mould taper, heat transfer and spray cooling in high …

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MOULD TAPER, HEAT TRANSFER AND SPRAY COOLING IN HIGH SPEED CONTINUOUS CASTING BY JUNLONG FU B. A. Sc. University of Science and Technology Beijing, 1984 M. A. Sc. University of Science and Technology Beijing, 1987 A THESIS SUBMITTED IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF APPLIED SCIENCE in THE FACULTY OF GRADUATE STUDIES DEPARTMENT OF METALS AND MATERIALS ENGINEERING We accept this thesis as confirming to the required standard THE UNIVERSITY OF BRITISH COLUMBIA March 2001 © Junlong Fu, 2001

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Page 1: MOULD TAPER, HEAT TRANSFER AND SPRAY COOLING IN HIGH …

MOULD TAPER, HEAT TRANSFER AND SPRAY COOLING IN HIGH SPEED

CONTINUOUS CASTING B Y

JUNLONG FU

B. A. Sc. University of Science and Technology Beijing, 1984 M. A. Sc. University of Science and Technology Beijing, 1987

A THESIS SUBMITTED IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF APPLIED SCIENCE

in

THE FACULTY OF GRADUATE STUDIES DEPARTMENT OF METALS AND MATERIALS ENGINEERING

We accept this thesis as confirming to the required standard

T H E U N I V E R S I T Y OF B R I T I S H C O L U M B I A

March 2001

© Junlong Fu, 2001

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In presenting this thesis in partial fulfilment of the requirements for an advanced degree at the University of British Columbia, I agree that the Library shall make it freely available for reference and study. I further agree that permission for extensive copying of this thesis for scholarly purposes may be granted by the head of my department or by his or her representatives. It is understood that copying or publication of this thesis for financial gain shall not be allowed without my written permission.

Department

The University of British Columbia Vancouver, Canada

Date AT'1 ^ 1

DE-6 (2/88)

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ABSTRACT

Competition around the world and market expectations are driving the steel industry

to improve billet quality and lower costs by increasing casting speed of continuous

casters. The demand for high casting speeds can be achieved by increasing mould length

and by making upgrades to the secondary cooling system. A plant trial was conducted at

Co- Steel Lasco for the purpose of assessing the performance of a 1016 mm long mould

having a parabolic taper on the high speed casting of 6 grades of steel billets. The mould

was instrumented with 52 thermocouples. The billet section size was 178x127 mm, cast

at speeds in the range of 2.2-2.9 m/min. Additionally, three linear variable displacement

transducers were installed on the mould wall to monitor the mould oscillation. Billet

samples were collected for several operating conditions.

A n inverse heat conduction model was used to calculate mould heat fluxes from

measured mould wall temperatures. Existing mathematical models were employed to

investigate mould-billet interaction and the adequacy of the mould taper.

It was shown that steel carbon content and casting speed had significant effects on

heat flux in the mould. Heat flux was highest for medium carbon steel followed by high

carbon steel; low carbon steel had the least amount of heat transfer. Increases in casting

speed consistently led to heat flux increases, although not proportionately.

Off-corner internal cracks and narrow face concavity were noted on all billet samples.

It was demonstrated that the taper was too tight for the low carbon grades which caused

squeezing of the shell by the mould and was responsible for the off-corner internal cracks

and the narrow face concavity of the billets. For the medium and high carbon billets the

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mould taper was inadequate especially in the lower part of the mould. Here, it was likely

that bulging of the broad face and corner rotation gave rise to longitudinal depressions on

the narrow face and off-corner internal cracks. Optimum tapers were recommended

respectively for low carbon, medium carbon and high carbon steels.

Spray cooling systems for three companies were also investigated. Billet surface

temperature was calculated with a mathematical model; the effect of surface reheating

between mould and spray cooling, between different spray cooling zones and between

spray cooling and radiation as well as the billet liquid pool depth were examined

It was shown that midway cracks can result from the billet surface reheating in the

secondary cooling zone. Additional spray zones and a longer spray chamber were shown

to decrease the occurrences of surface reheating and thereby mitigating midway cracking.

Finally, recommendations were made for a spray cooling chamber appropriate for high

speed casting.

in

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Table of Contents

ABSTRACT ii

LIST OF TABLES ix

LIST OF FIGURES x

LIST OF SYMBOLS xv

ACKNOWLEDGEMENTS xv i i .

CHAPTER 1 - INTRODUCTION l

CHAPTER 2 - LITERATURE REVIEW 4

2.1 Heat Transfer in the Mould 6

2.1.1 Mould with Different Lubricants 7

2.1.2 Influence of Superheat 8

2.1.3 Influence of Steel Grade 9

2.1.4 Influence of Casting Speed 10

2.2 Billet Shrinkage and Mould Taper in High Speed Casting 11

2.2.1 Billet Shrinkage in the Mould 11

2.2.2 Mould Taper 11

2.2.3 Mould Taper for High Speed Continuous Casting 13

iv

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2.3 Secondary Cooling Zone 14

2.3.1 Water Spray and Air-mist Spray 14

2.3.2 Factors to Influence the Heat Transfer of Spray Cooling Zone 15

2.3.3 Billet Surface Temperature and Reheating 17

2.4 Defects in Continuous Casting 18

2.4.1 Mechanical Properties of the Steel at High Temperature 20

2.4.2 Defects Related to the Mould 23

2.4.2.1 Oscillation Marks 23

2.4.2.2 Rhomboidit 24

2.4.2.3 Off-corner Internal Cracks 26

2.4.3 Defects Related to the Secondary Cooling Zone 27

2.4.3.1 Midway Cracks 27

2.4.3.2 Diagonal Cracks 28

CHAPTER 3 - SCOPE AND OBJECTIVES 30

CHAPTER 4 - INDUSTRIAL PLANT TRIAL 32

4.1 Caster Details and Nominal Operating Practice 32

4.2 Mould Temperature Measurement 33

4.3 Metal Level and Casting Speed 34

4.4 Mechanical Signals 34

4.5 Billet Samples 34

v

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CHAPTER 5 - RESULTS OF PLANT TRIALS 41

5.1 Billet Quality Evaluation 41

5.1.1 Surface Quality 41

5.1.2 Off-corner Internal Cracks 41

5.1.3 Off-squareness 41

5.1.4 Midway Cracks 42

5.1.5 Oscillation Mark Depth 42

5.2 Oscillator Performance 42

5.3 Mould Temperature 43

5.3.1 Mould Temperature Response 43

5.3.2 Time-average Mould Temperature Distribution 43

CHAPTER 6 - MODELLING OF MOULD HEAT TRANSFER 64

6.1 The Mould Heat Transfer Model 64

6.2 Heat Flux Calculation 67

6.2.1 Broad and Narrow Face Heat Flux Profiles 67

6.2.2 Comparison of Lasco Data with Results from Other Plants 68

6.3 Influence of Process Factors on Mould Heat Flux 69

6.3.1 The Influence of Steel Carbon Content on Mould Heat Flux 69

6.3.2 The Influence of Casting Speed on Mould Heat Transfer 69

6.3.3 The Influence of Cooling Water Velocity on Mould Heat Transfer. 70

6.3.4 The Influence of Oil Flow Rate on Mould Heat Transfer 70

6.3.5 The Influence of Superheat on Mould Heat Transfer 70

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6.3.6 The Influence of Metal Level on Mould Heat Transfer 70

6.4 Difference Between Heat Fluxes Predicted by Model and by Cooling Water 71

CHAPTER 7 - SHRINGKAGE CALCULATION AND MOULD

TAPER DESIGN 86

7.1 Mathematical Model of Billet Shrinkage 86

7.2 Shell Growth and Billet Surface Temperature 87

7.3 Billet Shrinkage 88

7.4 Mould Behavior and Billet Quality 89

7.4.1 Mould Taper and Related Defects 89

7.4.2 Mould Heat Transfer, Metal Level Fluctuations and Off-squareness 90

7.5 Taper Design 91

CHAPTER 8 - ANALYSIS OF HEAT TRANSFER IN SPRAY

COOLING 109

8.1 Plant Data 109

8.2 The Spray Heat Transfer Model 110

8.3 Results and Analysis 112

8.3.1 Shell Thickness and Surface Temperature 112

8.3.2 Surface Reheating 112

8.3.3 Metallurgical Length 113

8.3.4 Spray-related Defects 114

8.4 Sprays design 116

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CHAPTER 9 - CONCLUSION 128

REFERENCES

131

viii

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LIST OF TABLES

Table 4.1 Casting machine specifications 36

Table 4.2 Mould details 36

Table 4.3 Parabolic mould taper 37

Table 4.4 Summary of heat chemistry 38

Table 4.5 Casting parameter changes and billet sampling 40

Table 5.1 Billet surface evaluation summary 45

Table 5.2 Time-average temperature and standard deviation on inside curved wall 60

Table 5.3 Time-average temperature and standard deviation on left straight wall 60

Table 5.4 Time-average temperature and standard deviation on outside curved wall 61

Table 5.5 Time-average temperature and standard deviation on right

straight wall 61

Table 6.1 Heat flux analysis 75

Table 7.1 Shrinkage analysis 97

Table 7.2 Predicted mould tapers 108

Table 8.1a Supplied and calculated data of spray system from three companies 118

Table 8. l b (con't) Supplied and calculated data of spray system from three

companies 118

Table 8.2 Surface reheating and depth of liquid pool at different plants 120

Table 8.3 Alta Steel spray cooling design 124

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LIST OF FIGURES

Fig. 2.1 Three zones of heat removal in a continuous casting machine 5

Fig. 2.2 Heat transfer profile over the mould length 7

Fig. 2.3 Affect of carbon content on mould heat flux 9

Fig. 2.4 Heat flux down the length of the mould for various casting speeds 10

Fig. 2.5 Influence of surface temperature on spray heat-transfer

coefficient, h 16

Fig. 2.6 Influence of water flux on spray heat transfer coefficient 17

Fig. 2.7 Schematic drawing of strand cast section showing different types of cracks 20

Fig. 2.8 Scanning electron micrograph of surface of a crack formed near the

solidus temperature. The inclusions are sulfides 22

Fig. 4.1 Thermocouple layout (all faces) 39

Fig. 5.1 Photograph of longitudinal depression on a billet sample from heat 664, medium carbon steel 46

Fig. 5.2 Lasco Steel Trial December 1998, narrow face concavity and midway cracks (High carbon steel, 1.99m/min, heat 665) 47

Fig. 5.3 Lasco Steel Trial December 1998, midway and off-corner internal

cracks (Low carbon steel, 2.59m/min, heat 643) 48

Fig. 5.4 The influence of steel carbon contents on off-squareness 49

Fig. 5.5 Oscillation marks for low, medium and high carbon steel 50

Fig. 5.6 The measured mould velocity calculated from the measured mould displacement for normal casting practice of a 0.2 % C

steel cast at 2.16 m/min for heat 668 51

Fig. 5.7 Mould thermal response of thermocouples located on the inside of the curved wall for heat containing 0.155 pet. carbon during casting speed change at approximately 1480 s 52

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Fig. 5.8 Mould thermal response of thermocouples located on the inside of the curved wall for heat containing 0.155 pet. carbon during casting speed change at approximately 1480 s 53

Fig. 5.9 Mould thermal response of thermocouples located on the left straight wall for heat containing 0.155 pet. carbon during a casting speed change at approximately 1480 s 54

Fig. 5.10 Mould thermal response of thermocouples located on the left straight wall for heat containing 0.155 pet. carbon during a casting speed change at approximately 1480 s 55

Fig. 5.11 Time-averaged mould temperature distribution on the inside curved wall for heat 642 containing 0.155 pet. carbon 56

Fig. 5.12 Time-averaged mould temperature distribution on the outside curved wall for heat 642 containing 0.155 pet. carbon 57

Fig. 5.13 Time-averaged mould temperature distribution on the left straight wall for heat 642 containing 0.155 pet. carbon 58

Fig. 5.14 Time-averaged mould temperature distribution on the right straight wall for heat 642 containing 0.155 pet. carbon 59

Fig. 5.15 Time-averaged mould temperature distribution on the inside curved wall for heats containing carbon levels of 0.157 and 0.412 pet. respectively 62

Fig. 5.16 Time-averaged mould temperature distribution on the inside curved wall for heat 664 containing 0.412 pet. carbon for casting speeds of 1.85 and 2.29 m/min respectively 63

Fig. 6.1 Schematic diagram of the midface longitudinal section of the mould wall 65

Fig. 6.2 Axial mould heat flux profiles for four faces of the mould for steel carbon content 0.155 pet. (heat 642) 72

Fig. 6.3 Axial mould heat flux profiles for four faces of the mould for steel carbon content 0.412 pet. (heat 664) 73

Fig. 6.4 Axial mould heat flux profiles for four faces of the mould for steel carbon content 0.767 pet. (heat 665) 74

Fig. 6.5 Comparison of axial mould heat flux profiles at three companies for high carbon steels 76

xi

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Fig. 6.6 Comparison of axial mould heat flux profiles at four companies for medium carbon steels 77

Fig. 6.7 Comparison of axial mould heat flux profiles at two companies for low carbon steels 78

Fig. 6.8 The influence of steel carbon content of average mould heat Transfer 79

Fig. 6.9 The influence of casting speed on axial mould heat flux profiles for a high carbon steel (heat 665) 80

Fig 6.10 The influence of mould water velocity on axial mould heat flux profiles (heat 645) 81

Fig 6.11 The influence of mould oil flow rate on axial mould heat flux

Profiles (heat 644) 82

Fig. 6.12 The influence of superheat on axial mould heat flux profiles 83

Fig. 6.13 The influence of metal level location on axial mould heat flux profiles on the outside curved wall (heat 685) 84

Fig. 6.14 Graph showing the match between predicted heat extraction rate in the mould and the heat extracted by the mould cooling water 85

Fig. 7.1 Mesh used for modeling one quarter of a transverse section of a billet 93

Fig. 7.2 Predicted billet surface temperature and shell thickness profiles for heat 642 containing 0.155 pet. carbon 94

Fig. 7.3 Predicted billet surface temperature and shell thickness profiles for heat 664 containing 0.412 pet. carbon 95

Fig. 7.4 Predicted billet surface temperature and shell thickness profiles for heat 665 containing 0.767 pet. carbon 96

Fig. 7.5 A comparison of mould and billet dimension for the broad and narrow faces of steel with carbon content 0.155 pet.(heat 642) 98

Fig. 7.6 A comparison of mould and billet dimension for the broad and narrow faces of steel with carbon content 0.183 pet.(heat 643) 99

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Fig. 7.7 A comparison of mould and billet dimension for the broad and narrow faces of steel with carbon content 0.412 pet.(heat 664) 100

Fig. 7.8 A comparison of mould and billet dimension for the broad and narrow faces of steel with carbon content 0.767 pet.(heat 665) 101

Fig. 7.9 Schematic diagram showing the development of concavity on the narrow face due to excessive squeezing at the corners 102

Fig. 7.10 Schematic diagram showing the formation of off-corner internal

cracks due to bulging at the broad face and rotation of the corners 103

Fig. 7.11 The influence of casting speed on off-squareness 104

Fig. 7.12 The relationship between off-squareness and temperature difference of adjacent faces of the mould wall at 950 mm below the top of the mould 105

Fig. 7.13 The relationship between off-squareness and standard deviation of the thermocouple near the meniscus 106

Fig. 7.14 Calculated mould tapers for the narrow face of the 5 x 7 inch

mould 107

Fig. 7.15 Calculated mould tapers for the broad face of the 5 x 7 inch mould 108

Fig. 8.1 Schematic drawing of transverse slice 110

Fig. 8.2 Temperature distribution and shell thickness in Alta continuous casting (low carbon steel, 152*152 mm 2 , casting speed 1.9 m/min) 121

Fig. 8.3 Billet temperature and shell thickness at Alta Steel, high carbon steel, 152x152 mm 2 , casting speed 1.9 m/min 122

Fig. 8.4 Billet temperature and shell thickness at McMaster Steel, low carbon steel, 150x150 mm 2 , casting speed 2.3 m/min 122

Fig. 8.5 Billet temperature and shell thickness at McMaster Steel, high carbon steel, 150x 150 mm 2 , casting speed 2.3 m/min 123

Fig. 8.6 Alta Steel: billet temperature and shell thickness for designed sprays high carbon steel, 203x203 mm 2 , casting speed 1.25 m/min 125

Fig. 8.7 Alta Steel: billet temperature and shell thickness for designed sprays low carbon steel, 203x203 mm 2 , casting speed 1.25 m/min 125

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Fig. 8.8 Alta Steel: billet temperature and shell thickness for designed sprays high carbon steel, 152x 152 mm2, casting speed 2.4 m/min 126

Fig. 8.9 Alta Steel: billet temperature and shell thickness for designed sprays low carbon steel, 152*152 mm2, casting speed 2.4 m/min 126

Fig. 8.10 Alta Steel: billet temperature and shell thickness for designed sprays high carbon steel, 120x120 mm2, casting speed 3.6 m/min 127

Fig. 8.11 Alta Steel: billet temperature and shell thickness for designed sprays low carbon steel, 120x120 mm2, casting speed 3.6 m/min 127

xiv

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LIST OF SYMBOLS

Cp specific heat (J kg"1 °C"')

Cpw specific heat of water (J kg"1 °C~l)

Cpm specific heat of mould (J kg"1 °C"')

dw width of cooling-water channel gap (mm)

Dh hydraulic diameter (m)

fs fraction of solid

h heat transfer coefficient (W m"2 °C~l)

hr effective heat transfer coefficient due to radiation (W m"2 "C"1)

hw heat transfer coefficient at the mould/cooling-water interface (W m"2 °C"1)

k thermal conductivity (W m'1 °C"')

k m thermal conductivity of mould walls (W m'1 °C"')

q heat flux (W m"2)

Qfc forced convection heat flux (W m"2)

t time (s)

tN negative-strip time (s)

T a ambient temperature (°C)

T s temperature of billet surface (°C)

T w temperature of water (°C)

V w velocity of cooling water in channel (m/s)

W spray water flux (/ m"2 s"1)

x, y, z spatial coordinates

p density (kg in"3)

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u. viscosity of fluid (N s m"2)

o Stefan-Boltzmann constant (5.6703xl0" 8 W m"2 K" 4 )

8 radiation emissivity

Subscripts

/ fluid

/ liquid

m mould

w water

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ACKNOWLEDGMENTS

I would like to express my sincere gratitude to my research supervisor Dr. Indira

Samarasekera for giving me an opportunity to work with her and for providing excellent

guidance and valuable encouragement throughout the course of my graduate study and

this research work. I also wish to thank the University of British Columbia and the

Natural Sciences and Engineering Research Council of Canada for the strategic research

project of high speed billet casting.

