modeling of ageing of li-ion battery at low temperatures

29
Avnish Narula ö ö

Upload: avnishnarula86

Post on 05-Dec-2014

108 views

Category:

Automotive


4 download

DESCRIPTION

Background The use of batteries in vehicles is increasing very strongly today. Still there remains a substantial amount of work regarding the ageing modelling of batteries. One specific ageing factor is operation at low temperatures, especially charging. The ageing processes lead to a drastically increased internal resistance, reduced power capability and capacity decrease. In this thesis, an equivalent circuit based ageing model will be implemented with focus on single Li-ion cells for resistance increase and capacitance decrease and the obtained values of the circuit components will be related to the electrochemical processes in the cells. The chosen Li-ion chemistry in this work is LiFePO4. Approximately 10 cells will be tested under realistic, but accelerating operating conditions. The specific ageing factor which is of interest in this work is charging at low temperature (-15°C …0°C).

TRANSCRIPT

Page 1: Modeling of Ageing of Li-ion battery at low temperatures

Avnish Narula ö

ö

Page 2: Modeling of Ageing of Li-ion battery at low temperatures

1

Page 3: Modeling of Ageing of Li-ion battery at low temperatures

2

Page 4: Modeling of Ageing of Li-ion battery at low temperatures

3

Page 5: Modeling of Ageing of Li-ion battery at low temperatures

4

Page 6: Modeling of Ageing of Li-ion battery at low temperatures

… …

° °

5

Page 7: Modeling of Ageing of Li-ion battery at low temperatures

7

6

Page 8: Modeling of Ageing of Li-ion battery at low temperatures

7

Page 9: Modeling of Ageing of Li-ion battery at low temperatures

… …

8

Page 10: Modeling of Ageing of Li-ion battery at low temperatures

°

9

Page 11: Modeling of Ageing of Li-ion battery at low temperatures

11

10

Page 12: Modeling of Ageing of Li-ion battery at low temperatures

®

11

Page 13: Modeling of Ageing of Li-ion battery at low temperatures

12

Page 14: Modeling of Ageing of Li-ion battery at low temperatures

°

°

°

°

°

°

°

°

°

°

13

Page 15: Modeling of Ageing of Li-ion battery at low temperatures

… …

)()(),( , TVSoCVTSoCV ocrefococ

14

Page 16: Modeling of Ageing of Li-ion battery at low temperatures

SoC

a

SoCa

oc eaSoCaaeaSoCV

1

5431

6

2)(

15

Page 17: Modeling of Ageing of Li-ion battery at low temperatures

16

Page 18: Modeling of Ageing of Li-ion battery at low temperatures

17

Page 19: Modeling of Ageing of Li-ion battery at low temperatures

18

Page 20: Modeling of Ageing of Li-ion battery at low temperatures

… …

19

°

Page 21: Modeling of Ageing of Li-ion battery at low temperatures

°

20

Page 22: Modeling of Ageing of Li-ion battery at low temperatures

21

Page 23: Modeling of Ageing of Li-ion battery at low temperatures

… …

22

Page 24: Modeling of Ageing of Li-ion battery at low temperatures

… …

23

Ω

Page 25: Modeling of Ageing of Li-ion battery at low temperatures

… …

24

Page 26: Modeling of Ageing of Li-ion battery at low temperatures

… …

°

°

25

Page 27: Modeling of Ageing of Li-ion battery at low temperatures

… …27

26

Page 28: Modeling of Ageing of Li-ion battery at low temperatures

© 28

Page 29: Modeling of Ageing of Li-ion battery at low temperatures