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Piezoelectricity From Wikipedia, the free encyclopedia Piezoelectricity ( / p i ˌ eɪ z oʊ ˌ i l ɛ k ˈ t r ɪ s ɪ t i/) is the charge that accumulates in certain solid materials (notably crystals, certain ceramics, and biological matter such as bone, DNA and various proteins) [1] in response to applied mechanical stress. The word piezoelectricity means electricity resulting from pressure. It is derived from the Greek piezo or piezein (πιέζειν), which means to squeeze or press, and electric or electron (ήλεκτρον ), which stands for amber, an ancient source of electric charge. [2] Piezoelectricity was discovered in 1880 by French physicists Jacques and Pierre Curie. The piezoelectric effect is understood as the linear electromechanical interaction between the mechanical and the electrical state in crystalline materials with no inversion symmetry. [3] The piezoelectric effect is a reversible process in that materials exhibiting the direct piezoelectric effect (the internal generation of electrical charge resulting from an applied mechanical force) also exhibit the reverse piezoelectric effect (the internal generation of a mechanical strain resulting from an applied electrical field). For example, lead zirconate titanate crystals will generate measurable piezoelectricity when their static structure is deformed by about 0.1% of the original dimension. Conversely, those same crystals will change about 0.1% of their static dimension when an external electric field is applied to the material. The inverse piezoelectric effect is used in production of ultrasonic sound waves. [4] Piezoelectricity is found in useful applications such as the production and detection of sound, generation of high voltages, electronic frequency generation, microbalances, and ultrafine focusing of optical assemblies. It is also the basis of a number of scientific instrumental techniques with atomic resolution, the scanning probe microscopies such as STM, AFM, MTA, SNOM, etc., and everyday uses such as acting as the ignition source for cigarette lighters and push-start propane barbecues. Contents 1 History 1.1 Discovery and early research 1.2 World War I and post-war 1.3 World War II and post-war 2 Mechanism 2.1 Mathematical description 3 Crystal classes 4 Materials 4.1 Naturally occurring crystals 4.2 Bone 4.3 Other natural materials 4.4 Synthetic crystals 4.5 Synthetic ceramics 4.6 Lead-free piezoceramics 4.7 Polymers 4.8 Organic Nanostructures 5 Applications 5.1 High voltage and power sources 5.2 Sensors 5.3 Actuators 5.4 Frequency standard 5.5 Piezoelectric motors 5.6 Reduction of vibrations and noise 5.7 Infertility treatment

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Page 1: Piezoelectricity - Wikipedia, the free encyclopedia · Piezoelectricity From Wikipedia, the free encyclopedia Piezoelectricity ( /piezo ilktrsti/) is the charge that accumulates in

PiezoelectricityFrom Wikipedia, the free encyclopedia

Piezoelectricity ( /piˌeɪzoʊˌilɛkˈtrɪsɪti/) is the charge that accumulates in certain solid materials

(notably crystals, certain ceramics, and biological matter such as bone, DNA and various proteins)[1] inresponse to applied mechanical stress. The word piezoelectricity means electricity resulting frompressure. It is derived from the Greek piezo or piezein (πιέζειν), which means to squeeze or press, and

electric or electron (ήλεκτρον), which stands for amber, an ancient source of electric charge.[2]

Piezoelectricity was discovered in 1880 by French physicists Jacques and Pierre Curie.

The piezoelectric effect is understood as the linear electromechanical interaction between the

mechanical and the electrical state in crystalline materials with no inversion symmetry.[3] Thepiezoelectric effect is a reversible process in that materials exhibiting the direct piezoelectric effect (theinternal generation of electrical charge resulting from an applied mechanical force) also exhibit thereverse piezoelectric effect (the internal generation of a mechanical strain resulting from an appliedelectrical field). For example, lead zirconate titanate crystals will generate measurable piezoelectricitywhen their static structure is deformed by about 0.1% of the original dimension. Conversely, thosesame crystals will change about 0.1% of their static dimension when an external electric field isapplied to the material. The inverse piezoelectric effect is used in production of ultrasonic sound

waves.[4]

Piezoelectricity is found in useful applications such as the production and detection of sound,generation of high voltages, electronic frequency generation, microbalances, and ultrafine focusing ofoptical assemblies. It is also the basis of a number of scientific instrumental techniques with atomicresolution, the scanning probe microscopies such as STM, AFM, MTA, SNOM, etc., and everyday usessuch as acting as the ignition source for cigarette lighters and push-start propane barbecues.

