optical and esr characterization of transition atoms in...
TRANSCRIPT
i
993i C d Ykh 1nary ompouns ooama, ,tlupp. 11438843,-23.
fT nAtmsnCAIS2uioiotirans
KAl
LJ
-
ies.itur
lba eI,
heh h f ftecargeranserroltebi mt
hed tan,areiternaresor
hllse-
i l trvaencaan
an
l tnovaenanl ftasoiS bor
nb df
mo dtnb dd
-tencalnoval ftasomoi
keil-onor
l ttaencesaesanh teypetnemi dv
tnstrealheri d tonsunert tera ma me
dhanlaenchltaibr softev eb dtote3
-orac-onort tanh leresu
-hecont
-
d一nleveilple色一 ds tl sof3
oU yofAg dT ,yltzooghectureanLClru.tiversEnTkoyltzoogy,hec
hierontl fteemenso)Alta-htos
-demarca(yi dtonoeepenergltea
-ionspecilb tcaasorphi terongroupop,tftyoimpur
hI dMppl 2(993 ppl
Op dESRCh no
dT
yofT
Tt tonaodERp 2S ht m(iiranstil l d d itngecrysas opew,
tesuya
mit tonao
io
nr mp n3po
Rs
hlcacoge
ii torgnael lecua
an
gi lcntet es ,
it taracerza
t trucure
do
t
S i d iit t ternaryemconucorrans,
iyr
mo ro
hlacop
t
Su
F lacu
S
)
S
ilcaan
Etrum,
coteragona
1
n
t
C fTtn on ernaryan. .h Vl3ys o. .
t tecenyearsernaryh
P.tP 9roc.
J AJpn..
C lliitrysa znI
AhCeit tesn ulSii h l bittesneacvaencesaeength i iesempur
2
ti fonsoi ttveconcenrah ltereaff lt tt terenvaencesaes,ihideritni tcearepresentiimpurTAihttah b f daseenountidIe.ih b dtaveeensu,NF C dn e oan, , ,iVC Mr,, ,i Tgroup e,..
kespossici honsw,t hma
-gma
O dun h b deanil levehFe ertfmp
mi nt
iesitur
heinergeitse
ior
itonza
i dganb dserve
h
h
how
navlba
aoepara
tfloin
tspecr
iitrans on
hw erea
Th mesamogtel
ma dh ebeeno ,ael nTdisT eIIs stei ne sOft
ionsi ttrena
he A
lievesitrcaoehioitosdT
noftedma nl nt
leTbanirzeiesaresudtuhteftsoleresuTh ESRs mma di
bytu
)doun 3,mpurferorbas
.hirze
h■ean
u
itw
avlt trysagrow
w
h d iereasopng
ig.h
I
win
hf dMnh eenp meddgtec hbyteCVTnF 1 eh esmma dteo ionilb tcaasorptp
d-icf horw2,Auionsh Tetfterso Ai nClS hd
nuseh lteexerna
Slauesipitqecvhtsdaswe,ilefitnecntot
lla ee esnv di
WAAKIH
brltasanibr d3do
NISib kouyu
inrhh dteoscompounthb d feangapoitnl levehF ieermtftonoh iieposd dt tepenenon
htehOon.ltaibr sofTA i nteo rh
2+-
iod tconuc-hllse-d
OSh Ce ut AI2Ch l ftecrysasoi iestiur nt
inlltconro gt)iesanitur dby2
iof d to conucltasibr
borti ionspartitrans yfk 3esic
osei honsw,cot
mp dof3hma
ioth iepos no
dendi
1 J4 apan,8iTkogane oyo,K
iganl do
dM 2 993)41,ayR ieceve(
VN,ON
ttpecra. Oun
ilcaantpihcangeno dESRsmp dwihTA imp
eaftureo
bm
haveingh ttesar
C Cr oan, , ,it tnsni lsee
,h
ssucddia nhaTiⅤ dNi eencrrido
gt me ot ix
teerh itavere
h icangn)
Tfoby
We dtodAimp1 gt
tC ldtrysasopeSh Ce utf AI2 hTAidwi mp
′
f tonsorwTl fvaueso-heg Ai oo
ohoh iesstyn ftec
n3+-TA2+a
tiopnltrya
h bsperesorioihtysoc
ff tterenak ieil-
itcepor
gai
pb mend mo yd gwihd
mp
dan.lvaenchte ebftoiolteahfranse
i te..a
hcarg
banT
et rtAl+, epdgplnr nto山e po
iolteaih ltecrysati faxso-hech lsown
ftoIII, gt
nr
ousetnslt tuen eeits me dfrs
OSuhtfiopnD go eC AI2 C
itonirans sTA
至,C3
AxEsO Igor,TASiktasuaK
-
mbpme
C lhtrysas av
lng 一ter
SS
eena muhi ot mlhierproi Ces u.mi AI2
,w hhsbeenr yf dt
d tue
oundb mieena ep )
il tcaproper
l
S
ec
t tneres
lnescence
nl mi gdu
tecen
Ho llt nC AIea 2
i tnearop
grow
c
-s
inglnon
h ltoou
inh
a
tt
tt trac
iclu
derete
dtnescenan
h
wevera,
h bave
inaresnionsihgree g
lu
grb
lroseiaah be anth ftecenero dgpwillg notsnear-
erfeech
htiot
lfeveoh
nergto
l i dteves nrouce,
inhtft
seiiivcnenergt
ahehe
iinceS
inqul leve
ecnbeu dtomo rtemo nofteF mi nt yo ee yl ed t.
