novel puff model calculations of ozone production rates and possible no, voc emissions in the la...

Upload: jpeterson1

Post on 07-Aug-2018

218 views

Category:

Documents


0 download

TRANSCRIPT

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    1/20

    @evcm Zuaa Gehcm Klmkumltde`s ea Eze`c

    Zrehuktde` _ltcs l`h Zessdomc @E, QEK

    Cgdssde`s d` tfc ML Olsd`

    Blkeo Zdml`hStlf [tltc S`dvcrsdty

    Hcplrtgc`ts ea Odekfcgdstry l`h Kegputcr [kdc`kc

    Hr. Olrry Mcacr, @L[L F\

    Hr. Xdg Ocrtrlg, S^ Glhdse`

    Hr. He` Omlic, SK Drvd`c

    [tcvc` [kfdmm, SK [l` Hdcne

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    2/20

    D`trehuktde`

    YE;WYE;W

     QEKs&@Ex

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    3/20

    ;2 D`trehuktde` te Ltgespfcrdk Kfcgdstry, Blkeo,

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    4/20

    Gclsurcgc`t Mekltde`s

    •Ssd`n Me`nOclkf ls lprehuktde`ped`t

    •Aemmew [cl orcczcs teE`tlrde

    YE;W

    ΘYE;W ≆8:ppo 

    YE;W 78?ppo YE;W 76

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    5/20

    Cstdgltd`n _eutc

    •@ELL FT[ZMDX cstdgltcs

     wd`h trlbckterdcs.

    •Xfc kfesc` c`hped`t wlsusch ls FT[ZMDX sfews l`lmgest hdrckt reutc octwcc` Me`n Oclkf l`h

    E`tlrde

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    6/20

    _clktde`s

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    7/20

    Hckdhd`n [eurkcs l`h [d`is

    Mdtcrlturc

    D`dtdlm Ke`kc`trltde`2KL_O Nreu`h [tltde`

    Zfetemysds2

    XSQ Gehcm

    Cstdgltch oy[c`sdtdvdty Xcstd`n

    Xdgc

    D`dtdlm Ke`kc`trltde`2

     Ldroer`c Zmltaerg

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    8/20

    Hctcrgd`d`n Xdgc

    •ZfetekfcgdklmKmeki olsch eaa eatfc rltdes ea Xemuc`cte Oc`zc`c

     ^lr`cic ct lm., Hctcrgd`ltde` ea urol` vemltdmc ernl`dk kegpeu`h cgdssde` rltdes l`h kegplrdse` wdtf l` cgdssde`s hltlolsc, Beur`lm ea Ncepfysdklm rcsclrkf, ?::>

    •Fyhrexym rlhdklmke`kc`trltde` tlic`areg l `ertfcr`fcgdspfcrc lvcrlnc

    Y Y Y?W

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    9/20

    [cke`h Zfetekfcgdklm Kmeki

    •[cke`h Kmeki olsch eaa

    ea tfc rltde ea g,p-Vymc`cs te Ctfymoc`zc`c

    •Xdgc ds aeu`h oy usd`ntfc ∁V octwcc` rltdes 

    •Xfc adrst kmeki ds mdicmyl` u`hcrcstdgltc, out oetf tdgcs wcrc sdgdmlr

    @cmse` l`h \udnmcy, Xfc g,p-xymc`cs2ctfymoc`zc`c rltde. L tckf`dquc aer cstdgltd`n fyhreklroe` lnc d` lgodc`t ltgespfcrcs, Ltgespfcrdk C`vdre`gc`t,

    D`dtdlm2 ?.6

    D`dtdlm2

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    10/20

    Gehcm Kfckiped`t

    @cch te admm d` gerc vlrdlomcs… 

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    11/20

    [dgpmdayd`n _F Ke`kc`trltde`s

     Lkctlmhcfyhc

    Xrdgctfymoc`zc`c

    Zrepc`c

    Vymc`c

    Dseprc`c

    Hul`, Bd`nkfu` ct lm, Ke`kc`trltde`, seurkcs l`h eze`c aergltde` petc`tdlm ea vemltdmc ernl`dk kegpeu`hs (QEKs) hurd`n eze`c cpdsehc d` Ocdbd`n, Ltgespfcrdk _csclrkf 66, ?::6

