noaa ns&t mussel watch program data: most recent data …...2007-2009 average 128.68 3067.21...

63
Appendix 3: Mussel Watch Data Appendix 3 Ocean Plan Exception Page 1 NOAA NS&T Mussel Watch Program Data: Most Recent Data 2007 – 2009, Resident Mussels, Comparison of ASBS with Non-ASBS Stations Lead Cadmium Chromium ASBS Enclosed bay Open costal non ASBS State Wide sites ASBS Enclosed bay Open costal non ASBS State Wide sites ASBS Enclosed bay Open costal non ASBS State Wide sites 2007-2009 average 2.279 2.011 1.396 1.948 7.522 3.069 4.198 5.163 1.760 1.639 1.753 1.719 STDEV 3.430 2.226 0.518 2.519 3.678 1.684 2.125 3.366 0.900 2.136 1.293 1.480 Median 1.345 1.320 1.515 1.360 6.825 2.760 3.940 5.010 1.600 1.260 1.460 1.420 85 Percentile 2.640 2.360 1.935 2.246 12.650 5.220 6.757 7.498 2.185 1.860 2.328 2.104 Nickel Zinc Mercury ASBS Enclosed bay Open costal non ASBS State Wide sites ASBS Enclosed bay Open costal non ASBS State Wide sites ASBS Enclosed bay Open costal non ASBS State Wide sites 2007-2009 average 2.973 2.632 3.153 2.913 156.835 135.605 138.794 144.980 0.144 0.107 0.086 0.116 STDEV 1.812 2.264 2.359 2.099 37.580 41.557 29.067 37.583 0.138 0.084 0.079 0.109 Median 2.500 2.020 2.135 2.180 160.500 133.000 130.000 138.000 0.106 0.074 0.057 0.074 85 Percentile 4.073 4.270 6.057 4.662 192.750 162.000 153.350 187.800 0.232 0.222 0.128 0.224 Copper Silver Arsenic ASBS Enclosed bay Open costal non ASBS State Wide sites ASBS Enclosed bay Open costal non ASBS State Wide sites ASBS Enclosed bay Open costal non ASBS State Wide sites 2007-2009 average 9.335 9.373 9.094 9.280 0.131 0.045 0.358 0.166 13.351 7.525 10.534 10.688 STDEV 2.490 2.508 3.125 2.645 0.169 0.068 0.635 0.368 7.487 1.324 2.818 5.543 Median 8.195 9.240 7.885 8.360 0.084 0.000 0.081 0.061 10.800 7.700 9.450 9.430 85 Percentile 12.350 11.800 12.990 12.640 0.186 0.105 0.742 0.212 15.075 8.710 13.440 13.280

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Page 1: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 1

NOAA NS&T Mussel Watch Program Data: Most Recent Data 2007 – 2009, Resident Mussels, Comparison of ASBS with Non-ASBS Stations

Lead Cadmium Chromium

ASBS Enclosed bay

Open costal non ASBS

State Wide sites

ASBS Enclosed bay Open

costal non ASBS

State Wide sites

ASBS Enclosed bay

Open costal non

ASBS

State Wide sites

2007-2009 average 2.279 2.011 1.396 1.948 7.522 3.069 4.198 5.163 1.760 1.639 1.753 1.719

STDEV 3.430 2.226 0.518 2.519 3.678 1.684 2.125 3.366 0.900 2.136 1.293 1.480 Median 1.345 1.320 1.515 1.360 6.825 2.760 3.940 5.010 1.600 1.260 1.460 1.420

85 Percentile 2.640 2.360 1.935 2.246 12.650 5.220 6.757 7.498 2.185 1.860 2.328 2.104

Nickel Zinc Mercury

ASBS Enclosed bay

Open costal non

ASBS

State Wide sites

ASBS Enclosed bay

Open costal non

ASBS

State Wide sites

ASBS Enclosed bay

Open costal non

ASBS

State Wide sites

2007-2009 average 2.973 2.632 3.153 2.913 156.835 135.605 138.794 144.980 0.144 0.107 0.086 0.116

STDEV 1.812 2.264 2.359 2.099 37.580 41.557 29.067 37.583 0.138 0.084 0.079 0.109 Median 2.500 2.020 2.135 2.180 160.500 133.000 130.000 138.000 0.106 0.074 0.057 0.074

85 Percentile 4.073 4.270 6.057 4.662 192.750 162.000 153.350 187.800 0.232 0.222 0.128 0.224

Copper Silver Arsenic

ASBS Enclosed bay

Open costal non ASBS

State Wide sites

ASBS Enclosed bay

Open costal non ASBS

State Wide sites

ASBS Enclosed bay

Open costal non

ASBS

State Wide sites

2007-2009 average 9.335 9.373 9.094 9.280 0.131 0.045 0.358 0.166 13.351 7.525 10.534 10.688

STDEV 2.490 2.508 3.125 2.645 0.169 0.068 0.635 0.368 7.487 1.324 2.818 5.543 Median 8.195 9.240 7.885 8.360 0.084 0.000 0.081 0.061 10.800 7.700 9.450 9.430

85 Percentile 12.350 11.800 12.990 12.640 0.186 0.105 0.742 0.212 15.075 8.710 13.440 13.280

Page 2: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 2

Total PAH

ASBS Enclosed bay Open costal non ASBS

State Wide sites

2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52

Median 100.10 594.50 122.05 122.20 85 Percentile 154.20 1949.00 240.14 759.71

Page 3: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 1

NOAA NS&T Mussel Watch Program Data: Most Recent Data 2007 – 2009, Resident Mussels, Comparison of ASBS with Non-ASBS Stations, Graphs Showing Individual Station Daya

Arsenic Concentration 2007-2009 at enclosed bay and open coastal non ASBS

0

2

4

6

8

10

12

14

16

18

Tiju

ana

Ri v

e r E

stu a

ryS

D B

a y C

o ro n

ado

Bri d

g eS

D B

ay H

a rb o

r Isl

and

Ven

tura

Br id

ge M

i ss i

o n B

ay

Agu

a h e

d io n

da la

g oo n

Ne w

p or t

ba y

PC

H B

r idge

San

Pe d

r o H

arbo

r F

ishi

ng P

ier

L ong

Be a

c h

Ana

h ei m

Bay

L o

s A

n gel

es R

ive r

mo u

t h

Mar

ina

Del

Rey

Sa n

Lu i

s O

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o B

a y 2

0 08

San

Lu i

s O

b isp

o B

a y 2

0 09

Mo r

ro B

ayS

F B

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umb a

rto n

Brid

g eS

F B

a y S

an M

a te o

Brid

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ay Y

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Bue

n a 2

009

SF

Bay

Ye r

b a B

uen a

200 8

SF

Bay

Em

e ry v

i lle

Tom

a le s

Ba y

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Sa m

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r.

I mpe

ri al B

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C

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de

Da n

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Pal

os V

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S

anta

Mo n

ica

Ba y

Car

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eria

Sta

te B

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o in t

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ta B

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r aA

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S

a n S

ime o

n P

t. 2 0

0 9S

a n S

ime o

n P

t. 2 0

0 8M

onte

rey

Bay

- Mos

s L a

n din

gM

o nt e

r ey

Ba y

- Sa n

t a C

ruz

Poi

n t A

rena

Pu d

ding

Cr e

e kE

u re k

a -H

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ldt B

ay je

tt y

Cr e

s ce n

t Ci ty

Sites

Con

cent

ratio

n (p

pm/ d

ry w

eigh

t)Encolosed bayOpen Coastal non ASBSMedian85 percentile

South North NorthSouth

Arsenic Concentration 2007-2009 at ASBS

0

5

10

15

20

25

30

35

40

45

Poi

nt L

a J o

lla

San

Cl e

men

te Is

land

San

Nic o

l as

I sl a

n d

Sou t

h C

a ta l

ina

Isla

n d

Cry

sta l

Co v

e St

a te

Beac

h

Ne w

por t

Be a

ch

Poin

t Dum

e

Anac

a pa

Isla

nd

San

Mig

uel I

s la n

d

Sant

a Cr

u z Is

lan d

Old

St a

i rs

Mu g

u La

g oon

J ul ia

P. B

urn s

Poin

t Lo b

os

Ca r

me l

Bay

Pac

if ic G

r ov e

Lo v

e rs

Po i

n t

An o

Nu e

vo Is

land

Far a

l lon

Isla

n ds

Du x

b ury

Re e

f

Poin

t Re y

e s

Bod

e ga

Bay

He a

d

Ge r

s tl e

Cov

e

Se a

Ra n

c h

Pt. D

elga

d a S

h el te

r Co

v e

Kla

ma t

h R

.

Scrip

p s R

eef

Site

Con

cent

ratio

n (p

pm/d

ryw

eigh

t)

ASBS Median85 percentile

South North

Page 4: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 2

Cadmium concentration 2007-2009 at ASBS

0

2

4

6

8

10

12

14

16

Poi

nt D

ume

New

port

Bea

ch

La J

olla

Cr y

stal

Cov

e S

t ate

Bea

chM

ugu

Lago

on

San

t a C

ruz

Isl a

nd

San

Mig

u el I

slan

d O

ld S

t air s

S

crip

ps R

eef

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capa

I sla

ndS

out h

Cat

alin

a Is

l and

Fa

ral lo

n Is

l and

sB

odeg

a B a

yG

erst

le C

ove

Sea

Ran

chP

t . D

elga

daD

uxbu

r y R

e ef

Poi

nt R

eye s

Pac

i fic

Gr o

veA

no N

uevo

San

Nic

olas

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ndC

arm

el B

ayP

oint

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osP

arti n

gton

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ntK

lam

ath

R.