yl dbyt
trongoemits
dnluoiteradtobeap ema lfrb eaivterspec
hosefeecap.anhot ro eb A di testene
lmpdtoe
hih
ichtyw,ft dget twec
foun
lcos
-hteertfero
h fereorecan,dtan,
ishttaelvaencehargeffereninl lofd tc d( )s softeveiot
-
-
eaahbe antin dgpcnb
-aref teec
-in-
-Heri
-
lShCAeuti fesotroper
db Aions.Tyl li dtevesnrouce)iton
J JeveF itpecrum erm,
AIBhteypetd founso
d tconucorseaanhieitur sinteb dgpofsmi
laicah teopT
:C 2SAuS JDtF
dgaband tesh iew
WOYEK
mp ditsouncomary
ebeen
l dtsocaeiotl l ieveposecni
d-d itconucors e,..ebeoserveiesca,itur nb dinsmi 1)d
iiv-d tonuc
in
・ 仙e ma ne nsnr-
h Fe er
触e dbytTht
tgne
rcadehe
h
hroug
esonans
ts
ttae
l levepa
hargeipltecro
h
yimi sse ht ma
nic,
nce.
rayoftec ds softed
energlt teecronsas
dfeec
l d ita an, ,′para
iontrca
ltpi
cryshte
-h tcargerans
hei ltonsreae,titransfttaeso
fl itpeso eecroncyhtencarge
Twds
ot dtot TA
ftnsot trealhertproperhe ma me
pty-tensaehl dpycmpoightibihx
htece(ESR)
tomiotirans na
trreehtnes e,dare,Suini ldncuT((A)imp
gC AI2) eepo Ha kaproc-Ah
ine
f tereore,ma
i tneahle
eTytedyd gd
hiemi f mtonsroth l i it teeecroncransi te..
floind一nh l leevesonionsatitransimp
mogt f3 ma dofTAs
ion.itzalreaievce
l leveFerfiotiepos no mi
illanergtn
orriitoonza
iltsnovaleve
hnergin
iotiproxdtrouce
l l d teves eno,
ma ni df TA.Thde yl saeesse
gtei neon.Thte Ai
Ferhe mithta
)2sdaswe,ilefh f ltecysath ff fteeeco llaionstf iterrans
byt,
-d deucelieeas
feroCons a,
enuitonan.Tor
Ninceboserve,l
liTbs ahtponens
h itesp
fro
nHami Th mb〟 df Ai nb yd
mt es
t tnesrucurecom丘
-onec
hel leveh Fe ert mi nt
f doun
-rca
rettencesalaach i ieseonstlvaenc
i fonso
llteconroe
ettcenra
t
Th esne hv ea
ob dbytehiolteailt toscrysahtfaban
184
dgpo eh nr ntotedma
ivltreaheonsano)i(ttaes fTAi dt
.S2- '
fnoioth iepos
-h h tecargerans
一iirg-
hefrroooccu mt
f
hta
ose
iot ttnerprea
dounsarecoo
uc
ernar
oeaso
ittaesl lecua
1 bence an
).iton Ther nfrs hani nistmo ro
ds nt ycmp mp do
hte tsvaperphindespon gtoteu mo -
heS-d lloh 3eounh h te oscotf mp dtot
ievei d igansorvceversa2.
i blernaresare ehle
i ionstoitpur
f iterransyintot )T
nt dt
-tporaoThtel ftasoibrl bvaence antmae
dodo A in(cce tah itpooexckeil
orrltabr sci
_ _
6
for A
b i ts arcenersteerso
nbndhl ae i fTtsorparamnw
Zteq.ftea iob tsorphoions K.SATO
hitAi nC 2
mJ nC 2i mpAI ncep me sl di
Dq hp me Bldncu
iarso
ter
oitse
ara
Ster
ISu
araRaca
AuiJ
,
)hT
ions
).b ktraces
T htth ierwt togeh tos
ndle
igvetrysaitObr
f Zor nlspnbu
htai-
S( nidan
thh l丘 etete c cc
.S tl itpecraposlIeTba
nc
meter
(iions
para
993 32-l3p.Sup)
xJ3 m)O( 1-c
Ap 2(1h Vl3ys o. .lPp.J Jpn..