The assistance of staff and students of billet casting research group: M r . Neil Walker

and M r . Gary T. Lockhart who conducted the industrial plant trial, Baofeng Wang, Cindy

Chow, Joungkuil Park, are deeply appreciated. I am also grateful to Mary Jansepar, Joan

Kitchen, Dianfeng L i , Zhengdong L iu and Xuzhan Ren for their friendship.

xvii

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CHAPTER 1 -INTRODUCTION

CHAPTER 1 - INTRODUCTION

Continuous casting of steel has been established worldwide for about thirty years.

The process involves pouring of molten steel into a water-cooled copper mould and the

continuously withdrawing a partial solidified strand. The oscillation of the mould and a

constant supply of lubricant onto the mould wall are required to avoid sticking of the

solidifying shell to the copper mould. As soon as the solidified shell is sufficiently thick

to contain the liquid steel, the strand leaves the mould and is further cooled by water

sprays.'11

The technology of continuous casting always aims to increase the casting speed, that

means strand productivity, in conjunction with better internal and surface quality of the

cast product.'21 Recently many billet producers are seeking to operate at significantly

higher speeds by using longer moulds of the order of 1000 mm and effective secondary

cooling. Several machine builders , 2"4 ] have developed specific designs, generally based

on a longer mould tube, to achieve high casting speeds with oil or mould powder

lubrication. Casting speeds of 3.0 to 4.5 m/min have been achieved in billet castings. '3"5]

Furthermore, the casting speed of 5.0 m/min for low carbon steel with low viscosity

powder was also reported in a pilot continuous casting machine. ' 5 1 In order to cast high

quality billets with high casting speed, heat transfer in the mould and the interaction

between the mould and the strand must be emphasized. Heat transfer from molten steel to

the walls of the mould is controlled largely by conduction across the air gap which forms

as the solidified shell shrinks. To compensate for billet shrinkage, mould walls are

1

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CHAPTER 1 - INTRODUCTION

tapered inwards; the resulting reduction in the air gap improves the rate of mould heat

extraction and decreases the surface temperature of the billet at the mould exit and

thereby increases the thickness of the shell. The lack of sufficient taper, additionally, can

lead to the formation of off-corner cracks. On the other hand, an excessive taper can

cause difficulty in the withdrawal of the strand which promotes mould wear, and in

extreme cases, causes the billet to jam in the mould. The quantification of the strand-

mould gap is thus a primary step toward defining mould taper. The gap, however is a

complex function of several variables such as casting speed, steel grade, etc., which

renders it extremely difficult to characterize.

Mould taper has gained increasing attention from researchers in the field of billet

casting since Dippenaar et al 1 6 1 earliest work, especially for high speed billet casting.' 2 ' 4 1

The calculation and design of mould taper has been made possible in the Billet Casting

Research Group in U B C through the development of mathematical models. ' 1 9 ' 2 0 1

Spray cooling is used to extract up to 60 percent of the heat given up on solidification

of a continuous cast product at a conventional casting speed and is a key region for the

formation of many internal defects.'71 As a result of increasing casting speed, the

productivity of the continuous caster and the quality of the products cast depend largely

upon the settings chosen for the secondary cooling.' 8 1 Thus, spray cooling needs to be

carefully designed and controlled to achieve this effect. Strong spray cooling has been

used in high speed continuous casting of billets. The added heat extraction can induce

large temperature gradients at the surface of the billets which could adversely affect the

internal quality of the products. Additionally, a significant reheating of the billet surface

puts the solidification front under tension and creates a risk of midway cracks. Therefore,

2

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CHAPTER 1 - INTRODUCTION

spray systems must be carefully rearranged and evaluated in order to achieve higher

casting speeds.

In this study, a plant trial was conducted at Lasco Steel for continuous casting of six

carbon grade steel of billets. The axial heat flux profiles of the mould have been

calculated using a mathematical model developed at UBC based on temperature data

taken from an instrumented mould. The calculated heat flux profiles vary with steel

grade, casting speed and other operating parameters. Mould distortion, billet shrinkage

and mould tapers for each steel grade have also been quantified and assessed as they

impact internal billet quality. Finally, based on these determinations, optimum mould

tapers were recommended to the plant.

The secondary goal of this work was to understand spray cooling heat transfer in

high speed continuous casting. Spray cooling systems in several plants have been

investigated. Along with water flux data and an empirical formula, [ 3 8 ] the heat transfer of

spray cooling has been calculated using a mathematical model. Both the temperature

distribution of the strand and spray-related defects have been analyzed. New spray

cooling system was also designed for high speed casting at Alta Steel.

3

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CHAPTER 2 - LITERA TURE REVIEW

CHAPTER 2 - LITERATURE REVIEW

The continuous casting of steel is primarily a heat-extraction process. The conversion

of molten steel into a solid semi-finished shape involves the removal of: (a) superheat

from the liquid entering the mould from the tundish; (b) the latent heat of fusion at the

solidification front as liquid is transformed into solid steel, and (c) sensible heat from the

solid shell. These heats, or enthalpies, are extracted by a combination of heat-transfer

mechanisms: (a) convection in the liquid pool due to the input of momentum from the

tundish stream as well as buoyancy-driven flows; (b) heat conduction down temperature

gradients in the solid shell from the hot solidification front to the colder outside surface

of the strand; and (c) external heat transfer by conduction, convection and radiation in the

three major heat-extraction zones: mould, sprays (plus support rolls for larger sections)

and radiation cooling to the surroundings (Fig. 2.1).

Because heat transfer is the major phenomenon occurring in continuous casting and

also the limiting factor in the operation of a caster, it has been investigated by many

researchers [ 1 ( M 8 ] . The depth of the liquid pool obviously cannot exceed the maximum

metallurgical length (defined as the distance from the meniscus to the cut-off stand)

without cutting into a liquid core. Thus, the casting speed must be limited to allow

sufficient time for the heat of solidification to be extracted from the core. The casting

speed is also limited by the shell thickness at the exit of the mould, to prevent breakouts.

4

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CHAPTER 2 - L1TERA TURE REVIEW

ing

Fig. 2.1 Three zones of heat removal in a continuous casting machine m

Heat transfer not only limits maximum productivity, it also profoundly influences

steel quality, particularly with respect to the formation of surface and internal cracks. In

part this is because steel, like other metals, expands and contracts during periods of

heating or cooling; thus, sudden changes in the temperature gradient through the solid

shell, resulting from abrupt changes in surface heat extraction, causes differential thermal

5

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CHAPTER 2 - LITERATURE REVIEW

expansion and the generation of tensile strains. Depending on the magnitude of the strain

relative to the strain-to-fracture of the steel, cracks may form in the solid shell.

Considerable research has been done with respect to the relationship between heat

extraction and quality[35"37'45"62'. But it should be clear that control of heat transfer, rather

than simple maximization of heat extraction, is a key element of good casting practice for

the production of quality steel.

2.1 Heat Transfer in the Mould

Heat from the solidifying shell is transferred to the mould cooling water via a series

of thermal resistances: the air gap separating the mould and the strand, the mould wall,

and the mould/cooling interface. Heat extraction from the surface of the shell is governed

by the behavior and properties of the gap that forms as the cooling shell shrinks from the

mould. The rate limiting process is heat conduction across the gap; and therefore, the gap

width strongly affects the steel-to-mould heat flow. The gap width depends not only on

shrinkage of shell but also on the ferrostatic pressure which opposes to it. The interaction

between shrinkage and bulging of the shell causes the gap width to vary in both the axial

and transverse directions. In addition to this complication, the thermal conductivity of the

gap depends on the type of material filling it which in turn is a function of the mould

lubricant used. In the case of oil, employed for the casting of smaller section sizes, the

gap is filled with the gaseous pyrolysis products of the lubricant. However, if mould

powders are used, as in the case of bloom and slab casting, the gap contains condensed

material that is solid against the mould but may be liquid in contact with the steel.

6

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CHAPTER 2 - LITERATURE REVIEW

2.1.1 Mould with Different Lubricants

Oil lubricants lubricate the mould by wetting the mould wall; they then partially

break down owing to the high temperature and contribute to the atmosphere in the gap.

Mould powders, on the other hand, simply melt and wet the steel; the wetting is

controlled by interfacial forces. 1 2 2 1 The difference in behavior between the two types of

lubricants gives rise to different patterns of heat extraction.

<x> <x>

T o

2L

c d "S< a> T 3 <x>

1.6

u

1.2

1.0

0.8

0.6

0.4

0.2

0

Casting consumables: Oil

— Low-melting casting flux — * — High-melting casting flux

100 200 300 400 500 600 700 Distance from mould top edge in mm

L 5 Zones

8

Fig. 2.2 Heat transfer profile over the mould length 1 2 1 1

Fig. 2.2 shows the heat extracted per kg of steel in the mould for a 240 mm wide and

700 mm long test liner as a function of the mould length and at a casting speed of 600

mm/min, for lubricants of rapeseed oil, low-melting casting flux and high-melting casting

flux. The maximum heat flux in the region of the meniscus is reduced when employing

7

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CHAPTER 2 - L1TERA TURE REVIEW

high-melting casting flux. Subsequently, the heat flux decreases towards the mould exit,

followed by a slight increase in the final zone. The differences in heat flux resulting from

the different lubricant types are largest in the meniscus zone and decrease towards the

mould exit. For example, near the meniscus the heat extracted in mould with a low-

melting casting flux is around 25% greater than in the case of a high-melting flux. Using

rapeseed oil for mould lubrication has been found to produce a further overall increase in

heat transfer of 40%. A possible reason for the higher upper-mould heat flux with oil is

the presence of a hydrogen-rich atmosphere in the gap, due to pyralysis of the oil.

The lubrication mechanism in the mould for high speed casting [ 3 1 ] was assumed to be

liquid lubrication because the measured frictional force is in good agreement with the

values calculated from a liquid lubrication model. The upper limit of casting speed in the

continuous casting process with an oscillating mould has been predicted to be 5-8 m/min

on the basis of a comparison of the frictional force and the tensile strength of the

solidified shell beneath the meniscus.

2.1.2 Influence of Superheat

Generally it has been observed that an increase in superheat, within reasonable limits,

has a negligible effect on heat transfer in the mould. [ 2 3 1 However, the higher pouring

temperature retards solidification in the early stages, thereby reducing the strength of the

billet shell. It is also observed that, as the superheat is increased, the shell thickness at the

corners decreases. This suggests that high pouring temperatures will give rise to

increased breakouts.

8

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2.1.3 Influence of steel grade

The effect of steel composition and particularly carbon content on the overall mould

heat transfer has been reported from several sources. [ 2 4 ' 2 5 ] These investigations have

revealed that the mould heat flux is a minimum when casting a 0.10% C steel, and varies

only slightly above 0.25% C in steel, as shown in Fig. 2.3. The effect of carbon content

on heat transfer leads to some quality problems being more acute within the carbon range

0.06 to 0.14% C (the peritectic range).

E

1800

<

if 1600

1 s UOO

2

0,8 C content in %

Fig. 2.3 Affect of carbon content on mould heat flux [24]

The breakout shells from several castings further revealed that the internal surface of

the skin of 0.10% C steel was rippled. The rippling effect decreased progressively with an

increase in carbon content; and above 0.40% C the inner surface was relatively smooth.

The effect of carbon on the appearance of the outer surface of the billets was found to be

the same.

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Grill and Brimacombe [ 2 5 1 have proposed a mechanism based on the 5-y-phase

transformation to explain these observations. They have pointed out that, compared to

higher carbon steels, 0.10% C steel undergoes the greatest solid-state transformation.

Since the transformation is accompanied by a contraction of 0.38%, 0.1% C steel

experiences a greater shrinkage than higher carbon steels. Air gaps then may form

intermittently because of this enhanced shrinkage and reduce the heat-extraction rate.

2.1.4 Influence of Casting Speed

Casting speed also has a marked effect on the distribution and mean heat flux in the

mould. Many investigators l l ' 2 4 ] have observed an increase in heat flux with an increase in

casting speed, as shown in Fig. 2.4.

200

£

X 3 < LU X

1001

CASTING SPEED

V . 1,3 (m/min) V-1.1 Y . I

v.o.a

0 100 200 300 400 500 600 700 DISTANCE DOWN MOULD (mm)

Fig. 2.4 Heat flux down the length of the mould for various casting speeds [i]

The average overall heat-transfer coefficient has also been noted to increase with

casting speed. Despite the increase in heat transfer rate with casting speed, it is important

10

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to note that the specific amount of heat extraction, Jkg"1, decreases, resulting in a net

decrease in shell thickness. It has been observed that the magnitude of temperature

fluctuations in copper mould plates increases with casting speed.

2.2 Billet Shrinkage and Mould Taper in High Speed Casting

2.2.1 Billet Shrinkage in the Mould

As previously mentioned, steel cools and shrinks in the mould and an air gap forms

between the mould and shell. Heat transfer from molten steel to the walls of the

continuous casting mould is largely controlled by the conduction across the air gap. The

air gap is a complex function of several variables and its width changes in both the

longitudinal and transverse direction which renders it extremely difficult to characterize.

Its magnitude is a primary step towards defining mould taper. Conversely, the mould

taper also influences the heat transfer and billet shrinkage in the mould. Furthermore, the

shrinkage of the billet is affected significantly by the grade of steel being cast,

particularly the low carbon grades where the contraction accompanying the solid-state

transformation from delta-ferrite to austenite phase must be taken into consideration.

2.2.2 Mould Taper

To minimize the air gap and improve heat transfer, moulds are tapered. The inward

mould taper which compensates for the shrinkage of the solidifying shell varies from no

taper to single taper, double taper and parabolic taper. Excessive taper can cause the billet

to bind in the mould; while moderate taper can result in an increase in heat transfer

between mould and billet. Although mould taper undoubtedly improves heat transfer and

reduces the surface temperature of the billet at the mould exit, excessive taper increases

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the resistance to withdrawal and exacerbates mould wear. In the limiting case, if the taper

is made too large, the billet can jam in the mould.

The conventional mould exhibits a maximum outward bulge near the meniscus. The

maximum bulge is located below the meniscus, so that the mould acquires a negative

taper above it and a positive taper immediately below. The negative taper at the meniscus

can cause defects, such as deep oscillation marks, non-uniform lubrication, and even the

possibility of breakout [ 2 6 " 2 9 1 .

Several researches [ 2 6 " 2 9 ] have revealed the strong influence of mould taper on the

depth and uniformity of oscillation marks on off-corner squareness and off-corner

internal cracks. More recent work , 5 9 ' also has shown that mould taper at the meniscus has

a profound effect on the local and overall heat extraction from steel, with consequences

for mould distortion and billet surface quality.

In the first published study of billet mould taper, Dippenaar et al l < 5 ] evaluated mould

tapers by estimating billet shrinkage. The two-dimensional transverse heat transfer model

originally presented by Brimacombe l 3 0 ] was used to calculate the temperature field in the

solidifying billet. The model assumed a constant thermal expansion coefficient. The

research concluded that larger gaps formed in the lower region of single-tapered moulds.

Calculations, based on axial profiles of measured mould heat extraction, shrinkage of the

cooling solid shell and mould distortion, have shown that double taper is desirable.

Chandra et al [ 5 9 ] modified the model to include a thermal-expansion coefficient

which was a function of temperature and carbon content. His work was particularly

important for calculating the shrinkage of peritectic steels.

1 2

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2.2.3 Mould Taper for High Speed Continuous Casting

In high speed casting, Danieli Co. 1 2 1 has developed a new technique. The key points

of the new technology are a new concept for cooling the mould and a new mould itself.

This new mould is called adaptable, because it is able to 'adapt' its original taper to the

billet shrinkage. This effect is controlled by the pressure of the mould cooling water.

High pressure, larger pressure drop and higher water velocity in the cooling channel are

used to improve the cooling conditions.

This innovative design allows a substantial increase in the casting speed. Moreover,

the mould is able to cast a wide range of steel grades without altering other process

parameters. The first design of the adaptable mould ( D A N A M phase 1, with a length of

780 mm and normal thickness of copper tube) permitted the casting of 130x130 mm

billets at 4.3 m/min, using open stream pouring. The billet quality results were equivalent

to or better than that for conventional continuous casting. The measured thickness of the

solid shell along the casting direction was similar to conventional casting at a lower

casting speed. It was reported that a thinner adaptable mould ( D A M A M phase2) of 1000

mm length, for speed of 6 m/min, would commence operation in the second half of 1995.

But published details of the trial are sparse.

For the purpose of improving productivity and billet quality, joint research was

conducted on high speed casting with a convex mould. [ 4 1 Beginning in September 1992,

a maximum casting speed of 3.5 m/min was achieved. The billet quality was found to be

superior which led to the claim that the convex mould was a proven technology.

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2.3 Heat Transfer in Secondary Cooling Zone

In the secondary spray zone below the mould, heat transfer by impinging water

droplets projected from a nozzle onto the strand involves boiling and the formation of a

steam layer against the steel. The water flux depends on the position within the spray

pattern, nozzle type, water pressure and the standoff distance. Interestingly, the rate of

solidification in the spray zone depends less on the external heat extraction than it does in

the mould because the solid shell is considerably thicker. As a result, conduction through

the shell becomes the rate limiting process and the primary effect of spray cooling is to

alter the temperature distribution through the shell.

2.3.1 Water Spray and Air-mist Spray

Beneath the mould of a continuous-casting machine, the moving steel strand is cooled

by banks of water sprays. The purpose of the spray cooling is to continue the heat

extraction and solidification initiated in the mould without generating tensile stresses of

sufficient magnitude to cause shape defects, surface cracks or internal cracks.

The water spray pattern impinging on the strand surface should cover as wide an area

as possible in order to prevent excessive local cooling in the strand shell. This purpose is

served by either employing hollow/full cone nozzles, either of which will provide a

square or round spray pattern, or flat spray nozzles | 3 2 ' 3 4 1 . The length of the spray chamber

may vary from as little as 0.5 m up to 6 m in the case of billet casters,' while extending to

10 m typically in slab casters, up to 17 m in high-speed slab casters. The sections are

usually divided into several smaller zones which can then be individually regulated.