Cr e

scen

t Ci ty

San

Cle

men

te Is

l and

Site

Con

cent

ratio

n (n

g/ d

ry g

)

South North

Cadmium concentration 2007-2009 at enclosed bay and others

0

1

2

3

4

5

6

7

8

9

New

por t

bay

San

Lu i

s O

b isp

o B

a y 2

0 08

Mar

ina

De l

Re y

San

Die

g o B

a y

San

Ped

ro H

arb o

r M

issi

on B

ay

An a

hei m

Ba y

Lo

s An

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s R

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mou

th

Tiju

ana

Ri v

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ryS

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ieg o

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S

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ay Y

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Bue

n a20

08A

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h edi

o nda

l ag o

onLo

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eac h

S

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Bue

na 2

0 09

San

Lu i

s O

b is p

o B

a y 2

009

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Sam

oa B

r.S

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a y- D

umba

r ton

Bri d

g eS

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ay-S

a n M

ateo

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an F

ran c

isc o

Ba y

-Em

e ryv

il leTo

ma l

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ayM

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Ba y

San

Sim

eon

Pt. 2

0 09

Po i

n t S

anta

Ba r

b ar a

Pal

o s V

erd e

s I m

peria

l Be a

c h

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p in t

e ria

Sta

t e B

eac h

D

ana

Poi n

t A

r roy o

Hon

do

Ca r

d iff

Ree

f S

an S

imeo

n Pt

. 20 0

8O

cean

side

R

edon

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ure k

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onte

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tere

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oss

L and

i ng

Pud

d in g

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ekP

oint

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n aL a

s Tu

nas

Be a

ch

Site

Con

cent

ratio

n(ng

/dry

g)

Enclosed bayOthers

Page 5: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 3

Chromium concentration 2007-2009 at ASBS

00.5

11.5

22.5

33.5

44.5

5

Poi

nt D

ume

New

por t

Bea

ch

La J

oll a

Cry

stal

Cov

e S

tat e

Bea

chM

ugu

Lago

on

San

t a C

r uz

Isla

nd

San

Mig

uel I

slan

d O

ld S

tai rs

S

crip

ps R

eef

Ana

capa

I sl a

ndS

outh

Cat

ali n

a I s

land

Fa

r all o

n I s

land

sB

odeg

a Ba

yG

erst

le C

ove

Sea

Ran

chP

t. D

elga

daD

u xbu

ry R

eef

Poi

nt R

eyes

Pac

i fic

Gro

veA

no N

uevo

San

Ni c

olas

Isla

n dC

arm

el B

ayP

oint

Lob

osP

arti n

gton

Poi

ntK

lam

ath

R.

Cr e

scen

t Ci ty

San

Cle

men

te Is

l and

Site

Con

cent

ratio

n (n

g/ d

ry g

)

Chromium concentration 2007-2009 at enclosed bay and others

0

2

4

6

8

10

12

New

port

b ay

San

Lu i

s O

bisp

o B

a y 2

0 08

Mar

ina

De l

Rey

San

Die

g o B

a y

San

Ped

r o H

a rb o

r M

issi

on B

a y

An a

hei m

Ba y

Lo

s An

g el e

s R

iver

mou

th

Tiju

ana

Ri v

e r E

s tu a

ryS

a n D

ieg o

Bay

S

F B

ay Y

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Bue

n a20

0 8A

gua

h ed i

ond a

lag o

onL o

ng B

eac h

S

F B

ay Y

e rba

Bue

na 2

0 09

San

Lui

s O

b is p

o B

ay 2

0 09

Eu r

e ka -

Sam

oa B

r .S

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a y-D

umba

rt on

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g eS

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an F

r anc

isc o

Ba y

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e ry v

illeTo

ma l

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a yM

o rro

Ba y

San

Sim

eon

Pt. 2

009

Po i

n t S

anta

Ba r

b ara

Pa l

o s V

e rd e

s Im

peri a

l Be a

ch

Ca r

pint

e ria

St a

te B

e ach

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ana

Poin

t A

rr oy o

Hon

do

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diff

Ree

f S

a n S

imeo

n Pt

. 20 0

8O

c ean

s id e

R

edo n

do B

each

E

u re k

a -H

umbo

ldt B

a y je

tt yM

ont e

r ey

Bay

- Sa n

t a C

r uz

Mon

tere

y B

a y- M

oss

L and

i ng

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d ing

Cre

e kP

oint

Ar e

n aL a

s Tu

nas

Be a

ch

Site

Con

cent

ratio

n(ng

/dry

g)

Enclosed bayOthers

Page 6: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 4

Copper Concentration 2007-2009 at ASBS

0

24

6

810

12

1416

18

Poi

nt L

a Jo

ll a

San

Cle

men

te Is

l and

San

Ni c

olas

Isl a

nd

So u

t h C

ata l

ina

Isl a

nd

Cr y

stal

Cov

e S

t ate

Bea

ch

New

p ort

Be a

ch

Poi

nt D

ume

Ana

capa

I sla

nd

San

Mig

uel I

slan

d

San

ta C

r uz

I sla

nd

Ol d

Sta

i rs

Mug

u La

goon

Julia

P. B

urns

Poi

nt L

obos

Car

mel

Bay

Pac

if ic

Gro

ve L

over

s P

oint

Ano

Nue

vo I s

l and

Far a

ll on

I sla

nds

Dux

bur y

Ree

f

Poi

nt R

eyes

Bod

ega

Bay

Hea

d

Ger

stle

Cov

e

Sea

Ran

ch

Pt .

Del

gada

She

lt er

C ove

Kl a

mat

h R

.

Scr

ipps

Ree

f

Site

Con

cent

ratio

n (p

pm/d

ryw

eigh

t)

ASBS Median85 percentile

South North

Copper Concentration 2007-2009 at enclosed bay and open coastal non ASBS

0

2

4

6

8

10

12

14

16

18

Tiju

ana

Riv

e r E

s tua

ry

SD

Bay

Co r

onad

o B

ridge

SD

Bay

Ha r

bor I

sla n

d

Ven

t ur a

Brid

ge M

issi

o n B

ay

Agu

a he

dion

da la

goon

New

port

bay

PC

H B

ri dge

San

Ped

r o H

arbo

r F

ishi

ng P

ier

Long

Bea

ch

Ana

heim

Bay

Los

Ang

e le s

Riv

erm

outh

Mar

ina

Del

Rey

San

Lu i

s O

b is p

o B

ay 2

008

San

Lu i

s O

b is p

o B

ay 2

009

Mo r

r o B

ay

SF

Bay

Dum

bar t

on B

ridge

SF

Bay

San

Ma t

eo B

ridge

SF

Bay

Yer

ba B

uena

200

9

SF

Bay

Yer

ba B

uena

2008

SF

Bay

Em

eryv

il le

Tom

a le s

Bay

Eu r

eka

Sam

oa B

r .

Impe

rial B

each

Ca r

d iff

Ree

f

Oc e

ansi

de

Dan

a P

o in t

Pa l

o s V

e rde

s

Red

ondo

Bea

c h

San

ta M

oni c

a B

ay

Car

pint

eria

Sta

te B

eac h

Poi

nt S

anta

Ba r

bara

Arr

o yo

Hon

do

San

Si m

eon

Pt.

2009

San

Sim

eon

Pt.

2 008

Mon

tere

y B

ay- M

oss

Land

ing

Mon

tere

y B

ay- S

anta

Cr u

z

Po i

n t A

r ena

Pud

ding

Cre

ekE

u re k

a -H

umbo

l dt B

ay j e

t ty

Cr e

scen

t City

Sites

Con

cent

ratio

n (p

pm/ d

ry w

eigh

t)

Encolosed bayOpen Coastal non ASBSMedian85 percentile

South North NorthSouth

Page 7: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 5

Lead Concentration 2007-2009 at ASBS

0

2

4

6

8

10

12

14

16

18

20

Poi

nt L

a J o

lla

San

Cl e

men

te Is

land

San

Nic o

l as

I sl a

n d

Sou t

h C

a ta l

ina

Isla

n d

Cry

sta l

Co v

e St

a te

Beac

h

Ne w

por t

Be a

ch

Poin

t Dum

e

Anac

a pa

Isla

nd

San

Mig

uel I

s la n

d

Sant

a Cr

u z Is

lan d

Old

St a

i rs

Mu g

u La

g oon

J ul ia

P. B

urn s

Poin

t Lo b

os

Ca r

me l

Bay

Pac

if ic G

r ov e

Lo v

e rs

Po i

n t

An o

Nu e

vo Is

land

Far a

l lon

Isla

n ds

Du x

b ury

Re e

f

Poin

t Re y

e s

Bod

e ga

Bay

He a

d

Ge r

s tl e

Cov

e

Se a

Ra n

c h

Pt. D

elga

d a S

h el te

r Co

v e

Kla

ma t

h R

.