0 J5 J
JO I
5J
248
-メ
0
、-・h l b devaenceant
lS2
S2
AtosZSn
Cu
HCiton
itw
T irans
3
2
ht
TRl+ l u+
+ . AI
inglcoup
8101ノ
522
1一一一
5510甜
064
〞
9777
つ
itT iony rans
Ln Lu P
050
P dare
1
-
.
くJ50 0
0SOa mC
FLUI
1Dq
-
he -n
o
)
2hg so.
ltea
3( g.
tpecr
hange
hav ee
io
ons
h
le,
1
2g.
ito
6.
h
i:
i
n
i
he
leve l
l tecrons (
hy Lss.
ltse
h xaanges
ls
bo serve
er
hcarg
lvaenc
S ・ lPftao perences. . .PTDTeram.
ht
idn uce
C ltrysasccoun.
fo
l irosn
T dsunoaa.n
ing-
Stn
er
iiann
Fer
lnnea
he
senoS Htao. ,
ink
.
dope
t terpree
t
e
ln
fastec
ntneeESmp Fi ao wsdc Rs fNi
oaTadCugiAI2 ta ot
er dc sint
dint ms eF mi nFi eb ni
mo ninr nt
WihTA g go ge dNiTA i Fi , ss) et
gOnt mil es
) IAk vadK ReAp) K ndT i hett 1(992
Rf3e.)0a2
(4
A546057
0)
)a
EHJu
0ノ
522.NiFeCrViT
624.
hl teowes 5
eeevbs
20.
T.12
i T2ng
8
A
24.
5
1 0
liulSAi
ahil leveFer
htef yTA ime mi ntebn d
506.20.80.
57.
ereies.008
t33/
iur12.2.CI
mp Th -
he
n
bserv
on
a
ion
tns,once trea
ivlteaherrope
iob tui itsrgadrepbyp rt malt
nofr ec wecno et
sofTA i si
・L
㌣/二芸
N〃1
inhanges
.
.
/A
nJ■u
n川川■u
S
/ヽ
7〝岬
′ヽ
te iCsn u
n■11日】
f
O5
nr
iiesson
fJ5
impurhteo
TfOi lSonenergeitonza
Dq B
Ai g一g。-8
ntot po AI2
5)46)(
335
7dh
dpon
6
on iss
d
Fe
3hecorre
/22
5e.
11
d5
icl f Tvauesor
hrw
cr
1.
)S-2
teuis
がが
ion
2
+
vedgAI Aijo ht nC
+ F3 2+
998200+ 2
834.
60(5
55
0
008
58
))(547(
4T 29904A 803
2-44TTl-l(P)
)(PTlJTT2→3.
03
6132451 5003
co2'
Ni2.
dT
dS
h reexpiusntaaSrotaeimtes)a dfmERd gt JJJつ44lHH川U■ur
.in E
003
)P10000 JTTl→3 (Mn+ 1 06A・2 l
nerg
86
57
99947
Ateer.o
V
fparamCon
3T2-
2 87
1ノ 21.
3710.
ET2→→i 44Al+4
021502
dCAl itan usse
)4Tl
10.
6.
2ll.
23.
(CRfeerence
8 2 5 I
.
or
1.
46 b
hosin
h beoserh teca
.
霊偶l
df i ldteecs ncu,
lei h tnesows
√▲
dl
b
。
Tba
Cγ"OlI,...
III.T
tossu tttiue
加・。 軒 9982
otll
gt ef medb iotiosep no
t tnrainitib gi atpecra.nicatophet
ht
ladESR岳 As
ea
hsoltesu s wn
a,e,levesoitrca oh de e
12
t ma nl fF Cr
ioltea31f ZSor nhta )inr
2/5
4
httaesex,hcargesH terenid
ZSn
A2
20 01928922400
19
誓
7い。
ll 373
1
.9
.9
hgth langnf Core,
+2
d2Fez
d5RO
lIIeTba .I
¢
Id
3'
fel '
TR
3e
Q f:nsgeer..
hggs,l,F eF?e-l
oJ, C
\
/'y円 \ c.謹 c =7OK
hi l t tcaspecra,top4321
℃VlRT2.I::rr-L, 'F2e+C3.r
'2R.iTii,
2
Ti3' 、
0f
2e
TR
+F '
KOTTR:l ;o=nl
T, ド.