Besides typical water spray cooling, an air-water spray has been applied recently. In

this system, cooling water is mixed with compressed air in a mixing chamber ahead of

14

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the nozzle, and the mixture emerges from the nozzle as a finely atomized, high-impulse,

wide-angled spray. This type of spray cooling is particularly suitable for high-grade steels

which are susceptible to cracking. Its more important advantages include a particularly

uniform cooling rate, a very wide volume flow control range (1:12), little danger of

nozzle clogging and fine water droplets for optimum cooling. l 3 3 ' 3 4 ]

2.3.2 Factors to Influence the Heat Transfer of Spray Cooling Zone

Heat extracted from the strand surface by water sprays has been measured by

researchers [ 3 4 ' 3 8 ] . Experiments have been conducted employing resistance-heated plates

which are spray cooled at steady state. Many spray variables influence the heat extraction

rate, q, usually expressed in terms of a heat transfer coefficient, h:

cj = hA(Ts-TJ (2-1)

where Ts is the surface temperature of the strand and Tw is the temperature of the spray

water. The heat transfer coefficient is obtained from experiments or plant measurements.

It mainly depends on the water flux. The strand surface temperature level decides the heat

transfer mechanism of transition boiling. The effect of variables such as nozzle type,

water pressure and nozzle-to-nozzle distance on spray heat transfer can be seen primarily

in terms of their effect on the spray water flux; whereas variables like water temperature

and steel surface temperature directly affect heat transfer.

Under normal continuous casting conditions, in which surface temperatures range

between 1300 °F (700 °C) and 2200 °F (1200 °C), surface temperature has only a small

effect on the heat transfer coefficient. As shown in Fig. 2.5, taken from the study of

Mizikar | 7 ] , increasing surface temperature causes the heat transfer coefficient to decrease

slightly. The relative lack of dependence of h on surface temperature, Ts, is characteristic

15

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of the film boiling region of the classical boiling curve. At lower surface temperatures,

below 1020 °F (550 °C), the heat transfer coefficient increases sharply as nucleate boiling

begins to take effect.

SURFACE TEMPERATURE. *F

Fig. 2.5 Influence of surface temperature on spray heat-transfer coefficient, h

The temperature of the spray water, Tw, does not have a large influence on the heat

transfer coefficient The measurements of Sasaki et al [ 3 8 ] have shown that an increase

in water temperature from 20 to 60 °C causes h to decrease by only about 14%.

A l l studies show that, in the temperature range of interest, the spray-water flux, W,

has the largest effect on the heat transfer coefficient. The experimental findings of the

different studies are shown in Fig. 2.6. Where it is seen that, with the exception of

Mizikar ' s results, the relationship is reported to be nonlinear.

16

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h=W"

Most researchers agree that the value of n lies between 0.5 and 1.0. [ 4 0 J

(2-2)

10 20

Water flux (gal/ft min)

30 40 50 60

8 V

c o

o w a.

NcioM tt ol o—© Sotoki •> ol O - O Albtrny**"**

* - * B o l l « ond Mourtou (lop tproy) 6 - £ 6 o l l t ond Mourtou (bottom sproy) x o-o-o

Minlio» ,'(ot 276 liPo) Miiikor^Jot 620 kPo)

-Mulltr ond Jtsehor 1 1

• —• Ishiguro tt o l " , _- __, „

H 5 0 0 e

o

—WOO 0

300

200 g

— 100 a. tn

Woter (lux. I/mi

Fig. 2.6 Influence of water flux on spray heat transfer coefficient[35]

2.3.3 Billet Surface Reheating

When the strand passes from a cooling zone with a high heat transfer rate to one with

a lower heat transfer rate, the surface temperature of the strand may increase. This is

caused by a relaxation of the large thermal gradients created during the high heat transfer

period and the subsequent accumulation of enthalpy at the surface of the casting.

It is generally agreed in practice that the change in surface temperature of the strand

below the mould should be as low as possible in order to avoid internal and surface

defects of the billet. Thereby both spray water flux and spray cooling length should be

17

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increased for high speed casting. The reheating effect must be limited, as it causes

thermally induced stresses that can result in cracking. Van Drunen and Brimacombe 1 3 7 1

have shown that such a reheating before complete solidification leads to the development

of tensile stresses at the solidification front; the strain reached is a function of the amount

of reheating and can exceed the fracture strength of the steel at the solidification front.

Although the actual reheat amount permitted seems to vary greatly with steel grade and

casting practice, some researchers | 8 ' 1 3 ' have suggested reheating limits. Several others

[38,39] n a v e c a ] c u i a t e a " t h e thermal stresses of the strand by different stress models.

Similarly, cooling rate should be limited.

It is proposed ' 3 ? 1 that because the ductility-to-fracture of steel at 1350 °C has been

reported to be 0.2-0.3 pet., and because the thermal expansion coefficient of common

steel grades is about 0.2 pet. per 100 °C, a surface reheat of 100 °C was likely to produce

cracks. Thus Brimacombe 1 3 7 1 recommended a maximum of 50 °C as a design criterion for

billet surface reheat. Furthermore for purposes of spray design, he proposed that the

surface temperature of the strand in the sprays should be maintained between 1000 °C

and 1100 °C to sustain a reasonable solidification rate.

2.4 Defects in Continuous Casting

The quality of the continuously cast billet is of great importance for further

processing of steel. The formation of cracks which may appear almost anywhere at the

surface or in the interior of the billets is one of the most serious quality problems. Surface

cracks are oxidized by air and, therefore, cannot reweld during rolling; i f they are not

removed by scarfing or grinding, surface cracks will lead to slivers or other types of

defects in the rolled product. Internal cracks are less susceptible to oxidation by contact

18

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with air but also can give rise to serious quality problems. Cracks that form just beneath

the surface may penetrate to the scale layer depending on the time the steel is at elevated

temperature or they may break through to the surface during rolling.

Owing to their deleterious influence on quality, cracks in continuously cast steel have

been investigated by many researchers I 3 6 , 4 4" 5 2 ' Many of the crack types in continuous

casting have been shown in schematic diagrams (Fig. 2.7).

The reason for the profusion of crack types lies in the nature of the continuous casting

process itself. Continuous casting has achieved widespread popularity because it is

capable of extracting heat at a remarkable rate with a combination of mould, sprays and

radiant cooling. The rapid cooling, however, results in steep temperature gradients in the

solid shell that can change rapidly and generate thermal strains as the shell expands or

contracts. In addition, because a semi-solid section is required to move through the

machine, it is subjected to a variety of mechanically induced stresses caused by friction in

the mould, roll pressure, ferrostatic pressure, machine misalignment, bending and

straightening operations. Depending on their magnitude, any of these stresses and strains

may result in crack formation.

Crack formation depends not only on the operating stresses and strains but also on the

mechanical properties of steel at continuous casting temperatures. Combining knowledge

of the strain induced in continuous casting and the ductility of steel at casting

temperature, we can get a clearer understanding of crack mechanisms which will help to

explain the known operating causes of, and solutions to, crack formation.

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Crocks in continuously cost steel

Internal crocks 1 Midway 2 Triple-point 3 Centreline 4 Diagonal 5 Straightening / bending 6 Pinch roll

Surface cracks 7 Longitudinal , mid -face 8 Longitudinal , corner 9 Transverse , mid-face

10 Transverse , corner I I S t a r

Fig. 2.7 Schematic drawing of strand cast section showing different types of

cracks | 3 6 ]

2.4.1 Mechanical Properties of Steel at High Temperature

The mechanical properties of steel at elevated temperatures are affected by several

variables: temperature, steel chemistry, structure, strain rate and thermal history.

Although many efforts 1 4 4 - 4 9 1 have been made, the strength and ductility of steel are

20

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imperfectly known under continuous casting conditions. There are three distinct

temperature ranges in which steel has low strength and/or ductility and is, therefore,

susceptible to cracking. There is ample evidence to indicate that at temperatures above

about 1340 °C both the strength and ductility of steel decline markedly. The low strength

and ductility seem to be due to the presence of liquid films in the interdendritic regions

which do not freeze until temperatures well below the solidus are reached [ 4 4 ' 5 0 ] . The

liquid films apparently contain high levels of sulfur, phosphorus and other elements

which have a segregation coefficient less than unity and which concentrate between the

growing dendrites. Evidence of liquid films can be seen in Fig. 2.8 which is a scanning

electron micrograph of the interior surface of a crack that formed near the solidus

temperature. The smoothness of the surface, with no signs of fracture, is indicative of the

presence of a liquid film at the time of crack formation.

The carbon content also affects the mechanical properties of steel just below the

solidus temperature. Morozenskii et al [ 4 7 1 have found that the strain-to-fracture and its

plastic component are a minimum for steel containing 0.17 to 0.20 pet carbon.

The second zone of low ductility in steel appears in the temperature range 800 to

1200 °C [ 9 ' 4 1 1 . The loss of ductility during cooling below 1200 °C strongly depends on the

Mn/S ratio and the thermal history of the steel. Increasing Mn/S increases the ductility of

the steel. The influence of thermal history is considerably more complicated.

Lankford | 4 6 ] has proposed that low ductility results from the precipitation of liquid

droplets of FeS in planar arrays at austenite grain boundaries, which are then paths of

easy crack propagation. Steels with Mn/S ratios above 60 are not embrittled because

sulfur is tied up in the stable phase, MnS , which precipitates in the matrix, and not

21

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predominantly at grain boundaries. The slower cooling rates improve the ductility even

with low Mn/S because manganese then has time to diffuse to the grain boundaries.

The third zone of low ductility is in the range of 700 to 900 °C. Generally, low

ductility is associated with soluble aluminum in the steel and the precipitation of A1N at

grain boundaries | 4 4 - 5 3 1 . l ida et al [ 5 1 ] have reported that A1N precipitation does not

proceed appreciably during cooling to as low as 800 °C, but can take place rapidly during

heating over the temperature range 700 to 1000 °C. On the basis of these findings, they

suggest that repeated cooling and reheating cycles which may occur in the spray chamber

could enhance A1N precipitation and lead to low ductility. Owing to the low temperatures

involved, the third zone of low ductility is seen to be a factor only in the formation of

surface or subsurface cracks.

2 2

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2.4.2 Defect Related to the Mould

The mould-related defects such as longitudinal depressions and cracks, transverse

cracks and depressions, laps, bleeds, rhomboidity, off-corner internal cracks are the major

quality problems encountered in continuously cast steel billets [ 3 6 > 4 4 ' 5 1 J The adverse

mould/strand interaction at the meniscus significantly influences these defects. Several

studies have focused on the meniscus region to understand the genesis of defects in

continuous casting. Surface cracks both transverse and longitudinal, observed at the

corner and midface locations in billets originate close to the meniscus [ 3 6 ' 5 1 ] . Defects such

as off-corner internal cracks and rhomboidity have been linked to the depth and

uniformity of oscillation marks | 2 7 ' 5 6 ' which form at the meniscus. Laps and bleeds in high

carbon steels are also thought to be caused by adverse mould/strand interaction at

[53,561

meniscus1 .

2.4.2.1 Oscillation Marks

Oscillation marks form at the meniscus (the site of initial solidification), because of

the mechanical interaction between the mould and strand during the negative strip period.

Although oscillation marks have not been considered a quality problem in the past, it is

clear | 2 7 - 5 6 ] that they are implicated strongly in the formation of off-squareness, off-corner

internal cracks, transverse cracks, bleeds in the mould and breakouts below the mould. In

an off-square billet, the oscillation marks are nearly always deeper at one or both of the

obtuse-angle corners as compared to the acute-angle corners. The effect of a deep

oscillation mark is to locally widen the shell/mould gap, retard heat extraction by the

mould and reduce the solidification rate. Thus the shell at obtuse angle corners is thinner

and emerges from the mould hotter than the acute-angle corners which, in practice, may

23

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be so cold as to appear black. Sprays impinging on the billet below the mold then may

pull the billet off-square owing to differential cooling of the hot and cold regions. The

influence of non-uniform oscillation marks applies equally to the formation of off-corner

internal cracks which generally are located 4-6 mm from the surface and about 15 mm

from the corner.

There are several factors that influence the depth and uniformity of oscillation

marks'271. Reducing negative-strip time down to 0.12 s decreases the depth of oscillation

marks and improves the uniformity of the marks between mid-face and off-corner

locations. Increasing superheat causes the oscillation marks at the mid-face to become

shallow while those at the off-corner remain essentially unaffected. The increasing

difference in oscillation mark depth between the two locations helps to explain the

dissimilarity in shell growth in the transverse plane and the formation of re-entrant

corners. Shallow oscillation marks at the mid-face also are promoted by a large positive

mould taper near the meniscus and by a thicker mould wall. More uniform oscillation

marks are observed with four-side, compared to two-side constraint of the mould tube

and by a large positive mould taper at the meniscus. All these observations can be

explained by a mechanism for oscillation mark formation based on the jamming of the

mould on the solidifying shell at the meniscus during negative strip and the resultant

buckling of the shell.

2.4.2.2 Rhomboidity

Rhomboidity could be a result of dimensional instability of the mould tube due to

boiling in the cooling channel caused by low cooling water velocity or due to deep and

non-uniform oscillation marks. The latter is caused by adverse mechanical interaction of

24

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the mould tube and the billet at meniscus. Factors that influence this are non-uniform

constraint of the mould tube at the top, long negative strip-times, inadequate upper taper.

Excessive distortion due to poor water quality is also a factor.

In an earlier study [ 5 7 1 on rhomboidity in billets, asynchronous boiling in the cooling

water channel was identified as an important contributor. A mechanism based on non­

uniform cooling around the billet periphery was proposed to explain the formation of

these defects in moulds.

Another mechanism was proposed to explain the generation of rhomboidity based on

oscillation mark formation and non-uniform heat transfer in the mould and the sprays [ 2 9 ] .

The problem begins with the formation of deep and non-uniform oscillation marks

around the billet periphery. In the vicinity of a deep oscillation mark, the rate of heat

removal is low due to a wide mould/strand gap. On the other hand, regions of the billet

having shallow oscillation marks experience higher rates of heat extraction. Thus, the

presence of non-uniform oscillation marks on the billet surface gives rise to markedly

different heat extraction rates around the billet periphery which ultimately leads to a non­

uniform solid shell. Thus, the billet exiting the mould, although reasonably square, has a

non-uniform solid shell. In the sprays, the colder portions of the strand, having a thicker

solid shell, tend to cool faster than the hotter regions because of the effects of unstable

boiling; the result is non-uniform shrinkage of the billet and rhomboidity.

Also, the metal level fluctuation affects oscillation mark formation, an event closely

linked to rhomboidity [ 2 9 - 5 2 1 . Furthermore, since the severity and orientation of

rhomboidity change randomly with time, it is possible that the problem has its roots in

metal level fluctuations.

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Another interesting aspect of rhomboidity is the effect of steel grade on its severity

[ 5 2 ] . The medium carbon grades experience more problems as compared to other grades

due to their high mould heat transfer and short freezing range.

2.4.2.3 Off-corner Internal Cracks

Internal cracks are sometimes observed near the corners of continuously cast billets.

In transverse sections the cracks are found normal to a given face and within 10-20 mm

of the corner | 6 1 ' 6 2 ' . The cracks are often associated with a longitudinal surface or off-

corner depression on the surface normal to an off-corner crack.

This defect may result from bulging of a given face and hinging of the shell about a

thin, weak off-corner. As bulging occurs, a hinging action develops near the colder and

stronger corners causing off-corner tensile stresses near the solidification front and

cracking. Because bulging is affected by mould taper, mould alignment, mould wear and

foot-roller guidance of the strand, these variables should affect the formation of off-

corner cracks. Since off-corner cracks extend into the upper-spray zones, the extent of

cracking may be reduced by increasing the water flux slightly, which reduces bulging and

imposes a compressive strain at the solidification front.

Off-corner cracks are also associated with rhomboidity and superheat. It has been

indicated that internal cracks are more severe with increasing superheat and increasing

rhomboidity. Besides, deep oscillation marks at off-corner regions cause local thinning of

the shell and contributes to formation of the cracks.

In general, the following observations in studies are important in understanding the

off-corner internal cracks:

1) A significantly thinner shell at the off-corner position than at the mid-face.

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2) Cracks start to form at about 5.5-12 s from the meniscus level which, in most

cases, is equivalent to a distance of from 250-500 mm down the mould; this

places the crack initiation event in the lower part of the mould or just below the

mould in the upper sprays.

3) An off-corner crack zone sufficiently far from the corner that it has the same

temperature as the midface region.

2.4.3 Defects Related to the Secondary Cooling Zone

Quality problems can also arise in the spray cooling zone in the continuous casting of

steel. Sprays can influence defect formation by generating tensile stresses, by altering the

strand temperature and hence, mechanical properties, by influencing the precipitation of

second phases which lower steel ductility, and by slightly influencing the solidification

rate [ 3 5 1 . Midway cracks and rhomboidity or diagonal cracks may take place in billet

casting by unsuitable spray cooling.

2.4.3.1 Midway Cracks

It is generally agreed that the excessive secondary cooling and a high casting

temperature are operating factors responsible for midway cracks [ 3 5 ' 3 6 ] . In addition, the

chemistry of the steel exerts an important influence; sulfur and phosphorus in particular

affect the crack susceptibility of steel.

Excessive spray cooling is a major factor in the formation of midway cracks because

it leads to subsequent reheating of the strand surface which provides the driving force for

cracking.'3 7 1 Reheating causes the surface to expand and this imposes a tensile strain in

the interior region of the solid shell which is weak and nonductile above about 1340 °C.

Viewed in a transverse plane, the tensile strain and stress run parallel to the surface, and

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thus, cracks will form perpendicular to the surface, depending on the magnitude of the

strain.

Strong reheating of the surface occurs whenever the rate of cooling decreases

abruptly such as below the spray chamber, between successive spray nozzles or below the

bottom of the mould. Obviously, the magnitude of reheating is very dependent on spray

cooling conditions.

High casting temperature has a large effect on the tendency to form midway cracks

because it influences the cast structure. A high casting temperature favors an enlarged

columnar zone extending inward from the surface at the expense of the central equiaxed

zone. Midway cracks are able to form much more easily between the dendrites in the

columnar zone which run perpendicular to the tensile stress, as compared to the equiaxed

zone.