Scrip

p s R

eef

Site

Con

cent

ratio

n (p

pm/d

ryw

eigh

t)

ASBS Median85 percentile

South North

South North NorthSouthSouth North NorthSouth

Lead Concentration 2007-2009 at enclosed bay and open coastal non ASBS

0

2

4

6

8

10

12

Tiju

ana

Riv

e r E

s tu a

r y

SD

Bay

Co r

o nad

o B

ridg e

SD

Ba y

Har

bor I

s la n

d

Ven

tura

Br id

ge M

iss i

o n B

a y

Agu

a h e

d io n

da la

g oo n

New

p or t

ba y

PC

H B

r idg e

San

Pe d

r o H

arbo

r F

ishi

ng P

ier

L on g

Be a

c h

An a

h eim

Ba y

L os

An g

ele s

Riv

e rm

o ut h

Mar

ina

De l

Rey

Sa n

Lu i

s O

b is p

o B

a y 2

0 08

San

Lu i

s O

b is p

o B

a y 2

0 09

Mo r

ro B

ay

SF

Bay

Dum

bart

on B

r idge

SF

Ba y

San

Ma t

e o B

ridg e

SF

Ba y

Ye r

b a B

u en a

200

9

SF

Ba y

Ye r

b a B

u ena

2 00 8

SF

Ba y

Em

e ry v

il le

Tom

a le s

Ba y

Eur

eka

Sam

o a B

r.

Imp e

rial B

each

Car

diff

Re e

f

Oc e

a ns i

d e

Da n

a P

o in t

Pa l

os V

e rd e

s

Re d

o ndo

Be a

c h

San

ta M

o nic

a B

ay

Ca r

p in t

e ri a

Sta

te B

eac h

Po i

n t S

a nta

Bar

b ar a

Ar r

o yo

Ho n

d o

San

Sim

e on

Pt.

200 9

Sa n

Sim

e on

Pt.

2 00 8

Mo n

tere

y B

a y- M

o ss

Lan d

i ng

Mon

tere

y B

a y- S

anta

Cru

z

Po i

n t A

rena

Pu d

ding

Cr e

e kE

u re k

a -H

umb o

l dt B

ay j e

t ty

Cre

s ce n

t Cit y

Sites

Con

cent

ratio

n (p

pm/ d

ry w

eigh

t)

Encolosed bayOpen Coastal non ASBSMedian85 percentile

Page 8: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 6

Mercury concentration 2007-2009 at ASBS

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

Poi

nt D

ume

New

por t

Bea

ch

La J

oll a

Cry

stal

Cov

e S

tat e

Bea

chM

ugu

Lago

on

San

t a C

r uz

Isla

nd

San

Mig

uel I

slan

d O

ld S

tai rs

S

crip

ps R

eef

Ana

capa

I sl a

ndS

outh

Cat

ali n

a I s

land

Fa

r all o

n I s

land

sB

odeg

a Ba

yG

erst

le C

ove

Sea

Ran

chP

t. D

elga

daD

u xbu

ry R

eef

Poi

nt R

eyes

Pac

i fic

Gro

veA

no N

uevo

San

Ni c

olas

Isla

n dC

arm

el B

ayP

oint

Lob

osP

arti n

gton

Poi

ntK

lam

ath

R.

Cr e

scen

t Ci ty

San

Cle

men

te Is

l and

Site

Con

cent

ratio

n (n

g/ d

ry g

)

Mercury concentration 2007-2009 at enclosed bay and others

0

0.05

0.1

0.15

0.2

0.25

0.3

0.35

0.4

New

por t

b ay

San

Lu i

s O

b is p

o B

a y 2

0 08

Ma r

i na

Del

Re y

San

Di e

g o B

a y

San

Ped

ro H

a rb o

r M

iss i

o n B

a y

Ana

h eim

Ba y

L o

s An

g ele

s R

ive r

mou

th

Tiju

a na

Riv

er E

s tu a

ryS

an D

ieg o

Ba y

S

F B

a y Y

erb a

Bue

n a20

0 8A

gua

h edi

onda

lag o

onL o

ng B

eac h

S

F B

ay Y

e rba

Bue

na 2

0 09

San

Lu i

s O

b is p

o B

ay 2

0 09

Eu r

e ka-

Sam

oa B

r.S

F B

a y-D

umba

rt on

Brid

g eS

F B

a y-S

a n M

a te o

Br id

geS

an F

r an c

isc o

Ba y

- Em

e ry v

i lleTo

ma l

e s B

a yM

o rr o

Ba y

San

Si m

eon

Pt. 2

0 09

Po i

n t S

anta

Bar

b ar a

Pal

o s V

erd e

s I m

peria

l Be a

c h

Ca r

p in t

e ria

St a

t e B

e ac h

D

ana

Poin

t A

r roy o

Hon

d o

Ca r

d if f

Ree

f S

an S

imeo

n Pt

. 20 0

8O

c ean

s id e

R

edo n

do B

e ac h

E

u re k

a-H

umbo

l dt B

a y je

t tyM

ont e

rey

Ba y

- Sa n

ta C

ruz

Mon

ter e

y B

a y- M

o ss

L and

ing

Pud

ding

Cre

e kP

oin t

Ar e

naL a

s Tu

n as

Be a

ch

Site

Con

cent

ratio

n(ng

/dry

g)

Enclosed bayOthers

Page 9: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 7

Nickel concentration 2007-2009 at ASBS

0123456789

10

Poi

nt D

ume

New

port

Bea

ch

La J

olla

Cr y

stal

Cov

e S

t ate

Bea

chM

ugu

Lago

on

San

t a C

ruz

Isl a

nd

San

Mig

u el I

slan

d O

ld S

t air s

S

crip

ps R

eef

Ana

capa

I sla

ndS

out h

Cat

alin

a Is

l and

Fa

ral lo

n Is

l and

sB

odeg

a B a

yG

erst

le C

ove

Sea

Ran

chP

t . D

elga

daD

uxbu

r y R

e ef

Poi

nt R

eye s

Pac

i fic

Gr o

veA

no N

uevo

San

Nic

olas

I sla

ndC

arm

el B

ayP

oint

Lob

osP

arti n

gton

Poi

ntK

lam

ath

R.

Cr e

scen

t Ci ty

San

Cle

men

te Is

l and

Site

Con

cent

ratio

n (n

g/ d

ry g

)

Nickel concentration 2007-2009 at enclosed bay and others

0

1

2

3

45

6

7

8

9

10

New

port

b ay

San

Lu i

s O

bisp

o B

a y 2

0 08

Mar

ina

De l

Rey

San

Die

g o B

a y

San

Ped

r o H

a rb o

r M

issi

on B

a y

Ana

hei m

Ba y

Lo

s An

g el e

s R

iver

mou

th

Tiju

ana

Ri v

e r E

s tu a

ryS

a n D

ieg o

Bay

S

F B

ay Y

e rba

Bue

na20

0 8A

gua

h ed i

onda

lag o

onL o

ng B

eac h

S

F B

ay Y

e rba

Bue

na 2

0 09

San

Lui

s O

b is p

o B

ay 2

0 09

Eu r

e ka -

Sam

oa B

r .S

F B

a y-D

umba

rt on

Brid

g eS

F B

a y-S

a n M

a te o

Br id

geS

an F

r anc

isc o

Ba y

- Em

e ry v

illeTo

ma l

e s B

a yM

o rro

Ba y

San

Sim

eon

Pt. 2

009

Po i

n t S

a nta

Ba r

b ara

Pa l

o s V

e rd e

s Im

peri a

l Be a

ch

Ca r

pint

e ria

St a

te B

e ach

D

ana

Poin

t A

rr oy o

Hon

d o

Ca r

diff

Ree

f S

a n S

imeo

n Pt

. 20 0

8O

c ean

s id e

R

edo n

do B

e ach

E

u re k

a -H

umbo

ldt B

a y je

tt yM

ont e

r ey

Bay

- Sa n

t a C

r uz

Mon

tere

y B

a y- M

oss

L and

i ng

Pud

d ing

Cre

e kP

oint

Ar e

n aL a

s Tu

n as

Be a

ch

Site

Con

cent

ratio

n(ng

/dry

g)

Enclosed bayOthers

Page 10: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 8

Silver Concentration 2007-2009 at ASBS

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

Poin

t La

J olla

San

Clem

ent e

Isla

nd

San

Nic o

las

Isla

nd

Sou t

h Ca

t alin

a I s

l and

Cry

s ta l

Cov

e St

ate

Bea

ch

New

p ort

Beac

h

Poi n

t Dum

e

Ana

capa

Isl a

nd

San

Mig

uel I

s land

San t

a C

r uz

Isla

nd

Old

Sta

i rs

Mug

u La

goon

Juli a

P. B

urns

Po i

n t L

obos

Ca r

me l

Bay

Pac if

i c G

rov e

Lov

e rs

Poin

t

Ano

Nue

v o Is

l and

Fara

ll on

Isla

nds

Dux

bury

Ree

f

Po i

n t R

eyes

Bode

ga B

ay H

ead

Ge r

s tl e

Cov

e

Sea

Ranc

h

Pt. D

e lga

da S

hel te

r Co

v e

Klam

ath

R.