L Tヽ
一
bl23I章.A3
一
.I
ヽ ~..
/i.Nli〟.
◆2r+c
ll
4CT4A,,,̂t2L /
,′L/////JJ/ ′′
ここL
dtesiXQC
芸,
6A T:-.I
l
V3 A2
-T2.
3o-3
:
十
A23
\
c r;+ ET2 、コ5.,
lc
Mn2'
,/
j230一 3bTノ'2 LiT"27N"Ti3.,..メ ■l′-
s -一 J′′、 ノ
F㌔+
2A'24o -
-franserprochierh iangnh f Cereore,d tan , gt
-d dttaes epenion.tl ievepos
3.610)
-m
itonios
Ti ftonspecraoeilb tcaasorptopfb dooserveionltaioi 1g.F . Cmp PHOTON ENERGY (V) Ai
hI t,1)i+TA(
+
/bittsurn en, ieurAi ieslevetipuriot nCsoufTA i. itnl lS mp sTAi
-i itxrnscconhend tepen en oivtaepntead eivtcl i lltecrcaiont tcenra ensofe y a gd
l lieve,Ferhefto mi ni
2
--
32-l3p.Sup)
-h Fe ertfnoi f :g ora.hFe mi
IveCifiposon
一-
F- er..三 l mHe
VB
-ad,・ lduanneae a,ld Cnneae,htattoeacuul Nes.abgrown,las-neaedsm p-v m a -C nde -Sn-
e.F Ce r, ,:2Auo
㊦@
iagramd
2・
fClS NiTh
7.2
i 2g..
tarac.
)1
A
ir
C 告ry
62lPPp..
n
J
4.
.
dsuse
6TKS tt a ao ,.,.
基 G ttro row.
19 . d Shh 3R∫ :ono oysy.s.. .
J 3c pn. .
K lSで tea. .
ni inF
)7Mo mb
hCh
dK )2117
Ap 1(992L5
Ni OCB
10
l.
348
de,b0
)74196(
-Gon.Kara,
itoth ieposftparoTh iergkreitcaereidsnabthbeainl leve yESRa ma dby0.ndgpi dint ht
leve
㊤㊤
energt ic
hce. As mai 3g.yl
F
@ 3・2・
J Jpn..St:ao App
0.8523)619aa9(
_
ioitcaidnsaheth 3ys.P me
3
:P
619a
ta
W.ll2(993 9(
i
1. Staa,.
h iyscen
hos
irP.
1:enAtao dn,
) diar
985
..
(1
K S )339a2aaM.Mo Okm oH Tk
n
eJ.T KiN:senov aure, . ,
∫).
niK Sta, .
Slido
1iel
3
kaseno
T iherans.
Z :unger.
S.. .
h 3ys.
8.
.
1
)) J
P.
16
76
98
10
12
13
)) DIAk 11Cl.Mc Ch
) H We2(993m:L5ll) ⅠAk vadX) T oadK
) A
3kaw_ hhysNiP.m.si
Chm.
Jpm P h 3ys.
6e. St:ao.1
6(
Cr239仁山N山NO(∝ト̂)UJ>uua
d dtt ttsaeseece
006004ELf
saswe,itwC l d dtrysas ope,D (mT)
hNi lla
Jpn.J.Appl.Phys.Vol.32(1993
2∞MAGNETIC F
●) ,. ,
Ni+, O3
Mu& 1bttsurg, 9
Res.taer.J Ipn..t:ao9..54p.n)87Xdu.
iS Poc.,oadK S Ap
)lp.12.35.3)2s..Jp1St:ao.h 3ys.lPp.niJ Jkpn aw..hs.iSNt:aao., Ap 1(992aadK 1(992Ni n JAp
+,2cr,C 6,(8
denhsperes
h i lfesgnnasrotan
d□ma mo 00o 0hesp diii ifi tononpuywmrtt +Ni os )i dtndaot'( sa ui mFs
krscorri lgnatw
an∫,+cr
▼hae 3十e
M89assSnowmilvey.s,tcdompoun ,1 6(
hylPp.
iAIarous2Sdinvh
Ce ufto
ZTaillt yC
. ERs tpecraSi 2g.F
(tn.D) ^ヒ
SNuト Nl
V
fS
.1
N9
旺 S
u
elannealyb tsusequen
Tn, .5senoseno.
naq
I4.LL1AkA vk vadKK
0
5respe,9-11.Cgi Isotroplearyn
Ysenov,IAk.)3
))弓し