Contents

1 History1.1 Discovery and early research1.2 World War I and post-war1.3 World War II and post-war

2 Mechanism2.1 Mathematical description

3 Crystal classes4 Materials

4.1 Naturally occurring crystals4.2 Bone4.3 Other natural materials4.4 Synthetic crystals4.5 Synthetic ceramics4.6 Lead-free piezoceramics4.7 Polymers4.8 Organic Nanostructures

5 Applications5.1 High voltage and power sources5.2 Sensors5.3 Actuators5.4 Frequency standard5.5 Piezoelectric motors5.6 Reduction of vibrations and noise5.7 Infertility treatment

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A piezoelectric disk generates a

voltage when deformed (change inshape is greatly exaggerated)

5.8 Surgery6 See also7 References

7.1 International standards8 External links

History

Discovery and early research

The pyroelectric effect, by which a material generates an electric potential in response to atemperature change, was studied by Carl Linnaeus and Franz Aepinus in the mid-18th century.[citation needed] Drawing on this knowledge, both René Just Haüy and Antoine César Becquerel positeda relationship between mechanical stress and electric charge; however, experiments by both proved

inconclusive.[citation needed]

The first demonstration of the direct piezoelectric effect was in 1880 by the brothers Pierre Curie and

Jacques Curie.[5] They combined their knowledge of pyroelectricity with their understanding of theunderlying crystal structures that gave rise to pyroelectricity to predict crystal behavior, anddemonstrated the effect using crystals of tourmaline, quartz, topaz, cane sugar, and Rochelle salt(sodium potassium tartrate tetrahydrate). Quartz and Rochelle salt exhibited the most piezoelectricity.

The Curies, however, did not predict the converse piezoelectriceffect. The converse effect was mathematically deduced fromfundamental thermodynamic principles by Gabriel Lippmann in

1881.[6] The Curies immediately confirmed the existence of the

converse effect,[7] and went on to obtain quantitative proof of thecomplete reversibility of electro-elasto-mechanical deformations inpiezoelectric crystals.

For the next few decades, piezoelectricity remained something of alaboratory curiosity. More work was done to explore and define thecrystal structures that exhibited piezoelectricity. This culminated in1910 with the publication of Woldemar Voigt's Lehrbuch der

Kristallphysik (Textbook on Crystal Physics),[8] which described the20 natural crystal classes capable of piezoelectricity, and rigorouslydefined the piezoelectric constants using tensor analysis.

World War I and post-war

The first practical application for piezoelectric devices was sonar, first developed during World War I. InFrance in 1917, Paul Langevin and his coworkers developed an ultrasonic submarine detector.[citation needed] The detector consisted of a transducer, made of thin quartz crystals carefully gluedbetween two steel plates, and a hydrophone to detect the returned echo. By emitting a high-frequencychirp from the transducer, and measuring the amount of time it takes to hear an echo from the soundwaves bouncing off an object, one can calculate the distance to that object.

The use of piezoelectricity in sonar, and the success of that project, created intense developmentinterest in piezoelectric devices. Over the next few decades, new piezoelectric materials and newapplications for those materials were explored and developed.

Piezoelectric devices found homes in many fields. Ceramic phonograph cartridges simplified playerdesign, were cheap and accurate, and made record players cheaper to maintain and easier to build.

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Piezoelectric plate used to convert

audio signal to sound waves

The development of the ultrasonic transducer allowed for easy measurement of viscosity and elasticityin fluids and solids, resulting in huge advances in materials research. Ultrasonic time-domainreflectometers (which send an ultrasonic pulse through a material and measure reflections fromdiscontinuities) could find flaws inside cast metal and stone objects, improving structural safety.

World War II and post-war

During World War II, independent research groups in the United States, Russia, and Japan discovereda new class of synthetic materials, called ferroelectrics, which exhibited piezoelectric constants manytimes higher than natural materials. This led to intense research to develop barium titanate and laterlead zirconate titanate materials with specific properties for particular applications.

