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This summary for PV course of CVUT winter 2015-2016

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  • Czech Technical University in Prague

    Faculty of Electrical EngineeringDepartment of Electroenergetics

    PV Summary

    Author:

    Minh-Quan Dang

    January 12, 2016Prague

  • CONTENTS

    Contents

    1 General considerations 11.1 What are the energy needs of mankind, trends and problems of fossil

    fuels? . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11.2 What is renewable source and what are perspectives of different types? 41.3 What are the spectral properties and components of the sunlight? . . 51.4 What are the time variation properties and limits of the sun as a source? 6

    2 Solar cell physical aspects 72.1 What is the main limit (hint: of the single-junction) solar cell efficiency? 72.2 What determines the generated voltage and the generated current in

    solar cell? . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82.3 Equivalent circuit of solar cell and diode equation. . . . . . . . . . . . 8

    3 Solar cell Construction and Technology 93.1 Fabrication of silicon wafers . . . . . . . . . . . . . . . . . . . . . . . . 93.2 Fabrication of standard crystalline silicon solar cell . . . . . . . . . . . 103.3 Optical losses, improvements of standard crystalline cell technology . . 143.4 External Quantum Efficiency, its integral, types of losses . . . . . . . . 15

    4 Thin film 174.1 Material requirements and application advantages of thin-film technolo-

    gies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174.2 Examples of mainstream and emerging thin film technologies, perspec-

    tives . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17

    5 Construction and technology of PV modules 195.1 What determines the total power parameters of the module? . . . . . . 195.2 Effect of shading and its mitigation . . . . . . . . . . . . . . . . . . . . 195.3 Module fabrication components and steps, thin-film solar module inter-

    connection scheme. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 225.4 Effect of temperature and its partial mitigation, what is NOCT? . . . 23

    6 Autonomous PV systems 246.1 System with battery with / without regulator . . . . . . . . . . . . . . 246.2 Standalone household system and its dimensioning with / without backup

    (hybrid). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25

    7 On-grid PV system 277.1 Types of on-grid systems, sizing of PV inverter and string, requirements

    for cables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 277.2 Types and topologies of inverters, detailed wiring of small and medium

    system . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 287.3 Effect of PV on the grid (quality, voltage, stability) . . . . . . . . . . . 29

    DANG Minh-Quan 1

  • 8 Diagnostics 308.1 Diagnostics: type of failures, their consequences and methods to reveal 308.2 Maintenance, lifetime, monitoring, diagnostics using inverters, Potential

    Induced Degradation . . . . . . . . . . . . . . . . . . . . . . . . . . . . 318.3 I-V measurements: indoor/outdoor, requirements for sun simulator . . 338.4 Photo-/electro-luminescence: principle and type of failures . . . . . . . 338.5 Thermography: principle and type of failures . . . . . . . . . . . . . . 34

    9 Economic consideration 359.1 Levelized Cost of Energy, effect of efficiency on the cost of electricity . 359.2 Structure of the end user electricity price, time evolution in yearly and

    daily scale . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 369.3 Billing scenarios, type of tariffs . . . . . . . . . . . . . . . . . . . . . . 379.4 Energy payback time, carbon footprint, recycle . . . . . . . . . . . . . 38

    References 39

  • 1 GENERAL CONSIDERATIONS

    1 General considerations

    1.1 What are the energy needs of mankind, trends and prob-lems of fossil fuels?

    Energy is typically stored in the form of energy carriers (coal, gas, wood, etc.). Thisform of energy is typically called primary energy.

    The pressure of the steam is again used to drive a generator that makes electricalenergy available at the exit of the power station. This energy is called secondaryenergy.

    End Energy = Primary Energy - Secondary Energy - Losses

    Figure 1: Energy flow

    Figure 2: Human energy consumptions

    DANG Minh-Quan 1

  • 1 GENERAL CONSIDERATIONS

    Primary sources by percentages [Oil - Coal - Gas - nuclear energy - biomass, wastes- Hydro - Renewable]

    Problems:

    1. Growing Energy Requirements

    2. Tightening of Resources

    3. Climate Change

    4. Hazards and Disposal

    Figure 3: Co2 problem

    DANG Minh-Quan 2

  • 1 GENERAL CONSIDERATIONS

    Figure 4: Greenhouse effect

    DANG Minh-Quan 3

  • 1 GENERAL CONSIDERATIONS

    1.2 What is renewable source and what are perspectives ofdifferent types?

    Figure 5: Renewable sources

    DANG Minh-Quan 4

  • 1 GENERAL CONSIDERATIONS

    1.3 What are the spectral properties and components of thesunlight?

    Figure 6: Solar radiation

    Figure 7: Types of irradiation

    DANG Minh-Quan 5

  • 1 GENERAL CONSIDERATIONS

    1.4 What are the time variation properties and limits of thesun as a source?

    While the solar radiation incident on the Earths atmosphere is relatively constant,the radiation at the Earths surface varies widely due to:

    -atmospheric effects, including absorption and scattering;-local variations in the atmosphere, such as water vapour, clouds, and pollution;-latitude of the location; and-the season of the year and the time of day.The sun has different heights depending on the time of day and year. Air Mass

    is the ratio between actual traveling distance of the light in comparison to the verticalpath though the atmosphere.

    Figure 8: Air mass

    where =Sun height angleThe limit of sun light source during nice day AM 1 EG = 1000W/m

    2

    DANG Minh-Quan 6

  • 2 SOLAR CELL PHYSICAL ASPECTS

    2 Solar cell physical aspects

    2.1 What is the main limit (hint: of the single-junction) solarcell efficiency?

    1. Silicon thickness

    2. Carrier recombinations (radiative, Auger, via local centers)

    3. Free carrier absorption

    Figure 9: Carrier recombination

    Figure 10: Factors limit the solar cell efficiency

    DANG Minh-Quan 7

  • 2 SOLAR CELL PHYSICAL ASPECTS

    2.2 What determines the generated voltage and the generatedcurrent in solar cell?

    Generated current depends on:

    1. The area of solar cell

    2. the number of photons come to cells surface

    3. the spectrum of incident light

    4. Optical properties(absorption and reflection)

    5. the collection probability

    Generated voltage depends on:

    1. Recombination (measured by dark saturation current)

    2. Thickness of bandgap (direct proportional)

    2.3 Equivalent circuit of solar cell and diode equation.

    Figure 11: Equivalent circuit of a solar cell

    DANG Minh-Quan 8

  • 3 SOLAR CELL CONSTRUCTION AND TECHNOLOGY

    3 Solar cell Construction and Technology

    3.1 Fabrication of silicon wafers

    Czochralski process used to produce noncrystalline silicon.

    1. Melting pieces of polysilicon in crucible at 1450oC

    2. Seed crystal is dipped into the melt from above

    3. Withdraw the the seed with light rotation

    Figure 12: Czochralski method

    DANG Minh-Quan 9

  • 3 SOLAR CELL CONSTRUCTION AND TECHNOLOGY

    Figure 13: Wafer fabrication

    3.2 Fabrication of standard crystalline silicon solar cell

    Figure 14: Standard mass production (c-Si cells)

    DANG Minh-Quan 10

  • 3 SOLAR CELL CONSTRUCTION AND TECHNOLOGY

    Figure 15: etching of damaged layer

    Figure 16: texturing

    DANG Minh-Quan 11

  • 3 SOLAR CELL CONSTRUCTION AND TECHNOLOGY

    Figure 17: Phosphorous diffusion

    Figure 18: SiO 2 /SiN X deposition

    DANG Minh-Quan 12

  • 3 SOLAR CELL CONSTRUCTION AND TECHNOLOGY

    Figure 19: Al print screen

    Figure 20: firing of contact pastes

    DANG Minh-Quan 13

  • 3 SOLAR CELL CONSTRUCTION AND TECHNOLOGY

    Figure 21: edge grinding

    3.3 Optical losses, improvements of standard crystalline celltechnology

    Optical losses

    1. Reflection

    (a) anti-reflective coating

    (b) surface texturing

    (c) use different layers with different thickness to minimum refection for specificwavelength.