Sc r

ipps

Ree

f

Site

Con

cent

ratio

n (p

pm/d

ryw

eigh

t)

ASBS Median85 percentile

South North

Silver Concentration 2007-2009 at enclosed bay and open coastal non ASBS

0

0.5

1

1.5

2

2.5

Tiju

ana

Riv e

r Es t

uar y

SD B

ay C

oron

ado

Brid

geSD

Bay

Har

bor I

s lan

dVe

ntu r

a B

ri dge

Mis

s ion

Bay

A

gua

hed i

onda

lago

onN

ewpo

rt ba

y P

CH B

r idge

San

Ped

ro H

arbo

r F

is hin

g P

ier

Long

Bea

ch

Anah

e im

Bay

Lo

s An

gel e

s R

iver

mou

th

Mar

ina

De l

Rey

San

Lu i

s O

b isp

o Ba

y 20

08S

an L

u is

Ob i

spo

Bay

2009

Mor

ro B

ayS

F B

ay D

umba

r ton

Brid

geSF

Bay

San

Mat

eo B

ri dge

SF

Bay

Yer

ba B

uena

200

9S

F B

ay Y

erba

Bue

na20

08SF

Bay

Em

ery v

i lleTo

mal

es B

ayEu

rek a

Sam

oa B

r .

I mpe

r ial B

eac h

C

ard i

ff R

eef

Oc e

ans i

de

Dan

a P

o in t

Pa

los

Verd

es

Red

ondo

Bea

c h

Sant

a M

oni c

a Ba

yC

arp i

nte r

ia S

tate

Bea

c h

Poin

t San

t a B

arba

raAr

roy o

Hon

do

San

Sim

eon

Pt .

2009

San

Sim

eon

Pt.

2008

Mon

ter e

y B

ay- M

oss

Land

i ng

Mon

ter e

y Ba

y - S

anta

Cru

zP

o in t

Are

naP

uddi

ng C

reek

Eur

eka-

Hum

bold

t Bay

jett y

Cr e

s cen

t Ci ty

Sites

Con

cent

ratio

n (p

pm/ d

ry w

eigh

t)

Encolosed bayOpen Coastal non ASBSMedian85 percentile

South North NorthSouthSouth North NorthSouth

Page 11: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 9

Zinc concentration 2007-2009 at ASBS

0

50

100

150

200

250

Poi

nt D

ume

New

por t

Bea

ch

La J

olla

Cr y

stal

Cov

e S

t ate

Bea

chM

ugu

Lago

on

San

ta C

r uz

I sla

nd

San

Mi g

uel I

slan

d O

ld S

t air s

S

crip

ps R

eef

Ana

capa

I sla

ndS

out h

Cat

alin

a Is

l and

F a

ral lo

n Is

l and

sB

odeg

a Ba

yG

erst

l e C

ove

Sea

Ran

chP

t . D

elga

daD

uxbu

ry R

eef

Poi

nt R

eyes

Pac

if ic

Gro

veA

no N

uevo

San

Nic

olas

Isl a

ndC

arm

el B

ayP

oint

Lob

osP

arti n

gton

Poi

ntK

lam

ath

R.

Cr e

scen

t Ci ty

San

Cle

men

te Is

l and

Site

Con

cent

ratio

n (n

g/ d

ry g

)

Zinc concentration 2007-2009 at enclosed bay and others

0

50

100

150

200

250

300

New

port

b ay

San

Lu i

s O

bisp

o B

a y 2

0 08

Ma r

ina

De l

Rey

San

Die

g o B

a y

San

Ped

r o H

a rb o

r M

issi

on B

a y

An a

heim

Ba y

Lo

s An

gele

s R

iver

mou

th

Tij u

ana

Ri v

e r E

stu a

r yS

a n D

ieg o

Bay

S

F B

a y Y

e rb a

Bue

n a20

0 8A

gua

hed i

o nd a

lag o

onL o

n g B

each

S

F B

a y Y

e rb a

Bue

na 2

0 09

San

Lu i

s O

bisp

o B

a y 2

0 09

Eu r

e ka -

Sam

oa B

r .S

F B

a y-D

umba

rton

Br id

g eS

F B

a y- S

an M

a te o

Bri d

g eS

an F

ran c

isco

Bay

-Em

eryv

i lleTo

ma l

e s B

a yM

o rr o

Ba y

San

Sim

eon

Pt. 2

0 09

Po i

n t S

a nta

Ba r

b ar a

Pal

os V

e rd e

s I m

per ia

l Bea

c h

Car

p in t

e ri a

Sta

te B

e ac h

D

ana

Poin

t A

r royo

Hon

d o

Ca r

d iff

Ree

f S

a n S

imeo

n Pt

. 20 0

8O

c ean

s id e

R

edo n

do B

e ac h

E

u re k

a-H

umbo

l dt B

a y je

t tyM

ont e

r ey

Bay

- Sa n

t a C

r uz

Mon

ter e

y B

a y- M

o ss

L and

i ng

Pud

d ing

Cre

e kP

oin t

Ar e

naL a

s Tu

n as

Be a

ch

Site

Con

cent

ratio

n(ng

/dry

g)

Enclosed bayOthers

Page 12: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 10

NOAA NS&T Mussel Watch: Historical Data through 2009, Resident Mussels Summary for Newport Beach (NBWJ) - NOAA program

Trend of Total Butyltin concentration at Newport Beach

y = -7.8977x + 15821R2 = 0.4614

-100

-50

0

50

100

150

200

250

1980 1985 1990 1995 2000 2005 2010

Year

Con

cent

ratio

n(ng

/dry

g)

Total Butyltin

Trend of Total Chlordane concentration at Newport Beach

y = -0.2928x + 594.89R2 = 0.1664

0

5

10

15

20

25

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/dry

g) Total Chlordane

Trend of Total DDT concentration at Newport Beach

y = -4.5922x + 9295.9R2 = 0.271

0

50

100

150

200

250

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/dry

g)

Total DDT

Page 13: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 11

Trend of Total Dieldrin concentration at Newport Beach

y = -0.1536x + 311.19R2 = 0.0607

02468

1012141618

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/dry

g)

Total Dieldrin

Trend of Total PAH concentration at Newport Beach

y = -0.371x + 832.83R2 = 0.0012

0

50

100

150

200

250

300

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/dry

g) Total PAH

Trend of Ag concentration at Newport Beach

y = -0.0784x + 157.19R2 = 0.6581

-1

0

1

1

2

2

1980 1985 1990 1995 2000 2005 2010

Year

Con

cent

ratio

n(ug

/dry

g)

Ag

Page 14: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 12

Trend of As concentration at Newport Beach

y = -0.1837x + 377.75R2 = 0.1949

02468

101214161820

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/dry

g)

As

Trend of Cd concentration at Newport Beach

y = 0.0351x - 68.742R2 = 0.1648

0

1

1

2

2

3

3

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/dry

g)

Cd

Trend of Cr concentration at Newport Beach

y = -0.0169x + 35.284R2 = 0.0158

0

1

1

2

2

3

3

4

4

5

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/dry

g)

Cr

Page 15: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 13

Trend of Cu concentration at Newport Beach

y = -0.0511x + 109.43R2 = 0.0554

0

2

4

6

8

10

12

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/dry

g)

Cu

Trend of Hg concentration at Newport Beach

y = -0.0037x + 7.4413R2 = 0.42

0

0

0

0

0

0

0

0

0

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/dry

g) Hg

Trend of Ni concentration at Newport Beach

y = -0.0334x + 68.095R2 = 0.059

0

1

1

2

2

3

3

4

4

5

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/dry

g)

Ni

Page 16: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 14

Trend of Pb concentration at Newport Beach

y = -0.1466x + 296.34R2 = 0.2978

0

1

2

3

4

5

6

7

8

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/dry

g)

Pb

Trend of Sb concentration at Newport Beach

y = -0.2078x + 414.04R2 = 0.7898

-0.5

0.0

0.5

1.0

1.5

2.0

1984 1986 1988 1990 1992 1994 1996

Year

Con

cent

ratio

n(ug

/dry

g)

Sb

Trend of Se concentration at Newport Beach

y = -0.018x + 38.333R2 = 0.1006

0

1

1

2

2

3

3

4

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/dry

g)

Se

Page 17: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 15

Trend of Sb concentration at Newport Beach

y = -72.971x + 145694R2 = 0.1667

0.0

200.0

400.0

600.0

800.0

1000.0

1200.0

1400.0

1984 1986 1988 1990 1992 1994 1996Year

Con

cent

ratio

n(ug

/dry

g)

Si

Trend of Zn concentration at Newport Beach

y = -2.1134x + 4370.5R2 = 0.1439

0

50

100

150

200

250

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/dry

g)