One significant example of the use of piezoelectric crystals was developed by Bell TelephoneLaboratories. Following World War I, Frederick R. Lack, working in radio telephony in the engineeringdepartment, developed the “AT cut” crystal, a crystal that operated through a wide range oftemperatures. Lack's crystal didn't need the heavy accessories previous crystal used, facilitating itsuse on aircraft. This development allowed Allied air forces to engage in coordinated mass attacksthrough the use of aviation radio.

Development of piezoelectric devices and materials in the United States was kept within thecompanies doing the development, mostly due to the wartime beginnings of the field, and in theinterests of securing profitable patents. New materials were the first to be developed — quartz crystalswere the first commercially exploited piezoelectric material, but scientists searched for higher-performance materials. Despite the advances in materials and the maturation of manufacturingprocesses, the United States market had not grown as quickly. Without many new applications, thegrowth of the United States' piezoelectric industry suffered.

In contrast, Japanese manufacturers shared their information, quickly overcoming technical andmanufacturing challenges and creating new markets. Japanese efforts in materials research createdpiezoceramic materials competitive to the U.S. materials, but free of expensive patent restrictions.Major Japanese piezoelectric developments include new designs of piezoceramic filters for radios andtelevisions, piezo buzzers and audio transducers that can connect directly to electronic circuits, andthe piezoelectric igniter, which generates sparks for small engine ignition systems (and gas-grilllighters) by compressing a ceramic disc. Ultrasonic transducers that transmit sound waves through airhad existed for quite some time, but first saw major commercial use in early television remote controls.These transducers now are mounted on several car models as an echolocation device, helping thedriver determine the distance from the rear of the car to any objects that may be in its path.

Mechanism

The nature of the piezoelectric effect is closely related to theoccurrence of electric dipole moments in solids. The latter mayeither be induced for ions on crystal lattice sites with asymmetriccharge surroundings (as in BaTiO3 and PZTs) or may directly becarried by molecular groups (as in cane sugar). The dipole density

or polarization (dimensionality [Cm/m3] ) may easily be calculatedfor crystals by summing up the dipole moments per volume of the

crystallographic unit cell.[9] As every dipole is a vector, the dipole density P is a vector field. Dipolesnear each other tend to be aligned in regions called Weiss domains. The domains are usuallyrandomly oriented, but can be aligned using the process of poling (not the same as magnetic poling),a process by which a strong electric field is applied across the material, usually at elevated

temperatures. Not all piezoelectric materials can be poled.[10]

Of decisive importance for the piezoelectric effect is the change of polarization P when applying amechanical stress. This might either be caused by a re-configuration of the dipole-inducing

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surrounding or by re-orientation of molecular dipole moments under the influence of the externalstress. Piezoelectricity may then manifest in a variation of the polarization strength, its direction orboth, with the details depending on 1. the orientation of P within the crystal, 2. crystal symmetry and 3.the applied mechanical stress. The change in P appears as a variation of surface charge density uponthe crystal faces, i.e. as a variation of the electrical field extending between the faces, since the units

of surface charge density and polarization are the same, [C/m2] = [Cm/m3]. However, piezoelectricity isnot caused by a change in charge density on the surface, but by dipole density in the bulk. For

example, a 1 cm3 cube of quartz with 2 kN (500 lbf) of correctly applied force can produce a voltage of

12500 V.[11]

Piezoelectric materials also show the opposite effect, called converse piezoelectric effect, where theapplication of an electrical field creates mechanical deformation in the crystal.

Mathematical description

Piezoelectricity is the combined effect of the electrical behavior of the material:

where D is the electric charge density displacement (electric displacement), ε is permittivity and E iselectric field strength, and

Hooke's Law:

where S is strain, s is compliance and T is stress.

These may be combined into so-called coupled equations, of which the strain-charge form is:

,

where is the matrix for the direct piezoelectric effect and is the matrix for the conversepiezoelectric effect. The superscript E indicates a zero, or constant, electric field; the superscript Tindicates a zero, or constant, stress field; and the superscript t stands for transposition of a matrix.