2.4.3.2 Diagonal Cracks

Diagonal cracks are associated with rhomboidity. This type of crack usually runs

between obtuse corners of the rhomboid section 1 3 6 , 5 3 1 . Clearly, diagonal cracks result

from distortion of the billet which can arise if two adjacent faces are cooled more rapidly

than the other faces in the mould or secondary cooling zone. The contraction of the steel

in the vicinity of the colder faces generates a tensile strain, oriented diagonally between

these faces. If sufficiently large, the strain causes distortion and cracks to form at right

angles to the strain axis that is between the obtuse corners. The cracks form initially in

the high temperature zone of low ductility but may grow outward toward the corners

depending on the magnitude of the strain.

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To eliminate this crack formation, equal cooling on each of the four faces of the billet

must be achieved by good alignment between the mould and roller cages and suitable

arrangement and maintenance of spray nozzles.

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CHAPTER 3 - SCOPE AND OBJECTIVES

The literature on billet casting indicates that mould and spray cooling are the key to

increase casting speed for billets. In high speed casting of billets, more heat must be

extracted from the mould and spray cooling zones. Thus, light must be shed on heat

transfer in the mould and spray cooling. Furthermore, billet quality is strongly associated

with mould behavior, thereforethe interaction between mould and strand under different

operating parameters and its effect on the billet quality should be investigated carefully.

Since spray cooling also impacts on the generation of billet cracks, suitable secondary

cooling should be employed.

It is clear that there cannot be a universal mould taper through which all grades of

steel can be successfully cast at different casting speed, due to the different shrinkage of

the billet in the mould.

To examine the variables influencing on mould heat transfer and taper design in high

speed casting, plant trials were carried out in which an operating long mould was

instrumented with thermocouples and LVDT's . Spray cooling data have been collected in

three companies to understand the factors which influence the consequences of spray

cooling in high speed casting.

With the analysis of the collected plant trial data, the following objectives were

formulated:

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1. To study the heat transfer in a parabolic tapered mould for several carbon steel

grades and at various operating parameters during high speed casting of large

section steel billets.

2. To evaluate the interaction between the parabolic tapered mould and strand during

high speed casting of steel

3. To evaluate billet quality in relation to the operating parameters of the caster.

4. To study heat transfer in spray cooling zone and correlate internal billet quality

with spray cooling conditions.

5. To design a suitable spray cooling system appropriate for high speed continuous

casting of steel billets.

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4.1 Caster Details and Nominal Operating Practice

In December of 1998, an instrumented mould trial was conducted at Co - Steel

Lasco at Whitby, Ontario. A retrofitted mould was instrumented with 52

thermocouples, and mould temperature data was recorded for a total of nine heats. The

operating parameters of the continuous casting machine at Lasco are presented in Table

4.1 and details of the mould system in Tables 4.2 and 4.3. The section size investigated

was 178x127 mm, cast at speeds in the range of 2.2-2.9 m/min, as shown in Table 4.1.

The mould was Cu-Cr-Zr with a wall thickness of 13 mm and a length of 1016 mm (see

Table 4.2). The tube had a parabolic taper, which varied from 3.42 %/m at 127 mm

from the top of the mould to 0.56 %/m at the bottom of the tube, as presented in Table

4.3. Four of the heats monitored were low carbon (0.155-0.159 pet. Carbon) and one

each of the following five carbon grades, 0.169, 0.183, 0.204, 0.412 and 0.767 percent.

The compositions of the steels cast during the trial are presented in Table 4.4. A total

of 16 billet samples were gathered in order to assess the billet quality. Three L V D T ' s

were also installed on the mould housing with the objective of determining mould

oscillation and negative strip time.

The oscillator stroke was typically 9.525 mm while the frequency was set at 2.2 H z

for a casting speed of 2.03 m/min, as presented in Table 4.1. The negative strip time is

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0.148 s. Mould water velocity was calculated to be 14 m/s. All heats were cast using

Quacast oil.

4.2 Temperature Measurements

The instrumentation of billet moulds with thermocouples has been described

previously by Brimacombe et al. [ 1 4 ' 2 6 ] A copper mould tube was fitted with 52 single

element constantan thermocouples; 13 on each of the four faces at locations shown in

Fig. 4.1. The thermocouples were prepared by forming a bead on the end of constantan

wires with a TIG welder. Beads were filed flat to 0.3-0.4 mm thick. Heat shrink tubing

was applied to the wire to provide electrical isolation away from the bead end.

Threaded holes were prepared through the water baffle and halfway into the copper

mould wall. The bead side of the wires was inserted into the mould wall to a depth of

approximately 6 mm from the hot face and was held in place by threaded copper plugs.

Silicone sealant was employed to prevent water leaks through the baffle. The

constantan wires were then attached to insulated copper wires in the cooling water

plenum. Groups of wires were bunched together and passed through a water-tight seal

at the bottom of the mould housing. A copper wire attached to the mould supplied the

return current for the single element thermocouples.

In addition, four commercially available extrinsic copper-constantan thermocouples

were installed - one on the centerline of each of the four faces at the exit of the water

channels - in order to measure the outlet temperature of the cooling water. Two similar

thermocouples were also placed in the mould housing to measure the bulk inlet and

outlet water temperatures.

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The thermocouple signals were recorded with the Labtech Notebook (Version 7. 1.

1), a commercially available software package. The data acquisition system consisted

of an IBM-PC equipped with a Metrabyte multiplexer DAS-8 board and an EXP-16

expansion interface. This system had a resolution of 0.012 mV or approximately 0.5°C.

Thermocouple signals were sampled at a rate of 10Hz for each of the nine heats.

4.3 Metal Level and Casting Speed

The metal level and casting speed signals were obtained from the plant as a 4-20mA

signal and converted into a 0-20mV output. The signals were recorded at 10 Hz in

conjunction with the thermocouple signals.

4.4 Mechanical Signals

Three linear variable differential transformers (LVDT's) were placed on the top of

the mould housing. In this way, the mould vertical displacement, front-to-back and

side-to-side motions were measured. A second data acquisition system was used to

acquire these signals at a sampling rate of 100 Hz for 30s intervals during each heat.

4.5 Billet Samples

Sixteen billet samples were taken during the tests at steady operating conditions,

before or after a change in practice was made (see Table 4.5). Billet samples were

transferred to our UBC Lab for evaluation. All samples were shot blasted to remove

any oxide layer present prior to examination. The evaluation included a usual

inspection for surface defects such as bleeds and laps, oscillation mark appearance,

billet surface roughness, longitudinal and transverse depressions, inclusions and

pinholes. The oscillation mark depth for all billet samples were measured using the

U B C profilometer. The measurements were made at three locations on each of the

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straight sides of the billet samples - one along the centerline and two along the off-

corner positions, approximately 14 mm from each corner. The dimensional quality of

the billet samples was assessed in terms of rhomboidity or off-squareness. Finally the

billet samples were sectioned transversely. These sections were ground and etched in

order to reveal the presence of any internal defects such as midway and off-corner

cracking. The presence of internal cracks and rhomboidity are of particular interest to

this study (see below Chapter 7).

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Table 4.1 Casting machine specifications

Machine Type Curved Mould

Mould Length 1016 mm

Billet Size 177.8 x 127 mm2

Casting Speed 2.03 m/min

Lubricant Quacast Oil

Reoxidation Protection No

Nominal Meniscus Level 110 mm

Oscillation Type Sinusoidal

Stroke Length 9.525 mm

Oscillation Frequency 2.2 Hz

Negative Strip Time 0.148 s

Mould Lead 3.21 mm

Table 4.2 Mould details

Material Cu-Cr-Zr

Thickness 13 mm

Corner Radius 1/8 in

Construction tube

Taper parabolic

Mould Length 1016 mm

Baffle Gap 3/16 in

Constraint 4 sided

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Table 4.3 Parabolic mould taper

Distance F rom Top Distance From Top Taper (in) (mm) (%/m)

0 0 0.00 1 25.4 0.00 2 50.8 0.00 3 76.2 0.00 4 101.6 0.00 5 127 3.42 6 152.4 2.73 7 177.8 2.38 8 203.2 2.10 9 228.6 1.91 10 254 1.78 11 279.4 1.63 12 304.8 1.52 13 330.2 1.43 14 355.6 1.35 15 381 1.27 16 406.4 1.21 17 431.8 1.15 18 457.2 1.10 19 482.6 1.05 20 508 1.01 21 533.4 0.97 22 558.8 0.94 23 584.2 0.90 24 609.6 0.87 25 635 0.84 26 660.4 0.81 27 685.8 0.79 28 711.2 0.76 29 736.6 0.74 30 762 0.72 31 787.4 0.70 32 812.8 0.68 33 838.2 0.66 34 863.6 0.65 35 889 0.63 36 914.4 0.61 37 939.8 0.60 38 965.2 0.59 39 990.6 0.57 40 1016 0.56

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Table 4.4 Summary of heat chemistry

Element Wt (%)

Heat Number Element Wt (%)

642 643 644 645 664 665 668 685 686

C 0.155 0.183 0.157 0.169 0.412 0.767 0.204 0.159 0.154

M n 0.806 0.756 0.865 0.825 0.756 0.776 0.874 0.672 0.746

P 0.005 0.005 0.007 0.004 0.004 0.007 0.005 0.003 0.003

S 0.023 0.042 0.026 0.028 0.024 0.026 0.032 0.014 0.014

Si 0.214 0.203 0.245 0.220 0.166 0.167 0.221 0.182 0.196

Cu 0.391 0.443 0.354 0.431 0.434 0.486 0.324 0.205 0.315

N i 0.138 0.103 0.124 0.126 0.115 0.143 0.104 0.139 0.114

Cr 0.102 0.085 0.125 0.092 0.088 0.130 0.082 0.330 0.334

M o 0.036 0.028 0.031 0.029 0.029 0.038 0.027 0.031 0.034

Sn 0.013 0.012 0.012 0.013 0.013 0.019 0.011 0.011 0.012

V 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.023 0.028

Zn 0.013 0.014 0.009 0.008 0.010 0.010 0.014 0.010 0.012

A l 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.259

Mn/S 35.0 18.3 33.3 29.5 31.5 29.8 27.3 48.0 53.3

Mn/S i 3.8 3.7 3.5 3.75 4.6 4.6 3.95 3.7 3.8

Cu/Ni 0.36 0.23 0.35 0.29 0.26 0.29 0.32 0.68 0.36

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TOP

105 mm 135 mm 150 mm 165 mm 180 mm 195 mm

300 mm

450 mm

600 mm

735 mm

850 mm

900 mm

950 mm

Fig. 4.1 Thermocouple layout (all faces).

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Table 4.5 Casting parameter changes and billet sampling

Heat No.

C % S/E Practice T ime of Samples

642 0.155 9:00/9:53 C S p : 2.0 A 2.4 m/min (9:28). DT:10 .6 A 11 .7 °C. W . V . : 13.6 m/s

9:25 9:52:22

643 0.183 9:54/10:47 C S p : 2.44 A 2.34 A 2.59 m/min (10:00, 10:11). D T : 11.7 A12.8 °C , W . V . : 13.6 m/s. O i l F low: 60 A 90 ml /min (10:20)

10:14:22 10:42:35

644 0.157 10:48/11:42 CSp: 2.56 A 2.16 A 2.26 m/min (10:49, 11:00). D T : 12.2 A 11.1 A 10.6 °C , W . V . : 13.4 m/s. O i l F low: 90 A 60 ml /min (11:15)

11:05:41 11:34:25

645 0.169 11:43/12:37 W . V . : 14 A 12 m/s D T : 10.6 A12.2 °C (12:00)

12:20:10

664 0.412 10:30/11:24 C S p : 1.83A2.24 m/min (10:54). D T : 12.2A13.3 ° C , W . V . : 13.45 m/s. Nozz le Size: 16.5A18.5 mm.

10:51:54 11:16:02

665 0.767 11:25/12:29 CSp: 2.13 A1.75 (12:00) Nozz le Size: 18.5 A16.5 m m D T : 13.3 A12.2 °C , W . V . : 13.56 m/s. Composit ion Change

12:01:58 *

668 0.204 14:20/15:14 CSp: 2.18 A2.41 (14:31), W . V . : 13.56 m/s. *

685 0.159 9:20/10:25 Meta l Level : 121.9 A142.2 m m (10:11) W . V . : 14.25 m/s, D T : 11.1 A10.6 °C.

9:50:20 10:22:37

686 0.154 10:26/11:23 O.F. : 122 cpm (10:26), 156 (10:35) W . V . : 13.78 m/s, D T : 10.6A11.1 °C.

10:45:00 11:06:05

Note: W . V . - water velocity; D T - temperature difference between outlet and inlet water; CSp - casting speed, * - no time record. O.F. - oscillation frequency, S/E - heat start and end times.

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CHAPTER 5 - RESULTS OF PLANT TRIALS

5.1 Billet Quality Evaluation

5.1.1 Surface Quality

A summary of the surface evaluation is presented in Table 5.1. All billets, with the

exception of the 0.4 pet carbon grade, had bleeds and laps. Oscillation marks were

typically non-parallel and non-linear, which result from metal level turbulence at the

meniscus.

Two main defects evident on all the sections were longitudinal off-corner depressions

on the straight narrow faces and concavity, as shown in Fig. 5.1 and 5.2. The concavity

had an average width of 106 mm and was typically 0.7-2.5 mm in depth.

5.1.2 Off-corner Internal Cracks

Off-corner internal cracks were found on all billets, which can be seen in Fig. 5.3. On

the straight narrow faces, the off-corner internal cracks were located approximately 8.0

mm beneath the surface at the site of longitudinal depressions. The cracks were generally

located approximately 19.8 mm off the corner. Cracks were predominant on the straight

right narrow face, close to the outside curved wall on all the samples. Many of the

samples contained cracks at more than one off-corner location.

5.1.3 Off-squareness

Results of an off-squareness measurement, as determined by a difference in the length

of the diagonals of the billet samples are presented in Fig. 5.4. Two samples with high

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off-squareness were from a heat cast at the high speeds (2.65-2.75 m/min) and contained

0.18 pet carbon. The two other billet samples cast at corresponding speeds did not exhibit

high off-squareness, and had carbon contents of 0.154 and 0.159 pet respectively.

5.1.4 Midway Cracks

All billet samples contained midway cracks on the two narrow straight faces, as

shown in Fig. 5.2 and 5.3. Occasionally cracks were also seen on the broad curved faces.

Crack initiation was typically 12-15 mm and 20-26 mm below the surface with a few

exceptions. Crack length was typically 10-30 mm.

5.1.5 Oscillation Mark Depth

The oscillation mark appearances for different grades are shown in Fig. 5.5. It is

evident that the oscillation marks are deep for all grades in the 0.15-0.2 pet carbon range,

with oscillation marks at the mid-face typically of the order of 0.4-0.5 mm. The

oscillation marks are shallower for the 0.7 pet carbon grade, and are on average

approximately 0.16-0.21 mm at the mid-face. For the 0.4 pet carbon grade, the depths of

the oscillation marks are a little deeper at 0.19-0.25 mm. In all cases, the oscillation mark

depths are not uniform and vary along the billet length, with some marks twice as deep as

others. The pitches of the marks are also not uniform, indicating considerable metal level

fluctuations.

5.2 Oscillator Performance

Fig. 5.6 shows the mould velocity profiles during casting for a frequency of 129 cpm.

It is evident that there is some minor distortion of the mould velocity at the maximum and

minimum points. However it is not severe and does not alter the negative strip time

significantly.

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5.3 Mould Temperature

5.3.1 Mould Temperature Response

On each face, mould wall temperatures were recorded for twelve of the thirteen

installed thermocouples. A sample of the data recorded on the inside curved wall and the

left straight wall for 0.155 pet carbon grade (heat 642) during a casting increase, which

occurred at approximately 1480 s, is shown from Figs. 5.7 to 5.10. It is evident that

temperatures recorded 950 mm below the top of the mould are generally higher than at

the 900 mm location on inside curved wall. It is shown that the thermocouples located

below the meniscus (110 mm from the top of the mould) recorded a measurable increase

in average temperature immediately following the casting speed increase.

5.3.2 Time-average Mould Temperature Distribution

The average mould temperature and standard deviation were calculated for each

position. The results for heat 642, corresponding to 0.155 pet carbon, are shown in Figs.

5.11 through 5.14. It is evident that the maximum mould temperature is recorded about

25 mm below the meniscus at a location 135 mm below the top of the mould. On the

inside and outside curved walls, a minimum temperature was recorded at a location

betweenl35 and 200 mm below the top of the mould, whereas for the straight walls the

temperature decreased uniformly with no obvious minimum. It was also evident that on

the inside and outside curved walls the temperature recorded by the thermocouple located

950 mm below the top of the mould was always higher than at the 900 mm level. This

phenomenon was not seen on the straight faces and this difference between the broad

curved and narrow straight faces was consistent for all the heats monitored. The average

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temperatures and their standard deviations in each of four faces for heats 644, 686, 664

and 665 are shown in Tables 5.2-5.5.

Of all the variables examined, steel carbon content and casting speed had the most

significant influence on mould temperature and consequently heat transfer. Figs. 5.15 and

5.16 show the influence of steel carbon content and casting speed on mould temperature

monitored on the inside curved wall. It is important to note that the effect of carbon

content, for a change of 0.157 to 0.412 pet carbon, on mould temperature is considerably

larger than the effect of speed, for a speed change of 1.85 to 2.29 m/min.

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Table 5.1 Billet surface evaluation summary

Heat % C

#of Billets

Bleeds or Laps

Irregu­lar

Spacing

Non-Parallel

Non-Linear

Rough­ness

Depres -sions

Inclus­ions

Pinholes OIT-Corner Depress­

ions Heat % C

#of Billets

L R L R L R L R L R L R L R L R L R

642 0.155

2 2 2 2 2 1 l 2 1 2 2 0 0 0 0 0 0 2 2

643 0.18

2 1 1 2 2 2 2 2 2 2 2 0 0 0 0 l 0 2 2

644 0.16

2 2 2 2 2 2 2 2 2 2 2 0 0 0 0 0 1 2 2

645 0.17 '

1 1 1 1 1 1 1 1 1 1 1 0 0 0 0 0 1 1 1

664 0.41

2 0 0 2 2 2 2 2 2 0 0 0 0 1 2 1 2 2 2

665 0.77

2 1 2 2 2 2 2 2 2 0 0 0 0 1 2 1 2 2 2

668 0.20

1 1 1 1 1 1 1 1 1 1 1 0 0 0 0 1 0 1 1

685 0.16

2 1 1 2 2 2 2 2 2 2 2 0 0 0 0 0 0 2 2

686 0.15

2 1 1 2 2 2 2 2 2 0 0 1 1 0 0 2 2

Total 16 9 10 15 15 15 15 16 15 12 12 0 0 3 5 4 6 16 16

% Defects

56 63 94 94 94 94 100 94 75 75 0 0 19 31 25 38 100 100

Note: L - left side; R - right side.

