ozone

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Ozone is a form of elemental oxygen. In its most stable form, elemental oxygen exists as diatomic molecules (O2). The molecules of ozone contain three oxygen atoms (O3) and are unstable with respect to O2. Ozone is a very reactive gas, and even at low concentrations it is irritating and toxic. It occurs naturally in small amounts in the Earth's upper atmosphere, and in the air of the lower atmosphere after a lightning storm. At room temperature, ozone is a pale blue gas with a sharp odor, characteristic of the air after a thunderstorm or near an old electric motor. It condenses to a dark blue liquid at -112°C and freezes at -193°C.

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Ozone is much more reactive than O2. It is a very powerful oxidizing agent, second among elements only to fluorine. It can oxidize many organic compounds and is used commercially as a bleach for waxes, oils, and textiles, and as a deodorizing agent. Because it is a powerful germicide, it is also used to sterilize air and drinking water. Ozone is usually manufactured by passing an electrical discharge through O2 gas or through dry air. The resulting mixture of ozone and O2 or air is usually suitable for most industrial applications of ozone. Because ozone is very unstable and reactive, the preparation of pure ozone is both difficult and hazardous and is seldom attempted.

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Ozone is not only removed by ultra-violet radiation from the Sun but also by reaction with reactive compounds such as nitrous oxide (NO), the hydroxy radical OH or halogen radicals such as Cl and Br. A slight decrease in ozone concentrations was predicted by scientists once significant amounts of halogen containing species started to be released into the atmosphere by human activity.  However, no-one predicted that such a dramatic decrease in ozone levels in the stratosphere would occur over Antarctica.

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