The strain-charge for a material of the 4mm (C4v) crystal class (such as a poled piezoelectric ceramicsuch as tetragonal PZT or BaTiO3) as well as the 6mm crystal class may also be written as (ANSIIEEE 176):

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where the first equation represents the relationship for the converse piezoelectric effect and the latter

for the direct piezoelectric effect.[12]

Although the above equations are the most used form in literature, some comments about the notationare necessary. Generally D and E are vectors, that is, Cartesian tensor of rank-1; and permittivity ε isCartesian tensor of rank 2. Strain and stress are, in principle, also rank-2 tensors. But conventionally,because strain and stress are all symmetric tensors, the subscript of strain and stress can bere-labeled in the following fashion: 11 → 1; 22 → 2; 33 → 3; 23 → 4; 13 → 5; 12 → 6. (Differentconvention may be used by different authors in literature. Say, some use 12 → 4; 23 → 5; 31 → 6instead.) That is why S and T appear to have the "vector form" of 6 components. Consequently, sappears to be a 6 by 6 matrix instead of rank-4 tensor. Such a re-labeled notation is often called Voigtnotation.

In total, there are 4 piezoelectric coefficients, , , , and defined as follows:

where the first set of 4 terms correspond to the direct piezoelectric effect and the second set of 4 terms

correspond to the converse piezoelectric effect.[13] A formalism has been worked out for thosepiezoelectric crystals, for which the polarization is of the crystal-field induced type, that allows for thecalculation of piezoelectrical coefficients from electrostatic lattice constants or higher-order

Madelung constants.[9]

Crystal classes

Of the thirty-two crystal classes, twenty-one are non-centrosymmetric (not having a centre ofsymmetry), and of these, twenty exhibit direct piezoelectricity (the 21st is the cubic class 432). Ten ofthese represent the polar crystal classes, which show a spontaneous polarization without mechanicalstress due to a non-vanishing electric dipole moment associated with their unit cell, and which exhibitpyroelectricity. If the dipole moment can be reversed by the application of an electric field, the materialis said to be ferroelectric.

Polar crystal classes: 1, 2, m, mm2, 4, 4 mm, 3, 3m, 6, 6 mm.Piezoelectric crystal classes: 1, 2, m, 222, mm2, 4, 4, 422, 4 mm, 42m, 3, 32, 3m, 6, 6, 622,6 mm, 62m, 23, 43m.

For polar crystals, for which P ≠ 0 holds without applying a mechanical load, the piezoelectric effect

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Any spatially separated charge willresult in an electric field, and

therefore an electric potential.Shown here is a standard

dielectric in a capacitor. In apiezoelectric device, mechanicalstress, instead of an externally

applied voltage, causes thecharge separation in the individual

atoms of the material, .

manifests itself by changing the magnitude or the direction of P orboth. For the non-polar, but piezoelectric crystals, on the otherhand, a polarization P different from zero is only elicited byapplying a mechanical load. For them the stress can be imaginedto transform the material from a non-polar crystal class (P =0) to a

polar one,[9] having P ≠ 0.

Materials

Many materials, both natural and synthetic, exhibit piezoelectricity:

Naturally occurring crystals

Berlinite (AlPO4), a rare phosphate mineral that is structurallyidentical to quartzSucrose (table sugar)QuartzRochelle saltTopazTourmaline-group minerals

The action of piezoelectricity in Topaz can probably be attributed toordering of the (F,OH) in its lattice, which is otherwisecentrosymmetric: Orthorhombic Bipyramidal (mmm). Topaz hasanomalous optical properties which are attributed to such

ordering.[14]

Bone

Dry bone exhibits some piezoelectric properties. Studies of Fukada et al. showed that these are notdue to the apatite crystals, which are centrosymmetric, thus non-piezoelectric, but due to collagen.Collagen exhibits the polar uniaxial orientation of molecular dipoles in its structure and can beconsidered as bioelectret, a sort of dielectric material exhibiting quasipermanent space charge anddipolar charge. Potentials are thought to occur when a number of collagen molecules are stressed inthe same way displacing significant numbers of the charge carriers from the inside to the surface ofthe specimen. Piezoelectricity of single individual collagen fibrils was measured using piezoresponseforce microscopy, and it was shown that collagen fibrils behave predominantly as shear piezoelectric

materials.[15]