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Fig. 5.1 Photograph of longitudinal depression on a billet sample from heat

664, medium carbon steel.

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Fig. 5.2 Lasco Steel Trial December 1998, narrow face concavity and midway

cracks (High carbon steel, 1.99m/min, heat 665)

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Fig. 5.3 Lasco Steel Trial December 1998, midway and off-corner internal

cracks (Low carbon steel, 2.59m/min, heat 643)

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i

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

Carbon (%)

Fig. 5.4 The influence of steel carbon contents on off-squareness.

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Fig. 5.5 Oscillation marks for low, medium and high carbon steel

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Fig. 5.6 The measured mould velocity calculated from the measured mould

displacement for normal casting practice of a 0.2 % C steel cast at

2.16 m/min for heat 668.

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Fig. 5.7 Mould thermal response of thermocouples located on the inside

curved wall for heat containing 0.155 pet carbon during casting speed

change at approximately 1480 s.

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Fig. 5.8 Mould thermal response of thermocouples located on the inside

curved wall for heat containing 0.155 pet carbon during casting speed

change at approximately 1480 s.

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Fig. 5.9 Mould thermal response of thermocouples located on the left straight

wall for heat containing 0.155 pet carbon during a casting speed

change at approximately 1480 s.

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Fig. 5.10 Mould thermal response of thermocouples located on the left straight

wall for heat containing 0.155 pet carbon during a casting speed

change at approximately 1480 s.

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<0 a.

180

160 4

140

120

E £ 100

8 0 4-

6 0

C % = 0 . 1 5 5 , M n % = 0 . 8 0 6 , P % = 0 . 0 0 5 , S % = 0 . 0 2 3 ,

S i % = 0 . 2 1 4 , C u % = 0 . 3 9 1 , N i % = 0 . 1 3 8 , C r % = 0 . 1 0 2

2 0 0 4 0 0 6 0 0

Thermocouple Position (mm) 8 0 0 1 0 0 0

Fig. 5.11 Time-averaged mould temperature distribution on the inside curved

wall for heat 642 containing 0.155 pet carbon.

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180

160

140

1 120

CL E

100 4-

80

60

C%=0.155, Mn%=0.806, P%=0.005, S%=0.023, Si%=0.214, Cu%=0.391, Ni%=0.138, Cr%=0.102

-+-

200 400 600

Thermocouple Position (mm)

800 1000

Fig. 5.12 Time-averaged mould temperature distribution on the outside curved

wall for heat 642 containing 0.155 pet carbon.

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180

160 4

140 4 o

% 120 k_ cu CL E a> *~ 100 4

80

6 0

C % = 0 . 1 5 5 , M n % = 0 . 8 0 6 , P % = 0 . 0 0 5 , S % = 0 . 0 2 3 ,

S i % = 0 . 2 1 4 , C u % = 0 . 3 9 1 , N i % = 0 . 1 3 8 , C r % = 0 . 1 0 2

2 0 0 4 0 0 6 0 0

Thermocouple Position (mm) 8 0 0 1 0 0 0

Fig. 5.13 Time-averaged mould temperature distribution on the left straight

wall for heat 642 containing 0.155 pet carbon.

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180

160 4-

140

o

is 120 0) CL E

100

80 4

60

C%=0.155, Mn%=0.806, P%=0.005, S%=0.023, Si%=0.214, Cu%=0.391, Ni%=0.138, Cr%=0.102

200 400 600

Thermocouple Position (mm) 800 1000

Fig. 5.14 Time-averaged mould temperature distribution on the right straight

wall for heat 642 containing 0.155 pet carbon.

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Table 5.2 Time-average temperature and standard deviation on inside curved wall

Position (mm)

Heat 644 (0.157 %C) .

Heat 686 (0.154 % C , CSp=2.53)

Heat 668 (0.204 %C)

Heat 664 (0.412 %C)

Heat 665 (0.767 %C) Position

(mm) CSp=2.26 ML=131 ML=111 CSp=2.32 CSp=2.13 CSp=1.99 Position

(mm)

T,°C Std T,°C Std T,°C Std T,°C Std T,°C Std T,°C Std

105 69.0 5.03 55.2 2.11 64.7 3.53 68.4 5.05 73.3 6.57 68.3 5.55 135 138.2 4.46 81.3 6.49 139.8 6.57 147.6 7.68 161.8 10.88 141.3 15.71 150 108.5 4.49 106.6 6.51 116.8 3.27 121.3 13.40 141.1 3.17 141.6 3.58 165 *** *** *** *** *** *** *** *** 138.2 10.36 137.3 14.11 180 119.5 4.12 121.2 5.34 115.2 3.70 113.2 5.03 156.8 5.31 149.6 6.92 195 118.6 4.14 124.6 5.89 120.7 3.79 107.4 4.17 151.1 4.07 143.8 6.18 300 117.2 4.24 121.5 4.54 120.7 3.46 118.2 3.57 152.7 5.24 148.7 6.86 450 113.8 3.30 123.6 3.87 121.4 3.47 116.9 3.35 131.5 6.96 136.2 5.7 600 100.2 5.54 102.9 3.09 100.7 3.49 103.6 6.22 *** *** *** *** 735 105.3 3.75 112.7 3.16 110.2 3.98 118.3 3.81 121.9 5.12 121.4 4.96 850 89.0 3.41 94.0 2.92 92.0 3.57 102.2 3.88 105.9 4.84 104.7 5.20 900 87.9 3.53 87.1 2.91 85.5 3.23 96.9 3.47 101.3 4.73 98.2 4.74 950 95.2 3.83 93.1 3.54 91.5 4.09 104.2 3.64 109.4 4.92 104.5 4.25

Note: Std - standard deviation; CSp - casting speed (m/min); M L - metal level (mm).

Table 5.3 Time-average temperature and standard deviation on left straight wall

Position (mm)

Heat 644 (0.157 %C)

Heat 686 (0.154 % C , CSp=2.53)

Heat 668 (0.204 %C)

Heat 664 (0.412 %C)

Heat 665 (0.767 %C) Position

(mm) CSp=2.26 ML=131 ML=111 CSp=2.32 CSp=2.13 CSp=1.99 Position

(mm)

T,°C Std T,°C Std T,°C Std T,°C Std T,°C Std T,°C Std

105 70.3 5.61 51.4 2.07 63.8 4.10 67.2 4.35 74.2 8.23 64.5 6.08 135 149.1 5.33 78.9 9.89 142.3 9.07 152.1 8.36 177.1 21.69 137.6 18.77

150 141.1 5.32 129.9 13.63 147.0 5.20 150.0 6.74 180.5 5.84 177.5 7.81

165 131.2 5.42 146.9 4.15 135.4 5.40 135.9 6.98 168.2 4.99 167.0 5.16

180 120.4 4.73 114.8 5.32 110.3 4.64 111.9 5.65 154.4 6.01 145.1 5.98 195 119.1 4.42 116.4 6.52 116.0 4.84 116.2 5.41 153.2 5.94 144.6 6.98 300 121.9 3.45 119.8 4.91 122.9 4.91 120.1 4.49 143.8 6.35 140.4 7.01 450 119.1 2.91 123.9 4.11 122.8 4.85 122.9 4.70 138.7 6.75 135.7 6.21 600 102.6 2.72 105.3 3.19 104.3 3.99 106.4 4.43 114.8 5.83 113.2 4.58 735 *** *** *** *** *** *** *** *** *** *** ***

850 87.5 3.17 92.4 2.85 91.3 3.79 94.5 4.86 103.7 5.60 99.52 4.67 900 89.1 3.26 88.7 2.81 87.9 3.72 90.4 5.07 97.5 5.46 93.0 4.33 950 81.5 2.96 87.4 3.20 86.9 3.95 86.9 5.44 96.6 5.82 89.9 4.97

Note: Std - standard deviation; CSp - casting speed (m/min); M L - metal level (mm).

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Table 5.4 Time-average temperature and standard deviation on outside curved wall

Position (mm)

Heat 644 (0.157 % C )

Heat 686 (0.154 % C , CSp=2.53)

Heat 668 (0.204 % C )

Heat 664 (0.412 % C )

Heat 665 (0.767 % C ) Posit ion

(mm) CSp=2.26 M L = 1 3 1 ML=111 CSp=2.32 CSp=2.13 CSp=1.99 Posit ion

(mm)

T,°C Std T,°C Std T,°C Std T,°C Std T,°C Std T,°C Std

105 64.5 4.86 52.7 2.92 60.7 3.52 64.4 4.86 69.6 7.02 64.6 4.78

135 132.3 4.84 76.3 8.27 132.5 6.77 140.5 7.11 153.8 11.73 141.9 14.59

150 115.8 5.13 114.9 10.35 136.5 4.11 127.5 6.12 146.7 7.18 160.1 5.50

165 99.0 4.15 145.7 4.08 134.2 4.94 106.6 6.26 143.4 8.73 154.5 6.92

180 106.6 4.29 124.9 4.48 118.0 4.09 98.6 6.66 132.4 7.57 140.7 6.15

195 119.8 4.88 132.5 6.13 129;0 4.50 105.8 7.61 146.8 8.35 151.0 8.35

300 111.8 3.66 114.9 4.59 115.2 3.94 110.4 4.19 142.1 6.61 145.2 5.99

450 102.9 3.19 113.8 2.64 111.0 3.37 109.4 3.61 122.2 5.16 122.5 4.79

600 108.1 3.32 113.9 2.55 111.3 3.78 114.0 3.85 123.7 5.30 122.6 4.51

735 *** *** *** *** *** *** *** *** *** *** *** *** 850 88.5 4.36 91.1 2.65 89.1 3.42 99.1 3.89 113.3 5.71 101.4 6.66

900 78.4 3.52 83.1 2.62 81.1 3.28 89.2 3.96 93.8 4.53 92.4 3.62

950 93.1 3.87 99.0 3.65 96.6 4.39 111.1 4.28 113.6 5.61 109.3 3.62

Note: Std - standard deviation; CSp - casting speed (m/min); M L - metal level (mm).

Table 5.5 Time-average temperature and standard deviation on right straight wall

Position (mm)

Heat 644 (0.157 % C )

Heat 686 (0.154 % C , CSp=2.53)

Heat 668 (0.204 % C )

Heat 664 (0.412 % C )

Heat 665 (0.767 % C ) Position

(mm) CSp=2.26 ML=131 ML=111 CSp=2.32 CSp=2.13 CSp=1.99

Position (mm)

T,°C Std T,°C Std T,°C Std T,°C Std T,°C Std T,°C Std

105 66.7 4.86 51.5 1.61 60.8 2.62 64.0 3.94 66.1 4.22 63.0 3.42

135 141.1 4.88 77.8 6.23 140.5 8.04 162.5 8.79 158.7 13.26 143.6 15.87

150 133.0 5.84 130.7 10.00 147.7 5.47 147.5 6.70 171.7 5.30 177.8 7.83

165 126.0 5.16 144.7 4.45 131.3 5.45 123.8 6.98 154.3 4.95 160.3 8.87

180 120.2 4.48 145.7 5.70 136.8 6.58 126.5 7.92 153.9 4.11 160.0 7.23

195 119.9 4.81 118.1 6.62 113.2 4.92 112.1 5.65 142.3 5.49 146.7 9.94

300 114.3 3.50 124.8 4.24 126.2 4.65 124.3 4.50 145.0 6.04 144.8 6.54

450 111.8 3.04 119.3 3.08 117.9 3.42 116.4 3.92 130.9 6.49 131.6 6.78

600 101.5 2.57 109.0 3.21 107.9 2.82 108.5 3.45 119.1 5.56 118.9 6.15

735 *** *** *** *** *** *** *** *** *** *** *** *** 850 87.3 2.50 94.8 2.14 93.1 2.95 95.22 3.18 104.8 5.65 101.6 6.72

900 85.0 2.81 93.2 2.47 91.5 3.01 93.23 3.04 101.7 5.50 97.1 6.43

950 87.6 2.93 93.9 2.98 92.7 3.68 95.1 3.00 101.9 6.02 96.9 7.40

Note: Std - standard deviation; CSp - casting speed (m/min); M L - metal level (mm).

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Fig. 5.15 Time-averaged mould temperature distribution on the inside curved

wall for heats containing carbon levels of 0.157 and 0.412 pet

respectively.

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60 4-

40 -I 1 1 1 1 A

0 200 400 600 800 1000

Distance from the T o p of the Mould (mm)

Fig. 5.16 Time-averaged mould temperature distribution on the inside curved

wall for heat 664 containing 0.412 pet carbon for casting speeds of

1.85 and 2.29 m/min respectively.

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CHAPTER 6 -MOULD HEAT TRANSFER CALCULATION

6.1 The Mould Heat Transfer Model

The two-dimensional steady heat transfer model t 5 8 ] was used to simulate heat

transfer process occurred in the mould wall. The model calculates heat flux and the

temperature distribution in a longitudinal section through the midface of the mould by

means of a finite difference method.

Fig. 6.1 shows a schematic diagram of the longitudinal section of the mould wall at

the midface of the mould wall.

The following assumptions were adopted in the formulation of the mathematical

model:

I. Transverse heat flow in a direction perpendicular to the longitudinal midface

plane is negligible.

II. Temperature variations due to mould oscillation and metal level fluctuations are

ignored, which make it permissible to employ the time-average temperature

distribution in the mould.

III. The top and bottom surfaces of the longitudinal midface plane are assumed to be

adiabatic.

IV. The cooling water channel extends to the top and bottom ends of the mould and

the cooling water is in turbulent plug-flow.

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V. Temperature dependence of the thermal parameters has not been taken into

account, as its effect on the mould heat transfer is negligible.

Z = 0 X=0 X=XM X

Z = Z F

Backing plate/ mould jacket

Z = Z M

Meniscus

Molten steel

Cooling water

Fig. 6.1 Schematic diagram of the midface longitudinal section of the mould

wall1581

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The governing differential equation for heat transfer in the mould wall can be written

as following:

d ( ,1,

d ( dT^ dx

Km \ DX ; dz

Km \ dz j

0

For plug flow, the heat transfer in the water channel yields:

PjJ.cpv (*XT(0, Z) - Tw (z)) = 0

The boundary conditions applied in the model are presented as follows:

i. Cold face of mould: x=0, 0<z<Zm

ox

i i . Top of mould wall: 0<x<Xm, z=0

and bottom of mould wall: 0<x<Xm, z=Zm

m dz

i i i . Hot face of the mould below the meniscus: x=Xm, Z/<z<Zn

-km — = q2{z) ox

iv. Hot face of the mould above the meniscus: x=Xm, 0<z<Zf

-km%- = h,(zXT(Xm,z)-Ta) dx

v. Inlet water temperature: z= Zm

T.„ = T

(6.1)

(6.2)

(6.3)

(6.4)

(6.5)

(6.6)

w a (6.7)

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The heat transfer between the copper mould wall and the cooling water can be

determined by forced convection due to the high cooling water velocity and cold face

temperature of the mould.

The convection heat transfer coefficient hfC is calculated at the average temperature of

water by the following correlation:

(hfM = 0.023 V J

r \ 0 A

cpfMf (6.8)

The heat flux Qfc for force convection is calculated as follows:

Qfc=hfc(Tw-T(0,z)) (6.9)

The mould wall was discretized in the X and Z directions as shown in Fig. 6.1 and

finite difference equations were set up for the configuration nodes using the governing

equation of heat transfer and boundary conditions.

6.2 Heat Flux Calculations

The heat transfer model was employed to calculate mould heat flux distributions from

the measured mould temperature data at steady state. The time-averaged axial mould

temperature was used as input to the model to determine the axial mould heat flux profile

at the centreline of the broad and narrow faces of the mould wall for a range of

conditions.

6.2.1 Broad and Narrow Face Heat Flux Profiles

Calculated heat flux profiles for the four faces of the mould are shown in Figs. 6.2,

6.3 and 6.4, for heats with carbon contents of 0.15, 0.41 and 0.77 pet respectively. The

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four faces behave differently especially at the meniscus and over most of the mould

length. In the case of the 0.15 and 0.41 pet carbon grades, the peak heat flux close to the

meniscus is highest on the inside curved faces, whereas the opposite is true for the high

carbon grade. The broad faces show greater variations in heat transfer along the length of

the mould than either of the narrow faces. Table 6.1 presents the average heat flux on

each of the four faces for all the heats monitored during the trial. From this data it is

evident that the mean heat flux of the inside and outside broad faces is consistently higher

than the average heat extraction on the narrow faces for almost all the heats with the

exception of heats 685 and 686; both heats had steel carbon contents of 0.15 pet.

6.2.2 Comparison of Lasco Data with Results from Other Plants

The axial mould heat flux profiles obtained for one of the straight walls for Lasco can

be compared with data obtained in previous plant trials [ 5 9 ] . Figs. 6.5, 6.6 and 6.7 present

comparisons for three steel grades with carbon contents of 0.7, 0.4 and 0.15 pet

respectively. For the medium and high carbon grades, it is evident that the heat flux

profiles obtained at Lasco are lower than Company C, which had a single taper of

0.4%/m at the meniscus. It has been shown in earlier studies [ 5 9 ] that a shallow meniscus

taper, of less than 2.0%/m, such as at Company C, gives rise to high mechanical

interaction between the mould and the solidifying shell at the meniscus and consequently

high heat transfer. The taper at the meniscus at Lasco was in excess of 3.4%/m, which

significantly reduces the mechanical interaction and meniscus heat transfer. Heat transfer

data for Company B is lower than that measured at Lasco. Note that the heat transfer

profile for the high carbon grade, 0.7 pet, at Lasco is identical to the results obtained at

Atlas for high speed billet casting (Fig. 6.5).