Zn

Page 18: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 16

South Catalina Island

Trend of Total Butlytins concentration at South Catalina Island-Bird Rock

y = -8.3213x + 16697R2 = 0.0342

-100

0

100

200

300

400

500

600

700

800

1980 1985 1990 1995 2000 2005 2010

Year

Con

cent

ratio

n(ng

/g d

ry w

eigh

t

Total Butlytins

Trend of Total Chlordane concentration at South Catalina Island-Bird Rock

y = -0.1918x + 385.27R2 = 0.3127

0

1

2

3

4

5

6

7

8

9

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/g d

ry w

eigh

t

TotalChlordane

Trend of Total DDT concentration at South Catalina Island-Bird Rock

y = -2.595x + 5217.2R2 = 0.2502

0

20

40

60

80

100

120

140

160

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/g d

ry w

eigh

t

Total DDT

Page 19: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 17

Trend of Total Dieldrin concentration at South Catalina Island-Bird Rock

y = -0.0664x + 133.82R2 = 0.2279

0

0.5

1

1.5

2

2.5

3

3.5

4

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/g d

ry w

eigh

t)Total Dieldrin

Trend of Total PAH concentration at South Catalina Island-Bird Rock

y = 0.9893x - 1914.7R2 = 0.0139

020406080

100120140160180

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/g d

ry w

eigh

t) Total PAH

Trend of Total PCBs concentration at South Catalina Island-Bird Rock

y = -0.2466x + 505.98R2 = 0.038

0

5

10

15

20

25

30

35

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/g d

ry w

eigh

t Total PCBs

Page 20: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 18

Trend of Ag concentration at South Catalina Island-Bird Rock

y = -0.007x + 14.402R2 = 0.0168

0

0.2

0.4

0.6

0.8

1

1.2

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t) Ag"

Trend of As concentration at South Catalina Island-Bird Rock

y = -0.2846x + 582.94R2 = 0.3522

0

5

10

15

20

25

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t) As"

Trend of Cd concentration at South Catalina Island-Bird Rock

y = 0.0923x - 179.89R2 = 0.1418

012345678

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t)

Cd

Page 21: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 19

Trend of Cr concentration at South Catalina Island-Bird Rock

y = 0.0035x - 5.2908R2 = 0.0007

00.5

11.5

22.5

33.5

44.5

5

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t) Cr

Trend of Cu concentration at South Catalina Island-Bird Rock

y = 0.0808x - 155.1R2 = 0.1741

0

2

4

6

8

10

12

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t Cu

Trend of Hg concentration at South Catalina Island-Bird Rock

y = -0.0029x + 5.9692R2 = 0.2238

0

0.05

0.1

0.15

0.2

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t Hg

Page 22: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 20

Trend of Ni concentration at South Catalina Island-Bird Rock

y = -0.0392x + 80.567R2 = 0.0312

01234567

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t Ni

Trend of Pb concentration at South Catalina Island-Bird Rock

y = -0.0525x + 106.47R2 = 0.2357

0

1

2

3

4

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t Pb

Trend of Sb concentration at South Catalina Island-Bird Rock

y = -0.1122x + 223.63R2 = 0.7296

-0.4

-0.2

0

0.2

0.4

0.6

0.8

1

1984 1986 1988 1990 1992 1994 1996

Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t

Sb

Page 23: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 21

Trend of Se concentration at South Catalina Island-Bird Rock

y = -0.0577x + 118.47R2 = 0.2251

0

1

2

3

4

5

6

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t Se

Trend of Si concentration at South Catalina Island-Bird Rock

y = -92.101x + 183470R2 = 0.6556

-400

-200

0

200

400

600

800

1000

1984 1986 1988 1990 1992 1994 1996

Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t) Si

Trend of Sb concentration at LaJolla

y = -0.0999x + 198.98R2 = 0.4435

-0.2

0

0.2

0.4

0.6

0.8

1

1.2

1.4

1985 1986 1987 1988 1989 1990 1991 1992 1993 1994 1995

Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t

Sb

Page 24: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 22

Trend of Se concentration at LaJolla

y = -0.0366x + 75.624R2 = 0.1594

0

0.5

1

1.5

2

2.5

3

3.5

4

4.5

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t Se

Trend of Si concentration at LaJolla

y = 55.217x - 109179R2 = 0.0333

0

500

1000

1500

2000

2500

3000

1985 1986 1987 1988 1989 1990 1991 1992 1993 1994 1995Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t) Si

Trend of Zn concentration at South Catalina Island-Bird Rock

y = -1.0605x + 2241.6R2 = 0.2049

020406080

100120140160180

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t) Zn

Page 25: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 23

La Jolla

Trend of Total Butyltin concentration at LaJolla

y = -1.6184x + 3255.8R2 = 0.038

0

20

40

60

80

100

120

140

160

180

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/g d

ry w

eigh

t)

Total Butyltin

Trend of Total Chlordane concentration at LaJolla

y = -0.3668x + 741.47R2 = 0.302

0

5

10

15

20

25

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/g d

ry w

eigh

t)

Total Chlordane

Trend of Total DDT concentration at LaJolla

y = -3.067x + 6155.5R2 = 0.2527

-20

0

20

40

60

80

100

120

140

160

180

1980 1985 1990 1995 2000 2005 2010

Year

Con

cent

ratio

n(ng

/g d

ry w

eigh

t)

Total DDT

Page 26: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 24

Trend of Total Dieldrin concentration at LaJolla

y = -0.0645x + 131.85R2 = 0.0309

0123456789

10

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/g d

ry w

eigh

t)

Total Dieldrin

Trend of Total PAH concentration at LaJolla

y = 3.3358x - 6584.3R2 = 0.3041

0

20

40

60

80

100

120

140

160

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/g d

ry w

eigh

t

Total PAH

Trend of Total PCB concentration at LaJolla

y = 0.1836x - 348.85R2 = 0.017

0

5

10

15

20

25

30

35

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/g d

ry w

eigh

t) Total PCB

Page 27: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 25

Trend of Ag concentration at LaJolla

y = -0.2811x + 563.49R2 = 0.4605

-1

0

12

3

4

5

67

8

9

1985 1990 1995 2000 2005 2010

Year

Con

cent

ratio

n(ng

/g d

ry w

eigh

t) Ag

Trend of As concentration at LaJolla

y = -0.2592x + 532.94R2 = 0.3367

0

5

10

15

20

25

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t)

As

Trend of Cd concentration at LaJolla

y = 0.0056x - 9.6005R2 = 0.0029

0

0.5

1

1.5

2

2.5

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t)

Cd

Page 28: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 26

Trend of Cr concentration at LaJolla

y = 0.0017x - 1.5834R2 = 0.0002

00.5

11.5

22.5

33.5

44.5

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

tCr

Trend of Cu concentration at LaJolla

y = 0.126x - 243.06R2 = 0.1377

0

2

4

6

8

10

12

14

16

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t

Cu

Trend of Hg concentration at LaJolla

y = -0.0087x + 17.541R2 = 0.5267

0

0.05

0.1

0.15

0.2

0.25

0.3

0.35

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t

Hg

Page 29: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 27

Trend of Ni concentration at LaJolla

y = 0.0176x - 33.727R2 = 0.0805

0

0.5

1

1.5

2

2.5

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t Ni

Trend of Pb concentration at LaJolla

y = -0.1372x + 276.33R2 = 0.3898

0

1

2

3

4

5

6

7

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ry w

eigh

t) Pb

Trend of Zn concentration at LaJolla

y = -0.4328x + 1005R2 = 0.0052

0

50

100

150

200

250

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/g d

ry w

eigh

t) Zn

Page 30: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 28

Point Dume

Trend of Total Butyltin concentration at Point Dume

y = -7.0765x + 14162R2 = 0.5023

-100

-50

0

50

100

150

200

1980 1985 1990 1995 2000 2005 2010

Year

Con

cent

ratio

n (n

g/ g

dry

wei

ght)

Total Butyltin

Trend of Total Chlordane concentration at Point Dume

y = -0.6065x + 1220.2R2 = 0.4551

0

5

10

15

20

25

30

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n (n

g/ g

dry

wei

ght

Total Chlordane

Trend of Total DDT concentration at Point Dume

y = -11.363x + 22804R2 = 0.3296

-100

0

100

200

300

400

500

600

1980 1985 1990 1995 2000 2005 2010

Year

Con

cent

ratio

n (n

g/ g

dry

wei

ght

Total DDT

Page 31: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 29

Trend of Total Dieldrin concentration at Point Dume

y = -0.2472x + 498.46R2 = 0.103

0

5

10

15

20

25

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n (n

g/ g

dry

wei

ght)

Total Dieldrin

Trend of Total PAH concentration at Point Dume

y = -0.9329x + 1946.6R2 = 0.0162

0

20

40

60

80

100

120

140

160

180

200

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n (n

g/ g

dry

wei

ght)

TotalPAH

Trend of Total PCB concentration at Point Dume

y = -0.4982x + 1017.6R2 = 0.1989

0

5

10

15

20

25

30

35

40

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n (n

g/ g

dry

wei

ght)

TotalPCB

Page 32: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 30

Trend of Ag concentration at Point Dume

y = -0.2355x + 473.68R2 = 0.3174

0

1

2

3

4

5

6

7

8

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n (u

g/ g

dry

wei

ght)