The piezoelectric effect is generally thought to act as a biological force sensor.[16][17] This effect wasexploited by research conducted at the University of Pennsylvania in the late 1970s and early 1980s,which established that sustained application of electrical potential could stimulate both resorption and

growth (depending on the polarity) of bone in-vivo.[18] Further studies in the 1990s provided themathematical equation to confirm long bone wave propagation as to that of hexagonal (Class 6)

crystals.[19]

Other natural materials

Biological materials exhibiting piezoelectric properties include:

TendonSilkWood due to piezoelectric textureEnamel

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Tetragonal unit cell of lead titanate

DentinDNAViral proteins, including those from bacteriophage. One study has found that thin films of M13bacteriophage can be used to construct a piezoelectric generator sufficient to operate a liquid

crystal display.[20]

Synthetic crystals

Gallium orthophosphate (GaPO4), a quartz analogic crystalLangasite (La3Ga5SiO14), a quartz analogic crystal

Synthetic ceramics

The family of ceramics with perovskite or tungsten-bronzestructures exhibits piezoelectricity:

Barium titanate (BaTiO3)—Barium titanate was the firstpiezoelectric ceramic discovered.Lead titanate (PbTiO3)Lead zirconate titanate (Pb[ZrxTi1−x]O3 0≤x≤1)—morecommonly known as PZT, lead zirconate titanate is the mostcommon piezoelectric ceramic in use today.Potassium niobate (KNbO3)Lithium niobate (LiNbO3)Lithium tantalate (LiTaO3)Sodium tungstate (Na2WO3)Zinc oxide (ZnO)Ba2NaNb5O5Pb2KNb5O15

Lead-free piezoceramics

More recently, there is growing concern regarding the toxicity in lead-containing devices driven by theresult of restriction of hazardous substances directive regulations. To address this concern, there hasbeen a resurgence in the compositional development of lead-free piezoelectric materials.

Sodium potassium niobate ((K,Na)NbO3). In 2004, a group of Japanese researchers led byYasuyoshi Saito discovered a sodium potassium niobate composition with properties close to

those of PZT, including a high .[21]

Bismuth ferrite (BiFeO3) is also a promising candidate for the replacement of lead-basedceramics.Sodium niobate NaNbO3Bismuth titanate Bi4Ti3O12Sodium bismuth titanate Na0.5Bi0.5TiO3

So far, neither the environmental impact nor the stability of supplying these substances have beenconfirmed.

Polymers

Polyvinylidene fluoride (PVDF): PVDF exhibits piezoelectricity several times greater than quartz.Unlike ceramics, where the crystal structure of the material creates the piezoelectric effect, inpolymers the intertwined long-chain molecules attract and repel each other when an electric fieldis applied.

Organic Nanostructures

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A strong shear piezoelectric activity was observed in self-assembled diphenylalanine peptidenanotubes (PNTs), indicating electric polarization directed along the tube axis. Comparison withLiNbO3 and lateral signal calibration yields sufficiently high effective piezoelectric coefficientvalues of at least 60 pm/V (shear response for tubes of ≈200 nm in diameter). PNTs demonstrate

linear deformation without irreversible degradation in a broad range of driving voltages.[22]

Applications

Currently, industrial and manufacturing is the largest application market for piezoelectric devices,followed by the automotive industry. Strong demand also comes from medical instruments as well asinformation and telecommunications. The global demand for piezoelectric devices was valued atapproximately US$14.8 billion in 2010. The largest material group for piezoelectric devices ispiezocrystal, and piezopolymer is experiencing the fastest growth due to its low weight and small

size.[23]

Piezoelectric crystals are now used in numerous ways:

High voltage and power sources

Direct piezoelectricity of some substances, like quartz, can generate potential differences of thousandsof volts.