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6.3 Influence of Process Factors on Mould Heat Flux

6.3.1 The Influence of Steel Carbon Content on Mould Heat Flux

It is well known that steel carbon content has the strongest influence on mould heat

transfer, a result which was reconfirmed in this Lasco trial. Fig. 6.8 shows the influence

of steel carbon content on the average mould heat flux. Note that the average mould heat

flux is a maximum for the 0.412 pet carbon steel, and slightly lower for the 0.77 pet

carbon grade. By comparison, the average heat flux is significantly lower for the grades

containing carbon contents of less than 0.20 pet, with 0.155 pet carbon heats having the

lowest heat flux. Singh and Blazek ( 2 4 ] showed that peritectic steels with carbon contents

in the range of 0.08-0.14 pet have the lowest mould heat transfer, and found increasingly

higher heat transfer for steel grades with carbon contents above 0.20 pet This study

places the transition from low to high heat transfer, at approximately 0.20 pet carbon,

although insufficient data in the 0.20-0.40 pet carbon range precludes determination of

the exact carbon level at which the transition to higher heat transfer is completed.

6.3.2 The Influence of Casting Speed on Mould Heat Transfer

Fig. 6.9 shows the influence of casting speed on axial mould heat flux profiles, for

0.77 pet carbon steel. An increase in speed causes an increase in heat extraction over the

entire length of the mould. In this case, a 25% increase in casting speed, from 1.73 to

2.17 m/min for the high carbon grade gave rise to a 11.7% increase in the overall heat

transfer. Clearly the increase in heat transfer for a casting speed increase cannot

compensate for the reduction in residence time in the mould and subsequently, a

disproportional decrease in the average shell thickness of the billet at the exit of the

mould.

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6.3.3 The Influence of Cooling Water Velocity on Mould Heat Transfer

Mould cooling water velocity has a negligible effect on mould heat transfer, for

mould water velocities in the 12-14 m/s range, as can be seen from Fig. 6.10. In this

range, boiling in the cooling channel is unlikely and there is no permanent distortion of

the mould tube. Thus the heat transfer coefficient at the cooling water interface has a

minimal effect on mould heat transfer for cooling water velocities in excess of 12 m/s.

6.3.4 The Influence of Oil Flow Rate on Mould Heat Transfer

An increase in the oil flow rate from 60 to 90 ml/min has a negligible effect of mould

heat transfer as presented in Fig. 6.11.

6.3.5 The Influence of Superheat on Mould Heat Transfer

Increasing superheat gives rise to a small increase in axial mould heat transfer as

shown in Fig. 6.12. Higher superheat presumably results in a thinner billet shell which

reduces oscillation mark depth and the average dimension of the air gap between the

mould and the strand.

6.3.6 The Influence of Metal Level on Mould Heat Transfer

Metal level location appears to have some influence on mould heat transfer. Fig. 6.13

shows the effect of changing the metal level position from 111 to 130 mm on mould heat

transfer on the outside curved walls. Note that the peak heat flux at the meniscus

increases quite significantly. It also can be observed from Table 6.1 that the average heat

flux increases from 1693 to 1708 kw/m 2 for heat 685 when the metal level rises from 130

to 111 mm below the top of the mould, although the casting speed decreases from 2.60 to

2.51 m/min. This can be attributed to an increase in the effective heat transfer area of the

mould as the metal level rises.

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6.4 Difference Between Heat Fluxes Predicted by Model and by Cooling Water

Fig. 6.14 shows a comparison of the average heat extracted by the mould as predicted

from the mathematical model versus that calculated from measured inlet and outlet water

temperature difference data. The agreement is good, within less than about 12%, which

reinforces the validity of the values of heat transfer obtained through the use of the

mathematical model.

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C — 0.155 Mn-0.806 S — 0.023 Si — 0.214 Cu—0.391 CSp=2.21 m/min

-Inside

Lefthand

- Outside

Righthand

100 200 300 400 500 600 700

Distance from the Top of the Mould (mm)

800 900 1000

Fig. 6.2 Axial mould heat flux profiles for four faces of the mould for steel

carbon content 0.155 pet. (Heat 642)

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>< 2500 +

C — 0.412 Mn-0.756 S — 0.024 Si —0.166 Cu—0.434 CSp=2.13 m/min

-Inside

Lefthand

- Outside

- Righthand

100 200 300 400 500 600 700

Distance from the T o p of the Mould (mm)

800 900 1000

Fig. 6.3 Axial mould heat flux profiles for four faces of the mould for steel

carbon content 0.412 pet. (Heat 664)

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C — 0.767 Mn-0.776 S — 0.026 Si —0.167 Cu—0.486 CSp=1.99 m/min

-Inside

Lefthand

-Outside

Righthand

100 200 300 400 500 600 700

Distance from the T o p of the Mould (mm)

800 900 1000

Fig. 6.4 Axial mould heat flux profiles for four faces of the mould for steel

carbon content 0.767 pet. (Heat 665)

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Table 6.1 Heat Flux Analysis

Heat CSp Chemicals (%) Oil Tundish Temp. Heat Flux (kw/m2) w.v. (°C)

No m/min M.L. C Mn S Si Cu O.F. Avg. AT Avg. In Left Out Right

642 2.21 0.155 0.806 0.023 0.214 0.391 1543 42 1589 1609 1564 1596 1575

2.02 1490 1507 1447 1507 1500

2.39 1657 1686 1655 1661 1628

643 2.59 0.183 0.756 0.042 0.203 0.443 60A90 1532 31 1770 1782 1758 1798 1724

2.73 Oil-60 1800 1819 1753 1850 1776

2.72 Oil-90 1846 1856 1841 1888 1799

644 2.26 0.157 0.865 0.026 0.245 0.354 90A60 1542 40 1578 1589 1615 1566 1541

2.26 Oil-60 1565 1570 1612 1586 1523

2.26 Oil-90 1582 1600 1609 1568 1551

645 2.21 0.169 0.825 0.028 0.220 0.431 14A12 1536 36 1598 1621 1587 1614 1551

2.19 W.V.-14 1591 1607 1585 1631 1540

2.22 W.V.-12 1592 1625 1584 1603 1554

664 2.13 0.412 0.756 0.024 0.166 0.434 1538 62 2062 2086 2043 2100 1990

1.85 1947 1997 1928 1990 1873

2.29 2115 2134 2108 2161 2057

665 1.99 0.767 0.776 0.026 0.167 0.486 1513 68 1939 1990 1867 1963 1903

2.17 2020 2071 1951 2054 2005

1.73 1807 1883 1786 1847 1711

668 2.32 0.204 0.874 0.032 0.221 0.324 1538 44 1707 1709 1702 1722 1697

2.19 1668 1671 1707 1659 1670

2.43 1729 1698 1719 1731 1736

685 2.53 0.159 0.672 0.014 0.182 0.205 111A131 1534 28 1698 1693 1702 1688 1714

2.51 M.L.-111 1708 1706 1707 1694 1724

2.60 M.L.-131 1693 1655 1719 1687 1710

686 2.56 0.154 0.746 0.014 0.196 0.315 131A111 1524 18 1636 1615 1654 1628 1658 122A156

2.53 M.L.-131 1631 1609 1613 1648 1653

2.53 M.L.-111 1639 1618 1644 1639 1654 0.F.-122

2.56 O.F.-156 1640 1615 1657 1627 1659

Note: Oil— oil flow rate (ml/min); W.V.— water velocity (m/s); M.L.— metal level (mm); O.F.—oscillation frequency AT - super heat (°C).

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800

700 +

600

500

| f 400 Li-

| 300 f

200

100

0 0

COMPANY GRADE (C%)

LASCO 0.767

ATLAS 0.72

COMPANY C 0.56

200 400 600 800 Distance from the Top of the Mould (mm)

100

Fig. 6.5 Comparison of axial mould heat flux profiles at three companies for

high carbon steels.

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C O M P A N Y G R A D E (C%)

L A S C O 0.412 C O M P A N Y C 0.45 C O M P A N Y B 0.45 C O M P A N Y E 0.45

100 200 300 400 500 600 700

Distance from the Top of the Mould (mm)

800 900 1000

Fig. 6.6 Comparison of axial mould heat flux profiles at four companies for

medium carbon steels.

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4500

4000 4

3500

C O M P A N Y G R A D E

(C%) L A S C O 0.155

C O M P A N Y B 0.15

10 15

Time Below Meniscus (s)

20 25

Fig. 6.7 Comparison of axial mould heat flux profiles at two companies for

low carbon steels.

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2100

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

Carbon Content (%)

Fig. 6.8 The influence of steel carbon content of average mould heat transfer

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6000 C — 0 . 7 6 7 Mn-0 .776 S — 0.026 Si — 0.167 Cu—0.486 CSp1=2.17 m/min CSp2=1.73 m/min Superheat: 68 °C

200 400 600 800

Distance f rom the T o p of the Mould (mm)

1000

Fig. 6.9 The influence of casting speed on axial mould heat flux profiles for a

high carbon steel ( Heat 665).

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4500

4000

3500

— 3000 + CM

E 5 x 3

2500

L Z 2000 + -*-» CO iu

1 1500

1000

500

0 0

C — 0.169 Mn-0 .825 S — 0.028 Si — 0.220 Cu—0.431 CSp1=2.19 m/min

(V—14 m/s) CSp2=2.22 m/min

(V—12 m/s)

Superheat: 40 °C

200 400 600 800

Distance from the Top of the Mould (mm)

1000

Fig 6.10 The influence of mould water velocity on axial mould heat flux

profdes (Heat 645).

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3500 C — 0.157 Mn-0 .865 S — 0.026 Si — 0.245 Cu—0.354 CSp1=2.26 m/min

(Oil—60) CSp2=2.26 m/min

(Oil—90) Superheat: 40 °C

200 400 600 800

Distance from the Top of the Mould (mm)

1000

Fig 6.11 The influence of mould oil flow rate on axial mould heat flux profiles

(Heat 644).

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Fig. 6.12 The influence of superheat on axial mould heat flux profiles

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4000

200 400 600 800

Distance from the Top of the Mould (mm)

1000

Fig. 6.13 The influence of metal level location on axial mould heat flux profiles

on the outside curved wall (Heat 685).

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Fig. 6.14 Graph showing the match between predicted heat extraction rate in

the mould and the heat extracted by the mould cooling water.

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CHAPTER 7 - SHRINGKAGE CALCULATION AND MOULD

TAPER DESIGN

A n existing mathematical model of billet shrinkage was employed to calculate billet

shell growth and temperature distribution and to predict billet dimensions for the broad

and narrow faces. Taking into account mould distortion, these results were employed to

obtain ideal cold mould dimensions that would match the predicted billet shrinkage

profiles. The predicted cold mould dimensions have been compared with the cold

dimensions of the mould used during the trial to assess the adequacy of the taper

employed at Lasco.

7.1 Mathematical Model of Billet Shrinkage

The Billet Casting Group at U B C has developed a mathematical model ' 5 9 ] to describe

the heat transfer in a continuously cast strand and to calculate the shrinkage of the billet

as a function of its axial position in the mould. The model is based on the equation for

two-dimensional, unsteady-state heat conduction in one quarter of a transverse slice of

the strand (shown in Fig. 7.1) as follows:

The initial and surface boundary conditions, mathematically expressed, are as

follows:

d f K

ar N d f k

ar" dx

f K

dx , _j dy

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, = 0, 0 < x < y , 0<y<^, T(x,y) = Tp (7.2)

t>0, x = 0, 0<y<~, ~ks^- = q0 (7.3) 2 ox

X r)T t>0, y = 0, 0<x<-, -k— = qQ (7.4)

2

Assuming symmetrical heat flow at the center plane we have:

X Y ?)T t>0, x = —, 0<y<-, -ks — = 0 (7.5)

2 2 ' dx

Y X dT t>0, v = —, 0 < x < — , -k — = 0 (7.6)

* 2 2 s By

Equation 7.1 was solved, subject to the above initial and boundary conditions, by an

alternating direction implicit finite difference method.

The initial dimensions of the steel billet were taken as those of the distorted copper

mould at the meniscus. The effect of ferro-static pressure was neglected. The mechanical

behavior of the solidified shell was also neglected. Neither the strains imposed by the

stress field nor creep of the solidified shell is included in the model. The differential

coefficient of linear thermal expansion of steel was calculated by computing the amount

phases present from the phase diagram.

7.2 Shell Growth and Billet Surface Temperature

The calculated shell growth and predicted surface temperature profiles of the billets

for heat 642, 664 and 665 are shown in Figs. 7.2, 7.3 and 7.4 respectively. The shell

thickness at the exit of the 1016 mm long mould is about 11.5 mm for the 0.15 pet carbon

steel, 12.8 mm for the 0.41 pet carbon steel and 11.9 mm for the 0.77 pet carbon steel.

The midface temperature of the billet at the mould exit is approximately 1000 °C for the

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low carbon steel, 770 °C for the medium carbon steel (0.412 carbon pet) and 790 °C for

the high carbon steel. The temperatures on the broad face at the exit of the mould are

about 50 °C lower than those on the narrow face for all heats except for heat 685 and 686,

due to the higher heat fluxes on the broad face and corner effects, i.e., the heat fluxes are

lower around corner region. Apparently, increasing casting speed results in higher surface

temperature. However, it can be seen in table 7.1 that, although the casting speeds of

2.21-2.26 m/min in heats 642, 644 and 645 are about 12% lower than ones (2.51-2.56

m/min) in heats 685 and 686, there are no significant differences in midface temperatures

at the exit of the mould due to the fact that the superheats in the first three heats are 16 °C

higher than the later two. The higher superheat gives rise to higher surface temperatures

of the billet. The corner temperature of the billet at first declines quickly; soon after the

formation of the shell, an air gap forms due to the rapid cooling around corner of the

strand leading to the low heat extraction rate. Thus, reaching the lowest value of the heat

flow, the temperature rebounds. A noticeable result is the reheat of the narrow faces of

the billet at a depth of approximately 600 mm below the top of the mould. It is postulated

that at the 600 mm level, the narrow face concavity develops and causes a local reduction

in heat transfer.

7.3 Billet Shrinkage

Hot billet dimensions and those corresponding to an ideal cold mould were calculated

from a billet shrinkage model developed by Chadara, et al. [ 5 9 1 The results of the

calculations for the steel grades with carbon content of 0.155, 0.183, 0.412 and 0.161%

are presented in Figs. 7.5 through 7.8, along with the actual (measured) cold mould

dimensions in order to assess the adequacy of the taper employed at Lasco. In all cases it

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is evident that broad and narrow faces of the billet shrink differently (Table 7.1). It is

important to note that for the 0.155 pet carbon steel (Fig. 7.5), binding of the billet and

the mould is likely to occur over the entire length of the mould. On the other hand the

taper seems to be close to optimum for the 0.183 pet carbon grade (Fig. 7.6), while the

taper is clearly inadequate for the 0.412 and 0.767 pet carbon steels (Figs. 7.7 and 7.8).

Besides carbon content of the steel, mould heat flux, metal level and casting speed

also influence billet shrinkage. When the mould heat flux increases, billet shrinkage

increases due to greater thermal contraction resulting in markedly higher taper

requirements.

7.4 Mould Behavior and Billet Quality

7.4.1 Mould Taper and Related Defects

Recall the longitudinal off-corner depressions, off-corner cracks, and narrow face

concavity observed in the billet samples of Lasco plant trial. These defects are formed in

the mould and can be linked to inadequate mould tapers (Fig. 7.5). Evidently for the 0.15

pet carbon grades, there is binding on both the narrow and broad faces of the mould over

most of the mould length. The binding causes the mould to squeeze the billet at the four

corners. Since there is a greater mismatch between the billet and mould dimensions for

the broad faces, especially from 200-600 mm below the meniscus, the mould will

interact with the billet at the corners on the narrow faces more than at the center, as

shown in Fig. 7.9. This could result in the development of concavity observed on the

narrow faces. This appears to occur 600 mm below the meniscus, because the big binding

just begins at this location, causing the narrow faces to reheat and expand. Consequently,

tensile stresses would arise at the solidification front and cause the formation of off-

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corner internal cracks, as shown schematically in Fig. 7.9. The average depth of the

cracks observed below the surface is approximately 8.0 mm, which coincides with the

narrow face shell thickness at approximately 650 mm below the top of the mould and

with the maximum reheating of the narrow face shell.

The 0.41 and 0.77 pet carbon steel grades shrink considerably more in the mould and

there is no binding either on the broad or narrow faces of the mould as shown in Figs. 7.7

and 7.8. However, large gaps open up between the mould and the billet. The broad faces

are prone to bulging with increasing distance below the meniscus, because of increasing

ferro-static pressure. This could also cause rotation of the narrow face corners as shown

schematically in Fig. 7.10, leading to the generation of tensile stresses at the solidification

front and off-corner internal cracks, as described in earlier publications [ 6 1 ' 6 2 ] . This event

also seems to occur at around the 600-700 mm location below the top of the mould. The

accompanying narrow face reheating and dimensional expansion are significantly smaller

than for the low carbon grades.

7.4.2 Mould Heat Transfer, Metal Level Fluctuations and Off-squareness

In previous studies, [ 5 2 , 5 3 ' it has been shown that off-squareness is the worst in the

medium carbon grades (0.18-0.40 pet). High carbon grades are less prone to off-

squareness, while off-squareness is minimal in low carbon steels (0.08-0.14 pet). These

differences have been explained on the basis that the medium carbon steels have the

shortest freezing range and the highest mould heat transfer at the meniscus. Metal level

fluctuations result in significant variations in shell thickness around the mould periphery,

which is the origin of off-squareness. Low carbon steels have low heat transfer, while

high carbon steels have a long freezing range, both of which result in thinner shells at the

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meniscus. Thus metal level fluctuations give rise to minimal variations in shell thickness

around the mould perimeter, resulting in lower off-squareness.

The findings in this study support these earlier observations [ 5 2 ' 5 3 ] . Fig. 7.11 shows

that off-squareness is worse in the medium carbon grades and increase with casting

speeds, although the number of data points are not adequate for a rigorous statistical

analysis. A correlation between differences in temperature of adjacent faces of the mould

at the 950 mm level was observed as shown in Fig.7.12. The large temperature

differences are prone to the serious off-squareness of the billets. For the medium carbon

steels, there was also limited evidence suggesting that high off-squareness was related to

higher fluctuations in meniscus temperature, which is linked to greater metal level

turbulence as shown in Fig. 7.13. Meniscus turbulence had less of an effect on off-

squareness in the low and high carbon grades. These findings suggest that it would be

worthwhile to conduct a long term study to establish whether thermocouples located at

the meniscus, and at the bottom of the mould could be used to successfully detect off-

squareness quantitatively. This would provide a means of on-line detection of off-

sqareness and corrective action could then be taken.