Ag

Trend of As concentration at Point Dume

y = -0.1413x + 291.66R2 = 0.4453

0

2

4

6

8

10

12

14

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n (u

g/ g

dry

wei

ght) As

Trend of Cd concentration at Point Dume

y = 0.1498x - 296.28R2 = 0.4519

0

1

2

3

4

5

6

7

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n (u

g/ g

dry

wei

ght) Cd

Page 33: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 31

Trend of Cr concentration at Point Dume

y = -0.0383x + 78.288R2 = 0.0514

0

1

1

2

2

3

3

4

4

5

5

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n (u

g/ g

dry

wei

ght) Cr

Trend of Cu concentration at Point Dume

y = -0.1184x + 244.01R2 = 0.3479

0

2

4

6

8

10

12

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n (u

g/ g

dry

wei

ght)

Cu

Trend of Hg concentration at Point Dume

y = -0.0035x + 7.1142R2 = 0.3295

0

0

0

0

0

0

0

0

0

0

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n (u

g/ g

dry

wei

ght)

Hg

Page 34: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 32

Trend of Ni concentration at Point Dume

y = -0.0099x + 21.009R2 = 0.0247

0

1

1

2

2

3

3

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n (u

g/ g

dry

wei

ght) Ni

Trend of Pb concentration at Point Dume

y = -0.0024x + 6.7617R2 = 0.0005

0

1

1

2

2

3

3

4

4

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n (u

g/ g

dry

wei

ght) Pb

Trend of Sb concentration at Point Dume

y = -0.2341x + 466.37R2 = 0.8759

-1

0

1

1

2

2

1985 1986 1987 1988 1989 1990 1991 1992 1993 1994

Year

Con

cent

ratio

n (u

g/ g

dry

wei

ght) Sb

Page 35: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 33

Trend of Se concentration at Point Dume

y = -0.0583x + 119.06R2 = 0.3522

0

1

1

2

2

3

3

4

4

5

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n (u

g/ g

dry

wei

ght) Se

Trend of Si concentration at Point Dume

y = -54.32x + 109123R2 = 0.0401

0

500

1000

1500

2000

2500

1984 1986 1988 1990 1992 1994Year

Con

cent

ratio

n (u

g/ g

dry

wei

ght Si

Trend of Zn concentration at Point Dume

y = -3.8551x + 7830R2 = 0.47

0

50

100

150

200

250

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n (u

g/ g

dry

wei

ght)

Zn

Page 36: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 34

Santa Cruz Island

Trend of Total Butyltin concentration at Santa Cruz Island

y = 0.0202x - 33.265R2 = 0.0004

0

2

4

6

8

10

12

14

16

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/g d

ryw

eigh

t)

Total Butyltin

Trend of Total Chlordane concentration at Santa Cruz Island

y = 0.0328x - 61.021R2 = 0.0138

0

1

2

3

4

5

6

7

8

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/g d

ryw

eigh

t)

Total Chlordane

Trend of Total DDT concentration at Santa Cruz Island

y = -1.2295x + 2480.5R2 = 0.196

0

10

20

30

40

50

60

70

80

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/g d

ryw

eigh

t)

Total DDT

Page 37: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 35

Trend of Total Dieldrin concentration at Santa Cruz Island

y = 0.0291x - 56.06R2 = 0.0466

0

1

1

2

2

3

3

4

4

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/g d

ryw

eigh

t)

Total Dieldrin

Trend of Total PAH concentration at Santa Cruz Island

y = 3.251x - 6435.8R2 = 0.2041

0

20

40

60

80

100

120

140

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/g d

ryw

eigh

t)

Total PAH

Trend of Total PCB concentration at Santa Cruz Island

y = 0.2343x - 456.89R2 = 0.0379

0

5

10

15

20

25

30

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/g d

ryw

eigh

t)

Total PCB

Page 38: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 36

Trend of Ag concentration at Santa Cruz Island

y = -0.0134x + 27.085R2 = 0.1524

0

0

0

0

0

1

1

1

1

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ryw

eigh

t

Ag

Trend of As concentration at Santa Cruz Island

y = -0.7736x + 1567.5R2 = 0.5011

0

5

10

15

20

25

30

35

40

45

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ryw

eigh

t)

As

Trend of Cd concentration at Santa Cruz Island

y = 0.1743x - 342.16R2 = 0.114

0

2

4

6

8

10

12

14

16

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ryw

eigh

t

Cd

Page 39: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 37

Trend of Cr concentration at Santa Cruz Island

y = 0.0053x - 8.2286R2 = 0.0012

01122334455

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ryw

eigh

t

Cr

Trend of Cu concentration at Santa Cruz Island

y = -0.0113x + 29.163R2 = 0.0108

0

1

2

3

45

6

7

8

9

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ryw

eigh

t)

Cu

Trend of Hg concentration at Santa Cruz Island

y = -0.001x + 2.1447R2 = 0.0558

0

0

0

0

0

0

0

0

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ryw

eigh

t)

Hg

Page 40: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 38

Trend of Ni concentration at Santa Cruz Island

y = -0.0375x + 76.92R2 = 0.1206

0

1

1

2

2

3

3

4

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ryw

eigh

t)

Ni

Trend of Pb concentration at Santa Cruz Island

y = 0.0099x - 19.03R2 = 0.0238

0

1

1

2

2

3

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ryw

eigh

t)

Pb

Trend of Sb concentration at Santa Cruz Island

y = -0.0592x + 117.97R2 = 0.3948

00000001111

1984 1986 1988 1990 1992 1994 1996

Year

Con

cent

ratio

n(ug

/g d

ryw

eigh

t

Sb

Page 41: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 39

Trend of Si concentration at Santa Cruz Island

y = -123.99x + 247002R2 = 0.8015

-400

-200

0

200

400

600

800

1000

1984 1986 1988 1990 1992 1994 1996

Year

Con

cent

ratio

n(ug

/g d

ryw

eigh

t)

Si

Trend of Se concentration at Santa Cruz Island

y = -0.0385x + 79.087R2 = 0.0937

0112233445

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ryw

eigh

t)

Se

Trend of Zn concentration at Santa Cruz Island

y = 1.4086x - 2631.1R2 = 0.2067

0

50

100

150

200

250

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/g d

ryw

eigh

t

Zn

Page 42: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 40

Pacific Grove Lovers Point

Trend of Total Butyltin concentration at Pcific Grove lovers point

y = -1.6654x + 3334.1R2 = 0.2984

-20-10

010203040506070

1980 1985 1990 1995 2000 2005 2010

Year

Con

cent

ratio

n(ng

/gdr

ywei

ght)

Total Butyltin

Trend of Total Chlordane concentration at Pcific Grove lovers point

y = -0.6524x + 1316.8R2 = 0.2246

05

101520253035404550

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/gdr

ywei

ght)

Total Chlordane

Trend of Total DDT concentration at Pcific Grove lovers point

y = -2.718x + 5473.9R2 = 0.1453

0

50

100

150

200

250

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/gdr

ywei

ght)

Total DDT

Page 43: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 41

Trend of Total Dieldrin concentration at Pcific Grove lovers point

y = -0.3952x + 800.61R2 = 0.1258

05

10152025303540

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/gdr

ywei

ght)

Total Dieldrin

Trend of Total PAH concentration at Pcific Grove lovers point

y = 1.2652x - 2458.7R2 = 0.0678

020406080

100120140160

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/gdr

ywei

ght) Total PAH

Trend of Total PCB concentration at Pcific Grove lovers point

y = -0.2058x + 433.11R2 = 0.0154

0

10

20

30

40

50

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/gdr

ywei

ght) Total PCB

Page 44: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 42

Trend of Ag concentration at Pcific Grove lovers point

y = 0.007x - 13.815R2 = 0.0217

0

00

1

11

1

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght) Ag

Trend of As concentration at Pcific Grove lovers point

y = -0.2422x + 497.38R2 = 0.3623

0

5

10

15

20

25

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght) As

Page 45: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 43

Trend of Cd concentration at Pcific Grove lovers point

y = 0.2667x - 525.66R2 = 0.2688

02468

101214

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght) Cd

Trend of Cr concentration at Pcific Grove lovers point

y = 0.0373x - 72.815R2 = 0.1708

0112233

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght)

Cr

Trend of Cu concentration at Pcific Grove lovers point

y = 0.078x - 147.92R2 = 0.0771

02468

101214

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght)

Cu

Page 46: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 44

Trend of Hg concentration at Pcific Grove lovers point

y = 0.0015x - 2.843R2 = 0.0533

000000

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght)

Hg

Trend of Ni concentration at Pcific Grove lovers point

y = 0.0334x - 64.834R2 = 0.1451

0

1

1

2

2

3

3

4

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght

Ni

Trend of Pb concentration at Pcific Grove lovers point

y = -0.0921x + 190.03R2 = 0.0531

0

2

4

6

8

10

12

14

16

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght)

Pb

Page 47: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 45

Trend of Se concentration at Pcific Grove lovers point

y = -0.0123x + 26.959R2 = 0.0214

01

122

33

44

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght)