The best-known application is the electric cigarette lighter: pressing the button causes a spring-loaded hammer to hit a piezoelectric crystal, producing a sufficiently high voltage electric currentthat flows across a small spark gap, thus heating and igniting the gas. The portable sparkersused to ignite gas stoves work the same way, and many types of gas burners now have built-inpiezo-based ignition systems.A similar idea is being researched by DARPA in the United States in a project called Energy

Harvesting, which includes an attempt to power battlefield equipment by piezoelectric generatorsembedded in soldiers' boots. However, these energy harvesting sources by association have animpact on the body. DARPA's effort to harness 1–2 watts from continuous shoe impact whilewalking were abandoned due to the impracticality and the discomfort from the additional energyexpended by a person wearing the shoes. Other energy harvesting ideas include harvesting the

energy from human movements in train stations or other public places[24][25] and converting a

dance floor to generate electricity.[26] Vibrations from industrial machinery can also be harvestedby piezoeletric materials to charge batteries for backup supplies or to power low-power

microprocessors and wireless radios.[27]

A piezoelectric transformer is a type of AC voltage multiplier. Unlike a conventional transformer,which uses magnetic coupling between input and output, the piezoelectric transformer usesacoustic coupling. An input voltage is applied across a short length of a bar of piezoceramicmaterial such as PZT, creating an alternating stress in the bar by the inverse piezoelectric effectand causing the whole bar to vibrate. The vibration frequency is chosen to be the resonantfrequency of the block, typically in the 100 kilohertz to 1 megahertz range. A higher outputvoltage is then generated across another section of the bar by the piezoelectric effect. Step-upratios of more than 1000:1 have been demonstrated. An extra feature of this transformer is that,by operating it above its resonant frequency, it can be made to appear as an inductive load,

which is useful in circuits that require a controlled soft start.[28] These devices can be used inDC-AC inverters to drive cold cathode fluorescent lamps. Piezo transformers are some of themost compact high voltage sources.

Sensors

Main article: Piezoelectric sensor

The principle of operation of a piezoelectric sensor is that a physical dimension, transformed into a

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Piezoelectric disk used as a guitar

pickup

Many rocket-propelled grenadesused a piezoelectric fuze. For

example: RPG-7[29]

Metal disk with piezoelectric diskattached, used in a buzzer

force, acts on two opposing faces of the sensing element.Depending on the design of a sensor, different "modes" to load thepiezoelectric element can be used: longitudinal, transversal andshear.

Detection of pressure variations in the form of sound is the mostcommon sensor application, e.g. piezoelectric microphones (soundwaves bend the piezoelectric material, creating a changing voltage)and piezoelectric pickups for Acoustic-electric guitars. A piezosensor attached to the body of an instrument is known as a contactmicrophone.

Piezoelectric sensors especially are used with high frequencysound in ultrasonic transducers for medical imaging and alsoindustrial nondestructive testing (NDT).

For many sensing techniques, the sensor can act as both a sensorand an actuator – often the term transducer is preferred when thedevice acts in this dual capacity, but most piezo devices have thisproperty of reversibility whether it is used or not. Ultrasonictransducers, for example, can inject ultrasound waves into thebody, receive the returned wave, and convert it to an electricalsignal (a voltage). Most medical ultrasound transducers arepiezoelectric.

In addition to those mentioned above, various sensor applicationsinclude:

Piezoelectric elements are also used in the detection and generation of sonar waves.Power monitoring in high power applications (e.g. medical treatment, sonochemistry andindustrial processing).Piezoelectric microbalances are used as very sensitive chemical and biological sensors.Piezos are sometimes used in strain gauges.Piezoelectric transducers are used in electronic drum pads to detect the impact of the drummer'ssticks, and to detect muscle movements in medical acceleromyography.Automotive engine management systems use piezoelectric transducers to detect Engine knock(Knock Sensor, KS), also known as detonation, at certain hertz frequencies. A piezoelectrictransducer is also used in fuel injection systems to measure manifold absolute pressure (MAPsensor) to determine engine load, and ultimately the fuel injectors milliseconds of on time.Ultrasonic piezo sensors are used in the detection of acoustic emissions in acoustic emissiontesting.

Actuators

As very high electric fields correspond to only tiny changes in thewidth of the crystal, this width can be changed with better-than-µmprecision, making piezo crystals the most important tool forpositioning objects with extreme accuracy — thus their use inactuators. Multilayer ceramics, using layers thinner than 100 µm,allow reaching high electric fields with voltage lower than 150 V.These ceramics are used within two kinds of actuators: direct piezoactuators and Amplified piezoelectric actuators. While directactuator's stroke is generally lower than 100 µm, amplified piezoactuators can reach millimeter strokes.