7.5 Taper Design

Steel carbon content is the most important factor influencing the mould taper

requirements as presented in Figs. 7.14 and Fig. 7.15. These two figures compare the

optimum mould taper with the existing taper for the three grades that shrink differently -

0.15, 0.41 and 0.77 pet carbon. Fig. 7.14 shows narrow face dimensions (broad face

taper) and Fig. 7.15 shows broad face dimensions (narrow face taper). Clearly the

existing taper is too severe for the 0.15 pet carbon grade and inadequate for the other two

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grades. The heat flux for the 0.15 pet carbon steel is lowest and hence the billet shrinks

less than the other two grades.

Furthermore in the upper part of the mould, the narrow face shrinkage is higher than

the broad face shrinkage (hence a larger broad face taper is required) than lower down in

the mould where the reverse is true. Table 7.2 summarizes the taper requirements

calculated for each heat monitored during the trial.

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1 y

5

0.1) e o e——

Oj) e

) o o o o

) o o o (ij)

o

5 o o o o

3 o o o o

0.1)

y= Y/2

x = X/2

Fig. 7.1 Mesh used for modeling one quarter of a transverse section of a billet. [ 5 9 )

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0 100 200 300 400 500 600 700 800 900 1000

Distance from the Top of the Mould (mm)

Fig. 7.2 Predicted billet surface temperature and shell thickness profiles for

heat 642 containing 0.155 pet carbon.

9 4

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Distance from the Top of the Mould (mm)

Fig. 7.3 Predicted billet surface temperature and shell thickness profiles for

heat 664 containing 0.412 pet carbon.

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0 100 200 300 400 500 600 700 800 900 1000

Distance from the Top of the Mould (mm)

Fig. 7.4 Predicted billet surface temperature and shell thickness profiles for

heat 665 containing 0.767 pet carbon.

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Table 7.1 Shrinkage analysis

Heat No 642 643 644 645 664 665 668 685 686

CSp (m/min) 2.21 2.59 2.26 2.21 2.13 1.99 2.32 2.51 2.60 2.56 2.53

Chemicals (%)

C 0.155 0.183 0.157 0.169 0.412 0.767 0.204 0.159 0.159 0.154 0.154

Chemicals (%)

M n 0.806 0.756 0.865 0.825 0.756 0.776 0.874 0.672 0.672 0.746 0.746

Chemicals (%) S 0.023 0.042 0.026 0.028 0.024 0.026 0.032 0.014 0.014 0.014 0.014 Chemicals (%)

Si 0.214 0.203 0.245 0.220 0.166 0.167 0.221 0.182 0.182 0.196 0.196

Chemicals (%)

Cu 0.391 0.443 0.354 0.431 0.434 0.486 0.324 0.205 0.205 0.315 0.315

Parameters CSp 2.02-2.39

Oi l 6 0 -90

Oi l 90-60

W.V. 14-12

CSp 1.85-2.29

CSp 1.73-2.17

CSp 2.19-2.43

M . L . I l l

M . L . 130

M . L . 130

M . L . I l l

Tundish Temp. (°C)

Avg 1543 1532 1542 1536 1538 1513 1538 1534 1534 1524 1524 Tundish Temp. (°C) AT 42 31 40 36 62 68 44 28 28 18 18

Slirinkage Status

Narrow B N B B G G B — G N N B B Slirinkage Status

Broard B G B G — B G G G G G G G

Shell Thickness (mm)

Broad 11.43 11.35 11.33 12.03 12.69 11.84 11.70 ' 11.41 11.10 11.37 11.18 Shell Thickness (mm) Narrow 11.78 11.38 11.69 12.14 12.64 11.62 11.88 11.83 11.22 11.73 11.24

Billet Midfece Temp. (°C)

Broad 1004 958 1030 986 733 761 933 986 1016 1023 1021 Billet Midfece Temp. (°C) Narrow 1056 1026 1063 1042 817 821 994 1003 1025 1033 1043

Heat Flux (kw/m 2)

Broad 1603 1790 1578 1618 2092 1977 1716 1691 1671 1622 1628 Heat Flux (kw/m 2)

Narrow 1570 1741 1578 1569 2017 1885 1694 1708 1715 1656 1633

Note: O i l — O i l Flow Rate (ni/min); W . V . — Water Velocity (m/s); M . L . — Metal Level (mm);

B — Binding; G — Gap; N — Normal.

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96.2

94.8 -I £ 1 1 1 1 1 1 1 •• 1 h-l

0 100 200 300 400 500 600 700 800 900 1000

Distance from the Top of the Mould (mm)

66.8

-P 66.7 4

0 100 200 300 400 500 600 700 800 900 1000

Distance from the Top of the Mould (mm)

Fig. 7.5 A comparison of mould and billet dimension for the broad and

narrow faces of steel with carbon content 0.155 pct.(heat 642)

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96.2

0 100 200 300 400 500 600 700 800 900 1000

Distance from the Top of the Mould (mm)

66.8

66.7

65.8 -| \1 1 1 j 1 1—• 1 1 1 h1

0 100 200 300 400 500 600 700 800 900 1000

Distance from the Top of the Mould (mm)

Fig. 7.6 A comparison of mould and billet dimension for the broad and

narrow faces of steel with carbon content 0.183 pct.(heat 643)

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66.8

•g- 66.6

0 66.4 w c OJ

1 66.2

fl) 66 co T5 CO

T3 5 65.8 o

65.6

111 mm (M.L.)

hot billet dimension

cold mould dimension

current mould

-+-

C —0.412 Mn-0.756 S — 0.024 Si —0.166 Cu—0.434 CSp=2.13 m/min

Superheat: 62 °C

- t -

0 100 200 300 400 500 600 700 800 900 1000

Distance from the Top of the Mould (mm)

Fig. 7.7 A comparison of mould and billet dimension for the broad and

narrow faces of steel with carbon content 0.412 pct.(heat 664)

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96.2

Distance from the Top of the Mould (mm)

66.8

66.7 4-

0 100 200 300 400 500 600 700 800 900 1000

Distance from the Top of the Mould (mm)

Fig. 7.8 A comparison of mould and billet dimension for the broad and

narrow faces of steel with carbon content 0.767 pct.(heat 665)

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Fig. 7.9 Schematic diagram showing the development of concavity on the

narrow face due to excessive squeezing at the corners

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O f f Corner Rotation Longi tudinal Depression

Inadequate taper

Fig. 7.10 Schematic diagram showing the formation of off-corner internal

cracks due to bulging at the broad face and rotation of the corners.

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~ 84-

• Low Carbon

gHigh Carbon A Medium Carbon

2.1 2.2 2.3 2.4 2.5

Casting Speed (m/min)

2.6 2.7 2.8

Fig. 7.11 The influence of casting speed on off-squareness

12

10

E E, 0) o c V I 5 JO TO C o TO 2 4

«> Low Carbon

•H igh Carbon

A Medium Carbon

12 17 22 Temperature Difference (°C)

27 32

Fig. 7.12 The relationship between off-squareness and temperature difference

of adjacent faces of the mould wall at 950 mm below the top of the

mould.

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12

10

^ 6

a

o

• Law Carbcn HHoji Carbon AlVtedumCatcn

A

A

+ 2 4 6 8 10

Standard Deviation of Therrral Couple near Meniscus (°C) 12 14

Fig. 7.13 The relationship between off-squareness and standard deviation of

the thermocouple near the meniscus.

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Fig. 7.14 Calculated mould tapers for the narrow face of the 5x7 inch mould.

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Fig. 7.15 Calculated mould tapers for the broad face of the 5x7 inch mould.

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Table 7.2 Predicted mould tapers

Distance from Top of M o u l d (mm)

Taper (%/m) or Casting Speed (m/min) Distance from Top of M o u l d (mm)

H642 H643 H644 H645 H664 H665 H668 H685 H686 Current

Narrow

1 0 1 . 6 - 2 0 3 . 2 2.20 2.62 2.30 2.33 3.45 3.11 2.41 2.49 2.38 2.65

Narrow 2 0 3 . 2 - 4 0 6 . 4 1.21 1.35 1.20 1.55 1.76 1.83 1.34 1.48 1.58 1.51 Narrow

4 0 6 . 4 - 1016 0.87 0.93 0.80 0.80 1.16 1.07 1.08 0.80 0.65 0.79

Broad

1 0 1 . 6 - 2 0 3 . 2 2.61 3.33 2.76 2.82 4.65 3.37 3.39 3.52 3.40 2.65

Broad 2 0 3 . 2 - 4 0 6 . 4 1.34 1.45 1.23 1.38 1.88 1.78 1.62 1.47 1.63 1.51 Broad

4 0 6 . 4 - 1016 0.56 0.54 0.51 0.61 0.76 0.66 0.63 0.68 0.56 0.79

C S p (m/min) 2.21 2.59 2.26 2.21 2.13 1.99 2.32 2.51 2.56 1.78/2.29

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CHAPTER 8 - ANALYSIS OF HEAT TRANSFER IN SPRAY

COOLING

Spray cooling systems in three plants have been investigated. The heat transfer during

spray cooling has been calculated employing a mathematical model. Both temperature

distributions of the strand and spray-related defects have been analyzed. The spray

system has also been designed for high speed billet casting at Alta Steel.

8.1 Plant Data

Spray cooling data provided by three companies have been analyzed. Parameters,

such as casting speed, spray chamber length, number of spray zones, nozzle types, nozzle

number, water pressure, nozzle stand off and water flow rate are shown in Tables 8.1a

and 8.1b. Tables also include the calculated data, for instance, heat transfer coefficients,

water flux and strand surface area of spray in different zones. It should be noted that the

heat transfer coefficients were calculated by formula (8-4) [ 3 8 ] and assuming 1000 °C for

the billet surface temperature.

The spray chamber lengths of casting in three plants vary from 1.2 to 3.04 m. The

spray systems usually consist of 2 or 3 zones. However, different nozzles and water flow

rate distributions are employed in each zone. In the Stelco McMaster case, the spray

chamber is divided into 3 zones; zone 1 consisting of 3 sub-zones and zone 2 and 3

consisting of 2 sub-zones respectively. In view of this design seven zones are used in

calculation and analysis. The water fluxes are arranged so as to decrease down the strand

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with the spray zones. The first zone supplies the largest water flux; the last one sprays the

smallest flux.

8.2 The Spray Heat Transfer Model

A two-dimensional mathematical model is to predict the temperature distribution and

shell thickness profiles of the strand. The model is based on the fundamental equation of

transient heat conduction, and on empirical data to characterize the complex heat

extraction processes at the surface of the strand in the different cooling zones. The

primary equation for the processes can be written as follows:

dt ox ox dy dy (8-1)

y q y (y=Y/2)

q x (x=X/2)

Fig. 8.1 Schematic drawing of transverse slice

The solution of above equation gives the temperature distribution in a transverse slice

of steel descending through the casting machine at the same withdrawal rate as the strand.

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A schematic diagram of the slice is shown in Fig. 8.1. The dark part is selected as the

calculation region due to symmetrical heat transfer of the strand.

The boundary conditions are the heat fluxes qx and qy. Considering symmetrical

cooling conditions, they are zero at the symmetrical axis (x=0, or y=0). On the surfaces,

they can be expressed in various ways depending on the cooling of the billet.

In the mould, the heat fluxes qx and qy can be obtained by measuring the mould

temperature in a plant trial or by an empirical formula.

In the spray cooling zone:

where Ta is the ambient temperature, a is Stefan-Boltzmann constant (5.6703xlCT8 W m"2

K" 4) and s is the radiation emissivity (e =0.8 for steel). ,

The initial condition is given by specified temperature at the meniscus (corresponding

with the tundish temperature).

The heat transfer coefficient h in spray cooling was decided by Sasaki's empirical

formula ( 3 8 ] , as shown in equation (8-4), and has been applied in the billet spray

calculation. The experimental conditions such as billet temperature range, scales of

pressure and water flow, are also indicated in the formula.

q = h(T-Tw) (8-2)

where Tw is the temperature of the cooling water, q represents qx and qy.

In the radiation zone:

(8-3)

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h = 70SW015TS~L2 + 0.116 (kw/(m2.°C) , l/m2.s)

(700<7;<1200oC, \.61<W<A\.61l/m2s, 196<pressure<490 kPa) (8-4)

A finite difference method is employed to solve the two-dimensional transient heat

conduction equation.

8.3 Results and Analysis

8.3.1 Shell Thickness and Surface Temperature

At earlier stage, the shell grows quickly in the mould, a little slower with the spray

cooling and then very slowly in the radiation zone as seen in Fig. 8.2. Near the bottom of

the liquid pool, the shell thickness increases rapidly due to a diminution in the latent heat

of solidification of the steel. Centerline segregation and cracks probably take place there.

After a rapid drop in the mould, the midface temperature of the strand keeps in a

certain range, usually from 1000 to 1200 °C, with some reheating when the strand goes

through the secondary cooling zone. It is evident that the surface temperature during

secondary cooling for low carbon steel is about 1100-1200 °C, 100 °C higher than that

for high carbon steel, as shown in Figs. 8.2 through 8.5. Besides, billet size, casting

speed, mould length and mould taper also impact the billet surface temperature during

spray cooling.

8.3.2 Surface Reheating

The surface temperature of the strand will increase when the strand passes from a

cooling zone with a high heat transfer rate to one with a lower heat transfer rate. This is

caused by a relaxation of the large temperature gradients created during the high heat

transfer period and subsequent accumulation of enthalpy in the surface of the casting.

Table 8.2 shows the correlation of surface reheating with casting speed, billet size, and

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steel grades in different plants. Although McMaster has the largest spray water flow rate

(180-202 USg/min.), the maximum surface reheating of the strand is the smallest

(104-147 °C) of all three plants. This is mainly due to the number of spray cooling zones

(7 sub-zones) employed, which decreases the surface temperature reheating. The longer

spray chamber, 3040 mm in McMaster, compared to 1200-2500 mm at the other plants,

has also contributed to the lower surface reheating for casting with oil lubrication. The

maximum surface reheating is 93-200 °C in Alta, and 84-238 °C in Atlas.

It also can be seen from Table 8.2 that the maximum reheating takes place at zone 1

and zone 2 in most cases (sub-zone 3 of zone 1 in McMaster). Thus, the strong spray

cooling is required just below the mould.

8.3.3 Metallurgical Length

The depth of the liquid pool has a significant influence on the formation of internal

cracks and formation of centerline segregation. Due to the rapid drop of center

temperature of the strand near the bottom of liquid pool and the low ductility of steel at a

temperature close to the solidus, the strand is very susceptible to cracks and centerline

segregation.

The depth of the liquid pool usually controls the position of the cutting torch. Among

various factors to influence the pool depth, casting speed and billet section size perform

important functions. The billet metallurgical lengths calculated for the different

companies are summarized in Table 8.2. When the casting speed increases from 1.9

m/min, for 152x152 mm 2 billet at Alta, to 2.3 m/min for 150x150 mm 2 billets at

McMaster, the pool depths increase about 1 m, from 15.78 to 16.94 m for low carbon

steel and 16.20 to 16.90 m for high carbon steel. Similarly, when the casting speed

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changes from 2 .9 to 4 .2 m/min for 1 2 0 x 1 2 0 mm2 billet at Alta and 1 1 0 x 1 1 0 mm2 billet at

McMaster, the pool depths increase about 3 m, from 1 6 . 4 9 to 19 .44 m for low carbon

steel and 1 7 . 0 0 to 2 0 . 0 9 m for high carbon steel. Comparing the pool depth of 1 2 0 x 1 2 0

(casting speed is 2 .9 m/min.) and 1 5 0 x 1 5 0 mm2 (casting speed is 2.3 m/min.) billets, the

pool depths are almost the same; i.e., 17 and 16 .9 m respectively. Pool depth increases

with the increasing of section size nearly compensates its increase with casting speed in

this case.

The distance from the top of the mould to the position of the cutting torch

(metallurgical length) is typically about 2 2 m for billet casting. For most cases shown in

table 8 .2, the calculated depths of the liquid pool are shorter than this distance. However,

the liquid depths of most strands are longer than the distances from the top of the mould

to the pinch rolls or unbending point. The mechanical deformation would have an adverse

effect upon the quality of the products. It should be indicated that McMaster supplied the

currently used spray cooling data for an expecting high casting speed, which causes the

calculated liquid depths are a little longer than the metallurgical length.

8.3.4 Spray-related Defects

. Several quality problems can arise in the secondary cooling of the continuous casting

of steel, including midway cracks and rhomboidity. Midway cracks can be detected in

sulfur prints and macroetches of transverse sections (Figs. 5.2 and 5 .3) . They are caused

by surface reheating of the strand. The mechanism of crack formation can be briefly

described as follows: Surface reheating forces the surface to expand and, in so doing,

imposes a tensile strain on the interior, hotter regions of the solidification front, which are

weaker and nonductile above 1 3 4 0 °C | 3 6 ] . The tensile strain and stress run parallel to the

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surface, and thus, cracks form perpendicular to the surface, depending on the magnitude

of the strain.

From the above description, it is clear that midway crack formation can be prevented

by minimizing the tensile strain; i.e., surface reheating. Minimization of the tensile strain

can be achieved by paying close attention to the design of the spray system to ensure that

the rate of cooling does not decrease abruptly between mould and sprays, sprays and

radiation cooling or between successive spray zones. Maintenance of the spray system is

also an important consideration because clogged or poorly positioned nozzles can cause

local reductions in cooling.

The other spray-related defect in billets is rhomboidity, although these problems may

be traced more frequently to the mould as shown in Fig 5.3. The cause of the rhomboidity

is unsymmetrical cooling, which can arise in the upper sprays if water pressure on all four

risers is not equal or nozzles are plugged or bent. Thus, if two adjacent faces are being

cooled more rapidly than the other faces, the billet contracts to generate a diagonal tensile

strain between the colder faces. If the strain is large, the billet distorts and takes on a

rhomboid shape with an acute-angle between the colder faces.

Rhomboidity formed in the mould may become worse in the spray zone. As stated

above, if the surface temperatures at the acute-corner of the billet is below 550 °C, the

heat transfer coefficient increases sharply as nucleate boiling begins to take effect.

Consequently the temperature at the acute-corner drops quickly including large tensile

stresses which menace rhomboidity. It is also conceivable that unsymmetrical spray

cooling may shift the strain within the mould to create non-uniform cooling in the mould.