Se

Trend of Sb concentration at Pcific Grove lovers point

y = -0.1568x + 312.23R2 = 0.8787

0

0

0

0

0

1

1

1

1

1980 1985 1990 1995 2000 2005 2010

Year

Con

cent

ratio

n(ug

/gdr

ywei

ght)

Sb

Page 48: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 46

Trend of Si concentration at Pcific Grove lovers point

y = -72.064x + 143866R2 = 0.1405

0

200

400

600

800

1000

1200

1400

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght)

Si

Trend of Zn concentration at Pcific Grove lovers point

y = -0.4198x + 1014.2R2 = 0.0097

0

50

100

150

200

250

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght) Zn

Page 49: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 47

Pt Delgada Shelter Cove

Trend of Total Butyltin concentration at Pt. Delgada Shelter Cove

y = -0.557x + 1118.4R2 = 0.1135

-5

0

5

10

15

20

25

30

35

1980 1985 1990 1995 2000 2005 2010 2015

Year

Con

cent

ratio

n(ng

/gdr

ywei

ght) Total Butyltin

Trend of Total Chlordane concentration at Pt. Delgada Shelter Cove

y = -0.2355x + 477.05R2 = 0.2496

0

2

4

6

8

10

12

14

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/gdr

ywei

ght) Total Chlordane

Trend of Total DDT concentration at Pt. Delgada Shelter Cove

y = -0.1714x + 347.96R2 = 0.181

0

2

4

6

8

10

12

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/gdr

ywei

ght) Total DDT

Page 50: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 48

Trend of Total Dieldrin concentration at Pt. Delgada Shelter Cove

y = -0.2428x + 491.79R2 = 0.2395

02468

10121416

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/gdr

ywei

ght) Total Dieldrin

Trend of Total PAH concentration at Pt. Delgada Shelter Cove

y = 3.8726x - 7643.5R2 = 0.1015

050

100150200250300

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/gdr

ywei

ght) Total PAH

Trend of Total PCB concentration at Pt. Delgada Shelter Cove

y = -0.0714x + 150.47R2 = 0.0045

0

5

10

15

20

25

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ng

/gdr

ywei

ght) Total PCB

Page 51: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 49

Trend of Ag concentration at Pt. Delgada Shelter Cove

y = 0.0061x - 12.046R2 = 0.065

0.000.050.100.150.200.250.300.350.400.45

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght) Ag

Trend of As concentration at Pt. Delgada Shelter Cove

y = -0.1247x + 261.29R2 = 0.14

02468

1012141618

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght) As

Trend of Cd concentration at Pt. Delgada Shelter Cove

y = -0.0096x + 25.843R2 = 0.0008

0

2

4

6

8

10

12

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght)

Cd

Page 52: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 50

Trend of Cr concentration at Pt. Delgada Shelter Cove

y = 0.0294x - 56.008R2 = 0.0912

011223344

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght)

Cr

Trend of Cu concentration at Pt. Delgada Shelter Cove

y = 0.2647x - 518.55R2 = 0.4935

0

24

68

1012

1416

18

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght) Cu

Trend of Hg concentration at Pt. Delgada Shelter Cove

y = 0.0005x - 0.9028R2 = 0.0034

0

0

0

0

0

0

0

0

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght Hg

Page 53: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 51

Trend of Ni concentration at Pt. Delgada Shelter Cove

y = 0.0839x - 164.29R2 = 0.2316

0

1

2

3

4

5

6

7

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght

Ni

Trend of Pb concentration at Pt. Delgada Shelter Cove

y = 0.014x - 26.437R2 = 0.0825

0

1

1

2

2

3

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght)

Pb

Trend of Se concentration at Pt. Delgada Shelter Cove

y = -0.0294x + 61.216R2 = 0.1054

0112233445

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght

Se

Page 54: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 52

Trend of Sb concentration at Pt. Delgada Shelter Cove

y = -0.1502x + 299.1R2 = 0.8064

-0.4-0.20.0

0.20.40.60.8

1.01.2

1985 1987 1989 1991 1993 1995

Year

Con

cent

ratio

n(ug

/gdr

ywei

ght)

Sb

Trend of Si concentration at Pt. Delgada Shelter Cove

y = 263.4x - 521726R2 = 0.0984

0

1000

2000

3000

4000

5000

6000

1985 1987 1989 1991 1993 1995Year

Con

cent

ratio

n(ug

/gdr

ywei

ght

Si

Trend of Zn concentration at Pt. Delgada Shelter Cove

y = -1.0832x + 2310.9R2 = 0.0853

0

50

100

150

200

250

1980 1985 1990 1995 2000 2005 2010Year

Con

cent

ratio

n(ug

/gdr

ywei

ght)

Zn

Page 55: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 53

Page 56: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 1

South Catalina Island Bird Rock La Jolla La Jolla Newport Beach West Jetty

Year

Number of

sample R2 R Table

R

Number of

sample R2 R Table

R

Number of

sample R2 R Table

R Total

Butlytins 9 0.034 0.185 0.666 11 0.038 0.195 0.602 10 0.461 0.679 0.632

T_CDANE 13 0.313 0.559 0.553 15 0.302 0.550 0.514 14 0.166 0.408 0.532

T_DDT 13 0.250 0.500 0.553 13 0.253 0.503 0.553 14 0.271 0.521 0.532T_DIEL

D 13 0.228 0.477 0.553 15 0.031 0.176 0.514 14 0.061 0.246 0.532Total PAH 10 0.032 0.179 0.632 12 0.304 0.551 0.576 11 0.001 0.035 0.602Total PCBs 11 0.038 0.195 0.602 12 0.017 0.130 0.576 12 0.126 0.354 0.576

Zn 13 0.205 0.453 0.553 14 0.005 0.072 0.532 14 0.144 0.379 0.532Ag 10 0.017 0.130 0.632 10 0.461 0.679 0.632 10 0.658 0.811 0.632AS 13 0.352 0.593 0.553 15 0.337 0.580 0.514 14 0.195 0.441 0.532CD 13 0.142 0.377 0.553 15 0.003 0.054 0.514 14 0.165 0.406 0.532CR 13 0.001 0.026 0.553 15 0.000 0.014 0.514 14 0.016 0.126 0.532CU 13 0.174 0.417 0.553 15 0.138 0.371 0.514 14 0.055 0.235 0.532HG 13 0.224 0.473 0.553 15 0.527 0.726 0.514 14 0.420 0.648 0.532NI 13 0.031 0.177 0.553 15 0.081 0.284 0.514 14 0.059 0.243 0.532PB 13 0.236 0.485 0.553 15 0.390 0.624 0.514 14 0.298 0.546 0.532SB 6 0.730 0.854 0.811 6 0.444 0.666 0.811 6 0.790 0.889 0.532SE 13 0.225 0.474 0.553 15 0.159 0.399 0.514 14 0.101 0.317 0.532SI 6 0.656 0.810 0.811 6 0.033 0.182 0.811 6 0.167 0.408 0.532

Page 57: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 2

Point Dume Point Dume Santa Cruz Island Fraser Pt. Pt. Delgada Shelter Cove Pacific Grove Lovers Point

Year

Number of

sample R2 R Table

R

Number of

sample R2 R Table

R

Number of

sample R2 R Table

R Number of data R2 R

table R(0.05)

Total Butlytins 11 0.502 0.709 0.602 9 0.000 0.020 0.666 12 0.114 0.337 0.576 12 0.298 0.546 0.576

T_CDANE 15 0.455 0.675 0.514 13 0.014 0.117 0.553 16 0.250 0.500 0.497 16 0.225 0.474 0.497 T_DDT 15 0.330 0.574 0.514 13 0.196 0.443 0.553 16 0.181 0.425 0.497 16 0.145 0.381 0.497

T_DIELD 15 0.103 0.321 0.514 13 0.047 0.216 0.553 16 0.240 0.489 0.497 16 0.126 0.355 0.497 Total PAH 12 0.016 0.127 0.576 10 0.204 0.452 0.632 13 0.102 0.319 0.553 13 0.068 0.260 0.553

Total PCBs 11 0.199 0.446 0.602 11 0.038 0.195 0.602 14 0.005 0.067 0.532 13 0.015 0.124 0.553

ZN 14 0.470 0.686 0.532 13 0.207 0.455 0.553 16 0.085 0.292 0.497 16 0.010 0.098 0.497 Ag 10 0.317 0.563 0.632 10 0.152 0.390 0.632 12 0.065 0.255 0.576 12 0.022 0.147 0.576 AS 15 0.445 0.667 0.514 12 0.501 0.708 0.576 16 0.140 0.374 0.497 16 0.362 0.602 0.497 CD 15 0.452 0.672 0.514 13 0.114 0.338 0.553 16 0.001 0.028 0.497 15 0.269 0.518 0.514 CR 14 0.051 0.227 0.532 12 0.001 0.035 0.576 16 0.091 0.302 0.497 16 0.171 0.413 0.497 CU 15 0.348 0.590 0.514 13 0.011 0.104 0.553 16 0.494 0.702 0.497 16 0.077 0.278 0.497 HG 14 0.330 0.574 0.532 13 0.056 0.236 0.553 16 0.003 0.058 0.497 16 0.053 0.231 0.497 NI 15 0.025 0.157 0.514 13 0.121 0.347 0.553 16 0.232 0.481 0.497 16 0.145 0.381 0.497 PB 15 0.001 0.022 0.514 13 0.024 0.154 0.553 16 0.083 0.287 0.497 16 0.053 0.230 0.497 SB 6 0.876 0.936 0.811 6 0.395 0.628 0.811 6 0.806 0.898 0.811 6 0.879 0.937 0.811 SE 15 0.352 0.593 0.514 13 0.094 0.306 0.553 16 0.105 0.325 0.497 16 0.021 0.146 0.497 SI 6 0.040 0.200 0.811 6 0.802 0.895 0.811 6 0.098 0.314 0.811 6 0.141 0.375 0.811