Loudspeakers: Voltage is converted to mechanical movementof a piezoelectric polymer film.

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A slip-stick actuator.

Piezoelectric motors: Piezoelectric elements apply a directional force to an axle, causing it torotate. Due to the extremely small distances involved, the piezo motor is viewed as ahigh-precision replacement for the stepper motor.Piezoelectric elements can be used in laser mirror alignment, where their ability to move a largemass (the mirror mount) over microscopic distances is exploited to electronically align some lasermirrors. By precisely controlling the distance between mirrors, the laser electronics canaccurately maintain optical conditions inside the laser cavity to optimize the beam output.A related application is the acousto-optic modulator, a device that scatters light off ofsoundwaves in a crystal, generated by piezoelectric elements. This is useful for fine-tuning alaser's frequency.Atomic force microscopes and scanning tunneling microscopes employ converse piezoelectricity

to keep the sensing needle close to the probe.[30]

Inkjet printers: On many inkjet printers, piezoelectric crystals are used to drive the ejection of inkfrom the inkjet print head towards the paper.Diesel engines: High-performance common rail diesel engines use piezoelectric fuel injectors,first developed by Robert Bosch GmbH, instead of the more common solenoid valve devices.Active vibration control using amplified actuators.X-ray shutters.XY stages for micro scanning used in infrared cameras.Moving the patient precisely inside active CT and MRI scanners where the strong radiation or

magnetism precludes electric motors.[31]

Crystal earpieces are sometimes used in old or low power radios.

Frequency standard

The piezoelectrical properties of quartz are useful as standard of frequency.

Quartz clocks employ a crystal oscillator made from a quartz crystal that uses a combination ofboth direct and converse piezoelectricity to generate a regularly timed series of electrical pulsesthat is used to mark time. The quartz crystal (like any elastic material) has a precisely definednatural frequency (caused by its shape and size) at which it prefers to oscillate, and this is usedto stabilize the frequency of a periodic voltage applied to the crystal.The same principle is critical in all radio transmitters and receivers, and in computers where itcreates a clock pulse. Both of these usually use a frequency multiplier to reach gigahertzranges.

Piezoelectric motors

Main article: Piezoelectric motor

Types of piezoelectric motor include:

The traveling-wave motor used for auto-focus in reflexcamerasInchworm motors for linear motionRectangular four-quadrant motors with high power density

(2.5 watt/cm3) and speed ranging from 10 nm/s to 800 mm/s.Stepping piezo motor, using stick-slip effect.

All these motors, except the stepping stick-slip motor work on thesame principle. Driven by dual orthogonal vibration modes with aphase difference of 90°, the contact point between two surfacesvibrates in an elliptical path, producing a frictional force betweenthe surfaces. Usually, one surface is fixed causing the other tomove. In most piezoelectric motors the piezoelectric crystal is excited by a sine wave signal at theresonant frequency of the motor. Using the resonance effect, a much lower voltage can be used to

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produce a high vibration amplitude.

Stick-slip motor works using the inertia of a mass and the friction of a clamp. Such motors can be verysmall. Some are used for camera sensor displacement, allowing anti shake function.

Reduction of vibrations and noise

Different teams of researchers have been investigating ways to reduce vibrations in materials byattaching piezo elements to the material. When the material is bent by a vibration in one direction, thevibration-reduction system responds to the bend and sends electric power to the piezo element tobend in the other direction. Future applications of this technology are expected in cars and houses toreduce noise.

In a demonstration at the Material Vision Fair in Frankfurt in November 2005, a team from TUDarmstadt in Germany showed several panels that were hit with a rubber mallet, and the panel withthe piezo element immediately stopped swinging.