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    12/20

    Ad`hd`n Y_E?W

    ZE; 7 ?iY_E?WY@EW er ?iYi?Y_FWtWY@EW

    •Dhc`tdadch 3 QEK—s

    rcspe`sdomc aer ~?1 pcrkc`tea Eze`c aergltde`

    •Ke`vcrtch QEK—s teprepc`c-cqudvlmc`kc

     Ke`vcrtch prepc`c (_F)te _E? 

    x 8

    Z 7 i ? 

    7 i ? t

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    13/20

    Gehcm Kfckiped`t

    Xfc _csumt ds 

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    14/20

    Caackt ea Cgdssde`s e` ZE;

       Z  r  e   h  u  k   t   d  e  `   _

      l   t  c  e   a   E  z  e  `  c   (  p  p   o   /  s   )

       Z  r  e   h  u  k   t   d  e  `   _

      l   t  c  e   a   E  z  e  `  c   (  p  p   o   /  s   )

       Z  r  e   h  u  k   t   d  e  `   _  l   t  c  e   a   E  z  e  `  c   (  p  p   o   /  s   )

       Z  r  e   h  u  k   t   d  e  `   _  l   t  c  e   a   E  z  e  `  c   (  p  p   o   /  s   )

       Z  r  e   h  u  k   t   d  e  `   _  l   t  c  e   a   E  z  e  `  c   (  p  p   o   /  s   )

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    15/20

    QEK l`h @Ex [c`sdtdvdty

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    16/20

    Ol`h ea [uppertch Eze`c Zrehuktde` Qlmucs

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    17/20

    Zessdodmdtdcs aer Auturc _csclrkf

    Dgprevc tfc puaa gehcm te l lkkeu`t aerhdspcrsde`

    •D`kmuhc gerc QEK rclktl`ts

    • Lkkeu`t aer kfcgdklm mess ea @E, FE?, Eze`c

    •D`kmuhc gerc hltl ped`ts lme`n tfc trlbckteryea tfc puaa gehcm

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    18/20

    Ke`kmusde`s

     L rclse`lomc Eze`c prehuktde` wls aeu`h aertfds scktde` ea tfc ML Olsd`

    •Dt ds mdicmy tflt tfcrc lrc oetf d`krclsch @E

    l`h QEK cgdssde`s d` tfc ML Olsd`

    •Xfds puaa gehcm prevdhcs pmlusdomc @E l`h

     QEK cgdssde` cstdgltcs

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    19/20

     

    Lki`ewmchncgc`ts2 

    [tcvc [kfdmm ◂ Hr. Olrry Mcacr ◂ Hr. Xdg Ocrtrlg ◂ Hr. He` Omlic ◂ Klmdaer`dl Ldr _cseurkc Oelrh ◂ Cgdmy [kflmmcr ◂ [cl` Arccgl` ◂ 

    Bdggy Amy`` ◂ @dki Fcltf ◂ _dki [fcttcr ◂ Lmm [L_Z Gc`ters ◂ HK6 Amdnft krcw ◂  [; ◂ Lmm Gy @cw Ardc`hs ◂ Zlmghlmc 

  • 8/20/2019 Novel puff model calculations of ozone production rates and possible NO, VOC emissions in the LA Basin

    20/20

    _cacrc`kcs

    Krutzc`, Zlum B. l`h Blki Adsfgl`. ”Lvcrlnc ke`kc`trltde`s ea EF d` tfc trepespfcrc, l`h tfc ouhncts ea KF8,KE, F? l`h KF;KKm;.‗ Ncepfysdklm _csclrkf Mcttcrs 8. Dssuc 6 (>)2 ;?