Page 58: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

Appendix 3: Mussel Watch Data

Appendix 3 Ocean Plan Exception Page 1

Historical California State Mussel Watch Data Summary, 1977-99 Trinidad Head At the Trinidad ASBS, results for ten constituents (aluminum, chromium, copper, mercury, manganese, nickel, selenium, oxychlordane, cis-chlordane, and chlorpyrifos) at times indicated elevated levels above the EDL 85. Of the 23 analyses, eight results for aluminum, five results for chromium, four results for copper, one result for mercury, 14 results for manganese, and two results for selenium were above the EDL 95 for during the period 1977 to 1999. Of the eight organic chemistry analyses performed, one result for gamma chlordane, six results for oxychlordane, and seven results for chlorpyrifos were above the EDL 95 from 1982 to 1999. Point Reyes Headlands At the Point Reyes ASBS, only results for two constituents, oxychlordane (one out of one test) and o,p’DDD (one out of five tests) indicated elevated levels above the EDL 95. James V. Fitzgerald At the James V. Fitzgerald ASBS, results for eight constituents (aluminum, chromium, nickel, oxychlordane, p,p’DDE, PCB 1248, PCB 1254, and total DDT) at times indicated elevated levels above the EDL 85. Of the eight metals analyses, three results for aluminum, one result for chromium, and two results for nickel were above their respective EDL 95 during 1977 to 1999. Of the nine organic chemistry analyses, two results for oxychlordane, three results for chlorpyrifos, one result for PCB 1248, one result for p, p’DDE, and one result for total DDT were above the EDL 95. Año Nuevo At the Año Nuevo ASBS, eight constituents (mercury, p,p’DDD, p,p’DDE, o,p’DDT, p,p’DDT, total DDT, PCB 1254, and dieldrin) at times indicated elevated levels for the EDL 85. Six out of six results for mercury were above EDL 95 from 1977 to 1982. Out of four organic analyses performed, four results for p,p’DDE, four results for total DDT, and three results for PCB 1254 were above the EDL 95. Pacific Grove At the Pacific Grove ASBS, 14 constituents (cadmium, copper, mercury, lead, zinc, trans-nonachlor, oxychlordane, chlorpyrifos, dachtal, p, p’DDD, o, p’DDT, endosulfan, alpha heptachlor, and pentachlorophenol) at times indicated elevated levels for the EDL 85. Of the 26 metals analyses, the highest frequency for exceeding the EDL 95 was for lead (nine results) and zinc (nine results).

Page 59: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

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Carmel Bay At the Carmel Bay ASBS, results for seven constituents (cadmium, nickel, selenium, dachtal, p,p’DDT, total endosulfan, and heptachlor) at times indicated elevated levels above the EDL 85. Of these, cadmium (16 out of 32 tests) most frequently exceeded the EDL 85. Northwest Santa Catalina Island & Southeast Santa Catalina Island At Santa Catalina Island (the general location for four ASBS), only four constituents (aluminum, manganese, lead, and zinc) at times indicated elevated levels. Lead was the constituent with consistent elevated levels (ten out of ten tests) exceeded the EDL 85. Robert E. Badham At the Robert E. Badham ASBS, ten constituents (silver, copper, manganese, mercury, lead, zinc, dachtal, p,p’DDT, PCB 1254, and p,p’DDD) at times indicated elevated levels. Silver (seven out of seven tests), lead (six out of seven tests), PCBs (five out of six tests), and p,p’DDT (six out of seven tests) most frequently exceeded the EDL 85. La Jolla At the San Diego Scripps and La Jolla ASBS, only four constituents (silver, lead, zinc, and o,p’DDT) at times indicated elevated levels. Silver (six out of eight tests) and lead (five out of eight tests) most frequently exceeded the EDL 85.

Page 60: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

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2001-2005 State Mussel Watch Data

Location Constituent 2001-2002

2002-2003

2003-2004

2004-2005

Trinidad Head Silver -8 0.015 ND ND

Aluminum 502 1044 90 1250 Asimuth 6.3 15.49 9.14 9.31 Cadmium 3.64 6.15 6.28 8.4 Chromium 4.55 5.62 6.85 6.11 Copper 7.09 11.62 8.22 7.36 Magnesium 13.2 21.69 16.47 15.38 Nickel 3.32 3.65 5.85 4.74 Lead 0.75 1.11 1.11 1.59 Selenium 2.7 3.91 3.09 2.36 Zinc 73 99 110 136 Mercury 0.08 0.075 0.093 0.117 Chlordane NT NT -8 NT DDE,p,p' NT NT -8 NT CCDAN NT 1.24 1.04 NT TCDAN NT 1.03 -8 NT TOTCL NT 2.27 1.04 NT DDDOP NT -8 -8 NT DDDPP NT -8 -8 NT DIELD NT 3.75 7.3 NT HCHA NT 4.48 3.62 NT HEPOX NT 1.2 1.09 NT PCB54 NT -8 16 NT TPCB NT -8 NT NT

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Bodega Head Silver 0.06 0.05 0.11 ND

Aluminum 239 28 326 475 Asimuth 10.77 9.61 8.87 11.06 Cadmium 9.3 17.3 13.97 15.12 Chromium 2.49 1.2 5.32 2.88 Copper 6.14 4.75 8.08 6.48 Magnesium 6.93 4.48 5.66 6.49 Nickel 3.56 1.38 4.55 1.77 Lead 1.33 0.44 0.91 1.55 Selenium 4.83 3.49 3.05 ND Zinc 161 66 133 153 Mercury 0.308 0.96 0.143 0.224 Chlordane NT NT 1.89 NT DDE,p,p' NT NT 4.86 NT CCDAN NT 1.75 1.06 NT TCDAN NT 2.11 -8 NT TOTCL NT 3.86 1.06 NT DDDOP NT -8 -8 NT DDDPP NT 5.44 -8 NT DIELD NT 7.3 7.44 NT HCHA NT 2.2 2.33 NT HEPOX NT 1.3 1.06 NT PCB54 NT -8 -8 NT TPCB NT -8 NT NT

Page 62: NOAA NS&T Mussel Watch Program Data: Most Recent Data …...2007-2009 Average 128.68 3067.21 293.24 1139.17 2007-2009 STDEV 129.12 10424.76 597.28 6037.52 ... Mi s s i o n B a A g

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J. Fitzgerald Silver 0.09 0.123 ND ND

Aluminum 407 379 634 538 Asimuth 9.95 9.1 10.11 9.43 Cadmium 6.31 9.18 7.01 6.62 Chromium 3.37 2.35 2.94 3.06 Copper 6.6 5.96 7.61 7.24 Magnesium 6.33 5.21 8.03 6.25 Nickel 2.71 2.52 3.01 1.73 Lead 0.98 0.93 1.16 1.02 Selenium 3.95 5.06 4.29 2.28 Zinc 122 105 155 123 Mercury 0.15 0.124 0.166 0.133 Chlordane NT 1.06 NT DDE,p,p' NT 5.68 NT CCDAN NT 3.04 1.12 NT TCDAN NT 2.99 -8 NT TOTCL NT 6.03 1.12 NT DDDOP NT -8 -8 NT DDDPP NT 4.43 -8 NT DIELD NT 8.39 6.37 NT HCHA NT 1.73 1.51 NT HEPOX NT 1.44 -8 NT PCB54 NT 17 13 NT TPCB NT 17 NT

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Pacific Grove Silver 0.09 0.037 ND NT

Aluminum 248 311 95 NT Asimuth 13.93 12.37 14.2 NT Cadmium 12.93 10.91 13.24 NT Chromium 2.05 2.2 2.44 NT Copper 6.51 6.14 7.16 NT Magnesium 4.32 4.15 3.55 NT Nickel 2.87 3.18 3.16 NT Lead 3.21 3.11 3.08 NT Selenium 4.03 4.58 3.64 NT Zinc 207 188 192 NT Mercury 0.2 0.136 0.133 NT Chlordane NT NT 1.29 NT DDE,p,p' NT NT 18.2 NT CCDAN NT 3.07 1.82 NT TCDAN NT 3.42 1.35 NT TOTCL NT 6.49 3.17 NT DDDOP NT 5.15 5.86 NT DDDPP NT 5.4 -8 NT DIELD NT 10.4 11.1 NT HCHA NT 1.69 -8 NT HEPOX NT -8 -8 NT PCB54 NT 21 18 NT TPCB NT 21 NT NT

Note: NT = Not Tested Note: ND = Not Detected