    2. Shading by means of contact finger

    (a) Reduce finger distance

    3. Parasitic absorption

    DANG Minh-Quan 14

  • 3 SOLAR CELL CONSTRUCTION AND TECHNOLOGY

    3.4 External Quantum Efficiency, its integral, types of losses

    Figure 22: External Quantum Efficiency

    Figure 23: Losses on solar cell

    DANG Minh-Quan 15

  • 3 SOLAR CELL CONSTRUCTION AND TECHNOLOGY

    Figure 24: Effect of losses

    DANG Minh-Quan 16

  • 4 THIN FILM

    4 Thin film

    4.1 Material requirements and application advantages of thin-film technologies

    Material used for production of thin film cell must possesses a direct bandgap.Advantages

    1. potentially cheap

    2. flexible, lightweight

    3. low material consumption

    4. better temperature factor

    4.2 Examples of mainstream and emerging thin film technolo-gies, perspectives

    Thin film production technology

    1. PVD = physical vapour deposition

    (a) Magnetron sputtering (PVD)

    2. CVD = chemical vapour deposition

    (a) CVD (PECVD)Plasma enhanced

    (b) metalorganic CVD

    (c) chemical vapor transport

    Major thin-film technologies

    1. Thin-film Si solar cell

    (a) absorber deposition: PECVD from SiH 4 with strong Hydrogen dilution defect passionating

    (b) advantages non-toxic materials

    (c) disadvantages Staebler-Wronski effect - low efficiency (10%) disorder -doping is problem - low voltage

    2. CIGS or CIS

    (a) advantages high efficiency (15 20%)

    (b) disadvantages homogeneity issues of ternary system, limited supply of In,toxicity of CdS

    3. CdTe

    DANG Minh-Quan 17

  • 4 THIN FILM

    (a) absorber deposition many methods (vapour transport dep.) + post-deposition treatment by Cl - grain boundary passivation

    (b) advantages low fabrication cost relatively high efficiency (15-20%)

    (c) disadvantages toxicity of Cd limited supply of Te

    4. AIIIBV multijunction cells

    (a) absorber deposition Molecular Beam Epitaxy vacuum< 1010 mbar !

    (b) advantages highest efficiency (46%)

    (c) disadvantages active cooling necessary, solar tracker necessary, extremelyexpensive equipment,

    DANG Minh-Quan 18

  • 5 CONSTRUCTION AND TECHNOLOGY OF PV MODULES

    5 Construction and technology of PV modules

    5.1 What determines the total power parameters of the mod-ule?

    The number of cells and type of interconnection determines the total power of themodule. Almost always cells are connected in series to increase the power and voltage.The current then depends on side of cell and its efficiency.

    5.2 Effect of shading and its mitigation

    Figure 25: Cell in parallel

    DANG Minh-Quan 19

  • 5 CONSTRUCTION AND TECHNOLOGY OF PV MODULES

    Figure 26: Cell in parallel shaded

    Figure 27: Cells in series

    DANG Minh-Quan 20

  • 5 CONSTRUCTION AND TECHNOLOGY OF PV MODULES

    Figure 28: Cells in series shaded

    Solution using bypass diodes. Bypass diode is connected anti parallel to solar cell.If no shady then cell has positive voltage, then no current flows through diode. If shadyis there, then cell has negative voltage. The current from unshaded cells go throughdiode. When the current is small enough then the voltage at shady will be positiveagain and contribute to the total current.

    Figure 29: Partial shading problem

    DANG Minh-Quan 21

  • 5 CONSTRUCTION AND TECHNOLOGY OF PV MODULES

    5.3 Module fabrication components and steps, thin-film solarmodule interconnection scheme.

    Module components

    Figure 30: Module components

    Module production steps

    1. Taking the cells

    2. Transporting the cells

    3. Soldering the cell strings

    4. Positioning the cell strings

    5. Feeding into the laminator

    6. Installation of the module frames

    Serial interconnection of thin film module by laser or mechanical scribing

    DANG Minh-Quan 22

  • 5 CONSTRUCTION AND TECHNOLOGY OF PV MODULES

    Figure 31: Thin film module

    5.4 Effect of temperature and its partial mitigation, what isNOCT?

    Figure 32: Effect of temperture

    Operating temperature of cells in the module depends on the ambient tempera-ture and the module construction (Thermal resistance rth) then to reduce impacts oftemperature:

    1. Use material with high heat transfer coefficient

    2. Low heat conductivity with larger thickness

    NOCT: Nominal Operating Cell Temperature is cell temperature at:

    1. Ambient temperature 20oC

    2. Irradiance 800 W/m2

    3. Wind speed 1m/s

    DANG Minh-Quan 23

  • 6 AUTONOMOUS PV SYSTEMS

    6 Autonomous PV systems

    6.1 System with battery with / without regulator

    Figure 33: Stand alone system without regulator

    Figure 34: Stand alone system with regulator

    DANG Minh-Quan 24

  • 6 AUTONOMOUS PV SYSTEMS

    Regulator or charge controller tasks:

    1. Overload protection

    2. Deep-discharge protection (10.8V for Pb-battery)

    3. Prevention of unwanted discharging

    4. State-of-charge monitoring

    5. Adjusting to battery technology (electrolyte/gel)

    6. Voltage conversion (possibly)

    7. MPP tracking (possibly) ensure PV system draws max. power from solar array.

    6.2 Standalone household system and its dimensioning with/ without backup (hybrid).

    Figure 35: off-grid PV applications

    DANG Minh-Quan 25

  • 6 AUTONOMOUS PV SYSTEMS

    Process of dimensioning the stand alone PV system:

    1. Determination of the energy demand and optimization of consumption

    2. Develop the concepts:

    (a) What voltage levels?

    (b) What type of PV system (DC, AC, combined AC/DC, with or withoutback-up generator)

    3. Sizing the PV generator and storage battery

    1

    cycleCS +

    GdGd0

    CA 1

    (a) Generator capacity

    CA =GAGGd0

    L

    Where A and are area and conversion efficiency of PV; G is mean valueof daily irr; L is mean value of daily load.

    (b) Battery capacity

    CS =CuL

    4. Dimensioning the charge controller

    5. Dimensioning the cables

    For PV with back-up system then smaller PV and battery system required. Systemwithout consumer limitations

    For PV without back-up system then consumer limitation or smart solutions mustbe applied to limit the size of the system.

    Cable requirements:

    1. Diameter 4-6mm2

    2. Water proof connectors

    3. Must be separated positive and negative in different tubes

    4. Loss < 1%

    DANG Minh-Quan 26

  • 7 ON-GRID PV SYSTEM

    7 On-grid PV system

    7.1 Types of on-grid systems, sizing of PV inverter and string,requirements for cables

    Figure 36: Grid-on PV system

    Figure 37: Hybird sytem

    DANG Minh-Quan 27

  • 7 ON-GRID PV SYSTEM

    7.2 Types and topologies of inverters, detailed wiring of smalland medium system

    Figure 38: PV installation

    Figure 39: Converter topologies for PV inverters

    DANG Minh-Quan 28

  • 7 ON-GRID PV SYSTEM

    7.3 Effect of PV on the grid (quality, voltage, stability)

    Quality

    1. Voltage: Maximum allowed voltage mismatch betweens PV and grid is 10%

    2. Frequency: maximum allowed frequency mismatch between PV and grid is0.2Hz or 0.5 Hz

    When V of f out of this range then PV system will be disconnected from the gridautomatically by its protective devices

    Figure 40: Voltage profile with present of PV

    PV system can supply active power but decrease power factor for the system.

    Figure 41: Incresing power factor

    DANG Minh-Quan 29

  • 8 DIAGNOSTICS

    8 Diagnostics

    8.1 Diagnostics: type of failures, their consequences and meth-ods to reveal

    Figure 42: Type of failures and method to reveal

    Figure 43: Diagnostics introduction

    DANG Minh-Quan 30

  • 8 DIAGNOSTICS

    8.2 Maintenance, lifetime, monitoring, diagnostics using in-verters, Potential Induced Degradation

    Figure 44: Causes of failures

    Figure 45: Life time

    DANG Minh-Quan 31

  • 8 DIAGNOSTICS

    Figure 46: Diagnostics using inverter

    Figure 47: Potential Induced Degradation

    DANG Minh-Quan 32

  • 8 DIAGNOSTICS

    8.3 I-V measurements: indoor/outdoor, requirements for sunsimulator

    Indoor measurement

    1. Continual sun simulators

    (a) Small area (cell)

    (b) Lab measurement (thin film)

    2. Flash test

    (a) large area (module)

    (b) Flash duration 1-10 ms

    (c) Error 2%

    Outdoor measurement

    1. Solar module analyzer

    2. Temperature measurement

    3. Irradiance measurement

    - Correction to STC

    -Error > 7%

    Sun simulator requirement

    1. Spectral mismatch

    2. non-uniformity (max-min)/(max+min)

    3. Short Term Instability (max-min)/(max+min)

    4. Long Term Instability (max-min)/(max+min)

    8.4 Photo-/electro-luminescence: principle and type of fail-ures

    The ideal is to light up a solar module as LED. Silicon emit spectrum about 1150nm then can not be seen by human eyes, the special camera must be used. Dark regionare critical for cell performance.