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To minimize rhomboidity, care must be taken to achieve equal cooling on each of the

four faces. This requires good alignment between the mould and roller cages and

avoidance of plugged or bent spray nozzles in the secondary cooling zone.

8.4 Spray Design

The spray chamber of a continuous casting machine must fulfill important thermal

requirements if steel is to be cast efficiently with a minimum of internal or external

defects. The sprays must remove sufficient heat from the steel to virtually complete

solidification of the cast section. The rate at which the heat extraction proceeds is critical

to the smooth operation of the process, because undercooling can result in excessively

long liquid pools and overcooling can lead to the formation of cracks. The heat extraction

in the sprays must also be arranged to achieve a smooth transition of the surface

temperature, with a minimum of reheating, as the steel passes from the mould to the

sprays and from the sprays to the radiation cooling zones. Water flux distribution and

length of the spray chamber can be adjusted to optimize the performance of the sprays.

In order to determine the best design for a given casting parameters, Brimacombe'161

set two criteria to define the optimum thermal conditions: minimization of midway crack

formation and maintenance of a reasonably high solidification rate. The first condition

can be met by minimizing reheating of the surface of the strand either at or below the

sprays. The second criterion can be met by maintaining the surface temperature of the

strand in the sprays between 1000 and 1100 °C.

Alta Steel required increasing the casting speed by about 25%. To do this the spray

cooling system must be redesigned. The current spray chamber is 1866.9 mm long and

divided into two zones, where zone 1 is 444.5 mm and zone 2 is 1422.4 mm. Under this

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spray system reheating of the billet surface is very large (93 to 200 °C) at or below the

sprays.

The spray design was carried out employing a mathematical model. In order to

smooth the transition of the surface temperature and to achieve a reasonable liquid pool

depth for higher the casting speed, a three-zone spray chamber and extensive spray

cooling were employed. The new spray chamber is 3289.3 mm long. This new system

kept the surface reheating of the billet to less than 100 °C in the spray chamber and

radiation zone. Billet temperature distributions and shell thickness were presented in

Figs. 8.6 to 8.11. The surface temperatures of the billet were basically between 1000 and

1200 °C, 1000 to 1100 °C for the high carbon grade and 1100 to 1200 °C for the low

carbon grade in spray cooling zone for different billet sizes. The liquid pool depths were

shorter than the maximum metallurgical length. The different spray zone length, water

flux distributions in each zone and surface reheat at sprays and radiation are shown in

Table 8.3.

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Table la Supplied and calculated data of spray system from three companies

C o m p a n y At las McMas te r Al ta

Grades H-Carbon, Stainless LH-Carbon LH-Carbon

Lubricant Powder Oil Oil

Billet S ize (mm^) 114x114 146x146 254 x203 110x110 150x150 120x120 152x152 203x203

M o u l d Length(mm) 780 813 734

C S p (m/min) 1.9-2.7 1.2-2.8 0.65-0.85 4.2 2.3 2.9 1.9 1

Spray Length (mm) 1200 1200 1200 3040 3040 1866.9 1866.9 1866.9

zonel 200 400 200 38.1 38.1 444.5 444.5 444.5

zone2 1000 800 1000 76 76 1422.4 1422.4 1422.4

zone3 206.5 206.5

zone4 587.7 587.7

zone5 933.45 933.45

zone6 546 546

zone7 648 648

Nozzle Type

zonel 6515 Flat 5008 Flat 8008Flat 1/4flat 3/8gg 8.1 1/4gg 10 1/4gg 10 1/4gg 10

zone2 T63.5 Cone T63.5Flat 5004Flat 1/4hh-10

1/4hh 12.5 1/4gg 10 1/4gg 10 1/4gg 10

zone3 1/4hh-10 1/4hh 12.5

zone4 1/4gg 6.5 1/4hh6.5

zone5 1/8gg 5.0 1/8gg 5.0

z0ne6-7 1/8gg 5.0 1/8gg 6.1 Nozzle Number 28 28 24 112 112 48 48 48

zonel 8 12 8 8 8 16 16 16

zone2 20 16 16 8 8 32 32 32

zone3 8 8

zone4 28 28

zone5 36 36

z0ne6-7 24 24

Pressure (psi) 80 80 36 38 40

Stand Off (inch) 4.62 5 6.25

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Table 8.1b (con ' t ) Supplied and calculated data of spray system from three companies

Company Atlas McMaster Alta

Grades H-Carbon, Stainless LH-Carbon LH-Carbon Lubricant Powder Oil Oil

Billet Size (mm') 114x114 146x146 254 X203 110x110 150x150 120x120 152x152 203x203

Mould 780 813 734

CSp (m/min) 1.9-2.7 1.2-2.8 0.65-0.85 4.2 2.3 2.9 1.9 1

Water Flow (usg) 56-78 42-63 44-58 180.11 202.40 89 92 93 zonel 24-34 18-27 17-22 11.29 16.80 30 31 31

zone2 32-45 24-36 27-36 21.61 26.38 59 61 62

zone3 21.61 26.38

zone4 47.62 47.62

zone5 46.80 46.80

zone6 15.60 19.21

zone7 15.60 19.21

Area (m2) 0.55 0.70 0.61 0.49 1.34 1.82 0.90 1.14 1.51 zonel 0.09 0.23 0.10 0.08 0.02 0.02 0.21 0.27 0.36

zone2 0.46 0.47 0.51 0.41 0.03 0.05 0.68 0.86 1.15

zone3 0.09 0.12

zone4 0.26 0.35

zone5 0.41 0.56

zone6 0.24 0.33

zone7 0.29 0.39

Water Rux(L/m2/S) 7.72 4.77 3.00 2.75 8.49 7.00 6.27 5.11 3.87

zonel 20.06 6.21 6.83 8.55 42.47 46.37 8.87 7.24 5.42

zone2 5.26 4.05 2.24 2.79 40.76 36.49 5.45 4.45 3.39

zone3 15.00 13.43

zone4 11.62 8.52

zone5 7.19 5.27

zone6 4.10 3.70

zone7 3.45 3.12

H. Trans. C (kw/m2/ °C)

0.82 0.57 0.41 0.48 0.88 0.77 0.70 0.60 0.49

zonel 1.69 0.70 0.75 0.89 2.96 3.16 0.91 0.78 0.63

zone2 0.62 0.51 0.33 0.39 2.87 2.64 0.63 0.54 0.44

zone3 1.36 1.25

zone4 1.12 0.89

zone5 0.78 0.62

zone6 0.51 0.47

zone7 0.45 0.42

Heat Flux (kw/m2) 823.99 574.09 405.5 479.7 884.87 765.34 704.27 604.70 490.71

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Table 8.2 Surface reheating and depth of liquid pool at different plants

Plant Steel

grade

Billet size

(mm2)

Casting

speed

(m/min)

Water

flow,

(usg/min)

Max surface

reheating

broad/narrow

Location

for max

reheat

(zone)

Number

ofzone

Depth of

liquid

pool (m)

Distance from

meniscus to torch /pinch rolls (ni)

L C 203x203 1.0 93 131 air 2 12.8

H C 203x203 1.0 93 179 air 2 12.7

Alta L C 152x152 1.9 92 111 1 2 15.8 26.52/

H C 152x152 1.9 92 200 1 2 16.2 8.28

L C 120x120 2.9 89 93 1 2 16.5

H C 120x120 2.9 89 177 1 2 17.0

A 114x114 2.4 67 184 2 2 13.0

M 114x114 1.9 67 216 2 2 9.0

H C 114x114 2.19 67 189 2 2 11.1

A 146x146 1.5 53 238 1 2 12.0

22/9.8 Atlas M 146x146 L5 53 157 1 2 11.3 22/9.8

H C 146x146 1.5 53 182 1 2 11.8

A 254x203 0.85 58 84/91 2 2 15.6

M 254x203 0.85 58 106/115 2 2 13.9

H C 254x203 0.85 58 94/102 2 2 14.9

L C 110x110 4.2 180 104 3 7 19.4

M c ­ H C 110x110 4.2 180 112 3 7 20.1 16.41/

Master 12.14 Master L C 150x150 2.3 202 137 3 7 16.9 12.14

H C 150x150 2.3 202 147 3 7 16.9

Note: A: austenitic stainless steel; M: martensitic stainless steel; LC: low carbon steel; HC: high carbon steel.

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Distance from the Top of the Mould (mm)

Corner Midface • » • - > • center ^ — — Shell Thickness

Fig. 8.2 Temperature distribution and shell thickness in Alta continuous

casting (low carbon steel, 152x152 mm2, casting speed 1.9 m/min).

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Fig. 8.3 Billet temperature and shell thickness at Alta Steel, high carbon steel, 152x152 mm2, casting speed 1.9 m/min.

Distance from the Top of the Mould (mm)

| Corner Midface • center — shell thickness |

Fig. 8.4 Billet temperature and shell thickness at McMaster Steel,

low carbon steel, 150x150 mm2, casting speed 2.3 m/min.

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Distance from the Top of the Mould (mm)

| Corner -Midface center — Shell Thickness]

Fig. 8.5 Billet temperature and shell thickness at McMaster Steel,

high carbon steel, 150x150 mm2, casting speed 2.3 m/min.

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Table 8.3 Alta Steel spray cooling design

Spray chamber

Length (mm)

Billet size

(mm2)

Casting speed

(m/min)

Water flux

(l/m2s)

Grade Surface reheat CQ

Liquid pool depth (m)

Zone 1 4 4 4 . 5

1 2 0 x 1 2 0 3 .6 15 L C 19

Zone 1 4 4 4 . 5

1 2 0 x 1 2 0 3 .6 15

HC 7 0

Zone 1 4 4 4 . 5 1 5 2 x 1 5 2 2 .4 12.5 L C 2 4 Zone 1 4 4 4 . 5 1 5 2 x 1 5 2 2 .4 12.5

HC 93

Zone 1 4 4 4 . 5

2 0 3 x 2 0 3 1.25 7.0 L C 4 4

Zone 1 4 4 4 . 5

2 0 3 x 2 0 3 1.25 7.0

HC 98

Zone 2 1 4 2 2 . 4

1 2 0 x 1 2 0 3 .6 8.0 L C 4 2

Zone 2 1 4 2 2 . 4

1 2 0 x 1 2 0 3 .6 8.0

HC 5 2

Zone 2 1 4 2 2 . 4 1 5 2 x 1 5 2 2.4 6.0 L C 6 0 Zone 2 1 4 2 2 . 4 1 5 2 x 1 5 2 2.4 6.0

HC 75

Zone 2 1 4 2 2 . 4

2 0 3 x 2 0 3 1.25 3.5 L C 4 8

Zone 2 1 4 2 2 . 4

2 0 3 x 2 0 3 1.25 3.5

HC 68

Zone 3 1422 .4

1 2 0 x 1 2 0 3.6 3.5 L C 6 0

Zone 3 1422 .4

1 2 0 x 1 2 0 3.6 3.5

HC 6 7

Zone 3 1422 .4 1 5 2 x 1 5 2 2.4 2.5 L C 63 Zone 3 1422 .4 1 5 2 x 1 5 2 2.4 2.5

HC 93

Zone 3 1422 .4

2 0 3 x 2 0 3 1.25 1.5 L C 4 9

Zone 3 1422 .4

2 0 3 x 2 0 3 1.25 1.5

HC 6 2

Radiation

1 2 0 x 1 2 0 3 .6 L C 73 18 .6

Radiation

1 2 0 x 1 2 0 3 .6

HC 98 19 .2

Radiation 1 5 2 x 1 5 2 2 .4 L C 64 18.5 Radiation 1 5 2 x 1 5 2 2 .4

HC 93 18.8

Radiation

2 0 3 x 2 0 3 1.25 L C 4 0 16 .2

Radiation

2 0 3 x 2 0 3 1.25

HC 7 0 16 .2

Note: HC — high carbon steel; LH — low carbon steel.

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Fig. 8.6 Alta Steel: billet temperature and shell thickness for designed sprays

high carbon steel, 203x203 mm2, casting speed 1.25 m/min.

Fig. 8.7 Alta Steel: billet temperature and shell thickness for designed sprays low carbon steel, 203x203 mm2, casting speed 1.25 m/min.

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Fig. 8.9 Alta Steel: billet temperature and shell thickness for designed sprays

low carbon steel, 152x152 mm2, casting speed 2.4 m/min.

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Dlstance from the Top ofthe Mould (mm)

Fig. 8.10 Alta Steel: billet temperature and shell thickness for designed sprays

high carbon steel, 120x120 mm2, casting speed 3.6 m/min.

D istance fro m the Top of the Mould (mm)

Fig. 8.11 Alta Steel: billet temperature and shell thickness for designed sprays

low carbon steel, 120x120 mm2, casting speed 3.6 m/min.

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CHAPTER 9 - SUMMARY AND CONCLUSION

A study was undertaken to analyze the impact of several casting variables on the heat

transfer for a long mould having a parabolic taper during casting of large section billets.

The interaction between the mould and strand as well as the generation of defects such as

off-corner internal cracks and narrow face concavities were examined. Spray cooling heat

transfer was also studied for high speed billet casting.

Data on mould wall temperature, metal level, casting speed and billet quality were

acquired during a plant trial conducted at Co- Steel Lasco. In the plant trial, an operating

billet mould was instrumented with an array of thermocouples, together with LVDT's .

The water temperature was also measured at the inlet and outlet of the cooling channel.

Metal level and casting speed signals were obtained from plant instrumentation. Billet

samples for various operating conditions were collected for quality evaluation.

Mould heat fluxes were calculated by a heat transfer model from measured mould

wall temperatures. Several mathematical models were employed to investigate mould-

billet interaction and to design the mould taper. Results from plant measurements, model

calculations and billet sample evaluations were utilized to assess the impact of operating

conditions on billet quality for 6 carbon steel grades.

Spray cooling systems in three plants were also investigated. The temperature

distribution of the strand was calculated from a mathematical model. The formation of

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spray-related defects, particularly midway cracks, was linked to billet surface reheating.

A new spray system was also designed for high speed continuous casting (at Alta Steel).

The main conclusions that can be made from this work are as follows:

(1) Steel carbon content and casting speed had significant effects on heat flux of the

mould. The heat flux was highest for the medium carbon grade (0.412 pet)

followed by the high carbon grade (0.76 pet), with the low carbon grades

(0.155-0.159 pet) transferring the least amount of heat to the mould. A 25%

increase in casting speed led to about 11% increase in the mould heat flux.

(2) The most serious defect on all the sections was off-corner internal cracks,

located at approximately 8 mm below the surface. All the billets also had

concavity on their narrow faces. It was demonstrated that the taper was too tight

for the low carbon grades which was responsible for the narrow face concavity

and off-corner internal cracks. For the medium (0.412% carbon) and high

carbon billets, the mould taper was inadequate, especially in the lower part of

the mould. Bulging of the broad face and corner rotation gave rise to

longitudinal depressions on the narrow face and off-corner internal cracks.

(3) Triple tapered moulds have been designed for low carbon, medium carbon and

high carbon steels. Generally, different grades have different taper

requirements. Low carbon grades require shallower tapers, while medium and

high carbon grades require steeper tapers.

(4) Large surface reheating usually occurred after the first zone for the three spray

cooling systems studied, which correlated with casting speed, billet size, steel

grades. It was determined that additional spray zones and a longer spray

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chamber were necessary in order to avoid large surface reheating of the strand

(for instance, 7 zones and 3040 m long as used at McMaster). Too great an

intensive cooling or a sudden cooling decrease in adjacent zones resulted in

large surface reheating which could induce midway cracks at the solidification

front of the strand.

(5) A new spray system was designed for Alta Steel for a casting speed increase of

25%. Intensive spray cooling, a long spray chamber and three spray zones were

employed in the spray design in order to achieve a billet surface temperature

between 1000 and 1200 °C in the spray zones and a surface reheating of less

than 100 °C.

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REFERENCES

REFERENCES

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[2] M . Pavlicevic, C. Tercelli and B. Matijasevic, 'High Speed Casting: A New Technology Revolution with D A N A M Mould,' Proceedings of the International Symposium on Near-Net-Shape Casting in the Minimills, Vancouver, British Columbia, Canada, 1995, pp.205-215.

[3] R. Bruder, J. Wolf and A. Borowski, 'Investigation and Results of SBQ Billets Cast with Double Speed at Thyssen Stahl A G , Oberhausen,' METEC Proceedings, Vol. 1, 1994, pp. 301-304.

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[8] M . Larrecq, J.P. Birat, C. Saguez, and J. Henry, 'Optimization of Casting and Cooling Conditions on Steel Continuous Caster,' 3rd Process Technology Conf, ISS-AIME, Pittsbrugh, PA, 1982, pp. 273-282.

[9] J.K. Brimacombe and I.V. Samarasekera, 'Heat Transfer,' Continuous Casting, Vol. 2, ISS-AIME, pp. 1-8.

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[II] C. G. Kang, Y . D. Kim, and S. W. Lee, ' A Solidification and Cooling Roll Deformation Analysis Considering Thermal Flow in Twin Roll Strip Continuous Casting Process,' Melt Spinning, Strip Casting and Slab Casting, 1995, pp. 65-86.

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[12] E.A. Mizikar, 'Mathematical Heat Transfer Model for Solidification of Continuously Cast Steel Slabs', Continuous Casting, Vol. 2, ISS-AIME, 1984, pp. 9-16.

[13] J.K. Brimacombe, 'Design of Continuous-Casting Machines Based on a Heat Flow Analysis: State-of-the-Art Review,' Can. Metal. Quart., Vol. 15, No. 2 1976, pp. 163-175.

[14] I.V. Samarasekera and J.K. Brimacombe, 'Thermal and Mechanical Behaviour of Continuous-Casting Billet Moulds,' Continuous Casting, Vol. 2, ISS-AIME, 1984, pp. 58-72.

[15] I.V. Samarasekera and J.K. Brimacombe, 'The Thermal Field in Continuous Casting Moulds,' Continuous Casting, Vol. 2, ISS-AIME, 1984, pp. 45-58.

[16] A . M . Ayoub and S.H. Hosam-Eddin, 'Mathematical Modeling of Heat Transfer in Continuous Casting of Steel Billet,' Advances in Continuous Casting Research and Technology, 1992, pp. 97-114.

[17] K .C . Mills, P. Grieveson, A. Olusanya, et al, 'Effect of Casting Powder on Heat Transfer in Continuous Casting,' Continuous Casting '85, 1985, pp. 57.1-7.

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