fundamental Units

    What is pound mass (lbm) ?One lbm is the amount of mass that weighs one lbf on earth

    Since weight is the force of gravity on an objectweight = 1 lbm gravity1 lbf = 1 lbm 32.17 ft/s21 slugft/s2 = 1 lbm 32.17 ft/s2

    and therefore

    1 lbm =1

    32.17slug

    650:351 Thermodynamics Mahsa Mortazavi 8

  • Fundamental Units

    The dierences between lbm and lbf and slug are important Failure to understand the dierences can lead to an error of nearlytwo orders of magnitude and thus . . .

    650:351 Thermodynamics Mahsa Mortazavi 9

  • Fundamental Units

    The dierences between lbm and lbf and slug are important Failure to understand the dierences can lead to an error of nearlytwo orders of magnitude and thus . . .

    650:351 Thermodynamics Mahsa Mortazavi 10

  • Systems and Control Volumes

    A system is a quantity of matter or region of space A closed system comprises a xed amount of mass An open system is a properly selected region of space

    Closed system

    Closed system

    moving boundary

    Open system

    650:351 Thermodynamics Mahsa Mortazavi 11

  • State and Equilibrium

    Thermodynamics deals with equilibrium states An equilibrium state represents a condition wherein there are nounbalanced forces or potentials in the system

    Thermal equilibrium implies that the temperature is the samethroughout the system

    Mechanical equilibrium implies that the net forces and moments onthe system are zero

    Phase equilibrium implies that the mass of each phase (e.g., solid,liquid and gas) remains constant

    Chemical equilibrium implies that the chemical composition of thesystem remains constant

    650:351 Thermodynamics Mahsa Mortazavi 12

  • State Postulate

    Once a sucient number of properties of a system are specied, theremaining properties can be determined

    As an example, consider the ideal gas equation

    pV = nRT

    For a given volume V, knowing the pressure p, and temperature T issucient to determine

    1

    the number of moles n

    The State Postulate

    The state of a simple compressible system

    is completely specied by

    two independent, intensive properties

    1R = 8.31447 kJ/kmoleK is the Universal Gas Constant

    650:351 Thermodynamics Mahsa Mortazavi 13

  • Processes and Cycles

    The change of a system from one state to another is a process The series of states through which a system passes from its initial tonal state is the path

    The path may be quasi-equilibrium or non-equilibrium

    Processes

    p V diagram

    650:351 Thermodynamics Mahsa Mortazavi 14

  • Steady Flow Processes

    During a steady ow process, the ow variables at a xed locationdo not change in time; however, they may change with position

    650:351 Thermodynamics Mahsa Mortazavi 15

  • Zeroth Law of Thermodynamics

    Two bodies in thermal equilibrium with a third body are in thermalequilibrium with each other (i.e., all have the same temperature)

    650:351 Thermodynamics Mahsa Mortazavi 16

  • Pressure

    Pressure is the average normal force on a small element of uid,either at rest or in motion

    The SI unit of pressure is the pascal (Pa)1 Pa = 1 Nt/m2

    There are several other units for pressureUnit Denition

    bar 10

    5

    Pa

    atm 101, 325 Papsi 6, 894.75 Pa

    The actual pressure is the absolute pressure The gage pressure is dened asp

    gage

    = p patm

    where p

    atm

    is 1 bar (1 atm)

    What does the pressure gage for an automobile tire measure ?

    650:351 Thermodynamics Mahsa Mortazavi 17

  • Variation of Pressure with Depth

    In a uid at rest the pressure varies linearly with depthdp

    dz

    = g

    where g = 9.8 m/s2, is the uid density and z is measured positiveupwards

    650:351 Thermodynamics Mahsa Mortazavi 18

  • Variation of Pressure with Depth

    Under hydrostatic (i.e., uid at rest) conditions, the pressure is thesame at all positions on a horizontal plane regardless of geometry,

    provided that the points are interconnected by the same uid

    650:351 Thermodynamics Mahsa Mortazavi 19

  • Pressure Measurement Devices

    The barometer measures the atmospheric pressure provided that thegap at the top of the tube is a vacuum

    p

    C

    + gh = pB

    = patm

    thus p

    atm

    = gh if pC

    = 0

    Note: The pressure on the open uid surface is p

    atm

    . Since point B

    and the open surface are connected by the same uid, p

    B

    = patm

    650:351 Thermodynamics Mahsa Mortazavi 20

  • Manometer

    The manometer measures pressure in the same manner as thebarometer

    p

    1

    = p2

    = patm

    + gh

    since the open end of the tube is subject to p

    atm

    The specic gravity of a uid is dened bySG = uid

    /water

    650:351 Thermodynamics Mahsa Mortazavi 21

  • Manometer

    Note that pA

    = pB

    (Why ?)

    Therefore assuming the uid is the same tube is at rest

    p

    1

    + 1

    g (a+ h) = p2

    + 1

    ga+ 2

    gh

    and thus

    p

    1

    p2

    = (2

    1

    ) gh

    650:351 Thermodynamics Mahsa Mortazavi 22