    1. Micro-crack (with/without effect on performance)

    2. Screen printing error

    3. interrupted metalization

    4. low-collection region

    5. low-lifetime region

    DANG Minh-Quan 33

  • 8 DIAGNOSTICS

    8.5 Thermography: principle and type of failures

    Defective cell will create hot spot (Joule heating) on PV module which can bedetected by thermometer camera.

    The knowledge of the characteristic thermo-pictures of the various operating con-ditions makes thermography a very effective means of quality control of photovoltaicplants. It is very easy to recognize incorrectly connected and defective modules.

    Figure 48: Solar module with 36 cells without bypass diodes: Shady acts as a load thatis massively heated by the remaining 35 cells

    Figure 49: View of various degrees of shading: The transferred heat power reaches amaximum for degrees of shading between a quarter and half of the cell

    DANG Minh-Quan 34

  • 9 ECONOMIC CONSIDERATION

    9 Economic consideration

    9.1 Levelized Cost of Energy, effect of efficiency on the costof electricity

    Figure 50: Levelised Cost of Energy LCOE

    Figure 51: Simple COE

    DANG Minh-Quan 35

  • 9 ECONOMIC CONSIDERATION

    Figure 52: Effect on efficiency on COE

    Figure 53: LCOE

    9.2 Structure of the end user electricity price, time evolutionin yearly and daily scale

    Figure 54: Structure of electricity price

    DANG Minh-Quan 36

  • 9 ECONOMIC CONSIDERATION

    Figure 55: Price variation

    9.3 Billing scenarios, type of tariffs

    Figure 56: Billing scenario

    DANG Minh-Quan 37

  • 9 ECONOMIC CONSIDERATION

    Figure 57: Feed in tariff

    9.4 Energy payback time, carbon footprint, recycle

    Figure 58: Energy payback time

    DANG Minh-Quan 38

  • REFERENCES

    References

    [1] Konrad Mertens. Photovoltaics: Fundamentals, Technology and Practice. JohnWiley & Sons, 2013.

    [2] Ph.D. Mgr. Jakub Holovsky. Ae1m13ezf - electrochemical sources and photo-voltaics.

    DANG Minh-Quan 39

    General considerations What are the energy needs of mankind, trends and problems of fossil fuels? What is renewable source and what are perspectives of different types?What are the spectral properties and components of the sunlight? What are the time variation properties and limits of the sun as a source?

    Solar cell physical aspectsWhat is the main limit (hint: of the single-junction) solar cell efficiency? What determines the generated voltage and the generated current in solar cell? Equivalent circuit of solar cell and diode equation.

    Solar cell Construction and Technology Fabrication of silicon wafers Fabrication of standard crystalline silicon solar cell Optical losses, improvements of standard crystalline cell technology External Quantum Efficiency, its integral, types of losses

    Thin filmMaterial requirements and application advantages of thin-film technologies Examples of mainstream and emerging thin film technologies, perspectives

    Construction and technology of PV modulesWhat determines the total power parameters of the module?Effect of shading and its mitigation Module fabrication components and steps, thin-film solar module interconnection scheme. Effect of temperature and its partial mitigation, what is NOCT?

    Autonomous PV systemsSystem with battery with / without regulator Standalone household system and its dimensioning with / without backup (hybrid).

    On-grid PV systemTypes of on-grid systems, sizing of PV inverter and string, requirements for cables Types and topologies of inverters, detailed wiring of small and medium system Effect of PV on the grid (quality, voltage, stability)

    DiagnosticsDiagnostics: type of failures, their consequences and methods to reveal Maintenance, lifetime, monitoring, diagnostics using inverters, Potential Induced Degradation I-V measurements: indoor/outdoor, requirements for sun simulator Photo-/electro-luminescence: principle and type of failures Thermography: principle and type of failures

    Economic considerationLevelized Cost of Energy, effect of efficiency on the cost of electricity Structure of the end user electricity price, time evolution in yearly and daily scale Billing scenarios, type of tariffs Energy payback time, carbon footprint, recycle

    References