Piezoelectric ceramic fiber technology is being used as an electronic damping system on some HEAD

tennis rackets.[32]

Infertility treatment

In people with previous total fertilization failure, piezoelectric activation of oocytes together with

intracytoplasmic sperm injection (ICSI) seems to improve fertilization outcome.[33]

Surgery

A recent application of piezoelectric ultrasound sources is piezoelectric surgery, also known as

piezosurgery.[34] Piezosurgery is a minimally invasive technique that aims to cut a target tissue with

little damage to neighboring tissues. For example, Hoigne et al.[35] reported its use in hand surgery forthe cutting of bone, using frequencies in the range 25–29 kHz, causing microvibrations of 60–210 µm.It has the ability to cut mineralized tissue without cutting neurovascular tissue and other soft tissue,

thereby maintaining a blood-free operating area, better visibility and greater precision.[36]

See also

Charge amplifierElectronic componentElectretElectrostrictionEnergy harvesting, methods of convertingother forms of energy to electricity.FerroelectricityFlexoelectricity

MagnetostrictionPhotoelectric effectPiezoluminescencePiezomagnetismPiezosurgicalPiezoresistive effectSonomicrometrySurface acoustic waveTriboluminescence

References

^ Holler, F. James; Skoog, Douglas A; Crouch, Stanley R (2007). "Chapter 1". Principles of Instrumental

Analysis (6th ed.). Cengage Learning. p. 9. ISBN 978-0-495-01201-6.1.

^ Harper, Douglas. "piezoelectric" (http://www.etymonline.com/index.php?term=piezoelectric) . Online

Etymology Dictionary. http://www.etymonline.com/index.php?term=piezoelectric.2.

^ Gautschi, G (2002). Piezoelectric Sensorics: Force, Strain, Pressure, Acceleration and Acoustic Emission3.

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Sensors, Materials and Amplifiers.. Springer.^ J. Krautkrämer, and H. Krautkrämer (1990). Ultrasonic Testing of Materials. Springer.4.^ Jacques and Pierre Curie (1880) "Développement par compression de l’électricité polaire dans les cristauxhémièdres à faces inclinées" (Development, via compression, of electric polarization in hemihedral crystalswith inclined faces), Bulletin de la Société minérologique de France, vol. 3, pages 90 - 93. Reprinted in:Jacques and Pierre Curie (1880) Développement, par pression, de l’électricité polaire dans les cristauxhémièdres à faces inclinées," (http://gallica.bnf.fr/ark:/12148/bpt6k30485/f296.image) Comptes rendus ... ,vol. 91, pages 294 - 295. See also: Jacques and Pierre Curie (1880) "Sur l’électricité polaire dans les cristauxhémièdres à faces inclinées" (http://gallica.bnf.fr/ark:/12148/bpt6k30485/f385.image) (On electric polarizationin hemihedral crystals with inclined faces), Comptes rendus ... , vol. 91, pages 383 - 386.

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International standards

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ANSI-IEEE 176 (1987) Standard on PiezoelectricityIEEE 177 (1976) Standard Definitions & Methods of Measurement for Piezoelectric VibratorsIEC 444 (1973) Basic method for the measurement of resonance freq & equiv series resistance ofquartz crystal units by zero-phase technique in a pi-networkIEC 302 (1969) Standard Definitions & Methods of Measurement for Piezoelectric VibratorsOperating over the Freq Range up to 30 MHz

External links

Gautschi, Gustav H., 2002, Piezoelectric Sensorics, Springer, ISBN 3-540-42259-5,Fundamentals of Piezoelectrics (http://www.amazon.com/Fundamentals-Piezoelectric-Sensorics-Mechanical-Thermodynamical/dp/3540439668/ref=sr_1_2?ie=UTF8&s=books&qid=1275053589&sr=1-2)Piezo motor based microdrive for neural signal recording (http://www.ncbi.nlm.nih.gov/pubmed/19163430)History of Piezoelectricity (http://www.piezoinstitute.com/about/piezohistory/index.php)Research on new Piezoelectric materials (http://www.scientificblogging.com/news_account/research_new_piezoelectric_materials)Piezo Equations (http://www.techonline.com/showArticle.jhtml?articleID=192201162&queryText=22)Piezo in Medical Design (http://medicaldesign.com/motors-motion-control/precision-via-piezo-20100501/)Video demonstration of Piezoelectricity (http://vega.org.uk/video/programme/195)DoITPoMS Teaching and Learning Package – Piezoelectric Materials (http://www.doitpoms.ac.uk/tlplib/piezoelectrics/index.php)Piezo Motor Types

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